PRACTICAL BASED ASSESSMENT (PBA) NOTE: Attempt all questions. Write your answer within the provided space. SECTION-A {Purpose of this experiment Isto deter purity ofthe sany {olution by volumes method when the given sokalon cntans Nass of Na Siuolvedpordm. ‘Apparatusused: Bret pipette, funnel conical ak beakers rons CChemicalused: | Methyl orange incicater, NCO, 01M HCL Dstiled wate, solution of {69 of NS2COBint am 16cm Na,CO,requredvalumeV, of HCtinem™ ‘Seeconthe figure givenbelow and recordthe observations intable en oe 0 Obseratontable: a tap, Volume ot nchuned 7 z st Mean volume of HClused = Wich one othe fooing gure shows te end poi when aids added o,CO, Solution? Encircle the correctoption. —_ = Scanned with CamScannerMean volume of HCI used = li) Which one of the following figure shows the end point when acid is added to Na,CO, Solution? Encircle the correct option. 0) 446 Wii) Whatis the purpose of using methyl orange? 1 Chemical Equations: 1m ” ‘i Na,CO, + HCt— NaHCO, + Nace —rremcancemitbanen PAPE NWA Scanned with CamScannerNaHCO, + HCt—= NaCt + H,0 + CO, Write Overall Reaction: UW Caleulations: m Find n¥ of Na{CO, and n,of HCI from chemical equation nie ma 1 You are advised to show fll working in all parts of calculations. 2. Calculate the molarity of Na,CO, by using formula: n MIVt . Mzv2 mt nz Becta mas f 60, er in! om ae tiation m iy Ae CE rercertage py Waco, « MSE SENED, lined om py Result: Percentage purity of Na,CO, = SECTION-B Q2: Encircle the correct option. |) Chromatogram of a mixture of ink is shown: Height of the “a solvent fronts 10 cm; distance covered by yellow is 4.7ern Rf Scanned with CamScannerSECTION-B 1.2: Encirelethe correct option. 1) Chromatogram of a mixture of ink is shown: Height of the “s" solvent front is 10 cm; distance covered by yellow is 4.7m Rf sen] value of yellow inkis: 1] A. 47cm B. o47em 47cm D. 10cm iy Rock sat can be purified by common ionic eect which of the folowing wil ie precntates i Rocksaltsolution + HNO, Rocksaltsolution + HCl Rocksaltsolution + SO, Rocksaltsolution + KCL + rar PhaniaBaRed heeORNEREOMN Beunscaner poep il) Lead and Cadmium are colorless tiquids. 1 ‘can be separated by chromatography, which can be us romatograpy, which one ofthe following ‘agent ed 10 ‘A. Nintydtinsolution 8. HCtsolution © _H,S0,solution DL HBrsolution jw) Estimate the Amount of 83+2 inthe given solution of BaCl2 gravimetrically canbe dane bythe adcivonof. 1 A. KO, solution Scanned with CamScanner» » v) gad and Cagmiom are cols ui, They can be spaated by paps: éhromatograpy, which one o color agent can be used to ident ttadand Gan — wy A Estimate the Amount of Ba+ im? \Nintydrin solution ctsolution 1450, solution HBrsolution the given solution of BaCl2 ‘gravimetrically can be done by the addition of 1 Ba" in the given solution of BaCl, can be estimated by sroimetncay A a c D solution yellow colorofthesolutionisgivenby. (1) [mer BaCh, solution rasmes ta K,Cr0, solution “oom KGr0, solution coer Kcr. sohiton é — Heat of Neutraiaon of OH and ff canbe eterna bythe apparatus shown, which one of the following graph canbeusedtocalcuateheatof neutralization. [1] eh ot my Scanned with CamScannerTEE REEEEE ° oomatote [ope ined | Teal 2 [a [se z 1s MeanvolmeotiCluied= 26580 Ateg © Metta sins msdn ety ong ese eolorotinbse ston Ma NACO,*2HCl ~ 2NACE* 140+, ated med Dita1@ a zese z Molar otNa€0, 041) © 1 molirmassofNaCO, =2423+ 1263406 M6 Moly =M «mass/molarmass +1 olaion Mass molariyrwolumein ds molrmassotNaCO, 213 mot senses t08 Maus = 14099 on Percentage purty tnc0,= F223 100, sans, SECTION-B Ss585e Scanned with CamScannerPRACTICAL BASED ASSESSMENT (PBA) IRIEMISTIRY |EISSE-I NOTE: Attempt all questions. Write your answer within the provided space. SECTION-A trong sulfate crystals have the formula FeSO,xH,0, where xis 2 whole number, A student determines the value of x using aqueous 0.0200 mol / dm’ potassium ‘manganate(Vil). Thisis solution F. Potassium manganate(Vi), whichis purple, oxidisesiron(ll) ions to iron(tll) ions. Apparatus used: Burette, pipette funnel, conical flask, beakers, iron stand. Chemical used: Indicator Potassium manganite (Vil itself Iron() sulfate, 0.0200 mol / AL HK + HSO4 B. HO + KSO, HO + Ko, DL Hy + KSO, Ili) Anaddition of NHClin which solution suppresses the concentration of OH-(aq)?-_ 1] AL Nace B KNO, c MgCh, DB. NHOH WW) ThepHofsolls canbe controlled through ‘A. neutralization B. acidic oxides | Amphoteric oxides D. neutral oxides m ¥) Whatwilb thesalto he gen reaction? "0 Z:NOH), + HNO, ~ 18, Star Chemistry Practical Based Assessment (PBA) Sc. 11th Federal Board) Scanned with CamScannerA. HNO, Zn(OH), c HO DB. Zn(No), vi) It is important that substances used in the synthesis of medicines are pure as purities in these products can be detrimental to our health. Samples of pure and impure paracetamol were analysed using chromatography. The resultinc chromatogramis shownbelow. to sokent ont — Joan @ Jozrem | osm |X Tame sm of persetmot oe ‘Y= pure paracetamol aseine Ly ‘he impure sample of puraetamol was contaminated wth on ote rnc used during its synthesis. A 070 B. O75 © 06s DL 08s Scanned with CamScannerSECTION-A 1: Astudent performs chemicaltest to demonstrate that enzymesare proteins. ‘Ans 9) themassofM2cO3 ‘Ans i) Gas:carbondioxide Test tumstimewatermily ‘Ans i) Thecolour changes romorangered toyellon om Titration Number 1 fina reading Fem? 339) initial reading / em" 00 ‘volume of 0.100 mol / drm? sodium hydroxide fem? | 259 ale] & Ea)» 255 est ration eas ole 3534355 = #25460 0 tes tno ‘Ans 9) Molanty= 20.9t males Moby x arerage volume = Malay xaveage volume Nootmotes: se = 2.1002 25.4 T0087 ‘= 0.00254 moles WW) Molerato= 1:1 Sothe numberof molesathydrochlove acidin250cm? 000254 moles vi) the umber of mole of in250em 00254 x250 7000 = 00254moles ‘SECTION-B az Scanned with CamScannerSECTION-B RERREe Ss t5se 2 Star Chemistry Practical Based Assessment (PHA) — FSc. 11th Federal Board) www.ilmge.com Scanned with CamScannerNOTE: Attempt all questions. Write your answer within the provided space. SECTION-A 1: Astudent is asked to determine the percentage by mass of ron(l) ions Fe, In some tablets. The student grinds two tablets into a powder. ‘Apparatusused: Burette. pipette, funnel,250cm' conical lask beakers, iron stand. CChemicalused: Indicator Potassium manganite (Vitel, Iron) Sulphate, 0.0200 mal dm potassium manganate( i) istiled water. ‘The powdered tablets are added to a previously weighed container, which is then reweighed. mass ofcontaner + tablets = 16079 mass ofcontainer = 11.03 1) Calculate the mass tablets used nthe experiment. m The powder is dissolved in excess dilute sulfuric acid and the solution made up to 250.0 em’ with distilled water. This is solution H. A 25.0 cm’ sample of H is measured into conical ask. « ji) Solution 6, 0.0200 mol / dm potassium manganate(Vi), which is purple, is put into a burette and runinto the conical ask containing H, ro Three titration are done. The diagrams below show parts ofthe burette with the liquid levels at the beginning and end of eachtitration. Usethe diagram to complete the esultstable. Tiwation Number [112] 3 | final burette reading / emt intial burette reading / em volume of 0.0200 molidm3 pelgsiom mangonate Scanned with CamScannerIhe powdered tablets are added to a previously weighed container, which is then reweighed. : mass of container + tablets = 16079 mmaszof container= 11.039 77) Goalatethermassof bles sedinte experiment. m ‘The powder is dissolved in excess dilute sulfuric acid and the solution made up to 250.0 cm’ with distilled water. This is solution H. A 250 cm’ sample of His measured into. conical flask. Fy” Solution 6, 0.0200 mol / dm’ potassium manganate(Vi), which is purple, is put into a Burerte andra nto the conical flask containing ol Three titration are done. The diagrams below show pars ofthe burette withthe liquid levels atthe beginning and end of eachtitration. Use the diagram to complete the results table, Titration Number T[273 final burette reading / emt initial burete reading / em ‘volume of 00200 mol/dm3 alpm mangaate Ivvaton 2nduadon 3rauwaton [Dest raion results (7) Summary: Tick) the best titration results. Using these results the average volume ‘0f0.0200 mol dm’ potassium manganate(Vi)is, iii) Calculate the number of moles of potassium manganate(Vil) in the average volume of Za Gusedin(b). tr Scanned with CamScannerWW) One mole of ponncehsrn reacts with five moles of irons 5 Brducr tne mimber ef rcine site" mbes ome i in280er' oft 9 Deduce the number of motes of Fe m m Wi) Coleulote the mace ofFe in 280 cm oft Ar Fe. $6) wi) ang you orem to tat ra cote te percereage by mam fe” ne athe, SECTION-B 2: Encircle the correct option. {) The diagram shows a chromatogram of 3 Winch statement iscorrect? [1] Scanned with CamScannerSECTION-B Q2: Encircte the correct option. 