Structure of Atom_36596229_2024_06_24_08_40

Structure of Atom
Problem Booklet
INDEX
Page No.
1. NEET (AIPMT) 01 – 05
2. Other Medical 05 – 15
3. JEE main (AIEEE) 15 – 17
4. JEE main (Online) 17 – 22
5. NCERT Exemplar 23 – 24
6. Hints & Solution 27 – 44

Chemistry Nitesh Vidyarthi-IITian, (IAS Mains Qualified)
STRUCTURE OF ATOM
(a) 211.6 pm (b) 211.6  pm
NEET (AIPMT) (c) 52.9  pm (d) 105.8 pm
1. From the following pairs of ions which one is not an 7. 4d, 5p, 5f and 6p orbitals are arranged in the order of
iso-electronic pairs? (2021) decreasing energy. The correct option is (2019)
(a) Fe 2 , Mn 2 (b) O 2 , F (a) 5f > 6p > 4d > 5p (b) 5f > 6p > 5p > 4d
(c) 6p > 5f > 5p > 4d (d) 6p > 5f > 4d > 5p

(c) Na , Mg 2 (d) Mn 2 3 8. Orbital having 3 angular nodes and 3 total nodes is
, Fe
2. A particular station of All India Radio, New Delhi, (a) 5p (b) 3d (2019)
broadcasts on a frequency of 1, 368 kHz (kilohertz). (c ) 4f (d) 6d
The wavelength of the electromagnetic radiation emitted 9. Which one is a wrong statement? (2018)
by the transmitter is [speed of light, c  3.0  108 m s1 ] (a) Total orbital angular momentum of electron in s-
(2021) orbital is equal to zero.
(a) 21.92 cm (b) 219.3 m (b) An orbital is designated by three quantum numbers
(c) 219.2 m (d) 2192 m while an electron in an atom is designated by four
quantum numbers.
 Z2  (c ) The electronic configuration of N atom is
Based on equation E  2.178  10 18 j
 n 2 
3. , certain
  1 1 1
conclusions are written. Which of them is not correct? 1s2 2s2 2p x 2p y 2p z
(2021)
(a) Equation can be used to calculate the change in (d) The value of m for dz2 is zero.
energy when the electron changes orbit. 10. Which one is the wrong statement? (2017)
(b) For n = 1, the electron has a more negative energy h
than it does for n = 6 which means that the electron (a) The uncertainty principle is E  t 
is more loosely bound in the smallest allowed orbit. 4
(b) Half filled and fully filled orbitals have greater
(c) The negative sign in equation simply means that the
stability due to greater exchange energy, greater
energy of electron bound to the nucleus is lower
symmetry and more balanced arrangement.
than it would be if the electrons were at the infinite
distance from the nucleus. (c ) The energy of 2s-orbital is less than the energy of
2p-orbital in case of hydrogen like atoms.
(d) Larger the value of n, the larger is the orbit radius.
h
4. The number of protons, neutrons and electrons in 175
71 Lu, (d) de-Broglie’s wavelength is given by   where
mv '
respectively, are (2020) m = mass of the particle, v = group velocity of the
(a) 71, 104 and 71 (b) 104,71 and 71 particle.
(c) 71, 71 and 104 (d) 175, 104 and 71 11. How many electrons can fit in the orbital for which
5. Which of the following series of transitions in the n = 3 and  = 1? (2016)
spectrum of hydrogen atom falls in visible region? (a) 2 (b) 6
(2019) (c) 10 (d) 14
(a) Brackett series (b) Lyman series 12. Which of the following pairs of d-orbitals will have
(c ) Balmer series (d) Paschen series electron density along the axes? (2016)
6. In hydrogen atom, the de Broglie wavelength of an (a) d z 2 , d xz (b) d xz ,d yz
electron in the second Bohr orbit is [Given that Bohr
radius, a 0  52.9pm] (2019) (c ) d z 2 , d x 2  y 2 (d) d xy,d x 2  y 2
1
Nitesh Vidyarthi-IITian, (IAS Mains Qualified) Chemistry
13. Two electrons occupying the same orbital are 21. According to law of photochemical equivalence the
distinguished by (2016) energy absorbed (in ergs/mole) is given as
(a) azimuthal quantum number (h = 6.62 × 10–27 ergs, c = 3 × 1010 cm s–1,
(b) spin quantum number NA = 6.02 × 1023 mol–1) (2013)
(c) principal quantum number 1.196  108 2.859  105
(a) (b)
(d) magnetic quantum number.  
14. Which is the correct order of increasing energy of the 2.859  1016 1.196  1016
listed orbitals in the atom of titanium? (2015) (c) (d)
 
(At. no. Z = 22) 22. What is the maximum numbers of electrons that can be
(a) 4s 3s 3p 3d (b) 3s 3p 3d 4s associated with the following set of quantum numbers?
(c ) 3s 3p 4s 3d (d) 3s 4s 3p 3d n = 3,  = 1 and m = –1 (2013)
15. The number of d-electrons in Fe2+ (Z = 26) is not equal (a) 4 (b) 2
to the number of electrons in which one of the (c) 10 (d) 6
following? (2015) 23. The outer electronic configuration of Gd
(a) d-electrons in Fe (Z = 26) (At. No. 64) is (2013)
(b) p-electrons in Ne (Z = 10)
(a) 4f 5 5d 4 6s1 (b) 4f 7 5d1 6s 2
(c) s-electrons in Mg (Z = 12)
(d) p-electrons in Cl (Z = 17) (c) 4f 3 5d5 6s2 (d) 4f 4 5d5 6s1
16. The angular momentum of electron in ‘d’ orbital is equal 24. Which of the following is not permissible arrangement
to (2015) of electrons in an atom? (2013)
(a) 2 3 h (b) 0 h (a) n  5,   3,m  0,s  1/ 2
(c ) 6h (d) 2h (b) n  3,   2,m  3,s  1/ 2
17. What is the maximum number of orbitals that can be (c) n  3,   2,m  2,s  1/ 2
identified with the following quantum numbers?
(d) n  4,   0,m  0,s  1/ 2
n  3,   1, m   0 (2014)
25. The number of spherical nodes in 3p orbitals are/is
(a) 1 (b) 2
(2013)
(c) 3 (d) 4
(a) one (b) three
18. Be2+ is isoelectronic with which of the following ions? (c) none (d) two
(2014) 26. Maximum number of electrons in a subshell with
(a) H+ (b) Li+   3 and n  4 is (2012)
(c) Na+ (d) Mg2+ (a) 14 (b) 16
19. Calculate the energy in joule corresponding to light of (c) 10 (d) 12
wavelength 45 nm. 27. The correct set of four quantum numbers for the valence
(Planck’s constant, h = 6.63 × 10–34]s, speed of light, electron of rubidium atom (Z = 37) is (2012)
c = 3 × 108 m s–1) (2014) (a) 5, 1, 1, +1/2 (b) 6, 0, 0, +1/2
(a) 6.67 1015 (b) 6.67  1011 (c ) 5, 0, 0, +1/2 (d) 5, 1, 0 +1/2
28. The orbital angular momentum of a p-electron is given
(c) 4.42 × 10–15 (d) 4.42 × 10–18
as (2012)
20. The value of Planck’s constant is 6.63 × 10–34 Js. The
speed of light is 3 × 1017 nm s–1. Which value is closest h h
(a) (b) 3
to the wavelength in nonometer of a quantum of light 2 2
with frequency of 6 × 1015 s–1 ? (2013)
(a) 50 (b) 75 3h h
(c) (d) 6
(c) 10 (d) 25 2 2
2
29. The total number of atomic orbitals in fourth energy (a) 1105 cm s 1 (b) 11011 cm s 1
level of an atom is (2011)
(a) 8 (b) 16 (c ) 1 109 cm s 1 (d) 1 106 cm s 1
(c) 32 (d) 4 37. consider the following sets of quantum numbers:
30. If n = 6, the correct sequence for filling of electrons n  m s
will be (2011)
(i) 3 0 0 +1/2
(a) ns   n  2  f   n  1 d  np (ii) 2 2 1 +1/2
(iii) 4 3 -2 –1/3
(b) ns   n  1 d   n  2  f  np
(iv) 1 0 –1 –1/2
(c) ns   n  2  f  np   n  1 d (v) 3 2 3 +1/2
Which of the following sets of quantum number is not
(d) ns  np   n  1 d   n  2  f possible ? (2007)
31. The energies E1 and E2 of two radiations are 25 eV and (a) (i), (ii), (iii) and (iv)
50 eV respectively. The relation between their (b) (ii), (iv) and (v)
wavelengths i.e., 1 and  2 will be (2011) (c) (i) and (iii)
(d) (ii), (iii) and (iv)
(a) 1   2 (b) 1  2 2
38. Given : The mass of electron is 9.11 × 10–31 kg. Planck
1 constant is 6.626 × 10–34 J s, the uncertainty involved
(c) 1  4 2 (d) 1   2 in the measurement of velocity within a distance of 0.1
2
Å is (2006)
32. According to the Bohr theory, which of the following
transitions in the hydrogen atom will give rise to the (a) 5.79  105 m s 1 (b) 5.79  106 m s1
least energetic photon? (2011)
(c) 5.79  107 m s1 (d) 5.79  108 m s 1
(a) n = 6 to n = 1 (b) n = 5 to n = 4
(c ) n = 6 to n = 5 (d) n = 5 to n = 3 39. The orientation of an atomic orbital is governed by
(2006)
33. A 0.66 kg ball is moving with a speed of 100 m/s. The
associated wavelength will be (h = 6.6 × 10–34 J s) (a) Principal quantum number
(2010) (b) Azimuthal quantum number
(a) 6.6 × 10–32 m (b) 6.6 × 10–34 m (c) Spin quantum number
(c ) 1.0 × 10–35 m (d) 1.0 × 10–32 m (d) Magnetic quantum number.
34. Maximum number of electrons in a subshell of an atom 40. The energy of second Bohr orbit of the hydrogen atom
is determined by the following (2009) is -328 kj mol–1; hence the energy of fourth Bohr orbit
would be (2005)
(a) 2  1 (b) 4  1
(a) –41 kJ mol–1 (b) –82 kJ mol–1
(c) 2n2 (d) 4  2 (c) –164 kJ mol–1 (d) –1312 kJ mol–1
35. If uncertainty in position and momentum are equal, then 41. The frequency of radiation emitted when the electron
uncertainty in velocity is (2008) falls from n = 4 to n = 1 in a hydrogen atom will be
(Given ionization energy of H = 2.18 × 10–18 J atom–1
1 h h and h = 6.626 × 10–34 J s) (2004)
(a) (b)
m   (a) 1.54 × 1015 s–1 (b) 1.03 × 1015 s–1
(c ) 3.08 × 1015 s–1 (d) 2.00 × 1015 s–1
1 h h
(c ) (d) 42. The value of Planck’s constant is 6.63 × 10–34 Js. The
2m  2
velocity of light is 3.0 × 108 m s–1. Which value is
36. The measurement of the electron position is associated closest to the wavelength in nanometers of a quantum
with an uncertainty in momentum, which is equal to of light with frequency of 8 × 1015 s–1? (2003)
1 × 10–18 g cm s–1. The uncertainty in electron velocity (a) 2 × 10–25 (b) 5 × 10–18
is (mass of an electron is 9 × 10–28 g) (2008)
(c ) 4 × 101 (d) 3 × 107
3
43. In hydrogen atom, energy of first excited state is –3.4 52. The ion that is isoelectronic with CO is (1997)
eV. Then find out K.E. of same orbit of hydrogen atom.
(a) CN– (b) N 2
(2002)
(c) O2 (d) N 2
(a) +3.4 eV (b) +6.8 eV
(c) –13.6 eV (d) +13.6 eV 53. What will be the longest wavelength line in Balmer series
of spectrum? (1996)
44. The following quantum numbers are possible for how
(a) 546 nm (b) 656 nm
many orbitals ? n = 3,  = 2, m = +2 (2001)
(c) 566 nm (d) 556 nm
(a) 1 (b) 2
54. In a Bohr’s model of an atom, when an electron jumps
(c) 3 (d) 4 from n = 1 to n = 3, how much energy will be emitted
45. Isoelectronic species are (2000) or absorbed? (1996)
(a) 2.389 × 10 –12 ergs (b) 0.239 × 10 –10 ergs
(a) CO, CN–, NO+, C 22  (b) CO  ,CN, NO,C 2 –11 –10
(c) 2.15 × 10 ergs (d) 0.1936 × 10 ergs
(c) CO  ,CN  , NO  ,C 2 (d) CO,CN, NO,C 2 55. The radius of hydrogen atom in the ground state is 0.53
Å. The radius of Li2+ ion (atomic number = 3) in a
46. For given energy, E = 3.03 × 10–19 joules corresponding similar state is (1995)
wavelength is (2000) (a) 0.53 Å (b) 1.06 Å
(h = 6.626 × 10–34 J sec, c = 3 × 108 m/sec) (c ) 0.17 Å (d) 0.265 Å
(a) 65.6 nm (b) 6.56 nm 56. Uncertainty in position of an electron (Mass = 9.1 ×
(c) 3.4 nm (d) 656 nm 10 –28 g) moving with a velocity of 3 × 10 4 cm/s
accurate upto 0.001% will be
47. Who modified Bohr’s theory by introducing elliptical
orbits for electron path? (1999) (Use h/(4) in uncertainty expression where
h = 6.626 × 10–27 erg second) (1995)
(a) Rutherford (b) Thomson
(a) 5.76 cm (b) 7.68 cm
(c) Hund (d) Sommerfeld
(c ) 1.93 cm (d) 3.84 cm
48. The uncertainty in momentum of an electron is
57. Which one of the following is not isoelectronic with
1 × 10–5 kg m/s. The uncertainty in its position will be
(h = 6.62 × 10–34 kg m2/s) (1999) O2 ? (1994)
(a) 5.27 × 10–30 m (b) 1.05 × 10–26 m (a) Tl+ (b) Na+
(c) 1.05 × 10–28 m (d) 5.25 × 10–28 m (c) N 3– (d) F –
58. For which of the following sets of four quantum
49. The de Broglie wavelength of a particle with mass 1 g
numbers, an electron will have the highest energy?
and velocity 100 m/s is (1999)
n  m s (1994)
(a) 6.63 1035 m (b) 6.63 1034 m (a) 3 2 1 +1/2
(b) 4 2 –1 +1/2
(c ) 6.63 1033 m (d) 6.65  1035 m
(c) 4 1 0 –1/2
50. The Bohr orbit radius for the hydrogen atom (n = 1) is (d) 5 0 0 –1/2
approximately 0.530 Å. The radius for the first excited
state (n = 2) orbit is (in Å) (1998) 59. The energy of an electron in the nth Bohr orbit of
hydrogen atom is (1992)
(a) 4.77 (b) 1.06
13.6 13.6
(c) 0.13 (d) 2.12 (a) 4
eV (b) eV
n n3
51. The position of both, an electron and a helium atom is
13.6 13.6
known within 1.0 nm. Further the momentum of the (c ) eV (d) eV
2 n
electron is known within 5.0 × 10–26 kg m s–1. The n
minimum uncertainty in the measurement of the 60. Electronic configuration of calcium atom can be written
momentum of the helium atom is (1998) as (1992)
(a) 8.0  1026 kg m s 1 (b) 80 kg m s–1 (a)  Ne 4p2 (b)  Ar  4s2
(c) 50 kg m s–1 (d) 5.0 × 10–26 kg m s–1 (c)  Ne 4s2 (d)  Kr  4p2
4
61. In a given atom no two electrons can have the same 70. The spectrum of He is expected to be similar to that
values for all the four quantum numbers. This is called (1988)
(a) Hund’s Rule (1991) (a) H (b) Li+
(b) Aufbau principle (c) Na (d) He+
(c) Uncertainty principle 71. If r is the radius of the first orbit, the radius of nth orbit
(d) Pauli’s Exclusion principle of H-atom is given by (1988)
62. For azimuthal quantum number  = 3, the maximum (a) rn 2 (b) rn
number of electrons will be (1991)
(c) r/n (d) r 2 n 2
(a) 2 (b) 6
(c) 0 (d) 14 Other Medical
63. The order of filling of electrons in the orbitals of an
atom will be (1991) 1. Assertion : The chemical properties of different isotopes
are same.
(a) 3d, 4s, 4p, 4d, 5s (b) 4s, 3d, 4p, 5s, 4d
Reason : Isotopes have same number of neutrons. (2019)
(c) 5s, 4p, 3d, 4d, 5s, (d) 3d, 4p, 4s, 4d, 5s
(a) If both assertion and reason are true and reason is the
64. The electronic configuration of Cu (atomic number 29)
correct explanation of assertion.
is (1991)
(b) If both assertion and reason are true but reason is not
(a) 1s 2 2s 2 2p 6 3s 2 3p6 4s 2 3d 9 the correct explanation of assertion.
(b) 1s 2 2s 2 2p6 3s 2 3p6 3d10 4s1 (c ) If assertion is true but reason is false.
(d) If both assertion and reason are false.
(c) 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 4p 6 5s 2 5p1
2. Match the following (2019)
(d) 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 4p 6 3d 3 Column-I Column-II
65. The total number of electrons that can be accommodated (A) Isotones (i) K-40 and Ca-40
in all the orbitals having principal quantum number 2 (B) Isotopes (ii) U-235 and Th-231
and azimuthal quantum number 1 are (1990)
(C) Isobars (iii) Protium and Tritium
(a) 2 (b) 4 (D) Isodiaphers (iv) C-14 and O-16
(c ) 6 (d) 8 (a) A-(i), B-(ii), C-(iii), D-(iv)
66. An ion has 18 electrons in the outermost shell, it is (b) A-(iv), B-(iii), C-(i), D-(ii)
(1990) (c) A-(iii), B-(ii), C-(iv), D-(i)
(a) Cu + (b) Th 4+
(d) A-(ii), B-(iii), C-(i), D-(iv)
(c) Cs + (d) K+ 3. A bulb is emitted electromagnetic radiation of 660 nm
67. Number of unpaired electrons in N2+ is/are (1989) wavelength. The total energy of radiation 3  10-18 J. The
(a) 2 (b) 0 number of emitted photons will be
(c ) 1 (d) 3
68. The maximum number of electrons in a subshell is given
 h  6.6 10  34Js,c  3 108 m/s  (2019)
by the expression (1989) (a) 1 (b) 10

