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Weekly Test-7 Sankalp2325 m1 Paper & Answer Key (Xii)
Weekly Test-7 Sankalp2325 m1 Paper & Answer Key (Xii)
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WT-SANKALP2325M1-PCM-(101206)-2
PART I : PHYSICS
SECTION – 1 : (Only One Option Correct Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.
2. Two conducting spheres of unequal radii are given charge such that they have the same charge
density. If they are now brought in contact,
(A) No charge will be exchanged between them
(B) Charge will flow from the larger to the smaller sphere
(C) Charge will flow from the smaller to the larger sphere
(D) No heat will be produced
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WT-SANKALP2325M1-PCM-(101206)-3
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WT-SANKALP2325M1-PCM-(101206)-4
This section contains 3 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE are correct.
10 20 30 r (cm)
(A) electric energy density is zero from r = 0 to r = 10 cm region.
1 2
(B) Electric flux through a spherical surface of radius r = 12 cm is 107 .N-m /C
90
1
(C) Electric potential energy of the system is 10 4 J
18
1
(D) .Electric potential energy of the system is 10 4 J
3
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WT-SANKALP2325M1-PCM-(101206)-5
8. A parallel plate capacitor of plate area 0.2 m 2 and spacing 10-2 m is charged to 103 volt and then
disconnected from the battery, and pulled apart to double the plate spacing (take 0 = 8.8 1012
C2/N-m2).
-5
(A) work required to pull the plate is 8.8 10 J
3
(B) final voltage on the capacitor is 2 10 Volts.
(C) final charge on the capacitor becomes two times of initial
(D) final charge becomes half of initial value.
9. A disk of radius R with uniform positive charge density is placed on the xy plane with its centre
at the origin. The Coulomb potential along the z-axis is
V z
2 0
R2 z2 z .
A particle of positive charge q is placed initially at rest at a point on the z axis with z = z0 and z0 >
0. In addition to the Coulomb force, the particle experiences a vertical force F ckˆ with c 0.
2c 0
Let . Which of the following statements(s) is (are) correct?
q
1 25
(A) For andz0 R , the particle reaches the origin.
4 7
1 3
(B) For andz0 R , the particle reaches the origin.
4 7
1 R
(C) For andz0 , the particle returns back to z=z0 .
4 3
(D) For > 1 and z0 > 0, the particle always reaches the origin.
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WT-SANKALP2325M1-PCM-(101206)-6
This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).
= 3 C/m
x
2m
Wire-2
z
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WT-SANKALP2325M1-PCM-(101206)-7
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.
O
C
PCl5 LiAlH4 PCC OH
1. O A B C
D
C
O
Product (D) is:
CH2OH CH2 O
(A) (B)
COO COOH
O
CH2OH
(C) (D) O
COO
O
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WT-SANKALP2325M1-PCM-(101206)-8
2. In the following series of transformations, provide the required information wherever a question
mark (?) is indicated respectively.
CH3 CH2Cl CH3COOH
? KCN ?
h
C2H5 OH
?
Heat
CH3CN CH2CN
CH2OH CH2OH
3. OH
CH3 CH CHCHO
dil
A C8H12O 2
H
Zn/Hg
B
HCl
C C 8H12
No. of stereo isomers are possible for compound (C) are:
(A) 2 (B) 8
(C) 6 (D) 4
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WT-SANKALP2325M1-PCM-(101206)-9
4. O
NH OH
2
HCl
?
(A) (B)
O
OH
N
(C) (D) N
CF CO H
3 3
B
Pr oduct
The product (B) is:
(A) O (B) O
O
O
(C) O (D) O
O
O
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WT-SANKALP2325M1-PCM-(101206)-10
6. The Keq. value in HCN addition to the following aldehydes are in the order:
O CHO
O C H
H3CO CHO
(I) (II) (III)
(A) I > II > III (B) III > II > I
(C) III > I > II (D) II > I > III
This section contains 3 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE are correct.
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WT-SANKALP2325M1-PCM-(101206)-11
This section contains THREE questions. The answer to each question is a SINGLE INTEGER VALUE.
For each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. XXXXX.XX).