1) Theduagram shows a chromatogram of severa! inka Which statement iscorreet? [1] fei. | tan the oe yee me pee [Black ank can be made by mang geen, fed and yellow inks Brown ink can be mace by mung Bue arc yxy ies Yellow snk can be used to make brown Yellow ink may be presentin green nk prep fi) The cagram shows the chromatogram cotened by anaiyus of a single dye m ‘Thee measurements are shown How 9 the R valve of dye calculated? a To ge toe ® da fj = [Wy Toe dugram shows the chromatogram offov ferent sugars ung the same sobvent Glucose has anf valve o10 $ Wrech sugars ghscose? a rr eon | ° | | ° Scanned with CamScannerBeanscanne c B lw) Anadditionof KCIO, inwhich solution suppresses the concentration of K+? m & Ke © Mach DL NHOH v) The: of ionization of weak acid ora weak base by the adding one ofits own ionsisknownas: 1 A. BufferSolution B. Ionization Effect m : A. Notreeions 4 Salts of metals Scanned with CamScannernCnOnA ne ne te ts ene re et ee ‘Ans a) themass oftabletsusedin the experiment.» 5.049 — Titration Number 1T2][3 final burette reading /cm™ wa [ 375 | 273 {inital burette reading / cm? 00 | 204 | 100 ‘volume of 0.0200 moVvde otagsiom manganate vin | r7a | rz | 173 ‘est tation results mle waa : 217260" P 9 of moles x 1000, ‘Ans ii) Molar: Noofmoles = Molaiy x average volume 7000 90200172 1000 =0000344mates a =Oooo.ar5 = o00172meles ‘0 numbeomolesof FeO, presentin250em'= 00223 250/25 “oorremaies i) Nootmoles = mass/mola Mastoffe™ root moles sSrmass soorraxse =o96%e9 Mito » 09632 109 Pie Weer Sd a191% RE SECTION-B Scanned with CamScannerNoot moles = Se 7000 (-210200 2 172 7000) '=01000344 moles Ans iM) =000034¢x5 '=000172 moles ‘Ans v) numberof melesot FeSO, presentin250 cm’ = 0.00223.x 250/25 '=00172moles Wi) Noofmoles = mass/molarmass MassofFe™ =noofmolesxmolarmass =00172x56 =096329 ix 100 , 09632 x 100 0. 30 19.11% s va SECTION-B e y RERRRE Ss3550 Scanned with CamScannerCO es PRACTICAL BASED ASSESSMENT (PBA) NESTE NOTE: Attempt all questions. Write your answer within the provided space. SECTION-A Q1: Astudentis asked to determine the value of xin the formula Na,CO,xH,0. Apparatus used: Burette, pipette, funnel, conical flask, beakers, iron stand. ‘Chemical used: Methyl orange Indicator, Na,CO, 0.1M HCi, Distilled water, solution of {6g of Na,CO, in 1 dm? 10cm" Na,CO, required volume V, of HCLin cm? 1) A sample of Na{CO,xH,0 is added to a previously weighed container, which is then reweighed. mM mass of container + Na,CO,xH,0 = 10.84g mass of container =7.49g Calculate the mass of Na,CO,xH,O.usedin the experiment. 2 ii) Thesampleis dissolved in distilled water and the solution made up to 250.0 cm’. Thisis H. In which apparatus should the solution be made up to 250.0 cm 1 iii) 25.0 cm’ sample of H is transferred into a conical flask and a few drops of methyl ‘orange indicator are added. ni ‘a. Name the apparatus used to transfer 25.0 cm’ of H into the conical flask. b. A burette is filed with 0.100 mol / dm* hydrochloric a The hydrochloric acid is added to H until the end-point is reached. Scanned with CamScanner(mass Of container + Neokajpary™ NG mass of container =7.499 Calculate the mass of Na,CO,xH,O used in the experiment. Ii) The sampleis dissolved in distilled water and the solution made upto 250.0.cm’. Thisis H. Inwhich apparatus should the solution be made up to 250.0 cm"? mM Wi)_A25.0 em’ sample of H is transferred into a conical flask and a few drops of methyl ‘range indicator are added. nm) ‘a. Name the apparatus used to transfer 25.0 cm’ of H into the conical flask. A burette i filled with 0.100 mol / dm’ hydrochloric acid. The hydrochloric acd is added to H until the end-point is reached. 2 ‘What isthe colour ofthe solution in the conical flask before the hydrochloric acid is added, at the end-point? Iv) The student does three titrations. The diagram below show parts of the burette with the liquid levels at the beginning and end of each titration BI Use the diagramsto complete the following table. Titration Number T1273 final burete reading / cm* initial burette reading / em? volume of 0.100 mol/den? hydrochloric acd em Dest tivation results (7) Is¢taton 2nd Wyation 31d ivation PBA Paver No.6 25 Scanned with CamScannerSECTION-B 2: Encircle the correct option. 1) Neutralizations reactions are m ‘A. Displacement reactions B. Double displacement reactions Decomposition reactions D. Combination reactions Ht) H gt OH ye -HOy m ‘A. Displacement reaction B. Doubledi © Decomp ct D. Neutralization reaction lacement reaction li) Chromatographyis the process which involves the distribution of asolute between [1], ‘A. Twomobiles phases B. Twostationary phases C._Astationary phase and a mobile phase 1D. two stationary phase and two mobile phase iv) TheChromatography in which stationary phases liquid is called ‘A. Partition Chromatography 'B. Adsorption Chromatography Column Chromatography 1D. PaperChromatography o) eyaungncrononson ebiaonel O 4, eas crore i J 1 Scanned with CamScanneri) lonization of hydrogen sulphide gas is suppressed by: a A ket B Nace © NHOH DB. Hct ROUGH WORK \ Scanned with CamScannerSECTION-A 1: Astudent performs chemical testto demonstrate thet enzymes areprotelns. ans ans ane ane 2 ThemassofNs,CO,xH,Oused inthe experiment ©3359 {The apparatusused totransfer25.0cm' of Hintothe conical flask s Volumetric ask 1B bebrtehyawalocccdl eestor Nien pone onngeted “ ‘Titration Number Traore eigen initial burette reading / em? rolume of ona0 movin a5g | as | a es iron eu 25-253 3 =234em! ¥)_thenumber of moles of hydrochloric acidin the average volume ot (0.100 mol/ dem hydrochloric acidin 10 of moles x 1000, Motwny= Seetmoies oe Noof moles = Molarity x average volume beh 7000 0.100 x23, : 1000) = 0.00234 moles 9 float, 40 vee therumberotmolerotzumentonte 22224 ascent oe Saori ‘The number of moles of sodium carbonate, N2,CO, in 25cm’ of H = 200117 x 250. 0.0117 moles 3 7 238 | a7 | 333 00 | 243 | 100 alo SECTION-B Scanned with CamScannerPAPER Ho. 7 PRACTICAL BASED ASSESSMENT (PBA) NOTE: Attempt ail questions. Write your answer within the provided space. SECTION-A Qi: Student determines the percentage by mass of water in oxalic acid hens by titration. Apparatus used: Burette, pipette, funnel, 250.cm' conical flask, beakers, iron stand, ‘Chemicalused: Indicator Potassium manganite (Vl itself, Oxalic Acid, 0.0200 mol / dm’ Potassium manganate(ViN, Distilled water. |) A sample of oxalic acid crystals is added to a previously weighed container, which is then reweighed. nm ‘mass of container + oxalic acid crystals = 11.329 ‘mass of container = 7.899 Calculate the mass of oxalic acid crystals used in the experiment. fi) The sample of oxalic acid crystalsis dissolved in distilled water and the solution made upto mM '500.cm’.Thisis solution H. ‘Name the apparatus in which solution H should be made up to S00 cm. iii) A25.0cm' portion of His transferredintoa conical flask. m a. Name the annaratis used to transfer 25.0 cm’ of H inta the ennical flacl Scanned with CamScanneraz BEEEEE Se255e =2Acm ‘thenumber of molesof hydrochloric acid the average volume of (0.100:mol/ dent hydrochloric aidin(. = 20. males x 1000 average volume Not moles = Molaiy xaverage volume ‘000 = 01002234 . 