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Arabian Journal
Arabian Journal
https://doi.org/10.1007/s13369-022-07349-5
Abstract
In this study, a variable compression ratio CI engine is tested to predict its performance and emission characteristics by varying
input criterions like engine load, CR, and fuel types. The brake thermal efficiency (BTE) is considered as the performance
characteristic and the emissions of carbon monoxide, hydrocarbon, nitrogen oxide, and smoke opacity are considered as the
emission characteristics for this study. The tests are conducted for variation in load from 4 to 12 kg and compression ratio
from 14 to 18 in the multi-fuel mode of operation with 0%, 50%, and 100% of Calophyllum Inophyllum biodiesel blend
and producer gas. The use of waste biomass like leaves, small tree branches, vegetable waste, and cow dung in producer gas
generation is attempted in this work toward better energy production and management of environmental waste. It has been
identified that load mostly influences the brake thermal efficiency, NOx emission, and opacity with a contribution of 58%,
67.5%, and 41.7%, respectively, whereas multi-fuel and compression ratio mostly affect CO emission and HC emission with
a contribution of 41.8% and 58.9%, respectively. The maximum BTE and minimum emissions of CO, HC, NOx, and opacity
are 15.49%, 0.525 ppm, 54.7 ppm, 125.032 ppm, and 37.99 HSU, respectively, are predicted as the optimum performance of
the test engine for composite desirability D of 0.910037. An economic study is conducted to determine the % relative cost
variation of the current sample fuel in comparison with diesel fuel. At optimum performance, the predicted fuel MF33.56
costing 10% more than MF0 has been observed.
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Experimental work is carried out on the CI engine fuelled and the exhaust gas temperature have been improved [9].
with biogas. Results indicate that carbon monoxide (CO) Using a mixture of Calophyllum Inophyllum biodiesel with
and hydrocarbon (HC) emissions increase linearly with TiO2 nanoadditions and exhaust gas recirculation, evaluate
the increase in biogas flow, while the opacity of smoking the performance and emission characteristics of a single-
decreases [1]. The CMFIS system is employed in the opti- cylinder diesel engine (EGR). When compared to B20 fuel,
mized 100C ATDC 600C duration SOI to use the METP and adding TiO2 nanoparticles to B20 fuel reduces CO and
hydrogen fuel mixture in the multiple injection method to HC emissions while increasing EGR [10]. Spray and mix
offer the dual-fuel engine with increased performance. Mul- the future generation of alternative fuels with hazelnut oil
tiple injections resulted in a homogeneous air–hydrogen mix- and diesel are investigated micro-emulsion process to make
ture, which improved the dual-fuel engines performance by diesel/n-butanol/hazelnut oil and diesel/1-pentanol/Hazelnut
increasing BTE and lowering smoke, HC, and CO emissions oil mixtures. EHN can lower NOx and HC emissions while
[2]. The addition of nanoparticles (metal, nonmetal, oxi- raising CO emissions when added to DPnH. NOx and HC
dized, organic, and fused) to emulsified diesel–biodiesel fuels emissions were reduced by 2.23% and 17.25%, respectively,
can improve engine performance, thermophysical properties, compared to DPnH, whereas CO emissions were increased
heat transfer coefficient, and fuel mix balance, and reduc- by 10.49% [11]. The BTE of a single-fuel operation is higher
tion in emissions was observed in [3]. An experiment was than that of a dual-fuel operation. CNG/HCNG can be used
conducted on the improved stability of the ethanol/jatropha to partially replace fossil fuels in the home. The levels of
biodiesel (JME) blend using N-butanol as the co-solvent. soot and NOx emissions from the dual-fuel operation were
The addition of ethanol can reduce BSFC compared to JME found to be lower than those from pure liquid fuel operation.