(a) 4 – 2 (b) 4 + 2 (c) 100 (d) 1000
(c) 2 + 2 (d) 2n 2 4. Which of the following series of transitions in the
spectrum of hydrogen atom falls in visible region?
69. Which of the following statements do not form a part
(2019)
of Bohr’s model of hydrogen atom? (1989)
(a) Brackett series (b) Lyman series
(a) Energy of the electrons in the orbits are quantized.
(c ) Balmer series (d) Paschen series
(b) The electron in the orbit nearest the nucleus has
the lowest energy. 5. If n = 2 for He ion then find out the wave length. (2019)
+
(c) Electrons revolve in different orbits around the (a) 3.32 Å (b) 6.42 Å
nucleus. (c) 1.47 Å (d) 2.37 Å
(d) The position and velocity of the electrons in the 6. 4d ,5 p,5 f and 6p orbitals are arranged in the order of
orbit cannot be determined simultaneously.
decreasing energy. The correct option is (2019)
5
(a) 5 f  6 p  4d  5 p (b) 5 f  6 p  5 p  4d 15. Assertion : Fine lines are observed in spectra if an atom
is placed in a magnctic field.
(c) 6 p  5 f  5 p  4d (d) 6 p  5 f  4d  5 p Reason : Degenerate orbitals split in the presence of
7. Orbital having 3 angular nodes and 3 total nodes is magnetic field. (2018)
(a) 5d (b) 3d (2019) (a) If both assertion and reason are true and reason is the
correct explanation of assertuion.
(c ) 4 f (d) 6d
(b) If both assertion and reason are true but reason not
8. Assertion : The free gaseous Cr atom has 6 unpaired the correct explanation of assertuion.
electrons.
(c) If assertion is true but reason is false.
Reason : Half-filled s-orbital has greater stability.(2019)
16. The position of both an electron and helium atom is known
within 1.0 nm. The momentum of the electron is known
(b) If both assertion and reason are true bur reason is not within 5.0  1026 kg m s-1. The minimum uncertainty in
the correct explanation of assertion. the measurement of the momentum of the helium atom is
(c ) If assertion is true but reason is false. (2018)
(d) If both assertion and reason are false. (a) 7.0 1026 kg ms 1. (b) 5.0  1026 kg ms 1.
9. Pauli’s exclusion principle states that (2019)
(c) 8.0  1026 kg m s1. (d) 6.0 1026 kg ms 1.
(a) pairing of electrons does not occur in orbitals of the
same subshell until each of them is first singly 17. Which one is a wrong statement? (2018)
occupied. (a) Total orbital angular momentum of electron in -sorbital
(b) orbitals are filled in order of their increasing energy. is equal to zero.
(b) Anorbital is designated by three quantum numbers
(c ) no two electrons in an aton can have the same set of
while an electron in an atom is designated by four
four quantum numbers
quantum numbers.
(d) none of these.
(c ) The electronic configuration of N atom is
10. Azimuthal quantum number describes the (2019)
1
(a) size of the orbital 1s2 2s2 2 p1x 2 py 2 p1z
(b) shape of the subshell
(c) orientation of orbital (d) The value of m for dz2 is zero.
(d) spinning rotation of the electron. 18. Penetrating power of the rays are (2017)
11. What is the maximum wavelength of line of Balmer series (a)      (b)     
of hydrogen speetrum? (c )   X-rays     (d)     
 R=1.09×107m-1  (2018)
19. Ionization potential of hydrogen atom is 13.6 eV. Hydrogen
atom in ground state is excited by monochromatic light
(a) 400 nm (b) 660 nm of energy 12.1 eV. The spectral lines emitted by hydrogen
(c) 486 nm (d) 434 nm according to Bohr’s theory will be (2017)
(a) one (b) two
12. Which of the following are isoelectronic species? (2018)
(c ) three (d) four.
(a) Ca2+ , K+ and Zn2+ (b) Mn2+ , Fe2+ and Ni2+
20. Which one is the wrong statement? (2017)
(c ) Na+ , Al3+ and Ne (d) Sc, Co2+ and Cu2+
h
13. Calculate the velocity of an electron placed in the second (a) The uncertainty principle is   t  .
4
orbit orbit of Li2+ ion. (2018)
(b) Half filled and fully filled orbitals have greater stability
(a) 0.521 m s-1 (b) 3.27  106 c m s-1 due to greater exchange energy, ereater symmetry
and more balanced arrangement.
(c) 4.23 4.23  103 ms -1 (d) 3.27  106 m s-1 (c ) The energy of 2s-orbital is less than the energy of
14. Wavelength of a particular transition for H atom is same 2p-orbital in case of hydrogen like atoms.
transition? (2018) h
(d) de-Broglie’s wavelength is given by   , where
(a) 400 nm (b) 100 nm mv
m= mass of the particle, v = group velocity of the
(c) 1600 nm (d) 200 nm partice.
6
21. Which of the following electronic configurations has 28. Which of the following pairs of d-orbitals will have
maximum energy? (2017) electron density along the axes? (2016)
1s2 3p 3d (a) d z 2,d xz (b) d xz d yz

(a) (c ) d 2 , d x 2 y2 (d) d xy , d x 2  y 2
z
29. The electronic configurations of Eu (Atomic No. 63), Gd

3s 3p 3d (Atomic No. 64) and Tb (Atomic No. 65) are (2016)
(b)
(a)  Xe 4 f 6 5d1,  Xe 4 f 7 5d1 6s 2 and  Xe 4 f 8 5d 16s 2
3s 3p 3d
(b)  Xe  4 f 7 6 s 2 ,  Xe 4 f 7 5d 1 6s 2 and  Xe  4 f 9 6 s 2
(c)
(c)  Xe  4 f 7 6 s 2 ,  Xe  4 f 8 6 s 2 and  Xe  4 f 8 5d 1 6 s 2
3s 3p 3d (d)  Xe  4 f 6 5d 2 6 s 2 ,  Xe  4 f 7 5d 2 6 s 2 and  Xe  4 f 9 6 s 2
(d)
30. Two electrons occupying the same oebital are distinguished
by (2016)
22. An element E loses one  and two  -particles in three
(a) azimuthal quantum number
successive stages. The resulting element will be (2016)
(b) spin quantum number
(a) an isobar of E (b) an isotone of E
(c) principal quantum number
(c ) an isotope of E (d) E itslf.
(d) magnetic quantum number.
23. The energy required to break one mole of hydrogen-
hydrogen bonds in H2 is 436 kJ. What is the longest 31. Which of the following atoms in itsground state has the
wavelength of light requird to break a single hydrogen highest number of unpaired electrons?
hydrogen bond? (2016) (Atomic numbers aew given in brackets.) (2016)
(a) 68.5 nm (b) 137 nm (a) Chromium (24) (b) Iron (26)
(c ) 274 nm (d) 548 nm (c) Manganese (25) (d) Vanadium (23)
24. According to Bohr’s theory, which of the following 32. The correct set of four quantum numbers for the electron
correctly represents the variation of energy and radius of in the outermost subshell of Cu atom (atomic number 29)
an electron in ntn orbit of H- atom? (2016) in its ground state, is
n l m1 ms (2016)
(a) En  1 , r  1 (b) En  1 ,r  n 2 1
n2 n2 n2 (a) 4 0 0 
2
1
(c) En  n 2 , r  n2 (d) En  n, r  1
n (b) 3 0 0 
25. The energy of electron in the ntn Bohr orbit of H-atom is 2
(2016) 1
(c) 4 1 0 
13.6 13.6 2
(a) 2
eV (b) eV 1
n n3 (d) 3 2 +1 
13.6 13.6
2
(c) eV (d) eV 33. Consider the following sets of quantum numbers : Which
n4 n3
of the below setting is not permissible arrangement of
26. The time taken for an elevtron to complete one revolution electrons in an atom? (2016)
in Bohr orbit of hydrogen atom is (2016)
n l m s
4m 2 r 2 n2h 2
1
(a) (b) (a) 4 0 0 
n2h2 4mr 2
2
42 mr 2 nh h
(c ) (d) 2 2 (b) 5 3 0 6
nh 4 mr 2
27. How many electrons can fit in the orbital for which n = 3 1
(c) 3 2 -2 
and l = 1? (2016) 2
(a) 2 (b) 6 1
(d) 3 2 -3 
(c) 10 (d) 14 2
7
34.  -particles can be detected by using (2015) (a) 4 s3s3 p3d (b) 3s3 p3d 4 s
(a) thin aluminium sheet (b) barium sulphare
(c ) 3s3 p 4s3d (d) 3s 4 s3 p3d
(c ) zinc sulphide screen (d) gold foil.
43. Which of the following arrangement is possible? (2015)
A A
35. In a decay process ZX CHANGES INTO z-l Y . Which n l m s
process is this? (2015) (a) 5 2 2 +1/2
(a)   decay (b)  -decay (b) 2 2 0 -1/2
(c) 3 -2 1 +1/2
(c)  -decay (d)  -decay (d) 0 0 1 +1/2
36. A monoatomic anion of unit charge contains 45 neutrons 44. The maximum number of electrons in a subshell is given
and 36 electrons. Identify the ion. (2015) by the expression (2015)
(a) Cl -
(b) F - (a) 2n 2
(b) 4l + 1
(c) I -
(d) Br- (c ) 4l + 2 (d) 4l - 2
37. The Balmer series in the hydrogen spectrum corresponds 45. For d-electron, the orbital angular momentum is (2015)
to the transition from n1 = 2 to n2 = 3, 4, ...... . This series
lies in the visible region. What is the wavelength of light 6h 2h
(a) (b)
emitted when the electron in a hydrogen atom undergoes 2 2
transition from an energy level with n = 4 to an energy
h 2h
with n = 2? (2015) (c) (d)
2 
(a) 486 nm (b) 386 nm
46. Which of the following sets of quantum numbers
(c) 846 nm (d) 648 nm
represents the highest energy of an atom? (2015)
38. Assertion : For Balmer series of hyfrogen spectrum, the
value n1 = 2 and n2 = 3, 4, 5.... (2015) 1
(a) n  3, l  0, m  0,s  
Reason : The value of n2 for a line in Balmer series of 2
hydrogen spectrum having the highest wavelength is 6. 1
(a) If both assertion and reason are true and reason is the (b) n  3, l  1, m  1,s  
2
1
(b) If both assertion and reason are true but reason is not (c ) n  3, l  2, m  1,s  
the correct explanation of assertion. 2
(c ) If assertion is true but reason is false. 1
(d) n  4, l  0, m  0,s  
(d) If both assertion and reason are false. 2
39. Energy associated with the first orbit of He+ is (2015) 47. Which of the following sets of quantum numbers is
possible ? (2015)
(a) 8.27  1018 joules (b) 0.827  10 18 joules
(a) n  3, l  3, ml  3, ms  1 / 2
(c) 0.827 1018 joules (d) 8.27 10 18 joules
(b) n  2, l  1, ml  2, ms  1 / 2
40. The ionisation of hydrogen atom is 13.6 eV. The energy
required to remove an electron from n = 2 state of (c ) n  2, l  0, ml  0, ms  1 / 2
hydrogen atom is (2015)
(d) n  2, l  0, ml  0, ms  0
(a) 27.2 eV (b) 13.6 eV
(c) 6.8 eV (d) 3.4 eV (e) n  3, l  2, ml  3, ms  1 / 2
41. The de Broglie waavelength associated with a ball of mass 48. What is the maximum number of electrons having same
1 kg having kinetic energy 0.5 J is (2015) spin with n +l = 4 (2015)
(a) 6.626  1034 m (b) 13.20  1034 m (a) 3 (b) 2
(c ) 4 (d) 5
(c) 10.38  1034 m (d) 6.626  1034 Å
49. Be is isoelectronic with of the following ions? (2014)
2+
42. Which is the correct order of increasing energy of the
listed orbitals in the atom of titanium? (a) H+ (b) Li+
(At. no. Z = 22) (2015) (c) Na +
(d) Mg2+
8
50. Which of the following pairs represent isotoes? (2014) 59. The emission spectrum of hydrogen discovered first and
77 78 195 190
the region of the electromagnetic spectrum in which it
(a) 33 As, 34Se (b) 78 Pt, 76 Os belongs, respectively are (2014)
(c) 108 112 (d) 178 137 (a) Lyman, ultraviolet (b) Lyman, visible
47 Ag, 48 Cd 72 Hf, 56 Ba
(c) Balmer, ultraviolet (d) Balmer, visible
51. Mass number of an atom is the sum of (2014)
(a) number of protons + number of neutrons + number 60. The ratio of de Broglie wavelengths of a deuterium atom
of electrons to that of an  -particle, when the velocity of the former
is five times gesater than that of the later. is (2014)
(b) number of protons + number of neutrons
(a) 4 (b) 0.2
(c) number of protons + number of electrons
(c) 2 (d) 0.4
(d) number of electrons + number of neutrons.
52. Atoms with identical atomic number but different atomic (e) 5
mass number are known as (2014) 61. As per de Broglie’s formula a macroscopic particle of
(a) polymers (b) isobars mass 100 g and moving at a velocity of 100 cm s-1 will
have a wavelength of (2014)
(c ) isotpes (d) isomers.
53. Which of the following are isoelectronic species? (2014) (a) 6.6  1029 c m (b) 6.6  1030 c m
(i) NH3 (ii) CH3+ (c ) 6.6 1031 c m (d) 6.6  1032 c m

(iii) NH -2 (iv) NH 4 62. What is the maximum number of orbitals that can be
indentified with the following quantum numbers ?
Choose the answer from the codes given below :
(a) (i),(ii),(iii) (b) (ii),(iii),(iv) n  3, l  1, ml  0 (2014)
(c) (i),(ii),(iv) (d) (i),(iii),(iv) (a) 1 (b) 2
(e) (ii),(iii) (c) 3 (d) 4
54. Negatively charged particles are called (2014) 63. The total number of orbitals associated with the principal
(a) electrons (b) protons quantum number n = 3, is (2014)
(c) neutrons (d) none of the above. (a) 9 (b) 8
55. Mass of a proton is (2014) (c) 5 (d) 7
(a) 0.00727 amu (b) 1.0087 amu 64. The maximum number of electrons which can be held by
(c) 0. 00054 amu (d) 1.00727 amu subshell with azimuthal quantum number ‘l’ in an atom is
56. Calculate the energy in joule corresponding to light of given by (2014)
wavelength 45 nm. (Planck’s constant, h = 6.63  10 34 J (a)  2l  1 (b)  2l  2 
s, speed of light,c = 3  108 m s )
-1
(2014)
(c ) 2  2l  1 (d) 2  2l  2 
(a) 6.67  10 15 (b) 6.67  10 11
(e) 2l
(c) 4.42  1015 (d) 4.42  1018 65. The atom/ion that has the highest number of unpaired
57. The smallest quantity of energy that can be emitted or electrons is (2014)
absorbed in the form of electromagnetic radiation is known
(a) Na + (b) F
is (2014)
(a) quantum (b) photon (c ) N (d) O 2-
(c) spectrum (d) photoelectron (e) B
58. Energy of one mole of photons of radiation whose
66. Among the elements from atomic number 1 to 36, the
frequency is 5  1014 Hz is (2014) number of elements which have an unpaired electron in
their s-subshell is (2014)
(a) 199.51 kJ mol 1 (b) 189.51 kJ mol 1
(a) 4 (b) 7
(c) 198.51 kJ mol 1 (d) 188.51 kJ mol 1
(c ) 6 (d) 9
9
67. The statement that is not correct is (2014) (a) Equation can be used to calculate the change in energy
(a) angular quantum number signifies the shape of the when the electron changes orbit.
orbital (b) For n = 1, the electron has a more negative energy
(b) energies of stationary states in hydrogen like atoms is than it does for n = 6 which means that the electron
inversely proportional to the square of the principal is more loosely bound in the smallest allowed orbit.
quantum number (c) The negative sign in equation simply means that the
(c ) total number of nodes for 3s orbital is three of electron bound to the nucleus is lower than it would
ber if the electrons were at the infinite distance from
(d) the radius of the first orbit of He  is half that of the the nucleus.
first orbit of hydrogen atom. (d) Larger the value of n, the larger is the orbit radius.
68. Which of the following is not in accordance with Aufbau 74. Which of the following expression represents the energy
principle? (2014) of electron a hydrogen atom? (2013)
2s 2p 2s 2p
(a) (b) 22 me4 1 42 me2 1
(a) E  (b) E 
h2 n2 h2 n2
2s 2p 2s 2p
2 2 me4 1 4 2 me2 1
(c ) (d) (c ) E   (d) E   0
h2 n2 h2 n2
69. The lectronic configuration of Cu is (2014) 75. A particle is moving 3 times faster than the speed of
electron. If the ratio of wavelength of particle and electron
(a)  Ne  3s 2 3 p 6 3d 9 4 s 2
is 1.8 1.8  10 4 , then particle is (2013)
(b)  Ne 3s 2 3 p 6 3d 10 4s1
(a) neutron (b)  -particle
(c)  Ne 3s 2 3 p 6 3d 3 4s 2 4 p 6 (c) deuteron (d) tritium.
(d)  Ne 3s 2 3 p 6 3d 5 4 s 2 4 p 4 76. Who proposed dual nature of electron? (2013)
70. An oin with mass number 37 possesses one unit of negative (a) de Broglie (b) Einstein
charge. If the ion contains 11.1% more neutrons than (c) Bohr (d) Heisenberg
electrons, the symbol of the ,X, is (2013) 77. Calculate the wavelength associated with an electron
(a) 35 (b) 35  moving with a velocity of 106 m/s. (2013)
17 X 17 X
(c) 37 (d) 37  (mass of e   9.11031 kg,h=6.6×10-34 kgm 2 /s)

17 X 17 X
71. Which one of the following sets of ions represents the (a) 6.2 108 m (b) 7.25  108 m
collection of isoelectronic species? (2013)
(a) K , Cl , Mg , Sc
+ - 2+ 3+
(b) Na , Ca , Sc , F-
+ 2+ 3+ (c) 6.25 Å (d) none of these.
(c ) K+, Cc2+, Sc3+,Cl- (d) Na+, Mg2+, Al3+, Cl- 78. What is the maximum numbers of electrons that can be
associated with the following set of quantum numbers?
72. According to law of photochemical equivalence the energy
absorbed (in ergs/mole) is given as n  3, l  1 and m = -1 (2013)
( h = 6.62  1027 ergs, c = 3  1010 mn (a) 4 (b) 2
cm s 1, N A = 6.02  1023 mol1 ) (2013) (c) 10 (d) 6
79. Assertion : Number of radial and angular nodes for 3p-
1.196 108 2.859  105 orbital are 1, 1 respectively.
(a) (b)
 
Reason : Number of radial and angular nodes depends
2.859  1016 1.196 1016 only on principal quantum number (2013)
(c) (d)
  (a) If both assertion and reason are true and reason is the
 Z2 
73. Based on equation E  2.178  1018 J  2  , certain (b) If both assertion and reason are true bur reason is not
n 
  the correct explanation of assertion.
conclusions are written. Which of them is not correct? (c ) If assertion is true but reason is false.
(2013)
10
80. Which of the following sets of quantum numbers is not 86. Which one of the following constitutes a group of the
possible? (2013) isoeelectronic species? (2012)
1
(a) n  1, l  0, ml  0, ms   (a) N 2 ,O-2 , NO+ ,CO (b) N 22 ,O-2 ,CO,NO
2
1 (c ) NO  ,C 22 ,CN - ,N 2 (d) NN  ,N 2, O 22 ,C22
(b) n  1, l  1, ml  0, ms  
2
1 87. Which of the following pair illustratates an isoelectronic
(c) n  2, l  1, ml  0, ms   pair? (2012)
2
1 (a) Li and Be +
(b) H and He
- +
(d) n  3, l  1, ml  0, ms   (c) He and H (d) Be+ and H

