Sec: SR.

IIT_*COSC(MODEL-A&B) WAT-53 Date: 07-07-24

Time: 3 Hrs 2023_P1 Max. Marks: 198
KEY SHEET
MATHEMATICS
1 ABC 2 ABCD 3 AD 4 B 5 A
6 D 7 B 8 9 9 53 10 432
11 1 12 351 13 66 14 D 15 B
16 C 17 A

PHYSICS
18 ABCD 19 BD 20 ACD 21 C 22 C
23 A 24 B 25 200 26 0 27 25
28 135 29 74 30 3333 31 C 32 D
33 D 34 B

CHEMISTRY
35 BCD 36 ABC 37 AB 38 C 39 A
40 B 41 C 42 6 43 1 44 3
45 8 46 7 47 4 48 A 49 A
50 A 51 A
Narayana IIT Academy 07-07-24_SR.IIT_*CO SC(MODEL-A&B)_JEE-ADV_WAT-53_KEY&SOL
SOLUTIONS
MATHEMATICS
1.
2. | Dn | no. of derangement of ' n ' distinct objects
= All ' n ' letters go to wrong addressed envelopes
a1 E1
a2 E2
. .
. .
ak Ek
. .
. .
an En
| Dn | (n  1)[| Dn1 |  | Dn2 |]
A1  Exactly i  letters to into Right addressed envelopes
| Dn | All the letters will go into Wrong addressed envelopes
| Dn | n! [ n( A1 )   n( A1  A2 )   n( A1  A2  A3 )....]
 1 1 1 ( 1) n 
| Dn | n!1     .....  
 1! 2! 3! n! 
3. A1  2l  1, A2  2m  2, A3  2h  3, A4  2 p
 2l  1  2m  2  2n  3  2 p  50
 2l  2m  2n  2 p  46  l  m  n  p  23, l , m, n, p  1
l ' m ' n ' p '  19, l ', m ', n ', p '  0
22
 Total number of ways distribution = C3
When A4 receiving not more than 14 marbles
l  m  n  p  23
1111
1118
l ' m ' n ' p '  12, l ', m ', n ', p '  0
15
Number of ways of distribution when A4 receiving 16 or more marbles = C3
22
 Number of ways when A4 receiving not more than 14 marbles = C3 15 C3  1085
5!
4. A) S (5,3)   10
3!(1!) 2 .2!
5! 120
 2
  15
1!(2!) .2! 8
= 25
S (n, k )  kS (n  1, k )  S (n  1, k  1)
C) S (6,3)  3S (5,3)  S (5,2)

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D) No. of onto functions from ‘6’ elt set to ‘3’ elt set = 3!S(6,3)
Set up this recurrence relation by considering two cases on the nth ball or use division
and distribution.
6! 6! 1
5.  3!  180
2!2!2! 4!1!1! 2!
6. Conceptual
7. Sol: Let total money that is to be distributed is 4 (  N ) and relative xi receives pi
n
rupees  Pi  4 , and 0  pi  4n  1
c 1
4 2 4 n1
 coefficient x in (1  x  x ....  x ) is to be formed
4 n2 1
2
Let (1  x  x ....  x
4 n 1 n
)   ar x r
r 0
Required coefficients is a4  a8  a12  ....
Put x  1, 1, i and i and add, we get
a0  a4  a8  ....  4n1.n n1
8. x1  x2  x3  x, x4  x5  y, z  x6
x  3 y  21  5 x6 x6  1, 2
x  3 y  16,11
( x, y , x6 )  (4,4,1),(7,3,1),(10, 2,1),(5, 2, 2)
43 2 421 7 31
Number of 6-tuples = C2 C1  C1 1032 C2 221
C1  532 C2 221
C1
= 9+30+36+6 = 81
Exactly one box empty
9. Sol: Four balls numbered 1,2,3,4 
 five boxes numbered 1,2,3,4,5
( dearrangement )

 1  1
r r
4 5
R.N .W  4!  5! (or) = 9+44=53
r 0 r! r 0 r!
10. f (1)  1; f (9)  f (3)  f (3)
i.e., f (3)  1 or 3
Total function = 1  6  2  6  6  1  432
11. 9  216  420  126  771 ways
12. Case – 1: All elements of set A satisfy f ( x )  x
In this case number of functions = 1
Case – 2: 4 elements of set A satisfy f ( x )  x
7
Total number of functions = C4 .2  70
e.g., : f (4)  4, f (5)  5, f (6)  6, f (7)  7
Now for elements {1,2,3} we have two options of mapping
Case – 3: 1 elements of set A satisfy f ( x )  x
For remaining six elements make groups of (3,3)
6!
Hence, total functions = 7C1   2  2  280
3!.3!.2!
Hence, total functions are 351
13. 
Use an  3.2
n1
 an1 
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14. x1  x2  x3  30
,
 xi  0
Number of solutions  496 When boxes and balls are identical.