10. What is the maximum number of moles of CH3MgCl that can be consumed by one mole of
phosgene(COCl2)?
11. Acetaldehyde when treated with Cl2 and NaOH solution followed by acidification forms CHCl3 and
compound X. CHCl3 can also give compound ‘X’ when treated with NaOH solution followed by
acidification. How many moles of NaOH used totally for the above mentioned reactions.
12. All possible carbonyl compounds with molecular formula (C8H8O) which has a benzene ring gives
in its structure and gives positive Tollen’s test, when are reacted with hydroxylamine how many
organic products will be possible with difference in melting point?
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WT-SANKALP2325M1-PCM-(101206)-12
This section contains 6 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE is correct.
x2 20
1. If I = x sin x 5cos x 2
dx , then I equals
x x
(A) – tan x c (B) cot x c
cos x x sin x 5cos x sin x x sin x 5 cos x
(C) (x sinx – 5cosx)–1 sinx + 7x + c (D) none of these
ex x 1 x ln x
2. dx is equal to
x2
x ln x x ln x 1
(A) e x c (B) e x c
x x
x ln x x ln x 1
(C) e x c (D) e x c
x2 x
1 1 1 1
(A) ln sec 3x ln sec 2x ln sec x c (B) ln sec 3x ln sec 2x ln sec x c
3 2 3 2
1 1 1 1
(C) C ln sec 3x ln sec 2x ln sec x (D) C ln sec 3x ln sec 2x ln sec x
3 2 3 2
tan2 x 4 2
4. If sin 4x e dx A cos x etan x
B , then A is equal to
(A) 1 (B) 2
(C) 1/2 (D) 4
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WT-SANKALP2325M1-PCM-(101206)-13
5. Let f(x) =
4x 4
2x 3 3x 2 4 dx . If f(0) = 2, then the value of f(–1) is
3 /2
x 4
x3 1
(A) 6 (B) 10
(C) 1 (D) none of these
dx
6. If cos 3
A tan1 sin x cos x Bln(f(x)) C , then A is equal to
x sin3 x
2 2
(A) (B)
3 5
2
(C) (D) none of these
3
This section contains 3 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE may be correct.
x sec 2 x tan xsin2x f x
7. If e x tan x 2 dx e g x c then which of the following is/are incorrect?
(A) f(0) is equal to = 1
3/2 1 3
(B) number of solution(s) of the equation g x x is 3
2 2
3/2 1 3
(C) number of solution(s) of the equation g x x is 1
2 2
(D) f(x) is an even function
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WT-SANKALP2325M1-PCM-(101206)-14
2014
8. If cos 2016x sin xdx f x c ; f(0) = 0, then
2
(A) f(x) is odd (B) f x dx 0
2015f x
(C) f x dx 0 (D) lim
x 0 x 2015
1
0
cos x 2
9. If
x
x lnx 1 dx = f(x) + c; f(1) = cos 1, and f x sec
2
x dx g x c ' ; g(1) = 0
x ln x
(A) f(x) = cos x (1 + ln x) – x sin x ln x (B) g x
cos x
g x
(C) L = 0 (D) lim 0
x x 2
This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. XXXXX.XX).
10. If
1 x 2
dx
a
c tan1 x d e , then a + b + c + d is
34 2x 4x 4 xb
1 4
x x
6
11. x3 3
2 3 dx = x 6 2x 3 3 c , then 2 is equal to
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WT-SANKALP2325M1-PCM-(101206)-15
(Batches: SANKALP2325M1)
IIT – JEE, 2325 Paper Code
101206
ANSWERS
PHYSICS (PART-I)
1. B 2. B 3. A 4. C
5. C 6. B 7. A, B, C 8. A, B
9. A, C, D 10. 1.50 11. 1.00 12. 5.00
CHEMISTRY (PART-II)
1. A 2. B 3. C 4. D
5. B 6. B 7. A, B 8. A, C, D
9. A, B, C 10. 3 11. 8 12. 8
MATHEMATICS (PART-III)
1. A 2. D 3. B 4. B
5. A 6. A 7. A, B, D 8. A, B, C, D
9. B, C 10. 0 11. 0.25 12. 0.50
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WT-SANKALP2325M1-PCM-(101206)-16
1. B
dV
E
dy
VQ VQ
dV Edy E0 (1 ky 3 )dy
VP VP
a
y 4k
VQ VP E0 y
4 0
4
a k
VQ VP E0 a
4
ka4
VQ E0 a
4
2. B
Let the spheres have radii r1 and r2 (r1 > r2).