2
81. What is the total number of electrons that can have the 88. Which of not isoelctronic with the other three? (2012)
values n = 2, l =1, s = 1/2 in the electronic configuration (a) CO (b) CO+
1s22s22p3? (2013)
(c) CN- (d) O2
(a) 1 (b) 3
89. Isotones have (2012)
(c) 5 (d) 7
(a) same neutron number but different proton number
82. Which of the following pairs is not correctly matched?
(b) same proton number but different neutron number
(2013)
(c) same proton and neutron number
(a) Hund’s rule In orbitals of equivalent energy
electron spins remain unpaired (d) same proton but different electron number.
if possible. 90. Thresold frequency of a metal is 5  1013 s 1 upon which
(b) Pauli’s exclusion No two elctrons can have all
1  1014 s 1 frequency light is focused. Then the maximum
principle the four quantum numbers kinetic energy of emitted electron is (2012)
identical.
(a) 3.3  1021 (b) 3.3  1020
(c) Zeeman effect The effect of magnetic field on
the atomic spectra. (c) 6.6  1021 (d) 6.6  1020
(d) Uncetrainty It is impossible to determine
nh
principle the position of an electron. 91. In Bohr’s indicates (2012)
2
83. The orbital diagram in which Aufbau principle is violated (a) momentum (b) kinetic energy
is (2013)
(c) potential energy (d) angular momentum.
2s 2p 2s 2p
92. Assertion : Bohr model fails in case of multi-electron
(a) (b) species.
2s 2p 2s 2p Reason : It does not mention electron-electron interactions.
(c ) (d) (2012)
84. ‘‘No two electrons in an atom will have all the four quantum correct explanation of assertion.
numbers same’’.The statement is known as (2013) (b) If both assertion and reason are true bur reason is not
(a) Uncertainty principle the correct explanation of assertion.
(b) Pauli ’s exclusion principle (c) If assertion is true but reason is false.
(c) Hund’s rule (d) If both assertion and reason are false.
(d) Aufbau principle. 93. Assertion : The spectrum of He+ is expected to be similar
85. Identify the correct statement. (2013) to that of hydrogen.
(a) Quantumnmbers (n,l,m,s) are obtainedarbitrarily. Reason : He+ is also one electron system. (2012)
(b) All the quantum numbers (n,l,m,s) for any pair of (a) If both assertion and reason are true and reason is the
electrons in an atom can be identical under special correct explanation of assertion.
circumstance.
(b) If both assertion and reason are true but reason is not
(c) All the quantum numbers (n,l,m,s) may not be required the correct explanation of assertion.
to describe an electron of an atom completely.
(c) If assertion is true but reason is false.
(d) All the quantum numbers (n,l,m,s) are required to
describe an electron of an atom completely. (d) If both assertion and reason are false.
11
94. Ratio of area of second orbit to first orbit in an atom

(iv)
(2012)
(a) 1 : 4 (b) 4 : 1 the most stable arrangement is
(c ) 16 : 1 (d) 1 : 16 (a) (i) (b) (ii)
95. If the 1 ionization energy of H atom is 13.6 eV, then the
st (c) (iii) (d) (iv)
2nd ionization energy of He atom is (2012) 103. Maximum number of electrons in a shell with principle
(a) 27.2 eV (b) 40.8 eV quantum number n is given by (2012)
(c ) 54.4 eV (d) 108.8 eV (a) n (b) 2n
96. Bohr model of hydrogen atom was unable to explain (2012) (c) n 2
(d) 2n2
(a) Rydberg ’s formula of atomic spectra 104. Which set of quantum numbers are not possible?
(b) Heisenberg’s uncertainty principle n l m s (2012)
(c) Planck’s law of energy quantization (a) 3 2 0 +1/2
(d) Rutherford’ model of atomic structure. (b) 2 2 1 +1/2
97. The de Broglie wavelength of a particle is (2012) (c) 1 0 0 -1/2
(a) proportional to its mass (d) 3 2 -2 +1/2
(b) proportional to its velocity (e) 2 1 1 -1/2
(c ) inversely proportional to its momentum 105. The correct set of four quantum numbers for the outer-
(d) proportional to its total energy. most electron of sodium (Z = 11) is (2012)
98. Which of the follwing does not represent the mathematical 1 1
(a) 3, 1, 0, (b) 3, 1, 1,
expression for the Heisenberg uncertainty principle? (2012) 2 2
1 1
(a) x  p  h /  4  (b) x  v  h /  4m  (c) 3, 2, 1, (d) 3, 0, 0,
2 2
(c) E  t  h /  4  (d) E  x  h /  4  106. Impossible orbital among the following is (2012)
99. Maximum number of electrons in a subshell with l = 3 (a) 2s (b) 3f
and n = 4 is (2012) (c) 2p (d) 4d
(a) 14 (b) 16 107. Which law represents the pairing of electron in a sub-
(c) 10 (d) 12 shell after each orbital is filled with one electron? (2012)
100. The correct cet of four quantum numbers for the valence (a) Pauli’s exclusion principle
electron of rubidum atom (Z = 37) is (2012) (b) Hund ’s rule
(a) 5, 1, 1, + 1/2 (b) 6, 0, 0, +1/2 (c) Heisenberg’s principle
(c ) 5, 0, 0, + 1/2 (d) 5, 1, 0, +1/2 (d) Hess’s law
101. The orbital angular momentum ofa p-electron is given as 108. According to the Bohr theory, which of the following
(2012) transitions in the hydrogen atom will give rise to the least
h h energetic photon? (2011)
(a) (b) 3
2 2 (a) n = 6 to n = 1 (b) n = 6 to n = 4
3h h (c ) n = 6 to n = 5 (d) n = 6 to n = 3
(c) (d) 6
2 2 109. Smallest wavelength occurs for (2011)
102. Out of the following electronic arrangements for outer (a) Lyman series (b) Balmer series
electronic configurations (2012) (c) 0Paschen series (d) Brackett series.
4s 3d 110. The energy of electron in the 1st orbit of hydrogen atom is
(i) (2011)
(a) 2.18  1018 J atom-1
(ii) (b) 2.18  1018 kJ atom–1
(c) 2.18  1018 ergs atom-1
(iii)
(d) 2.18  1018 J atom-1
12
111. What transition in the hydrogen spectrum would have the (a) 1   2 (b) 1  2 2
same wavelength as Balmer transition, n = 4 to n = 2 in 1
the He+ spectrum? (2011) (c) 1  4 2 (d) 1   2
2
(a) n = 3 to n = 1 (b) n = 3 to n = 2 119. Splitting of spectral lines in electric field is called (2011)
(c) n = 4 to n = 1 (d) n = 2 to n = 1 (a) Zeeman’s effect (b) Stark effect
112. For Balmer series in the spectrum of atomic hydrogen, (c) photoelectric effect (d) shielding effect
the wave number of each line is given by 120. If the energies of the two photons are in the ratio of 3 : 2,
 1 1  their wavelengths will be in the ratio of (2011)
v  R H  2  2  wher R is a constant and n and n
n  (a) 9 : 4 (b) 2 : 3
 1 n2 
H 1 2
are integers. Which of the following statements is (are) (c) 1 : 2 (d) 3 : 2

correct? (2011) 121. The electronic transitions from n = 2 to n = 1 will produce
1. As wavelength decreases, the lines in the series shortest wacelength in (where n = principal quantum state)
converge. (2011)
2. The inteher n1 is equal to 2. (a) Li 2+
(b) He +
3. The ionization energy of hydrogen can be calculated (c) H (d) H+

from the wave number of these lines. 122. Which of the follwing is wrong for Bohr model? (2011)
4. The line of longest wavelength corresponds to n2= 3. (a) It establishes stability of atom.
(a) 1, 2 and 3 (b) 2, 3 and 4 (b) It is inconsistent with Heisenberg uncertainty principle.
(c ) 1, 2 and 4 (d) 2 and 4 only (c) It explains the concep of spectral lines for hydrogen
like species.
(e) 2 only
(d) Electrons behave as particle and wave.
113. The ionisation potential for He+ is (2011)
123. The de Broglie wavelength of a ball of mass 10 g moving
(a) 54.4 eV (b) 6.8 eV with a velocity of 10 m s-1 is (2011)
(c) 13.6 eV (d) 24.5 eV
 h  6.626  1034 Js 
114. Radius of n orbit of H-like particles is proportional to
th  
(2011) (a) 6.626  1033 m (b) 6.626  1029 m
(a) n 2 (b) n 2 Z (c) 6.626  1031 m (d) 6.626  1036 m
(c) n 2 / Z 2 (d) n 2 / Z 124. A 120 g cricket ball is thrown with a speed of 44.7 m/s,
what will be its de Brogile wavelength? (2011)
115. The energy of an electron in first Bohr orbit of H-atoms is
(a) 1.2  1034 cm (b) 1.2  1032 cm
13.6 eV. The possible energy value of electron in the excited
state of Li2+ is (2011) (c) 1.6  1032 cm (d) 1.6  1030 cm
(a) -122.4 eV (b) 30.6 eV 125. Wavelength of an electron moving with velocity 106 cm/s
(c ) -30.6 eV (d) 13.6 eV is (2011)
116. Which of the following pairs is isoelectronic? (2011) (a) 7.2  108 cm (b) 7.2  10 8 m
(a) Ar and Cl (b) Na and Ne
+
(c) 1.2  10 10 m (d) 1.2  108 m
(c) Na and Mg
+
(d) Mg and Ne
126. The total number of atomic orbitals in fourth energy level
117. In which one of the following pairs the two species are of an atom is (2011)
both isoelectronic and isotopic? (Atomic numbers:
(a) 8 (b) 16
Ca = 20, Ar = 18, K = 19, Mg = 12, Fe = 26, Na = 11) (c) 32 (d) 4
(2011)
127. If n = 6, the correct sequence for filling of electrons will
(a) 40Ca2+ and Ar (b) 39K+ and 40k+ be (2011)
(c) 24Mg2+ and25 Mg (d) 23Na and 24Na+
(a) ns   n  2  f   n  1 d  np
(e) 56Fe3+ and 57Fe2+
(b) ns   n  1 d   n  2  f  np
118. The energies E1 and E2 of two radiations are 25 eV and 50
eV respectively. The relation between their wavelengths (c) ns   n  2  f  np   n  1 d
i i.e., 1 and  2 will be (2011) (d) ns  np   n  1 d   n  2  f
13
128. Which of the following set of quantum numbers represents 135. The line spectrum of He+ ion will resmble that of (2010)
the 19th electron in chromium? (Z = 24 for Cr). (2011) (a) hydrogen atom (b) Li+ ion
1 1 (c) helium atom (d) lithium atom
(a) 4,0,0, (b) 4,1, 1,
2 2 136. The wave number of the spectral line in the emission
1 1 8
(c) 3, 2,2, (d) 3, 2, 2, spectrum of hydrogen will be equal to times the
2 2 9
129. The electrons identified by quantum numbers n and l : Rydberg’s constant if the electron jumps from (2010)
(2011) (a) n = 3 to n = 1 (b) n = 10 to n = 1
(1) n = 4, l = 1 (2) n  4, l  0 (c) n = 9 to n = 1 (d) n = 2 to n = 1
(3) n  3, l  2 (4) n  3, l  1 137. When the electron of a hydrogen atom jumps from n = 4
to n = 1 state, the number of spectral lines emitted is(2010)
can be placed in order of increasing energy as
(a) 15 (b) 9
(a) (4) < (2) < (3) < (1) (b) (2) < (4) < (1) < (3)
(c ) 6 (d) 3
(c) (1) < (4) < (1) < (4) (d) (3) < (4) < (2) < (1)
138. What is the maximu no. of emission lines obtained when
130. Which one of the following sets of quantum number the excited electrons of a hydrogen atom in n = 5 drop to
represents the highest energy level in an atom? (2011) ground state ? (2010)
1 (a) 10 (b) 5
(a) n  4, l  0, m  0, s  
2 (c) 12 (d) 15
1
(b) n  3, l  1, m  1, s   139. In Sommerfeld’s modification of Bohr’s theory, the
2 trajectory of an electron in a hydrogen atom is (2010)
1
(c ) n  3, l  2, m  2, s   (a) a perfect ellipse
2
(b) a closed ellipse like curve, narrower at the perihelion
1
(d) n  3, l  0, m  0, s   position and flatter at the aphelion position
2
(c) a closed loop on a spherical surface
131. Which one of the following decided the shapes of orbitals
in an energy shell? (2011) (d) a rosette.
(a) Magnetic quantum number 140. A 0.66 kg ball is moving with a speed os 100 m/s. The
associated wavelength will be
(b) Principal quantum number
(c ) Azimuthal quantum number  h = 6.6 1034 J s  (2010)
(d) Spin quantum number
(a) 6.6  1032 m (b) 6.6  1034 m
132. The representation of the ground state electronic
(c ) 1.0  10 35 m (d) 1.0  10 32 m
configuration of He by box-diagram as is wrong
because it violates (2011) 141. Assume that you are travelling at a speed of 90 km/h in a
small car with a mass of 1050 kg. If the uncertainty in
(a) Heisenberg’s uncertainty principle
(b) Bohr’s quantization theory of angular momenta the velocity of the car is 1%   0.9 km/h  , what is the
(c ) Pauli’s exclusion principle uncertainty (in meters) in the position of the car?(2010)
(d) Hund’s rule. (a) x  1  1035 m (b) x  2  1037 m
133. If a species has 16 protons, 18 electrons and 16 neutrons.
(c) x  2  1036 m (d) x  4  1038 m
Find the species and its charge (2010)
(a) S 1-
(b) si 2+ 142. Dual behaviour of matter was proposed by (2010)
(c) P 3-
(d) S2- (a) Neils Bohr (b) Erwin Schrodinge
134. In photoelectric effect, the kinetic energy of photoelectrons (c ) Louis de Brogile (d) Max Planck.
increases linearly with the (2010) 143. In the ground state of Cu+, the number of shells occupied,
(a) wavelength of incident light subshells occupied, filled orbitals and unpaired electrons
respectively are (2010)
(b) frequency of incident light
(a) 4, 8, 15, 0 (b) 3, 6, 15, 1
(c) velovity of incident light
(c ) 3, 6, 14, 0 (d) 4, 7, 14, 2
(d) atomic mass of an element.
14
144. For 2s orbital, the nodal surfaces exists at a distance of 2. The isotopes of hydrogen are : (2019)
(2010) (a) Tritium and protium only
(a) a0 from the nucleus (b) 1.5a0 from the nucleus (b) Protium and deuterium only
(c ) 2a0 from the nucleus (d) none of these is correct
(c ) Protium and deuterium and tritium
145. Out of the following which is the correct set of quantum
numbers for outermost electron of potassium (Z = 19)? (d) Deuterium and tritium only
(2010) 3. For any given seies of spectral lines of atomic hydrogen,
n l m s let v  vmax  vmin be the difference in maximum
(a) 4 3 2 –1/2 and minimum frequencies in cm1. The ratio
(b) 4 2 0 –1/2
v  vLyman / vBalmer is : (2019)
(c) 4 1 0 +1/2
(d) 4 0 0 –1/2 (a) 4 : 1 (b) 9 : 4
146. The set of quantum numbers for the outermost electron (c) 5 : 4 (d) 27 : 5
for copper in its ground state is (2010) 4. The radius of the second Bohr orbit for hydrogen atom
(a) 4, 1, 1, +1/2 (b) 3, 2, 2, +1/2
is : (Plank’s const. h  6.6262 1034 Js; mass of
(c ) 4, 0, 0, +1/2 (d) 4, 2, 2, +1/2
147. For n = 2 the correct set of azimuthal and magnetic electron  9.1091  1031 kg; charge of electron
quantum numbers are (2010)
e  1.60210  10 19 C; permittivity of vaccum
(a) l  2; m  2, 1,0, 1, 2
e0  8.854185  10 12 kg 1m 3A 2 ) (2017)
(b) l  1; m  2, 1,0, 1, 2
(a) 1.65Å (b) 4.76Å
(c) l  0; m  1,0, 1
(c) 0.529Å (d) 2.12Å
(d) l  1; m  1,0, 1
5. The group having isoelectronic species is : (2017)
148. Ground state configuration of Cr atom is (2010)
(a) O 2 ,F , Na  , Mg 2 (b) O 2  , F , Na, Mg 2 
(a)  Ar 3d 4 4 s 2 (b)  Ar  3d 5 4 s1
(c) O 2  , F , Na, Mg 2  (d) O  , F , Na, Mg 2 
(c)  Ar  3d 5 4s 0 (d)  Ar  3d 5 4s 2
149. An electron will have the highest energy in the set(2010) 6. A stream of electrons from a heated filaments was passed
two charged plates kept at a potential difference V esu.
(a) 3, 2, 1, 1/2 (b) 4, 2, –1, 1/2
If e and m are charge and mass of an electron,
(c) 4, 1, 0, –1/2 (d) 5, 0, 0, 1/2 respectively, then the value of h /  (where  is
150. Which of the following orbitals will have zero probability wavelength associated with electron wave) is given by:
of finding the electron in the yz plane? (2010)
(2016)
(a) px (b) p y
(a) meV (b) 2meV
(c) pz (d) dyz
(c) meV (d) 2meV
JEE main (AIEEE) 7. Which of the following is the energy of a possible excited
state of hydrogen ? (2015)
1. For emission line of atomic hydrogen from n1  8 to
(a) –3.4 eV (b) +6.8 eV
 1 
n f  n , the plot of wave number    against  2  will (c) +13.6 eV (d) -6.8 eV
n 
8. The correct set of four quantum numbers for the valence
be (The Rydberg constant, R H is in wave number unit)
electrons of rubidium atom (Z = 37) is : (2014)
(2019)
(a) Linear with intercept  R H 1 1
(a) 5,0,0  (b) 5,1,0 
2 2
(b) Non - linear
(c) Linear with R H 1 1
(c) 5,1,1  (d) 5,0,1 
(d) Linear with  R H 2 2
15
9. Energy of an electron is given by E = (a) 0.40 nm (b) 2.5 nm

