Download as pdf or txt
Download as pdf or txt
You are on page 1of 21

(Batches: SANKALP2325M1)

IIT – JEE, 2325 Paper Code


101206
Time: 2 Hours Maximum Marks: 126
INSTRUCTIONS
A. General
1. Write your Name, Enrolment number in the space provided on this booklet as soon as you get the paper.
2. Blank papers, clipboards, log tables, slide rules, calculators, cameras, cellular phones, pagers, and electronic
gadgets of any kind are NOT allowed in the examination hall.
3. Use a ball point pen do darken the bubbles on OMR sheet as your answer besides Name, Enrolment
number, Phase, Paper sequence, Venue, Date along with your signature on OMR sheet.

B. Question Paper Format


The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part consists of
three sections.
4. Section–1 (01 – 06) contains (06) Multiple Choice Questions which have Only One Correct answer. Each
question will be evaluated according to the following marking scheme.
Full Marks : +3 If only (all) the correct option(s) is (are) chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases
5 Section–2 (07 – 09) contains (03) Multiple Choice Questions which have one or more than one
correct answer. Each question will be evaluated according to the following marking scheme.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and
both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
6. Section–3 (10 – 12) contains (03) Non-Negative Numerical Value Questions, the answer to each
question is a Non-Negative Numerical Value. For each question, enter the correct numerical value
corresponding to the answer and each question carries +4 marks for correct answer. There is no
negative marking.

Enrolment No. :

Name : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Batch : . . . . . . . . . . . . . . . . . . . . . . .Session :. . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . .

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
WT-SANKALP2325M1-PCM-(101206)-2

PART I : PHYSICS
SECTION – 1 : (Only One Option Correct Type)

This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.

1. P and Q are two conductors carrying equal and opposite y


charge. The electric field created by two conductor is shown  Q

in the figure which is non uniform. The magnitude of electric  
   
 
field along y-axis is given by E  E0 1  ky3 , where k is a a
constant. The electric potential of conductor ‘P’ is + +
+ P +
 ka4  + +
2E0  a   . Then the potential of conductor Q is
 4  + +

 ka4   ka4 
(A) 2E0  a   (B) E0  a  
 4   4 
E0  ka4   ka4 
(C)  a   (D) 3E0  a  
2  4   4 

2. Two conducting spheres of unequal radii are given charge such that they have the same charge
density. If they are now brought in contact,
(A) No charge will be exchanged between them
(B) Charge will flow from the larger to the smaller sphere
(C) Charge will flow from the smaller to the larger sphere
(D) No heat will be produced

3. A solid conducting sphere of radius 2R, carrying charge Q is surrounded Q


R
by two point charges Q and 2Q as shown in the figure. The electric field at Q 2Q
point P due to the induced charges on conducting sphere is O P
7 KQ 1 KQ
(A) 2
towards right (B) towards right 3R 3R
16 R 8 R2
KQ
(C) 2 towards right (D) zero
R

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
WT-SANKALP2325M1-PCM-(101206)-3

4. Consider the capacitor circuit shown in the figure. Initially only K1 is C 2C


1
closed and after sufficiently long time, K2 is also closed. The charge
flowing through section 1  2 after closing the K2 is
K2
CE CE
(A)  from 2 to 1 (B)  from 2 to 1
2 6
CE K1 2
(C) CE from 2 to 1 (D) from 1 to 1 E
4
 
5. Two dipoles P1 and P2 are oriented as shown in the figure. y

Assuming dipole of dipole moment P2 to be placed at origin and

 
dipole of moment P1 is at a distance ‘d’ from origin then P2 P1
 1 P1P2
(A) Torque experienced by P1 is  k̂ d x
80 d3
 1 2P1P2
(B) Torque experienced by P1 is + k̂
4 0 d3
 1 P1P2
(C) Torque experienced by P2 is  k̂
40 d3
 1 P1P2
(D) Torque experienced by P2 is + k̂
40 d3

6. A charged particle A hangs with an inextensible string of length . Another O



charged particle B is fixed at a distance  below the point of suspension O 
A+

as shown in the figure. In the equilibrium the particle A is at a height h + h


above the level of particle B. If the mass of the particle A is m and B
acceleration due to gravity is g, then the electrical potential energy of
interaction of the particle in the equilibrium will be
(A) mgh (B) 2mgh
(C) 3mgh (D) 4mgh

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
WT-SANKALP2325M1-PCM-(101206)-4

SECTION – 2 : (One or More Than One Options Correct Type)

This section contains 3 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE are correct.

