04.10.20 CTA-4

Sec: SR.
IIT_CO-SC Date: 04-10-20

Time: 3HRS Max. Marks:240
Name of the Student: H.T. NO:
04-10-20_SR.IIT_CO-SUPER CHAINA_Jee-Adv_CTA-4_SYLLABUS
PHYSICS: PT-1 & PT-7 SYLLABUS ONLY
CHEMISTRY: PT-1 & PT-7 SYLLABUS ONLY
MATHEAMTICS: PT-1 & PT-7 SYLLABUS ONLY

Narayana IIT Academy 04-10-20_Sr.IIT_CO-SC _JEE-Adv_CTA-4_Q’P
Time: 3:00 Hour’s IMPORTANT INSTRUCTIONS Max Marks: 240
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 8) Questions with Integer Answer Type 4 0 8 32
Sec – II(Q.N : 9 – 16) Questions with Multiple Option Correct 4 -2 8 32
Questions with Comprehension Type
Sec – II(Q.N : 17 – 20) 4 -2 4 16
(2 Comprehension -2+2=4Q)
Total 20 80
CHEMISTRY:
Section Question Type Marks Marks Qs marks
Sec – II(Q.N : 37 – 40) 4 -2 4 16
Total 20 80
MATHS:
Section Question Type
Marks Marks Qs marks
Sec – II(Q.N : 57 – 60) 4 -2 4 16
Total 20 80
SR.IIT_CO-SC Page. No. 2
A dull mind gets bored easily. A curious mind expands forever.

PHYSICS Max Marks : 80
SECTION – I
(INTEGER ANSWER TYPE )
This section contains 8 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +4 for correct answer , 0 if not attempted and 0 in all other cases.
1. A cylinder contains 0.15 kg of hydrogen. The cylinder is closed by a piston supporting a

weight of 74 kg (see fig.), n × 103 J amount of heat is given to lift the weight by 1.2 m ?
The process should be assumed isobaric, the heat capacity of the vessel and the
atmospheric pressure should be neglected. Find n (n is single digit.)
2. The emissivity of tungsten is approximately 0.35. A tungsten sphere 1 cm in radius is

suspended within a large evacuated enclosure whose walls are at 300 K. What power
input is required to maintain the sphere at a temperature of 3000 K if heat conduction
along the supports is neglected ? Express your answer in kW after rounding off to the
nearest integer. Take  = 17 × 10–8 S.I. units and  = 213 .
3 68
3. A bar measured with a Vernier Caliper is found to be 1800 mm long. The temperature
during the measurement is 10ºC.
The measurement error if the scale of the Vernier Caliper has been graduated at a
temperature of 20ºC is found to x × 10–2 mm. Find x. (   1.1106 / k )
4. An insulated container is filled with mixture of water & ice at 0°C. Another container is
filled with water that is continuous boiling at 100°C. In a series of experiments, the
containers are connected by various thick rods that pass through the walls of the
containers. The rod is insulated in such a way that there is no heat loss to surroundings. In
experiment 1, a copper rod is used and the ice melts in 20 min. In experiment 2, a steel
rod is used and ice melts in 60 min. How long would it take to melt the ice if the two rods
are used in series is 10x minutes find x.
ice +
water
water
100°C
0°C rod

5. A straight infinitely long cylinder of radius R0 = 10 cm is uniformly charged with a
surface charge density  = + 10–12 C/m2. The cylinder serves as a source of electrons, with
the velocity of the emitted electrons perpendicular to its surface. Minimum electron
velocity must be … × 105 m/s to ensure that electrons can move away, from the axis of the
cylinder to a distance greater than r = 103 m.
6. Two identical capacitors are connected as shown and having initial charge Q0. Separation
between plates of each capacitor is d0. Suddenly the left plate of upper capacitor and right
plate of lower capacitor start moving with speed v towards left while other plate of each
capacitor remains fixed.
(given Q0V
= 10 amp). The value of current (in amp) in the circuit is..............× 4 ampere.
2d0
Q0
V
V
Q0
7. A satellite is revolving round the earth in a circular orbit of radius ‘a’ with velocity v0. A
particle is projected from satellite in a forward direction with relative velocity v  5 
 
=  4 –1 
 
v0. Then it is found that the maximum distance of particle from earth's centre is na
. Then
3
the value of n is
8. Each resistance is of 2. Current in resistance R (R = 2) is (x + 9.75) ampere find x.
2 50V 2
2 2
2 R 2
2 2
i i
100V

SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer, out of which
ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
9. One mole of an ideal gas undergoes a process P = P0
. Here P0 and V0 are
1 (3V0 / V)2
constants. Volume is changed from V = V0 to V = 3V0 –
A) temperature of gas when its volume is 3V0 is 3P0V0