 Z2  (c) 14.0 nm (d) 0.32 nm
2.178  1018 J  2  . Wavelength of light required to
n  15. In an atom, an electron is moving with a speed of 600
 
excite an electron in an hydrogen atom from level n = 1 m/s with an accuracy of 0.05%. Certainty with which
to n = 2 will be : the position of the electron can be located is
( h  6.6  10 34 kg m 2s 1 , mass of electron,
 h  6.62  10 34 8
Js and c=3.0  10 ms 1
 (2013)
e m  9.1  10 31 kg ): (2009)
3
(a) 5.10  103 m (b) 1.92  10 m
(a) 1.214  107 m (b) 2.816 107 m
4
(c) 3.84  103 m (d) 1.52  10 m
7 7
(c) 6.500  10 m (d) 8.500  10 m
16. Which one of the following constitutes a group of the
10. The electrons identified by quantum numbers n and l : isoelectronic species? (2008)
(2012) (a) C 22 ,O 2 ,CO, NO (b) NO  ,C 22  ,CN  , N 2
(A) n = 4, l = 1 (B) n = 4, l = 0  
(c) CN  , N 2 ,O 22 ,C 22 (d) N 2 ,O 2 , NO ,CO
(C) n = 3, l = 2 (D) n = 3, l = 1
17. The ionization enthalpy of hydrogen atom is
can be placed in order of increasing energy as :
(a) (C) < (D) < (B) < (A) (b) (D) < (B) < (C) <(A) 1.312  106 J mol1. The energy required to excite the
electron in the atom from n = 1 to n = 2 is (2008)
(c) (B) < (D) < (A) < (C) (d) (A) < (C) < (B) < (D)
11. A gas absorbs a photon of 355 nm and emits at two (a) 8.51 105 J mol1. (b) 6.56  105 J mol1.
wavelengths. If one of the emission is at 680 nm, the
other is at: (2011) (c) 7.56  105 J mol1. (d) 9.84 105 J mol1.
(a) 1035 nm (b) 325 nm 18. Which of the following sets of quantum numbers
represents the highest energy of the atom? (2007)
(c ) 743 nm (d) 518 nm
(a) n = 3,l = 0,m = 0,s = +1/2
12. The energy required to break onemole of Cl - Cl bonds
(b) n = 3,l = 1,m = 1,s = +1/2
in Cl2 is 242kJ mol1 . The longest wavelength of light
(c ) n = 3,l = 2,m = 1,s = +1/2
capable of breaking a single Cl - Cl bond is (2010)
(d) n = 4,l = 0,m = 0,s = +1/2
8 1 23 1
(c  3  10 ms and N A  6.02  10 mol ) . 19. According to the Bohr’s theory, the angular momentum
of an electron in 5th orbit is (2006)
(a) 594 nm (b) 640 nm
(a) 10 h/  (b) 2.5 h/ 
(c) 700 nm (d) 494 nm
(c) 25 h/  (d) 1.0 h/ 
13. Ionisation energy of He+
is 19.6 × 10–18 J atom–1. The
20. Uncertainty in the position of an electron (mass =
energy of the first stationary state (n = 1) of Li2+ is
(2010) 9.1  1031 kg ) moving with a velocity 300 ms –1 ,
accurate upto 0.001% will be (2006)
(a) 4.41 1016 J atom 1
(a) 1.92  102 m (b) 3.84  102 m
17 1
(b) 4.4110 J atom
(c) 19.2  102 m (d) 5.76  102 m
15 1
(c) 2.2  10 J atom 21. Which one of the following sets of ions represents a
collection of isoelectronic species? (2006)
(d) 8.82  1017 J atom1
(a) N3 ,O2  ,F ,S2
14. Calculate the wavelength (in nanometer) associated with
a proton moving at 1.0  103 ms 1. (b) Li  , Na  , Mg 2 ,Ca 2 
(Mass of proton = 1.67  1027 kg and h  6.63 1034 Js ) (c ) K  ,Cl ,Ca 2 ,Sc3
(2009)
(d) Ba 2 ,Sr 2 ,K  ,Ca 2
16
22. In a multi-electron atom, which of the following orbitals (a) 4 (b) 5
described by the three quantum members will have the (c) 6 (d) 3
same energy in the absence of magnetic and electric
fields? (2005) 29. The orbital angular momentum for an electron revolving
(A) n = 1,l = 0, m = 0 (B) n = 2,l = 0, m = 0 h
in an orbit is given by (  l).
. This momentum
(C) n = 2,l = 1, m = 1 (D) n = 3,l = 2, m = 1 2
for an s-electron will be given by (2003)
(E) n = 3,l = 2, m = 0
(a) (D) and (E) (b) (C) and (D) h
(a) zero (b)
2
(c) (B) and (C) (d) (A) and (B)
h 1 h
23. Of the following sets which one does NOT contain (c) 2. (d)  .
isoelectronic species? (2005) 2 2 2
30. Which one of the following groupings represents a
(a) BO33 ,CO32 , NO3 (b) SO32 ,CO32 , NO3 collection of isoelectric species ? (At. nos. : Cs : 55,
2
Br : 35) (2003)
(c) CN  , N 2 , C2 (d) PO34 ,SO24 ,ClO 2
(a) N3 , F , Na  (b) Be,Al3 ,Cl
24. Which of the following sets of quantum numbers is
correct for an electron in 4f orbital ? (2004) (c) Ca 2 ,Cs  ,Br (d) Na  , Ca 2  , Mg 2 
31. In Bohr series of lines of hydrogen spectrum, the third
(a) n  4,   3,m  1,s   1 2
line from the red end corresponds to which one of the
following inter-orbit jumps of the electron for Bohr
(b) n  4,   4, m  4,s   1 2
orbits in an atom of hydrogen (2003)
(c) n  4,   3,m  4, s   1 2 (a) 5  2 (b) 4  1
(c) 2  5 (d) 3  2
(d) n  3,   2,m  2,s   1 2
32. The de Brogile wavelength of a tennis ball of mass 60 g
25. Consider the ground state of Cr atom (X = 24). The moving with a velocity of 10 metres per second is
number of electrons with the azimuthal quantum approximately (2003)
numbers,   1 and 2 are, respectively (2004)
(a) 1031 metres (b) 1016 metres
(a) 16 and 4 (b) 12 and 5
(c) 12 and 4 (d) 16 and 5 (c) 1025 metres (d) 1033 metres
26. The wavelength of the radiation emitted, when in a Planck’s constant, h = 6.63 × 10–34 Js
hydrogen atom electron falls from infinity to stationary
33. In a hydrogen atom, if energy of an electron in ground
state 1, would be (Rydberg constant = 1.097  107 m 1 ) state is 13.6. ev, then that in the 2nd excited state is
(2004) (2002)
(a) 406 nm (b) 192 nm (a) 1.51 eV (b) 3.4 eV
(c) 6.04 eV (d) 13.6 eV.
(c ) 91 nm (d) 9.1  108 nm 34. Uncertainty in position of a minute particle of mass 25
27. Which one of the following sets of ions represents the g in space is 10-5 m. (2002)
collection of isoelectronic species ? (2004) (a) 2.1  1034 (b) 0.5 1034
(a) K  ,Cl , Mg 2 ,Sc3 (c ) 2.1  1028 (d) 0.5  1023
(b) Na  ,Ca 2 ,Sc3 ,F
JEE main (Online)
(c ) K  ,Ca 2 ,Sc3 ,Cl
1. A 50 watt bulb emits monochromatic red light of
(d) Na  , Mg 2  , Al3 ,Cl wavelength of 795 nm. The number of photons emitted
(Atomic nos. : F = 9, Cl = 17, Na = 11, Mg = 12, Al = per second by the bulb is x  1020. The value of x is
13, K = 19, Ca = 20, Sc = 21) _____. (2021)
28. The number of d-electrons retained in Fe2+ (At. no. of [Given : h  6.63  10  34 Js and c  3.0  108 ms 1 ]
Fe = 26) ion is (2003)
17
2. If the Thompson model of the atom was correct, then Choose the most appropriate answer from the options
the result of Rutherford’s gold foil experiment would given below :
have been : (2021) (a) (C) only (b) (A) only
(a) All of the  -particles pass through the gold foil
(c) (A),(C) and (D) only (d) (A) and (D) only
without decrease in speed.
8. The kinetic energy of an electron in the second Bohr
(b)  -Particles are deflected over a wide range of
angles. h2
robit of a hydrogen atom is equal to . The value
(c) All  -particles get pounced back by 180°. xma 02
of 10x is _____. (a0 is radius of Bohr’s orbit) (Nearest
(d)  -Particles pass through the gold foil deflected by
integer)
small an gles and with reduced speed.
3. A source of monochromatic radiation of wavelength 400 [Given :   3.14] (2021)
nm provides 1000 J of energy in 10 seconde. When 9. Given below are two stements.
this radiation falls on the surface of sodium,
Staement I : According to Bohr’s model of an atom,
x  10 20 electrons are ejected per second. Assume that qualitatively the magnitude of velocity of electron
wavelength 400 nm is sufficient for ejection of electron increases with decrease in positive charges on the
from the surface of sodium metal. The value of x is nucleus as there is no strong hold on the electron by
_____. (Nearst integer) the nucleus.
 h  6.626 1034 Js  (2021)

Staement II : According to Bohr’s model of an atom,
qualitatively the magnitude of velocity of electron
4. The wavelength of electrons accelerated from rest increases with decrease in principal quantum number.
through a potential difference of 40 kV is x  1012 m. In the light of the above statemcnts, choose the most
The value of x is _____. (Nearest integer) appropriate answer from the options given below :
Given : Mass of electron  9.11031 kg (2021)
(a) Both Statement I and Statement II are false
Charge on an electron  1.6  1091 C
(b) Both Statement I and Statement II are true
Planck’s constant  6.63  1034 Js (2021)
(c ) Statement I is false but Statement II is true
5. Which of the following forms of hydrogen emits low
(d) Statement I is true but Statement II is false
energy  particles? (2021)
10. The number of photons emitted by a monochromatic
(a) Proton H+ (b) Tritium 13 H (single frequency) infrared range finder of power 1 mW
and wavelength of 1000 nm, in 0.1 second is x × 1013.
(c) Protium 11 H (d) Deuterium 2
1H The value of x is ______. (Nearest integer)
6. Electromagnetic radiation of wavelentgh 663 nm is just
(h = 6.63 × 10–34 Js, c = 3.00 × 108 ms–1) (2021)
sufficient to ionise the atom atom of metal A . The
ionization energy of metal A in kJ mol -1 is ____. 11. A metal surface is exposed to 500 nm radiation. The
(Rounded-off to the nearest integer) (2021) threshold frequency of the metal for photoelectric
current is 4.3 × 1014 Hz. The velocity of ejected electron
h  6.631034 Js,c  3,00 108 ms1,NA  6.02 1023 mol1
  is ______ × 105 ms–1 (Nearest integer)
7. According to Bohr’s atomic theory : (2021) [Use h  6.63  1034 Js, m e  9.0  10 31 kg] (2021)
Z2 12. An accelerated electron has speed of 5 × 106 ms–1 with
(A) Kinetic energy of electron is 
n 2 an uncertainty of 0.02%. The uncertainty in finding its
location while in motion is x × 10–9 m. The value of x
(B) The product of velocity (v) of electron and principal is _____. (Nearest integer)
quantum number  n  ,' vn ' Z2 . [Use mass of electron
(C) Frequency of revolution of electron in an orbit is
 9.1 1031 kg, h  6.63  1034 Js.   3.14] (2021)
Z2
 . 13. When light of wavelength 248 um falls on a metal of
n3
threshold energy 3.0 eV, the de-Broglie wavelength of
(D) Coulombic force of attraction on the electron is
emitted electrons is _____ Å. (Round off to the Nearest
Z2
 . 34
n4 Integer).  Use : 3  1.73,h  6.63 10 Js  (2021)
18
14. A ball weighing 10 g is moving with a velocity of 90 91 271
ms–1. If the uncertainty in its velocity is 5%, then the (c ) (d)
5 5
uncertainty in its position is ______ × 10 –23 m.
(Rounded off to the nearest integer) 25. For the Balmer series in the spectrum of H atom,
 Given : h=6.63  10 34Js  (2021)   1 1 
  v  R H  2  2  , the correct statements among (I) to
 n1 n 2 
15. A proton and a Li3+ nucleus are accelerated by the same
(IV) are: (2020)
potential. If  Li and  p denote the de Broglie
(I) As wavelength decreases, the lines in the series
wavelengths of Li3+ and proton respectively, then the
converge
value of is x 101. The value of x is ______ (II) The integer n1 is equal to 2
(Rounded off to the nearest integer) (II) The lines of longest wavelength corresponds to
(Mass of Li3+ = 8.3 mass of proton) (2021) n2 = 3
16. The value of magnetic quantum number of the outermost (IV) The ionization energy of hydrogen can be calculated
electron of Zn+ ion is ______ . (2021) from wave number of these lines
17. The Azimuthal quantum number of the valence electrons (a) (I), (III), (IV) (b) (I), (II), (III)
of Ga+ ion is _____ . (2021) (c) (I), (II), (IV) (d) (II), (III), (IV)
(Atomic Number of Ga = 31) 26. The radius of the second Bohr orbit, in terms of the
18. A certain orbital has no angular nodes and two radial Bohr radius, a0 in Li2+ is (2020)
nodes. The orbital is (20201)
2a 0 4a 0
(a) 2p (b) 3p (a) (b)
3 9
(c ) 3s (d) 2s
19. A certain orbital has n = 4 and mL = –3. The number of 4a 0 2a 0
(c ) (d)
radial nodes in this orbital is ______. (2021) 3 9
(Round off to the Nearest Integer). 27. The figure that is not a direct manifestion of the quantum
20. The number of orbitals with n = 5, m1 = +2 is _____. nature of atoms is : (2020)
(Round off to the Nearest Integer). (2021)
21. The orbital having two radial as well as two angular Intensity
of black k body
nodes is : (2021) radiation T2 > T1
(a) 3p (b) 4d (a)
T1
(c ) 5d (d) 4f
Wavelength
22. The difference between the radii of 3td and 4th orbits
of Li2+ is R1. The differlnce between the radii of 3rd Kinetic
Rb K Na
energy of
and 4th orbits of He+ is R 2 . Ratio R1 : R 2 is photoelectrons
(2020) (b)
(a) 8 : 3 (b) 3 : 8 Frequency of incident
(c ) 2 : 3 (d) 3 : 2 radiation
23. The region in the electromagnetic spectrum where the

Balmer series lines appear is : (2020)
(a) Visible (b) Microwave (c)
(c) Infrared (d) Ultravioket

24. The shortest wavelength of H atom in the Lyman series Internal
is 1. The longest wavelength in the Balmer series is energy of
Ar
He+ is : (2020)
(d)
361 51
(a) (b) 300 400 500 600
5 9 Temperature (K)
19
28. The work function of sodium metal is 4.41 × 10–19 J. Velocity of light  3 108 ms 1
If photons of wavelength 300 nm are incident on the
metal, the kinetic energy of the ejected electrons will be Planck’s constant  6.626  1034 Js
(h = 6.63 × 10–34 Js; c = 3 × 108 m/s)____ × 10–21 J. Charge of electron  1.6  1019 JeV 1 )
(2020) (a) 0.9 eV (b) 3.1 eV
29. The de Broglie wavelength of an electron in the 4th (c ) 2.1 eV (d) 4.0 eV
Bohr orbit is: (2020)
37. The ratio of the shortest wavelength of two spectral
(a) 2a 0 (b) 4a 0 series of hydrogen spectrum is found to be about 9.
(c) 6a 0 (d) 8a 0 The spectral series are : (2019)
30. In the sixth period, the orbitals that are filled are : (a) Lyman and Pschen (b) Balmer and Brackett
(2020) (c) Brackett and Pfund (d) Paschen and Pfund
(a) 6s, 4f ,5d, 6p (b) 6s,5d,5f ,6p 38. For any given series of spectral lines of atomic hydrogen,
  
let v  vmax  v min be the difference in maximum and
(c) 6s,5f ,6d,6p (d) 6s,6p,6d,6f
minimum frequencies in cm –1 . The ratio
31. The correct statement about probability density (except  
v Lymar / vBefore is: (2019)
at in finite distance from nucleus) is : (2020)
(a) It can be zero for 1s orbital (a) 4 : 1 (b) 9 : 4
(b) It can be negative for 2p orbital (c) 5 : 4 (d) 27 : 5
(c ) It can be zero for 3p orbital 39. Which one of the following about an electron occupying
the 1s orbital in a hydrogen atom is incorrect? (The
(d) It can never be zero for 2s orbital
Bohr radius is represented by a0). (2019)
32. Consider the hypothetical situation where the azimuthal
(a) The probability density of finding the electron is
quantum number, , takes values 0, 1, 2, ....... n + 1,
maximum at the nucleus.
where n is the principal quantum number. Then, the
element with atomic number : (2020) (b) The electron can be found at a distance 2a0 from
the nucleus.
(a) 9 is the first alkali metal
(c) The magnitude of the potential energy is double that
(b) 13 has a half-filled valence subshell
of its kinetic energy on an average.
(c) 8 is the first noble gas
(d) The total energy of the electron is maximum when
(d) 6 has a 2p-valence subshell it is at a distance a0 from the nucleus.
33. The number of subshells associated with n = 4 and m 40. Heat treatment of muscular pain involves radiation of
= –2 quantum numbers is : (2020) wavelength of about 900 nm. Which spectral line of H-
(a) 8 (b) 2 atom is suitable for this purpose?
(c) 16 (d) 4 [RH = 1×105 cm–1, h = 6.6 × 10–34 Js, c = 3 × 108
34. The number of orbitals associated with quantum numbers ms –1 ] (2019)
1 (a) Paschen,   3 (b) Paschen, 5  3
n  5, ms   is: (2020)
2 (c) Balmer,   2 (d) Lyman,   1
(a) 11 (b) 25 41. Which of the graphs shown below does not represent
(c) 50 (d) 15 the relationship between incident light and the electron
35. Among the following, the energy of 2s orbital is lowest ejected from metal surface? (2019)
in : (2019)
(a) K (b) H K.E. of
e– s
(c) Li (d) Na
36. What is the work function of the metal if the light of
wavelength 4000Å generates plotoeletrons of velocity
-1 (a)
6  105 ms from it? (2019)
(Mas of electron  9  1031 kg 0 Energy of light
20
K.E. of 3 1
e– s (a)  (b) 
4 2
2 4
(c)  (d) 
3 9
(b) 45. If the de Broglie wavelength of the electron in nth Bohr
orbit in a hydrogenic atom is equal to 1.5 a 0 (a0 is
0 Frequency of light Bohr radius), then the value of n/z is: (2019)
(a) 0.40 (b) 1.50
K.E. of (c) 1.0 (d) 0.75
e– s
46. The de Broglie wavelength (  ) associated with a
photoelectron varies with the frequency (v) of the
incident radiation as, [v0 is threshold frequency];
(c ) (2019)
1
1
0 Frequency of light 
(a)   v  v (b) 1
 0  v  v0  4
K.E. of
e– s 1 1
 3
 1
(c) (d)
 
v  v0 2  v  v0  2
47. The electrons are more likely to be found : (2019)
(d)
0
 x 
Intensity of light
a
42. The ground state energy of hydrogen atom is –13.6 eV.
The energy of second excited state of He+ ion in eV is: b x
(2019) x
(a) –54.4 (b) –3.4 c
(c ) –6.04 (d) –27.2
43. For emission line of atomic hydrogen from ni = 8 to
 1  (a) in the region a an c (b) in the region a and b

nf = n, the plot of wave number (v) against  2 
n  (c) only in the region a (d) only in the region c
will be (The Rydberg constant, RH is in wave number
48. The graph between  2 and r (radial distance is shown
unit) (2019)
(a) Linear with intercept - RH below. This represents : (2019)
(b) Non linear
(c) Linear with slope RH
(d) Linear with slope RH 2

