MODEL SCHOOL

Run by - MODEL EDUCATION SOCIETY, ROHTAK

ENRICHMENT TEST - 1 (2024-25)
Class- XII
Subject- Chemistry
Time: 1 hr. Date-08.05.2024 M.M-40

Name______________ Section ___________ Roll No._____

Q1 The depression in freezing point for 1M urea,1M glucose, 1M NaCl are in
the ratio of
a. ) 1:2:3. b) 3:2:2 (c) 1:1:1. d)1:1:2
Q2 Which one of the following salts would have the same value of van’thoff
factor as that of K [Fe(CN) ]
3 6

a) Al ( SO )
2 4 3 b)NaCl c)Na SO
2 4 d)Al(NO )
3 3

Q3 An azeotropicmixture of two liquids boils at a temperature lower than

either of them when:
a) It is saturated b) It does not deviate from Raoult’s law
c) It shows negative deviation from Raoult’s law
d) It shows positive deviation from Raoult’s law.
Q4 A solution has an osmotic pressure of 0.0821atm at 300K. It’s concentration
would be:
a) 0.66M b) 0.32M c) 0.066M. d) 0.033M
Q5 One mole of sugar is dissolved in two moles of water.The vapour pressure of
the solution relative to that of pure water is
a. 2/3 b) 1/3 c) 3/2. d)1/2
Q6 A 500g toothpaste sample has 0.2g fluoride concentration.What is
the concentration of flouride in terms of ppm level?
a) 250 b) 200 c) 400 d) 1000
Q7 When 20g of napthoicacid (C H O )is dissolved in 50 g of benzene
11 8 2

(K =1.72Kkg/mol), a freezing point depression of 2K is observed. Thevan’thoff

f

factor is:
a. 0.5 b) 1 c)2 d) 3
Q8 What is the mole fraction of methyl alcohol in its 5.2 molal aqueous
solution?
a. 0.050 b) 0.100 c) 0.190 d) 0.086
Q9 150 ml of a liquid Ais mixed with 50 ml of liquid B and forms a non ideal
solution with positive deviation.The volume of the resulting mixture would be
a. 100 ml b) 200ml c) just less than 200ml d) just more than 200ml
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Q10 Y g of an organic substance of molecular mass M is dissolved in 250 g of
benzene.Molal elevation constant of benzene is K . Elevation in boiling point is
b

given by:
a) M/ k Y b) 4K Y/M
b bc)K Y/4M d) K Y/M
b b

Q11 Relative lowering in vapour pressure of a solution containing 1 mole of

K SO in 54 g water will be K SO is 100% ionized
2 4 2 4

a) 1/55 b) 3/55 c) ¼ d) 1/2

Q12 The value of Henry's constant is
a) Greater fo r gases with higher solubility
b) Greater for gases with lower solubility
c) Constant for all the gases d) Not related to the solubility of gases
Q13 Three aqueous solutions of calcium chloride are labelled as A,B and Cwith
concentration 0.1 M, 0.01M, 0.001 M respectively the value of van’t hoff factor
for these solutions will be in the order
a) i <i <i
A Bb) i >i >i
C A B Cc)i = i = i A d) i <i >i
B C A B C

Q14 50 ml of an aqueous solution of urea( molar mass 60 g per mole) contains

6.02× 10 molecules.The concentration of the solution will be
21

a) 0.1M b) 0.2M c) 1.0M d) 2.0M

Q15 A20 ml of sample of CuSO (molar mass 159.5 g per mole) solution was
4

evaporated to dryness, leaving 0.967 gram of residue .What was the molarity
of original solution?
a) 0.484M b) 0.0207M c) 4.84M d) 0.303M
Q16 4 l of aqueous 0.02 molar solution of NaCl was diluted by adding 1l of
water. The molarity of resultant solution is
a) 0.004 b) 0.008 c) 0.012 d) 0.016
Q17 Which of the following is the cause of low concentration of oxygen in the
blood and tissues of people living at high altitude?
a) High atmospheric pressure b) Low atmospheric pressure
c) Low temperature d) Both low temperature and high atmospheric pressure
Q18 While relating the concentration of solution to its vapor pressure which
mode of concentration is useful ?
a) Molality b) Parts per million c) Mass percentage d) Mole fraction
Q19 If the molality of dilute solution is doubled, the value of molal depression
constant will be
a) Halved b) tripled c) Unchanged d) doubled
Q20 1 g of non volatile, non electrolyte solute is dissolved in 100 gram of two
different solvents A and B whose molal elevation constants are in the ratio of
1:5. The ratio in the elevation of their boiling points is
a) 5:1 b) 1:2 c) 10 :1 d)1:5
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Q21 An aqueous solution of salt MX at certain temperature has a van’thoff
2

