河 北 大 学 课 程 考 核 试 卷

考核科目 有机化学 2023—2024 学年春学期 2023 级 医学 专业（类）

课程类别 必修课 考核类型 考试 考核方式 闭卷 考试时间 120 分钟 卷别 A

I. Name the following compounds. (10 points)

1. 2. 3. 4. 5.

II. Write the structural formula for each of the following compounds. (10 points)
6. methylcyclohexane 7. 5-bromo-2,3,3-trimethylheptane
8. (E)-5,5,6-trimethyl-2-heptene 9. cyclopentanol 10. diethyl ether
III. Choose the best answer for each of the following questions. (30 points)
11. Which one of the following is that all carbon atoms in the molecule are sp2
hybridized? ( C )
A. B.
C. D. CH3CHClCH3
12. Which one of the following substituents activates an aromatic nucleus? ( C )
A. -COOH B. -NO2 C. -OCH3 D. -SO3H
13. Which of the following lettered C-C bond is the longest? ( D )

A. B. C. D.

14. Which one of the following carbocation is most stable? ( A )

15. Which one of the following compound is easiest water-soluble? (A )

16. Which one of the following exists  conjugate system? ( A )

A. 1,3-butadiene B. C. D.
17. Which one of the following exists p conjugate system? ( C )
A. benzaldehyde B. 1,3-cyclohexadiene C. D.
 18. Which of the following shows the strongest acidity? ( B )

A. B. C. D.

19. Which of the following shows the highest activity toward SN1 reaction?( D )
A. methylbromide B. ethylbromide
C. 3-bromo-2-methylbutane D. 2-bromo-2-methylbutane
20. The isomers of propanol differ in: ( C )
A. the number of carbon atoms B. molecular mass
C. the arrangement of the carbon atoms D. the type of functional group
21. Which of the following shows the highest activity toward nucleophilic acyl
substitution?( A )
A. CH3COCl B. CH3COOCOCH3 C. CH3CO2CH3 D. CH3CONH3
22. Which one is the most stable? ( )

23. Which of the following are pairs of enantiomers? ( )

24. A specific arrangement of several atoms which gives characteristic properties to an

organic molecule is known as a(an): ( B )
A. carboxyl group B. functional group C. group D. alkyl group
25. Which of the following can be used as Lewis base? ( A )
A. BF3 B. H2SO4 C. Br+ D. CN-
IV. Complete the following reactions. (20 points)
V. Preparation of the following compounds by using designated materials with
appropriate reagents. (20 points)

26. Synthesize from .

27. Synthesize from .

28. Synthesize from .

29. Synthesize from .

 30. Synthesize from .

VI. Explain the following concepts. (10 points)

31. Lewis Acids
32. LUMO
33. SN1
34. Nucleophilic addition
35. sp2-hybridized orbital