® SAFETY DATA SHEET

SIN RUBTECH (according to GHS requirements) Doc. Ref.: SRT SDS(ZDEC)

Issue No.: 1
Issue Date: 28 thOctober 2022

SECTION 1: Identification of Substance and Company

Product Name : SIN RUBTECH® P O L Y M E R B O U N D P R E D I S P E R S E D C H E M I C A L S
Trade Name : ZDEC – 80G, ZDEC-75G/NBR
Recommended Use : Rubber Vulcanization Accelerator for Rubber Compounding
Manufacturer : Sin Rubtech Consultancy Sdn. Bhd.
Address : 10-12 Jalan Industri Cherok To’Kun 2, Taman Industri Cherok To’Kun, 14000 Bukit
Mertajam, Seberang Prai Utara, Penang, Malaysia.
Telephone/ Emergency : 604 – 5511804
Contact
Fax : 604 – 5514804
Website / E-Mail : www.sinrubtech.com / marketing@sinrubtech.com

SECTION 2: Hazards Identification

Classification : Acute toxicity 4, Aquatic Chronic 1, Aquatic Acute 1, Skin Irritation 2, Skin Sensitivity 1
GHS Label Elements :

Zinc diethyldithiocarbamate

Signal Word : WARNING

Hazard Statements(s)

H302 - Harmful if swallowed

H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H319 - Causes serious eye irritation
H400 - Very toxic to aquatic life
H410 - Very toxic to aquatic life with long lasting effects
Precautionary Statement(s)
Prevention
P280 - Wear protective gloves/protective clothing/eye protection/face protection.

P270 - Do not eat, drink or smoke when using this product.

P273 - Avoid release to the environment.

Precautionary Statement(s) :
Response
P301+302 - IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P333+313 - If skin irritation occurs : Get medical advice / attention.
Precautionary Statement(s) : Not Applicable
Storage
SRT SDS(ZDEC) Page 1 of 6
SIN RUBTECH CONSULTANCY SDN BHD (Company No : 103451-P)
Contact Address : 10-12, Jalan Industri Cherok To’Kun 2, Taman Industri Cherok To’Kun, 14000 Bukit Mertajam, Malaysia.
Telephone : (604) 5511804 | Fax : (604) 5514804 | E-Mail : marketing@sinrubtech.com
 Precautionary Statement(s) :
Disposal
P501 - Dispose of contents/container in accordance with local/regional/national/international
regulation.

SECTION 3: Composition / Information on Ingredients

A proprietary MIXTURE of predispersed Zinc diethyldithiocarbamate in elastomeric / processing aids binder.
INGREDIENTS Zinc diethyldithiocarbamate) Elastomeric/ Nitrile Rubber Styrene Butadiene
Processing (NBR)/ Rubber (SBR)/
Aids Binder Processing Aids Processing Aids
Binder Binder
CAS No 14324-55-1 Trade Secret 9005-98-5 9003-55-8
(NBR) (SBR)

Classification of individual Acute Toxicity 4, Aquatic Chronic 1, N/A N/A N/A

ingredients Aquatic Acute 1, Skin Irritation 2,
Skin Sensitivity 1, Eye Irritation 2,
STOT SE 3: H302, H315, H317,
H319, H410, H400, H335
PRODUCT NAME (PRODUCT CODE)
ZDEC-80G (PBPC012) 80% 20%
ZDEC-75G/NBR 75% 25%
(PBPC013NBR)

SECTION 4: First-aid Measures

Inhalation : Not applicable at ambient temperatures.

Skin Contact : Wash with plenty of water and soap.

Eye Contact : Wash with plenty of water and obtain medical attention if any sensation persists.
Ingestion : Symptomatic treatment. Rinse out mouth and then drink plenty of water. Consult a physician.