7 =000234moles RatiofN,C0, :HeL Viz thenumbeofmelesotsedum carbonate» 223 in 0c of (000117 moles Trerumberotmoeolsodum ibn NCO, indent » 204171250 00117 moles SECTION-B 2 8 . ¢ a ° ° Scanned with CamScannerji) The sample of oxalic acid crystals is dissolved in distilled water and the solution made upto 1m 500 cm’ Thisis solution H, [Name the apparatusin which solution H should be made up to 500cm’. iil)_A25.0cm' portion of His transferred into aconical flask. m ‘a. Name the apparatus used to transfer 25.0 cm of H into the conical flask. b. His a colourless solution. mM G is 0.0200 mol / dm’ potassium manganate (VI). i, « G is put into a burette and run into the conical flask congSdiing H. ‘What is the colour of the solution in the conical flask when G is just in excess? iv) The student does three titrations. The diagrams below show parts ofthe burette with theliquidlevels atthe beginning and end of each titration. RI Use the diagrams to complete the following table. , Titration Number ts) s2i] 93] final burete reading / om initial burete reading / cm volume of G/ cm” ‘best ization resuls (7) Ix waton 2nd vvaton 3d tizavon PBA Paper No.7 29 www.ilmge.com Beanscinner Scanned with CamScanneros ‘Summary: Tick () the best titration results. Using these results, the average volume ofGis: /otassium manganate(Vil). Calculate the number of moles of tevin nthe average volume of Gused in ch, "1 ¥) Gis 0.0200 mol / di potassium mangan: es of oxalic acid crystals. vi) Two moles of potassium manganate(Vl) react with fi a Deduce the number of moles of oxalic acid crystals in 26-Bcm’ of H. vil) Deduce the number of moles of oxalicacid crystals in 500.cm of H. m SECTION-B Q2: Encircle the correct option. i) Chromatographyis a physical method thatis used to Separate: ‘A. Simple mixtures 8. Complexmixtures Viscous mixtures DL Metals m 1i)_ Which forceisinvolvedin the Chromatography? m A. Hydrogenbonding Scanned with CamScannerSECTION-B 2: Encircle the correct option. 1 Chromatographyis a physical method thats ised to Separate: m ‘A. Simple mixtures Complex mixtures Viscous mixtures D. Metals i) Which forceisinvolvedin the Chromatography? m ‘A. Hydrogen bonding oO B Londonforce C Hlectricstaticforce D. Alloftheabove lil) When HCtis added to H,S aqueous solution, itsionization m ‘A. Increases B. Remainsconstant <. Decreases DD. Firstincreases and then decreases 1) Wich equaionrepesetstheneuatstonofrieicacidusng sodium ychanie? ‘A. NaQH(aq) + HNO,(aq) ~ NaNOJ2q) + H,0() B. NaQH{aq) + HNO,(aq) ~ NaNO,() + H,() C_NaOH() + HNO,() = NaNO,() + H,0(aq) 1D. NaOH() + HNO,() ~ NaNO) + 01) ¥)_ An experiment is carried out to seperate a mixture of two dyes. A line is drawn on a piece of chromatography paper and.a spot of the dye mixture placed on it. The paper fs dipped into a solvent and left for several minutes. Which statement about this experimentis correct? oT Fe 11th fader Roan Scanned with CamScanner hamish Brartcal acad Retasemantoot sven eve Thedvesmus dierinthei boil Thelite must be den 1. Theline must be placed below thelevelof the solvent. A. Heatofreaction Heat of sublimation © Heatofneutralization DL Heatofcombustion ROUGH WORK Scanned with CamScanner‘Ans ‘Ans ‘Ans Ans ™ vi . Purple/ pink SECTION-A 1: Astudent performs chemical test to demonstrate that enzymesare proteins. 1) Themass of oxalic acid crystals usedin the experiment = 3439 i) The apparatusinwhich solution H should be made up to S00 cm is Volumetric Flask ‘Titration Number 1 2 ii) a. Theapparatus used to transfer25.0cm' of Hinto the copbpl flaskis Pipette 3 final burette reading / cm? 73 379 427 initial burette reading /em? 00 700 156 ‘volume of G/ em” 273 279 24 ‘best titration results m om 271+ 273, a =272cm Molarity ‘average volume oof moles « Molaity x average volume Noofmoles: a 00200 x272 “000 = 0000544 moles = 0000544 5 z +=0.00136 moles = 2.00136 x 500 3 = 0.0272moles 1n0 of moles x 1000 SECTION-B Scanned with CamScanneraz BRERRE va SsE55e Dest titration results ” ” 21+273 z 22a Motarity = 22. moles x 1000 ‘average volume ‘Noof moles = Molarity x average volume 000 = 00200 x272 = 0.00136 500 3 = 0.0272moles SECTION-B ne>noe Scanned with CamScanner[NOTE: Attempt all questions. Write your answer within the provided space. SECTION-A student determines the percentage composition by mass of » mixture of two Sali todtim chloride, NaCeandsodumcatoonte NCO, Te emicure Me ‘Apparaturured: Suet pipette unnl conc es bekers ron stand. CChemialused: Methylorange indenter slsioncfNiCO, 0 MNCE Disiled water 1 Asumpleoslceinaprevonty weighed contain wie tan rey tmossofcontaines += 8059 mass ofeontaine’=7239 CGelatethemassolM sedinthe experiment 1) The sample of Mis issolved in stile water and the solution made upto 250 em Thsissotutiona. ‘The appaatusinwich solution shouldbemade upto 250¢msVlumevie ask, 1) 4250 cn sample of is ranted into conic flask anda few drops of methyl ” ‘Gedngeindcatrareadded Aburetel ied no 100mal/Gmhyérchion aaa” ThehyroconcacdisaddedtoQuntitheend-poinireached Iu) The student does three trations. The grams below show pars ofthe burete with {heliguidlees atthe beginning ndendot each vation. 31 Usethe diagrams to complete thefelowin table Scanned with CamScanner|) Asample of Mis placedin previously weighed container, whichis then reweighed.[1] mass of container + M = 9.059 mass f container = 7.239 Calculate the mass of Musedin the experiment. fi) The sample of M is dissolved in distilled water and the solution made up to 250 cm’. Thisis solution Q. ‘Theapparatus in which solution Q should be made up to 250.cm’is Volumetric Flask. iil) 425.0 cm? sample of Qis transferred into a conical flask and a few drops of methyl ‘orange indicator are added. Aburetteis illed with 0.100 mol/ dm’ hydrochlp-9 acid. ‘The hydrochloric acids added to Q untithe end-points reached. iW) The student does thee titrations. The diagrams below show parts ofthe burette with the liquid levels at the beginning and end of each titration. 3) Use the diagrams to complete the following table. Tivation Number] 1] 2] 3 foal butte reading / en? | | inl burt reading / em? ‘ume of hydrochloric acid /cm? = Isewvation 2ndvatin araivaton [best ivation reals (7) ‘Summary: Tick (V) the best titration results Using these results, the average volume ‘of hydrochloricacidrequiredis: moles of hydrochloric acd in the average volume of 0.109 Scanned with CamScannervi) Sodium carbonate reacts with hydrochloric acid but sodium chloride does not Construct the equation for the reaction between sodium carbonate, Na,CO, and hydrochloric acid. 1 ‘One mole of sodium carbonate reacts with two moles of hydrochloric acid. vi) Using te information n (9 and your answer to (e deduce the number of moles of sodium carbonatein25.0cm'of m vill) Calculate the number of moles of sodium carbonate in 250.cm’ of Q. m ix) Use your answer to (h) to calculate the mass of sodium carbonate, Na,CO, in the sample of M. 1 [Ar.Na,23;C, 12:0, 16) SECTION-B Q2: Encircle thecorrect option. 1) Enthalpy of neutralization of all the strong acids and strong bases has the same value because; 1 ‘A. The net chemical change involves the combination of H+ and OH-ions to form water. Scanned with CamScannerbw) Use your answer to (h to calculate the mass of sodium carbonate, Na,CO, in the sampleofM co) [Ar Na, 23;C, 12;0, 16} SECTION-B Q2: Encirele the correct option. 