prvONG THPT THANH NAN DE CUONG ON TAP vur TET : 7 HOA-11 Coho bist di luone nguyén ti (theo dvC) cia cdc nguyen tb; ‘Ag=08 TAP THIN 2024 15 C=12; O16; C=35,5; Ne14; Be PHAN I. Cau trie nghiém nhigu phuong én lya chon Mfj Cau 1: Khi thién nhién duge ding lam nhign lige cee " ‘Oi thi sinh chi chon mgt phuong ¢ Thanh phan chinh cia khi thie ha may san xu: methyl alcohol, a BCH, ite phan tir eda methane fa-2: Alkane li nhiing hydrocarbon no, mach hi, ¢6 cone are chur 14 — ‘AcCoHlane2 (021). B.CaHan(n>2). 1 D.Callana(n26) Ci 3: Voi su c6 mit cia dnh séng, ethane va chlor ia phai A } =e h ine tham: tng voi é ta0 ra hd spphin. Hap ht ndo duéi dy ¢6 thé 6 mat trong hn hop sie pl ie maMal ‘A.CHsCHa B.CHLCHS. C.CHCHCHC 4 Cl - -CHsCH:CH:Cl. DCCL Ciu 4: Cho day cc alkane: butane, isobutane, isoper Ie, se ET 5 tt Glas Cinaay isopentane, neopentane. Alkane nao trong diy c6 chia A. Isobutane. B. Butane. C£Neopemane. D. Isopenta Cau 5: Cho alkane 6 céng thie cdu ta0 nhur sau (cusps HAC(CH)s Ten soit alkane the da thay thé li ‘A. 2/2,4-trimethylpentane, B. 2,4-trimethylpethanee. a 2,4.4-trimethylpentane, D. 2-dimethyl-4-methylpentane. (Cu 6: Phin trim khdi Iugng carbon trong phan tir alkane Y bing 83,33%. Céng thig phan ti cia Y A. CoH6. B. C3Hs. C. CuHio. 'sHi2. Cf 7: Khi cho 2-methylbutane tac dung véi Cl trong, kign c6 chiéu sang dé tao din xudt mo: thi sin phdm chinh tgo thanh cé tén goi li A. |-chloro-2-methylbutane. BF chorea maison C. 2-chloro-3-methylbutane. -1-chloro-3-methylbutane. CAu 8: Tién hanh cracking C)sHs2 thu duge | phan ti chat hu co X va 1 phan tir heptane. Cong t itr pha hgp voi X 1a A. Cal (Beate .Csth: D. Cath. Céu 9: Chat nao dudi day Aldrig phai la san phim cia qué trinh oxi héa alkane trong oxygen? A.COz 7 BSO:. €.C0. D. 110. PAu 10: Acetylene (ethyne)e6 cong thire phan ti Ia A.CHi. B. CoH: Cote D. Cos. ‘au 11: Chat ndo sau day la alkene? A.CHy-CH-CHs. — (B, CH:=CH-CH. C. CHEC-CHs. D. CH=CH. Cau 12: Phat biéu nao sau day khdng ding khi m6 ta dic diém cdu tao cia alkyne? Phan tir chi e6 C va H. B. Cé mét lién két ba trong phan ti. ‘E Lién két ba chia In va 26, D. Phan tir e6 mach carbon hé. ‘dw 13: Hop chat hiu co nao sau day khéng cé déng s phan cis-trans? A. CHCI=CHCI. CA. CHsCH2CH=C(CHS)CHs. C. CH}CH=CHCHs. D. CHsCH2CH=CHCHs. fiu 14: Chat X c6 céng thtte: CH}~CH(CH;)-CH=CHg, Tén thay thé ca X la ‘A. 3-methylbut-I-ene. B3-methylbut--ene. C. 2-methylbut-3-ene. 2-methylbut-3-yne. c- fu 15: Alkyne CsHs c6 sé dong phinedutaola = ¢ 2c) C-¢ a AS B.2. Nn DA iu 16: Alkene Y cé téng sé lién két o trong phan tir 1a 11, $6 dong phan cau tao cia X 