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MATHEMATICS

PART : I MATHEMATICS
SECTION-1 (Maximum Marks: 24)
 This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is (are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen,
both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and
it is acorrect option;
Zero Marks : 0 If unanswered;
Negative Marks : −2 In all other cases.
 For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct
answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 mark;
choosing ONLY (B) will get +1 mark;
choosing ONLY (D) will get +1 mark;
choosing no option(s) (i.e. the question is unanswered) will get 0 marks and choosing any other option(s)
will get −2 marks.

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MATHEMATICS
1. If f(x) and g(x) are two positive and increasing functions, then which of the following is NOT always
true?
(A)  f  x   (B) If  f  x  
g(x) g(x)
is increasing is decreasing, then f(x) < 1

(C) If  f  x   (D) If f(x) > 1, then  f  x  


g(x) g(x)
is increasing, then f(x) > 1 is increasing.

2. Consider two curves y = x – ax2 , ay = x2, where ‘’a’’ is aparameter which of the following are True?
(A) Area bounded by curves is maximum when a = –1,0,1
1
(B) Maximum area by curves is
24
1
(C) If a =–1 then area by curves is
24
(D) Minimum area is obtained when a = –1.

33 33 49
3. If  = 
r 0
33
Cr , m = 
r 0
66
C 2r , n = 
r 0
99
Cr . Then which of the following is/are true ?

299 – 2
(A) n = (B)  2 = 2m (C) n = 2m (D) n = m
3

4. If 1, z1, z2, ..., zn-1 are the nth roots of unity, then
1 1 1 n.3n 1 1
(A)   .........  = n 
3  z1 3  z 2 3  zn 1 3 1 2
(B) (2 – z1) (2 – z2)........(2 – zn – 1) = 2n –1
(C) z1 + z2+……...+ zn –1 = –1
1 1 1 n.3n1
(D)   .........  = n 1
3  z1 3  z 2 3  zn 1 3 1

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MATHEMATICS
5. There are 10 seats in the first row of a theatre of which 4 are to be occupied. The number of ways of
arranging 4 persons so that no two persons sit side by side is:
(A) 7C4 (B) 4. 7P3 (C) 7C3. 4 ! (D) 840

6. An equilateral triangle ABC is inscribed in the parabola y = x 2 and one of the sides of the equilateral
triangle has the gradient 2. If the sum of x-coordinates of all the vertices of the triangle is expressed in
p
the form of (where p & q are co prime natural number), then the value of |p – q| is not equal to
q
(A) 6 (B) 2 (C) 4 (D) 8

SECTION 2 (Maximum Marks: 12)


 This section contains THREE (03) question stems.
 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For Online:
For each question, enter the correct numerical value corresponding to the answer in the designated place
using the mouse and the on-screen virtual numeric keypad. If the numerical value has more than two
decimal places, truncate/round-off the value to TWO decimal places.
 For Offline:
If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal
places.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.
Paragraph for Question Nos. 7 to 8

 1
x
Int
Let F(x) = f(x) – f   , where f(x) =
x
 1 t  t
1
2
dt,  x 1. Then

7. F(e) =

8. F(nx) =

Space for Rough Work

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MATHEMATICS
Paragraph for Question Nos. 9 to 10
dy x(x 2  3y 2 )
The solution of the differential equation,   0 is xa + yb + 6xdyd = c
dx y(y 2  3x 2 )
9. a + b is

10. d is

Paragraph for Question Nos. 11 to 12


 tan 2 x
 2 for x  0
 x   x

2
 
Given a real valued function f such that f  x   
 where [x] is the integral part and
 x cot x for x  0




{x} is the fractional part of x, then

11. lim f  x   1
equals is
x0

12. cot 1  lim f  x    1


 x0 

SECTION 3 (Maximum Marks: 12)


 This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases.

