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chap_03_01 sir JP chemistry © Mdcatian's Stetho - Mdcat Aspire Avenue
chap_03_01 sir JP chemistry © Mdcatian's Stetho - Mdcat Aspire Avenue
38. The positive column in discharge tube is formed when pressure 52. Discovery of the nucleus of an atom was due to the experiment
inside tube is: carried out by
(a) 1mm Hg (b) 0.1mm Hg (a) Bohr (b) Mosley
(c) 0.01mm Hg (d) 0.001mm Hg (c) Rutherford (d) Thomson
39. The line spectrum is formed by________ light: 53. As electron moves away from the nucleus, its potential energy:
(a) Polychromatic (b) Monochromatic (a) Increases (b) Decreases
(c) Trichromatic (d) NOT (c) Remains constant (d) None of these
40. An element has 13-electrons in M-shell. The element maybe 54. Which of the following electron transition in a hydrogen atom will
(a) Copper (z=29) (b) Nickel (z=28) require the largest amount of energy
(c) chromium (z=24) (d) NOT (a) From n = 1 to n = 2 (b) From n = 1 to n = 3
41. In which of the following process maximum amount of energy is
(c) From n = ∞ to n = 1 (d) From n = 1 to n = 5
evolved?
55. Nitrogen has three unpaired electrons because of
(a) F + e → F–1 (b) Cl + e → Cl–1
(a) Pauli’s exclusion principle (b) Auf –bau principal
(c) Br + e → Br –1 (d) I + e → I–1
(c) Uncertainly principal (d) Hund’s rule
42. The wave length of spectral lines emitted by jumping of electron is
56. The evidence of radioactivity shows that atom is:
inversely proportional to ___________.
(a) Complex organization of matter & energy
(a) Energy (b) Mass of electron
(b) divisible
(c) Charge of electron (d) Radius of orbit
(c) both a & b
43. Which of the followings electron transition needs more energy?
(d) none of these
(a) n = 1 to n = 2 (b) n = 2 to n = 3
57. Since violet light has shortest wave length in visible region
(c) n = 3 to n = 4 (d) n = 4 to n = 5
therefore:
44. Bohr’s concept of circular path was disproved by
(a) It suffers minimum deviation when white light passes through
(a) classical theory of physics
prism
(b) Pauli’s Exclusion Principle
(b) It suffers maximum deviation when white light passes through
(c) Heisenberg uncertainty Principle
prism
(d) NOT
(c) It has highest frequency
45. The four quantum numbers are used to describe completely the
(d) Both b & c
(a) Atom (b) Nucleus
(e) None of these
(c) Orbital (d) NOT
58. Product of momentum (mv) and circumference (2πr) of an orbit is
46. The spectrum of He is expected to be similar to
equal to:
(a) H (b) Li + (a) Gas constant
(c) Na (d) He + (b) Bohr’s radius for hydrogen atom
47. The number of electrons in an atom of an element is equal to its (c) Plank’s constant
(a) Atomic weight (b) Atomic number (d) Angular momentum
(c) Equivalent weight (d) Electron affinity 59. Gamma rays very penetrating because:
48. The nucleus of the element having atomic number 25 and atomic (a) They are short wave (b) Electromagnetic in nature
weight 55 will contain (c) Massless (d) All of these
(a) 25 protons and 30 neutrons (b) 25 neutrons and 30 protons 60. Bohr’s radius for hydrogen atom, when its electron revolves in the
(c) 55 protons (d) 55 neutrons ground state is:
49. Energy electron in 2nd shell of hydrogen atom will be: o o
(a) 0.45A (b) 2.11A
13.6 13.6
(a) − e.V (b) − e.V (c) 0.529 A
o o
(d) 5.9 A
2 4
4 13.6 61. The nature cathode rays:
(c) − e.V (d) − J (a) Does not depend upon electrodes
13.6 2 (b) Does not depend upon the gas used in the discharge tube
50. Which of the following expression is correct? (c) Does not depend upon the composition of glass tube
2π 2 mZ 2 e 4 (d) All of these
(a) E = − 62. Faraday’s experiment indicated the presence of:
n2h2
(a) Neutrons (b) Protons
2 2 4 1 1
(b) ∆E = − 2π mZ e − (c) Nucleus (d) Electrons
h 2 n2 n2 63. Line spectrum serves as the finger print for the identification of
1 2
elements because:
2 2 4 1 1
(c) ν = − 2π mZ e − (a) Each element produces line spectrum consists of same colour
h 3 n2 n2
1 2 (b) Each element produces a characteristic set of lines
(d) All of these (c) Each element has same electronic configuration
51. The mass of an atom is constituted mainly by (d) None of these
(a) Neutron and neutrino (b) Neutron and electron 64. The charge by mass ratio for electrons is:
(c) Neutron and proton (d) Proton and electron (a) 1.758 × 1011 C.Kg −1 (b) 1.758 × 108 C.Kg −1
(c) 1.758 × 1011 C.g −1 (d) None of thèse
65. Positive rays are produced due to: (c) cathode rays (d) Ƴ-rays
(a) Ionization of atoms of anode 83. Chadwick discovered neutron when beryllium wad bombarded with
(b) Ionization of gases atoms (a) β-rays (b) 𝛾𝛾-rays