Most important symptoms and effects, both acute and delayed

May cause sensitization by skin contact.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Indication of any immediate medical attention and special treatment needed.
TREAT SYMPTOMATICALLY

SECTION 5: Fire-fighting Measures

Extinguishing Media : Water spray, foam, carbon dioxide, dry chemicals.
Special Protective : Protective clothing and self-contained breathing equipment should be available for firemen.
Equipment

Special hazards arising : Emits toxic fumes under fire conditions. (Carbon monoxide, Carbon dioxide, Hydrogen Cyanide,
for substrate or mixture ZnO fumes, Sulphur oxides, Nitrogen Oxides)

Advice for Firefighters : Wear breathing apparatus plus protective gloves.

Emits toxic fumes under fire conditions. (Carbon monoxide, Carbon dioxide, nitrogen oxides,
sulphur dioxide)

SRT SDS(ZDEC) Page 2 of 6

SIN RUBTECH CONSULTANCY SDN BHD (Company No : 103451-P)
Contact Address : 10-12, Jalan Industri Cherok To’Kun 2, Taman Industri Cherok To’Kun, 14000 Bukit Mertajam, Malaysia.
Telephone : (604) 5511804 | Fax : (604) 5514804 | E-Mail : marketing@sinrubtech.com

Methods for Cleaning /
Collecting
Handling
General Precautions
Engineering Controls
Occupational Exposure
Limits.
Personal Protection
Eye and face protection
Skin Protection
Body Protection
Respiratory Protection
Contact Address : 10-12, Jalan Industri Cherok To’Kun 2, Taman Industri Cherok To’Kun, 14000 Bukit Mertajam, Malaysia.
Telephone : (604) 5511804 | Fax : (604) 5514804 | E-Mail : marketing@sinrubtech.com
SECTION 6: Accidental Release Measures
: Sweep up and transfer product to a suitably labelled container and dispose at an approved site.
Take precautions to prevent entry into waterways, sewers, or surface drainage systems. Dispose
according to local or international regulations.
SECTION 7: Handling and Storage
: No special precautions necessary but normal industrial good housekeeping practices should be
followed as for any rubber additive.
SECTION 8: Exposure Controls / Personal Protection
: Good industrial hygiene should be followed.
: Adequate ventilation should be maintained when handling heated product.
: Derived No Effect Level (DNEL): No further relevant information available.
:
: Not applicable under ambient temperatures.
: The material may produce skin sensitisation in predisposed individuals.
Wear physical protective gloves
: Not applicable under ambient temperatures.
: Not applicable under ambient temperatures.
SRT SDS(ZDEC) Page 3 of 6
SIN RUBTECH CONSULTANCY SDN BHD (Company No : 103451-P)
 SECTION 9 : Physical and Chemical Properties

Form/Colour/Odour : Granules / White – Off-white / Relative Density (Water=1) : 1.22 approx

Odour Threshold
PH
Melting Point/ Freezing
Point (oC)
Initial Boiling Point and
boiling range (oC)
Flash Point (oC)
Evaporation Rate
Flammability
Upper Explosive Limit (%)
Lower Explosive Limit (%)
Vapour Pressure (kPa)
Solubility in water (g/L)
Vapour Density (Air=1)
pH as a solution (1%)
Faint
: Not Available Partition Coefficient n-
octanol/ water
: >5.9-<6.4 for Active Ingredient Auto-ignition temperature
(oC)
: 172-183oC for Active Ingredient Decomposition
Temperature
: 301oC for Active Ingredient Viscosity (cSt)
: Not Applicable Molecular Weight (g/mol)
: Not Applicable Taste
: Not Applicable Explosive Properties
: Not Applicable Oxidising Properties
: Not Applicable Surface Tension (dyn/cm or
mN/m)
: Not Applicable Volatile Component (%vol)
: Insoluble Gas Group
: Not Applicable VOC g/L
Not Applicable
: Not Available
: Not Self-igniting.
: Not Available
: Not Applicable
: Not Available
: Not Available
: Not Explosive
: Not Available
: Not Applicable
: Nil
: Not Available
: Not Available
:

SECTION 10: Stability and Reactivity

Stability
Conditions to Avoid
Materials to Avoid
Hazardous Decomposition
Products
Hazardous Polymerisation
: Stable under normal conditions.
: Heat, sparks, flames, elevated temperatures
: Avoid reaction with strong acids, alkali, amines and oxidizing agents.
: None under normal conditions
: Will not occur.