1) Enthalpy of neutralization of all the strong acids and strong bases has the same value because: m ‘A. The net chemical change involves the combination of H+ and OH- ions to form water. » Sipputeeremenene D. Acids ali¥ys give rise to H+ ions and bases always furnish OH- ions to form water. di) The heat of neutralization of a week acid by a strong base as compared to that of a strong acid by astrong bases always: 11) A less B. greater equal 1B. noneof these iit) Chromatography with solid stationary phase is called: 0 A Giclecomatogrphy uare chromatogra ._Solidchromatogrephy . Adsorption chromatography Scanned with CamScanneriv) The patternon the paperin chromatography is called: m A. Chroming B. Chroma © Chromatography D. Chromatogram v)_ The Rfvalue of red colour in the chromatogram givenis? m A 02 {— ) ste B. 06 c 08 j—®| due D. 05 toby ro Purple b ls Origin vi) Whatistheneteffect of the common ion? m AA. - Itincreases the solute in the solution. B. Itreduces the solubility of the solute in the solution. CC. Itcauses more product to be made. DD. Itcauses more ions to form. ROUGH WORK Scanned with CamScannerSECTION-A Ct Audet pron cnt teen cymes 9 Temetwedinecpnent 23 at "ae fatbarsemsang/ay [a8 [a [7 lute rg on? [80-0 [4 wayne of avec Tang | sas | a2 ‘est titration resis mya) BERE 191 +193 ey, #192 Ans wi) =Na,CO,+2HCL ~ 2NaCl* CO, +40 fos vip =RavootNnco, Heb v2 thenumberotmtestsadumcabostes 22012 in250cn'ath : 0.00096moles Scanned with CamScannerNetra 2.100192 ae = 000182 moles W) =NB,CO, + 2HCL ~ 2Nacl+C0,+H0 thenumbertnlescadimentonte «220 in2sent oth Somes ne i) 00096 moles fos "h) te mantchadumeatostesroctmolesxmolmast SECTION-B RRRRRE SsE8s5 26 tar Chemicty Practical Rated Accecement (PRA — Ge 119k fader Bane Scanned with CamScannerscanner PAPER He. 9 PRACTICAL BASED ASSESSMENT (PBA) NOTE: Attempt all questions. Write your answer within the provided space. SECTION-A Q.1: Limestone's impure calciygy carbonate. A student does an experiment to determine the percentageby mass p/ calcium carbonatein a sample of limestone. The sample: limestone is placed in apreviously weighed contai Apparatusused: Burette, pipette, funnel, conical flask, beakers, iron stand. < Chemical used: Methyl orange indicator, solution of Na,CO,,0.1MHCt Di mass of container + limestone = 10229 massofemptycontainer = 5.729 1) Calculate the mass of limestone used inthe experiment. m The student transfers the sample ofimestone into a beaker and adds 50.0 cm’ of 2.00 mol / dm’ hydrochloric acid, an excess. The calcium carbonate reacts with the hydrochloric acid. CaCO, + 2HCL =CaCh, + CO, + H,0 ‘The student transfers the contents of the beaker into another container and the volume is made up to 250cm’ with distilled water. Thisis solution T. i) Name the container in which solution T should be made. 2E Arm nf Fie tranefaread to arene al lack ane fewer Scanned with CamScannerFryaroctnon dud. CaCO, + 2HCL=CaCh, + CO, + HO ‘The student transfers the conten of the beaker into another container and the volumeismadeup to 250em with dstiled water. ThisissolutonT. 1) Namethecontainerinwhich solution T should be made. m 25.0em'of is transferred to a conical flask and afew drops of methyl orange indicator ae added. An aqueous solution of €.100 mal / dm’ sodium hydroxide ie put into burette and runinto the conical iaskutl the end: points reached. {ily Whatisthecolourchange of themethy| orangeaatthe end-point? m ‘Thecolourchangesfrom.... ‘Three titrations are done. The diagrams show pats ofthe burete withthe liquid level the beginning and end ofeach ration. 1 ‘uravon 1 twravon 2 ‘weaton 3 PBA PaperNo.9 37 www.ilmge.com Scanned with CamScannerv= ~ vilt) Calculate the number of moles of hydrochloric acidin 250cm'ofT. Use the diagrams to complete the results table. Titration Number 7 ‘inal burette reading / em" intial burettg reading fem ‘volume of £2300 mol em? Fryode om! ‘est itation results 0 ‘Summary: Tick (V) the best titration results. W)_ Using these results the average volume of.100mol/dm'sodiumhydroxideis (2) vi) Calculate the number of moles of sodium hydroxide in the average volume of 0.100 ‘mol dm? sodium hydroxide (v). m (0.5) vii) Using the equation NaOH + HCl NaCl+ H,0 ‘and your answer to (vi), deduce the number of moles of hydrochloric acid in 25.0 cm* oft. 10.5) Scanned with CamScannerbx) Calculate the number of moles of hydrochloric acid in the original 50.0 em’ of 2.00 mol /dm’ hydrochloric acid, mW ¥9 Using your answers to (x) and (vil, calclate the numberof moles of hydrochloric acid that reacted with the calcium carbonate in the sample of limestone. SECTION-B Q.2: Encircle the correct option. 1) Theheat of neutralization of a strong acid by a strong base is about. a 0) A -11.9Kcal B. -13.7Keal Cc. -12.3Kcal D. -127Kcal gL 38 Star Chemistry Practical Based Assessment (PBA) — FSc. 11th (Federal Board) www.ilmge.com 2 Camseanne Scanned with CamScanneree }—@ | Purple }—0 | rea L— J orn m ROUGH WORK Bulk phenomenon A B. Attenuation © D. Surfaceproperty PBA Paper No.9 39 www.ilmge.com Branseanne Scanned with CamScannerip i) SECTION-B 2: Encirele the correct option. 1) Theheat of neutralization of a strong acid by a strong baseis about. m AL -119Kcal B. -137Kcal © -123Keal D. “12.7 Keal ‘38 Star Chemistry Practical Based Assessment (PEA) — FSc. 11th (Federal Board) www.ilmge.com 7 CamSeanner Viatistecommonionetec? nF ‘A. When the addition of an ion common to two solutes causes precipitation or reduces ionization, B, When the subtraction of an ion common to two solutes causes precipitation or reducesionization. . © When a molecule is added to a solution and causes precipitation or reduces ionization. 1D. Theeffect of adding ions toa solution. ‘Addition of CH,COOH and CH,COONa gives in water obey which effect? m Compton Bohr Photoelectric Commonion poop ‘ Scanned with CamScanner‘Ans 1) massofcontaines SECTION-A limestone = 10229 mmassofemptycontainer =5729 | Themassofimestoneusedinthe experimentis 4509 ane Ans Therameotconsnerinichscton sou be made Voumetic ask dns) Theclorchangeothemetyoxngestheed points omorngeredto elon ‘ns 9) Usetentatoninte dara tconpltethe reise, co a z z Ye az ie ra deg ot | 00 7 m7 etna t we ar ae Bs ent noone 7 ten rsensas| a Using tee ret he avengevolmeof0100m0/ do NSOH em! Bee <2Sen! ‘Ans hydroxide in(d)are cary =nactmaesx100/ average ohne | Nootmoler = Motarysavege volume, 100) > o10os298 8 0.00295 moles 1 ‘Ans vil) RatioofNOH : HCE 1 ‘The number of moles of hydrochloric acidin25.0¢mofT, = 0.00295 x1. Scanned with CamScanner= 0.00295 moles Ans vii) The umber of moles of hydrochloric acid in 250cm' of T= 0.00295 x250 Ans BEREEz ia) iii) iv) v) vi) 0.0295 moles ‘The number of moles of hydrochloric acid in the original $0.0 cm' of 200 mol / dm’ Hydrochloric acidare Molarit Noof moles no of moles x 1000/average volume ‘Molarity xvolume/ 1000 =2.00 x 500. 1000 =0.1 moles Using answers to (h) and (9), the number of moles of hydrochloric acid that reacted with the Calcium carbonate in the sample of limestone = 0.1-0.0295 = 0.0705 moles SECTION-B 8 A o B c A o 40 Star Chemistry Practical Based Assessment (PBA) — FSc. 11th (Federal Board) www.ilmge.com Bccamscannes Scanned with CamScannerPRACTICAL BASED ASSESSMENT (PBA) NOTE: Attempt all questions. Write your answer within the provided space. SECTION-A Q1: Iron tablets are used to treatiron deficiency in the body. Iron tablets contain iron(t!) ions, Fe". A student does a series of titrations with aqueous = ¢ potassium manganate(Vi), KMnO, to determine the = percentage of iron in some iron tablets. Apparatus used: Burette, pipette, funnel, 250 cm’ conical flask, beakers, iron stand, 4 Chemical used: Indicator Potassium manganite (il itsel, ron (ly Sulphate, 0.0200 mal / dm" potassium manganate(Vi), Distilled water. Diagrams of some of the apparatus the student uses areshown. i) Name the three piecesof apparatus. BI A 8 c i) Thestudent: ‘© records the total mass of five ron tablets Scanned with CamScannermanganateVi), Dstiled water. ‘seu ci possi T Diagrams ofsome of the apparatus the student uses sreshown. oo 1 Name the three pices of apparatus, a a . c 1) Thestudent: «records the total mass offveiron tablets ‘© crushes the tablets, dissolves them in distilled water and makes the solution upto 250¢m" «© uses apparatus Cto transfer 25.0 cm’ of the solution of Fe ions into a conical flask + ysee apparatus 8 to add 100 co of lilt sufrc aid tothe conical isk + filppartus Awith 00800 mal /dn?kMnO faq) '* titrates the solution of Fe" with the 0.00500 mol / dm’ KMnO,(aq) until theta permanentpnkeoauraacen inthe coicalfask + repeats thetivaton three tines 2 ‘Theequaton forthe reaconsshorn Winds Se" te Me SF ‘a. Suggestwhy dilute sulfuricacidis addedto the conical ask. 0 sy poavaperNo.10. 