44. If p is the momentum of the fastest electron ejected
from a metal surface after the irradiation of light having
wavelength >>, then for 1.5p momentum of the
photoelectron, the wavelength of the light should be: r
(Assume kinetic energy of ejected photoelectron to be
very high in comparison to work function): (2019) (a) 3s orbital (b) 2s orbital
(c) 1s orbital (d) 2p orbital
21
49. The isoelectronic set of ions is (2019) (c) Photon has momentum as well as wavelength
(a) N3 ,O 2 , F and Na + (d) Rydberg constant has unit of energy
54. Ejection of the photoelectron from metal in the
(b) N 3 , Li  ,Mg 2 and O 2- photoelectric effect experiment can be stopped by
(c) F  , Li  , Na  and Mg 2 applying 0.5V when the radiation of 250 nm is used.
The work function of the metal is : (2018)
(d) Li  , Na  ,O 2  and F2 (a) 4 eV (b) 5.5 eV
50. The quantum number of four electrons are given below: (c ) 4.5 eV (d) 5 eV
(2019)
55. The de-Broglie’s wavelength of electron present in first
I. n  4,   2,m  2, ms  1/ 2 Bohr orbit of ‘H’ atom is: (2018)
II. n  3,   2,m  1,ms  1/ 2 (a) 4  0.529Å (b) 2 0.529Å
III. n  4,   1,m   0, ms  1/ 2 0.529
(c) Å (d) 0.529Å
IV. n  3,l  ,m   1,ms  1/ 2 2
The correct order of their increasing energies will be: 56. If the shortest wavelength in Lyman series of hydrogen
atom is A, then the longest wavelength in Paschen series
(a) IV < III < II < I (b) I < II < III < IV
of He+ is : (2017)
(c ) IV < II < III < I (d) I < III < II < IV
51. The size of the iso-electronic species Cl –, Ar and Ca2+ 5A 9A
(a) (b)
is affected by (2019) 9 5
(a) azimuthal quantum number of valence shell
36A 36A
(b) electron-electron interaction in the outer orbitals (c) (d)
5 7
(c) principal quantum number of valence shell
57. The electron in the hydrogen atom undergoes transition
(d) nuclear charge from higher orbitals to orbital of radius 211.6 pm. This
52. Which of the following combination of statements is transition is associated with : (2017)
true regarding the interpretation of the atomic orbitals? (a) Lyman series (b) Balmer series
(2019)
(c) Paschen series (d) Brackett series
(a) An electron in an orbital of high angular momentum
58. The total number of orbitals associated with the principal
stays away from the nucleus than an electron in
quantum number 5 is: (2016)
the orbital of lower angular momentum.
(a) 20 (b) 25
(b) For a given value of the principal quantum number,
the size of the orbit is inversely proportional to the (c) 10 (d) 5
azimuthal quantum number. 59. At temperature T, the average kinetic energy of any
(c) According to wave mechanics, the ground state 3
particle is kT. The de Broglie wavelength follows
h 2
angular momentum is equal to the order : (2015)
2
(a) Visible photon > Thermal neutron > Thermal
(d) The plot of  vs r for various azimuthal quantum electron
numbers, shows peak shifting towards higher r (b) Thermal proton > Thermal electron > Visible photon
value.
(c) Thermal proton > Visible photon > Thermal electron
(a) (a), (d) (b) (a), (b) (d) Visible photon > Thermal electron > Thermal neutron
(c) (a), (c) (d) (b), (c) 60. If the principal quantum number n = 6, the correct
53. Which of the following statements is false? (2018) sequence of filling of electrons will be : (2015)
(a) Splitting of spectral lines in electrical field is called (a) ns   n  2  f  np   n  1 d
Stark effect
(b) Frequency of emitted radiation from a black body (b) ns   n  2  f   n  1 d  np
goes from a lower wavelength to higher wavelength (c) ns  np   n  1 d   n  2  f
as the temperature increases
(d) ns   n  1 d   n  2  f  np
22
(a) It is a negatively charged particle.
NCERT Exemplar (b) The mass of electron is equal to the mass of neutron.
1. Which of the following conclusions could not be derived (c) It is a basic constituent of all atoms.
from Rutherford’s -particle scattering experiment? (d) It is a constituent of cathode rays.
(a) Most of the space in the atom is empty. 6. Which of the following properties of atom could be
(b) The radius of the atom is about 10–10 m while that explained correctly by Thomson Model of atom?
of nucleus is 10–15 m.
(a) Overall neutrality of atom.
(c ) Electrons move in a circular path of fixed energy
(b) Spectra of hydrogen atom.
called orbits.
(c) Position of electrons, protons and neutrons in atom.
(d) Electrons and the nucleus are held together by
(d) Stability of atom.
electrostatic forces of attraction.
7. Two atoms are said to be isobars if
2. Which of the following options does not represent
ground state electronic configuration of an atom? (a) they have same atomic number but different mass
number.
(a) 1s2 2s2 2p6 3s2 3p6 3d8 4s2
(b) 1s2 2s2 2p6 3s2 3p6 3d9 4s2 (b) they have same number of electrons but different
number of neutrons.
(c) 1s2 2s2 2p6 3s2 3p6 3d10 4s1
(c) they have same number of neutrons but different
(d) 1s2 2s2 2p6 3s2 3p6 3d5 4s1 number of electrons.
3. The probability density plots of 1s and 2s orbitals are (d) sum of the number of protons and neutrons is same
given in figure. but the number of protons is different.
8. The number of radial nodes for 3p orbital is _______.
(a) 3 (b) 4
(c) 2 (d) 1
9. Number of angular nodes for 4d orbital is _______.
1s 2s
(a) 4 (b) 3
The density of dots in a region represents the probability
density of finding electrons in the region. (c ) 2 (d) 1
On the basis of above diagram, which of the following 10. Which of the following is responsible to rule out the
statements is incorrect? existence of definite paths or trajectories of electrons?
(a) 1s and 2s orbitals are spherical in shape. (a) Paulis exclusion principle
(b) The probability of finding the electron is maximum (b) Heisenberg’s uncertainty principle
near the nucleus. (c) Hund’s rule of maximum multiplicity
(c) The probability of finding the electron at a given (d) Aufbau principle
distance is equal in all directions. 11. Total number of orbitals associated with third shell will
(d) The probability density of electrons for 2s orbital be _________ .
decreases uniformly as distance from the nuiformly
(a) 2 (b) 4
as distance from the nucleus increases.
(c ) 9 (d) 3
4. Which of the following statements is not correct about
the characteristics of cathode rays ? 12. Orbital angular momentum depends on _________ .
(a) They start from the cathode and move towards the (a) l (b) n and l
anode. (c) n and m (d) m and s
(b) They travel in straight line in the absence of an 13. Chlorine exists in two isotopic forms, Cl-37 and Cl-35
external electrical or magnetic field. but its atomic mass is 35.5. This indicates the ratio of
(c) Characteristics of cathode rays do not depend upon Cl-37 and C-35 is approximately
the material of electrodes in cathod ray tube. (a) 1 : 2 (b) 1 : 1
(d) Characteristics of cathode rays depends upon the (c ) 1 : 3 (d) 3 : 1
nature of gas present in the cathode ray tube.
14. The pair of ions having same electronic configuration is
5. Which of the following statements about the electron is __________.
incorrect?
23
(a) Cr3 , Fe3 (b) Fe3 , Mn 2

(c) Fe3 ,Co3 (d) Sc3 ,Cr 3
15. For the electrons of oxygen atom, which of the
following statements is correct?
(a) Zeff for an electron in a 2s orbital is the same as
Zeff for an electron in a 2p orbital.
(b) An electron in the 2s orbital has the same energy as
an electron in the sp orbital.
(c) Zeff for an electron in 1s orbital is the same as
Zeff for an electron in a 2s orbital.
(d) The two electrons present in the 2s orbital have
spin quantum numbers ms but of opposite sign.
16. If travelling at same speeds, which of the following
matter waves have the shortest wavelength?
(a) Electron (b) Alpha particle (He2+)
(c) Neutron (d) Proton
24
Answers Structure of Atom

77. (d) 78. (b) 79. (c ) 80. (b)
NEET (AIPMT) 81. (b) 82. (d) 83. (c ) 84. (b)
85. (d) 86. (c ) 87. (a) 88. (d)
1. (a) 2. (b) 3. (b) 4. (a)
89. (a) 90. (b) 91. (d) 92. (b)
5. (c) 6. (b) 7. (b) 8. (c)
93. (a) 94. (c ) 95. (c ) 96. (b)
9. (c) 10. (c) 11. (a) 12. (c)
97. (c ) 98. (d) 99. (a) 100. (c )
13. (b) 14. (c) 15. (d) 16. (c)
101. (a) 102. (b) 103. (d) 104. (b)
17. (a) 18. (b) 19. (d) 20. (a)
105. (d) 106. (b) 107. (b) 108. (c )
21. (a) 22. (b) 23. (b) 24. (b)
109. (a) 110. (a) 111. (d) 112. (c )
25. (a) 26. (a) 27. (c) 28. (a)
113. (a) 114. (a) 115. (c ) 116. (b)
29. (b) 30. (a) 31. (b) 32. (c)
117. (b) 118. (b) 119. (b) 120. (b)
33. (c) 34. (d) 35. (c) 36. (c)
121. (a) 122. (d) 123. (a) 124. (b)
37. (b) 38. (b) 39. (d) 40. (b)
125. (b) 126. (b) 127. (a) 128. (a)
41. (c) 42. (c) 43. (a) 44. (a)
129. (a) 130. (c ) 131. (c) 132. (c )
45. (a) 46. (d) 47. (d) 48. (a)
133. (d) 134. (b) 135. (a) 136. (a)
49. (c) 50. (d) 51. (d) 52. (a)
137. (c ) 138. (a) 139. (a) 140. (c )
53. (b) 54. (d) 55. (c) 56. (c)
141. (b) 142. (c ) 143. (c ) 144. (c )
57. (a) 58. (b) 59. (c) 60. (b)
145. (d) 146. (c ) 147. (d) 148. (b)
61. (d) 62. (d) 63. (b) 64. (b)
149. (b) 150. (a)
65. (c) 66. (a) 67. (c) 68. (b)
69. (d) 70. (b) 71. (a) JEE main (AIEEE)
Other Medical 1. (d) 2. (c) 3. (b) 4. (d)
5. (a) 6. (b) 7. (a) 8. (a)
1. (c ) 2. (b) 3. (b) 4. (c )
9. (a) 10. (b) 11. (c) 12. (d)
5. (a) 6. (b) 7. (c ) 8. (c )
13. (b) 14. (a) 15. (b) 16. (b)
9. (c ) 10. (b) 11. (b) 12. (c )
17. (d) 18. (c) 19. (b) 20. (a)
13. (d) 14. (b) 15. (a) 16. (b)
21. (c) 22. (a) 23. (b) 24. (a)
17. (c ) 18. (c ) 19. (c ) 20. (c )
25. (b) 26. (c) 27. (c) 28. (c)
21. (a) 22. (c ) 23. (c ) 24. (b)
29. (a) 30. (a) 31. (a) 32. (d)
25. (a) 26. (c ) 27. (a) 28. (c )
33. (a) 34. (c)
29. (b) 30. (b) 31. (a) 32. (a)
33. (d) 34. (c ) 35. (b) 36. (d) JEE main (Online)
37. (a) 38. (c ) 39. (d) 40. (d)
41. (a) 42. (c) 43. (a) 44. (c ) 1. (2) 2. (d) 3. (2) 4. (6)
45. (a) 46. (c ) 47. (c ) 48. (c ) 5. (b) 6. (181) 7. (d) 8. (3155)
49. (b) 50. (a) 51. (b) 52. (c ) 9. (c) 10. (50) 11. (5) 12. (58)
53. (d) 54. (a) 55. (d) 56. (d) 13. (9) 14. (1) 15. (2) 16. (0)
57. (a) 58. (a) 59. (d) 60. (d) 17. (0) 18. (c) 19. (0) 20. (3)
61. (c ) 62. (a) 63. (a) 64. (c ) 21. (c) 22. (c) 23. (a) 24. (c)
65. (c ) 66. (c ) 67. (c ) 68. (c ) 25. (b) 26. (c) 27. (d) 28. (222)
69. (b) 70. (d) 71. (c ) 72. (a) 29. (d) 30. (a) 31. (c) 32. (b)
73. (b) 74. (c ) 75. (a) 76. (a) 33. (b) 34. (b) 35. (a) 36. (c)
25
37. (a) 38. (b) 39. (d) 40. (a)

41. (c) 42. (c) 43. (d) 44. (d)
45. (d) 46. (d) 47. (a) 48. (b)
49. (a) 50. (c) 51. (d) 52. (a)
53. (b) 54. (c) 55. (b) 56. (d)
57. (b) 58. (b) 59. (d) 60. (b)
NCERT Exemplar
1. (c) 2. (b) 3. (d) 4. (d)
5. (b) 6. (a) 7. (d) 8. (d)
9. (c) 10. (b) 11. (c) 12. (a)
13. (c) 14. (b) 15. (d) 16. (b)
26
Hints & Solution Structure of Atom

NEET (AIPMT) 11. For n  3 and l  1, the subshell is 3p and a particular 3p orbital
can accommodate only 2 electrons.
1. Among the given pairs of ions, Fe2+ and Mn2+ 12. d x 2  y 2 and d 2 orbitals have electron density along the axes while
z
is not an iso-electronicpair
d xy , d yz and d xz orbitals have electron density in between the
c c 3  108 ms 1 axes.
2.   ;    219.3m
  1368  103 s 1 13. for the two electrons occupying the same orbital values of n, l
3. The electron is more tightly bound in the smallest allowed orbit. 1 1
and m1 are same but m, is different, i.e.,  and  .
175 2 2
4. 71 Lu, Number of protons = Number of
elecctrons = Atomic number = 71 14. Ti  22  :1s 2 2 s 2 2 p 6 3s 2 3 p 6 4 s 2 3d 2
Number of neutrons = Mass number - Atomic number  Order of increasing energy is 32,3 p ,4 s ,3d .
= 175 - 71 = 104 15. Number of d-electrons in Fe2+ = 6
5. Lyman series : UV region Number of p-electrons in Cl = 11
Balmer series : Visble region
16. Angular momentum  l  l  1h
Paschen series : IR region
Brackett series : IR region For d-orbital, l  2
6. Bohr radius, a0 = 52.9 pm Angular momentum  2  2  1h  6h
n = 2, rn = n2a0 = (2)2a0 = 4  52.9 pm = 211.6 pm
17. Only one orbital, 3pz has following set of quantum numbers,
The angular momentum of an electron in a given stationary state
can be expressed as in equation, n  3, l  1 and m1  0 .
h h h 18. Species No. of electrons
mvr  n.  2   mvr   h ...(i)
2 2  Be2+ 2
de-Brogile equation, H+ 0
h Li+ 2
 ; mv  h ...(ii)
mv Na+ 10
From equations (i) and (ii), we get   r Mg+2 10
Putting the value of r,   211.6 pm hc

19. E [Given, =45nm=45  10 9 m]
7. Higher the value of (n + l) for an orbital, higher is its energy. 
However, if two different types of orbitals have same value of On putting the given values in the equation, we get
(n + l), the orbital with lower value of n has lower energy. 6.63  1034  3  108
E  4.42  1018 J
Therefore, decreasing order of energy of the given orbitals is 45  109
5 f  6 p  5 p  4d . 20. c  
8. Number of spherical/radial nodes in any orbital  n  l  1
c 3  1017
Number of planar/angular nodes in orbital  l  3    50nm
 6  1015
 Total number of nodes in any orbirtal  n  1  3
hcN A
 n4 21. We know that, E 

Thus, the orbital is 4f.
9. According to Hund’s rule of maximum multiplicity, the correct 6.62  1027  3  1010  6.02  10 23

configuration of ‘N’ is 
1
1s 2 2s 2 2 p1x 2 p y 2 p1z 1.1955 108 1.196  108
 ergs mol1
 
22. The orbital associated with n  3, l  1 is 3 p. One orbital (with
10. In case of hydrogen like atoms, energy depends on the principal m  1) of 3p-subshell can accommodate maximum 2 electrons.
quantum number only. Hence, 2s-orbital will have energy equal
to 2p-orbital. 23. The electronic configuration of 64 Gd is  Xe  4 f 7 5d 1 6 s 2 .
27
24. In an atom, for any value of n, the values of l  0 to  n  1 . 2 h

or  mv    x  p 
4
For a given value of l, the values of m1  l to +l and the value
of s  1/ 2 or  1 / 2. h h
or v 
2m 
In option (b), l  2 and m1  3
This is not possible, as values of m1 which are possible for 36. Uncertainty in momentum  mv 
l  2 are  2, 1,0, 1 and +2 only.
 11018 g cms1
25. No. of radial nodes in 3p-orbital  n  l  1
26. l  3 and n  4 represents 4f. So, total number of electrons in a Uncertainty in velocity  v 
subshell  2  2l  1  2  2  3  1  14 electrons. Hence, 1 1018

  1.1109 cm s 1
9  1028
f  subshell can contain maximum 14 electrons.
37. (i) represents an electron in 3s orbital.
27. Rb  37  :1s 2 s 2 p 3s 4 s 3d 4 p 5s
2 2 6 6 2 10 6 1
(ii) is not possible as value of l varies from 0, 1, .... (n – 1).
(iii) represents an electron in 4f orbital.
For 5 s , n  5, l  0, m  0, s  1 / 2 or -1/2
(iv) is not possible as value of m varies from l...  l .
28. Orbital angular momentum (m)
(v) is not possible as value of m varies from l...  l , it can
h
 l  l  1 never be greater than l.
2
38. x.mv  h / 4
For p-electrons; l  1
6.626  1034
0.1 1010  9.11  1031  v 
h 2h h 4  3.143
Thus, m  11  1  
2 2  2 6.626  10 34
 v 
29. Total number of atomic orbitals in any energy level is given by 0.1 1010  9.11  10 31  4  3.143
n2 .  5.79  106 ms 1
30. P 39. Principal quantum number represents the name, size and energy
hc hc of the shell to which the electron belongs. Azimuthal quantum
31. E1  and E 2 
1 2 ; number describes the spatial distribution of electron cloud and
angular momentum. Magnetic quantum number describes the
E1 hc  2  2
   orientation of distribution of electron cloud. Spin quantum number
E2 1 hc 1
represents the direction of electron spin around its own axis.
25  2 1  2 2
or  or   1  2 2 Z
50 1 2 1 40. En   k  
n
32. We know that Z = 1 for hydrogen: n = 2
1 k  1
1 E2   E2  328k Jmol 1; K  4  328
E   2  2  , where n > n 4
 n1 n2  2 1
k 1 1
 n = 6 to n = 5 will give least energetic photon. E4   E4  4  328   82K J mol 1
16 16
h
33. According to de-Brogile eqation,   41. E  h or   E / h
mv
21.8  1019
Given, h  6.6  1034 J s; m = 0.66 kg ; v = 100 m s 1 For H atom, E  J atom-1
n2
6.6  1034  1 1
   1 1035 m E  21.8  1019  2  2   20.44  1019 J atom-1
0.66  100 4 1 
34. For a given shell, l, the number of subshells, m1   2l  1 20.44  1019
Since each subshell can accommodate 2 electrons of opposite   3.08  1015 s 1
6.626  1034
spin, so maximum number of electrons in a subshell
 2  2l  1  4l  2. 42. Applying   c / ,
35. From Heisenberg uncertainty principle, c 3  108

