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2023_Water Air Soil Pollution_Sutlej Hydrograph
2023_Water Air Soil Pollution_Sutlej Hydrograph
https://doi.org/10.1007/s11270-023-06744-4
Abstract This study examines the proportional for Ropar is 59 ± 2% (snow/ice melt), 23 ± 2% (rain-
contribution of snow/ice melt, rainfall, and ground- fall), and 18 ± 2% (groundwater); and for Yusuf-
water to Sutlej River discharge at various locations. pur, 25 ± 3% (snow/ice melt), 39 ± 3% (rainfall),
Sutlej River is a major tributary of the Indus River and 36 ± 2% (groundwater) during July–December
system and an important water supply source for irri- 2013. The findings from the hydrograph-separation
gation through the canal network in northwest India. and SNOWMOD analysis established a fundamental
Here, we used hydrograph separation and associated understanding of the hydrological processes in the
uncertainty and applied the snowmelt runoff model Sutlej River system, providing valuable baseline data
(SNOWMOD) to estimate the contribution from dif- essential for developing sustainable water resource
ferent water sources to the Sutlej River. We used δ18O management strategies.
and electrical conductivity values of different waters
for the hydrograph-separation approach. The first- Keywords Sutlej River · Hydrograph separation ·
order Gaussian error propagation and Monte-Carlo Stable isotopes · Uncertainty · SNOWMOD · Western
simulation are used to assess the accuracy. The esti- Himalayas
mated contribution at Rampur is ~ 62.7% (snow/ice
melt), 18.7% (rainfall), and ~ 18.4% (groundwater);
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groundwater samples from monitoring wells oper- Rao et al. (2017), Varay et al. (2017), Joshi et al.
ated by the state and central government agencies, (2018), and Maurya et al. (2018) have collected
public tube wells, and hand pumps in the Sutlej River water samples in pre-cleaned polypropylene bottles
Basin. They have adopted a water sampling procedure (20 ml) for stable isotope analysis. The bottles were
such as Clark and Fritz (1997) and purged wells for rinsed with the sample water more than once at the
25–30 min before water sampling (e.g., Joshi et al., sampling site. In order to avoid evaporative losses
2018). from the sample bottles and storage containers, bot-
Precipitation is the primary recharge source of tles were tightly sealed and brought to the labora-
groundwater and river discharge. Groundwater tory for isotopic analysis. A handheld global posi-
recharge from the canal and irrigation return flow tioning system measured sample latitude, longitude,
are also important in Northwest India (Lapworth and altitude. Water’s electrical conductivity (EC)
et al., 2017; Joshi et al., 2018). The irrigation is also measured during the sampling (Rao et al.,
canals typically convey the water from the Sutlej 2017; Varay et al., 2017; Joshi et al., 2018; Maurya
River, such as the Bist-Doab Canal, a major irri- et al., 2018).
gation canal drawn from the Sutlej River in Pun-
jab in NWI (Joshi et al., 2020). To understand the 3.2 Isotopic Analysis
isotopic signatures of different sources in the study
area, we complied isotopic values of precipitation The stable isotopic analysis was carried out in the
during the monsoon season (July to September) for Nuclear Hydrology Laboratory at the National Institute
2013 from Joshi et al. (2018) and river water sam- of Hydrology, Roorkee, India. The stable isotope meas-
ples from two locations (Rao et al., 2017; Maurya urements were made using continuous flow isotope ratio
et al., 2018) for the Sutlej River Basin. mass spectrometry and dual inlet isotope ratio mass
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spectrometry following standard procedures (Epstein and i.EI + g.EG + r.ER = ET (5)
Mayeda, 1953; Brenninkmeijer and Morrison, 1987).
The results are expressed in per mil (i.e., ‰) on Vienna where i, g, and r denote the discharge fractions due to
Standard Mean Ocean Water (VSMOW) on the δ scale: snow/ice melt, groundwater, and rainfall, respectively.
( R −R ) E is EC.