41 www.ilmge.com fA. Scanned with CamScannerVv Give the formu ofthe ion responsible forthe pnkclourseen atthe end 0.5) point i) The diagrams show parts of apparatus A with the quid levels atthe beginning and the end of titration 3. Bl Record the values in the result table. seston Complete the results table foreach of titration 1, 3.90 4. aay ea” Pa exdng TirationNomber [1] 2] 3 [4 ‘ 1 final reading / cm" 172 | 34.1 16.9 initial reading / cm’ 0.0 | 172 volume used / cm? 16.9 16.7 1 Best ration resus (7) “I ‘Summary: Tick(¥) the best titration results. Z iv) Use the ticked values to calculate the average volume of 0.00500 mol / dm’ KMnO,(aq) n) used. W) A second student does another series of titrations using the same method and 0.00500 mol /dm' KMn0,(a9). This student obtains an average volume of 16.9.cm’. 1 The equation for the reactionis shown, Mn0,- + SFe"" + 8H+ + Mn" + SFe" + 4H,0 Scanned with CamScannerpation 3 ‘Complete the results table for each of titration 1, 3 and 4. yea resaty 9 bat tesang Tusisstonter | s]2 [3s] ‘ 1 final reading / cm’ 17.2 | 341 16.9 ao [ma] | 169 767 ! , ‘Summary: Tick (¥) the best titration results. 1) Used ticked values to caluate the average volimeof 0.00500 meld kMnO daa) ¥) A second student does another series of titrations using the same method and (0.00500 mol dm’ kMnO,(aq).This student obtains an average volume of 16.9 cm. m The equation for the reactionis shown. MnO,- + SFe™ + BH ~ Mn" + SFe + 44,0 vi) Calculate the number of moles of MnO,- used by the second student. go mM vii) Calculate the number of moles of Fe" ions presentin the 25.0.cm’ sample of solution. m Scanned with CamScannerSECTION-B Q.2: Encirele the correct option. 1). The heat of neutralization ofan acid by a base is given by: H'+ OH ~H,OOH = 137 cal. The heat of neutralization of one mole of sulphuric acid with two moles of NaOH willbe: m A. -27AKeal B -137Keal © -123Keal (ese D. -685Kcal fen 1) The Rfvalue of PURPLE colour inthe chromatogram given @ |oue i Mm ih A 02 B06 c 08 D. os |—@ |re Origin ili) Which techniqueis also knownas colour writing? m A NMR B. Mass spectroscopy Chromatography D. Alloftheabove oO iv) Which ofthe following is used asa spraying reagentin paperchromatography? {11 A. Cone Het ‘ B._NaCésolution © Ninhydrin solution D. CuSO, solution ooh, 0 vy) Thermochemistry provides useful information about: m ‘A. bondlength B. bondenergy Scanned with CamScannerA 02 B 06 c 08 D. os fil) Which techniqueis also knownas colour writing? A NMR B. Mass spectroscopy Chromatography D. Alloftheabove 11 en| re cf —0 |pee m Iv) Which of the followingis used asa spraying reagent in paper chromatography? [1] A Conc Het B.NaCtsolution Ninhydrin solution D. CuSO, solution v)_ Thermochemistry provides useful information about: A bondlength B. bondenergy molecularstructure D. bondorder vi) Theextent ofionizationincrease ‘on decreasing the temperature of solution A B. onaddition of excess watertosolution c ._ onstirring the solution vigorously fo) ren Scanned with CamScannerSECTION-A 4: tron tablets are used to treat ron defiiencyin the body. Iron tablets contain ron ons, Fe". aos ‘Thenamesof theapparatusare Deen cee teprodehe wa, a [ean ]ass as tral ree rong oP Terao] Sianeecea Tor co fwapor po vole of 060 melon aa] 172 | 169 | 4 | 167 ease naa) a : Tick(V) the best tiation results Theticked values to calculate the average volume of 0.00500 mol/ dim KMnO, aq) used Averagevolume 1622167, sae’ oO ‘Thenumberofmolerof MnO,-used bythe second student ‘Molarity= oof moless1000/ average volume Noofmoles = MolartysAveragevelume /1000, = o00s00% 168. 1008 = 0.0000845 moles ‘The number of moles off ions with MnO" ratio present inthe 2.0 cm sample with es Balineed equation ba a RatioofMno™ Fe ‘10000845 += 500000805 ad Scanned with CamScannerae =168cn ‘Ans v) Thenumberofmoles of MnO,~used by the second student ‘Molarity = no of molesx 1000/ average volume ‘Noof moles = Molarty x Average volume / 1000 = 000500% 168 = 010000845 moles ‘Ans, v) The number of moles of Fe” ions with MnO” ratio present in the 25.0 em’ sample with respect to balanced equation Ratioof MnO" : Fe ‘0.000084, = 5x0.0000845 assenees az ans 0A Ans 8 Ans) Ans WC 44 Star Chemistry Practical Based Assessment (PBA) — FSc. 11th (Federal Board) Scanned with CamScannerPAPER Mo. 8 PRACTICAL BASED ASSESSMENT (PBA) NOTE: Attempt all questions. Write your answer within the provided space. SECTION-A Q.1: Determine the value of X by Volumetric Method in the given sample of 6.30 g of (COOH),.XH,0 dissolved per dm’ with standard solution of 0.1M NaOH. Apparatus used: Burette, pipette, funnel, conical flask, beakers, iron stand. Chemical used: Indicator Phenolphthalein, Oxalic Acid, 0.1M NaOH, Distilled water. 1) Definestandard solution. m re Nan An if) Write the equation between (COOH),. XH, + NaOH ~ m Iii) Whatis the mole ratio between these two reactants? mM Scanned with CamScanner‘Write the equation between (COOH),-XH, + NaQH = m ‘Whats the mole ratio between these wo reactants? m Use the information below mentionedandtocompletetheresultsinatable. (3) Titration Number 1 2 p= Tal reading / en? 98 3041 7 initial reading / cm’ 0.0 39 wee iieoon, 29 02 best vation resus Inthe table tick the best titration results Use these best results to calculate the average volume of (COOH), XH,Oused, Calculate the molarity of (COOH), XH,O solution from 10ml of NaOH taken to average volume of (COOH) ,.XH,Oused with the help of balanced equation. m PBA PaperNo.11. 45 Scanned with CamScannervi) Find Xwater molecules of (COOH) , XH,O? a SECTION-B - Q.2: Encircle the correct option. 1) The heat neutralization of an acid “A with a base “8° is -13.7 Kcal. Which of the followings true for Aand 8? ru] A. Aisstrong and Bis also strong B. AisstrongandBisweak . AisweakandBisstrong D. AisweakandBis alsoweak ii) The result ofa paper chromatography experiment are shown. 0 san aquecussohsion ofasaltl aGroup eer, ‘is an aqueoussolution of asaltof atransition element. snene Which rowiscorrect? nom Scanned with CamScannerSECTION-B ~ Q.2: Encircle the correct option. i) The he neutralization of an acid “A” with a base “B” is -13.7 Kcal. l Which of the followingis tue for Aand B? fy A. Aisstrong and Bisalso strong B. Aisstrong and Bisweak . Aisweakand Bis trong D. Aisweakand is alsoweak fi) The esult ofa paper chromate Xisanaqueous solution of as Yisanaqueous solution of Wri raphy experimentare shown. m ‘of aGroup|elempnt. ofatranston element. satvent or rowiscorrect? Targer R, value | requires a locating agent A B © D. x x oO x Y Y x cam a Y y 1) Paper chroma tography is used to determine the R values forfour diferent fad ings Which food colouringhas an value of 087 i) af sober ont ze | . opt taeine ‘46 _ Stat Chemistry Praca Based Assessment (PBA) — FS. 11th (Federal Board) ——- -www.ilmge.com - Fe. Scanned with CamScannerly) Inthe chromatography shown, which label represents the solvent front? a c v) An excess of aqueous silver nitrate is added to aqueous barium chloride and precipitate is removed by filtration. What are the mainionsinthefiltratepresent? (1] A 8. c D. ‘Ag’ and NO,- ‘Ag’. Ba" and NO,- 2 82" and NO,- Ba" ,Ct-and NOM vi)_ Inthe presence of commonion, the ionization of an electrolyte will? m A 8. c D. Increase Noeffect, Moderate change Decrease ROUGH WORK Scanned with CamScannerete o www. ilmge.com Beonscannee SECTION-A {2X eterine the wl of by Yuna Method in the gen sample of 6209 of (0m, ‘Stsalvedperdnv withvtandordsohivons( 0.14 MaOH. m0 fae) Acandard soni chen ston wich hase now concen Sint saonct aur enenpentr ha bees ancercued To prepare asondasoution sgt Serceteegene a ae echelon eee whet end eoenemoans isusually expressed in terms of molarity (M) or moles per dm’ (mol /dm'). ‘Ans Theequationbetween (COOH), XH,0 + NSOH = (COOH), XH,O + 2NaOH=(COONA), + 2XH,0 ‘Ans i) Themoleratiobetweenthese tworeactansis (COOH), HO: NaOH 1 2 ta M1 [Ricunatiembe | ——T 7 tanemaied [88 ry intresting ent | 00 s as waaensogpoon | a8 m7 7) wor axaaeontea [FEET a al lnthetable.tickthe best titration ests Use these bestresuts to calculate the average volume of(COOH),XH,Oused, 99+99/2 = 99cm’ ‘Ans v) According to molarity equation Musas MV/0, (COOH), XH,0:NaOH Scanned with CamScannerInthe table, tick the best titration results Use these best results to calculate the average volume of (COOH), XH,Oused. 