fuel, and the production of CO, UHC, and NOx was signif- Higher performance is provided by HCNG. HCNG allows
icantly reduced by 40%, 40%, and 40%, respectively, with the engine to run on a lean mixture, reducing HC and CO
the addition of ethanol [4]. Various biodiesel fuel additive emissions but increasing NOx emissions [12]. The effects of
blends have been developed, and their lubrication proper- anti-corrosion additives such as 8% and 16% (vol. %) palm
ties, as well as the impact of these mixtures on lubricating olein (PO) and ordinary diesel (DO) on engine performance,
oil contamination and the impact of ternary fuel mixtures on emission behavior, engine component wear, and lubrica-
properties, were investigated. The WSD of B30 fuel, which tion properties are studied. POD8A and POD16A mixes had
is a mixture of DMC fuel additive and TiO2 , is significantly greater brake-specific fuel consumption (BSFC) than ODF
reduced compared to the pure B30 fuel mixture as result by 1.8%t and 3.1%, respectively [13]. Experiments were con-
[5]. The effect of Nigella biodiesel (NSME25) mixed with ducted on a single-cylinder 4-stroke CI engine using Honge
diesel, n-butanol, and asymmetric graphene oxide nanopar- oil methyl ester and gas produced from biomass raw mate-
ticles on the improved CRDI engine is summarized. The rials. Operating a household gas producer (OW) under ideal
NSME25B10GO90 brake thermal efficiency (BTE) is close operating conditions and 80% load leads to an increase in
and compatible with diesel. The BTE change will increase BTE of 16.1% and 29.6% compared to operating household
the EGT of the diesel–nanofuel mixture, resulting in faster gas from the northwest and HW. Comparing OW with NW
fuel combustion [6]. The effects of VCR, a mixture of zinc and HW, HC and CO emissions were decreased by 7.4% and
oxide nanoparticles and soybean biodiesel, BTDC with an 16.1%, respectively, and CO emissions were decreased by
IT of 230 °C, and a single-cylinder engine were investigated. 19.1% and 26.1%, respectively [14]. The engine was tested
SBME25 biodiesel compared to the SBME25 fuel mixture in single- and dual-fuel modes with diesel, K10 (10% pure
increased BTE by 20.59% and decreased BSFC by 20.37% oil + 90% diesel), and K20 (20% pure oil + 80% diesel)
and emissions due to the improved catalytic activity of zinc and employed the best production gas flow. Under a steady
oxide nanoparticles [7]. The production of nanoadditives load of 10 kW, the engine was tested in dual-fuel mode with
for diesel and biodiesel fuels has been evaluated in detail. the same test fuel and varied gas flow rates [15]. The BSFC
Nanoparticles in liquid fuel can offer several benefits, includ- and BTE of CI engines using B10 and B20 were enhanced
ing improved performance and reduced emissions. They also when compared to diesel engines, according to the experi-
suggested that the study should focus on dose levels and the mental results reported. In the dual-fuel mode, however, the
long-term stability of nanoparticles and fuel mixtures [8]. HC and CO emissions of KOME blended fuel were lower
The feasibility of using palm kernel oil methyl ester (PME) than diesel. The NOx emissions of the three pilot fuels were
and various aluminum oxide nanoparticles (ANOP) to fuel reduced in the dual-fuel mode, but as the KOME mixing per-
a 4-stroke single-cylinder engine with direct injection and centage increased, the NOx emissions increased [16]. Pilot
compression ignition is being investigated. Both the heat quantity and injection timing have a substantial impact on
release rate and the cylinder pressure have increased signif- CNG/diesel dual-fuel engines investigated the emissions of
icantly, and the ignition delay has decreased significantly. dual-fuel CNG/diesel engines with various volumes of pilot
By installing AONP, the thermal efficiency of the brake fuel and adjusted pilot injection time. The unburned HC emis-
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sions from the dual-fuel natural gas engine were substantially examined. The performance and emission behavior of a vari-
greater than those from the diesel engine [17]. It was found able compression single-cylinder CI engine are investigated
that the SFC contained approximately 1 kg/kWh of biomass in multi-fuel mode related to variable load and compres-
and a 55 ml/kWh of diesel engine. This technology pack- sion ratio. Multiple objective optimizations are carried out
age emphasizes the feasibility and environmental benefits for maximum performance and minimum emissions from
of distributed generation. The use of biomass as fuel has the test engine using response surface methodology. An eco-
reduced the amount of fossil fuels used, resulting in a net nomic analysis is also carried out for the test engine based on
reduction in CO2 emissions [18]. The chicken fat biodiesel brake-specific fuel consumption BSFC in percentage relative
including synthetic magnesium additions in a single-cylinder to the recent cost of fuels available in the market. The follow-
direct injection diesel engine is used to see how it affected ing section introduces performance research, optimization,
engine performance and emissions. The results showed that and economic analysis.