75 61
450 366
13
15 6
6 45 39
3 3

1 1
496 406
11 6 3 2 1 1
15. xy  15!  2 3 5 7 1113
(A) No. of the integral solutions = no. of ways of fixing x
= the no. of factors of 15!
= (1+11)(1+6)(1+3)(1+2)(1+1)(1+1)=4032
 Total no. of integral solutions = 2 x 4032 = 8064
(B) HCF ( ,  ) = 1. So identical primes should not be separated
6
So, no. of solutions = 2  64
5 3 1 1
(C) The largest number whose perfect square can be made with 15! Is 2 3 5 7
So the no. of ways of selecting x will be
(1+5)(1+3)(1+1)(1+1)=96
(D) Let   351 and   35 where HCF (1 , 1 )  1

Now,   15!  11  21136511113

1 1

5
So, no. of solutions = 2  32
16.
17. A) f 1  f  2   3  f  3
 f 1  f  2   3  f  3  3
The only possibility is 0+1+2=3
 Elements 1,2,3 in the domain can be mapped
With 0,1,2 only.
So number of bijective function  3  5  720
B) As function is one-one and onto, out of 50 elements
Of domain set 17 elements are following restriction
f  3  f  9   f 15  ........  f  99 
So number of ways = 50
C17 .1.33 50 P33
C) Using P.I.E. 5! 3. 5C3 .2!  2. 5C4  1  1
D) 4  2 ' s,5  1' s or 1  4,1  3,1  2, 4  1s or 1  4,3  2 ' s,3  1' s
7! 7! 7!
   371
2!5! 4! 3!3!

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PHYSICS
18. .(A) Central fringe is 2
a

(B) At 3 , intensity is zero

a
2
 a 
 sin   sin   
(C) I    
   a  
   sin   
   

(D) Intensity is not maximum at EXACT sin 1 3  2a  , but close to it. Maximums occur at
a  a 
tan  sin     sin  
     
19. For plane polarized light the ratio of two components must be a constant.
2 2
20. 1,4   6l      6 l     2n for constructive  12  l   2n  1 
 
2 2
2,3   2 l    2 l   2n for constructive  2 l  n
 
2 2
1,3   4l      4 l      2n  1  for destructive  4 l  n
 
2 2
2,4   4 l    4 l    2n  1  for destructive  8 l   2n  1 
 

1.22 d
21. Radius r 
D

22. E   v  B and v  f 

23. Converting all geometric path lengths to optical w.r.t vacuum we get
2 2
   2 SS 2  S 2C    SS1  1  S1C  t    t   =    1 b  1  1  D   1    t 
   2
24. The light is travelling along negative x-axis;therefore, line of sight is positive x-axis.
E 6 3
Before, tan b  y    b  37o
Ez 8 4

Ey 3 1
After, tan  a      a  30o
Ez 3 3 3
25. 5th minima of interference should match with 1st minima of diffraction.
 1  9 1
sin    4       b  0.2mm
 2d b 2d b
26. Both fields are always in-phase.

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1
27. I n ,max 
 2n  1
2

28. Malus’ law: I  540 cos 2  55o  10o   cos 2  80o  55o   135 W/m2

29. Incident angle must be Brewster’s angle as reflected is plane polarized.

4
tan  i    i  53o    180  2  53  74o
3

2 2
30.    2h      2h      2n  1  for destructive interference
 

2h  2 h 2h 
   n , 
n  max min 

31. NCERT Textbook - I, Table 8.1, page 211, November 2022 edition

2
32.    a sin  


 sin  Resultant Amplitude Resultant Intensity Ratio

0 0 4A 16I 1

2 
3 A 3I 3/16
6 6a

2 
A I 1/16
5 5a

2 
0 0 0
4 4a

33. Center of curvature of the incoming wavefront is the object for the mirror or lens leading to an image
that acts as the center of curvature of the reflected or refracted wavefront.

34. Unpolarised light will turn to plane polarised with an intensity of I/2 after passing through the first

polaroid. After this there are (n+1) polaroids at a pass-axis angle of  with each other, each
 n  1
 
will rotate the plane of polarisation by this angle and the intensity drops to a cos 2    factor.
  n  1 

 n 1
I  
Therefore, I final   cos 2   
2   n  1  

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CHEMISTRY
3
35. Cu  CN 4   Sp 3

36. Conceptual
2
37. Cl is weak ligand so no pairing of elements so  NiCl 4  is tetrahedral.

pph 3 group is bulkier one so it favours tetrahedral geometry, through pph 3 is strong field ligand

38. Two geometrical and two linkage isomers

39. In CrO42 , colour is due to L  M charge transfer

40. The original complex must have the chlorides ions in the trans position, since then all other four
positions which could be replaced are equivalent

41. NO is 3e donor

42. Complexes No. of geometrical isomers

(i)  Pt  NH 3 2  SCN 2  2

(ii) Co  NO2 3  NH 3 3  2

(iii)  Pt  en  Cl2  0

(iv) Cr  en 2 Br2  2

3
(v)  Rh  en 3  0

CoCl2 Br2 
2
(vi) 0

Hence, sum of total number of geometrical isomers = 6

43.

3
44.  (i) Cr  ox 3  : optically active.

(ii) cis   Pt  Cl2  en   : optically inactive

(iii) cis   Rh  Cl2  NH 3  4  : optically inactive

3
(iv)  Ru  dipy 3  : optically active

(v) cis  Co  NO2 3  dien   : optically active

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(vi) Trans  Co  NO2 3  dien   : optically inactive

(vii) cis  Co  NO2 3  NH 3 3  : optically inactive

 Total number of optically active complexes = 2

45. (i)  Fe IF  CN  H 2O  en  

X = 12 (active isomer)
2
(ii)  MoCl2 F2  gly  

y = 4 (active isomer)
x-y =12-4
8
46. Conceptual
47. x=1,y=3,z=0
48. Conceptual

49. NiCl42  sp 3 and two unpaired e  – Tetrahedral

Ni  CN  4 dsp 2 and no unpaired e  – Square planar

2

Ni  CO 4 sp 3 and no unpaired e  – Tetrahedral

2
 Pd  Cl  4  dsp 2 and no unpaired e  . – Square planar.

50. Conceptual
51. Conceptual

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