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16-06-2024

2404CJA101002240003 JM

PHYSICS

SECTION - I

1) If distance of a particle is zero, the displacement covered :

(A) must be zero


(B) may or may not be zero
(C) cannot be zero
(D) depends upon the particle

2) A particle starts moving along x-axis, with constant velocity of 4 m/s. After 2 s from the start of
motion of the first particle, another particle starts in the same direction, with the same position with
constant velocity of 6 m/s. Calculate the time at which second particle will catch the first particle.

(A) 6 S
(B) 10 S
(C) 2 S
(D) 3 S

3) Mark the wrong statement:-

(A) Nothing is in the state of absolute rest or state of absolute motion.


(B) Magnitude of displacement is always equal to the distance travelled.
(C) Magnitude of displacement can never be greater than the distance travelled.
(D) Magnitude of instantaneous velocity is equal to the instantaneous speed.

4) An object thrown vertically up from the ground passes the height 5 m twice in an interval of 10 s.
What is its time of flight ?

(A)
(B)
(C)
(D)

5) A balloon starts rising from ground from rest with an upward acceleration 2 m/s2. Just after 1s, a
stone is dropped from it. The time taken by stone to strike the ground is nearly :-

(A) 0.3 s
(B) 0.7 s
(C) 1s
(D) 1.4 s
6) The water drops fall at regular intervals from a tap 5 m above the ground. The third drop is
leaving the tap at instant the first drop touches the ground. How far above the ground is the second
drop at that instant ? (Take g = 10 ms–2) :-

(A) 3.75 m
(B) 4.00 m
(C) 1.25 m
(D) 2.50 m

7) The position x of a particle varies with time (t) as x = at2 – bt3. The acceleration at time t of the
particle will be equal to zero, where t is equal to :-

(A) 2a/3b
(B) a/b
(C) a/3b
(D) zero

8) A train covers the first half of the distance between two stations at a speed of 40 km/h and the
other half at 60 km/h.
Then its average speed is :-

(A) 50 km/h
(B) 48 km/h
(C) 52 km/h
(D) 100 km/h

9) Two balls A and B are thrown with same speed u from the top of a tower. Ball A is thrown vertical
upwards and the ball B is thrown vertically downwards. If tA and tB are the respectively time taken by
the balls A and B to reach the ground then identify the correct statement :-

(A) tA > tB
(B) tA = tB
(C) tA < tB
(D) Cannot be interpreted

10) A stone is thrown upward with a speed 'u' from the top of the tower & it reaches the ground with
speed '3u'. The height of the tower is :-

(A)

(B)

(C)

(D)
11) If and the magnitude of and are 5, 4 and 3 units respectively, then angle
between and is :-

(A)

(B)

(C)

(D)

12) Which pair of the following forces will never give resultant force of 2 N :-

(A) 2 N and 2 N
(B) 1 N and 1 N
(C) 1 N and 3 N
(D) 1 N and 4 N

13) If and , the vector having the same magnitude as B and parallel to A is :-

(A)
(B)
(C)
(D)

14) If & = & is perpendicular to then find the value of α :-

(A) α = – 1
(B) α = 1
(C) α = 5
(D) α = – 5

15) If is a unit vector then c is :-

(A)
(B) 0.2
(C) 0.3
(D)

16) The resultant and makes an angle α with and β with . Then :-

(A) α > β
(B) α < β
(C) α > β if B > A
(D) α > β if B < A

17) Which of the following can not be a set of fundamental quantities?

(A) Mass, length, density


(B) Length, time, density
(C) Mass, time, density
(D) Time, volume, density

18) If the energy (E),velocity (u) and force (F) be taken as the fundamental quantity, then the
dimensions of mass will be :

(A) Fu–2
(B) Fu–1
(C) Eu–2
(D) Eu2

19) Choose the incorrect statement :-

(A) A dimensionally correct equation may be correct


(B) A dimensionally correct equation may be incorrect
(C) A dimensionally incorrect equation may be incorrect
(D) A dimensionally incorrect equation must be incorrect

20) In a particular system of units, length, mass and time are chosen to be 10 cm, 10 g and 0.1 s
respectively. The unit of force in this new system will be :-

(A) 0.1 N
(B) 1 N
(C) 10 N
(D) 100 N

SECTION - II

1) If the resultant of two forces of magnitudes P and Q acting at a point at an angle of 60° is

√7 Q, then P/Q is

2) Two forces and of magnitude each are inclined at an angle of 1.8° to each other.
What is the magnitude (in N) of vector ? (Take π2 = 10.)