   37.5  109 m
h h  8  1015
p.x  or mv  x 
4 4
 37.5nm  4  101 nm
28
2 53. The longest wavelength means the lowestn
1 2  e 2 
43. Kinetic energy  my     2m
 energy. We know that relation for wavelength
2  nh 
 1  1 1 
2e2   RH  2  2 
v     
 nh   n1 n2 
(RH, Rydberg constant = 109677 cm-1)
2 4  e2 2 for n1 = 2, n2 = 3
2 me
Total energy. En   2 2
    2m   K .E .
 nh 
n h   1  1 1 
 109677  2  2   15233
 Kinetic energy = - En   (3) 
 (2)
Energy of first excited state is - 3.4 eV.
 1
Kinetic energy of same orbit (n = 2 ) will be + 3.4 eV. or,    6.56  105 cm
44. n  3, l  2, m  2 15233
It symbolises one of the five d-orbitals (3d).  6.56 107 m  656 nm
m = + 2 +1 0 –1 –2 54. Energy of an atom when n=1
1312
E1   2
 1312 kJ mol 1
45. Species having same no. of eletrons are called 1
isoelectronic species.
1312
Similarly energy when n = 3,  E3   
The no. of electrons is CO = CN- = NO+ = C22 = 14. So, these  3 2
are isoelectronic species.
 145.7 kJ mol 1
 34 8
hc 6.62  10  3  10 The energy absorbed when an electron jumps from n = 1 to
46. E 
 3.03  10  19 n = 3,
= 656 nm E3  E1  145.7   1312   1166.3 kJ mol 1
47. Sommerfeld modified Bohr’s theory
considering that in addition to circular orbits electrons 1166.3
  193.6  1023 kJ
also move in elliptical orbits. 6.023  1023
h 1 joule = 107 ergs 
48. x  p   193.6 1020 J  
4
(Heisenberg uncertainty principle)  193.6  1013 ergs = 0.1936  10 10 ergs
6.62  1034 55. Due to ground state, state of hydrogen atom (n) = 1; Radius of
 x   5.27  10 30 m hydrogen atom (r) = 0.53 Å
4  3.14  105
Atomic no. of Li (Z) = 3
h 6.63  1027 erg sec n2
2
1  0.17 Å
49.  
mv 1g  104 cm/s Now, radius of Li2+ ion = r   0.53 
Z 3
 6.63  1031cm  6.63  1033 m 56. Mass of an electron  m   9.1  10 28 g
50. For ntn orbit of ‘H’ atom, rn  n 2  r1 Velocity of electron  v   3  10 4 cm/s
 radius of 2nd Bohr’s orbit.
r2  4  r1  4  0.53  2.12Å Accuracy  0.001%  0.001 amd
100
51. According to uncertainty principle the product of uncertainty in
position and uncertainty in momentum is constant for a particle. Planck’s constant  h   6.626  10 27 erg-second.
h We know that actual velocity of the electron
i.e., x  p 
4 0.001
As, x  1.0 nm for both electron and helium atom, so p  v   3  10 4   .3cm/s
100
is also same for both the particles.
Therfore, uncertainty in the position of the electron,
Thus, uncertainty in momentum of the helium atom is
also 5.0  1026 kg ms 1. h 6.626  1027
 v     1.93cm
52. Since both CO and CN- have 14 electrons, 4mv 4  (9.1  1028 )  0.3
therefore these are isoelectronic species (i.e. having same 57. The number of electrons in O2-, N3-, F- and
number of electrons). Na+ is 10 each, but number of electrons in Tl+ is 80.
29
58. energy of electron depends on the value of  n  l  . The subshell 3. Number of photons emitted = n
nhc 6.6  1034  3  108  n
are 3d, 4d, 4p and 5s, out of which 4d has highest energy. E  3 1018 
59. Energy of an electron in n th Bohr orbit of hydrogen atom =
 660  109
30
13.6  n  10
eV . 3
n2 4. Lyman series : UV region
Balmer series : Visible region
60. Atomic no. of Ca = 20
Paschen series : IR region
 Electronic configuration of Ca   Ar  4 s 2 Brackett series : IR region
61. This is a Pauli’s exclusion principle. n2
5. 2r  n  2  0.529   n
Z
62. l  3 means f -subshell
2  0.529  n 2  3.14  0.529  2
Maximum no. of electrons in f-subshell = 14  
Z 2
f-subshell =   3.32 Å
6. Higher the value of (n + l) for an orbital, higher is its energy.
63. Higher the value of  n  l  for an orbital, higher is its energy.. However, if two different types of orbitals have same value of
However, if two different types of orbitals have same value of (n + l), the orbital with lower value of n has lower energy.
Therefore, decreasing order of energy of the given orbitals is
n  l , the orbital with lower value of n has lower energy..
5f  6p  5p  4d.
64. Electronic configuration of Cu is 7. Number of spherical/radial nodes in any orbital = n - l - 1
1s 2 2 s 2 2 p 6 3s 2 3 p 6 3d 10 4 s1. Number of planar/angular nodes in orbital = l = 3
65. n  2, l  1  Total number of nodes in any orbital = n – 1 = 3
It means 2p-orbitals.  n  4. Thus, the orbital is 4f.
Total no. of electrons that can be accommodated in all the 2p 8. The 3d-subshell in case of Cr gets exactly half-filled with
orbitals = 6 configuration 3d54s1 which imparts stability to the atom.
66. Cu+ ion has 18 electrons in its outermost shell. 11. For maximum wavelength in the Balmer series, n 2  3 and n1  2
Electronic configuration of Cu  is 1s 2 2s 2 2 p 6 3s 2 3 p 6 3d 10 1  1 1 
  1.09  10 7  12  2  2 
 2 3 
67. N 2  1s 2 2 s 2 2 p1
1 1 1  5 
 No of unpaired electrons = 1   1.09  107  1    1.09  107  1 
 4 9  36 
68. No. of orbitals in a subshell  2l  1
36
 No. of electrons  2  2l  1  4l  2   m  6.60 107 m  660 nm
5  1.09  107
69. It is Heisenberg’s uncertainty principle and not
12. Na  .Al3 and Ne all have same number of electrons.
Bohr’s postulate.
13. The velocity of an eletron in nth shell of the
70. Both He and Li+ contain 2 electrons each. hydrogen like atom
71. Radius of nth orbit of H-atom = r0n2
2.18  106 ms 1  Z
where r0 = radius of the first orbit. 
n
Other Medical On putting Z = 3 and n = 2,
2.18  106  3
1. Isotopes have different number of neutrons. v  3.27  106 ms 1
2
2. Isotones - Atoms of different elements having same number of
1  1 1 
neutrons e.g., 14 16
6 Cand 8 O.  R H  2  2   Z2
14.   
Isotones - Atoms of same elements having same atomic number  n1 n 2 
but different mass numbers e.g., protium  11H  and tritium  13 H . 1  1 1 

 R H  2  2  (1) 2
Isobars - Atoms of different elements having same mass number 400 n 
40
 1 n2 
but different atomic numbers e.g., 19 K and 40
20Ca.
Isodiaphers- Species having same isotopic number i.e., (no. of 1  1 1 
 R H  2  2  (2)2
235 231  He n 
neutrons-no. of protons) e.e., 92 U and 90 Th both have 51  1 n2 
isotopic number. On dividing equation (i) by (ii), we ger
30
400 400 nh
 He    100 nm 26. We know according to Bohr’s theory, mvr 
2 2 4 2
(as the notations bear their usual meanings)
h
16. The Heisenberg uncertainty principle, x  p , where x
4 nh
v
= Uncertainty position, p = Uncertainty in momentum and 2mr
h / 4  constant. As x is same for clectron and helium and h/  Time required for one complete revolution,
4 is a constant, therefore minimum uncertainty in the 2r 2r 42 mr 2
measurement of the momentum of the helium atom will be same T   2mr 
v nh nh
as that of an electron which is 5.0  1026 kg m s 1. 27. For n = 3 and l = 1, the subshell is 3p and a particular 3p orbital
17. According to Hund’s rule of maximum multiplicity, the correct can accommodate only 2 electrons.
configuration of ‘N’ is d x 2  y2 and d z 2 orbitals have electron density along the axes while
28.
1 1 1
1s2 2s2 2p x 2p y 2p z dxy, dyz and dxz orbitals have electron density in between the
axes.
30. For the two electrons occupying the same orbital values of n, l
1 1
18. As regards penetrating power,   particles are the least, followed and ml are same but ms is different,  and  .
2 2
by   rays (100 times that of   particles) and   rays (1000
times that of   particles). 31. 
5 1

Chromium 3d 4s  6 unpaired electrons
19. Since ionization potential of hydrogen atom is
13.6 eV. 6 2

Iron 3d 4s  4 unpaired electrons
 E1  13.6eV
Now, En  E1 
13.6
 (13.6)  112.1
5 2
 
Manganese 3d 4s  5 unpaired electrons
2
n

3 2

Vanadium 3d 3s  3 unpaired electrons
13.6
 13.6  12.1 32. The electronic confrguration of Cu in ground
n2
 n=3 state :  Ar  3d10 4s1
After absorbing 12.1 eV, the electron of H-atom is excited Hence, for outermost subshell, n = 4, l = 0
to 3rd shell . 1
Thus, possible transitions are 3i.e.,3  2, 2  1 and 3  1 ml = 0 and ms = +
2
20. In case of hydrogen like atoms, energy depends on the principal 33. For a given value of ‘l’ the permissible values of
quantum number only. Hence, 2s-orbital will have energy equal ‘m’ are - l, - (l - l) ....0....(l - l), l. Thus, for l = 2, m cannot
to 2p-orbital. have a value of - 3.
21. The order of increasing energy of the sub-atomic orbitals is s < p 34. Rutherford first of all used zinc sulphide (ZnS) as phosphor in
< d < f. The energy in excited state is more than that in the detection of   Particle.
ground state. In option (a), two electrons are in excited states
 or  
A A
therefore, it has maximum energy. 35.  ZA Y  01 e
Z X 
A  A4  A4  A4 36. Let the monoatomic anion be X– .

22. Z E Z2 X Z1 Y  Z W
Number of electrons in X – = 36
Both elements E and W have same atomic number but different  Number of electrons in monoatomic atom (X) = 36–1 = 35
mass numbers. Hence, both are isotopes. So, the resulting element Atomic number = number of electrons in neutral atom
will be an isotope of E. = number of protons in neutral atom = 35
23. Amount of energy required to break one H––H bond is Mass number of monoatomic atom (X)
= number of protons + number of neutrons
4.36  103 436
 J mol 1 = 35 + 45 = 48
6.023 1023 6.023 1020 Hence, ion must be Br–.
37. According to Rydberg equation,
hc 6.626  10 34  3  108
Now, E     6.023  1020 m
 436 1  1 1 
 R 2  2 
  
6.626  6.023  3  n1 n 2 
  106 ~ 274 nm
436
Here, n1  2,n 2  4 and R  109677 cm 1
24. According to Bohr’s theory,
1  1 1  1 1   4 1 
n 2h 2  k 2 2 2 mZ 2e4   109677  2  2   109677     109677  
r and E n   2 4   4 16   16 
42mZe 2k n 2h 2
31
16 n  4, l  0 represents 4s  orbital
  4.86  10 5 cm
109677  3 The order of increasing energy of the orbitals is:
3 s  3 p  4 s  3d
 486  109 m  486nm  1nm  10 9 m 
  47. (a) For a particular value of n, l  0 to n  1.
38. The wavelength of the line can be calculates by the Rydberg For n  3, l cannot be equal to 3.

1  1 1  (b) For a particular value of l , ml  l to l including zero.
formula :  R  2  2  , R  Rydberg constant
  n 2 
 n1  For l  1, ml cannot be 2 which is greater than l .
Therefore, wavelength will be highest in Balmer series
1 1
(n1 = 2) when n2 is 3. (d) ms   ,   ms cannot be equal to zero.
2 2
39. For H-like particles,
(e) ml cannot be greater than l.
21.78  1019 21.78 1019
En  Z2 J   (2)2 48. Subshells with n  l  4 are 3p and 4s.
n2 12
 8.712  1018 J Value of n Value of l Value of n+l Type of orbitals

40. Ionisation potential of hydrogen = 13.6 eV
3 1 3+1 3p,
 E1  13.6eV
E1 13.6 4 0 4+0 4s,
and E n     3.4eV
2 4
Hence, 3.4 eV energy is required to remove an electron Hence, maximum no. of electrons having same spin will be 4.
from n = 2 state of hydrogen atom.
Species Be 2 H Li  Na  Mg 2
1 49.
Kinetic energy  mv  m  mass, v  velocity 
2
41. No. of electrons 2 0 2 10 10
2
1 50. Isotones have the same number of neutrons.
or, 0.5   1 v 2 or, v  1 m s 1
2 As  77  33  44; Se  78  34  44
51. The total number of nucleons is termed as mass number (A) of
h
de Broglie wavelength,   the atom.
mv
Hence, Mass number (A) = No. of protons (p) + No. of neutrons
6.626  10 24 (n)
or,    6.626  1034 m
1kg  1 m s 1
42. Ti (22) : ls2 2s2 2p6 3s2 3p6 4s2 3d2 S. No. Species No. of electrons
 Order of increasing energy is 3s, 3p, 4s, 3d. i  NH 3 10
43. For a given value of n, l = 0 to n - 1;  ii  CH 3 8
For a given value of l, m = -l to + l including zero; 53.  iii  NH 2 10
1 1 NH 4
For a given value of m =  ,   iv  10
2 2
 When n = 5, then l = 0, 1, 2, 3, 4; Hence, the isoelectronic species are (i), (iii) and (iv).
when l = 2, then m = -2, 1, 0, + 1, + 2
The value of s can be 1 / 2 Particles Symbol Relative charge
Hence, the arrangement, n = 5, l = 2, m = 2, s = + 1/2 is Electrons e 1
possible for an electron. 54. Pr otons p 1
44. For a given shell, l, Neutrons n 0
the number of subshells, ml = (2l + 1)
Since, each subshell can accommodate 2 electrons of 55. (d)
opposite spin, so maximum number of electrons in a subshell
hc 
= 2 (2l + 1) = 4l + 2. 56. E Given,   45nm  45  109 m 
  
45. The angular momentum of an electron in an orbital is given by
On putting the given values in the equation, we get
h
μ l = l l+1
2π 6.63  1034  3  108
h h
E 9
 4.42  1018 J
For d-orbital, l  2 2  2 21  6 45  10
2 2
57. Planck gave the name ‘quantum’.
46. n = 3, l = 0 represents 3s-orbital.
58. Energy of a photon, E  h
n  3, l  1 represents 3 p  orbital.
n  3, l  2 represents 3d  orbital. weber, h  6.626  1034 Js,   5  1014 s 1  or Hz 
32
E  6.626  1034 Js  5  1014 s 1  3.313  1019 J Then, number of neutrons present  x  11.1% of x
 Energy of 1 mole of photons  x  0.111x  1.111x
 3.313  1019 J  6.022  1023 mol 1  199.51 kJ mol 1 Number of electrons in the neutral atom   x  1 (when an ion
59. Balmer series was discovered during the year 1885 whereas Lyman carries a negative charge, it carries an extra electron).
series was discovered in 1906. Balmer series lies in the visible  Number of protons in the neutral atom = x – 1
region whereas Lyman series in the UV zone. Given, Mass number of the ion = 37
h 1   x  1  1.111x  37  2.111x  38  x  18
60. Using de Broglie’s equation,   ;   37 
The symbol of the ion is 17 X .
mv mv
 2 3 
 D  mv  Species 19 K 20 Ca 21Sc 17 Cl
 71.
   mv  D No. of electrons 18 18 18 18
On putting the values in equation (i), we get hcN A
72. We know that, E 
 D 4 1 
  0.4
 2  5 6.62  1027  3  1010  6.02  10 23