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MATHEMATICS
Paragraph for Question Nos. 13 to 14

There are 4 boxes A1, A2, A3 and A4. Box Ai contains exactly i cards each bearing a number from the
set {1, 2, 3, ....., i}. No two cards from the same box bear same number. A box is selected at random,
the probability of selection of box Ai  i. Now from the selected box a card is drawn randomly, let Ei
be the event that the card selected bears the number i, then

13. The probability that the card drawn bears the number 2 is
4 2 3 4
(A) (B) (C) (D)
5 5 10 10

14. If the drawn card bears the number 1, then probability that the card was drawn from box A 3 is
1 1 2 1
(A) (B) (C) (D)
2 4 3 3

Paragraph for Question Nos. 15 to 16


/2
1  sin2x a
If
 (1  sin2x)
0
2
dx 
b
where a, b are relatively prime & tangent to the curve y = a – xb

(0 < x < 1) meets co-ordinate axes at A & B such that area of triangle AOB is minimum (Where O is
origin). If minimum area of AOB is c and point of tangency is (d, e) for minimum area, then

15. a + b equal to
(A) 1 (B) 2 (C) 3 (D) 4

16. c equals
5 5 5 5
c 3.2
(A) 3
(B) 4 . 23 (C) 5 . 23 (D) 6 . 23

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MATHEMATICS
SECTION–4: (Maximum Marks: 12)
 This section contains THREE (03) questions.
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, BOTH INCLUSIVE.
 For Online:
For each question, enter the correct numerical value of the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter the answer.
 For Offline:
For each question, fill the correct numerical value of the answer in the place designated to enter the
answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct numerical value is entered;
Zero Marks : 0 In all other cases.

x 7 y 5 z3 x 1 y  1 z  1
17. Consider the lines L1 :   and L2 :   . A line L whose direction ratios are 2,
3 2 1 2 4 3
2, and 1 intersect the lines L1 and L2 at A and B. If the distance between A and B is , then find the
 4  1
value of   – .
 4  4
 

18. Two circle of radii 'a' and 'b' touching externally are inscribed in area bounded by y = 1 x 2 and x
1 1
axis. If b = and a = , then k is
2 k

19. Let f(x.y) = f(x) + f(y); x > 0, y > 0 and f(e) = 2. If the area bounded by the curves y = f(x),
 b 
x = 2 and x-axis is a n   then value a2 + b2 .
 e 

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PHYSICS
PART : II PHYSICS
SECTION-1 (Maximum Marks: 24)
 This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is (are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both
of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If unanswered;
Negative Marks : −2 In all other cases.
 For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct
answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 mark;
choosing ONLY (B) will get +1 mark;
choosing ONLY (D) will get +1 mark;
choosing no option(s) (i.e. the question is unanswered) will get 0 marks and choosing any other option(s)
will get −2 marks.

20. The centres of spheres 1,2 and 3 lie on single straight line. sphere 1 is moving with an (initial) velocity
(v1) directed along this line and hits sphere 2. sphere 2 , according after collision a velocity v 2, hits
sphere 3. Both collision are absolutely elastic, then chose corrects statement(s), if velocity acquire by
m3 after collision to m2 is v3

1 2 3
Space
v1 for Rough Work

m1
(A) value of m2 corresponds to maximum value of v3 is m2 = m1m3 IF m1 and m3 is known.
(B) If m1 >>m3 and m1 >> m2 then v3= 4v1
(C) If m1 = m2 in this case m 2 = m1 = m3 and v3 = v1
4v 1m1
(D) If m1 << m3 assuming that m 2 >> m1, we get v3 =
m3

Space for Rough Work

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PHYSICS
21. A box contains L, C and R, when 250 v DC is applies to the terminals of the box, a current of 1A flows
in the circuit. when an AC source of 250 v rms at 2250 rad/s is connected a current of 1.25 A rms flows
it is obsered that current rises with frequency and becomes maximum at 4500 rad/s Then which
statements are correct
(A) R,C,L are in series haring R = 250 , C = 1F and L = 0.049H
(B) C and L are in series and is connected with R in parallel
(C) R = 250 C 1F, L = 49 H
(D) R = 250 , C = 1F , L = 0.049H