1a Cyt Al. B.2. a Da ¢ iu 17: Alkyne CsHe 06 s6 ding phan céu tgo la ¢ NO 3. D hat nao sau day thuge day ding ding cia alkyne? ure aut bing ConScarrer—— ———_—_—__—_ TRUONG : RUONG THT -THANIENHAN ales ' 022 aay LG A. CoHanes (n> Ine (02 2) i tigp sin PI vaH20. D.C yy 449: Ost ide nina eat 00 MO Er LCOOH AMO. P-Cray, cag gato nin, ooh Mage dita che eg va kt du md. A: Sodium acetsee ( pi khy biowss- © Atinigies oo : hyp chit sau Chu 21: Bhe cia nguyen td cagbon dan du (2) 1088 MOP CHG gy cH Gay 1a durge t0i da bao nhieu din y bie. b.bje Il Ti, D. bie IV- 5 chlorine th 22: Khi cho 2,2-dimethylbutane tée dung Oi Sapehlorey ee c. oo ae 2. thuong)? Au 23: Phat bigu nao sau diy khong ding (@ dieu Kien A; Cac alkane tir Cy aén Ca vi neopentane oan Mg B. Cac alkane tir Cs dén Cir (trie neopentane) 6 ane OT C; Céic alkane khéng tan hoje tan rit it trong nuSE VATE og, (PC alkane khéng tan hode tan rt FONE - ane Cau 24: Alkene la nhimg hydrocarbon oé dic diém ne Két ba C=C. uc. BB. khong no, mach vong, e6 mot D. no, mach vong- é thong ‘no, mach hd, e6 mot li 3 (Ckhéng no, mach ho, o6 mot li H-CHs-CH2-CHs? C8325: Chit nio sau diy I ding pin cia CH=CHCHPCESC YC, oy, ( ls)C=CH-CH. 1D. CH2=CH-CH2-CH=Clh, : “-CHs-CH:-CHs, " (C4u 26: Céng thite edu tao ciia 3-methylbut-I-yne li B.CHsCH2CH2-C=CH. D. CH3CH2- C=C-CHs. 3 CH:CHs. H = Cu 27: Céc alkene khéng cé cfc tinh chit vat I dje trung nao sau day? CAeTan t6t trong nude va cde dung moi hire co 1g nh hon khéi lugng riéng ca nude. : ip hon alkane phan tir c6 cing s6 nguyén tr carbon. D. Khéng din dign. Cfiu 28: Cho so dé phan img sau: CHj-C=CH + AgNO; + NH; ——> X + NH,NO. tg0 la A. CHy-CAg = CAg. BJCHs-C = CAg. C. AgCH>-C =CAg. D. A, B, C déu c6 thé ding, Céiu 29: Déin tir tir 8,4 gam hdn hop X gdm but-l-ene va but-2-ene 191 chm qua bin Khi két thc phan tng thay 6 m gam bromine phan img. Gid tri m la A. 12 gam. B.)24 gam. C.36 gan D. CAiu 30: Cho phan img CHs-CH=CH-CHs + Hz — X. Tén goi cia X 1a A. butene, B. butane. C. isobutane, D Cu 31: Cho propyne téc dung hodn toan véi He du (xt Ni, *) thu duge sn phim cf A. CH=CH. B. CH;-CHa-CHb. C. HCH. C= Crash Cfiu 32: San pham chinh thu duge khi cho methylacetylen tic dung véi lung du’ ¢ Hel ng, Nie tde thich hgp) la ~Ch ACH CCl CH BCHChCHrCis, (CAHECCI-CHy, 1 ‘du 33: Hop chét nao duge tao thanh khi pent-2-ene phig «7, E if phan ing véi nude bromine? A. I,l-dibromopentane, B Licdibomens C. 2,2-dibromopentane, Ors yromopentane ‘ 3-dibromopentane, fu 34: Hop chit nao dui day phan img vi hydro “Cibror dm chinh? "hydrogen bromide d tao ra 2-bron A. (CH3)2C=CHCH3. B (CH (CHs)2C=CHp, Du