7. Variation of electric potential (V) due to a V Rectangular


3
charge spherical conducting system is (10 volt) hyperbola
shown in the figure.
1

10 20 30 r (cm)
(A) electric energy density is zero from r = 0 to r = 10 cm region.
1 2
(B) Electric flux through a spherical surface of radius r = 12 cm is  107 .N-m /C
90
1
(C) Electric potential energy of the system is  10 4 J
18
1
(D) .Electric potential energy of the system is  10 4 J
3

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
WT-SANKALP2325M1-PCM-(101206)-5

8. A parallel plate capacitor of plate area 0.2 m 2 and spacing 10-2 m is charged to 103 volt and then
disconnected from the battery, and pulled apart to double the plate spacing (take 0 = 8.8  1012
C2/N-m2).
-5
(A) work required to pull the plate is 8.8  10 J
3
(B) final voltage on the capacitor is 2  10 Volts.
(C) final charge on the capacitor becomes two times of initial
(D) final charge becomes half of initial value.

9. A disk of radius R with uniform positive charge density  is placed on the xy plane with its centre
at the origin. The Coulomb potential along the z-axis is

V z 
2 0 
R2  z2  z . 
A particle of positive charge q is placed initially at rest at a point on the z axis with z = z0 and z0 >

0. In addition to the Coulomb force, the particle experiences a vertical force F  ckˆ with c  0.
2c 0
Let   . Which of the following statements(s) is (are) correct?
q
1 25
(A) For   andz0  R , the particle reaches the origin.
4 7
1 3
(B) For   andz0  R , the particle reaches the origin.
4 7
1 R
(C) For   andz0  , the particle returns back to z=z0 .
4 3
(D) For  > 1 and z0 > 0, the particle always reaches the origin.

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
WT-SANKALP2325M1-PCM-(101206)-6

SECTION – 3: (Numerical Answer Type)

This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).

10. Three identical capacitors C1 , C2 and C3 have a


capacitance of 1.0 F each and they are uncharged V0 S2
initially. They are connected in a circuit as shown in the C3
figure and C1 is then filled completely with a dielectric
C1
material of relative permittivity r . The cell electromotive
force (emf) V0 = 8V. First the switch S1 is closed while the S1 C2
switch S2 is kept open. When the capacitor C3 is fully
charged, S1 is opened and S2 is closed simultaneously.
When all the capacitors reach equilibrium, the charge on C3
is found to be 5C. The value of r =_________.

11. A long wire has uniform charge density  = 3 C/m is


kept along z-axis. Another similar wire 2 is lying on x- y

y plane such that the minimum separation between


them is d = 2 m. Calculate the work done (in Joule) in
Wire-1
moving the wire-2 upto origin. (approximately)
 = 3 C/m

 = 3 C/m
x
2m
Wire-2
z

12. An electric field line emerges from the point charge q1 = 36 C at


an angle  to the straight line joining a negative charge of
 
magnitude (5K) C . If the same electric field line enters negative q1 q2
charge at an angle  to the same line, if  = 60o and  = 74o, then
find the value of K.

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
WT-SANKALP2325M1-PCM-(101206)-7

PART II: CHEMISTRY


SECTION – 1: (Only One Option Correct Type)

This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.