adding 10% chicken fat biodiesel did not significantly mod-
ify engine torque, but the specific fuel consumption was
increased by 5.2% due to the low calorific value of biodiesel 2 Materials and Methods
[19]. The performance and exhaust emission characteristics
of a single-cylinder commercial DI diesel engine that was air- 2.1 Fuel Preparation Method
cooled and naturally aspirated. The goal of this project was to
identify performance parameters and study the possibilities 2.1.1 Calophyllum Inophyllum Oil
of lowering exhaust emissions. The performance parameters
were found to be comparable to the benchmark diesel oper- Calophyllum Inophyllum oil is used in the current research
ation [20]. The biodiesel of Mahua and Karanja does not work to prepare biofuel as the test fuel due to its abundant
corrode the metals of pistons and piston bushings, whereas availability, higher production rate, restriction on the use of
the biodiesel of Salvadora had a significant corrosive effect edible oil, and cheaper production process. It is commonly
on both metals due to its high sulfur content (1600 ppm), indi- called Bitaog in India. It is an evergreen tree. It is a non-
cating that this oil was not suitable for biodiesel production, edible oilseed from the Clusiacea family. It grows in the
especially when the Bharat III and Bharat IV standards were coastal areas of India. The fruit (cone) of the Calophyllum
implemented [21]. The CI engine runs on two fuels: turpen- Inophyllum tree is round with a diameter of 24 cm. In the
tine and diesel. With the exception of volumetric efficiency, mature stage, it contains about 71% unsaturated fatty acids
all other performance and emission metrics were found to be (oleic acid and linoleic acid). Polish trees bear fruit twice a
superior to diesel fuel at 75% load. The levels of dangerous year. A fully grown tree can provide about 100 kg of fruit,
chemicals such as CO and UBHC are slightly higher than which is equivalent to 18 kg of oil. The three-stage production
the diesel baseline (DBL). In DF mode, it produces about process of biodiesel from Calophyllum Inophyllum seeds is
40–45% less smoke [22]. Numerical work is carried out to pre-treatment, alkali-catalyzed transesterification, and post-
compare the effectiveness of blended fuels of diesel–ethanol, treatment.
diesel–biodiesel, and general diesel in high-speed DI diesel
engine. The result shows the lower value of ethanol blend 2.1.2 Extraction of the Calophyllum Inophyllum Oil
gives lower value of efficiency as well as a lower value of
CO2 and soot emission [23]. An investigation is done to know The Calophyllum Inophyllum seeds are separated from ripe
the performance and emission characteristics of nine differ- Calophyllum Inophyllum fruits. They are dried in open sun-
ent fuels (diesel, biodiesel–diesel blends, biodiesel–kerosene light for two days at an average temperature of 35 °C for
blend, etc.) in a DI diesel engine running at constant speed eliminating moisture from the seeds. The oil is mechanically
at different loading conditions. It is found that lower NOX extracted from the seeds using an electrically operated oil
levels were found in the case of CK30 compared to diesel press machine (screw type) with specifications mentioned in
[24]. Table 1. The extraction oil is then filtered by a filter with a
After referring to several research papers, it has been found mesh size of 5 microns. After filtering the oil color was dark
that the performance and emission study of CI engines in brown.