3) Three vectors and are such that and . If the angle


between and is (in radians) then find the value of (α).

4) A bird starts flying with a speed of 10 m/s along a vector . If initial point of bird is (12m,
10m, 5m), then find the x coordinate (in m) after the 2 sec.

5) A truck moving with constant acceleration covers the distance between two points 180 m apart in
6 seconds. Its speed as it passes the second point is 45 m/s. Find its acceleration in m/s2?

6) A stone is dropped from a certain height and can reach the ground in 5 s. If during its fall, the
stone is stopped after 3 sec of the fall for a moment and is dropped again at once, then total time
taken to reach at ground will be ?

7) At time t = 0 s a car passes a point with velocity of 16 m/s and thereafter slows down with
acceleration a = –0.5t m/s2, where t is in seconds. It stops at the instant t =

8) A particle moves in east with velocity of 15 m/s for 2 sec. then moves northward with 5 m/s for 8
sec, then magnitude of average velocity (in m/s) of the particle is:

9) A balloon is going up with a velocity of 12 m/s. It releases a packet, when it is at a height of 65m
from the ground. How much time (in second) the packet will take to reach the ground if g =10 m/s2?

10) If x = 3t2 – t3 + 4t is position of particle moving along x axis then initial acceleration of particle
is.

CHEMISTRY

SECTION - I

1) The third Ionization energy is least for

(A) Nitrogen
(B) Phosphorus
(C) Aluminium
(D) Boron

2)

The correct order of Ionization energies of F–, Cl–, F and Cl is -

(A) Cl < F < Cl– < F–


(B) Cl– < F– < Cl < F
(C) F– < Cl– < Cl < F
(D) Cl– < Cl < F– < F

3) Identity CORRECT order according to their mentioned properties.

(A) Mn+2 > Mn+4 > Mn+6 (Ionisation potential)


(B) Li > B > Be (2nd Ionisation potential)
(C) B > Aℓ > Ga > Tℓ (atomic size)
(D) F > Cℓ > Br > I (electron affinity)

4) Identify the process which is not exothermic in the following

(A) N3–(g) → N(g)


(B) O2–(g) → O(g)
(C) Ca+2(g) → Ca(g)
(D) P–(g) → P+(g)

5) Radius of A = 1Å ; radius of B = 1.5Å, Assuming electronegativity of A and B to be same, bond


length of AB is.

(A) dA–B = 2.5Å


(B) dA–B > 2.5Å
(C) dA–B < 2.5Å
(D) None of these

6) The correct order of electron affinity is -

(A) Be < B < C < N


(B) Be < N < B < C
(C) N < Be < C < B
(D) N < C < B < Be

7) Outermost electronic configuration of the most electronegative element is :-

(A) ns2np3
(B) ns2np6
(C) ns2
(D) ns2np5

8) The correct order of most negative electron gain enthalpy is

(A) S > Se > Te > O


(B) Te > Se > S > O
(C) O > S > Se > Te
(D) S > O > Se > Te
9) Which of the following is correct order of EA.

(A) N < C < O < F


(B) F > Cl > Br > I
(C) Cl < F < Br < I
(D) C < N < O < F

10) Electron affinities of O,F,S and Cl are in the order.

(A) O < S < Cl < F


(B) O < S < F < Cl
(C) S < O < Cl < F
(D) S < O < F < Cl

11) Which of the following statement is correct ?