99+99/2 = 99cm" ‘Ans v) According to molarity equation MMJay= MI, (COOH), xH,0:N20H fea M1x99/120.1%10/2 M1 20.1%10/99x2 Mi =005M ‘Ans vi) Find X water molecules of (COOH),-XH,O? Mrof{(COOH) ,XH,0 = 90+ 18x “Amounting/dm’ = Molaiy xMalmass of Oxalic Acid 63 =005x(90+ 180 2 63/005 =90+ 16K 126 =90: 18x 12690= 18% 36nt=x Xe2 RESULT: Waterofexystalization of Oxalic Acid =2 SECTION-B am DA ans D8 ans) ans WR an owe ans vO Scanned with CamScannerPRACTICAL BASED ASSESSMENT (PBA) NOTE: Attempt all questions. Write your answer within the provided space. SECTION-A Q.1: The given solution contains 8.0 g of a mixture of oxalic acid and sodium oxalate in 1000 em’. Determine the percentage composition volumetrically of a mixture Dehydrated oxalic acid and sodium oxalate. ‘Apparatus used: Burette pipette, funnel, conical flask, beakers, iron stand. Chemicalused: Indicator Phenoiphthalein, Oxalic Acid 0.1M NaOH, Distilled water |) Whatis Volumetric analysis? 2 m li). Write the equation between (COOH), 24,0 + NaOH ~ m {il)_Whatis the moleratio between these two reactants? m iv) Usetheinformation below mentioned andtocompletetheresultsinatable. [3] Titration Number 7 2 3 fina reading Jem? 101 299) Scanned with CamScanner1: The given solution contains 8.0 9 of a mixture of oxalic acid and sodium oxalate in 1000’ cm’. Determine the percentage composition volumetrically of a mixture Dehydrated oxalicacid and sodium oxalate. ‘Apparatusused: Burette, pipette, funnel, conical ask, beakers, iron stand. Chemical used: Indicator Phenolphthalein, Oxaic Acid 0.1M NaOH, Distilled water. 1) Whatis Volumetric analysis? m ii) Write the equation between (COOH), 2H,0 + NaQH = m iit) Whatis the mole ratio between these two reactants? 1m ty) Usetheinformation below mentionedandtocompletetheresultsinatable. [3] Titration Number 1 2 3 final reading / em 104 299 ° intial reading / em 00 100 Z| ‘volume of (COOH sono 99 99 best titration results Inthe table, tick the best titration results Use these best results to calculate the average volume of (COOH), 2H,Oused. Scanned with CamScannerli) Write the equation between (COOH),.2H,0 + NaOH ~ m iii) Whatis the mole ratio between these two reactants? mM iv) Use the information below mentioned and to complete the results in a table. BI) Tivation Number 7 z Hl final reading / cm? 10.1 29.9 ° initial reading / cm’ 0.0 10.0 egyaicoom, .3 39 est ation es Inthe table, tick the best titration results ‘Use these best results to calculate the average volume of (COOH),.2H,Oused. 'v) Calculate the molarity of (COOH), 2H,0 solution from 10ml of NaOH taken to average volume of (COOH) 2.2H,Oused with the help of balanced equation. o) PBA Paper No. 12 49 www.ilmge.com rams Scanned with CamScannerSECTION-B Q.2: Encircle the correctoption. |) Whatis Rfvalue meansin Chromatography? m ‘A. The distance covered by a component in a mixture in relation to the distance covered by the solvent. B. The distance covered by a solute in a mixture in relation to the distance covered bythe solution. _Thedistance covered by solution ina misture in elation to the distance covered bythe solvent. D. The distance covered by a solvent ina mixture in relation to the distance covered bythesolute. i) A student carries out an investigation on different plant extracts using paper chromatography. The experimental set-up he usesis shown below. i Where should he place the samples of plant extract? Choose youranswer ABCD aa ‘A. Onthepencilline B. Below the pencillineinthe solvent pect Exactly 1 cmabove the penc D._ Exactly 1cmbelow the penci fi) Ayellow metallc solid, Wis soluble in water. Which method of separation can be used toobtain the solid W from an aqueous solution? io) ‘A. Neutralisation short Scanned with CamScannerWw) Ina saturated solution of an electrolyte, the ionic product of their concentration is constant ata constant temperature, and this constant forelectrolyteisknownas (1) A. Ionicproduct 8. Solubility product © onization constant B._Dissociationconstant 1 On passing a current of hydrochloric acid gas in a saturated solution of sodium chloride, the solubility of sodium chloride 1 ‘A Decreases B. Increases © Remainsunaffected D. Sodium chloride decomposes vv) Commonion effect finds extensive application in: nm Quantitative analysis Qualitative analysis Thermalanalysis Spectroscopic analysis ———, Scanned with CamScanner pne>ar SECTION-A, Thegleenoltlon contain 8.03 of amintureof ral ac and sodium oxalatln 1000’. Determine the percentage composition volumeticaly of emorture Dehydrated ovalictld end sodium oxalate ‘Ans 1 Wolumetic ani «chemical rata procedure bed on messwement of volumes of reaction in solons W uses tration to determine the Concentration of solution by earehay ‘mestrig thewolume of one soon need toreactwat another ‘Ans i) (COOH), 2H,0(ag) + 2NsOHaq)—NaO409) +4440 ‘Ans ii) Moleratio between (COOH), 240 (a) and NaOH according tobalanced equations (COOH, 2H,0NGOH 1 2 ‘Ans M1 [Tiration Number 7 2 3 nal eading fem? vos 193 299 inl reading em? 00 700 arg] ‘alum of {C00 Tor 38, 3 Soro est ivan ee 7 7 Inthe table, tick he besttitationesuts ‘Usethese best results to calculate the average volume of (COOH)2.2H20used. 99+99/2 = 99cm ‘Ans ¥) Calelate the molarity of solution from 10m of NaOH taken to average volume of {oor Oosegvan ne heiperbsance equation, ‘According tomolaity equation MV/n,2M\/0, (oom 20": Nao tesortoanet072 M1 =01410/992 a1 0054 ‘Ans vi) Determine te percentage composition volumetrically of amiture oxalic acid & sodium oxalate. Mrol(COOH), 24,0 = 126 “Amountof (COOH), 24,0in gdm = MoartyxMoLmassofOalic Acid 005x126 ‘i a ‘Amountot iatue/dm3« 80gram Scanned with CamScannerans RREREE “1 Catculate the molarity of (COOH), 24,0 solution from 10ml of NaOH taken to average volume ot (Cor, 2 Oca vin ehepafbaincedequaton. 1) Determine the percentage composition volumetrically ofa mixture oxalic acid & sodium oxalate, Mrof(COOH),. 24,0 = 125 ‘Amount of (COOH), 24,0in g/d» MoarityxMotmass of Oralic Acid 7 #0050126, : 639 ‘Amountof mieture/ém3= 80 gram 9 ofmiturecontains oxalic acid = 639 YO nn 63410078 = 78S “While percentage of sodium oxalte = 100-787 22125% RESULT: Percentageot Onalic Acid = 78.75% and percentage of sodium oxalat SECTION-B DA ma w 8 ms wa 2 we ‘52 Star Chemistry Practical Based Assessment (PBA) — ESc. 11th Federal Board) www.ilmge.com_ Scanned with CamScanner[NOTE Artempt ll questions. Write your answer within the provided space. SECTION-A (21: Purpose of this isto determine the percentage composition ofthe spun volumetric ering ie gant det i) sravand The ‘Bienen contain 0 g mitre of anhydrous occ andheeo, S05 cm Soltion Determine the percentage purty of anhydrous oxahicaeidin thé miture. ‘Apparatusused: Burete pipette funnel conical ask beakers, fon stand ‘Chemical wsed:indeator Phelps OraicAcid 0 1MEOH Dita water, 1) Dieremiotebetweentirant (ey anduivand? m 19 witeteequtonbreensncrotontcscdandetasumtydotite 7D 1 |w) Usetheinformation belowmentionedandtocompletetheresutsinatable. (3) Scanned with CamScanner< ¢ W) Wrtetheequatonbetweenanhydrousoralcacidandpotasiumhydroxide [1] Ii) Whatisthemoeraiobetween these tworeactants? m e iv) Use the information below mentioned and to complete the results ina table. BI TieatlonNomber[ z 7 final reading / cm’ 1s 30.0 initial reading / cm? 1,00 10.0 wugegiicoon, 100 100 best titration results PBA Paper No. 13 53 www.ilmae.com Scanned with CamScanner¥) Calculate the molarity of anhydrous oxalic acid solution from 10m of KOH taken to average volume of anhydrous oxalic addused with the help of balanced equation. (2] vi) Determine the percentage composition volumetrically of a mixture oxalic acid & Potassium oxalate. Ry SECTION-B Q.2: Encircle the correct option. ') For different dyes labelled P,Q. R