Acid Bases Salt Pyq

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Acids, Bases and Salts


OBJECTIVE ANSWER
Q. 1. An aqueous solution ‘A’ turns Ans. (c) CaSO4. 21 H 2O
phenolphthalein solution pink. On addition of
an aqueous solution ‘B’ to ‘A’ and ‘B’. Q. 4. When sodium hydrogen carbonate is added
(a) A is strongly basic and B is a weak
to ethanoic acid a gas evolves. Consider the
base.
following statements aboutthe gas evolved?
(b) A is strongly acidic and B is a weak (A) It turns lime water milky.
acid.
(B) It is evolved with a brisk
(c) A has pH greater than 7 and B has
pH less than 7. effervescence.
(C) It has a smell of burning sulphur.
(d) A has pH less than 7 and B has pH
greater than 7. (D) It is also a by-product of

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[CBSE OD, Set 1, 2020] respiration.The correct statements are:
(a) (A) and (B) only
Ans. (d) A has pH greater than 7 and B has (b) (B) and (D) only
pHless than 7. (c) (A), (C) and (D)
Q. 2. Baking soda is a mixture of: (d) (A), (B) and (D)
(a) Sodium carbonate and acetic acid [CBSE Delhi, Set 3, 2020]
(b) Sodium carbonate and tartaric acid
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Ans. (d) (A), (B) and (D)
(c) Sodium hydrogen carbonate and
tartaric acid Q. 5. When a small amount of acid is added to
(d) Sodium hydrogen carbonate and water, the phenomena which occur are:
acetic acid [CBSE Delhi, Set 1, 2020] (A) Dilution
Ans. (c) Sodium hydrogen carbonate and (B) Neutralization
tartaric acid. (C) Formation of H3O+ ions
(D) Salt formation
Q. 3. The chemical formula for plaster of Paris
A

The correct statements are:


is: (a) (A) and (C) (b) (B) and (D)
(a) CaSO4. 2H2O (b) CaSO4. H2O
(c) (A) and (B) (d) (C) and (D)
(c) CaSO4. 1 H2O (d) 2CaSO4. H2O
2 [CBSE Delhi, Set 3, 2020]
B

[CBSE Delhi, Set 1, 2020] Ans. (a) (A) and (C)


VERY SHORT ANSWER

Ans. (d) Formation of bubbles of a colourless and


Q. 1. When you add a few drops of acetic acid to
a test-tube containing sodium bicarbonate odourless gas.
powder, which one of the following is your Q. 2. You have four test tubes, A, B, C and D
observation? containing sodium carbonate, sodium chloride,
(a) No reaction takes place. lime water and blue litmus solutions
(b) A colourless gas with pungent respectively. Out of these the material of which
test tube/test tubes would be suitable for the
smellis released with brisk
correct test of acetic/ethanoic acid?
effervescence. (a) Only A (b) A and B
(c) A brown coloured gas is released (c) B and C (d) A and D
with brisk effervescence. [CBSE, Term 2, Set 1, 2017]
(d) Formation of bubbles of a Ans. (d) A and D
colourlessand odourless gas.
[CBSE OD, Term 2, Set 1, 2017]
.

Q. 3. The two colours seen at the extremeends Ans. (b) more than 2 but less than 7
of the pH chart are:
(a) Red and blue Q. 8. A student added a drop of universal
(b) Red and green indicator to one ml of the given solution andfound
(c) Green and blue that a green colour is produced. pH value of the
(d) Orange and green solution will be in the range of: (a) 0–3 (b) 4–6
(c) 7–9 (d) 10–12
[CBSE, Term 1, Set 1, 2016]
[CBSE, Term 1, Set 1, 2015]
Ans. (a) Red and blue Ans. (c) 7–9.
Q. 4. Four students A, B, C and D determine the Q. 9. A students takes about 4 mL of distilled
pH of water, lemon juice and dil. sodium water in four test tubes marked P, Q, R and
bicarbonate solution. They recorded their S. He then dissolves in each test tube an equal
observations and arranged them in descending amount of one salt in one test tube, in namely
order of pH values as follows: sodium sulphate in P, potassium sulphate in Q,
calcium sulphate in R and magnesium sulphate in
Student Solutions
S. After that he adds an equal amount of soap