2R
B) temperature of gas when its volume is V0 is P0V

0
10R
C) change in temperature is 5P0V0/8R
D) temperature remains constant
10. A spherical shell has inner and outer radius R1 and R2 respectively. Inner surface is
maintained at temperature 5T0 while outer surface is maintained at temperature T 0.
Thermal conductivity is K, then –
A) Temperature gradient decrease in radially outward direction
B) Isothermal surface will be spherical
C) Temperature of mid-point of shell 5R 2  R1

R1  R 2 T0
D) Heat flown in time t 4 (R 2 – R1 )KT0

is R1R 2
. t
11. A vessel is partly filled with liquid. When the vessel is cooled to a lower temperature, the
space in the vessel, unoccupied by the liquid remains constant. Then the volume of the
liquid (VL), volume of the vessel (Vv), the coefficients of cubical expansion of the
material of the vessel (V) and of the liquid (L) are related as -
A) L > V B) L < V C) V/L = VV/VL D) V/L = VL/VV

12. 1 kg of ice at 0°C is mixed with 1.5 kg of water at 45°C [Latent Heat of fusion = 80
cal/gm & specific heat of water = 1 cal/gm°C] then -
A) Temperature of mixture is 0°C B) Temperature of mixture is 15°C
C) Mixture contains 156.25 gm of ice D) Mixture contains 843.75 gm of ice
13. Two identical conducting balls have positive charges q1 & q2 respectively. The balls are
brought together so that they touch and then put back in their original positions. The force
between the balls may be –
A) remain same as it was before the balls touched

B) greater than before the balls touched
C) less than before the balls touched
D) zero
14. A parallel plate air capacitor is connected to a battery. If plates of the capacitor are pulled
further apart, then which of the following statements are correct ?
A) Strength of electric field inside the capacitor remain unchanged, if battery is

disconnected before pulling the plate.
B) During the process, work is done by an external agent to pull the plates whether battery
is disconnected or it remain connected.
C) Potential energy in the capacitor decreases if the battery remains connected

during pulling plates apart.
D) None of the above
15. A double star in a system of two stars of masses m and 2m, rotating about their centre of
mass only under their mutual gravitational attraction. If r is the separation between these
two stars then their time period of rotation about their centre of mass will be proportional
to-
A) r3/2 B) r C) m1/2 D) m–1/2

16. The internal resistance of the cell shown in the figure is negligible then on closing the key
K, the ammeter reading changes from 0.25 amp to 5/12 amp, then which options is/are
correct –
K R1
R = 10 
E
A
ideal
ammeter
A) R1 = 10
B) R1 = 15
C) power drawn from the cell increases
D) the current through R decreases by 40%
SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a paragraph. Each
question has 4 choices A), B), C) and D) for its answer, out of which ONE OR MORE is/are correct.
Paragraph for Question Nos. 17 & 18:
Consider the (P - T) graph shown in the figure. The pressure varies two times within the
cycle The heat received by the gas in process 1-2 is equal to the heat received in process
3-4. The process is done on one mole of monoatomic gas.
P
1 2
3 4
T0 T

17. For the given process –
A) Heat released is 0.5 RT0 in process (2 – 3)
B)Heat released is RT0 in process (2 – 3)
C) Work done is zero in process (2 – 3)
D) Woerk done is zero in process (4 – 1)
18. Choose the correct indicator diagram for the process –

T T P P 1 2
1 1 2
1 2
3
A) B) C) D) 3
4 4 3 3 4 4
2
V V V V

A large parallel plate capacitor with uniform surface charge  on the upper plate & – 
on the lower is moving with a constant speed V as shown in figure.
+ V
–
V
19. Magnetic field between the plates is –
A) Parallel to the plates and perpendicular to velocity
B)Parallel to velocity and perpendicular to plates
0V
C) 2 D) 0V
20. Magnetic force per unit area on the upper plate, including its direction –
A) 02V2 B) 2 2
0 v
C) Upwards D) Downward
2

CHEMISTRY Max Marks : 80
SECTION – I
21. Consider the given two molecules
If [X] is the position of –OH group in [I] and[Y] is the position of –Cl group in [II] then
what is the value of [X] +[Y] (Take all the positions as per IUPAC rules)
22. The total number of enantiomeric pairs possible with molecular formula C5H12O is?
23. How many of the following compounds are more basic than aniline?
24. Choose the appropriate reagent sequence from the given reagents pool to complete the
synthetic conversation. Make sure to use strictly four reagents, not more not less.
Note: you can simply mention the numerical values corresponding to the reagents in the
boxes P, Q, R, S, respectively and aslo consider major organic product in each step.
What is the value of [P + Q + R –S]

25. Consider the major organic product formed in the given reaction, If [X] is the total
number of double bonds which are in conjugation in major organic product then value of
[X]?
26. If [X] is the number of isomeric alkynes with molecular formula C6H10 that can produce
methane with CH3MgBr, then what is value of [X]?
27. Number of -Cl atoms present in the Major organic product obtained in given reaction is?
28. How many of them are more acidic than