auit bi ConScarrenHANIUNTAN pose re Ho | CUCHICTUCL D.C cuen-cr, EEA bgt ethane ¥4 ethene, ding phn ang nba sat iy? a 8 mana eit 1. Phan tang cQng vai hydrogen. oi mnve brorning 1D. Phin tng ti hop, lung deh bromine? NoAut-locne carbon D.methytpropane pin 0,08 mot hn hop E gdm ethane va ethene vio binh dyng dung dich by romine dur, Ket thie thi a. 3 1B. 14,5, C142, D. 146. aa 39 Cho 0.025 aot) hin hop X gdm methane va atkene di qua binh dng dung dich brom dus KEL thie ahi nghi¢ms, KOE Wrong binh bromine tng 0,728 gam va e6 297,48 mL Kh bay ra (Ake), Cong thie phan tir tropens D.bat-t-ene, evaathene Ia ROH oh ACs BCatho, CCl, D.Calls Caw 40: Butel-ene te dng VSi NICH Qo ta sin phim ehinh We A. [-ehlorobutene, 1. }-chlorobutene, C.{-chlorobutane, ‘D.2-chlorobutane, (Caw 41: Cho phan ding hoa hye: CH=CH + Hy U5 x. Ten gol theo dank phap thay thé ea X ta ‘A. ethane. (BWrethene C.acetylen, D. ethyne, Cau 42: Cho hdn hop 2 alkene Wi qua binh dig nude bromine dur thay khdi lugng bromine phan dng 1 gam, Tong sé mol eda 2 alkene la ALOT @. C.0,025. D.0,005. chu An tmg Abt chay methane xay ra nr sau: CHA(g) + 20408) ——> COxw) + 2113:001) Gia trj bign thign enthalpy phin img tinh theo enthalpy tgo thinh e6 gid tr] HA (bigt enthalpy tgo thanh ct cata ede chit CHa(g)= 74,8 kY/mol; COs(g)= -393,5 kV/mol; HO())= -285,8 kl/mo}}> A, = 604,5 KJ, BL +8903 kJ, C.-997,7kI. D> 890,3 kJ. Khi cho khi methane téc dung vai khi chlorine c6 chiéu sing, ngudi ta thdy ngoai sin phim C adn tao ra L hop chit X trong dé phan trim khdi lugng eda nguyén tit Cl 18 89,12%. Cong thie phan CHCl: @hucn ccc D.CHsCh. Din tir tir 0,015 mol hn hgp gdm metylpropen, but-1-en va but-2-en vio binh dung dung ¢ hi Két thie thi nghigm, e6 m gam Br di phan img. Gid tr] eda m 1a ALLS. B.A. C.32. (3 Os. Mau46: Sé nguyén tir carbon va nguyén tir hydrogen trong phin tit benzene Lin Wt Ki cova 6, B.6 vas. C7 vas. D.8 vas. Mu 47: Gée aryl C,H, 06 tén goi la _ A. benzyl. B. Vinyl. Ci Phenyl, D. Benzene. daw 48: Hop chat CH, ~ Br ggi tén theo danh phip gée ehite I A. ethyl bromide. (BJ Methyl bromide, C. Bromomethane, D. Bromoeth: ‘iu 49: Cho cite din xuit halogen sau : () GH Q) CMsbr (3) Calist @) CHSC Dit negiim dan nbigt d6 sdi la AB) > (2)>A)> (I). B.(1)> 4)> Q)>@). C.(1)> 2)>GB)> A). D.G)> Q)> (> A). iu $0; Tén thay thé cia ColtsCHs la A.methyl benzene, (B.Toluene, C. Ethyl benzene, D. Stirene, iw S1: Khi cho but-L-ene tie dung voi dung dich HBr, theo qui the Markovnikov sin phim ‘a phdm chinh? 