The elements having high negative electron gain enthalpy are generally behave like strong
(A)
oxidising agents.
(B) The element having low value of ionization enthalpies act as strong reducing agents
(C) The formation of S2–(g) from S(g) is an endothermic process
(D) All of these

12) Identify the incorrect statement

(A) Fe3+ has greater electron affinity than Fe2+


(B) Formation of Cl– from Cl(g) is more exothermic than formation of F– from F(g)

(C) IE1 of Cl = electron affinity of Cl
(D) Electronegativity depends only on electron affinity

13) Which will be the correct order of electronegativity ?

(A) I < Br < F < Cl


(B) F > Cl > Br > I
(C) I > Br > F > Cl
(D) F < Cl < Br < I

14) For Na+, Mg2+, F– and O2– ; the correct order of increasing ionic radii is :

(A) Mg2+ < Na+ < F– < O2–


(B) O2– < F– < Na+ < Mg2+
(C) Na+ < Mg2+ < F– < O2–
(D) Mg2+ < O2– < Na+ < F–

15) The atomic radius of Ag is closest to :

(A) Cu
(B) Hg
(C) Au
(D) Ni

16) If the ionisation energy and the electron affinity of an element are 5.1 eV & 2.7 eV respectively.
The Mullikan scale electronegativity is

(A) 5.1
(B) 2.7
(C) 7.8
(D) 3.9

17) The correct order of increasing atomic size of element N,F, Si & P.

(A) N < F < Si < P


(B) F > N < P < Si
(C) F < N < P < Si
(D) F < N < Si < P

18) From the given set of species, point out the species from each set having smallest Size
(a) O2–, F–, Na+ (b) Li, Be, Na (c) Li+, H–

(A) a-Na+ b-Be c-Li+


(B) a-O2– b-Li c-H–
(C) a-F– b-Na c-Li+
(D) a-Na+ b-Be c-H–

19) In a given energy level, the order of penetration effect of different orbitals is :

(A) f < p < d < s


(B) s < p < d < f
(C) f < d < p < s
(D) s = p = d = f

20) Which of the following order of radii is correct ?

(A) Li > Na
(B)
(C) F > Cl
(D) I < Br

SECTION - II

1) Number of elements having positive ΔHe.g. in the following set of elements are -
Li, Be, B , C, O, Ne, Mg
2) What is atomic number of element which has maximum electron affinity?

3) Which of the following has electronegativity greater than ‘O’ :-


S, N, Cl, Na, K, Fe, Mn, Y, Ac

4) The bond lengths of A – A and B – B bonds are 4.0 Å and 2.0 Å respectively if electron negativity of
A and B are 2.5 and 1.5 respectively, according to Schomaker and Stevenson’s equation the bond
length of A – B bond (in Å) should be .............

5)

Electronegativity of an element is 1.0 on the Pauling scale. Its value on Mulliken scale will be x ×
10–1. What is the value of x.

6)

What is the value of electron gain enthalpy of Na+ if IE1 of Na = 5.1 eV?

7) If the successive ionisation energy values for an element 'X' (belongs to 2nd period) are given
below :
IE1 = 1086 kJ / mol. ; IE2 = 2352 kJ / mol.
IE3 = 4625 kJ / mol. ; IE4 = 6222 kJ / mol.
IE5 = 37830 kJ / mol.
then the atomic number of element 'X' is :

8) How many pair/s are present below, in which first species has lower value of electron affinity than
second species:
(i) N and O (ii) O+ and S+
(iii) F+ and Cl+ (iv) I and I–
+ –
(v) Li and Li (vi) O and S

9) EN of Bromine is smaller than how many element among these.