22. U frame ABCD and a sliding rod PQ of resistance R, starts moving with velocities v and 2v respectively,
parallel to a long wire carrying current i0 when distance AP =  at t = 0 then just before connecting rod
PQ 10 loses contact with 'U' frame.
A B

2V

i0
P R Q

V
L
D C

a a
(A) current flows in the circuit in anticlockwise direction
(B) current flows in the circuit in clockwise direction
e
(C) current growth at any time t in LR circuit is given by i = (1 + e–tR/L)
R
(D) If VP represent potent in at point then VP > VQ while VD < VC

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PHYSICS
23. An adiabatic cylinder has 8g of helium. A light smooth adiabatic piston is connected to a light spring of

force constant 300 N/m. The other end of spring is connected with block of mass 10 kg kept on rough

horizontal surface of cofficient of friction  = 0.3. Area of cross section of cylinder is A = 25 cm 2. Initially

spring is in a relax position and temperature of gas is 400 k, the gas is heated slowly for some time by

mears of an electric heater so as block M just starts moving. If W is work done by gas, Tf is final

temperature and H is heat supplied by the heater, g = 10 m/s 2 1 atm = 105 N/m2 then

(A) Tf = 449.6 K and H = 1265 J, W = 26.5 J

(B) W = 26.5 J, TF = 440 K, H = 1400J

(C) Block start moving when compression in spring is 0.1m

(D) W = 25 J, TF = 449.6 K, H = 1265 J

Space for Rough Work

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PHYSICS
24. P and Q are infinite conducting plates kept parallel to each other and separated by distance 2r.
A conducting ring of radius r falls vertically between plsnes such that planes are always tangent to the
ring. Both the planes are connected by resistance R. there exists a uniform magnetic field of strength B
perpendicular to the plane of ring. The arrangement is shown in figure, plane Q is smooth and friction
between plane P and the ring is enough to prerent slipping
At T = 0 the ring was at rest and neglect the. resistance of planes and the ring if i is current in R at any
time t and teminal velocity of ring is v then

P R Q

2r

   2B 2r 2  
 .t  
   2B 2r 2  
 .t  
mgR   mR


 mgR   mR 
(A) v = 2 2
 1  e  (B) v = 2 2 1  e  

4B r   B r  
   
   2B 2r 2  
 .t  
   2B 2r 2  
 .t  
mg   mR  mg   mR 
(C) i = 1  e  
 (D) i = 1  e  

2Br   1Br  
   

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PHYSICS
25. In the arrangement all the pulleys are smooth and massless. When system is released from rest

acceleration of block 2 and 3 relative to 1 are 1m/s 2 and 5m/s2 downwards respectively. Acceleration of

block 3 relative to 4 is zero. a1, a2 a3 , a4 are absolute acceleration of block 1 , 2, 3, and 4 respectively

then

2 3

(A) a1 = 2 m/s2 (up), a2 = 1ms2 (up)

(B) a3 = 3m/s2 (down) , a4 = 3 m/s2 (down)

(C) a1 = 2 m/s2 (up) , (a2 = 1m/s2 (up) , a3 = 3 m/s2 (up)

(D) a2 = 1m/s2 (up) , a3 = 3m/s2 (down) a4 = 3 m/s2 (down)

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PHYSICS
W

SECTION 2 (Maximum Marks: 12)


 This section contains THREE (03) question stems.
 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For Online:
For each question, enter the correct numerical value corresponding to the answer in the designated place
using the mouse and the on-screen virtual numeric keypad. If the numerical value has more than two
decimal places, truncate/round-off the value to TWO decimal places.
 For Offline:
If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal
places.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.