SRT SDS(ZDEC) Page 4 of 6

SIN RUBTECH CONSULTANCY SDN BHD (Company No : 103451-P)
Contact Address : 10-12, Jalan Industri Cherok To’Kun 2, Taman Industri Cherok To’Kun, 14000 Bukit Mertajam, Malaysia.
Telephone : (604) 5511804 | Fax : (604) 5514804 | E-Mail : marketing@sinrubtech.com
 SECTION 11: Toxicological Information - For ZDEC Powder (14324-55-1)
Harmful if swallowed.
Oral LD50 > 1960mg/kg (rat)
ZDEC can however cause irritation and soreness to skin and eyes with long term exposure.
Toxicokinetics, metabolism and distribution Toxicokinetic data are available on the structural analogue of ZDEC, ZDMC. Based
on the higher molecular weight of ZDEC, it is expected that its absorption from the gut shall not be faster than that of ZDMC. For
ZDMC, at least 60% oral absorption was determined based on the available toxicokinetic study. The distribution of ZDEC,
similarly to ZDMC, is expected to occur primarily to organs of metabolism and excretion (liver, lung, kidney) and vascularised
tissues (spleen, thyroid, adrenals), as well as body fat. The metabolism is expected to occur via a hydrolysis of a parent compound
into the respective acid, which either undergoes a transformation to CS2, further oxidized into CO2, or a conjugation with
glucuronic acid or GSH. For the dermal absorption, a value of 0.1% as observed in the study with ZDMC is considered to be a
worst-case approach (due to the very low solubility of ZDEC and the possible amount of water that can penetrate the skin,
0.00012% would be observed maximally).
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
- Genetic toxicity:
in vitro (mamalian cell gene mutation assay, mouse lymphoma cells) - negative
in vitro (chromosome abberation, human lymphocytes) - positive
in vivo (rats, unscheduled DNA synthesis) - ambiguous results
in vivo (mouse, chromosome abberation) - negative
- Carcinogenicity : NOAEL: 717 mg/kg bw/day
- Reproductive toxicity: effects on fertility : NOAEL (maternal): 10 mg/kg bw/day NOAEL (neonatal): 10 mg/kg bw/ day (Read
Across from ZDMC (CAS 137-30-4)
toxicity on development : NOAEL (maternal): 125 mg/kg bw/day 250 mg/kg bw/day
May cause sensitisation by skin contact

SECTION 12: Ecological Information

For ZDEC Powder (14324-55-1)
Aquatic Toxicity : EC50: 1.428 mg/kg (activated sludge) (toxicity to microorganisms, 3-h) r.a. ZDBC

LC50: 0.23 mg/L (Oncorhynchus mykiss) (toxicity to fish, 96-h)

NOEC: 3.2 µg/L (Daphnia magna) (toxicity to aquatic invertebrates, 21-d) 3.2 µg/L
(Danio rerio) (toxicity to fish, 11-d)

EC50: 0.24 mg/L (Daphnia magna) (toxicity to aquatic invertebrates, 48-h)

ErC50: 1.1 mg a. i. /L (Chlorella pyrenoidosa) (toxicity to aquatic algae and

cyanobacteria, 96- h)
Persistence and Degradability : 2 % biodegradation (activated sludge) (28-d, ready biodegradability, not readily
biodegr.) r.a ZDBC

7.7 % biodegradation (activated sludge) (28-d, ready biodegradability, not readily

biodegr.) r.a. ZDMC
Bioaccumulative potential : No further relevant information available.
Mobility in Soil : 4.17 = log Koc, 25 °C (none, from calculation) (QSAR:KOCWINTM 2008. Version
2.00. U.S. EPA)
General Notes : Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for
water Do not allow product to reach ground water, water course or sewage system,
even in small quantities. Danger to drinking water if even extremely small quantities
leak into the ground.