𝛿 = sample (1)
standard
R
× 1000% VSMOW ( )( )
standard
𝛿T − 𝛿I EG − EI − (𝛿G − 𝛿I )(ET − EI )
r= ( (6)
where Rsample is the 18O/16O or 2H/1H ratio of the
)( )
𝛿R − 𝛿I EG − EI − (𝛿G − 𝛿I )(ER − EI )
water samples, and Rstandard is the corresponding ratio
in VSMOW. The overall precision is based on ten ( )( )
𝛿T − 𝛿I ER − EI − (𝛿R − 𝛿I )(ET − EI )
repeated measurements for each sample, which was g= ( (7)
within the error limits of ± 1.0‰ for δ2H and ± 0.1‰
)( )
𝛿G − 𝛿I ER − EI − (𝛿R − 𝛿I )(EG − EI )
for δ18O, respectively.
We used Eq. (3) to calculate the i value.
We assumed EC and δ18O of three end-members
3.3 Hydrograph Separation are constant throughout the year (Penna et al., 2016;
Jeelani et al., 2017), excluding the river discharge
We used the hydrograph separation approach to esti- component as it varies significantly during pre- and
mate snow/ice melt, rainfall, and groundwater contri- post-monsoon. In the present study, the upper and
bution to the Sutlej River to determine the tracer-based lower limit of snow/ice melt fraction estimates for
contribution. The fundamental assumption is that water river discharge were obtained from Pande et al.
and snow precipitation will distinctly fractionate heavy (2000), Rai et al. (2016), Biggs et al. (2015), and Ren
and light oxygen isotopes. The altitude effect mainly et al. (2016).
affects the isotopic values of snow at higher altitudes.
Hence, the snow has a relatively lesser amount of heav- 3.4 Uncertainty
ier (18O) isotope than liquid precipitation.
It should be noted here that the river discharge in The primary sources of uncertainty using the hydro-
the alluvial region of NWI and WH are mainly com- graph separation are spatio-temporal variations of
prising three components, namely, (i) snow/ice melt, δ18O and EC values of water (Delsman et al., 2013;
(ii) groundwater, and (iii) rainfall. These discharge Davis et al., 2015). We first used first-order Gauss-
components are mainly due to summer rainfall, post- ian error propagation to evaluate uncertainty in the
monsoon interflow, and winter snowmelt from the hydrograph separation (Genereux, 1998). Measure-
catchment area. Therefore, discharge can be calcu- ment errors in δ18O (± 0.1‰) and EC (± 10 μS/cm)
lated based on Eq. (2). are considered in uncertainty propagation (Schmieder
T =I+G+R (2) et al., 2018). The first-order Gaussian error propaga-
tion method is applied by considering measurement
where T is the total discharge, I is the snow/ice melt, errors in all factors for hydrograph separation. Factors
G is the groundwater, and R is the rainfall due to equations for hydrograph separation (Eq. 3) are par-
summer rainfall, post-monsoon interflow, and winter tially differentiated for individual factors, and these
snowmelt from the catchment. values are summed in a quadrature manner to esti-
If the total discharge is considered one, then the mate the propagated uncertainty in the final results
three components can be considered a fraction of 1 (Taylor, 1997; Uhlenbrook & Hoeg, 2003; Guo et al.,
(Eq. 3). 2015; Camacho Suarez et al., 2015; Swarnkar et al.,
i+g+r =1 (3) 2018; Chen et al., 2019; Loukili et al., 2022). Equa-
tion 8, used for the first-order Gaussian error propa-
gation method, is described below.
i.𝛿I + g.𝛿G + r.𝛿R = 𝛿T (4)
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zone (Table 1). We have used additional information Table 2 Summary of the isotopic composition of groundwater
such as the total study area up to Rampur, elevation samples in the Sutlej River basin
band-wise area, SDC, and altitude of rainfall and tem- Sample Range EC (µS/cm) δ18O (‰) δ2H (‰)
perature monitoring stations for SNOWMOD simula-
All Samples Minimum 340.0 − 11.3 − 81.6
tion. We have used daily observed discharge data for
Maximum 1840.0 − 6.1 − 37.4
model calibration and validation. We also assigned
Average 724.6 − 7.6 − 52.3
generated runoff from the model to snowmelt and
Std 274.2 1.3 9.7
rainfall runoff, estimated using the runoff coefficient.
Downstream Minimum 340.0 − 11.3 − 81.6
The remaining runoff is from the baseflow generated region Maximum 1840.0 − 6.1 − 37.4
from the snowmelt or rainfall.