1b A. CH:Br-CH(CHs)-CHBr. B,CHs-CH(CHs)- CHaBr. ©. CHs-CH(CH)-CHBr-CHy. (Bjewscuscibe-ct, iu 52, Chat nao sau day li din xuat halogen ciia hydrocarbon 2 A.CE-CH>COOH.B. CcHs-CHSCl, C.CHs-CH>-Mg-Br. DL C-C ure aut bing ConSearrery TRUONG THPT THANH NHAN nae edu go : CHsCH-Chiscy, Srp Qenk ht my wn ala aastalone © ek rene ebetcloranente tence eh srg ma ho lim duge nhur: DG ben cao, kha nang cch abit tt Rhine 9 STE 89 a st nko nang chéng mai mén tét nhat. Do vay img dung cla loai ae ae = che tg, déo ma sat thdp, ludi trugt bang, bang dinh chju nhigt, chio chéng dinh,..- Chao duge phi lép chéng dinh Tefton Teflon duge téng hop tit A.CH=CH-CI. B.CF=C! Gu $5. Trong y khoa, gay mé li phurong phip lim ge sau me Dg ans 42u va dam bio an ton trong suét qu trinh phdu thudt. Halothane duge ding Kam mé, phii hop cho nhidu dé tudi, it Anh hudme dén site khot cia bénh nhin trong VA sau phiu th thie céu tgo eda phan tir halothane la: Fo ct wow Frc de, Foe~ dla Fog — Ca 9) bok ap Fa c D. koa C4u 56. Sin phim chinh cia phan img sau day la chit nio? CH3-CH>CHCI-CHs | wna A..CH3-CH>-CH=CH: B, CH-CH-CH(OH)CHs. (C. CH3-CH=CH-CHs. D.CH3-C! - (CayS7. ‘Thay phin Bromoethane bing dung dich NaOH & diéu Kin thich hop thu duge ch Al CHs-CH>-OH . B. CH3OH. C. CHs-CH2-ONa. D. CHs- Cfu 58: Alkylbenzene la hydrocarbon cé chita: A. vong benzene. C. g6c alkyl va hai ving benzene. Caso: Hoat tinh sinh hoc cha benzen, toluen la A, Gay hai cho sire khée. C. Gay anh hung tét cho size khée. D. Tay thudc vao nhiét d6 c6 thé gay hai ho: CAu 60: Lugng chlorobenzen thu duge khi cho 15 higu suat phan img dat 80% la A. 14 gam. B. 16 g: (c. 1 gam. _ D.20 CAu 61: Dan 3,7185 lit (diéu kign chudn) hdn hop X gdnv2 alkene la ding ding ké tiép bromine du, thay khéi lygng binh tng thém 7,7 gam. CTPT cia 2 alkene la A. CoHy va C3He. (Be Ose va Cals, C. Cals va CsHio. D.C Céiu 62: Din m gam khi propyine Idi that chim qua binh dung dung dich AgNOsNH3« kévti xuat hién. Gia tri cia m la ( AA2 gam. _B.24 gam. C.6 gam. D.2 Cau%63: Phan tich x gam chat hiru co X chi thu duge a gam CO2 va b gam 20. Bigt b). Ti khdi hoi cia X so véi Khong khi nhé hon 3. CTPT cia X 1a A. CHAO. ——_ (B/C3H.02. _ €. CHO. _ ea Dy Céiu 64: Hn hop A gdm CsHs, Cals, CsHs. Ti khdi hoi cita A so véi He bing 21, 4,958 lit (diéu kign chuan) h6n hop A roi cho sin phim chay vao dung dich Ca(Oh): dich sau phan tm, A. gidm 20,1 gam. gc alkyl va ving benzene. / 26¢ alkyl va mgt vong benzene B. Khéng gay hai cho sire khée. khong gay hai. 6 gam Coll tae dung hat véi Cla (te im 22,08 gam. C. tang 19,6 gam. D ue auit big ConScarenIni sinh chon dang hoge s “> Calla + CHa tinh: Cy ‘Ch (ask) 90 duge t6i da2 sin phim monochloro.