JEE

Prayas JEE 2025

Chemistry
DPP: 2
Thermodynamics

Q1 For the reaction : (A) Used to determine the heat changes

PCl5 ( g) → PCl3 ( g) + Cl2 ( g) (B) Whose value is independent of path
(A) ΔH = ΔE (C) Used to determine pressure-volume work
(B) ΔH > ΔE (D) Whose value depends on temperature only
(C) ΔH < ΔE
Q7 Which of the following expressions is true for
(D) None of these
an ideal gas?
Q2 Out of the following, state functions are (A) ( ∂V ) = 0
∂T P
(A) Entropy
(B) ( ∂P ) =0
(B) Free energy ∂T V
(C) Internal energy (C) ( ∂U ) = 0
∂V T
(D) Enthalpy (D) None of these

Q3 Which of the following is path function?

Q8 In an isothermal expansion of an ideal gas
(A) Enthalpy
(A) q = 0
(B) Heat (B) ΔV = 0
(C) Entropy
(C) ΔU = 0
(D) Gibb's free energy (D) W = 0

Q4 Which among the following is not state

Q9 In an adiabatic expansion of an ideal gas
function?
(A) ΔT = 0
(A) Internal energy (B) w = 0
(B) Free energy
(C) q = 0
(C) Enthalpy
(D) ΔU = 0
(D) Work
Q10 One mole of a gas undergoes a change of
Q5 During a cyclic process. state (2.0 atm, 3.0 L, 95 K) → (4.0 atm,
(A) ΔH = 0
5.0 L, 245 K) with a change in internal energy,
(B) ΔU = 0
ΔU = 30.0 L atm. The change in enthalpy
(C) q = 0
(ΔH) of the process in L atm is
(D) both A and B (A) 40.0

Q6 Choose the correct answer. A (B) 42.3

thermodynamic state function is a quantity (C) 44.0
(D) Not defined as p is not constant

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Answer Key
Q1 (B) Q6 (B)

Q2 (A, B, C, D) Q7 (C)

Q3 (B) Q8 (C)

Q4 (D) Q9 (C)

Q5 (D) Q10 (B)

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