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(A) water, lemon juice, sodium solution in eachtest tube. On shaking each of these
bicarbonate solution test tubes well, he observes a good amount of
(B) water, sodium bicarbonate lather(foam) in the test tubes maked.
(a) P and Q (b) Q and R
solution, lemon juice
(c) P, Q and S (d) P, R and S
(C) lemon juice, water, sodium
[CBSE OD, Term 2, Set 2, 2015]
bicarbonate solution
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Ans. (a) P and Q.
(D) sodium bicarbonate solution,
water, lemon juice Q. 10. In the neighbourhood of your school, hard
water required for an experiment isnot available.
The correct sequence is of the student: Select from the following groups of salts
(a) (A) (b) (B) available in your school,a group each member of
(c) (C) (d) (D) which, if dissolved in distilled water, will make
[CBSE, Term 1, Set 1, 2016] ithard:
(a) Sodium chloride, calcium chloride
A

Ans. (d) D.
(b) Potassium chloride, sodium chloride
Q. 5. Zinc metal is added to dilute hydrochloric (c) Sodium chloride, magnesium chloride
acid. The gas evolved is: (d) Calcium chloride, magnesium
(a) Oxygen (b) Hydrogen chloride[CBSE OD, Term 2,
B

(c) Chlorine (d) Carbon dioxide Set 1, 2016]


[CBSE, Term 1, Set 1, 2016]
Ans. (d) Calcium chloride, magnesium chloride
Ans. (b) Hydrogen.
Q. 11. A student was given a solution to find itspH.
Q. 6. A solution of FeSO4 in water is: His teacher declared his recorded pH as wrong.
(a) colourless (b) blue Student explained to his teacher, all the steps
(c) light green (d) brown done by him while finding pH of sample. Mark
[CBSE, Term 1, Set 1, 2016] the step taken by student in which he committed
Ans. (c) Light green mistake.
(a) collection of apparatus.
Q. 7. The pH value of a sample of hydrochloric (b) clearing of all apparatus
acid is 2. pH value of this sample when diluted (c) making pH paper wet and then dip
by adding water will be: it in sample.
(a) less than 2 but more than 0 (d) recording observation.
(b) more than 2 but less than 7 [CBSE, Term 1, Set 2, 2015]
(c) more than 7
(d) no change in pH.
[CBSE, Term 1, Set 1, 2015]
.

Ans. (c) making pH paper wet and then dip it in (c) Red litmus turns blue and blue
sample. litmus turns red.
Q. 12. A student was provided with four samples (d) Red litmus becomes colourless and
of solutions as shown in figures(I), (II), (III), and blue litmus remains blue.
(IV). He determined pH value of each solution [CBSE OD, Term 2, Set 1, 2015]
by using pH paper. The correct sequence of Ans. (a) Red litmus remains red and blue litmus
colour change of pH paper observed by the turns red.
student will be: Q. 14. A student takes about 4 mL of distilled
I II magnesium sulphate
water in four in marked
test tubes S. AfterP, that he adds an
Q, R and
Dil. sodiumbicarbonate Lemonjuice equal
S. He then dissolves in each test tubetube.
amount of soap solution in each test On
an equal
solution shaking
amount of one salt in one test tube, in namelya
each of these test tubes well, he observes
sodium sulphate in P, potassium sulphate in Q,
calcium sulphate in R and

III IV
good amountof lather (foam) in the test tubes marked
Water

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Dil. hydrochloricacid(a) P and Q (b) Q and R
(a) Indigo, light red ,green, red test tube
(c) P, Q and S containing 2 mL of distilled
(d) P, R and S [CBSE OD, water.
Term He2,
(b) Red, indigo, green, light red then shakes
Set 1, 2015] the test tube well and leaves it to
(c) Indigo, red, green, yellow settle for some time. After about 5 minutes he
Ans. (a) P and Q
(d) Green, red, yellow, indigo observes that in the test tube there is:
Q. 15. A student
(a) a adds 2 mLtransparent
clear of acetic acidcolourless
to a
[CBSE, Term 1, Set 2, 2015]
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solution
Ans. (a) indigo light red green red (b) a clear transparent pink solution
Q. 13. What do we observe on pouring acetic (c) a precipitate settling at the bottom
acid on red blue litmus papers? of the test tube
(a) Red litmus remains red and blue (d) a layer of water over the layer of
litmus turns red. acetic acid.
(b) Red litmus turns blue and blue [CBSE Delhi, Term 2, Set 1, 2015]
litmus remains blue. Ans. (a) a clear transparent colourless solution
A