single- and dual-fuel modes with Calophyllum Inophyllum
oil biodiesel blend has been carried out; however, in multi- 2.1.3 Refinement of Calophyllum Inophyllum Oil
fuel mode with Calophyllum Inophyllum oil, diesel fuel, and
producer gas, the combination found in the literature is rare. The insoluble impurities have been mainly separated in the
The functional stability of the engine with specific combi- filtration process, but it is not an easy task to separate solu-
nation of Calophyllum Inophyllum oil and producer gas is ble impurities like natural wax, fatty acids, phosphatase, and
tested and its possibility replacing the diesel fuel in future is mucilaginous. In a chemical laboratory, 1250 ml of Calo-
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Table 1 Oil extraction press specification Table 2 Comparison between the properties of Calophyllum Inophyl-
lum oil and the diesel available in market
Sl. No Properties Value
Properties Calophyllum Inophyllum oil Diesel
1 Operating type Automatic
2 Mechanical Type Cold Press Density (kg/m3 ) 858 826
3 I/P voltage 220–240 Volt Viscosity at 40 °C 3.9 3.1
4 Motor power 0.25 HP Flash point 138 °C 48 °C
5 RPM 60 Cetane number 59 52
6 Capacity 3 kg/hr Heating value 41,300 MJ/kg 42,500 MJ/kg
7 Weight 13 kg
8 Size 20(length) × 8(width) × 10(height) inch
phyllum Inophyllum oil is put in a round-bottomed flask and 2.1.7 Generation of Producer Gas
was mixed with 1.25 ml of H3 PO4 . The mixture is stirred up
to 2 h continuously at a temperature of 60 °C. Then after set- Producer gas is generally produced by the gasification of
tling down the mixture, pure oil is collected from the upper solid/liquid fuels. Biomass gasification is one of the technolo-
layer. gies used to convert biomass into combustible gas mixtures,
called producer gas. Producer gas is the gas produced when
wood, charcoal, or coal is gasified with air and comprises
2.1.4 Esterification of Calophyllum Inophyllum Oil about 40% combustible gas, primarily carbon monoxide,
hydrogen, and some methane. The rest is nonflammable,
Esterification is a chemical process that results in forming a mainly composed of nitrogen, carbon dioxide, and water
product of ester. The process gives an ester and water. So, vapor. The gas also contains condensable tar, acid, and dust.
the process needs external heat to evaporate water evolved The main component of gasification is the gasifier, which
during the process. The refined Calophyllum Inophyllum oil is a chemical reactor in which many physical and chemical
is mixed along with 24 volume percentage of CH3 OH and 1 processes such as drying, heating, pyrolysis, partial oxida-
volume percentage of H2 SO4 as the catalyst. The mixture is tion, and final reduction occur. Gasifiers can be roughly
subjected to continuous stirring and heats up to 70 °C for the divided into three categories according to the direction of gas
removal of water particles and extra CH3 OH. flow: They are draft, downdraft, and cross airflow. Generating
the producer gas for this experiment, a downdraft gasifier as
shown in Fig. 1 is used with the specifications as mentioned
in Table 3. A fixed bed gasifier with a neck is known as
2.1.5 Transesterification of Calophyllum Inophyllum Oil a downdraft gasifier. Waste biomass like leaves, small tree
branches, vegetable waste, and cow dung was fed to the top
To make the Calophyllum Inophyllum oil into usable of the gasifier. The detailed properties of waste biomasses
biodiesel and lower its viscosity, the transesterification pro- are given in Table 4. A blower is fitted with the gasifier;
cess is used. Esterified 1250 ml of Calophyllum Inophyllum whose prime objective was to supply forcefully atmospheric
oil is put in a 2-L round-bottomed flask fitted with a sep- air into the gasifier. Before starting the blower, 200 ml of
aration valve at the bottom. The total unit is called the kerosene is sprinkled on the waste biomasses. It is easy to
transesterification unit. Then the oil was heated up to 70 °C, catch fire due to the presence of kerosene. At around 850 °C,
so that extra ester and KOH is removed from the oil. the hot producer gas is gathered at the bottom. The producer
gas is then transferred through a counterflow heat exchanger,
where it exchanged heat with normal water. The temperature
2.1.6 Characterization of Fuel Properties of the producing gas has to be lowered for at least 30 min.
After that, the gas is kept in a steel container. The ingredients
Before using the Calophyllum Inophyllum biodiesel in the CI of producer gas and calorific value of producer gas are mea-
engine, characterization is done for knowing the fuel prop- sured by biogas analyzer and bomb calorimeter, respectively.
erties like calorific value, viscosity, density, cetane number, The technical specification of the biogas analyzer and bomb
fire point, etc. Many types of ASTM methods are used to calorimeter are given in Tables 5 and 6. The properties of
determine the above-said properties. A comparison between producer gas available at the end of the cotton filter are given
Calophyllum Inophyllum oil and diesel is given in Table 2. in Table 7.