and S produced the chromatograms as shown below. til Which dye has an, value of 0.7? sovene A. Sonly 4 Scanned with CamScanner> SECTION-B 2.2: Encircle the correct option. ') For different dyes labelled P, Q. R and S produced the chromatograms as shown below. tH Which dyehas an Rvalueof072 fpmommm—b sonene A. Sonly Cc Ronly . BothPanda : D. None tony i) Astudent has been givena sample of an sores cron ppart of the investigation the student will have to use 77Zcating agent to make the colourless amino acid spots visible. The Rf valueis then &#{culated to identify the a a Which row describes the correct steps? How ta add the locating agent | How to identify the amino acid ‘A | Add to solvent ‘Calculate the 8 | Spray on the chromatography | Compare the R, value to that of paper before the experiment ‘known solvent | Spray on the surface of the solvent | Perform the experiment again and compare the f, value D | Spray on the chromatogram ‘Compare the R, value to that of ‘amino acids 54 Star Chemistry Practical Based Assessment (PBA) HM (Federal Board) A ay Scanned with CamScannerwi) » Itisimportant that substance used inthe synthesis of medicines are pure as impurities in these products can be detrimental to our health. Samples of pure and impure paracetamol were analysed using chromatography. The resulting chromatogram fs shown below. fo The impure sample of paracetamol was contaminated with one of the new chemicals used during its synthesis. WhatistheRfvalueofthe chemical? shert hort stom Fas A. 070 0 |ozrn) x= srr mee B. O75 9 [2180 | y= © 065 ses =—=— D. 08s x The solubility of KCIO, in wateris suppressed by adding: m AL NaCiO, BL Nace Kee Wz D. KMnO, Dissociation of H,S in watercan be suppressed by the: m A. NHI : B. NHOH NaOH DB. HCI ImAgClsolution, some salt of NaClis added then AgClwillbe precipitated dueto: [1] ‘Commonion effect Solubility effect Electrolytic effect Unsaturation effect poe UGH WARE — Scanned with CamScanner |yy yu QA: Purpose of this eto determine the pose ‘experiment SECTION-A "The gen soltion contains 4. 3 9° ‘uring the tration of titrant (titer) and ttrand. ‘mixture of anhydrous oxalic seid and K;C,0, In 800 em’ solution. Determine the percentage purty, ‘snhydrous oxalleaei in this mixture. Ane ans Ans 1) + Thetitrantisthe solution that is added tothe tiand in a tration experiment. It is typically a ‘rong acd or base and ts concentration is knovn. The tivant is usually added into aitand fn ‘conics fas) using aburete ‘+The ttrand isthe soltion that is being analyzed in a titration experiment. Its concentration i unknown andis being determined through the use of the titrant. The titrandistypcaly anacidor basetakenina conical Mask with indicator. 4) (COOH(aq) + 2KOHIag) =K,C,0aq) + 24,0 i) Mole ratio between (COOH),(aq)and KOH according to balanced equation is (COOH): KOH ‘ere ™) [Titration Num 7 z P 3 final reading / cm’ 705 200 300 Initial reading / em? 1.00) 100) 200 volume of Se 35 100 700) ‘best titration results 7 v Inthe table, tckthe best titration results Use these best results to calculate theaverage volume of anhydrous oxalic acid used. 100-190 = 100m" ‘According to molarity equation (COOH), : KOH M1710. 94 32 Tomes Scanned with CamScannerent 109 700 eas z 7 Inthe table, tick the best tivation results Use these best results to calculate the average volume of anhydrous oxalic acid used. 100-190 = 100em" ‘Ans v)_ According tomolarity equation M Mv. My, wi sonxaaea 0 wo Mi = 005 ‘Ans vi) Mrof(COOH), BEEEER =90 ‘Amount of (COM), 2H,Oin g/dm’ = Molarity x Mol:mass of Oxalic Acid '005%90 as Amountofistrein 00cm = gram Aevountofmotrein100dem'= 80 70m sgglritreconisoaiacd 433" =5675% While percentage of potassium oxalate = 100-56.25 « 43.75% RESULT: Percentage of Oxalic Acid = 56.25% and percentage of potassium oxalate = 43.75% SECTION-1 Ssd8se poneon Scanned with CamScannerle. 19 PRACTICAL BASED ASSESSMENT (PBA) NOTE: Attempt all questions. Write your answer within the provided space. SECTION-A 2: stanarca the gan slain of KM, and cael lume of KMn0, required for preparing, 1 dm of 0.01M KMn0, solution veAnetricaly. You are proviced Ot Miron Sulphate solar. Apparatusused: Burette pipette, funnel, conical faik, beakers, iron stand. O° ‘Chemical used: 0.1 M ion) Sulphate, 00200 mal / dn’ potassium manganate(i, Distled water 1) Whatismeantbyredox tivation? m 1) Whichindieatoris used inthistration? mn Ii write the equation between ron Sulphate, potassium manganate() mn iv) Whatisthemoleratiobetweenthese two reactants? 0 Scanned with CamScanneriii) Write the equation between Iron ) Sulphate, potassium manganate(VIl) mM iv) Whatis the mole ratio between these two reactants? ro] V) Use the information below mentioned and to complete the results in a table. BI Serial] Initial Reading | Final Reading | Volume of KMnO, | Best Titration No. Lem’ Lem’ Jem’ Results 1. 10.1 70.1 2 100 98 3. 200 298 In the table above, tick the best titration results use these best results to calculate the average volume of potassium manganate (viilused. www.ilmge.com & ‘amScannet Scanned with CamScannerow vi) Calculate the molarity of potassium manganite (Vil) solution from 10mi of Iron (I) Sciphate solution taken to average volume potassium manganite VI) used with the help of balanced equation. mn vii) Calculate the volume of KMnO, required for preparing 1 dm’ of 0.01M KMno, solution, 2 SECTION-B Q.2: Encirclethe correctoption. |) Amixture of sugars can be separated out by paper chromatography. a ‘The student sprays the dried chromatogram with alocating agent. Whyisthisused? ‘A. Tohelp the sugars dissolvein the solvent To stop the sugars reacting with each other © Toform coloured spots with thesugars D. Toaidthe separation ofthe mixture Scanned with CamScannerSECTION-B Q.2: Encircle the correct option. |). Aminture of sugars can be separated out by paper chromatography. m The student sprays the dried chromatogram witha locating agent. Whyis thisused? A. Tohelpthe sugars issolveinthesolvent B. Tostop the sugars reacting with eachother C. Toformcoloured spots with the sugars 1D. Toaid the separation of the mixture ii) Paper chromatography was used to determine ° preservative X, is present in four samples obtained from four Sifferent packaged foods labelled A 8, C, andD. TH | o 8°38 ‘The result ofthe analysis ofthe foodstuffs are shown in the ° diagram below. Cn ee ‘Which foodstuff contains? A B c oo ‘crvomatoy apne paper abanned | 0 0 fil) According to the given chromatogram, which sample is showing low Rf value? oO) * A. BothX&Y Samples Ll pace B BothX@z Samples Bothy azSamples “ D. OnlyxSample eae 58 star Chemistry racial Based Assessment PRA) —FSc 11h Federal Board) www.ilmae.com Scanned with CamScanner &Ww) onization of hydrogen sulphide gasis suppressed by: m A KCl B NaCl © HCl D. KCIO3 ) ForthereactionH+ + OH- ~H,0,thechangeinehthalpyiscalledheatof? [1] AL Reacti B. Neutralization © Combustion D. Solution vi) Theexothermic process/reactionis: 0 A. Neutralization 8. Sublimation © Evaporation D. Boiling ROUGH WORK Scanned with CamScannerSECTION-A G1: standardize the given solution of KMnO, and calculate the volume of KMnO, raqulred for SnPotootmnntnd,zaktion voumenialy. NovareprovidedO.1 Miron i) Sulphate selalon: ?* ‘Ans @) RedoxTiration Aredoxreaction wolves an onidation and reduction reaction between the ang {ivand) andthe tron dunngachemeatrencvon smuttaneousy ‘Ans i) KMn0, sett ‘Ams fi) 2XNINO, + 10FeS0, + 84,50, ‘Ans i) KMOO, » FeSO, 2: 0 SFe$0), + 2Mn$0, + $0, +840 am vy ‘Initial Reading: ‘Volume of KMn0, | Best Titration Lem’ Results, Tat asm os 8 z _| = 7 = oa Z Inthe table above. tickthe Best tiration results Use these best results to calculate the average volume of potassium manganite (Vi) used. Herston wre 82eor 3d Mi -on2mia0, 2 fans wi Actofngtoiioneqetion Mavens Mave Oozevi = ootxto00 ‘vi=001% 1000 902 Scanned with CamScanner& PEPER? Ss 3 Se = 200 a {othe table above. tick the best tration result Use these best results to calculate the average volume of potassium manganite (Vi) used. See SSS According to dilation equation Concentrated solution: dite solution Rav have Oozxv1 = 001x000 Visors: a vi = 490em" Result: Take 490 cm from 002M KMnO, olution in 1CO0em' volumetric Imrkwatted water ThswilbeGOTNiRnO ston” OMMEUE Mask and top up ibe SECTION. 