4r12 r1 4r2 2 r2
V1 ,V2
40 r1 0 40 r2 0
V1 > V2
charge will flow from the larger to the smaller sphere.
Any flow of charge cause loss of energy and hence heat is produced.
3. A
k 2Q k Q 7kQ
Ei =
2R 2 4R 2 16R2
4. C
Initially charge configuration (before K2 is closed) is 2
CE
2
C 3 CE
2
CE
2
CE
3 3 3
1
K2
K1 2
E
Final charge configuration (after K2 is closed) is
The net change of charge in the encircled region can +CE CE 1 0 0
happen only because of charge flowing in section 1 2.
Initial charge = 0
K2
Final charge = CE
Charge flown = CE from 2 to 1.
K1 2
E
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WT-SANKALP2325M1-PCM-(101206)-17
5. C
2P2 ˆ 2P1P2 ˆ
1 P1 E P1 ˆj 3
i k
4 0 d 40 d3
P1 ˆ PP
2 P2 E P2 ˆi 3
j 1 2 3 kˆ
40 d 40 d
6. B
h x
sin x2 = 2h …(i)
x 2 T F
q1q2 902
F …(ii) q1
40 x 2
h 90 x/2
F mg
x/2 mg
sin(180 2) sin(90 ) q2
F mg 2mgh
F 2mgsin =
sin2 cos x
q1q2 2mgh
40 x 2 x
q1q2
U 2mgh
40 x
From these relation we get U = 2gh
7. A, B, C
8. A, B
9. A, C, D
10. 1.50
11. 1
AP = r = (x2 + d2 )1/2 E
Electric field at A due to wire 1
E= A x
Q
x Wire 2
20 r dx
dx B
Force on each elemental length dF = E. dq d
r d
2 dx
dF = ( dx) =
20r 20 (x2 d2 )1/2 P
Net force on the elemental length Wire 1
dFnet =2dF cos
2 dX.cos 2 dx.d
=
0 (x2 d2 )1/2 0 (d2 x2 )
Hence total force required to hold the wire 2 = dFnet
2d dx 2 (3 10 6 )2
Fnet = = 0.51 Newton.
0 (d2 x 2 ) 20 2 8.86 1012
As Fnet is independent of separation between the wire. Hence required work done
W = 0.51 2 = 1 Joule.
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WT-SANKALP2325M1-PCM-(101206)-18
12. 5
q1 1 cos q2 1 cos
CHEMISTRY (PART-II)
1. A
O O
C C
PCl5 Cl
O LiAlH 4
Cl
C C
O O
CHO CH2 OH
CH2OH
PCC
OH
CHO CH2 OH
COO
2. B
3. C
O
||
A CH3 CH CH CH OH CH2 CH CH C H
O
||
B CH3 CH CH CH CH CH CH C H
C CH3 CH CH CH CH CH CH CH3
4. D
HO
O N OH
O NH2 OH HO NH
H2 N OH
H2 O
IMPT
N OH2 OH
N N
H2 O
H
HO
2
H
5. B
Bayer-Villiger oxidation.
6. B
III > II > I
In I – OCH3 is electron donating group (+M) so will decrease the electron deficiency at carbonyl
carbon to the most.
In II there is no electron donating group.
In III electron withdrawing group is present which will increase by electron deficiency at carbonyl
carbon.
7. A, B
8. A, C, D
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WT-SANKALP2325M1-PCM-(101206)-19
9. A, B, C
10. 3
O O O Me
MeMgCl MeMgCl MeMgCl
Cl C Cl Me C Cl Me C Me Me C Me
O
11. 8
O
Cl2 NaOH /
H3 C C H HCOOH CHCl3
NaOH / H
HCOOH
X
4 moles of NaOH Here also 4 moles
is consumed of NaOH is used
4+4=8
12. 8
CH3 H3C
These are possible carbonyl compounds each of which will form two oximes.
