1.

The correct order of stability of the carbocations

. [DEC-2020]
2. The HOMO of π – molecular orbitals of methyl azide is .
. [DEC-2020]
3. The correct order of the pKa of the following compound is
[DEC-2020]
4. The following carboxylic acids undergo decarboxylation upon heating. The ease of
decarboxylation in the order . . [DEC-2020]
5 .Among the following, the correct statement about π molecular orbitals (π –
MO’s) of benzene is [NET-JUNE-2019]

(1) Only lowest energy MO is doubly degenerate.

(2) Only LUMO is doubly degenerate.
(3) Only HOMO is doubly degenerate.
(4) Both the HOMO and LOMO are doubly degenerate.
6. The major product formed in the following reaction is
[DEC -2018]
7. The correct statement about following species is
[JUNE – 2018]

1. Both A and B are aromatic.

2. A is aromatic and b is anti-aromatic.
3. A is non aromatic and B is anti-aromatic.
4. A is aromatic and B is homo aromatic.
8. The correct order of rate of Solvolysis in 80% ethanol at 25 degree C is [JUNE – 2018]
9. The correct order of basicity for the following Heterocycles is
[DEC – 2017]
10. The correct order of stability of the following carbocation is
[DEC – 2017]
11. The correct order of pKa values for the following species is
[JUNE – 2017]
12. The correct order of the bond dissociation energies for the indicated
C-H bond in following compound is [DEC – 2016]
13. The correct order of the acidity for the following compound is [DEC – 2016]
14. Correct match for the products of the reactions in the column A with the properties
in column B is [DEC – 2016]
15. The correct order of PKa values for the compounds X, Y and Z
is [JUNE – 2016]
16. The compound that gives precipitate on warming with aqueous
AzNo3 is [JUNE – 2015]
17. The correct order of heat of hydrogenation for the following compound is [JUNE – 2015]
18. The compound that is anti-aromatic is [DEC – 2014]

(a) I (b) II (c) III (d) IV

19. The increasing order of pKa values of the circled hydrogen’s
In the following compound is [DEC – 2014]
20. The decreasing order of basicity of the following compound
is [DEC – 2014]
21. The correct order for the basicity for the following
anions is [JUNE -2014]
22. Consider the statements about the following structures X and
Y. [JUNE-2014]

(A) X and Y are resonance structures

(B) X and Y are tautomer.
(C) Y is more basic then X.
(D) X is more basic then Y.
The correct statements among the above is/are.

(a) A and B (b) C (c) B and D (d) B and C

23. Amongst the following, the compound which has the lowest energy barrier
for the cis-trans isomerization is [DEC-2013]
24. The IUPAC name of the compound given below is. [DEC-2013]

(a) (2E, 4E)-3- chlorohexa-2, 4-diene-1, 6-diol

(b) (2Z, 4E)-3- chlorohexa-2, 4-diene-1, 6-diol
(c) (2Z, 4Z)-4- chlorohexa-2, 4-diene-1, 6-diol
(d) (2E, 4Z)-4- chlorohexa-2, 4-diene-1, 6-diol
25. Among the following compounds, the one which has highest dipole
moment is [JUNE-2013]
26. The correct order of acidity of the compound A-C is [DEC-2012]
27. Among A-C, the aromatic compounds are [DEC-2011]

(a)A, B and C (b) A and B only (c) B and C only (d) A and C only
28. Among the carbocation given below [JUNE - 2011]

(a) A is homoaromatic, B is anti-aromatic and C is aromatic.

(b) A is aromatic, B is anti-aromatic and C is homoaromatic.
(c) A is anti-aromatic, B is aromatic and C is homoaromatic.
(d) A is homoaromatic, B is aromatic and C is anti-aromatic.
29. The correct order of acidity of the following compound A-C is [JUNE-2011]
30. The correct order of basicity of the following onions is
. [DEC – 2019]
31. The correct statements are about the reaction of X and Y with NaNH2
are [JUNE – 2016]

A.X reacts faster than Y C. X and Y behave as Lewis acids

B. Y reacts faster than X D. X is stronger bronsted acid than Y
1. A and C 2. A and D 3. B and C 4. B and D
 GOC-CSIR-NET
Answer-key

1 .d 2. b 3. b 4. a 5. 4 6. 2 7. 2 8. 4

9. 3 10. 4 11. 2 12. 4 13. 3 14. 1 15. c 16. c

17. b 18. a 19. c GOC20.- CSIR

c -21.
NETa 22. d 23. c 24. b
Answer key
25. b 26. c 27. c 28. a 29. c 30. 4 31. 2