(c) Emission of proton by anode (c) Helium nuclei (d) Electrons
(d) Both a & b 84. A radioactive substance after emitting ∝-practice results
66. Which of the following rays is/are electromagnetic in nature? (a) Mass number decease by 2
(a) α -rays (b) β -rays (b) mass number decrease by 4
(c) Mass number increase by 1
(c) γ -rays (d) Cathode rays
(d) Atomic number increase by 1
67. Which of the following statement(s) is/are correct? 85. Which of the following is fast moving electron
(a) Positive rays are produced, when high speed cathode rays strike (a) ∝-rays (b) 𝛾𝛾-rays
the molecules of the gas enclosed in the discharge tube. (c) β -rays (d) Anode rays
(b) Positive rays are produced, when high speed cathode rays strike 86. Which is heavier particle
the anode. (a) Hydrogen atom (b) Neutron
(c) Positive rays are produced, when the gas molecules strike the (c) Proton (d) ∝-practice
anode. 87. The angular momentum of electron is
(d) All of these (a) nh/4𝜋𝜋 (b) 2𝜋𝜋/nh
68. The mass of electron in a.m.u: (c) ze2/r2 (d) nh/2𝜋𝜋
(a) 0.000550 (b) 5.5 x 10-4 88. Spectroscopy indicates the existence of
(c) Both a & b (d) None of thèse (a) Neutron (b) Nucleus
69. Neon gas conducts electricity (c) energy levels (d)Proton
(a) High temperature (b) Low temperature 89. X-rays are
(c) High pressure (d) Low pressure (a) Negatively charged (b) Positively charged
70. The radius of 1storbit of hydrogen is (c)Neutral particles (d) short wave length rays
(a) 0.529 A˚ (b) 5.29x10-11m 90. Radioactivity is the process in which certain element emit
(c) 5.29x10-9cm (d) All of these (a) Proton (b) Neutron
71. Which of the following given discrete spectrum (c) Invisible rays (d) X-rays
(a) Sun light (b) incandescent lamp 91. The nucleus of an atom is
(c) Sodium vapors lamp (d) all of these (a) Neutral (b) Negatively charged
72. Faraday’s experiment indicates the existence of (c) Positively charged (d) Large size
(a) Proton (b) Neutron 92. The value of plank’s Constant is
(c) Electron (d) All of these (a) 6.625x10-27Js (b) 6.625x10-34 erg sec
73. X – rays are (c) both of these (d) None of these
(a) Short wave length radiations 93. All are positively charged except
(b) negatively charged helium nuclei (a) Anode rays (b) Cathode rays
(c) Positively charged helium nuclei (c) ∝-rays (d) Protons
(d) neutrons 94. When α -particles are sent through a thin metal foil, most of them
74. All are negatively charged except go straight through the foil because
(a) Cathode rays (b) Beta rays (a) Alpha particles are much lighter than electrons
(c) Electron (d) Anode rays (b) Alpha particles are positively charged
75. Charge to mass ratio Anode rays depend upon (c) Most part of the atom is empty space
(a) Gas (b) Electrode (d) Alpha particles move with low velocity
(c) Both of these (d) None of these 95. When beryllium is bombarded with α -particles, extremely
76. Which colour has longest wave length? penetrating radiations which cannot be deflected by electrical or
(a) violet (b) red magnetic field are given out. These are:
(c) green (d) blue (a) A beam of protons (b) α -rays
77. Which colour is more energetic?
(c) A beam of neutrons (d) X-rays
(a) Violet (b) red
96. In which one of the following pairs of experimental observations and
(c) Blue (d) indigo
phenomenon does the experimental observation correctly account for
78. Which of the following rays are highly penetrating
phenomenon
(a) X-rays (b) β-rays
Experimental observation Phenomenon
(c) 𝛾𝛾-rays (d) None of these
(a) X -ray spectra Charge on the nucleus
79. Rutherford’s experiment of Scattering of ∝-rays indicate
(b) α -particle scattering Quantized electron orbit
(a) Momentum of electron (b) Dimension of nucleus
(c) Emission spectra The quantization of energy
(c) Energy levels (d) Presence of neutron
(d) The photoelectric effect The nuclear atom
80. Violet colour wave length
97. Which of the following are isoelectronic with one another
(a) 7000A˚ (b) 6000A˚ + +
(c) 3000A˚ (d) 4000A˚ (a) Na and Ne (b) K and O
81. The photon of violet colour are_____ energetic than red colour (c) Ne and O
+
(d) Na and K
+
(a) More (b) Less 98. In a Bohr's model of atom when an electron jumps from n = 1 to
(c) Equal (d) None n = 3 , how much energy will be emitted or absorbed :
82. which rays remain un-deflected in electric and magnetic field −11 −10
(a) ∝-rays (b) β-rays (a) 2.15 × 10 erg (b) 0.1911 × 10 erg
126. The maximum number of electrons that can fit in all the orbitals (c) B > Al > Ga > C (d) O > N > C > B
with n = 2 and l = 1? 140. Which of the following is correct order of I.P of I –A & II –A gorups?