O
C

PCl5 LiAlH4 PCC OH
1. O   A  B   C 

D
C
O
Product (D) is:
CH2OH CH2 O

(A) (B)
COO COOH
O
CH2OH
(C) (D) O
COO
O

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
WT-SANKALP2325M1-PCM-(101206)-8

2. In the following series of transformations, provide the required information wherever a question
mark (?) is indicated respectively.
CH3 CH2Cl CH3COOH

? KCN ?

h

C2H5 OH
 ?  
Heat

CH3CN CH2CN

(A) H3O+, , Cl2 (B) Cl2, , H3O+

CH2OH CH2OH

(C) HCl, , H3O+ (D) Cl2, , HCl


3. OH
CH3 CH  CHCHO 
dil
 A  C8H12O 2  

H
Zn/Hg
B 
HCl
 C  C 8H12 
No. of stereo isomers are possible for compound (C) are:
(A) 2 (B) 8
(C) 6 (D) 4

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
WT-SANKALP2325M1-PCM-(101206)-9

4. O

NH OH
2

HCl
?

The major product of the following reaction is.....?


OH
Cl N

(A) (B)

O
OH
N
(C) (D) N

5. In the following reaction,


O

CF CO H
3 3
  B
Pr oduct 
The product (B) is:
(A) O (B) O

O
O

(C) O (D) O

O
O

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
WT-SANKALP2325M1-PCM-(101206)-10

6. The Keq. value in HCN addition to the following aldehydes are in the order:
O CHO

O C H

H3CO CHO
(I) (II) (III)
(A) I > II > III (B) III > II > I
(C) III > I > II (D) II > I > III

SECTION – 2 : (One or More Than One Options Correct Type)

This section contains 3 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE are correct.

7. Enolic form of which compounds contain intramolecular H bonding?


(A) O O (B) O O
H3C C CH 2 C CH3 H3C C CH2 C O C2H5
(C) O (D) O
H3C C CH2 CH3 H3C CH2 C H

8. In which of the following reaction(s), a pair of geometrical isomers would be produced


O O
|| ||
Heat Heat
(A) Ph  C  CH3  NH3   (B) Ph  C  Ph  NH3  
O
||
Heat Heat
(C) CH3CH2CHO  CH3NH2   (D) CH3  CH2  C  H  NH3  

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
WT-SANKALP2325M1-PCM-(101206)-11

9. NaHSO3 easily form adduct with


(A) CH3 – CHO (B) CH3 – CH2 – CHO
O
||
(C) CH3  C  CH3 (D) C6H5  CO  C6H5

SECTION – 3: (Numerical Answer Type)

This section contains THREE questions. The answer to each question is a SINGLE INTEGER VALUE.
For each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. XXXXX.XX).

10. What is the maximum number of moles of CH3MgCl that can be consumed by one mole of
phosgene(COCl2)?

11. Acetaldehyde when treated with Cl2 and NaOH solution followed by acidification forms CHCl3 and
compound X. CHCl3 can also give compound ‘X’ when treated with NaOH solution followed by
acidification. How many moles of NaOH used totally for the above mentioned reactions.

12. All possible carbonyl compounds with molecular formula (C8H8O) which has a benzene ring gives
in its structure and gives positive Tollen’s test, when are reacted with hydroxylamine how many
organic products will be possible with difference in melting point?

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
WT-SANKALP2325M1-PCM-(101206)-12

PART III : MATHEMATICS


SECTION – 1: (Only One Options Correct Type)

This section contains 6 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE is correct.

x2  20
1. If I =   x sin x  5cos x  2
dx , then I equals

x x
(A) –  tan x  c (B)  cot x  c
cos x  x sin x  5cos x  sin x  x sin x  5 cos x 
(C) (x sinx – 5cosx)–1 sinx + 7x + c (D) none of these

ex  x  1  x  ln x 
2.  dx is equal to
x2
 x  ln x   x  ln x  1 
(A) e x  c (B) e x  c
 x   x 
 x  ln x   x  ln x  1 
(C) e x  c (D) e x  c
 x2   x 

sin 2x  sin 4x  sin 6x


3.  1  cos 2x  cos 4x  cos 6x dx is equal to

1 1 1 1
(A) ln sec 3x  ln sec 2x  ln sec x  c (B) ln sec 3x  ln sec 2x  ln sec x  c
3 2 3 2
1 1 1 1
(C) C  ln sec 3x  ln sec 2x  ln sec x (D) C  ln sec 3x  ln sec 2x  ln sec x
3 2 3 2

tan2 x 4 2
4. If  sin  4x  e dx   A  cos x  etan x
 B , then A is equal to
(A) 1 (B) 2
(C) 1/2 (D) 4

Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
WT-SANKALP2325M1-PCM-(101206)-13

5. Let f(x) =
 4x 4
 2x 3  3x 2  4 dx  . If f(0) = 2, then the value of f(–1) is
 3 /2
x 4

 x3  1
(A) 6 (B) 10
(C) 1 (D) none of these

dx
6. If  cos 3
 A tan1  sin x  cos x   Bln(f(x))  C , then A is equal to
x  sin3 x
2 2
(A) (B)
3 5
2
(C)  (D) none of these
3

SECTION – 2: (Multi Correct Choice Type)

This section contains 3 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE may be correct.


x sec 2 x  tan xsin2x  f x
7. If e  x tan x  2 dx  e  g  x   c then which of the following is/are incorrect?
 
(A) f(0) is equal to = 1
3/2 1 3
(B) number of solution(s) of the equation  g  x    x is 3
2 2
3/2 1 3
(C) number of solution(s) of the equation  g  x    x is 1
2 2
(D) f(x) is an even function

Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
WT-SANKALP2325M1-PCM-(101206)-14

2014
8. If  cos  2016x   sin xdx  f  x   c ; f(0) = 0, then
2
(A) f(x) is odd (B)  f  x  dx  0


2015f  x 
(C)  f  x  dx  0 (D) lim
x 0 x 2015
1
0

cos x 2
9. If 
x
 
x lnx  1 dx = f(x) + c; f(1) = cos 1, and  f  x  sec
2
x dx  g  x   c ' ; g(1) = 0

and L  lim g  x  , then


x 0

x ln x
(A) f(x) = cos x (1 + ln x) – x sin x ln x (B) g  x  
cos x
g x
(C) L = 0 (D) lim 0
x  x 2

SECTION – 3: (Numerical Answer Type)

This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. XXXXX.XX).

10. If
1  x 2

dx 
a
 c tan1  x  d  e , then a + b + c + d is
34 2x  4x 4 xb

1 4

 x  x   
6
11.  x3 3
 2 3 dx =  x 6  2x 3 3  c , then 2 is equal to

12. The differentiable function F: R  R satisfies F(0) = –1 and


F  
F  x    sin  sin  sin  sin  x      cos  sin  sin  x     cos  sin  x    cos  x  . Then  2
is

Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
WT-SANKALP2325M1-PCM-(101206)-15

(Batches: SANKALP2325M1)
IIT – JEE, 2325 Paper Code
101206
ANSWERS
PHYSICS (PART-I)
1. B 2. B 3. A 4. C
5. C 6. B 7. A, B, C 8. A, B
9. A, C, D 10. 1.50 11. 1.00 12. 5.00

CHEMISTRY (PART-II)
1. A 2. B 3. C 4. D
5. B 6. B 7. A, B 8. A, C, D
9. A, B, C 10. 3 11. 8 12. 8

MATHEMATICS (PART-III)
1. A 2. D 3. B 4. B
5. A 6. A 7. A, B, D 8. A, B, C, D
9. B, C 10. 0 11. 0.25 12. 0.50

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
WT-SANKALP2325M1-PCM-(101206)-16

HINTS AND SOLUTION


PHYSICS (PART-I)

1. B
dV
E
dy
VQ VQ

 dV  Edy    E0 (1  ky 3 )dy
VP VP
a
y 4k
VQ  VP  E0 y 
4 0

 4
a k
VQ  VP  E0  a  
 4 
 ka4 
VQ  E0  a  
 4 

2. B
Let the spheres have radii r1 and r2 (r1 > r2).
4r12  r1 4r2 2  r2 
V1   ,V2  
40 r1 0 40 r2 0
 V1 > V2
 charge will flow from the larger to the smaller sphere.
Any flow of charge cause loss of energy and hence heat is produced.