SECTION – II
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer, out of
which ONE OR MORE than ONE option can be correct.
29. Which among the following path b is better than path a to achieve target molecule
A)
B)
C)
D)
30. Choose the correct statement (s) about the given conversion
A) Conversion of [P] to [Q] involves crossed cannizzaro reaction.
B) Conversion of [P] to [Q] involves crossed aldol reaction.
C) Compound [Q] has a chiral centre
D) Compound [Q] has a hemiacetal linkage

31. Which among the following reagent(s) can convert pentanol to pentanal
A) Cu /573 K B) Alkaline KMnO4
C) PCC in dichloro methane D) anhydrous CrO3
32. Choose the correct statement regarding major organic product obtained in the given
reaction
A) Tertiary alcoholic group present in [P]

B) There is a one chiral centre present in [P]
C) Reactant and product [P] are isomers
D) During this reaction mechanism hydroxyl group is the one which protonated first
33. Which of the following is/are correct regarding nucleophilic substitution reaction?
A)
B)
C)
D)
34. The correct statement(s) for the following addition reactions is (are)
i) ii)
A) (M and O) and (N and P) are two pairs of diastereomers
B) Bromination proceeds through trans-addition in both the reactions
C) O and P are identical molecules
D) (M and O) and (N and P) are two pairs of enantiomers

35. Which among the given reactions can yield the tribromo phenol as a major product?
A) B)
NO2
Br Br
1.aq. KOH
2. H+
C) D) Br
36. Which of the following reactions cannot produce propane as a major product?
A) B)
C) D)
SECTION – III
(PARAGRAPH TYPE)
Observe the scheme of the reaction and answer the following questions
37. Choose the correct statement (s) regarding [P]
A) [P] can give positive 2,4-DNP test B) [P] is an isomer of [T]
C) [P] can give positive fehiling test D) [P] can give positive iodoform test

38. Choose the correct statement (s) regarding [Q]
A) Number of stereoisomers possible for Q is 2
B) [Q] can produce 4 stereoisomers on reaction with NH2OH
C) [Q] is a functional isomer of [T]
D) [Q] can also obtained by aldol reaction of acetaldehyde with dil NaOH.
39. Choose the correct option (s) among the given?
A) B)
C) D)
40. Choose the correct option regarding [X]
A) B)
C) D)

MJATHEMATICS Max Marks : 80
SECTION – I


1 cos1 tan  x  x
1 
  sin n  n  8n x 
 
    n 2
41. If f  x   lim 4  0, x  , is continuous at

x2  x 1  x
n
n

 k, x0

x = 0 then find the value of  k  2 .
a x
2
 1  2  3   99  
 
42. Let f  x   ,a1 = f  100   f  100   f  100   ....  f  100   .dx  k 11 then k
a x  a and
0         
43. Let f : 0,   0, be a function differentiable at 3 and satisfying f(3) = 3f ' 3 . If the

   

  3  x
f3x
value of lim   is L then [L] is (where [.] is greatest integer function)


x
 f 3 
 
 
3 
44. The value of 4
cos x is equal to  then k = ……
 1 cos x dx k
2

4
45. If F(x) =
1 x1 x  x2 1 x  x2   x2 
 then find the value of [F(99) – F(3)].
dx1 2x  3x  4x  3x  2x  x
2 3 4 5 6
Note : [k] denotes greatest integer less than or equal to k]
46. Let g:R 

be a function given by gx  x3 f 't   2 x2f ''t   4x f 0  6 4, x  R
4
 f  t   2dt, 0  x  6
x
and h(x) is defined as h  x    0 12


 
2
 x  6  20, 6  x 

. If number of integers in the range of
N
h(x) is N then, the value of .
19

1 3
47. If the area bounded by y  f  x  , x  , x  and x – axis is A sq. units where
2 2
2 24 246
f  x   x  x3  x5  x7  ...., x  1; then the value of [4 A] is (where [.] is G.I.F)
3 35 357
1 cos x 
n 4
4
 ex
48. If f  x  lim where x4 0, then the total number of points of
1 1 cos x 
n n

4
2
discontinuity of f(x) is
SECTION – II
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer, out of which
ONE OR MORE than ONE option can be correct.
49. Let f(x) is a differentiable function such that for every u, v  R
2u f u  v2  v3  u4v  2v f u2  v u3  consider the curve P defined by
uv4
1
P : f  x  y  x  y  

2f
xy , then 
2
4
A) Area bounded by curve P with coordinate axis is
4
B) Range of the function f(x) is R

C) Number of normals which can be drawn from point (1, 1) to the curve P will be 4
D) Length of tangent drawn from origin to the curve P is 1
50. let f(x) be a non constant twice differentiable function defined on R such that f(8 + x) =
f(2 – x) also 3

f '1  f '  f '  7   f '8  0 . Then which of the following is/are correct ?
 
