EXAM FORMULA SHEET

Thermodynamics and transport phenomena

Auxiliary functions G and A
∂G
dU = TdS - PdV dH = TdS + VdP T =−H
∂T T2
dA = - SdT - PdV dG = - SdT + VdP
Partial molar properties
 ∂Z  c
Zi =   −SdT + VdP = ∑ n i dµ i
 ∂ n i  P,T,n j≠i i

Phase equilibrium

dP ∆H d(ln P) ∆H
L = C +2−F = =
dT T∆V dT RT 2
Mixtures and solutions

µ idis,id = µ *i (l) + RT ln x i pi (g) = p*i x i (dis) lim p 2 = lim p 2 = k 2 x 2

x1 →1 x 2 →0

 v 1
p
v a
µ i (T, p) = µ 0
i (T, p ) + RT ln ai
0
d ln a = dp ln = ∫  −  dp
RT p 0  RT p
c
yi p
∆G = RT∑ (x i ln γ i +x i ln x i ) γi =
i =1 pi* xi ( dis )

P =P2* + ( P1* − P2* ) x1 P=

P1* P2*
P1* + ( P2* − P1* ) y1

Colligative properties

∆Tc = K c m 2 Kc =
( ) 2
R Tc* M 1 π = c RT
g
1000 ∆H Ofus ,1
kg
Chemical equilibrium
 ∂G  ∆Gr0 d ln K a ∆H
0
  = ∑ µiν i = ∆Gr ln K a = − =
 ∂ξ T , P i RT dT RT 2
dξ eq ∆H r dξ eq ∆V
p = const : = T = const : =− r
dT TG ' ' dP G' '
Electrochemistry
Im RT
log γ ± = −0.510 z + z − E = E0 − ln ∏ aνi i ∆G = −nFE
m0 nF
Transport phenomena
Λ = Λ0 − A c Λ = Λ 0 − (A + BΛ 0 ) c / c0 Λ = ν + λ+ + ν − λ−
κ ion
strong elect. λion = = ν ion zionuion F
M*
R= 0.082 atm l/K mol= 8.314 J/K mol=1.987 cal/K mol