3. A
k  2Q  k  Q  7kQ
Ei =  
 2R 2  4R 2 16R2

4. C
Initially charge configuration (before K2 is closed) is 2
 CE
2
C  3 CE
2
 CE
2
 CE
3 3 3
1

K2

K1 2
E
Final charge configuration (after K2 is closed) is
The net change of charge in the encircled region can +CE CE 1 0 0
happen only because of charge flowing in section 1  2.
Initial charge = 0
K2
Final charge = CE
 Charge flown = CE from 2 to 1.
K1 2
E

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
WT-SANKALP2325M1-PCM-(101206)-17

5. C
    2P2  ˆ 2P1P2 ˆ
1  P1  E   P1  ˆj   3 
i k
 4 0 d  40 d3
    P1  ˆ PP
2  P2  E   P2  ˆi    3 
j   1 2 3 kˆ
 40 d  40 d

6. B
h x
sin     x2 = 2h …(i)  
x 2  T F
q1q2  902
F …(ii)  q1
40 x 2
h 90 x/2
F mg
 x/2 mg
sin(180  2) sin(90  ) q2
F mg 2mgh
  F  2mgsin  =
sin2 cos  x
q1q2 2mgh
 
40 x 2 x
q1q2
U  2mgh
40 x
From these relation we get U = 2gh

7. A, B, C

8. A, B

9. A, C, D

10. 1.50

11. 1
AP = r = (x2 + d2 )1/2 E
Electric field at A due to wire 1
 
E= A x
Q
x Wire 2
20 r dx
dx B
Force on each elemental length dF = E. dq d
r d
   2 dx
dF =   ( dx) =  
 20r  20 (x2  d2 )1/2 P
Net force on the elemental length Wire 1
dFnet =2dF cos 
 2 dX.cos   2 dx.d
= 
0 (x2  d2 )1/2 0 (d2  x2 )
Hence total force required to hold the wire 2 =  dFnet
2d  dx 2 (3  10 6 )2
Fnet =   = 0.51 Newton.
0  (d2  x 2 ) 20 2  8.86  1012
As Fnet is independent of separation between the wire. Hence required work done
W = 0.51  2 = 1 Joule.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
WT-SANKALP2325M1-PCM-(101206)-18

12. 5
q1 1  cos    q2 1  cos  

CHEMISTRY (PART-II)
1. A
O O
C C
PCl5 Cl
O   LiAlH 4

Cl
C C
O O
CHO CH2 OH
CH2OH
PCC

OH  

CHO CH2 OH
COO
2. B

3. C
O
||
 A   CH3  CH  CH  CH  OH  CH2  CH  CH  C H
O
||
B   CH3  CH  CH  CH  CH  CH  CH  C H
 C   CH3  CH  CH  CH  CH  CH  CH  CH3
4. D
HO
O N OH
O NH2 OH HO NH
H2 N OH
H2 O




IMPT

 
 
 

N OH2 OH

N N
  H2 O
H

 
 
 HO
 
2
H

5. B
Bayer-Villiger oxidation.

6. B
III > II > I
In I – OCH3 is electron donating group (+M) so will decrease the electron deficiency at carbonyl
carbon to the most.
In II there is no electron donating group.
In III electron withdrawing group is present which will increase by electron deficiency at carbonyl
carbon.

7. A, B

8. A, C, D

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
WT-SANKALP2325M1-PCM-(101206)-19

9. A, B, C

10. 3
O O O Me
MeMgCl MeMgCl MeMgCl
Cl C Cl   Me C Cl   Me C Me   Me C Me
O

11. 8
O
 
Cl2 NaOH /
H3 C  C H    HCOOH  CHCl3   
NaOH / H
 HCOOH
 X
4 moles of NaOH Here also 4 moles
is consumed of NaOH is used

4+4=8

12. 8

CH2 CHO , CHO, CHO , H3C CHO

CH3 H3C
These are possible carbonyl compounds each of which will form two oximes.