(a) 8 (b) 2 (a) 1st I.P of I –A group > 1st I.P of II –A group
(c) 6 (d) 4 (b) 1st I.P of I –A group < 1st I.P of II –A group
127. The maximum number of electrons with l = 3 is (c) 2nd I.P of I –A group > 2nd I.P of II –A group
(a) 14 (b) (d) Both b & c
(c) 10 (d) 6 141. Which is the correct about electron affinity?
128. Which of the following can be the quantum numbers for an orbital? (a) Energy change when an electron is added into the last shell of
(a) n = 4, l = 4, m = 3 (b) n = 2, l = 3, m = 1 an atom
(c) n = 3, l = 2, m = -1 (d) n = 3, l = 0, m = -3 (b) E.A of fluorine is higher than Chlorine
129. The subshell dz2 has : (c) E.A is directly proportional to atomic radii
(a) one nodal plane (b) two nodal planes (d) None of these
(c) no nodal plane (d) three nodal planes 142. Ist I.P of V –A group is higher than VI –A group is due to :
130. The probability of finding an electron is uniform in every direction is (a) Smaller atomic radii of V –A group elements
in which orbital? (b) Half filled atomic orbital of V –A group
(a) s (b) p (c) Both a & b
(c) d (d) p (d) None of thèse
131. Following Hund’s rule which element contains six unpaired electron 143. Which of the following has highest 2nd I.P?
(a) Fe (b) Co (a) Na (b) Mg
(c) Ni (d) Cr (c) K (d) Ca
132. For the n = 2 energy level, how many orbitals of all kinds are 144. Atomic radii of :
possible (a) Fluorine is smaller than Chlorine
(a) 2 (b) 3 (b) Fluorine is smaller than Neon
(c) 4 (d) 5 (c) Copper is smaller than zinc
133. Azimuthal quantum number for valence electron of Na atom is (d) All the statements are correct
(a) 1 (b) 2 145. Tendency of an atom lose electron :
(c) 3 (d) 0 (a) Decrease from top to bottom is all groups
When the azimuthal quantum number has a value of l = 0, the (b) Increase from top to bottom in all groups
shape of the orbital is (c) Increase from left to right in all periods
(a) Rectangular (b) Spherical (d) None of thèse
(c) Dumbbell (d) Unsymmetrical 146. What is true about neutron?
134. When 3d orbital is complete, the new electron will enter the (a) It is slightly heavier than Proton
(a) 4p-orbital (b) 4f-orbital (b) It is slightly lighter than Proton
(c) 4s-orbital (d) 4d-orbital (c) Its mass is equal to mass of Proton
135. The maximum energy is present in any electron at (d) Both a & c
(a) Nucleus 147. The derivation for frequency of electron of hydrogen atom is _____.
(b) Ground state − 2π 2 mZ 2e 4 n2h2
(c) First excited state (a) (b)
n 2h 2 4π 2 mZe 2
(d) Infinite distance from the nucleus
The total number of unpaired electrons in d- orbitals of atoms of 2π 2 mZ 2e 4 1 1 1 1
(c) 2 − 2 (d) RH Z 2 2 − 2
element of atomic number 29 is : h 3
n1 n2 n1 n2
(a) 10 (b) 1
(c) 0 (d) 5 148. Ground state electronic configuration of nitrogen is:
136. Which statement about the four quantum numbers which describe (a)
electrons in atoms is incorrect?
(a) n = principal quantum number, n = 1, 2, 3, ...... (b)
(b) l = subsidiary (or azimuthal) quantum number, l = 1, 2, 3, ... , (c)
(n+1)
(c) ml = magnetic quantum number, ml = -l, 0, +l (d)
149. Which of the following is quantized?
(d) s = spin quantum number, s = + ½ or - ½
(a) Energy of shells (b) Angular momentum of electron
137. Which of the following sets of quantum numbers is not allowed?
(c) both a & b (d) None of thèse
(a) n = 3, l = 1, ml = -1, s = + ½
150. Quantum numbers of four electrons are given below :
(b) n = 2, l = l, ml = 0, s = + ½
E1 = n= 3, l= 0, m= 0, s= - ½
(c) n = 3, l = 0, ml = 0, s = + ½
E2 = n= 4, l= 0, m= 0, s= ½
(d) n = 2, l = 2, ml = -1, s = - ½
E3 = n= 3, l= 2, m= 0, s= ½
138. Atomic radii :
E4 = n= 3, l= 1, m= 0, s= - ½
(a) Is directly proportional to number of shells
Correct order of decreasing energy of thèse electrons is :
(b) Is inversely proportional to nuclear charge
(a) E3 > E1 > E4 > E2
(c) Is directly proportional to sheilding effect
(b) E4 > E2 > E3 > E1
(d) All of thèse
(c) E3 > E2 > E4 > E1
139. Which of the following is correct order of atomic radii
(d) E2 > E4 > E3 > E1
(a) H > Be < B > Al (b) H < Be < Mg < Na