Average 720.5 − 7.7 − 52.8
Std 279.1 1.3 9.8
Upstream Minimum 430.0 − 10.6 − 71.2
4 Results region Maximum 1115.0 − 6.1 − 41.8
Average 754.5 − 7.2 − 49.2
4.1 Isotopic Composition of Groundwater and River
Std 246.7 1.4 9.4
Water
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sources to river discharge (Varay et al., 2017). For the upstream region of Ropar and − 7.6 ± 1.3‰ for the
Sutlej River Basin, we used δ18O and EC values of upstream part of Yusufpur. The EC value of ground-
snow/ice melt, rainfall, and groundwater to identify water ranges from 430 to 1115 μS/cm (average:
the potential end-members (Genereux 1998; Penna 755 μS/cm) for the upstream region of Ropar and
et al., 2016). from 340 μS/cm to 1840 μS/cm (average: 725 μS/cm)
The surface runoff mainly comprises various com- for the upstream part of Yusufpur (Table 2).
ponents such as snowmelt during winters and rainfall- We plotted all three end-members in a cross-
runoff during monsoon and post-monsoon seasons. plot of δ18O vs. EC values of groundwater, rainfall,
The isotopic composition of precipitation shows snow/ice melt, and Sutlej River water (Fig. 4). Fig-
seasonality in the mountainous region (Kumar et al., ure 4 shows the isotopic values of Sutlej River water
2010). We used the Amount Weighted Annual Pre- at Ropar and Yusufpur that exhibit good agreement
cipitation (AWAP) isotope value of − 5.54‰ for δ18O with the end members. The depleted δ18O value and
from Joshi et al. (2018, 2020), and EC is 50 μS/cm lower EC were observed at Ropar, enriched δ18O, and
(Lambs, 2000; Maurya et al., 2011) for monsoon and higher EC value at the Yusufpur monitoring station.
post-monsoon season.
The isotopic snow/ice melt values are highly varia- 4.3 Relative Contributions
ble in WH (Pande et al., 2000; Rai et al., 2016; Biggs
et al., 2015; Ren et al., 2016; Varay et al., 2017). The Figure 5 shows various sources’ contributions to
EC values of the stream show seasonality in WH. In the Sutlej River at Ropar and Yusufpur. The snow/
comparison, the isotopic values of snow/ice meltwa- ice melt contributions show seasonality from July to
ter are − 15.54 ± 3.34‰ for δ18O and 115 μS/cm for December (Fig. 5a–b).
EC (Pande et al., 2000; Rai et al., 2016; Biggs et al., We found that the maximum contribution from
2015; Ren et al., 2016). snow/ice melt is 69 ± 2% at Ropar and 35 ± 2% at
Further to this, we have used groundwater’s two Yusufpur during July–August, respectively, and
separate δ18O and EC data in the upstream region of a minimum of 50 ± 2% at Ropar and 18 ± 3% at
Ropar and Yusufpur stations for hydrograph separa- Yusufpur during November–December, respectively
tion. The average δ18O value is − 7.2 ± 1.4‰ for the (Table 3). The lower contribution of snow/ice melts
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(~ 18.7%), and groundwater (~ 18.4%) at Rampur Bookhagen and Burbank (2010) used remotely
from 2000 to 2006. Also, we have computed model sensed datasets to calculate rainfall, evaporation, and
efficiency based on daily computed and observed snowmelt amounts. They suggested snowmelt runoff
data. The simulated daily streamflow data agrees contributes ~ 57% and ~ 43% from rainfall and other
with the observed data, as the coefficient of deter- sources. Singh and Jain (2003) used Landsat MSS,
mination (r2) value is obtained as 0.93 and 0.91, IRS LISS-I, and in situ data from rain gauge stations
respectively. From the evaluation criteria (r2), it is to calculate snowmelt contribution at Bhakra Dam.
found that the model performs well for both periods They suggested ~ 32% contribution from rainfall
(calibration and validation) (Fig. 6b–c). and ~ 68% from snowmelt and other sources (Singh &
Jain, 2003). They pointed out seasonality in the rela-
tive contributions from 1988 to 1999. Further to this,
5 Discussion Varay et al. (2017) used a mixing model and estimated
melt contribution for the Sutlej River Basin (Fig. 7).