¢ ing v* toan 4,958. . (dke) X thu duge 10, al sia X so vO He 122. Day) ae 7 khdi hoi © 0) Te sedng thie edu tgo thu gon fA (CHs)2C=C(CaH CHa, 2 Xb cunt X eg thite phan ti Calli, “1 » ‘ren goi thay thé cita X 14 2 - ethyl - 3 ~ methy!but — 2 - ene, > ) x 06 ding pha mis. Dig Ning hda hoe dae trumg c0a X fa phan ding thé. Sey, n tr [M*] 66 wi tr m/z a) Phi " 7 cau 3: Tipo MS Y, ngudi ta xi dinh duge ion ph ‘a) Phin tram khdi lugng ota hidrogen c6 trong Y I8 7.69%. ug bY phn tak Pa Sr Tae ac sin phim la ethanolr iy 24.79 it kl c) inh chia Iugng dv Ag ong NI é oan lease HE ‘gam két ta mau vang, 24 wong chu AgNOs trong NH;, sow khi phn dng xy 1d) Cho ALCs vio nus thu duge Y. Sa) cau 4s Thi nghigm: phan dng bromine hod hexane Chudn bj: 6ng nghiém, h 6c bromine, ede thuy tinh, Tién han! . Bude 1: Cho vio ong n higm khoang | mL hexane rdi cho tiép vio dé khodng 1 mL nude sau dé hie d Bucie 2: } 1) Sau bude 1, dung di da ankyn\ pat éng nghigm vio céc nude dm (khoang 50 °C). ich trong dng nghiém ddng nhit, So b) Sau bude I, hexane khong mau ndiléntrén, Pur, ¢) Sau bude 2, dung dich trong ng nghiém c6 mau ving. %-, dd) Sau bud 2, dung dich trong dng nghigm ding nhat. ary ‘aw 8: Cé hai dng nghigm, mdi dng chia | mL dung dich bromine trong nude ¢6 mau ving nha thém vao ng thir nhdt ImL hexane va Sng thir hai ImL hex-I-ene. Lic déu dng nghigm, sau dé ing nghigm trong vai phat. ‘a) Oca hai ng nghiém c6 sy tach ldp. Dini, 1) Ong nghiém thi nhdt: Mau vang nhgt khong di, Ding, ) Ong nghiém thir nhdt khong xay ra phan tg, Ong nghigm thir 2 xay ra phan img. 1), 4) Chai dng nghigm déu xdy ra phan img. 3, ‘ho so do chuyén hoa diéu ché poly(vinyl chloride) sau day: ‘au cH, att” ene D ae 7 — y(vinyl chloride) wa poly(vinyl eblor 1, [=e PaPncoy, “cl, a a) A liacetylene. b)Bliethane. ©, ¢) Dcé céng thite phan tir la CoHsCl. > ) Phan tir khdi cita C 14 97 (dvC). Pity Oh At ca chat X theo cdc bude sau day: \w 7: Tién hinh thi nghigm digu ché va thir tinh chat Bueée I: Cho vai miu nd calei carbide vio dng net Ong din khi diu vudt nhon. Bure 2: bt khi sinh rao dau éng vudt nhon. Bueie 3: Din ki qua ng nghiém dung dung dich KMnO, va dung dich AgNOs trong NH. m di dung 1 ml nude va diy nh ede phat bigu sau: Dur autt bing ConScarrerTRUONG THPT THANH NHAN 8) C6 thé thay calei carbide bing dt din)" if b) Khi chdy, X toa nhidu nhigt nén duge ding trong dn xi dé han, cit kim loa ¢) Din khi X dén du qua dung dich KMnO,, mau tim nhat din dé Igi trong éng ghiem dung dich tron, tring. Sy sudt, khéng mau, On @) Din khi X qua dung dich AgNO, trong NH thy tgo thinh két tia ma (Cau 8: Tidn hanh thi nghigm hur