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Table 7 Properties of producer gas obtained from the gasifier Table 8 Specification of diesel engine
Properties Values Sl. No. Particulars Specification
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Multi-fuel mode I (MF0) [blend of 100% diesel fuel and Table 12 Uncertainty of measurement during experiment
0% Calophyllum Inophyllum + 50% Producer gas in air] Measurement particular Accuracy
The engine intake manifold was divided with two pas-
sages: one for atmospheric air and another for producer gas. Brake thermal efficiency ± 2.5%
The intake manifold was controlled by two regulating flow BSFC ± 2.9%
control valves. Diesel was used to start the engine. It is CO ± 0.001%
allowed to run for 15–20 min in order to reach a steady con- HC ± 1 ppm
dition. Then 50% of producer gas was introduced to the air NOX ± 1 ppm
line once the engine runs smoothly. Readings were taken Opacity ± 2 HSU
after reaching a steady state. Gradually sized tubes that were
installed in the fuel line to the engine were used to record fuel
consumption rates at various loads. Engine was only running
on diesel and 50% of producer gas in air during this time, not 2.3 Response Surface Methodology
Calophyllum Inophyllum oil. An emission recorder captured
data on exhaust emissions. An eddy brake dynamometer was The performance of CI engines has been enhanced through
used to record NOX , CO, CO2 , and N2 at various loads. the application of numerous techniques. A CI engine’s per-
Multi-fuel mode II (MF50) [Blend of 50% diesel fuel and formance is influenced by a number of variables, including
50% Calophyllum Inophyllum + 50% Producer gas in air] the load, compression ratio, injection pressure, temperature
Once the engine was running smoothly with diesel for of the cooling water, fuel type, and engine cylinder temper-
10–15 min, the blend of 50% diesel and 50% Calophyllum ature. Implementing the right optimization techniques can
Inophyllum oil was introduced in the cylinder after closing significantly improve the performance of the CI engine.
the flow line of diesel in running condition. It is allowed RSM is a potent optimization tool mostly used for model-
to run the engine for about 20 min to attain a steady state. ing and analyzing different engineering challenges. It is a set
The intake manifold of the engine was allowing both air and of mathematical and statistical techniques that can be applied
producer gas in equal percentage. Then follow the same pro- to any test design in which several input variables have the
cedure for recording the engine performance and emission potential to affect the performance measure or quality of the
characteristics. product or process.
Multi-fuel mode III (MF100) [Blend of 0% diesel fuel and RSM is essential in the creation, formulation, and testing
100% Calophyllum Inophyllum + 50% Producer gas in air] of new scientific research and products. It can also be used to
Initially the engine was started with diesel and allowed improve existing research and products. The most common
to run for 10–15 min. Then in running condition, flow line RSM applications are found in industrial science, biological
of diesel was cut off and 100% Calophyllum Inophyllum science, clinical science, social science, food science, phys-
oil was introduced in the engine. It is allowed to run the ical science, and engineering science.
engine for about 10 min to attain a steady state. After attaining The response surface methodology, RSM, technique is
a steady state, 50% producer gas was introduced with the mostly used for developing polynomial model using input
atmospheric air through intake manifold of the engine. After design data in order to find the optimal solution. The main
running smoothly, all required readings were recorded. purpose of RSM technique is to determine the optimized
results for multiple responses; specifically, it finds the best
2.2.3 Experimental Error Analysis compromise among the responses rather than optimizing
individual ones. Secondly, it investigates the impact of vari-
In experimental work, uncertainty or error analysis is very ous design parameters on output responses.
much essential for the prediction of precise results, as mea- In the RSM, the functional relationship between indepen-
suring instruments are always associated with a certain error. dent variables and the output responses is predicted using the
In this work, several parameters like load, temperature, pres- following equation.
sure, flow, and emissions are measured by eddy current
dynamometer, thermocouple wire, manometers, flow meter,
exhaust gas analyzer, and opacity meter, respectively. So, for
y f (x1 , x2 , x3 . . .) ± e (1)
getting accurate results from the instruments, it is needed
to evaluate the effect of error on output from the mentioned
instruments for the present study. The uncertainties involved
in several output parameters like brake power, BSFC, CO, where y is the response, x1 , x2 , x3 . . . are independent
HC, and NOx emissions as well as opacity are measured and variables and e is the error or noise factor associated with
presented in Table 12. the experiment.