5.1 Snow/Ice Melt Contribution Our estimates based on the hydrograph separation
and the SNOWMOD results suggest a good agreement
Previously, Singh and Jain (2003) and Bookhagen with the previous modeling-based studies in the higher
and Burbank (2010) used modeling approaches to Himalayan mountains (Singh and Jain, 2002 & 2003;
estimate the Sutlej River Basin hydrological budget. Bookhagen and Burbank, 2010; Wulf et al., 2016). At
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Table 3 Summary of contributions (%) of snow/Ice melt, Ropar, the maximum snow/ice melt was 69 ± 2% on
groundwater, and rainfall in Sutlej river discharge at Yusufpur, August 10, 2013, and the minimum was 50 ± 2% on
Ropar, and Rampur
November 10, 2013. Yusufpur’s maximum snow/ice
Station Month Rainfall Groundwater Snow/ice melt melt was 35 ± 2% on July 30, 2013, and the minimum
was 18 ± 3% on December 10, 2013. This analysis fur-
Yusufpur July 37.5 30.3 32.2
ther suggests that the upstream region’s highest snow/
August 39.0 33.9 27.0
ice melt contribution was during July–August 2013.
September 35.3 34.9 29.8
We also observed a higher snow/ice melt contribution
October 39.6 36.7 23.6
of ~ 64% at Ropar from 2000 to 2006. Similarly, Varay
November 39.9 39.0 21.1
December 41.7 38.9 19.5
et al. (2017) observed a higher snowmelt contribution
Annual 38.8 35.6 25.5
(67%) at Lipa in the mountainous region (Fig. 7). The
Ropar July 21.8 12.5 65.7
study results highlight the downstream variability in
August 24.5 14.5 61.1
snowmelt contribution (Wulf et al., 2016). We suggest
September 17.7 17.3 65.0
that the ice/snowmelt runoff is the primary source of
October 25.6 19.7 54.7
the Sutlej River.
November 25.0 22.3 52.7
December 23.9 22.2 53.9
5.2 Uncertainty in Hydrograph Separation
Annual 23.1 18.1 58.8
Rampur Annual 19.0 –- 64
The uncertainty of the hydrograph separation
approach is not avoidable (Uhlenbrook and Hoeg,
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2003). Several factors control the hydrograph sepa- summed in quadrature to obtain uncertainty in rain-
ration approach’s accuracy in any glacierized basin fall contribution.
(Penna et al., 2017). Thus, the uncertainty assess- In MC simulations, uncertainty in the rainfall con-
ment is a helpful approach that gives probable like- tribution was estimated by generating random val-
lihood values by propagating measurement errors to ues and using them in the equations (Eq. 3, 6, and
the final results (Swarnkar et al., 2018; Chen et al., 7). Hence, the first-order uncertainty assessment of
2019; Swarnkar et al., 2021b). The spatio-temporal rainfall contribution uncertainty is relatively higher
variation of various contributing sources might influ- than the MC uncertainty simulations. It is also proved
ence the hydrograph separation approach’s uncer- that the uncertainties might be over-estimated if they
tainty in the isotopic composition of end members are assessed through the first-order uncertainty pro-
(Uhlenbrook & Hoeg, 2003). Further to this, the cedure. The assessed uncertainty could be underes-
hydrometeorological parameters (temperature and timated. Other sources, i.e., spatial uncertainty due
humidity) and moisture source influence the rainfall to inhomogeneities in the hydrometeorological pro-
tracer concentration (Clark & Fritz, 1997). Therefore, cesses, temporal variation in measurement uncer-
these uncertainties could be much higher than labora- tainty, and stochastic and model errors, should be
tory errors (Penna et al., 2017). The statistical uncer- incorporated into the uncertainty framework. Com-
tainty can be quantified using a first-order uncertainty bining these different sources of uncertainty might
estimate (Schmieder et al., 2018) or the Monte Carlo give relatively higher values than the current uncer-
framework (Genereux, 1998). In the present study, we tainty estimates.