Paragraph for Question Nos. 26 to 27


Question Stem
A rod AB of mass 3m and length 4a is falling freely in a horizontal position and C is a point distant a
from A. when the speed of rod is a, the point C collides with a particle of mass m which is moving
vertically upward with speed u. If impact between particle and rod is perfectly elastic

C G
A B
u u
m
m
26. If speed of particle after collision is  u then (m + n) is ––––––
n
x
27. If speed of rod centre of mass is  u after collision then (y -x) is –––––
y

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PHYSICS
Paragraph for Question Nos. 28 to 29
Question Stem
A solution contains a mixture of two isotopes A (half life = 10 days) and B (half life = 5 days). Total
activity of maxture is 1010 dps at time t = 0, the activity reduces to 20% in 20 days

28. If initial activity of A is (x × 109) dps then x is

29. Ratio of initial number of nuclei of A and B.

Paragraph for Question Nos. 30 to 31


Question Stem
One mole of diatomic ideal gas ( = 1.4) is taken through a cyclic process starting from point A The
process A  B is an adiabatic compression,
B  C is isobaric expansion, C  D is adiabatic exparsion and D  A is isochoric.
If volume ratios VA /VB = 16 and VC / VB = 2 and
temperature at A is TA = 300 K

30. Temperature B is (abc) kelvin then a + b+ c is –––––

31. Temperature at C is (xywz) kelvin then x + y + z + w is ––––

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PHYSICS
SECTION 3 (Maximum Marks: 12)
 This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases.

Paragraph for Question Nos. 32 to 33


In the following R–C circuit the capacitor is in the steady state. The initial seperation of capacitor plate
is x0. if at t = 0 separation between plates starts changing so that a constant current flows through R.

C R

+ –
i E
A is area of plate of capacitor, i is steady current flow

32. Velocity of moving plates as a function of time


   
   
i / 0 A  1  i / 0 A  1 
(A)   (B)  
iR  E   i /  A  2
1  iR  E   i /  A  2
1 
  E  iR t  x     E  iR t  x  
0 0

   0     0 

   
   
i / 0 A  1  0 A 
Space for Roughi / Work 1 
(C) (D)
iR  E   i /  0 A  1  iR  E   i /  0 A  1 
  t    t  
  E  iR  x 0    E  iR  x 0 

33. Separation 'x' of moving plate as a function of time.


1 1 i/  A  1 1 i/  A 
(A)  +  0  t (B)  –  0  t
x x0  E  iR  x x 0  E  iR 
1 1 i/  A  1 1  i /  0 A 
(C)  +  0  t (D)  + t
x x0  E  iR  x x 0  E  iR 

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PHYSICS
Paragraph for Question Nos. 34 to 35
The arrangement shown in figure consists of two identical uniform solid cylinders each of mass m on

which two light threads are wounds symmetrically then chose the correct statement (s), negleet friction

in axis of upper cylinder

34. Tension of each thread in process of rotation.

(A) mg/5 (B) mg/10 (C) mg/20 (D) mg/2

35. acceleration of the lower cylinder

(A) 2g/5

(B) 3g/5

(C) 4g/5

(D) g/5

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PHYSICS
SECTION–4: (Maximum Marks: 12)
 This section contains THREE (03) questions.
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, BOTH INCLUSIVE.
 For Online:
For each question, enter the correct numerical value of the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter the answer.
 For Offline:
For each question, fill the correct numerical value of the answer in the place designated to enter the
answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct numerical value is entered;
Zero Marks : 0 In all other cases.

36. A glass tube with length  = 50 cm and a cross section a = 0.5 cm 2 is soldered at one end and is
submerged into water [ = 1000 kg/m3] as shown if a force of F = 8.5 × 10–2 N is applied hold the tube
under the water if distance from the surface of water to be soldered end is 'h' cm and atm
p0 = 1.01 × 105 N/m2. The weight of tube is 1.47 × 10–1N
Take = 9.8 m/s2. Assume temperature of gas inside tube remains constant the value of 'h' is ab (two
digit number) then (a + b) has value.