2 penoen Scanned with CamScannerPAPER fo. 0S PRACTICAL BASED ASSESSMENT (PBA) NOTE: Attempt all questions. Write your answer within the provided space. SECTION-A 1: Purpose of this experiment is to determine the percentage impurity of the sample solution by volumetric method when the given solution contains 10 gms of a ‘mixture of Na,SO,8 Na,CO, dissolved per dm’. 0.05 MH,SO, solutions isgiven. Apparatus used: Burette, pipette, funnel, conical flask, beakers iron stand. Chemicalused: 005M H,.SO, solution, Distilled water, 109 mixture of Na,5O,8 Na,CO, intdm ’) Whatisthe principle of thistitration? m0 i) Whichindicatoris usedin this titration & what will be the end point? mn ili) Write the equation between Na,CO,and H,SO, m iv) Whatis the mole ratio between these two reactants in a balanced equation? m | Scanned with CamScannermixture of Na,SO,8& Na,CO, dissolved per dm’. 0.05 MH,SO,solutions is given. — Apparatus used: Burette, pipette, funnel, conical flask, beakers, iron stand. Chemical used: 0.05M H,SO, solution, Distilled water, 10g mixture of Na,SO,& Na,CO, intdm’ 1) Whatis the principle ofthis titration? m0 fi) Whichindicatoris used in thistitration & what willbe the end point? W Til) Write the equation between Na,CO,and H,SO, oy |v) Whatis the mole ratio between these tworeactantsinabalanced equation? [1] V1 Usetheinformationbelowmentionedandtocompletetheresultsinatable. £3) Serial] initial Reading | Final Reading | Volume of #,S0, | Best Titration No | fem fem yen" Results. t 21 10.1 z 120 28 3 120) 3 Inthe table above, ick the best tiation results use these best results to calculate the ‘average volume of ,S0, used. Scanned with CamScannerA) CamScanner 7 gz vil). Determine the percentage impurity of the sample solution. SECTION-B. Q.2: Encircle the correct option. 1) Separation of the constituents of a mixture of inorganic compounds containing two ‘cations, Pb and Ca, using which chromatographic technique? 1) A. Column Chromatography B. Thin Layer Chromatography Scanned with CamScannerSECTION-B. Q.2: Encircle the correct option. a iii) iy) ‘Separation of the constituents of a mixture of inorganic compounds containing two ‘ations, Pb" and Ca", using which chromatographic technique? 1 ‘A Column Chromatography B. ThinLayerChromatography Paper Chromatography 1D. GasLiquid Chromatography ‘Acomponenthaving small value of distribution coefficient mostly remainsinthe (1) A. Mobile phase B. Stationary phase Solvent 1D. Chromatographic tank During chromatography, sip shouldbe dipped into solvent mixture to depth of which height? 1 A 34mm B. 4.5mm © 67mm D. 5-6mm When an acid (H+) is added to alkali (OH-), the productis ms A. hydroxides B. water salts D. hydrogen gas 62. Star Chemistry racial Based Assessment (PBA) — FSc. 11th Federal Board) ' www.ilmge.com = Scanned with CamScanner¥)_Inneutralization reactions, for datalogging m ‘A. biosensors should be used B._gassyringeshallbeused Conductivity meters shallbeused D._ Heat sensors should beused wv When does precipitate form? m0 ‘When something is insoluble in solution. ‘When something is soluble in solution. Wheneverasolidis added to solution. Whenever liquid is added toa solution. poe ROUGH WORK Scanned with CamScannerSECTION-A Om a ren er Sam SN Foantebinettoctee sae) wissen can screens fo Neyaneaendpiteougeed fos 19 4s. 1450S, fm) NED, HD “9 Does [yarns [era | pra ae 3 wo | __199) 29) Inthe table above tick thebesttivationresults ‘Use these best resultsto calculate the average volume of SOwused, a8gg8 = 988 ow [Ans wi) Acording tomalanty equation MY MY, ah ago, + 50, t 7 4 wil oos 2 M1 =005MNa,CO, ‘Ans vi) MrofNaiCO,= 106 ‘Amount of Na,COjng/dmn'= MolatyxMolmassofNa,CO, =005"106 +=539/dm' ‘Amountofmiature givenis= 100 gram 10g of mixture contains N3CO,= 539 100 Scanned with CamScanner10g of mitre contains No,C0,= 5.39 1009. 53x 1 53% purity ‘wile percentageimpurity willbe «100-53, 47% Result: The percentage impurity ofthe sample soltionis 47% SECTION. az an 9c Ans 8 Ans ii) O ans) 6 ans 0D Anew) A G4 Star Chemistry Practical Based Assessment (PBA) —FSc. 11th (Federal Board) Scanned with CamScannerwww.ilmge.com Beanscane PRACTICAL BASED ASSESSMENT (PBA) [NOTE Attempt all questions, Write your answer within the provided space. SECTION-A, 11: Determine the percentage compariton of Iethod when the given rolution contains 12 gmt ‘solved per de O0SMH,SO, solution sgiven. Apparatus used: Burtt pipette funnel conc fick beakers rontand. Chemical used: 005M N50, slution,Diledate gmt fREIBKCO,n Ld 1D Whatisaciimetctination? m1 smple solution by volumetric Pi minture of kes eR, 1) Whichindeatorisusedinthistraon hate the endpoint? om 'W)_Witethe equationbetweenK.CO,and¥.S0, m Scanned with CamScannerwww. ilmige:ednt Besnscnnse ~ Vil) Determine the percentageimpurty of the sample solution t6Aolumetric method, Scanned with CamScannerSECTION-B Q.2: Encircle the correct option. 1) The purity of a substance canbe identified m ‘A. Chromatography B. Sublimation . Filtration D. Solvent Extraction i) Inchromatography, the stationary phase? mn B. Isaliqui €. Maybeliquid orgas D. Maybesolidorliquid iii) Inpaper Chromatography during identification of Ph2+ and Ca ions, whichagents u A. Oxidizing agent B. Dehydrating agent Locating agent D, Reducingagent 66 Star Chemistry Practical Based Assessment (PBA) — FSC. i eta toe www.iimge.com « |CamScanne: Scanned with CamScannerWw) Ca(OH),{s)= Ca" (aq) + 20H(2q) K,=5.5x10* at298K m The equilibrium in a saturated solution of Ca(OH), is represented above. In an experiment, a student repeats the experiment but this time places 50g of Ca(OH)(8) into 100.0mL of 0.0010M NaOH{(2q) instead of distilled water A. Less solid will dissolve, because the larger value of [OH] will ause the equilibrium Position tolie farther to the right. 8. Less solid will dissolve, because the larger value of (OH] will cause the equil Position toliefarther to theleft. More solid will dissolve, because the larger value of [OH] will cause the . rium equilibrium position tole farther to the right. More solid will dissolve, because the smaller value of [OH] will cause the ‘equilibrium position tole fartherto the left. VW) AQCN(s) <= Ag+(aq) + CN (a9) m The dissolution of solid AgCN is represented by the chemical equation above. In pu water, the equilibrium concentration of Ag" ions ina saturated solution is 7.7 x 1 ‘a'smail amount of solid NaCNV is added to the saturated AgCN solution, S ‘ofthe following would be observed? Thek, increases and more AgCn dissolve. A BL Thek, increase and some AgCn precipitates. The molar solubility of AgCN becomes smaller than 7.7 x 10°M and some AgCN precipitates. D._ The molar solubility of AgCN becomes larger than 7.7 x 10°M and more AgCN dissolves. Wi) The amount ofthe heat released when 20 mi0.5 NaOH is mixed with 100 ml0.1 M HCL isxbl. Heatof neutralizationis m A. -100xkd/mol 1 B. -50xki/mol .100xtd/mol D. SOxki/mol co Rous WorK | Scanned with CamScannerar SECTION-A Determine the ofthe sample solution by volumetric method when the giver: ‘sohion contains t2gmotambcare ct KEL RCO, daalved per Sm ns zORRE }O5MH,50,solutlon Isgiven. 1 Amethod of determining aaine substances (bases uing ration involving an acids known as Scns snte Sesion snd ese eacbons oe asa ahedneuwaesion eachons | Methy orange and end point willbe orange-red i) KC0,+H)S0,22>50,+H,0+C0, im Re: SO, Seal] titareping | Fal anna | Voline oO, ] Best tion of No Lem Lem Ten Results, [aa 0 100 a m0 100 7 = 80 Ba 8 Inte ablatovetcktbebes aon ets o eee bestest cathe orope volume of SO. ‘agian’ ooo 18 coring ely equation ia aes mete ‘RCO, : SO, at 10. 995 x10 to 412 vs 0smKc0, Wi) MeolK,c0,= 138, “Amount o¥,COjng/dm'» Moaryx MolmassofK,CO, 70050138 =699/ém" ‘Amountof mixture givenis = 120gram IagolmiureconairsKC0,*699 ‘pp Scanned with CamScanner