1

LAKSHYA JEE 2023

Haloalkane & Haloarene DPP-05

5. Aryl halides can be prepared by

Fe/Br
1.  2
→ (1) Sand mayer’s method
Dark
(2) Friedel-craft reaction
(3) Gattermann’s reaction
(1) (2) (4) 1 and 3

6. The conditions that is necessary in the preparation

of Aryl halides from benzene
(1) Low temperature
(3) (4) Both (2) & (3) (2) Absence of sunlight
(3) Presence of halogen carrier
(4) All of the above

2. 7. In Gattermann reaction, a diazonium group is

replaced by X using Y, X, Y are:
X Y
−

Set of reagents for above conversion is/are (1) Cl Cu/HCl
(1) (i) Conc ⋅ HNO3 + conc ⋅ H 2SO 4 ⊕
(2) Cl CuCl2/HCl
(ii) Cl2, sunlight −

(2) (i) Cl2, fe, dark (3) Cl CuCl2/HCl
(ii) Conc ⋅ HNO3 + conc ⋅ H 2SO 4 (4) Cl2 Cu2O/HCl
(3) (i) Conc ⋅ HNO3 + conc ⋅ H 2SO 4
8. Chlorobenzene can be prepared by reacting aniline
(ii) Cl2/fe/dark with
(4) (i) HNO2 (ii) Cu/HCl (1) Hydrochloric acid
(2) Cuprous chloride
NaNO + HCl Kl
3. C6 H5 − NH 2 →
2
o A → B + C ↑ (3) Chlorine in presence of anhydrous aluminium
0 −5 C
chloride
Here B and C are (4) Nitrous acid followed by heating with
(1) C6 H5 I, N 2 (2) C6 H5 l,O 2 cuprous chloride
(3) C6 H 6 ,l2 (4) C6 H5 CH 2 l, N 2

4. Aryl fluoride may be prepared from arene 9.

diazonium chloride using:
(1) HBF4 / ∆ Set of reagents for above conversion is
(1) NaBF4/∆
(2) HBF4 / NaNO 2 ,Cu, ∆
(2) NaNO 2 (298K) followed by NaBF4//∆
(3) CuF/HF
(3) NaNO2 (273K) followed by NaBF4//∆
(4) Cu/HF
(4) NaNO2 + HBF4 (273K)
 2

10. 11.

X is-
Above reaction is known as-
(1) Swarts Reaction
(2) Sandmeyer’s Reaction
(1) (2)
(3) Hunsdiecker Reaction
(4) Kolbe’s Reaction
(3) (4) None of these
 3

Answer Key
1. (4)
2. (3)
3. (1)
4. (1)
5. (4)
6. (4)
7. (1)
8. (4)
9. (3)
10. (2)
11. (2)

For more questions, kindly visit the library section: Link for app: https://links.physicswallah.live/vyJw

For more questions, kindly visit the library section: Link for web: https://physicswallah.live/tabs/tabs/library-tab

PW Mobile APP: https://physicswala.page.link/?type=contact-us&data=open

For PW Website: https://www.physicswallah.live/contact-us