hinh ve: 1.58 gam khi A > Ha Dang dich, Calcium carbide AgNO: HgS0, + H,80, + H,0 8.88 gamehitrin sau: a) Khi A thoat ra la khi acetylene, v() b) Phuong trinh héa hge xay ra trong binh (1) li: CH ¢) Phuong trinh héa hoe xay ra trong binh (1) las 0, HC =CH +2Ag(NH3p]OH > AgC +120 28 5 CH3—CHO for: ‘Ag + 4NH3 #21207; d) Higu sudt phan img dat 75%. Sy Cu 9: Cho alkane X phan img vi Clz trong digu kign thich hop duge hin hgp sin phim thé chloro, dé c6 mot din xudt ¢6 phan tir khdi la 113. a) X c6 tén goi Li 2 - methylpropaneSa. b) X e6 phan tir khdi 1a 42. Meg ¢) Ti khdi hoi ciia X so véi khong khi c6 gid tr] gan 1,52. 4) X phan tig voi Cl (askt, ti 18 mol 1:1) thu duge sin phim chinh la 2 — chloropropane. /) Cau 10: Alkene Y cé phan trim khdi Irgng carbon bing 85,71%. Cl, . a) Ti khéi hoi cia Y so vai hydrogen Ia 20, b) Y phan img véi HCI ( xt), thu duge mét sin phim eng duy mht, Dr; c) Déng phan ctia Y la propene. S 4d) Oxi héa hoan toan 24,79 Lit ¥ (dke) thu duge 3,6 gam H20. 9, Cfu 11: Cho so dé phan img sau: 1500°C,lin + Hz du (Wit°C) | Cly(askt) Methane ———> X =") y 25 7 (din xudt monochloro). Col Col oI Ch Cho ede phat biéu sau: a) X lam mat mau thudc tim (KMnO4)..) nf b) X phan tg voi H20 (Hg?*, 80°C), thu duge ethanal- > ¢) Cracking Y thu duge methane. ° ‘ 4d) Z.cé tén goi la ethylchloride. Py 2 ( Céu 12: Cho 14 gam hén hgp X gdm hai alkene la dbng ding lign tiép di qua nude Bro thay lam vira dit dung dich chira 5 gam Bn. uw Cho cae phat biéu sau: 1a) Céng thie phan teeta hai ankene Li Cats vi CoH, fp - b) Phan tram khdi lugng ea ankene e6 phan tr khdi nhé hon la $0%. Sy 6) Cho hdn hgp X qua H20 (HsPOs,1"C), thu durge sin phim e6 chia t6i da 2 alcohol) 4d) Kh6i lugng eda ankene ¢6 phan tr khdi Ién hon ta 8,4 gam, Dur autt bing ConScarrerONG THPT THANH NHAN TRU iu 13: Cho cde phat biéu sau: 4) Trong phan tir alkyne chi chtta lién két don (lién kéto). Sa b) Propene, propyne, 2-methylpropene déu lam mat mau dung dich nuéc bromine & c) Acetylene ding lam nhién liéu trong dén xi oxi-axetilen (khi duge tac dung voi oxy) dé han hay cat kim loai. d) Cac alkane c6 sO nguyén tir carbon tir C2o tré én ding dé san xudt nén, dau mé béi tron. 775 Cau 14: Cho cdc phat biéu sau: a a) Phan tram khdi lugng cacbon trong phan tir ankan Y bang 83,33% vay céng thite phan tir ciia Y 1a CsHi2. b) Butadien va isopren cd thé diéu ché cdc chat c6 tinh dan hdi cao dé sin xuat cao su. Daf, ¢) Hidrocacbon CsHs_ mach ho c6 4 déng phan thd : ng voi Cle (askt), th . Z aman, 74NG u duoc 4 dan xudt monochloro. ony d) 2.3 - dimethylbutane phan th ot C " Dur aute bing CanScarrer