2

A) f(-2) = f(12)
`B) /8
 f 5  x  tan 4x dx  0
/8
C) 2 10
2f 2  x2cosx dx 6  f 10  x2cosx dx

D) Minimum number of roots of the equation
f '  x  f '''x   f ''  x    are 14
2
0

51. Let f:0,1  [0, be a differentiable function so that f 'x is decreasing function;
)
1
dx
f(0) = 0, f '1  0, f '  0   0 I then which of the following is
1 f 2  x 
and 0
dx
INCORRECT ?
f
A)
1 I  B) f C) f D) f 1
I1 I1 I
f '1 f '1
f '1 f '1
52. Let the function f :R  be defined by f  x   x3  x2   x and let g : R  be an

R R
1sin x
arbitrary function. Let fg : R  R be the product function defined by (f g) (x) = f(x) g(x).
Then which of the following statement is/are TRUE ?
A) If g is continuous at x =1, then fg is differentiable at x = 1
B) If fg is differentiable at x = 1, then g is continuous at x = 1
C) If g is differentiable at x = 1, then fg is differentiable at x = 1
D) If fg is differentiable at x = 1, then g is differentiable at x = 1
53. If 1/

2017  2018  
n n
2018 2017
lim
n  is equal to ab where a, b  then a – b is equal to
N
n  
A) 2009 B) 1 C) -1 D) 0
  x
3
dy x4  3x2
 y________  4x  3ex is in the form y =
2
54. If the solution of the differential equation

1
dx   x 2 12 
 
f(x) (where f(0) = 1), then f(1) + f(-1) is
A) 2 e B) 3 C) 4 D) 6
e e e
55. Which of the following inequalities is/are TRUE ?
3 8
A) 1 x cos x dx  0
 A dull mind gets bored easily. A curious mind expands forever.

3 1 1 1
B) x sin x dx  2
 0
1
C) x2 cos D) x2 sin x dx 
0 10  9
x dx  2 0

  tan x 
1
56. If  is the value of
lim 1 tan x
10 10
tan x  e
10
1
1 1
1 and the range of the function
1 10

x0
e tan x
2 tan1 x
2
 1 2 


f x  2 2 2 is [a, b] then the value of   a  is
 b

3tan1 x  2 tan1 x
3   
A) 4 152  36 2 C) 4 152  40 2
2 B) 2  2 2 D) 2  27
27 2
[Note : Let e denote the base of the natural logarithm
SECTION – III
(PARAGRAPH TYPE)
A function f(x) having the following properties :
(i) f(x) is continuous except at x = 3
(ii) f(x) is differentiable except at x = -2 and x = 3

(iii) f  0   0, lim f  x   , lim f  x   3, lim f  x   0
x3 x x
(iv) f '  x   0x , 2   3,  and f '  x   0x 2, 3
(v) f ''x  0x , 2 2, and f ''x  0x 0, 3 3, 
0
57. The maximum possible number of solutions of f(x) = |x| is (are) greater than are equal to
….
A) 1 B) 2 C) 3 D) 4
58. If
f '  0   0 , the graph of function y f   x is non-differentiable at
= 
A) 2 points B) 3 points C) 4 points D) 5 points

Let F : R  R be a thrice differentiable function. Suppose that F(1) = 0, F(3) = -4 and

F 'x 
0
for all x 1 / 2, 3  . Let f(x) = xF(x) for all x  R .
59. The correct statement(s) is (are)
A) f '1  B) f(2) < 0

0
C) f '  x   0 for any x 1, D) f '  x   0 for some x 1,

3 3
3 3
60. If  x2F'  x  dx  12 and
1 1
 x3F''  x  dx  40 , then the correct expression(s) is
(are)
3
A) 9f '3  f '1  32  B)  f  x  dx 
0
12
3
C) 9f '3  f '1  32  D)  f  x  dx 
0
12