SHORT ANSWER
Ans. The value of pH for water is not correct. The
Q. 1. A teacher provided acetic acid, water, correct value of pH of water is 7 because it has
B

lemon juice, aqueous solution of sodium almost equal concentration of H+ and OH– due to
hydrogen carbonate and sodium hydroxide to which it is neutral.
students in the school laboratory to determine
the pH values of these substances using pH Q. 2. What is observed when a pinch of sodium
papers. One of the students reported the pH hydrogen carbonate is added to 2 mL of acetic
values of the given substances as 3, 12, 4, 8 and acid taken in a test tube? Write chemical
14 respectively. Which one of these values is not equation for the reactioninvolved in this case.
[CBSE OD, Set 1, 2019]
correct? Write its correct value stating the reason.
[CBSE OD, Set 1, 2019]
.

Ans. CO2 gas is evolved with brisk effervescence Ans. (i) Solution A will turn blue litmus red as it
when sodium hydrogen carbonate is added to has pH 3 which is acidic in nature.
acetic acid. (ii) Solution B will turn phenolphthalein from
NaHCO3 + CH3COOH colourless to pink as it is basic innature having pH
Sodium hydrogen Acetic acid 10.5.
carobonate
CH3COONa + H2O + CO2 Q. 7. While demonstrating decomposition
Sodium reaction in laboratory the teacher heated ferrous
acetate sulphate crystals in a hard glass dry boiling tube.
(i) What change in the colour of ferrous
Q. 3. Blue litmus solution is added to two test
sulphate crystals you will observe?
tubes A and B containing dilute HCl and NaOH
(ii) What type of smell of the gases
solution respectively. Inwhich test tube a colour
coming out of the boiling tube
change will be observed? State the colour change
would you feel?
and give its reason. [CBSE Delhi, Set 1, 2019]
[CBSE, Term 1, Set 1, 2016]
Ans. Test tube A will show colour change be- Ans. (i) Light green crystal will become white.
cause acids turn blue litmus to red. So the final (ii) No smell.
colour of test tube would be red.

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Q. 8. What do you observe when you drop a few
Q. 4. What is observed when 2 mL of dilute
drops of acetic acid to a test-tube containing:
hydrochloric acid is added to 1 g of sodium (i) phenolphthalein
carbonate taken in a clean and dry test tube? (ii) distilled water
Write chemical equation for the reaction (iii) universal indicator
involved.
(iv) sodium hydrogen carbonate powder
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[CBSE Delhi, Set 1, 2019]
[CBSE Delhi, Term 2, Set 1,
Ans. A brisk effervescence would be observed if 2016]
HCl is added to Na2CO3 due to the evolution of Ans. (i) No colour change
CO2 gas. (ii) No change
Na2 CO3 + HCl  NaCl + H2O + CO2. (iii) Turns pink
Q. 5. A gas is liberated immediately with a brisk (iv) Colourless, odourless gas with brisk
effervescence, when you add acetic acid to effervescence is evolved.
A

sodium hydrogen carbonate powder in a test Q. 9. (i) While studying the combination reaction
tube. Name the gas and describe the test thaton adding water to quick lime, name the product
confirms the identity of the gas. formed andwrite its colour.
[CBSE Delhi, Term 2, Set 1, 2017] (ii) While studying the decomposition reaction
B

Ans. CH3COOH + NaHCO3  CH3COONa + by heating ferrous sulphate crystals in a test-


CO2 + H2O tube, a product is formed in the test-tube. Name
the product and write its colour.
Gas evolved is Carbon dioxide (CO2). It is tested by [CBSE, Term 1, Set 2, 2015]
passing CO2 in lime water which turns milky due
to formation of insolubleCaCO3. Ans. (i) Quicklime (CaO) reacts vigorously with
Ca(OH)2 + CO2  CaCO3 + H2O water to form slaked lime [Ca(OH)2] which is
white in colour.
Q. 6. Two solutions A and B have pH values CaO (s) + H2 O (l) C ombin n  Ca(OH)2 (s)
atio
of 3.0 and 10.5 respectively. Which of
these will turn: Calcium Calcium
oxide hydroxide
(i) Blue litmus solution to red and
(Quick (Slaked lime)
(ii) Phenolphthalein from colourless to lime) (white)
pink?
Justify your answer in each case. (ii) When ferrous sulphate is heatedstrongly, it
[CBSE, Term 1, Set 1, 2016] decomposes to form
.