Na, F, O, Cl, K, Ba, Ar, Kr

10)

Find the number of elements, whose E.N. on pauling scale is greater than 'B'

S , N , Cl , F , C , Al , Mg

MATHEMATICS

SECTION - I
1) If x – y = a and x2 + y2 = b, then the value of x3 – y3 is :

(A)

(B)

(C)

(D) a2 + b

2) The value of is

(A) a integer
(B) an irrational number
(C) a rational number which is not integer
(D) none of these

3) Let α and β are roots of quadratic equation x2 – 13x + 1 = 0, then value of is

(A) 13

(B)

(C) –13

(D)

4) Sum of the solutions of the equation |x – 1| + |x + 1| = 4 is

(A) 0
(B) 2
(C) –2
(D) 4

5) If the number M39048458N is divisible by both 8 and 11, where M & N are single digit integers,
then

(A) M = 4, N = 6
(B) M = 6, N = 4
(C) M – N = – 2
(D) None of these

6) The set of values of 'x' satisfying the inequality


(A)
(B)
(C)
(D) None of these

7) If x2 + y2 + z2 + 4 = 4z + 2xy where x, y, z are real numbers then:

(A) x = y = z
(B) x + y = 0, z = 2
(C) x = y, z = – 2
(D) x = y, z = 2

8) The number of positive real roots of the equation |x2 – x – 6| = (x + 2) is

(A) 1
(B) 2
(C) 3
(D) 4

9) is equal to :-

(A)

(B)

(C)

(D)

10) If value of is k, then k2 is :

(A) 7
(B) 14
(C) 21
(D) 28

11) The equation |x2 - x| + |x + 1| = 5 has

(A) Two rational solution


(B) Two irrational roots
(C) One rational and one irrational roots
(D) No real solution

12) If quadratic equations x2 + px + q = 0 & 2x2 – 4x + 5 = 0 have a common root then p + q is


never less than {p, q ∈ R} :-
(A) 0
(B) 1
(C) 2
(D) 3

13) If one root of the equation x2 + px + 12 = 0 is 4, while the equation x2 + px + q = 0 has equal
roots, then the value of q is -

(A)

(B) 2
(C) 3
(D) 12

14) For all x ∈ R, x2 + λx + > 0 then the interval in which λ lies

(A) λ < –10


(B) –10 < λ < 4
(C) λ > 10
(D) 4 < λ < 10

15) If one root of x2 – x – k = 0 is, square of other then k is

(A)
(B)
(C)
(D)

16) If α and β are roots of equation x2 – 10x + 10 = 0 such that , , then roots of equation
x2 + x + b = 0 are

(A) Rational and distinct


(B) Real and equal
(C) Imaginary
(D) Irrational and distinct

17) If the roots of the equation x2 + px + q = 0 are 8 and 2 and the roots of x2 + rx + s = 0 are 3 and
3, then roots of x2 + px + s = 0 are

(A) –1, –9
(B) 1, 9
(C) 8, 3
(D) None
18) Which of the following graph represents the expression f(x) = ax2 + bx + c ( a 0 ) when a > 0
, b < 0 and c < 0

(A)

(B)

(C)

(D)

19)

If (2 + 1)(22 + 1)(24 + 1)(28 + 1).....n terms = 2256 – 1, then the value of n is

(A) 4
(B) 9
(C) 8
(D) 10

20) If α and β are the roots of the equation x2 – x + 11 = 0, then the value of 3α3 – 3α2 + 2β3 – 2β2 +
11α is-

(A) 33
(B) –33
(C) 22
(D) –22

SECTION - II

1) If α, β are the roots of x2 – 2kx + 6 = 0 such that α2 + β2 = 4, then the value of k2 is

2) The least integral value of 'λ' for which the expression (λx2 – 4x + 3λ + 1) is positive for all x ∈ R,
is

3) If quadratic equations x2 – 3x + m = 0 & nx2 + 6x + 3 = 0 have both roots in common, then value
of 2|m – n| is :

4) If α and β be two roots of the equation x2 + 2x + 2 = 0, then the value of (α + 1)4 + (β + 1)4 is

5) If α & β are roots of the equation 2x2 + 6x – 5 = 0, then the value of is

6) The value of is

7) Number of solution(s) of the equation is

8) If , then is equal to

9) If then the value of

10) If , then (a + b) is _______


ANSWER KEYS

PHYSICS

SECTION - I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A A B C B A C B A B B D D B D C A C C A