quantified uncertainty by applying both methods and
comparing their applicability (Table 4). 5.3 Limitations of the Present Study
Our uncertainty results suggest 1.7–1.8% and
2.0–3.0% uncertainty in groundwater and rainfall We used hydrograph separation and SNOWMOD
contribution (Table 4). The first-order uncertainty to estimate groundwater, rainfall, and snow/ice melt
and MC simulations yielded similar results for both contributions to Sutlej River discharge at various
contributing factors. The uncertainty in snow/ice locations in the study area. Due to the remoteness and
melt contribution (i) varies between 2.7–3.7% and inhomogeneities in climatic conditions, collecting
1.6–3.0% using first-order and MC simulations. water samples from the higher altitude region for the
It should be noted here that the uncertainty value isotopic analysis in the Sutlej River Basin is impos-
of groundwater and rainfall was estimated by par- sible. Therefore, we collected water samples from
tially differentiating Eqs. 6 and 7 in the first-order the lower altitude region for isotopic study (Varay
uncertainty assessment. The obtained uncertainty et al., 2017; Maurya et al., 2018). We applied an iso-
of groundwater and surface-water components were topic approach for the lower altitude and a modeling
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Table 4 Summary of results obtained from the hydrograph separation approach and associated uncertainty
Result (%) Monte Carlo Gaussian
Location Date Rainfall Groundwater Snow/ice melt Rainfall Groundwater Snow/ice melt Rainfall Groundwater Snow/ice melt
Ropar 10 Jul 2013 24.7 12.4 63.0 2.3 1.8 2.0 2.3 1.8 2.9
Water Air Soil Pollut
20 Jul 2013 20.2 12.2 67.6 2.2 1.8 1.8 2.2 1.8 2.8
30 Jul 2013 20.5 13.0 66.4 2.2 1.8 1.8 2.2 1.8 2.8
10 Aug 2013 17.6 13.5 68.9 2.1 1.8 1.7 2.1 1.8 2.7
20 Aug 2013 27.3 14.5 58.2 2.4 1.7 2.1 2.3 1.7 2.9
30 Aug 2013 28.5 15.4 56.1 2.4 1.7 2.1 2.4 1.7 2.9
10 Sep 2013 18.3 16.7 65.0 2.1 1.8 1.7 2.1 1.8 2.7
(2023) 234:719
20 Sep 2013 18.5 17.5 64.0 2.1 1.8 1.7 2.1 1.8 2.7
30 Sep 2013 16.4 17.8 65.9 2.1 1.8 1.6 2.0 1.8 2.7
10 Oct 2013 19.8 20.0 60.2 2.1 1.7 1.7 2.1 1.7 2.7
20 Oct 2013 30.7 16.2 53.1 2.5 1.7 2.2 2.4 1.7 3.0
30 Oct 2013 26.3 23.0 50.8 2.3 1.7 2.0 2.3 1.7 2.8
10 Nov 2013 27.8 22.4 49.9 2.3 1.7 2.1 2.3 1.7 2.9
20 Nov 2013 25.9 21.4 52.7 2.3 1.7 2.0 2.3 1.7 2.8
30 Nov 2013 21.3 23.3 55.4 2.1 1.7 1.8 2.1 1.7 2.7
10 Dec 2013 25.5 22.9 51.6 2.3 1.7 2.0 2.2 1.7 2.8
20 Dec 2013 23.9 19.6 56.4 2.2 1.7 1.9 2.2 1.7 2.8
30 Dec 2013 22.3 24.1 53.6 2.2 1.7 1.8 2.2 1.7 2.7
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Table 4 (continued)
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Location Date Rainfall Groundwater Snow/ice melt Rainfall Groundwater Snow/ice melt Rainfall Groundwater Snow/ice melt
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Yusufpur 10 Jul 2013 39.7 31.3 29.0 2.8 1.8 2.7 2.8 1.8 3.3
20 Jul 2013 37.9 29.4 32.7 2.7 1.8 2.6 2.7 1.8 3.2
Page 14 of 18
30 Jul 2013 35.0 30.1 34.9 2.6 1.8 2.4 2.6 1.8 3.1
10 Aug 2013 38.6 31.2 30.3 2.8 1.8 2.7 2.7 1.8 3.2
20 Aug 2013 38.9 34.5 26.6 2.8 1.8 2.7 2.7 1.8 3.3
30 Aug 2013 39.6 36.2 24.2 2.8 1.8 2.7 2.8 1.8 3.3
10 Sep 2013 40.6 33.0 26.4 2.8 1.8 2.8 2.8 1.8 3.3
20 Sep 2013 30.9 35.3 33.8 2.4 1.8 2.3 2.4 1.8 3.0