61. Mass (m) = 100 g; velocity (v) = 100 cm s–1 
According to de Broglie’s equation, 1.1955  108 1.196  108
  ergs mol1
 
h 6.626  1027
   6.6  1031 cm 73. The electron is more tightly bound in the smallest allowed ordit.
mv 100  100 74. The energy of an electron in the nth orbit of
62. Only one orbital, 3p, has following set of quantum numbers,
22me 4
n  3, l  1 and ml  0 . hydrogen is given by E n 
n 2h 2
2
63. By using the relation, no. of orbitals  n
 particle vparticle
2
  3  9 75. Given :  1.8  104 and 3
 electron velectron
64. For a given shell, ,
h
According to de Broglie equation,  
the number of subshells, m   2  1 mv
Since, each subshell can accommodate 2 electrons of opposite
 particle h m v
spin, so maximum number of electrons in a subshell   electron electron
 electron m particle  v particle h
 2  2  1  4  2.
65. m electron velectron
Atoms/ At. No. of Electronic No. of unpaired  
m particle v particle
ions no. electrons configuration electrons
Na  11 10 1s 2 2 s 2 2 p 6 0 9.1  1031 kg 1
 1.8  104  
m particle 3
F 9 9 1s 2 2 s 2 2 p 5 1
2 2 3
N 7 7 1s 2 s 2 p 3 9.1  1031
m particle   1.6852 1027 kg
O 2 8 10 1s 2 2 s 2 2 p 6 0 1.8  104  3
B 5 5 1s 2 2 s 2 2 p1 1 Actual mass of neutron is 1.67493  1027 kg.
Hence, the particle is neutron.
66. 1H  1s1; 3 Li  2s1; 11Na  3s1; 19 K   Ar  4 s1; h
77. From de Broglie equation,  
mv
24 Cr   Ar  3d 4 s
5 1
29Cu   Ar  3d 4 s
10 1
6.6  1034
67. No. of nodes for any orbital  n  l  1   7.25  1010 m
9.1 1031  106
For 3s-orbital, n = 3 and l = 0
78. The orbital associated with n  3, l  1 is 3p.
69. Cu  29  :1s 2 2s 2 2 p 6 3s 2 3 p 6 3d 10 4 s1 (using Aufbau principle and
One orbital (with m  1 ) of 3p-subshell can accommodate
Hund’s rule of maximum multiplicity.)
maximum 2 electrons.
Ne 10  :1s 2 2 s 2 2 p 6 79. For 3p-orbital, number of radial nodes
 n  l 1  3 1 1  3  2  1
So, Cu  29  :  Ne 3s 2 3 p 6 3d 10 4 s1
Number of angular nodes  l  1
70. Let the number of electrons in the ion carrying a negative charge
be x. Number of radial and angular nodes depends on both n and l.
33
80. If n  1, l can have only one value i.e. l  0. (ii) the splitting of lines in magnetic and electric field.
Hence, this set of quantum numbers is not permitted since the 97. The de Broglie wavelength () of a particle is inversely
value of l cannot he equal to n. proportional to its momentum (p).
81. Orbital No. of electrons 1
i.e.,  
p
n  2, l  1, s  1 / 2 2 p3 3
98. Heisenberg uncertainty principle :
82. According to uncertainty principle, it is impossible to measure h h
simultaneously the position and momentum of an electron with x.p  or x.mv 
4 4
absolute accuracy.
h
83. According to Aufbau principle, in the ground state of the atoms, x.v 
the orbitals are filled in order of their increasing energies. 4m
86. Number of electrons in each species are given below: Momentum = mass × velocity
velocity
N 2  14,CN   14,O2  17,C22  14, NO   14,O22  18  mass   time  force  time
time
CO  14, NO  15 Momentum × distance = force × distance × time = energy × time
h
p.x  E.t  E.t 
It is quite evident from the above that NO ,C22 ,CN  , N 2 and 4
CO are isoelectronic in nature. 99. l  3 and n  4 represents 4f orbital. So, total number of electrons
87. Li and Be+ have same number of electrons. in a subshell  2  2l  1  2  2  3  1  14 electrons. Hence, f-
88.  
CO, NO and CN have 14 electrons while O2 has 16 electrons. subshell can accommodate maximum 14 electrons.
89. Atoms of different elements having same number of neutrons are
100. Rb  Z  37  :  Kr  5s1
called isotones.
90. Following the conservation of energy principle, n  5, l  0, m  0, s  1 / 2
101. Orbital angular momentum
1 2
Kinetic energy  me    h    0  h
2   l  l  1 (  for p-electrons; l  1 )
2
  6.626  1034 Js 1 1014 s 1  5  1013 s 1 
h 2h h
 l 1  l 
 
 6.626  1034 J s  5  1013 s 1   3.313  1020 J 
2 2 

2
nh 102. Exactly half-filled electronic configuration is more stable because
91. mvr  which represents angular momentum of greater symmetry and greater exchange energy.
2
92. Bohr model does not explain the spectra of multi- electron atoms. 104. Value of l  0.....  n  1
93. All species like He+, Li2+, Be3+ having one
l cannot be equal to n.
eletron are expected to have similar spectrum as that of hydrogen.
105. E.C. of Na (Z = 11): 1s 2 2 s 2 2 p 6 3s1
n2
94. We know that, rn  0.529  Å Outermost electron occupies 3s orbital.
Z
1
(1) 2  n  3, l  0, m  0, s  2
For second orbit, r1  0.529 
Z
106. 3f is impossible since for n  3
(2) 2
For second orbit, r2  0.529 
Z possible values of l  0 to  n  1 i.e., l  0,1, 2
2 So, only 3s ,3 p and 3d are possible for n  3.
2  0.529 
Area of first orbit  r1     108. We know that
 Z 
2 1 1 
2  0.529  4  E   2  2  , where n  n
Area ofsecond orbit  r2     2 1
 Z   n1 n 2 
Ratio of area of second orbit to first orbit = 16 : 1  n  6 to n  5 will give least energetic photon.
Z2 109. Series : Lyman, Balmar, Paschen, Brackett, Pfund
95. E n  13.6 eV,(E1) H  13.6eV
n2 Increa sin g wavelength


Z2 22
 E1 He   13.6 2  13.6   54.4eV 1312 2.18  1018
n 1
110. E   2
kJ / mol or  J / atom
The second I.E.  E   (E1 He  0  (54.4)eV  54.4eV
) n n2
96. Bohr model of hydrogen atom could not explain: where n is number of energy shell.
(i) de Broglie concept of dual nature of matter and Heisenberg’s For 1st orbit of hydrogen atom, n = 1
uncertainty principle. Hence, E  2.18  1018 J atom 1
34
 1 n1  1,n 2  2
1  1 
111.  v  R H Z2  2  2 
 n 
 1 n2  1 1 1  1 3 2
 Z2 R H      R H Z .   2
1
 1 4   4 Z
1   1 1 
 vHe   R H  22  2  2  Hence element having high atomic number will produce
 He 2 4  shortest wavelength.
122. (a) It successfully explained the stability of atoms.
1 1  1
 RH  2  2   for n 2  2 to n1  1 (b) It is not in agreement with Heisenberg uncertainty principle.
1 2  H (c) It does not explain the spectra of multi-electron atoms.
112. (1) Beyond a certain wavelength the line spectrum becomes (d) It does not explaing de Broglie concept of the dual character
band spectrum. of matter.
(2) For Balmer series n1  2 h
123.  
(4) The line of longest wavelength in this series, n 2 = 3 mv
10
13.6 13.6 h  6.626  1034 Js, m   0.01 kg, v  10 ms 1
113. E n  2
Z2 ; E1   4  54.4eV 1000
n 12 Putting the values,
Ionisation potential  E   E1  0   54.4  eV  54.4eV 6.626  1034
  6.626  1023 m
114. rn  0.529 n 2 / Z 0.01  10
h
rn  n 2 / Z 124.  
mv
Z2 m
120
 0.12 kg, v  44.7 m s 1
115. E n  E1  2 1000
n
E1= energy of hydrogen in first orbit 6.626 1034 Js
  1.2 1034 m  1.2  1032 cm
n = 2, Z = atomic number 0.12kg  44.7 ms 1
E  13.6 
 32  30.6 eV 125. v  106 cm / s  104 m / s
 2 2 h 6.6  1034
   0.72  107 m  7.2  10 8 m
116. 
Na and Ne both contain ten electrons so these are isoelectronic. mv 9.1 1031  104
126. Total number of atomic orbitals in any energy level is given by
Na  Z  11 :1s 2 , 2s 2 ,2p6 ,3s1
n2  42  16.  n  4 
Na  :1s 2 , 2s 2 , 2p 6 ,3s 0
127. Energy of orbitals increases in the order :
Ne  Z  10  :1s 2 , 2s 2 ,2p6 6 s, 4 f , 4 d ,6 p
117. 39  40  2 2 6 2 6 5 1
K and K contains same number of electrons so they are 128. Cr  1s 2 s 2 p 3s 3 p 3d 4 s
isoelectronic. They have same atomic number but different mass th
19 electron enters 4s because it is filled earlier than 3d.
numbers so they are also isotopes.
1 1
For 4s , n  4, l  0, m  0, s   or -
hc hc E1 hc  2  2 2 2
118. E1   and E 2   ; E    hc  
1 2 2 1 1 129. (1) n  4, l  1  4 p
25  2 1 2 (2) n  4, l  0  4 s
or  or   1  2 2
50 1 2 1 (3) n  3, l  2  3d
119. Splitting of spectral lines in electric field is called Stark effect. (4) n  3, l  1  3 p
Zeeman‘s effect is splitting of spectral lines in magnetic field.
Increasing order of energy is 3 p  4 s  3d  4 p
120. The energies of two photons are in the ratio 3 : 2, their
wavelengths will be in the ratio of 2 : 3, because  4    2    3  1
1 Alternatively,
E (according to Planck’s quantum theory)
 for (1) n  l  5; n  4
E1  2 (2) n  l  4; n  4
 
E 2 1 (3) n  l  5; n  3
So, 1 :  2  2 : 3 (4) n  l  4; n  3
Lower n  l means less energy and if for two subshells n  l is
1 1 1  same then lower n, lower will be the energy.
121.  Z2R H  2  2 
  n1 n 2  Thus correct order is  4    2    3  1 .
35
130. The orbital with highest  n  l  value will have the highest energy.. 142. Dual nature of matter was proposed by Louis de Broglie in
1924.
In the given sets, set with n  3, l  2, m  2, s  1 / 2 has
143. Cu  :1s 2 2 s 2 2 p 6 3s 2 3 p 6 3d 10
n  l  5 i.e., 3d orbital has the highest energy..
131. Principal quantum number tells the principal energy level or shell Shells occupied = 3, subshells occupied = 6,
to which the electron belongs or the average distance of the filled orbitals = 14 and unpaired e– = 0
electron from the nucleus. 144. For 2s orbital, the nodal surface (also called nodal point) exists at
Azimuthal quantum number tells, the shape of the various a distance of 2a0 from the nucleus.
subshells present within the same principal shell.
6
Magnetic quantum number determines the number of preferred 2s
5
orientations of the electrons present in a subshell. Spin quantum 4
number helps to explain the magnetic proporties of the 3
substances. 2 2a0
132. Pauli’s exclusion principle states that an orbital can have maximum 1
two electrons and these must have opposite spins.
133. The species is S2–.
r(Å)
No. of electrons = 16 + 2 = 18
146. Electronic configuration of Cu
No. of protons = 16
2
No. of neutrons = 16 29Cu 1s 2s2 2 p6 3s2 3 p6 3d10 4s1
134. The kinetic energy of photoelectrons increases linearly Outermost electron is in 4s sub-shell
with the frequency of the incident light used. For 4 s; n  4, l  0, m  0, s  1 / 2 or  1/2.
135. All single electron species show similar line spectrar.
147. For n  2, l can be 0 and 1.
Thus, the line spectra of H, He+,Li2+, atc. will be similar.
136. According to Rydberg’s formula, For l  0.m  0 and for l  1, m  1,0, 1.
Z2 149. Energy level order is (b) > (d) > (c) > (a),
1 1  8
  R  2  2  If   R i.e., 4d  5s  4 p  3d .
 n1 n 2  9 150. The px-orbital lies along the x-axis and the probability of finding
then n1 should be equal to 1 and n2 should be equal to 3 electron is zero in the yz-plane.
1 1  9 1 8
i.e.,   R  2  2  (1) 2  R 
1 3 
 R
 9  9
JEE main (AIEEE)
137. Number of lines in the spectrum will be equal to 1. As we know,
 n 2  n1  n 2  n1  1  1 1 
2 v  R H  2  2  Z2  where, Z  1
n 
 2 n1 
Here, n 2  4,n1  1
After putting the values, we get
N
 4  1 4  1  1  3  4  6
 1 1 
2 2 v  R H  2  2 
138. Number of emission lines in the spectrum will be equal to n 8 
 n 2  n1  n 2  n1  1 v
RH RH

where n2 = 5 and n1  1. 
2 64 n 2

 5  1 5  1  1  20  10 lines Comparing to y = mx + c,we get
.
2 2
h x = and m = - RH (slope)
140. According to de Broglie equation,  
mv 2. Hydrogen has three isotopes:
Given, h  6.6  1034 Js, m  0.66kg, v  100 ms 1 Protium (1H1), deuterium (1H2) and tritium (1H3).
6.6  1034 3. v  E
 =  1  1035 m
0.66  100 For H-atom
h 1 1 
141. x   4  mv  v  R 2  2
 n1 n 2 
For Lyman series,
6.626  1034
x   1
 4  3.14 1050  0.9  
1  1000  v  max   13.6 1  
   
 3600  1 
 1
x  2  1037 m v  min   13.6  1  
 4
36
1 10. (a) 4p (b) 4s (c) 3d (d) 3p

 vmax  vmin  13.6  
4
According to bohr Bury’s  n   
For Balmer series,
rule, increasing order of energy (D) < (B) < (C) < (A).
1 1 
v  max   13.6    Note : If the two orbitals have same value of  n    then the
4 
orbital with lower value of n will be filled first.
1 1
v  min   13.6    11. Energy of absorbed photon = Sum of the energies of emitted
4 9
photon
1
 vmax  vmin  13.6  
9 hc hc hc 1 1 1
  or  
 1  2  1  2
vLyman 9

vBalmer 4 1 1 1
 
4. Radjus of nth Bohr orbit in H-atom 355  109 680  109 2
 0.53n 2Å 1 1 1
   1.346  106
Radius of 2nd Bohr orbit = 0.53×(2)2  2 355  109 680  109
= 2.12 Å
or  2  1/ 1.346 106  743 109 m  743nm
5. Isoelectronic species have same no. of electrons.
12. Energy required to break one mole of Cl - Cl bonds in Cl 2
ions O 2 F Na  Mg 2
8  2 9  1 11  1 12  2 242  103 hc 6.626  1034  3  108

  
6.023 1023  

No. of e  10 10 10 10
Therefore O 2 ,F  , Na  ,Mg 2 are isoelectronic 6.626  106  3  108  6.023  1023

 
242  108
6. As electron of charge ‘e’ is passed through ‘V’ volt, kinetic energy
of electron will be eV
 0.4947  106 m  494.7nm
h
Wavelength of electron wave     Z2
2m.K.E 13. I.E   13.6eV ...(i)
n2
h h
   2meV
2meV  I1 Z12 n 22
or   ...(ii)
13.6Z2 I2 n12 Z22
7. Total energy  eV
n2
where n = 2, 3, 4 ... Given I1  19.6 1018 , Z1  2,n1  1, Z2  3 and n 2  1
Putting n = 2 Substituting these values in equation (ii).

13.6
Er   3.4eV 19.6  1018 4 1
4   
I2 1 9
8. The electronic configuration of Rubidium (Rb = 37) is
1s 2 2s 2 2p 6 3s 2 3p6 3d10 4s 2 4p6 5s1 18 9

 4.41 1017 J / atom
or I 2  19.6  10 
Since last electron enters in 5s orbital 4
1 6.63  1034
Hence n  5,   0, m  0,s   
h

2 14.
mv 1.67  1027  1 103
 1 1  hc
9. E  2.178 1018  2  2  
1 2    3.97  1010 meter  0.397 nanometer
15. According to Heisenberg uncertainly principle.
18 3 hc 6.62  1034  3  108
2.17  10    h h
4   x.mv  , x 
4 4mv
6.62  1034 3  108  4
  1.214 107 m
2.17  1018 3 600  0.005
Here v   0.03
100
37
6.6 1034 6.62  1034

So, x  31 x   1.92  102 m
4  3.14  9.110  0.03 4  3.14  0.003  9.11031
 1.92  103 meter
21. (a) N 3  7  3  10e  , O   8  2  10e 
16. Species having same number of electrons are isoelectronic
calculating the number of electrons in each species given here, we F  9  1  10e  ,S  16  2  18e 
get.
(not iso electronic)
CN   6  7  1  14  ; N 2  7  7  14  ;
(b) Li   3  1  4e  , Na   11  1  10e  ,
O 22  8  8  2  18  ;C 22  6  6  2  14  ;
Mg   12  2  10e 
O 2  8  8  1  17  ; NO  7  8  1  14 
CO  6  8  14  ; NO  7  8  15  Ca   20  2  18e   not iso electronic 
From the above calculation we find the all the species listed in (c) K   19  1  18e  , C   17  1  18e  ,
choice (b) have 14 electrons each so it is the correct answer.
Ca   20  2  18e,Sc3  21  3  18e 
17.  E  , The energy required to excite an electron in an atom of (isoelectronic)
hydrogen from n = 1 to n = 2 is E (difference in energy E2 and (d) Ba  56  2  54e,Sr  38  2  36e 
E1)
Values of E2 and E1 are, K   9  1  18e  ,Ca   20  2  18e 
E1  1.312 106 J mol1 (not isoelectronic)

2 22. The energy of an orbital is given by (n + ) in (d) and
1.312  106  1
E2   -3.28  105 J mol 1 (c). (n + ) value is (3 + 2) = 5 hence they will have same
 2 2 energy, since there n values are also same.
E is given by the relation, 23. Calculating number of electrons
 E  E 2  E1   3.28  105    1.312  106  J mol1 BO33  5  8  3  3  32 

    

1. CO32  6  8  3  2  32  iso-electronic species

 3.28  105  1.312  106 J mol1 NO3  7  8  3  1  32 


 9.84  105 J mol1 SO32  16  8  3  2  42 
Thus the correct answer is (d) 

2. CO32  32  not-iso-electronic species
18. (a) n  3,   0 means 3s-orbital and n + 1 = 3  
NO3  32 
(b) n  3,   1 means 3p-orbital n + 1 = 4
(c) n  3,   2 means 3d-orbital n + 1 = 5 CN 2  6  7  1  14 


(d) n  4,   0 means 4s-orbital n + 1 = 4 N 2  7  2  14  iso  electronic species
3. 
2
Increasing order of energy among these orbitals is C 2  6  2  2  14 
3s < 3p < 4s < 3d
PO34  15  8  4  3  50 
 3d has highest enerhy.. 