MATHEMATICS (PART-III)
1. A
Multiply and divide by x8
x5 5x 4 cos x x5 sin x
I=– sec 2 xdx
5 4
cos x x sin x 5x cos x 5 4
x sin x 5x cos x
x
=– tan x c
cos x x sin x 5cos x
2. D
ex x 1 x ln x 1 1 e
x
dx e x 2 ln dx
x2 x x x
ex ex ex e x ex ex
= ln d = ln c = (x – lnx – 1) + c
x x x x x x
3. B
2sin3x cos x 2sin3x cos3x
2cos2 x 2cos x cos5x
dx
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WT-SANKALP2325M1-PCM-(101206)-20
4. B
tan2 x
sin 4x e dx
1 tan2 x tan2 x
4 sinx cos x 2
e dx
1 tan x
2 2
Put tan x = y, 2 tan x sec x dx = dy
1 y dy
2 sin x cos x e y
1 y tan x sec 2 x
1 y y 1 y
= 2 dy = 2 e dy
4
sec x 1 y 1 y 2
1 2 2e y
= 2 e y 2
dy = B
1 y
1 y 3
1 y
2
A=2
5. A
A x 4 x3 1 Bx C 4x 3 3x 2 4x 4 2x 3 3x 2 4
A = 4, B = 2, C = 1
dx 2x 1 4x3 3x2
f(x) 4 3/2
x 4 x3 1 x 4
x3 1
dx 2 2x 1 4dx 2 2x 1
= 4 1/ 2
1/ 2
1/ 2
c
4
x x 1 3
4
x x 1 3
4 3
x x 1 x x3 1
4
6. A
dx cos x sin x dx
I= cos x sin x 1 sin2x = 1 sin2x 1 sin2x
2 2
Put cos x + sin x = t ; (cos x – sin x)dx = dt
2dt 2 1 1 2 1 2
I= 2 2 dt = tan sin x cos x
ln(f(x)) C
2 t t 1 3 t 1 t 2
2 2 3 3 2
7. A, B, D
2 2
2 sin2x x sec 2 x tan x cos x cos x
e
x sec
x tan x
x tan x
2
dx = e
2
x sec 2
x tan x
2
2 cos2 x
= e x sec x tan x c
2
8. A, B, C, D
2014
2014
cos 2015x x sin xdx = cos 2015x cos x sin x dx sin2015x sin2015 x dx
u v
cos2015x sin2015 x 2015
= sin2015x sin2015 x dx sin2015x sin2015 x dx
2015 2015
cos2015x sin2015 x
= c
2015
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WT-SANKALP2325M1-PCM-(101206)-21
9. B, C
1 1
cos x x ln x x dx = cos x x ln x dx cos x x dx
v
u
u
v
= x ln x sin x ln x 1 sin x dx cos x ln x sin x ln x dx
= x ln x sin x + cos x + cos x ln x + c = f(x) + c
cos x 1 ln x x ln x sin x x ln x
Now 2
dx = c
cos x cos x
x ln x g x ln x
Now L lim 0 and lim 2 lim
x 0 cos x x x x x cos x
ln x
When x = 2n 1 , n , is undefined
2 x cos x
10. 0
I
1 1 x 2
dx
1 1 x2 dx
4 3 4 4 1 1
2
x 4 2x 2 2
4 x x 4 x 2x
2
=
1 1 x2 1
dx =
1 1
tan1 x
1
4 2 1 2 3 8 e
1 8 2
x 2x x 2x x
2 2 2
11. 0.25
1
x x dx ; x 6
5
x2 6
2x3 3 + 2x3 = t; (6x5 + 6x2) dx = dt
1 4 4
dt 1 3 3 1 6
t3 t c =
6 6 4 8
x 2x3 3 c
12. 0.50
F(x) = –cos(sin(sin(sin (x))))
For integration put = sin(sin(sin (x)))
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