Sec: SR.IIT_CO-SC CTA-4 Date: 04-10-20
Time: 3HRS 2015_P2 Max. Marks: 240
KEY SHEET
PHYSICS
1 3 2 2 3 2 4 8 5 4
6 5 7 5 8 9 9 AB 10 ABCD
11 AD 12 AC 13 AB 14 ABC 15 AD
16 BC 17 BC 18 D 19 AD 20 BC
CHEMISTRY
21 4 22 4 23 4 24 3 25 5
26 5 27 6 28 0 29 AB 30 ABC
31 ACD 32 ABCD 33 A 34 AB 35 AC
36 BD 37 ABD 38 ABD 39 BCD 40 D
MATHEMATICS
41 3 42 9 43 2 44 2 45 3
46 3 47 1 48 4 49 AD 50 ABC
51 CD 52 AC 53 C 54 D 55 ABD
56 D 57 ABC 58 A 59 ABC 60 CD
Narayana IIT Academy 20-09-20_Sr.IIT_CO-SC _JEE-Adv_CTA-3_KEY&SOL
SOLUTIONS
PHYSICS
1. w = mwgh
7
Q = × mwgh
2
7
= × 74 × 9.8 × 1.2  3 × 103 J
2
n=3
2. P =  A e (30004 – 3004) = 2kW
3. x = 0t
x=2
4. When Cu rod is used
100
× 20 = m × L …..(1)
RCu
when stell rod is used
100
× 60 = mL ….(2)
R stell
when both are in series
Req = RCu × Rstell
100
× t = mL
RCu  R
stell
from (1) & (2)
RCu = 2000
mL
Rstell = 6000
mL
100 mL
t = mL
8000
t = 80 minutes
1
5. mv2 = e logn r
2 20 R
0
e log r
v
0 m R0
Q R0
= r
2R 0 
L
Q
= =  × 2R0  v = 2eR 0
L 0 m logR
3.7 × 105m/s or 4 × 105 m/s0
6. q1 q2

C1 C2
q1 + q2 = 2Q0
0 A 0 A
C1 = , C2 =
q1 d0  d0  Vt
Vt  d0  Vt 
d0  Vt
  q2 + q2   = 2Q0
q2 d0   d0  Vt
Vt 
Education consists mainly of what we have unlearned.

SR.IIT_CO-SC Page 2

 2d0 
 q2   = 2Q0
 d0  Vt

2Q0
 q2 =
2d0 (d0 + Vt)
dq2 Q 0V
I=  = 20 amp
dt d0
7. m ur = m (v0 + v) a
u GMe
5GMea
= 4r 2 as v0 = a
1 2 GMem 1 GMem
also mu – = m (v0 +v)2 –
2 r 2 a
8. At y according to Kirchoff's junction law
y  x y  x 100 y  50 y y  50
2  2  2 2  2 0
5y – 2x = 200 …(1)
similarly at x
50  x y …(2)
xi = 
2 2
at x + 100
x 100  50 x 100  …(3)
yi = 
2 2
we get y – 2x = 50 …(4)
from (1) and (4)
y = 37.5 V
So current through R is 18.75 A.
9. PV = nRT …(i)
P0
P=
 3V 2
1  0 
 V 
at V = 3V0
P
P= 0
2
Equation (i)
P0
. 3V0 = nRT
2
3P0V0
T  2R
when V = V0
P0
P= 2 P
 3V  = 100
2 0 
 V0 
P0
V0 = 1 × RT
10
P0V0
T  10R
SR.IIT_CO-SC Page 3

10.
R1
R2 dx
x
1 dx
dR = ... (i)
K 4x 2
 Thermal resistance of shell of inner radius ‘R1’ and outer radius ‘x’ is
1  1 1
R =
4    ... (ii)
K R1 x
From (i)
dR 1
dx  x 2
 Temperature gradient decrease with increase in x
dT 1
 dx  x
2
From (ii) resistance of shell from inner to the mid-point

1 
R 2  R1 
Rinner = 
 R )
4K R (R
 1 1 2 
and that of shell from mid-point to outer
1  R 2  R1 
Router = 4K  R (R  R ) 
 1 1 2 
Temperature of mid-point is given by,
5T0  T
T 5R 2  R1
= T0 T .T0
Rinner = R1  R 2
R outer
Thermal resistivity of shell is

R=  RR 
1 1 2
 
4K  R 2  R1 
 Heat flown in time t
Q 5T0  T0
R
= .t
4(R 2  R1 )KT0
= R1R 2
.t
11. VL = VV
 LVL = VVV or  L  VV
V VL

best VV > VL  L > V
SR.IIT_CO-SC Page 4

12. Heat lost by water
q  1500 × 1 × 45 = 67500 Cal
Let "m" gm of ice melts so,
m × 80 = 67500
m = 843.75
So amount of ice left = 1000 – 843.75
 156.25 gm.
13. If q1 = q2 = Q
Fi  q1q2  Fi  Q2
After touching new charges on each
ball is Q1  Q2 = 2Q = Q
2 2
Fnew  Q 2
 Fi = Fnew
if q1  q2
 q  q 2
Fnew =  1 2 
 2 
q12 q22 2q q
=  1 2
+
4 4 4
Fnew > Fi
14.
CV –CV
V
If battery is disconnected and plate are pulled apart, then charge will remain constant
Q
E= Q
2A ×2
0 A 0
=
E remain same (A) is correct
work is done against attractive force by Fext
+ –
Fele. Fext
(B) is correct
1
U = CV2
2
V = constant [as battery is connected]
 A
C = 0 as d increase, C decrease
d
 U decrease, option (C) is correct.
SR.IIT_CO-SC Page 5