factor of 2. The degree of dissociation for the solution of this salt is

a) 0.67 b) 0.80 c) 0.33 d) 0.50
Q22 Determination of molar mass of acetic acid dissolved in benzene using
freezing point depression is affected by
a) partial dissociation b) Complex formation
c) Dissociation d) Association
Q23 The solubility of any compound increases with increase in
a) pressure b) temperature
c) lattice energy of the compound d) solvation energy
Q24 Which of the following compounds is used as antifreeze in automobile
radiators?
a) Methyl alcohol b) Glycol c) Nitrophenol d) Ethyl alcohol
Q25 The boiling point of 0.2 molal solution of X in water is greater than
equimolal solution of Y in water.Which of the following statement is true
in this case?
b) Molar mass of x is larger than Y b) Molar mass of X is less than Y
c) Y undergoes dissociation in solution
d) X undergoes dissociation in solution
Consider the data given below to answer question 26 , 27
Q26 Which of the following is the strongest oxidizing agent?E Cr O Cr o
2
2-
7 /
3+

=1.33V, E Cl / Cl =1.36V ,E MnO / Mn = 1.51V ,E Cr /Cr = -0.74V

o
2
- o
4
- 2+ o 3+

a) Cl -
b) Mn c) MnO
2+
d) Cr 4
- 3+

Q27 Which among the following is the most stable oxidized species?
a) Cr 3+
b) MnO c) Cr O 4
-
d) Mn 2 7
2- 2+

Q28 On increasing dilution, conductance of the solution

a) Increases b) decreases c)Remains constant d)none
Q29 What will be EMF of a cell
Ni|Ni (0.1M)|| Au (1.0M)|Au
2+ 3+

If E for Ni /Ni is-0.25V, E for Au /Au is 1.50V

o 2+ o 3+

a) +1.25V b) -1.75V c)+1.75V d)+4.0V

Q30 The gibbs energy for the decomposition of Al O at 500 C is 2 3
o

2/3 Al O →4/3Al +O
2 3 2

∆G =960 KJ/mol
The potential difference needed for the electrolytic reduction of Al O is at least 2 3

a) 4.5V b) 3.0V c) 2.5 V d)5.0V

Q31 The standard reduction potential values of three metallic cations X,Y and Z
are 0.52 ,– 3.03 and -1.18 volt rerespectivelyThe order of reducing power
of the corresponding metals is
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 a) Y >Z >X b) X >Y >Z c) Z >Y >X d) Z>X>Y
Q32 In the electrochemical reaction
2Fe + Zn → Zn +2Fe
2+ 2+ 2+

Increasing the concentration of Fe 2+

a) Increases cell EMF b) Increases the current flow

c) Decreases the cell EMF d) Alters the pH of the solution
Q33 An electrochemical cell can behave like an electrolytic cell when
a) E = 0
cell b) E cell> E ext c) E >E d) E = E ext cell ext cell

Q34 Which of the following statement is correct?

Eo Cu /Cu = 0.337V
2+

Eo Sn /Sn = -0.136V
2+

a) Cu ions can be reduced by H

2+
b) Cu can be oxidized by H
2
+

c) Sn ions can be reduced by H

2+
d) Cu can reduce Sn
2
2+

Q35 Saturated solution of KNO is used to make salt bridge because

3

a) Velocity of K is greater than that of NO

+
3
–

b) Velocity of NO is greater than that of K

3
- +

c) Velocity of both K and NO are nearly the same

+
3
-

d) KNO is highly soluble in water

3

Question 36 to 38 are of assertion reason type

a) If both assertion and reason are correct and reason is correct explanation
of assertion
b) If both assertion and reason are correct but reason is not the correct
explanation of assertion
c) If assertion is correct but reason is wrong
d) If assertion is wrong but reason is correct
Q36 Assertion:for a cell to function E cell should have a positive value .
Reason :Ecathode should be smaller than Eanode for the cell to function.
Q37 Assertion:The voltage of isolated half cell is not possible to be measured.
Reason:Oxidation or reduction cannot take place alone.
Q38 Assertion: NaCl or CaCl2 is used to clear snow on roads in the hills.
Reason: The salts depress the freezing point of water.
Q39 Assertion: if red blood cells were removed from the body and placed in pure
water, the pressure inside the cell increases.
Reason: The concentration of the salt content in the cell increases.
Q40 Assertion: Dissolution of sulphuric acid in water gives a solution which
shows negative deviation.
Reason: The solutions which have same vapour pressure at a given temperature
are called isotonic solutions.

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