1

LAKSHYA JEE 2023

Haloalkane & Haloarene DPP-06

1. The ease with which an alcohol can be halogenated 6. Which of the following compound gives same SN1
by treating it with HX in the presence of anhydrous and SN2 product?
ZnCl2 is Cl
(1) tertiary alcohol < secondary alcohol < primary
alcohol
(2) tertiary alcohol > secondary alcohol > primary (1) (2)
alcohol Cl
(3) tertiary alcohol > secondary alcohol < primary
alcohol (3) (4)
(4) tertiary alcohol < secondary alcohol > primary Cl Cl
alcohol
7. Which of the following SN2 reactions is the
2. In SN1 reaction, the first step involves the formation slowest?
of (1) CH3CH2CH2Br + HO– 

(1) Free radical (2) Carbanion
(3) Carbocation (4) Final product CH3CH2CH2OH + Br–
(2) CH3CH2CH2Cl + HO– 

3. The order of reactivities of the following alkyl
halides for a SN2 reaction is CH3CH2CH2OH + Cl–
(1) RF > RCl > RBr > RI (3) CH3CH2CH2I + HO– 

(2) RF > RBr > RCl > RI CH3CH2CH2OH + I–
(3) RCl > RBr > RF > RI
(4) RI > RBr > RCl > RF (4) CH3  CHCH3  HO 

|
4. The compound which undergoes SN2 reaction F
fastest is CH3 CHCH3  F
Cl |
OH
(1) 8. What would be the product when isopropyl chloride
Cl reacts with KCN?
(2) (1) Propene (2) 2-Methyl propane nitrile
(3) Propyne (4) Propane nitrile
(3) Br
Br 9. The increasing order of the reactivity of the
following halides for SN1 reaction is
(4) (I) CH3 –CH CH2 CH3

Cl
5. Among the bromides i-iii are below order of (II) CH3CH2CH2Cl
reactivity SN1 reaction is (III) CH3CO – C6H4 – CH2Cl
O (1) III < II < I (2) II < I < III
(3) I < III < II (4) II < III < I

10. In SN1 reaction, the order of reactivity of halides is

(1) 3° > 2° > 1° > methyl
Br Br Br (2) methyl > 1° > 3° > 3°
(i) (ii) (iii) (3) 3° > 2° = 1° > methyl
(1) iii > i > ii (2) iii > ii > i (4) 2° > 1° > methyl > 3°
(3) ii > iii > i (4) ii > i > iii
 2

Answer Key
1. (2)
2. (3)
3. (4)
4. (3)
5. (1)
6. (3)
7. (4)
8. (2)
9. (2)
10. (1)

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