15.
r2 r1
m 2m
r c.m. 
r2 = 2mr 2r
m  2m = 3
2
42r3
T2 = Gm2
2 322r3
T2 =
27Gm
T2  r3/2, T2  m–1/2
16. When K was open
Reading of E
A = amp = 0.25
10
when K was closed  E = 2.5 V
Reading of
A E(10  R1 ) 5
= 10R1
= 12
12 (5 + 0.5R1) = 10 R1
60 + 6R1 = 10R1  R1 = 15
power drawn
V2
=
Req
as Req decreases
power
V will increase
= 2
Req
current through R = 0.25 amp (initially)

after K is closed current through R = 0.25 amp
17. Q1  2 = Q3  4  Cp (T2 – T0) = Cp(T0 – T3)
2  3 Isochoric process  2T0 = T2 + T3
Q2  3 = Cv (T3 – T2) = – CvT3 = – RT0
 heat released = RT0
(P1 = P2 =2P3=2P, 2  3 isochoric T2 = P2 =2)
T3 P3
T3 = 2
3 T0
18. Conceptual

SR.IIT_CO-SC Page 6

19. Current per unit width (J) =
ℓ
b V
+
–
i
= b
+
A A

=
ℓb = V
tb
J = V
B due to both plate 0J
2
is Both are upward
 Bnet = 0J J
2 + 02
= 0 J
BNet = 0V
20. Magnetic force on upper plate area

ℓ
b dx i
x6
Jdx  0 J  ℓ
=
x0
 2
2
 0 J b ℓ
= 2
2 2
0 V b.ℓ
f= 2
force per unit area 2 2

 0  V b ℓ
=
2(ℓ b)
2 2
0 V
= 2 upward
SR.IIT_CO-SC Page 7


CHEMISTRY
21.
22.
OH OH O
OH
2 2 2
2
23.
24.
P=5
Q=2
R=4 O
S=8
1. CH3CH2CH2Cl, AlCl3 5. CH3Cl, AlCl3 9. CH3CH2Cl, AlCl3
2. NBS, ROOR, hv
6. H2O2, NaOH, H2O 10. PCC
3. BH3·THF 7. HBr
4. HC C 8. H2O, H2SO4, HgSO4

25.
SR.IIT_CO-SC Page 8


26.
27.
28. Conjugate acid base pair

concept 29.
30.
SR.IIT_CO-SC Page 9

31. To get an aldehyde from alcohol using chromium reagent always we should use dry solvent If there is
a water that will convert in to hydrate form will oxidize further CrO3 in anhydrous medium is used as
the oxidising agent for the isolation of aldehydes.
32.
33.
34. Br2 addition is anti addition

Cis will give racemic mixture; trans will give meso compound
35.
36.
SR.IIT_CO-SC Page 10

Q no 37, 38
Q. no 39 & 40
 
1 MATHS
 
 cos1 tan   x 
  4 
,x 0
41. f x   x2
 sin 4x
 , x0
 3 2
    

1 cos  1 tan   x  1 tan  4  x 
 
f 0   lim 4 1
lim 
 

x0 x2 2 x0 x2
1 4 tan2 x
 lim 2
2 x0 x2 1 tan x 
2
sin 4x 1
f 0   lim 2
x0 x

2
f 0  2  3

42. f(x) + f(1 – x) = 1
 1 2  1 1  1 99
f   ....f f 49 ....   49  
f 1  f 1 
      100 100 2 2
100  100 2 
         
2
99
.dx  99
 2
0
1
43. Let x 
t
1
lim 
 f 33tf 3   f '33t.3 
 f 3  3t t lim
  
lim 
e
 e
t0

tf  t0 f
 3 e 
3
t0
 f 3 
3/ 4 cos x
44. dx (k and A)
I
/ 4
1 cos x
2I  3/ 4 cos x  1 
1 dx
 1 

/ 4
 cos x 1 cos x 
3/  
4 cot2 x dx  2 2 
 
2I  2 
/ 4
 2

I2
2
45.
46. Since, g:R  4
 g(x) is constant function equal to 4.

 g(x) = 4
 x3 f 't   2 x2f ''t   4x f 0  6 4  4, x  R
f 't   2  0, f ''t   0, f 0  6  0
f(t) = 2t – 6
x2  8x; 0  x  4

 h  x   x2  8x  32; 4  x  6

x  6  20; 6  x  12
2
 Range of h(x) is [0, 56]

i.e., N = 57


47.  2 24 5  d
f '  x   1 x 2x  4x3  6x  ...  1 x xf  x    1 xf  x   x2f '  x 
 
 3 35  dx
1 x  f '  x   1 xf x

2
sin1 x
f x  , Now solve
1 x2

1 cos x 
n 4
4
 ex
48. f  x  lim
1 cos x 
n n
 4
1
1 ;1 cos x4  1
1 ex4 4
f x   ;1 cos x  1