MATHEMATICS (PART-III)
1. A
Multiply and divide by x8
x5 5x 4 cos x  x5 sin x
I=–   sec 2 xdx
 5 4
cos x x sin x  5x cos x   5 4
x sin x  5x cos x 
x
=–  tan x  c
cos x  x sin x  5cos x 

2. D
ex  x  1 x  ln x  1 1  e 
x

 dx   e x   2   ln  dx
x2 x x  x 
ex  ex   ex  e x ex ex
=  ln d   = ln    c = (x – lnx – 1) + c
x  x   x  x x x

3. B
2sin3x cos x  2sin3x cos3x
 2cos2 x  2cos x  cos5x
dx

sin3x  cos x  cos 3x 


 cos x  cos x  cos 5x 
dx

2sin3x  sin 2x  sin x


 2cos x  cos 3x  cos 2x
dx

 tan3x  tan2x  tan x dx


=   tan3x  tan2x  tan x  dx

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
WT-SANKALP2325M1-PCM-(101206)-20

4. B
tan2 x
 sin  4x  e dx
 1  tan2 x  tan2 x
4 sinx cos x  2 
e dx
 1  tan x 
2 2
Put tan x = y, 2 tan x sec x dx = dy
 1 y  dy
2 sin x cos x e y  
 1  y  tan x sec 2 x
1 y y 1 y
= 2 dy = 2 e dy
4

sec x 1  y   1  y 2
  1 2  2e y
= 2   e y  2
   dy =  B


 1  y 
 1  y 3 
 1  y 
2

A=2

5. A
  
A x 4  x3  1  Bx  C  4x 3  3x 2  4x 4  2x 3  3x 2  4 
 A = 4, B = 2, C = 1
dx  2x  1  4x3  3x2 
f(x)  4   3/2
x 4  x3  1 x 4
 x3  1 
dx 2  2x  1 4dx 2  2x  1
= 4   1/ 2
 1/ 2
 1/ 2
c
4
x  x 1 3
 4
x  x 1 3
  4 3
x  x 1   x  x3  1
4

6. A
dx  cos x  sin x  dx
I=   cos x  sin x  1  sin2x  =  1  sin2x  1  sin2x 
   
 2   2 
Put cos x + sin x = t ; (cos x – sin x)dx = dt
2dt 2  1 1  2 1 2
I=    2  2 dt = tan  sin x  cos x  
 ln(f(x))  C
 2  t  t  1 3  t  1 t  2 
2 2 3 3 2

7. A, B, D
 2 2 
2  sin2x  x sec 2 x  tan x  cos x   cos x  
e
x sec

x  tan x
x tan x 
2 
dx =  e
 2
x sec 2
x  tan x     

  2  
2 cos2 x
= e x sec x tan x  c
2

8. A, B, C, D
2014
2014
 cos  2015x  x  sin xdx =  cos 2015x  cos x  sin x dx   sin2015x  sin2015 x dx
 
u v
cos2015x  sin2015 x 2015
=  sin2015x  sin2015 x dx   sin2015x  sin2015 x dx
2015 2015 
cos2015x  sin2015 x
= c
2015

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
WT-SANKALP2325M1-PCM-(101206)-21

9. B, C
 1 1
 cos x  x ln x  x  dx =  cos x  x ln x  dx   cos x  x dx
v 
 u
u
v
= x ln x  sin x    ln x  1 sin x dx  cos x ln x   sin x  ln x dx
= x ln x sin x + cos x + cos x ln x + c = f(x) + c
cos x 1  ln x   x ln x sin x x ln x
Now  2
dx = c
cos x cos x
x ln x g x ln x
Now L  lim  0 and lim 2  lim
x 0 cos x x  x x  x cos x

 ln x
When x =  2n  1 , n  , is undefined
2 x cos x

10. 0

I
1 1  x  2

dx 
1 1 x2  dx

4 3 4 4 1  1 
2
x 4  2x  2  2
4  x  x  4   x  2x   
   2

=
1 1 x2 1
dx =  
1  1 
  tan1  x 
1 
4 2 1  2 3 8  e
1  8  2 
 x  2x   x  2x   x  
 2  2  2

11. 0.25
1

 x  x  dx ; x 6
5
 x2 6
 2x3 3 + 2x3 = t; (6x5 + 6x2) dx = dt
1 4 4
dt 1 3 3 1 6
 t3    t c =
6 6 4 8
x  2x3   3 c

12. 0.50
F(x) = –cos(sin(sin(sin (x))))
For integration put  = sin(sin(sin (x)))

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -16, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.

You might also like