FNT CHEM_ (XII)

1. When ethyl iodide is treated with dry silver oxide, it forms

(a) Ethyl alcohol (b) Diethylether
(c) Silver ethoxide (d) Ethylmehylether.
2. In Williamson’s synthesis
(a) An alkyl halide is treated with sodium alkoxide
(b) An alkyl halide is teated with sodium
(c) An alacohol is heat with conc. H 2So 4 at 130oC
(d) Any of the above
3. The product ‘A’ in the following reaction is
H 2 C — CH 2
⎯⎯ ⎯→ A
RMgI

O
(a) RCHOHR (b) RCHOH  CH 3
R
(c) R − CH 2 − CH 2 − OH (d) CHCH 2 OH
R
4. The correct order of boiling point for primary (1 o ), secondary (2 o ) and tertiary (3 o ) alcohols is
(a) 1 o  2 o  3 o (b) 3 o  2 o  1 o
(c) 2  1  3
o o o
(d) 2 o  3 o  1 o
5. What will be the products of reaction if methoxybenzene reacts with HI
(a) Methyl alcohol (methanol) + iodobenzene
(b) Methyl iodide (iodomethane) + benzene
(c) Methyle iodide + phenol
(d) Methyl iodide + iodobenzene
6. Distinction between primary, secondary and tertiary alcohol is done by:
(a) Oxidation method
(b) Lucas test
(c) Victor Meyer method
(d) All of these
7. Epoxides are
(a) Cyclic ethers
(b) Not ethers
(c) Aryl-alkyl ethers
(d) Ethers with another functional group
8. PCl 5 reacts with a compound containing
(a) −SO 3 group (b) – OH group
(c) − NO 3 group (d) – NO group
9. Phenol is more acidic than:
OH OH
OCH3
(a) (b)
NO2

(c) C2 H 2 (d) Both (a) and (c)

10. Phenols are more acidic than alcohols. Which of the following statement is correct to describe it?
(a) Phenols turns blue litmus red
(b) Alcohols liberate CO2 with carbonate or bicarbonate solution
(c) Phenoxide ion is stabilized due to resonance
(d) Alkoxide ion is stabilized due to resonance
FNT CHEM_ (XII)

11. Oxonium ion is formed when:

(a) Ethanol is treated with Na –metal
(b) Phenol reacts with NaOH
(c) Ether is treated with HI
(d) Ethanol is treated with aqueous KOH
12. Which of the following can be used to distinguished methyl alcohol & ethyl alcohol?
(a) Silver mirror test
(b) Lucas test
(c) Haloform test
(d) None of these
13. When alkyl halides are treated with dry Ag2O, then:
(a) Alcohols are formed
(b) Epoxides are formed
(c) Ethers are formed
(d) Aldehydes are formed
14. Recent commercial method method for the preparation of phenol is:
(a) Dow’s process
(b) Acidic oxidation of cumene
(c) Hydrolysis of phenyl acetate
(d) Hydrolysis of benzene sulphonic acid
15. Order of reactivity of alcohols which involes the breaking of C –O bond is:
(a) 3o>1o>2o
(b) 1o >2o >3o
(c) 3o >2o >1o
(d) All have same order of reactivity
16. Identify the final product of the following reaction?
−
 −  −

CH3 O OMgI  
 H OH
Mg + H C H H C H
H+
?

CH3
I
(a) Carboxylic acid
(b) Primary alcohol
(c) Ketone
(d) Ester
17. End product of the following reaction:
K 2Cr 2O 7
OH + [O] H 2SO 4
(a) Aldehyde
(b) Ether
(c) Ketone
(d) Carboxylic acid
18. Nitration of propane -1,2,3 –triol yields:
(a) Trinitropropanol
(b) Nitroglycerin
(c) Nitropropane
(d) Both b & c
19. Condensation of alcohol in the presence of H2SO4 at low temperature gives:
(a) Ester
(b) Ether
FNT CHEM_ (XII)

(c) Symmetrical ketones

(d) Peroxyacids
20. What is the correct sequence of enzymes?
(Step #01) 2(C 6H 10O 5) n + n H 2O n C 12H 22O 11

(Step #02) C 12H 22O 11 + H 2O 2 C 6H 12O 6

(Step #03) C 6H 12O 6 2 C 2H 5OH + 2 CO 2

(a) Step #01 (zymase) Step #02 (diastase) Step #03 (maltase)
(b) Step #01 (diastase) Step #02 (maltase) Step #03 (zymase)
(c) Step #01 (maltase) Step #02 (diastase) Step #03 (zymase)
(d) None of these
21. Which of the following reagent can be used for the conversion of alcohols into alkyl halides?
(I) PCl3 (II) PCl5 (III) SOCl2 (IV) HX
(a) Only (I) & (II)
(b) Only (II) & (III)
(c) Only (I), (III) & (IV)
(d) All can be used
22. Williamson’s synthesis of ethers is an example of
(a) Nucleophilic substitution reaction
(b) Nucleophilic addition
(b) Electrophilic addition
(d) None of above
23. Which of the following is correct?
(a) Primary alcohols on oxidation give ketones
(b) Alcohols on condensation with carboxylic acids gives ethers
(c) Ethers can react with oxidizing & reducing agents easily
(d) Ethers can only react with strong acids
24. Picric acid is obtained when
(a) Alcohol is treated with conc: HNO3
(b) Ethers is treated with conc: HNO3
(c) Phenol is treated with conc: HNO3
(d) Phenol is treated with dil: HNO3
25. Acetone on reduction will give:
(a) 1o R –OH
(b) 2o R –OH
(c) 3o R –OH
(d) Ketones cannot be reduced