2
e x
4
; 0  1 cos x4  1
1 ; cos x4  0
1 ex4 4
f x 
  ; cos x  0

2
e x
4
; 1  cos x4  0
1/ 4 1/ 4
  3 
Points are x =    ,   
2  2
49. 2u f u  v2  v3  u4v  2v f u2  v u3  uv4
Putting v = 0 we get
u2
2u f u   f u
3
2
u 
x2 1 xy
y
 Equation of curve P is xy 2
2 2 2
 x2  y2  2x  2y 1 
0
Which is a circle with center (1, 1) and radius 1
Hence touches both the coordinate axes therefore correct options are (A) and (D)
50. (A) f(8 + x) = f(2 – x)  f(x) is symmetric about the line x = 5.
f 2  f 12
/8 /8

(B)
 f 5  xtan 4x dx   f 5  xtan 4xdx  1  0
/8 /8

2
(C)
I  2 f  x  22cosx dx, put x  2  10  t
6
I  10f 10  t 2cost dt  RHS
(D)
f 8  x   f  2  x   f  x  is symmetric about the line x = 5
 f '1f '9  0, f '3 / 2  f '7 / 2  0
f '7  f '3  0, f '8  f '2  0 also f '5  0
 f '  x   0 has atleast 9 roots
 f ''  x   0 has atleast 8 roots
f 'xf ''x 
has atleast 17 roots
0
d / dx f 'f ''  x   0 has atleast 16 roots.
51. For
x [0,1], f '  x   f '1 (given condition in question)
f '1 f 'x
 f 2  x  1 f 2 x
1
dx
On integrating we get, f '11  tan1 f 1 tan1 f 0
 f 2  x  1
0
1
dx tan f 1 f 1
1
i.e.,  f 
0 f x 1
2
f '1
'1

 tan1  x for x  0
For equality to hold,

tan1 f 1  f 1
1
dx
i.e., f(1) = 0 then  f 2 x 1 
0
0 1 f 1
dx

which is not possible as this is a strictly positive function. 0 f 2 x 1
Hence, f '1
52. f:R
R f  x    x 2  sin x   x f 1   f 1   0
1
fg  x  : f  x  .g
fg : R  R
x
Let fg(x) = h(x) = f(x).g(x) h:RR
Option (c) h 'x  f 'xg x  f xg
'x h '1  f '1g 1  0,


(as f(1) = 0, g’(x) exists}
 if g(x) is differentiable then h(x) is also differentiable (true) option (A) If g(x) is continuous at x
= 1 then g 1   g 1   g 1
h 1 h  h 1
h'1 h0
lim 
h
f 1 hg 1 h  0

h'1 h0
lim  f '1g 1

h
f 1 hg 1 h  0
h'1  lim  f '1g 1
h0 h
So h(x) = f(x) . g(x) is differentiable
at x = 1 (True)
h 1 h   h 1
option (B) (D) h '1   lim
h0 h
f 1 h  g 1 h 

h '1   lim  f '  1 g  1 
h0 h
f 1 h  g 1 h 
h '1   lim  f '1.g 1   g 1   g 1 
h0 h
So we cannot comment on the continuity and differentiability of the function
1 1
 ln x 1 
53. Let f  x   xx  f '  x   x x  2 
 x 
If x > e then f(x) is decreasing
1 1
2017 2018
2018  2017  f 2018  f 2017  2018 2018  2017 2017  2018  2017
n
n1
 2018  
1
n  2018
2017
 
2017  lim 2017
2018 2017 2018
 lim n  n    2017
2018
   
 1 
2017 
2018
x n  
   
 x4 3x2 dx
 2 x3 x3 x3
54. I,F = x
   4x  3dx  f  x   y   2x 2  3x 1  e x
2
2 2 2
e  ex 1
 ye x 1 1
1 
 f 1  6 e & f 1  0  f 1  0
2 4
55. A) cos x  1 x  x  ....
2! 4!
3 5
sin x  x  x  x  ....
3! 5!

x2
cos x  1
2
1 1
 x2  1 1
 x cos x   x 1 2  2 8
0 0  
1
3
 x cos x 
8
True
0
x3
B) sin x  x 
6
1 1
 x3 
 x sin x  x  x  dx
6
0 0 
1 1
1 1 3
 x sin x     x sin x dx True)
0 3 30 0 8
1 1
x2 sin xdx  x2 x x dx
3
D)  6

0 0  
1
1 1
 x2 sin x dx  
0
4 36
1
2
x
2
sin x dx

True
9
0
C) cos x  1
x2 cos x  x2
1 1
x cos xdx   x2dx

2
0 0
1 1
x2 cos xdx 
 3
0
So option ‘C’ is incorrect.
   