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PHYSICS
37. A metal rod of length 1m is clamped at two points as shown. Distance of the clamp from two ends are

5 cm and 15 cm respectively. The minimum frequency of natural longitudral oscillation in KHZ is

(x × 10) then x is :

Given that young's modulus of elasticity and density of metal are Y = 1.6 × 10 11 Nm–2 and  = 2500kg

m–3 respectively

P g
R S
80 cm 15 cm
5cm

38. Two blocks of masses m and M are connected by a chord passing around a frictionleis pulley which is

attached to a rotating frame, which rotates about vertical axis with an angular velocity w. If cofficient of

friction between two masses and surface be 1 and 2 respectively then value of w at which block starts

sliding radially if. 1= 0.1

2 = 0.3, m= 10 kg, M = 30 kg, r2 = 4 m, r1 = 2m, g = 10 m/s2

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CHEMISTRY
PART : III CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
SECTION-1 (Maximum Marks: 24)
 This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is (are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both
of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If unanswered;
Negative Marks : −2 In all other cases.
 For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct
answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 mark;
choosing ONLY (B) will get +1 mark;
choosing ONLY (D) will get +1 mark;
choosing no option(s) (i.e. the question is unanswered) will get 0 marks and choosing any other option(s)
will get −2 marks.

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P2-01JP-JPT2-210523-C1 18
CHEMISTRY
r  2 2
39. A hypothetical solid A+B– has A  then correct statement(s) is/are :
R  2
B
(A) B– touches total 18 ions
(B) A+ touches total 6 ions
(C) Each body diagonal passes through the centre of 2 cations and 1 anion of a unit cell.
(D) Each body diagonal passes through the centre of 2 anions and 1 cation of a unit cell.

40. Choose the correct option(s) for following molecule in view of chemical bonding:
Cl H
C=C=C=C
H Cl

(A) Non-Planar (B)   0


(C) Planar (D)  = 0

41. An amount of 0.2 mol of each A2(g) and B2(g) is introduced in a sealed flask and heated to 2000 K then
following equilibrium is established : A2(g) + B2(g) 2AB(g)
At equilibrium moles of AB is 0.3 mol At this stage 0.1 mol of C2(g) is added and a new equilibrium is
also established as : A2(g) + C2(g) 2AC(g)
At the new equilibrium the moles of AB(g) becomes 0.24 mol.
(A) Equilibrium constant for first reaction is 36
(B) Equilibrium constant for first reaction is 32
(C) Equilibrium constant for second reaction is 16
(D) Equilibrium constant for second reaction is 18

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CHEMISTRY
42. The radial probability distribution function [P(r)] is used to determine the most probable radius, which is
dP(r )
used to find the electron in a given orbital. for 1s-orbital of hydrogen like species having atomic
dr
number Z is :
dP 4Z 3  2Zr 2  2Zr / a0
 3 2r  e
dr a0  a0 
dP(r )
(A) At the point of maximum value of radial probability distribution function 0
dr
a
(B) Most probable radius of Li2+ is 0
3
a
(C) Most probable radius of He+ is 0
2
(D) None of these

43. Which of the following is/are correct order:


O O
(A) Ph—C—CH2—C—CH3 (% enol)

(B) (Acidic strength)

(C) Phenol > m-cresol > p-cresol > o-cresol (acidic strength)

(D) > Et3N (Basic strength)


N
Space for Rough Work
Triethylamine
Quinuclidene
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CHEMISTRY
44. Observe the following reaction
O
(1) CH3–C–Cl/AlCl3 NBS/ NaOH MnO2/
X Y Z W
(2) Zn-Hg/HCl

Choose the correct options


(A) W gives +ve test with 2,4-DNP (B) W gives +ve test with tollens reagent
(C) W gives iodoform with I2/NaOH (D) W is acetophenone
W

SECTION 2 (Maximum Marks: 12)

 This section contains THREE (03) question stems.


 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For Online:
For each question, enter the correct numerical value corresponding to the answer in the designated place
using the mouse and the on-screen virtual numeric keypad. If the numerical value has more than two
decimal places, truncate/round-off the value to TWO decimal places.
 For Offline:
If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal
places.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.