SECTION - II

Q. 21 22 23 24 25 26 27 28 29 30
A. 2.00 1.00 3.00 0.00 5.00 7.00 8.00 5.00 5.00 6.00

CHEMISTRY

SECTION - I

Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
A. C C B D A B D A A B D D B A C D C A C B

SECTION - II

Q. 51 52 53 54 55 56 57 58 59 60
A. 3.00 17.00 0.00 2.91 28.00 -5.10 6.00 2.00 3.00 5.00

MATHEMATICS

SECTION - I

Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
A. B A A A B A D B A B C A A B A C B C C D

SECTION - II

Q. 81 82 83 84 85 86 87 88 89 90
A. 4.00 2.00 1.00 2.00 19.80 3.00 1.00 18.00 51.00 2.00
SOLUTIONS

PHYSICS

2)

If t is the time, the first particle takes, till meeting, then for the second particle the time will be (t –
2). For the meeting, the displacement of both the particles must be same. Thus
4t = 6(t – 2)
or
t=6s

4)

…(1)
t2 – t1 = 10 …(2)
solving (1) and (2)
T = t1 + t2 =

5)

Initial velocity of stone → U = 2 × 1 = 2 m/s

–1 = 2 × t

6)

Position 2nd drop from ground = 3 × 1.25 = 3.75m

7)

x = at2 – bt3

velocity =

and acceleration =

acc. will be zero if

10)

v2 = u2 + 2as
(–3u)2 = u2 + 2 (–g) (-h)

h=

13)

Suppose the vector is

if is parallel to then

= 3b – 4a = 0
3b = 4a

from option, a = 15, b = 20

15) =1

C=

17)

18)

m ∝ Ea vb Fc
a = 1, b = –2, c = 0.

20)

n2 = n1

=1×
=

= Newton

21)

7Q2 = P2 + Q2 + PQ
P2 – 6Q2 + PQ = 0
P2 + QP – 6Q2 = 0

22)

23)

24)

Velocity vector =
∴ Displacement after 2sec =
∴ x-coordinate after 2 sec = (12 – 12) = 0
25)

6u + = 180
⇒ 6u + 18 a = 180 … (i)
u + 6a = 45 … (ii)
from (i) and (ii)
a = 5 m/s2 and u = 15 m/s.

28)

Average velocity =

29)

30) x = 3t2 – t3 + 4t
a = 6 – 6t
a0 = 6

CHEMISTRY
37) Ans : ns2np5

38)

Due to very high electronic repulsion in oxygen upon addition of electron, it will move to last
position inspite of higher nuclear charge.

41)

From notes

48)

For isoelectronic species, as Z increases, Zeff increases (and vice versa).

49)

The order of penetration effect of different orbitals depends upon the different energies of the
various sub-shells for the same energy level, e.g., electrons in s-subshell will have lowest energy and
thus will be closest to the nucleus and will have highest penetration power, while p-subshell
electrons will penetrate the electron cloud to lesser extent and so on.

50)

Theory based.

51)

Element having ΔHeg = (+) ve are


Be, N, Ne, Mg

53)

54)

60) S, N, Cl, F, C
having more value of electronegativity on Pauling scale as compared to B.

MATHEMATICS

61)

x–y=a
∴ x2 + y2 – 2xy = a2
b – a2 = 2xy
...(1)
3 3 3
Now x – y = (x – y) + 3xy(x – y)

62)

63)

64)

x ≥ 1, x – 1 + x + 1 = 4 ⇒ x = 2
x ≤ –1, –x + 1 – x – 1 = 4 ⇒ x = –2
sum = 0

65)

M39048458N
For divisible by 8 last three digits should be divisible by 8.
58N should be divisible by 8
580, 582, 584, 586, 588
only 584 is divisible by 8
hence N = 4
for divisible by 11
|Sum of even places – Sum of odd places| = 0
or multiple of 11
(3 + 0 + 8 + 5 + N) – (M + 9 + 4 + 4 + 8)
16 + 4 – M – 25
|– M – 5|
M + 5 = 11t t∈w
M + 5 = 11

Other will M will not be single digit natural no.