brown coloured ferric oxide and sulphur dioxide Ans. Carbon dioxide, turns lime water milky.
gas and sulphur trioxide gas. Q. 11. List two observations which you make
2FeSO (s) 4 Fe O (s) +
Decomposition 23 when you add a pinch of sodium hydrogen
SO2 (g) + SO3 (g) carbonate to acetic acid in a test tube. Write
Ferrous Ferric chemical equation for the reaction that occurs.
sulphate oxide [CBSE Delhi, Term 2, Set 1, 2015]
(green colour) (brown)
Ans. Two observations observed are:
Q. 10. When you add sodium hydrogen (i) Brisk effervescence are evolved.
carbonate to acetic acid in a test tube, a gas (ii) Evolution of a colourless and
liberates immediately with a brisk odourless gas.
effervescence. Name this gas. Describe the
CH3COOH + NaHCO3  CH3COONa +
method of testing this gas.
[CBSE OD, Term 2, Set 1, 2015] H2O + CO2

SHORT ANSWER

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Q. 1. Complete and balance the following be added to water and not water to the acid?
chemical equations: (b) Dry hydrogen chloride gas does not change
[CBSE OD, Set 1, 2020] the colour of dry litmus paper why? [CBSE OD,
(i) NaOH(aq) + Zn(s)  Set 1, 2019]
LA
(ii) CaCO3(s) + H2O(l) + CO2(g)  Ans. (a) The process of mixing the concentrated
(iii) HCl(aq) + H2O(l)  acid with water is highly exothermic. So, when a
Ans. (i) 2NaOH + Zn 5 50 C
 Na2 ZnO2 + H2 concentrated acid is added to water then heat is
easily absorbed by the large amount of water.
(ii) Calcium carbonate will react with Thus it is recommended to add acid to water and
water that is saturated with carbon not water to the acid.
dioxide to form the soluble calcium (b) Dry hydrogen chloride does not contain any
bicarbonate. hydrogen ions in it, so it does not show acidic
A

CaCO3(s) + CO2 (g) + H2O (l) behaviour and thus does not change the colour of
 Ca (HCO3)2(aq) drylitmus paper.
(iii) HCl + H2O  H3O+ + Cl– Q. 4. How is sodium hydroxide manufacturedin
Q. 2. List the important products of the industries? Name the process. In this process a
B

gas X is formed as by-product. This gas reacts


Chloralkali process. Write one important use of
with lime water to give a compound Y, which is
each. [CBSE Delhi, Set 1, 2020]
used as a bleaching agent in the chemical
Ans. The three products of the chlor-alkali industry. Identify X and Y and write the
process are sodium hydroxide (NaOH), chlorine chemical equationof the reaction involved.
(Cl) and hydrogen (H). [CBSE OD, Set 1, 2019]
(i) Sodium hydroxide is used in the Ans. Sodium hydroxide is manufactured by the
manufacturing of paper, soap and electrolysis of concentrated aqueous solution of
detergents. sodium chloride.
(ii) Chlorine is used in the manufacturing 2NaCl (aq.) + 2H2 O (l) Ele
ctr
icit
y 

of bleaching powder, production of Sodium chloride water
(Electrolysis)
HCl, paints etc. (Brine)
(iii) Hydrogen is used as a fuel for rockets
and in hydrogenation of oils to obtain
vegetable ghee.
Q. 3. (a) While diluting an acid, why is it
recommended that the acid should
.