30 Sep 2013 34.3 36.4 29.3 2.6 1.8 2.4 2.6 1.8 3.1
10 Oct 2013 36.2 37.5 26.4 2.7 1.8 2.5 2.6 1.8 3.2
20 Oct 2013 39.9 34.6 25.5 2.8 1.8 2.7 2.8 1.8 3.3
30 Oct 2013 42.8 38.2 19.0 3.0 1.8 2.9 2.9 1.8 3.4
10 Nov 2013 40.6 38.7 20.7 2.9 1.8 2.8 2.8 1.8 3.3
20 Nov 2013 39.2 39.4 21.3 2.8 1.8 2.7 2.8 1.8 3.3
30 Nov 2013 40.1 38.7 21.2 2.8 1.8 2.7 2.8 1.8 3.3
10 Dec 2013 43.7 38.3 18.0 3.0 1.8 3.0 3.0 1.8 3.5
20 Dec 2013 42.4 38.9 18.7 2.9 1.8 2.9 2.9 1.8 3.4
30 Dec 2013 38.9 39.4 21.7 2.8 1.8 2.7 2.8 1.8 3.3
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approach for the Sutlej River Basin’s higher altitude snow/ice melt contribution, originating in the WH
region. higher-altitude region. In contrast, groundwater and
First, δ18O and EC values of groundwater, rain- rainfall mainly govern the Sutlej River discharge in
fall, snow/ice melt, and river water have been used the alluvium region. Our results can provide an oper-
for hydrograph separation for Yusufpur and Ropar ational monitor and groundwater manager to manage
(Fig. 5). Second, SNOWMOD has been used for the water resources to sustain long-term existence in the
mountainous region at Rampur (Fig. 6). As men- mountainous river system.
tioned earlier, there are limitations regarding isotopic
and in situ data for SNOWMOD. We have used the Acknowledgements The authors would like to thank the
Director of the National Institute of Hydrology, Roorkee, for
available data for our analysis in the present study. their support during the study. The isotopic data of snow/ice
The isotopic data used in the paper was collected in melt, groundwater, surface water, and precipitation used in this
2013, and in situ data for SNOWMOD was collected study are obtained from Pande et al. (2000), Rai et al. (2016 &
from 2000 to 2006. 2019), Biggs et al. (2015), Ren et al. (2016), Rao et al. (2017),
Joshi et al. (2018; 2020), Maurya et al. (2018), and Boral et al.
We also observed a higher snow/ice melt con- (2019). Data obtained from the Asian Precipitation—Highly
tribution during July and a decreasing trend until Resolved Observational Data Integration Towards Evaluation
December (Figs. 5 and 6), possibly due to tempera- (http://aphrodite.st.hirosaki-u.ac.jp/download/), Advanced Spa-
ture variability and hydrometeorological parameters ceborne Thermal Emission and Reflection Radiation Digital
Elevation Model (https://gbank.gsj.jp/madas/?lang=en#top),
(Fig. 2a–b). We cannot determine the actual cause(s) Moderate Resolution Imaging Spectroradiometer land surface
for the observed decreasing trend in snow/ice melt reflectance 8-day maximum snow cover products (MOD10A2)
relative contribution due to the lack of stable isotope, with a 500-m spatial resolution (https://nsidc.org/data/MOD10
EC, river discharge, and hydrometeorological datasets A2/versions/6), and hydrometeorological data (rainfall and
temperature) data from Indian Meteorological Department
from the present study. (http://imdpune.gov.in/Clim_Pred_LRF_New/Grided_Data_
Download.html) are thankfully acknowledged. The data
obtained from the Bhakra Beas Management Board (BBMB),
6 Conclusions Government of India, is thankfully acknowledged.
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hydrogeomorphic and climatic controls on soil erosion
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