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CHEMISTRY
Paragraph for Question Nos. 45 to 46
At 100° C a gaseous reaction A  B + 2C is observed to be of first order. On starting with pure A,
at the end of 10 minutes the total pressure was found to be 250 mm of Hg. After a long time the total
pressure of the system was 450 mm of Hg. Consider the volume and temperature to be constant.

45. The initial pressure of A is _________ × 101 mm Hg

46. The rate constant of the reaction given is_________ × 10–3 min–1.
[ln10 = 2.3, log 2 = 0.3, log 3 = 0.48]

Paragraph for Question Nos. 47 to 48



(i) P + Cl2  Q (ii) Q + H2O  R + HCl
(iii) BN + H2O  R + NH3  (iv) Q + LiAlH4  S + LiCl + AlCl3
(v) S + H2O  R + H2  (vi) S + NaH  T
(P, Q, R, S, and T do not represent their chemical symbols)

47. How many statement(s) are ture about compound Q.


(I) Compound Q has zero dipole moment
(II) Compound Q has a planar trigonal structure
(III) Compound Q has an electron deficient compound
(IV) Compound Q has a Lewis base

48. How many statement(s) is/are ture about compound T.


(I) Compound T is used as an oxidising agent
(II) Compound T is used as a complexing agent
(III) Compound T is used as a bleaching agent
(IV) Compound T is used as a reducing agent

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CHEMISTRY
Paragraph for Question Nos. 49 to 50
Consider the figure

mixture separation
of amino of amino
acids acids

filter paper
Buffer solution
Buffer solution (pH = 5.0)
(pH = 5.0)

(Electrophoresis) (After Electrophoresis)

pKa Values
S.No. Amino acids
side chain

1. Arginine 2.17 9.04 12.48

2. Alanine 2.34 9.69 ------

3. Aspartic acid 2.09 9.82 3.86

4. Lysine 2.18 8.95 10.79

5 Glutamic acid 2.19 9.67 4.25

6. Valine 2.32 9.62 ------

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CHEMISTRY
49. Number of non essential amino acids move towards cathod are.

50. Number of essential amino acids move towards anode are.

SECTION 3 (Maximum Marks: 12)


 This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases.

Paragraph for Question Nos. 51 to 52

(A) greenish salt soluble in water gives a greenish ppt with NH4OH. When this ppt is boiled with caustic
soda and bromine water (with Na2O2) a yellow solution is obtained. On addition of lead acetate and
acetic acid to the yellow solution a yellow ppt is formed.

51. The formula of greenish salt is


(A) Cr2(SO4)3 (B) Al2(SO4)3
(C) FeSO4 (D) None of these

52. Which of the following group reagent is used for identification of cationic part of (A) ?
(A) NH4Cl + NaOH (B) NH4Cl + NH4OH
(C) H2S gas in basic medium (D) None of these

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CHEMISTRY
Paragraph for Question Nos. 53 to 54
Consider the following reactions to answer the next two questions
Cl2/hv
x
Ph (1eq.)

Cl2/AlCl3
CH3 y

53. Major product X and Y are respectively

(A) (B)

(C) (D)

54. If product X is treated with AlCl3, it undergoes Friedel-Crafts reaction. The expected product is

(A) (B)

(C) (D)

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CHEMISTRY
SECTION–4: (Maximum Marks: 12)
 This section contains THREE (03) questions.
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, BOTH INCLUSIVE.
 For Online:
For each question, enter the correct numerical value of the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter the answer.
 For Offline:
For each question, fill the correct numerical value of the answer in the place designated to enter the
answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct numerical value is entered;
Zero Marks : 0 In all other cases.

55. 1 mol of each of the following acids exactly neutralize a maximum of how many moles of NaOH, under

required favourable conditions (Give your answer after dividing by 2) ?

HCl, HNO3, H2SO4, H2SO3, H3PO4, H3PO3, H3PO2,H4P2O5, H3BO3, H3P3O9

56. pH of 0.01 M ClC6H4NH3Cl is y. Find value of y/0.6 (Kb = 4×10–12, log 3.9 = 0.6).

57. How many meso compounds can be possible by C6H12Br2

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