2 NaOH (aq.) + Cl2 (g) + H2 (g) oceans millions of years ago. Sometimes pressure
Sodium hydroxide Chloride Hydrogen from deep inside the earth forces up large masses
(Caustic Soda)
of rocks to from salt like domes.
The process of manufacturing sodium hydroxide
by electrolysis process is called chloro-alkali Q. 6. Identify the acid and base which form
process. sodium hydrogen carbonate. Write chemical
equation in support of your answer. State
Gas X is chlorine gas and compound Y is calcium
whether this compound is acidic, basic or
oxychloride (Bleaching powder).
neutral. Also write its pHvalue. [CBSE, Delhi
Ca (OH)2 + Cl2 (g) + CaOCl2 + H2O
Lime Chlorine Calcium Set 2, 2019]
water gas (X) oxychloride (Y) Ans. The acid and base that forms sodium
hydrogen carbonate are as follows:
Q. 5. Identify the acid and the base from which
Acid – H2CO3Base –
sodium chloride is obtained. Which type of salt
NaOH
is it? When is it called rock salt? How is rock salt
formed? The chemical equation for its formation will be
[CBSE Delhi, Set 1, 2019] NaOH + H2CO3  NaHCO3 + H2O
Sodium Hydrogen Sodium

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Ans. NaCl is made by reacting an acid and a Hydroxide Bicarbonate Hydrogen
base. or Carbonic acid carbonate

The base is NaOH (Sodium hydroxide). The compound will be basic and its pH value will
HCl + NaOH NaCl+ H2O be around 8 or in the range between 7 and 10.
So, it is a Neutralisation Reaction.
LA
It is known as rock salt in crystalline form.It is the
result of the evaporation of ancient
Q. 7. An ore on treatment with dil. HCl gives the smell of rotten egg. Name the type of this ore.
How can the metal be obtained from its concentrated ore? [CBSE, 2019]
A
B
.

Q. 8. 2 ml of sodium hydroxide solution isadded Ans. Zn + 2NaOH  Na2ZnO2 + H2


to a few pieces of granulated zincmetal taken in Sodium Hydrogen

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zincate gas
a test tube. When the contents are warmed a gas
evolves which is bubbled through a soap When a burning candle is brought towards the
solution before testing. Write the equation of the hydrogen gas, it burns with the pop sound and
chemical reaction involved and the test to detect the candle goes off.
the gas. Name the gas which will be evolved When zinc metal reacts with dilute solution of
when the same metal reacts with dilute solution strong acid then zinc chloride and hydrogen gas
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of a strong acid? [CBSE, 2018] will be formed.
Zn(s) + HCl (aq.)  ZnCl2 (aq.) + H2 (g)
Q. 9. The pH of a salt used to make tasty and crispy pakoras is 14. Identify the salt and write a
Zinc
chemical equation for its formation. List its two uses. chloride [CBSE, 2018]
A
B
.

Ans. The salt commonly used to make tasty and Ans. (i) First take three strips of blue litmus paper
crispy pakoras is baking soda i.e., sodium and dip one in each test tube.
hydrogen carbonate (NaHCO3). (ii) The liquid in test tube A turns blue
Chemical equation for its formation: NaCl + litmus to red. It means test tube A
contains acid because (acid turns blue
H2O + CO2 + NH3  NH4Cl litmus to red).
+ NaHCO3 (iii) If other two test tubes do not change
Uses of Baking soda: the colour of blue litmus paper, it
(i) It is used in fire extinguisher. shows that one of them contains a
(ii) It is also used as ingredient of antacid. base and the other contains distilled
water.
Q. 10. Write one point of difference between
each of the following: Now put the blue litmus paper which is
(v) turned red by the acid of test tube A in
(i) A hydrated salt and an anhydrous
the remaining two test tubes.
salt If the liquid of test tube B turns that red
(ii) Washing soda and soda ash
litmus paper to blue again, it shows that
(iii) Baking soda and Baking powder it is a base.
[CBSE, Term 1, Set 1, 2016]

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Ans. (i) Hydrated salt is a salt with wateras water
of crystallisation whereas Anhydrous salt is the
salt which givesaway its water of crystallisation.
(ii) Washing soda is sodium carbonate
having ten molecules of waterof
crystallisation (Na2CO310H2O)
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whereas soda ash is sodium
carbonatedecahydrate
Acid Either base or distilled water
(Na2CO310H2O) when it loses its 9
units of crystallisation itis called
soda ash (Na2CO3H2O).
(iii) Baking soda is sodium bicarbonate
A