SO 24   16  4  8  2  50  iso  electronic species
19. Angular momentum of an electron in nth orbital is given by, 4. 
ClO 4  17  8  4  1  50 
nh 
mvr 
2 Hence the species in option (b) are not isoelectronic.
For n = 5, we have 24. The possible quantum numbers for 4f electron are
5h 2.5h
Angular momentum of electron   1
n  4,   3, m  3, 2  1,0,1, 2,3and s  
2 
2
20. Given m  9.1  10 31kg ,h  6.6  10 34 Js Of various possiblities only option (a) is possible.
25. Electronic configuration of Cr atom (z = 24)
300  .001
v   0.003ms 1  1s 2 , 2s 2 2p6 ,3s 2 3p 6 3d 5 , 4s1
100
From Heisenberg’s uncertainity principle when   1, p -subshell,
38
Numbers of electrons = 12
1000
when   2, p -subshell, source per second   100J
10
Numbers of electrons = 5
hc
26. TIPS/Formulae : Energy required to eject electron 

1  1 1  6.626  1034
 R 2  2 
    3  108
  n1 n 2  400  109
Number of electrons ejected
1 1 1  100
 1.097 107     1.097 107 
 1   6.626  1034  3  108
400  109
  91.15 10 9 m  9ln m
400  1071026
27. 19K  , 20 Ca 2 ,21 Sc3 ,17 Cl   2.01 1020
6.626  3
each contains 18 electrons. 4. D-broglie-wave length of electron:
 e is accelerated 
28. Fe++ (26 -2 = 24) = 1s2 2 s2 2p6 3s2 3p6 4s0 3d6 hence on.  
h
of d electrons retained is 6. e   from rest 
2m  KE   
[Two 4s electron are removed]   KE  q  V 
29. TIPS/Formulae:
h
For s-slectron,   0 
2mqV
h
 Orbital angular momentum  0  0  1 2  0
6.63  1034

30. N , F- and Na contain 10 electrons each.
3- +
2  16  1019  9.1 1031  40  103
31. The lines falling in the visible region comprise Balmer
 0.614  1011 m  6.14  1012 m
series. Hence the third line from red would be n1 = 2,
OR
n 2  5i.e.5  2.
12.3
 Å
h 6.6  10 34 V
32.    1033 m
mv 60 103 10

12.3
200
 6.15  1012 m 1Å  1010 m 
33. 2 excited state will be the 3 energy level.
nd rd
5. Among the isotopes of hydrogen, only tritium is radioactive and

13.6 13.6 emits low energy   particles.
E n  2 eV or E  eV  1.51eV.
n 9
hc 6.63  1034  3  108
34. TIPS/Formulae : 6. E  J  3  1019 J / atom
 663  109
h h Ionisation energy per mol
x.p  ; or x.m. v 
4 4
 3  1019  103  6.02  1023
34
6.62 10
 v  5
 2.11028 ms1  180.6 kJ mol1  181
4  3.14  0.025 10
7. According to Bohr’s theory :
JEE main (Online)  Z 2e 4 m Z2
(A) K.E.   KE 
1. Total energy per sec. = 50 J 802 n 2 h 2 n2
nhc nh
 E  nhv  (B) Speed of electron, v 
 2mr
Z2e 4 m
n  6.63  1034  3  108 (C) E  hv  E  
50  8 02 n 2 h 2
795  109
n ~ 2  1020 Z2
v  .
2. As in Thomson model, protons are diffused (charged is not n2
centered)   particles deviate by small angles and due to
Ze 2 0 n 2 h 2
repulsion from protons, their speed decreases. (D) F  where r 
4 0 r 2 me 2 Z
3. Total energy provided by
39
Z3e6 m 2  Z3 1
 F  F .  11.271  10 20 J   9  1031  v 2
2
402 n 2 h 4 n 4
v  5  105 ms 1.
nh
8. mvr  13. Incident energy of photon = Work function of metal
2
+ K.E. of photoelectron
1
K.E.  mv 2 hv  hv0  KE ...(i)
2
Incident energy of photon
n 2h 2
K.E.  hc 6.63 1034  3 108
2
8 mr 2   eV  5eV
 248  109  1.6  1019
For n  2,r  4a 0 Now using equation (i),
5  3  K.E.
4h 2  4  h2
 2
 2  K.E.  2.0eV
82m  4a 0   8  16  ma 02
h
Comparing with given value For de-broglie wavelength   ;
mv
 4  1
 2  1 2KE
 8  16  x KE  mv 2 so v 
2 m
 x  315.507
Then,
 10x  3155 (nearest integer)
h
9. According to Bohr’s model 
2m K.E.
z
v 6.63  1034
n 
z = Atomic no. (corresponds to +ve charge) 2  9.1 1031  2  1.6  1019
n = Principle quantum no.
 8.68  1010 m  9Å
This relation suggest that when the z increases, the velocity will
14. According to Heisenberg uncertainty principle,
also increase, so statement I is wrong and as ‘n’ decreases, velocity
will also increase. So statement II is correct. h
xp 
4
10. Power of infrared range  1mW  103 W or 103Js 1
 In 0.1 second the energy emited = 10 J
–4 h
x   p  mV 
c 4mV
 E  nhv  nh 
5
hc V  90   4.5 m/s
then; 10–4  n  100

n  6.63  1034  3  108 6.63  1034 Js  kgm 2 
 104  x  3 1J  2 
1000  109 4  3.14 10  10 kg  4.5 m/s  s 
 n  5.02  1014  50.2  1013  1.173  1033 m

 50 (nearest integer)  1  1033 m
11. Einstein equation E    K.E max
h
15. 
1 2mqV
12. hv  hv0  mv 2
2
 Li mp  e V
hc 1  m Li  8.3 m p
  hv 0  mv 2 P m Li  3e  V 
 2
6.63  1034  3  108  Li 1 1

    0.2  2  101
500  10 9 P 8.3  3 5
1 16. Zn   1s 2 2s 2 3p 6 3s 2 3p 6 3d10 4s1.

 6.63  1034  4.3  1014  mv 2
2 Outermost electron is in 4s subshell, so m = 0
6.63  30  10 20 1
17. Ga  :1s 2 2s 2 2p 6 3s 2 3p 6 3d10 4s 2
  6.63  4.3  1020  mv 2 The azimuthal quantum number for the valence electrons (4s-
5 2
subshell) of Ga+ ion is zero (0).
40
25. In the Balmer series of H-atom the transition takes place from
18. Angular nodes Radial nodes the higher oribtal to n = 2. Therefore the longest wave length
Orbit
   n    1 corresponds to n1 = 2 and n2 = 3. As the wave length decreases,
2p  1 2 1 1  0 the lines in the series converges. Hence, statement I, II, III are
3p  1 3 1 1  1 the correct statement among the given options.
3s 0 3  0 1  2 a 0n 2
26. r
2s 0 2  0 1  1 Z
2
a  2 4a
3s orbital has no angular node two radial nodes. For Li 2 , r  0  0
3 3
19. Given : n = 4 and ml = - 3
27. (a), (b) and (c) are according to quantum theory but (d) is
Hence, l value must be 3.
statement of kinetic theory of gases.
 Number of radial nodes = n - ml - 1
=4-3-1=0 E
KE
20. Possible values of l = 0, 1, 2, 3, 4
If l = 0, m = 0 28.
 = 1, m = 1,0, 1 Metal (Work function = E 0)
  2,m  2, 1,0, 1  2 E  E 0   KE max

  3, m  3, 2, 1,0, 1  2  3 hc
 4.41  1019  KE

  4, m  4, 3, 2, 1,0, 1  2  3  4
6.63  1034  3  108
  4.41 1019  KE
5d, 5f and 5g-sub shell contains one-one orbital having (m = + 2). 300  109
21. Number of radial nodes = n -  -1 So,  KE max  6.63  10
19
 4.41 1019
Number ofangular nodes = 
 2.22  1019 J  222  1021 J
For 5d; n = 5,  = 2
29. 2r  n
5d or bital has two radial nodes and two angular nodes.
n 2a 0
r
n2 Z
22. r  0.529 Å
Z 42
2  a 0  4
For Li 2  , 1
4
  2  a 0
 rLi n 4   rLi n 3  0.529
2 2
3 
 4 2  32   R1

1
For He4,   8a 0
 rHe n 4   rHe n 3  0.529

 
2 
 4 2  32    R 2

30. 6s 4f 5d 6p
n   6  0 4  3 5  2 6 1
R1 2
    
R 2 3
6 7 7 7
23. In hydrogen spectrum maximum lines of Balmer series lies in
Thus, order of orbitals filled are
visible region.
6s  4f  5d  6p.
24. Shortest wvelength  Max. energy    1
31. Radial node = n -  - 1
For Lyman series of H atom,
1 2 1 
1s  0  2  0 
 R H 1   0 
1 1   
2s  1   0 2
1 1 2p  0   2  0 
  RH  RH 
3p  1  2  0 
1 1
For Balmer series of He+,
1 2 1 1 1 94
 R H  2  2  2    R H  4
2
 
Probability density  can be zero for 3p orbital other
 than in finite distance. It has one radial node.
 2 3    36 
Thus, statement (c) is correct.
1 5R H 9 9 32. Under the given situation for
    1
 9 5R H 5
n  1,   0,1, 2
41
n  2,   0,1,2,3   1
v  max   13.6 1  
n  3,   0,1,2,3,4  
According to (n + ) rule of order of filling of subshells will be :   1
v  min   13.6  1  
1s 1p 1d 2s 2p 3s 2d 3f  4
Atomic number 6 1s2 1p4    
1
 v max  v min  13.6  
Atomic number 9 1s2 1p6 1d1 4
Atomic number 8 1s2 1p6 For Balmer series,

V  max   13.6   
Atomic number 13 1s2 1p6 1d5 1 1
Therefore option (b) is correct. Atomic number of first noble gas 4 
will be 18 (1s2 1p6 1d10).  1 1
V  min   13.6   
33. For n = 4 possible values of  = 0, 1, 2, 3; only  = 2 and  4 9
 = 3 can have m = - 2. So possible subshells are 2.   1
34. The possible number of orbitals in a shell in term of  Vmax  Vman  13.6  
9
‘n’ is n2 
v Lyman 9
 n  5; n 2  25 So,  
vBalmer 4
35. As the value of Z (atomic number) increases, energy of orbitals 39. The total energy of the electron is minimum at a distance of a0
decreases (becomes more - ve value) from the nucleus for 1 s orbital.
 Order of energy of 2s orbital is H > Li > Na > K. 1  1 1 
hc 40.  R 2  2 
E  hv   n 
36.  1 n2 

n1  3,n 2  
6.626 1034  3108
E  4.97 1019 J
4000 1010 1 1 9 9
 R       5  9  105 cm  900 nm
 9 R 10
4.97  1019 J
  3.1eV 41. K.E. = ha – hv0
1.6  1010 J eV 1
where, v = Frequency of incident radiation
 
1 1 2 v0 = Threshold frequency
KE  mv 2   9  1031 kg  6  105 ms 1
2 2 KE is independent of intensity but it depends on frequency of
light. Intensity is directly proportional to the no. of electrons
 1.62  10 19 J 1J  kg.m 2s 2  emitted.
 
 1 eV 42. According to Bohr’s model energy in n th state
According to photoelectric effect, Z2
 13.6  eV
K.E.  hv  hv0 n2
For second excited state, of He+, n = 3
hv0  hv  K.E.
22
Work function (W0) = E - K.E.  
 E3 He  13.6 
32
eV  6.04eV
 3.1  1  2.1 eV
43. As we know,
37. For determined shortest wavelength, n 2  
 1 1 
 1 v  R H  2  2  Z2  where, Z=1
 1 1  n
 2 n1 

Lyman series v L  R 2  2
L  1   After putting the values, we get

 1 1 
 1  1 1  v  R H  2  2 
Paschen series v P  R 2  2 n 8 
P   3  

 RH RH
vL P  v 
  9 64 n 2
vP  L
 Comparing to y  mx  c, we get
38. v  E
For H-atom 1
x and m  R H  slope 
n2
 1 1
vR 2  2 44. In photoelectric effect,
 n1 n 2 
hc
For Lyman series,  w  KE of electron

42
Given that KE of ejected photoelectron is very high in comparison 49. Atomic numbers of N,O,F and Na are 7,8,9,and 11
to work function w. respectively. Therefore, total number of electrons in each
hc
 KE of N3-, O2-, F-, and Na+ are 10 and hence they are isoeletronic.

50. n
hc 1 2  m 
 mv   (I) n4 2 4d 6
 2 m
(II) n  3 2 3d 5
hc 1 m 2 v 2
 . (III) n  4  1 4p 5
 2 m
(IV) n  3  1 3p 4
hc p 2 The energy of an atomic orbital increases with increasing

 2m n  . For identical values of n  , energy increases with
New wavelength increasing value of n. Therefore the correct order of energy is:
2
hc 1.5P  4 3p < 3d < 4p < 4d
  1  
1 2m 9 IV II III I
45. Given   1.5a 0 , 51. Iso-electronic species differ in size due to different effective nuclear
n  2 r ....(i) charge.
Radii of stationary states (r) is expressed as : nh
52. (a) Anhular momentum (L) 
n2 2
r  a0 .....(ii)
z Therefore, as n imcreases, L also increases.
From eqn (i) and (ii) n2
(b) r
2a 0 n2
2a 0 n z
n  ;  h
z z (c) For n  1, L 
n 2
1.5a 0  2a 0 (d) As  increases, the peak of  vs r shifts towards
z
n 1.5 higher ‘r’ value.
  0.75
z 2
46. According to de-Broglie wavelength equation, 3s
h 1 Node 3d Node
    3p
mv v
According to photoelectric effect,
1 1 mv 2 0
hv  hv0  mv 2 ; v  v 0  
2 2 h
v  v0  v 2 5a0 10a0 15a0

r
1/2
v   v  v0 
53. When temperature is increased, black body emits high energy
1 radiation from higher wavelength to lower wavelength.
 
 v  v0 1/2 54.   250nm
47. Probability of finding an electron will have maximum hc 1240eV.nm
E   4.96eV
value at both ‘a’ and ‘c’. There is zero pr obability of finding an  250nm
electron at ‘b’. KE = stopping potential = 0.5 eV
48. The given probability density curve is for 2s orbital due to the E  W0  K.E.
presence of only one radial node. 1s and 2p 4.96  W0  0.5
orbital do not have any radial node and 3s orbital has two
W0  4.46  4.5eV
radial nodes. Hence, option (b) is correct.
55. First Bohr orbit of H atom has radius r = 0.529 Å
Also, the angular momentum is quantised.
2
 radial node mvr 
h
2
h
2r  
mv
r    2  0.529Å
43
56. For lyman series (shortest wavelength)

NCERT Exemplar
n1  1, n 2  
1. Rutherford’s a-particle scattering experiment could not tell
1  1 1  anything about arrangement of electrons in the atom.
 RZ2  2  2 
 n  2. The ground state electronic configuration will be
 1 n2 
1s 2 2 s 2 2 p 6 3s 2 3 p 6 3d 10 4 s1
1 1 1  1
  12 R      R 3. The probability density of electrons for 2s orbital first increases
A  1   A
then decreases and after that it begins to increase again.
Longest wavelength = 1st line 4. Nature of the gas in the cathode ray tube does not determine the
n1  3, n 2  4 characteristics of cathode rays. Their properties are independent
of the nature of the gas.
1  1 1  1 R7
 RZ2  2  2    5. The mass of electron is negligible as compared to the neutron.
 3 4   36 6. According to Thomson model of atom, the mass of the atom is
assumed to be uniformly distributed over the atom. This model
1
R was able to explain the overall neutrality of the atom.
A
7. Isobars are the elements having same atomic mass (sum of number
1 of protons and neutrons) but different atomic number (number
7
1 A 1 7 36A of protons).
   
 36  36A 7
8. Number of radial nodes = (n - l -1) = (3 - 1 - 1) = 1
9. Number of angular nodes = l = 2
n2
57. r  0.529  Å 10. According to Heisenberg’s uncertainty principle, the position
Z
and velocity of an electron cannot be determined simultaneously
r  211.6pm  2.11Å with accuracy which rules out the existence of fixed paths.
11. For third shell
n2
 0.529   2.11Å n = 3, l = 0,
Z
1,  2
n  2  Balmer series  m = 0 
1,0,1 2,1,0,1,2
58. Number of orbitals in a shell = n2 = (5)2 = 25. Total no. of orbitals = 1 + 3 + 5 = 9
3 12. l or azimuthal quantum number determines angular momentum of
59. Kinetic energy of any particle  kT
2 the orbital.
1 2 13. Average atomic mass of Cl can be calculated as
Also K.E.  mv
2 37  1  35  3
 35.5
1 3 3kT 4
mv 2  kT  v 2  which shows the ratio of 37
Cl and 35
Cl in 1 : 3.
2 2 m
3kT
14. Cr 3
 Z  24    Ar  3d 3
v
m Fe3  Z  26    Ar  3d 5
h h
de-broglie wavelength     Mn2  Z  25    Ar  3d 5
mv 3kT
m
m Co3  Z  27    Ar  3d 6
h 1 Sc3  Z  21   Ar  3d 0
 ; 
3kTm m
Fe3+ and Mn2+ will have same number of electrons i.e., 23 and
Mass of electron < mass of neutron hence, have same electronic configuration.
  electron     neutron  15. Paired electrons present in any orbital will have opposite spins
60. According to Aufbau principle, the sequence of filling according to Pauli’s exclusion principle.
h
electrons in sixth period is 16. de Broglie equation,  
m
6s  4f  5d  6pi.e,(ns)  (n  2)f  (n  l)d  np Since, alpha particles have the largest mass, they have shortest
wavelength.
44

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Structure of Atom

3. JEE main (AIEEE) 15 – 17

4. JEE main (Online) 17 – 22

6. Hints & Solution 27 – 44

(c ) 6h (d) 2h (b) n  3,   2,m  3,s  1/ 2

by the expression (1989) (a) 1 (b) 10

1s2 3p 3d (a) d z 2,d xz (b) d xz d yz

29. The electronic configurations of Eu (Atomic No. 63), Gd

(i) NH3 (ii) CH3+ (c ) 6.6 1031 c m (d) 6.6  1032 c m

(c) 37 (d) 37  (mass of e   9.11031 kg,h=6.6×10-34 kgm 2 /s)

(d) n  3, l  1, ml  0, ms   (c) He and H (d) Be+ and H

94. Ratio of area of second orbit to first orbit in an atom

are integers. Which of the following statements is (are) (c) 1 : 2 (d) 3 : 2

3. The ionization energy of hydrogen can be calculated (c) H (d) H+

9. Energy of an electron is given by E = (a) 0.40 nm (b) 2.5 nm

 h  6.626 1034 Js  (2021)

23. The region in the electromagnetic spectrum where the

(c) Infrared (d) Ultravioket

(Mas of electron  9  1031 kg 0 Energy of light

 1  (a) in the region a an c (b) in the region a and b

(a) Cr3 , Fe3 (b) Fe3 , Mn 2

Answers Structure of Atom

37. (a) 38. (b) 39. (d) 40. (a)

Hints & Solution Structure of Atom

Putting the value of r,   211.6 pm hc

24. In an atom, for any value of n, the values of l  0 to  n  1 . 2 h

subshell  2  2l  1  2  2  3  1  14 electrons. Hence, 1 1018

35. From Heisenberg uncertainty principle, c 3  108

Other Medical On putting Z = 3 and n = 2,

but different mass numbers e.g., protium  11H  and tritium  13 H . 1  1 1 

A  A4  A4  A4 36. Let the monoatomic anion be X– .

 8.712  1018 J Value of n Value of l Value of n+l Type of orbitals

1 10. (a) 4p (b) 4s (c) 3d (d) 3p

8  2 9  1 11  1 12  2 242  103 hc 6.626  1034  3  108

Therefore O 2 ,F  , Na  ,Mg 2 are isoelectronic 6.626  106  3  108  6.023  1023

Putting n = 2 Substituting these values in equation (ii).

1s 2 2s 2 2p 6 3s 2 3p6 3d10 4s 2 4p6 5s1 18 9

6.6 1034 6.62  1034

E1  1.312 106 J mol1 (not isoelectronic)

 E  E 2  E1   3.28  105    1.312  106  J mol1 BO33  5  8  3  3  32 

(c) n  3,   2 means 3d-orbital n + 1 = 5 CN 2  6  7  1  14 

5. Among the isotopes of hydrogen, only tritium is radioactive and

 n  5.02  1014  50.2  1013  1.173  1033 m

6.63  1034  3  108  Li 1 1

1 16. Zn   1s 2 2s 2 3p 6 3s 2 3p 6 3d10 4s1.

  2,m  2, 1,0, 1  2 E  E 0   KE max

For He4,   8a 0

 rHe n 4   rHe n 3  0.529

v  v0  v 2 5a0 10a0 15a0

56. For lyman series (shortest wavelength)

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