1 10
 
10
ln1 tan1 x 1
1 tan x 
1 10
etan x   1
 
56.   lim e
x0
etan1 x10 


  
10
 
ln 1 tan1 x
 
 tan1 x  1 
 10 
10

1 tan x 
1
e
 
  1 1
  lim    1 
10
x0 x 2 2
 
Let tan1 x  t;  t
f t  2 2
2t2 2
3t2  2t2  3
f  t  |min  0
Also, f  t  
 2  f  t  |max 2
32 27

 2t   27

 t
57.
Maximum possible number of solutions = 3

58. y = f(-|x|)
Clearly non-differentiable at 2 points


59. F'  x   F  x   xF'  x 
f '1  F1  F'1  0  ive  ive
f  2   2F  2   0 as F(x) decreasing for x > 1
f '  x   F  x   xF'  x   0 x 1, 3
as F(x) < 0 for x > 1 and F’(x) = 0

3 2
60. 1 x F'  x  dx  12
3
1
 x2F  x 1  1 2x F  x  dx  12
3
9F3  F1  2 f xdx  12
1
3 3
36  2 f  x  dx  12   f  x  dx  12
1 1
1
x3F''xdx  40
3 3
 x3F'  x 1  1 3x2F'  x  dx  40
3 3
x2  xF'  x   1  31 x 2 F'  x  dx  40
9 f '3  F  3   1  f '1  F  1    312  40
 9f '3  f '1  32  0


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Sec: SR.

IIT_CO-SC Date: 04-10-20

Name of the Student: H.T. NO:

PHYSICS: PT-1 & PT-7 SYLLABUS ONLY

CHEMISTRY: PT-1 & PT-7 SYLLABUS ONLY

MATHEAMTICS: PT-1 & PT-7 SYLLABUS ONLY

SR.IIT_CO-SC Page. No. 2

A dull mind gets bored easily. A curious mind expands forever.

1. A cylinder contains 0.15 kg of hydrogen. The cylinder is closed by a piston supporting a

2. The emissivity of tungsten is approximately 0.35. A tungsten sphere 1 cm in radius is

SR.IIT_CO-SC Page. No. 3

A dull mind gets bored easily. A curious mind expands forever.

SR.IIT_CO-SC Page. No. 4

A dull mind gets bored easily. A curious mind expands forever.

constants. Volume is changed from V = V0 to V = 3V0 –

A) temperature of gas when its volume is 3V0 is 3P0V0

B) temperature of gas when its volume is V0 is P0V

D) temperature remains constant

A) Temperature gradient decrease in radially outward direction

B) Isothermal surface will be spherical

C) Temperature of mid-point of shell 5R 2  R1

D) Heat flown in time t 4 (R 2 – R1 )KT0

A) L > V B) L < V C) V/L = VV/VL D) V/L = VL/VV

SR.IIT_CO-SC Page. No. 5

A dull mind gets bored easily. A curious mind expands forever.

A) Temperature of mixture is 0°C B) Temperature of mixture is 15°C

C) Mixture contains 156.25 gm of ice D) Mixture contains 843.75 gm of ice

A) remain same as it was before the balls touched

A) Strength of electric field inside the capacitor remain unchanged, if battery is

C) Potential energy in the capacitor decreases if the battery remains connected

D) None of the above

A) r3/2 B) r C) m1/2 D) m–1/2

SR.IIT_CO-SC Page. No. 6

A dull mind gets bored easily. A curious mind expands forever.

C) power drawn from the cell increases

D) the current through R decreases by 40%

SR.IIT_CO-SC Page. No. 7

A dull mind gets bored easily. A curious mind expands forever.

A) Heat released is 0.5 RT0 in process (2 – 3)

B)Heat released is RT0 in process (2 – 3)

C) Work done is zero in process (2 – 3)

D) Woerk done is zero in process (4 – 1)

18. Choose the correct indicator diagram for the process –

Paragraph for Question Nos. 19 & 20:

19. Magnetic field between the plates is –

A) Parallel to the plates and perpendicular to velocity

B)Parallel to velocity and perpendicular to plates

SR.IIT_CO-SC Page. No. 8

SR.IIT_CO-SC Page. No. 9

A dull mind gets bored easily. A curious mind expands forever.

28. How many of them are more acidic than

SR.IIT_CO-SC Page. No. 10

A dull mind gets bored easily. A curious mind expands forever.

A) Conversion of [P] to [Q] involves crossed cannizzaro reaction.

B) Conversion of [P] to [Q] involves crossed aldol reaction.

C) Compound [Q] has a chiral centre

D) Compound [Q] has a hemiacetal linkage

SR.IIT_CO-SC Page. No. 11

A dull mind gets bored easily. A curious mind expands forever.

A) Tertiary alcoholic group present in [P]

A) (M and O) and (N and P) are two pairs of diastereomers

B) Bromination proceeds through trans-addition in both the reactions

C) O and P are identical molecules

D) (M and O) and (N and P) are two pairs of enantiomers