(NaHCO3) whereas baking powder


isa mixture of baking soda
(NaHCO3) and tartaric acid
(C4H6O6).
B

Q. 11. You are provided with three test tubes A, B


and C which contain distilled water, acidic
solution and basic solution respectively. If you
are given blue litmus paper only, how will you
identify the contents of each test tube?
[CBSE, Term 1, Set 2, 2015]
(vi) The liquid in test tube C does not turn the
colour of either blue litmus or red litmus
thus is distilled water.
Step I: Put blue litmus paper
Test tube A Test tube B Test tube C
  
turns red remains blue remains blue
  

Step II: Put red litmus paper


(red turned by acid)
Test tube B Test tube C
 
.

turns blue remains red


 
Base Distilled water

LONG ANSWER
Q. 1. (a) Define indicator. Name two indicatorsdilute hydrochloric acid. What is this reaction
obtained from plants. called?
(b) Write balanced chemical equation [CBSE, Term 1, Set 1, 2016]
for the reaction that takes place
when sodium oxide reacts with Ans. (a) Indicator is any substance that gives
water. How will this solution behave visible sign usually by colour change for the
towards phenolphthalein and red presence or absence of a chemical species. Two
litmus paper? indicators are litmusand turmeric.
(c) State what happens when sodium
hydroxide solution reacts with

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A
B
.

(b) Na2O + H2O  2NaOH


NaOH in phenolphthalein shows pink colour and turns red litmus blue.
(c)NaOH+ HCl (dil.)  NaCl + H2O.
This is a neutralisation reaction whereacid and base react to give salt and water.
Q. 2. (a) The blue colour of crystals of a substance changed on heating in a closed test tube but the
colour was regained after sometime on cooling. Name the substance and write its chemical
formula. Explain the phenomenon involved.
(b) Write name and chemical formulaof two such compounds whose one formula unit is associated
with 10 and 2 water molecules respectively.
[CBSE, Term 1, Set 2, 2015]
Ans. (a) The substance is copper sulphate crys- tals (CuSO4·5H2O) which are blue in colour. When
copper sulphate crystals are heated strongly, they lose all the water of crystallisation and forms anhy

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drous copper sulphate (which is white):
CuSO .5H O H t  2CuSO + 5H O
ea4 4 2
Hydrated Anhydrous Water
copper copper (goes
sulphate (Blue) sulphate away)(White)

Thus, on strong heating blue copper sulphate crystals turn white due to the loss of water of
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crystallisation.
The dehydration of copper sulphate crystals is a reversible process. So when water is added to
anhydrous copper sulphate, it gets hydrated and turns blue due to the formation of hydrated copper
sulphate.
A

(b) Chemical formula of two such compounds whose one formula unit is associated with 10
and 2 water molecules respectively are:
B

Washing soda — Na2CO310H2O(Sodium carbonate decahydrate)


(i) Gypsum — CaSO42H2O (Calcium sulphate dihydrate)
Q. 3. (a) Define a universal indicator.Mention its one use.
(b) Solution A gives pink colour when a drop of phenolphthalein indicator is added to
it. Solution B gives red colour when a drop of methyl orange is added to it. What type
of solutions are A and B and which one of the solutions A and B will have a higher
pH value?
(c) Name one salt whose solution has pH more than 7 and one salt whose solution has
pH less than 7.
[CBSE, Term 1, Set 1, 2015]
Ans. (a) Universal indicator is a mixture of many different indicators which gives different colours
at different pHvalues of the entire pH scale. It shows different colours at differentconcentrations of
hydrogen ions in a solution.
(b) Solution A gives pink colour when a drop of phenolphthalein indicator is added,
therefore A is a base. Solution B gives red colour when a drop of methyl orange is
added to it, therefore B is an acid.
Hence, solution A will have less concentration of hydrogen ion than B.
Thus, A will have pH more than 7 because pH value of:
(i) an acid solution < 7
(ii) a base solution > 7
.

(iii) a neutral solution = 7


(c) (i) The salts of strong acids and weakbases give acidic solution having pH less than 7.
Example, NH4Cl, Ammonium chloride will have pH less than 7.
(ii) The salts of weak acids and strong bases give basic solution having pH more than 7.
Example,Na2CO3 Sodium carbonate will have pH more than 7.

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A
B
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