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Gyana vikash academy)

Electrochemistry DPP-05

1. Identify the incorrect statement(s): (2) Infinite dilution, each ion makes definite
(1) m increase with increase in temperature contribution to equivalent conductance of an
(2) m decreases with increase in concentration. electrolyte, whatever be the nature of the other
(3) Specific conductance increase with increase in ion of the electrolyte
concentration. (3) Finite dilution, each ion makes definite
(4) Specific conductance decreases with increases in contribution to equivalent conductance of an
temperature. electrolyte, whatever be the nature of the other
ion of the electrolyte
2. According to to Kohlrausch law, the limiting value of (4) Infinite dilution each ion makes definite
molar conductivity of an electrolyte A2B is: contribution to equivalent conductance of an
(1)  +  electrolyte depending on the nature of the other
( ) (B )
A
ion of the electrolyte.
(2)  
( A ) –  ( B ) 6. The correct order of equivalent conductance at
1 infinite dilution in water at room temperature for H+,
(3) 2 + 
( A ) 2 (B ) K+, CH3COO– and HO– ions is:
(1) HO– > H+ > K+ > CH3COO–
(4) 2  +  2
(A ) (B ) (2) H+ > HO– > K+ > CH3COO–
(3) H+ > K+ > HO– > CH3COO–
(4) H+ > K+ > CH3COO– > HO–
3. The value of molar conductivity of HCl is greater than
that of NaCl at a particular temperature because:
(1) Molecular mass of HCl is less than that of NaCl 7. The equivalent conductance of M/32 solution of a
weak monobasic acid is 8.0 mho cm2 and at infinite
(2) Velocity of H ions is more than that of Na
dilution is 400 mho cm2. The dissociation constant of
ions.
(3) HCl is strongly acidic this acid is:
(4) Ionization of HCl is larger than that of NaCl (1) 1.25 × 10–5
(2) 1.25 × 10–6
4. An increase in equivalent conductance of a strong (3) 6.25 × 10–4
electrolyte with dilution is mainly due to: (4) 1.25 × 10–4
(1) Increase in number of ions
(2) Increase in ionic mobility of ions 8. The equivalent conductance of Ba2+ and Cl– are
(3) 100% ionization of electrolyte at normal dilution respectively 127 and 76 ohm–1 cm2 eq–1 at infinite
(4) Increase in both, i.e., number of ions and ionic dilution. What will be the equivalent conductance of
mobility of ions BaCl2 at infinite dilution?
(1) 139.5
5. Kohlrausch’s law states that at: (2) 101.5
(1) Infinite dilution, each ion makes definite (3) 203
contribution to conductance of an electrolyte (4) 279
whatever be the nature of the other ion of the
electrolyte.
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9. The molar conductance’s of NaCl, HCl and 14. If 0.5 amp current is passed through acidified silver
CH3COONa at infinite dilution are 126.45, 426.16 nitrate solution for 10 minutes. The mass of silver
and 91 ohm–1 cm2 mol–1 respectively. The molar deposited on cathode is: (Eq. mass of silver nitrate
conductance of CH3COOH at infinite dilution (  = 108 )
m)
is: (1) 0.235 g (2) 0.336 g
(1) 698.28 ohm–1 cm2 mol–1 (3) 0.536 g (4) 0.636 g
(2) 540.48 ohm–1 cm2 mol–1
(3) 201.28 ohm–1 cm2 mol–1 15. 2.5 F of electricity are passed through a CuSO4
(4) 390.71 ohm–1 cm2 mol–1 solution. The number of gram-equivalent of Cu
deposited on cathode is:
10. 
m for NaCl, HCl and NaA are 126.4, 425.9 and
(1) zero (2) 1.25
(3) 2.5 (4) 5.0
100.5 S cm2 mol–1, respectively. If the conductivity of
0.001 M HA is 5 × 10–5 S cm–1, degree of dissociation
16. The current in a given wire is 1.8 A. The number of
of HA is:
coulombs that flow in 1.36 minutes will be:
(1) 0.25 (2) 0.50
(1) 100 C (2) 147 C
(3) 0.75 (4) 0.125
(3) 247 C (4) 347 C
11. Mark the correct choice of electrolytes represented in
17. During the electrolysis of an electrolyte, the number
the graph:
of ions produced is directly proportional to the:
(1) time consumed
 m(sc m mo l )
–1

(2) electrochemical equivalent of electrolysis

2

A (3) quantity of electricity passed

(4) mass of electrons
B

c1/2 (mol–1) 18. A current of strength 2.5 amp was passed through
CuSO4 solution for 6 minutes 26 seconds. The
(1) A→NH4OH, B → NaCl amount of copper deposited is: (Atomic weight of Cu
(2) A→NH4OH, B → NH4Cl = 63.5)
(3) A→ CH3COOH, B → CH3COONa (1 faraday = 96500 coulomb)
(4) A→ KCl, B → NH4OH (1) 0.3175 g (2) 3.175 g
(3) 0.635 g (4) 6.35 g
12. What is the amount of chlorine evolved when 2
amperes of current is passed for 30 minutes in an
19. What current strength in ampere will be required to
aqueous solution of NaCl ?
liberate 10 g of chlorine from sodium chloride
(1) 66 g (2) 1.32 g
solution in one hour?
(3) 33 g (4) 99 g (1) 7.55 ampere (2) 7.15 ampere
(3) 7.50 ampere (4) 7.45 ampere
13. Total charge on 1 mole of a monovalent metal ion is
equal to: 20. An electric current of 100 amperes is passed through
(1) 9.65 10 coulomb 4 a molten liquid of sodium chloride for 5 hours.
(2) 6.28 1018 coulomb Calculate the volume of chlorine gas liberated at the
electrode at NTP.
(3) 1.6 10−19 coulomb (1) 210.5 L (2) 200 L
(4) none of these (3) 211 L (4) 208.91 L
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Answer Key
1. (4) 11. (4)
2. (4) 12. (2)
3. (2) 13. (1)
4. (2) 14. (2)
5. (1) 15. (3)
6. (2) 16. (2)
7. (1) 17. (3)
8. (3) 18. (1)
9. (4) 19. (1)
10. (4) 20. (4)

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