Ans. (B)

66)

–1 ≥ 0
≥0

≥ 0

x = –4, 3, 1/2 , –3

x∈(–∞,–4]∪ ∪[3,∞)(A)

67)

x2 + y2 + z2 + 4 = 4z + 2xy
2 2 2
x – 2xy + y + z – 4z + 4 = 0
2 2
(x–y) + (z – 2) = 0
x = y & z = 2 (D)

68)

|x2 – x – 6| = x + 2
x2 – x – 6 = ±(x + 2
Considering (+)
x2 – x – 6 = x + 2
x2 – 2x – 8 = 0
x = 4, –2
is positive real solution.
considering (–)
x2 – x – 6 = –x – 2
x2 = 4
x = ±2
is positive real solution.
Total 2 positive real solution.
Ans. (B)

69)

Hence;

70)
squarring both sides
k2 = 8 + 6 = 14

71)

|x(x – 1)| + |x + 1| = 5
(I) x ≥ 1
x2 = 4
x = +2 or x = –2

(II) 0 ≤ x < 1
–(x2 – x) + (x + 1) = 5
x2 – 2x + 4 = 0
D<0

(III) –1 ≤ x < 0
+(x2 – x) + x + 1 = 5
x2 = 4
x = +2 or x = –2

(IV) x < –1
+(x2 – x) – (x + 1) = 5
x2 – 2x – 6 = 0


(I) ∪ (II) ∪ (III) ∪ (IV)
⇒ x = 2 or
⇒ One rational root and one irrational root.
Ans. (C)

72)


So, both roots are imaginary & imaginary roots always occur in pair of conjugate.

73)

16 + 4p + 12 = 0 ⇒ p = –7

p2 = 4q ⇒ q =
74)

Use : D < 0 ⇒
⇒ λ2 + 6λ – 40 < 0
⇒ (λ + 10)(λ – 4) < 0
⇒ λ ∈ (–10, 4)

75)

Let roots are α, α2


α + α2 = 1 , α.α2 = –k
(α + α2)3 = 1
α3 + α6 + 3α3(α + α2) = 1
–k + k2 – 3k(1) = 1
k2 – 4k – 1 = 0

76)

, second equation becomes


2
x + x + 8 = 0 ; D < 0 ⇒ Imaginary

77)

78)

a > 0, b < 0 and c < 0


∵a>0
∴ Graph will be concave upwards.

Also tip of the graph i.e. minimum point has coordinates


∵b<0
∴ x coordinate must be positive.
D = b2 – 4ac
= (–)2 – 4 × (+) (–)
= +ve
D > 0, a > 0
∴ y-coordinate will be –ve.
x > 0, y < 0
and c ≠ 0
∴ it will not pass through origin.

80)

α2 – α + 11 = 0 ⇒ 3α3 – 3α2 + 33α = 0 ...(i)


β2 – β + 11 = 0 ⇒ 2β3 – 2β2 + 22β = 0 ....(ii)
(i) + (ii)
⇒ 3α3 – 3α2 + 2β3 – 2β2 + 33α + 22β = 0
⇒ 3α3 – 3α2 + 2β3 – 2β2 + 11α = –22(α + β) = –22

81)

(α + β)2 – 2αβ = 4
4k2 – 12 = 4 ⇒ k2 = 4

82)

Do Yourself.

83)

⇒m= & n = –2

∴ |m – n| = = 0.50

84)

∵ x2 + 2x + 2 = 0
∴ α2 + 2α + 2 = 0
⇒ α2 + 2α + 1 = –1
⇒ (α + 1)2 = –1
⇒ (α + 1)4 = (–1)2 = 1
same as, (β + 1)4 = 1
so, (α + 1)4 + (β + 1)4 = 2

85)

2x2 + 6x – 5 = 0
86)

= x (x > 0)

x = –2 (reject), 3

87)

Possible when x = 2

88)

taking cube

89)

=
= 4 (7) + 23 = 51

90)
a = 1, b = 1
a+b=2

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