SRT SDS(ZDEC) Page 5 of 6

SIN RUBTECH CONSULTANCY SDN BHD (Company No : 103451-P)
Contact Address : 10-12, Jalan Industri Cherok To’Kun 2, Taman Industri Cherok To’Kun, 14000 Bukit Mertajam, Malaysia.
Telephone : (604) 5511804 | Fax : (604) 5514804 | E-Mail : marketing@sinrubtech.com

Waste Disposal Method
Contaminated Container
Disposal
SECTION 13: Disposal Consideration
: Dispose according to local regulations. Must not be disposed together with household garbage.
Do not allow product to reach sewage system.
: Observe local regulations for chemical waste.

SECTION 14: Transport Information

Regulation 14.1 UN 14.2 UN Proper Shipping Name 14.3 Label 14.4 14.5 14.6 Special Precautions for user
Number Class* PG* Env*

ADR 3077 ENVIRONMENTALLY HAZARDOUS 9(M7) 9 III Yes

SUBSTANCE, SOLID, N.O.S.
(contains Zinc diethyldithiocarbamate)

ADN 3077 ENVIRONMENTALLY HAZARDOUS 9 9 III Yes

SUBSTANCE, SOLID, N.O.S.
(contains Zinc diethyldithiocarbamate)

RID 3077 ENVIRONMENTALLY HAZARDOUS 9 9 III Yes

SUBSTANCE, SOLID, N.O.S.
(contains Zinc diethyldithiocarbamate)

IATA 3077 ENVIRONMENTALLY HAZARDOUS 9 9MI III Yes

Cargo SUBSTANCE, SOLID, N.O.S.
(contains Zinc diethyldithiocarbamate)

IATA 3077 ENVIRONMENTALLY HAZARDOUS 9 9MI III Yes

Passenger SUBSTANCE, SOLID, N.O.S.
(contains Zinc diethyldithiocarbamate)

IMDG 3077 ENVIRONMENTALLY HAZARDOUS 9 9 III Marine

SUBSTANCE, SOLID, N.O.S. Pollutant
(contains Zinc diethyldithiocarbamate)
• Description – 14.3 Transport Hazard Class(es), 14.4 Packing Group, 14.5 Environmental Hazards

SECTION 15: Regulatory Information

Safety, health and environmental regulations/legislation specific for the substance or mixture :
Not Available

Chemical safety assessment:

A Chemical Safety Assessment has not been carried out.

SECTION 16: Other Information (training needs, possible restrictions, data sources, etc)
Data Sources : Sin Rubtech Consultancy Sdn. Bhd.
Department issuing MSDS : Technical Department.
Contact : Sin Yoong Leong, Technical Manager

Disclaimer
The data contained herein is based on information that Sin Rubtech® believes to be reliable, but no expressed or
implied warranty is made with regard to the accuracy of such data or its suitability for a given situation. Such data
relates only to the specific product described and not to such product in combination with any other product and no
agent of Sin Rubtech® is authorized to vary any of such data. Sin Rubtech® and its agents disclaim all liability for
any actions taken or foregone on reliance on such data.

SRT SDS(ZDEC) Page 6 of 6

SIN RUBTECH CONSULTANCY SDN BHD (Company No : 103451-P)
Contact Address : 10-12, Jalan Industri Cherok To’Kun 2, Taman Industri Cherok To’Kun, 14000 Bukit Mertajam, Malaysia.
Telephone : (604) 5511804 | Fax : (604) 5514804 | E-Mail : marketing@sinrubtech.com