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The function f is denoted by a second-order polynomial consumption BSFC in relation to the most recent market fuel
in RSM of independent variables as prices. Since producer gas is made from waste materials and
is available for free during the experiment, its cost is zeroed
k
k
k
k out in this study.
y β0 + βi xi + βii xi2 + βi j xi x j + e (2)
C Cblend − Cdiesel
i1 i1 i i × 100 % × 100
Cdiesel Cdiesel
Pblend
xdiesel + xblend Pdiesel BSFC
where β is the unknown regression coefficient of the 1+ − 1 × 100 (3)
xdiesel + xblend ρρdiesel
blend
BSFCdiesel
second-order model.
This response data used in the equations is to calcu- where C Cblend − Cdiesel is the difference in spe-
late the regression coefficients for the RSM model (β). To cific fuel price between fuel blend price and diesel price.
improve the accuracy of the model equations, the least- Cblend and Cdiesel are the specific fuel price of fuel blend
squares method with the least residual error is used. ANOVA and diesel, respectively, in Indian Rupees per kilo Watt-hour
is used to check the fitting of the model that how efficiently it (Rs/kWh). xdiesel and xblend are the volumetric ratio of diesel
can predict output responses related to the input parameters. and fuel blend, respectively. Pblend and Pdiesel are the price of
Design-Expert version 11 software is used for instigating the fuel blend and diesel per liter (Rs/lt), respectively. ρblend and
RSM in the current research. In the current study, the RSM ρdiesel are the densities of blended fuel and diesel (kg/m3 ),
technique is employed to determine the VCR CI engine’s respectively. BSFC BSFCblend − BSFCdiesel is the differ-
optimal performance by altering the engine load, CR, and ence in BSFC between fuel blend and diesel fuel.
fuel blend. References [25–28] provide additional informa-
tion on the RSM.
Box–Behnken design is employed in the present RSM 3 Result and Discussion
analysis because it aids in determining the best performances
by choosing the fewest number of test runs. The following In this section, the engine performance and emission char-
points are taken into account in the Box–Behnken design: acteristics of the VCR CI engine are investigated concern-
ing various input parameters, and the optimum values for
• Each independent variable or factor is assigned one of the these parameters are determined for maximum engine per-
three evenly distributed values, usually encoded as 1, 0, or formance and minimum emissions. It includes statistical
+ 1. analysis, ANOVA, engine performance, emission character-
• The design must be able to fit a quadratic model that istics study, and multiple response optimization (MRO) are
includes quadratic terms, two-element products, linear described in the following section in detail.
terms, and intercepts.
• The total number of runs, N 2k(k − 1) + cp to be exe- 3.1 Statistical Analysis
cuted during the experiment should be reasonable relative
to the number of coefficients in the quadratic model. The In statistical analysis, the engine performance like BTE and
total number of experiments (N) and central points (cp) emission characteristics like CO, HC, NOX, and opacity
required for various factors (k) should be reasonable. are studied and analyzed by response surface methodology
(RSM) regarding compression ratio, load, and multi-fuel
2.4 Economic Analysis mode of operation.
Table 13 represents the design of experiments (DOE)
Economic concerns are a major promoter for the devel- generated by RSM in coded format for analyzing output
opment of low-cost feedstock and process technology for responses concerning 3 input parameters as shown in Table
biodiesel production. Although the total cost of biodiesel pro- 12. A quadratic model is prepared using the Box–Behnken
duction is heavily influenced by feedstock costs, some other design of response surface methodology for three control
factors like the total capital investment cost, total manufac- factors and 15 test runs are performed as mentioned in Table
turing cost, and biodiesel break-even price are considered as 14. An ANOVA test is performed as part of the statistical
the main economic criteria. To evaluate the biodiesel produc- response analysis to check the model suitability for estimat-
tion processes, different researchers used different economic ing the output responses.
criteria emphasizing different points of view. In the present The ANOVA table predicts R2 -value, R2 -pred, R2 -adj, p-
paper, economic analysis of using diesel, Calophyllum ino- value, F-value, and adequate precision for validation of the
phyllum oil, and producer gas blend in multi-fuel mode of model effectiveness for predicting output responses.
operation is carried out using formula derived in [29] and Using analytical software, coefficients of various model
[30] and Eq. (3) based on the test engine’s brake-specific fuel terms of the quadratic polynomial regression equations are
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A B C Load (L) Comp. Ratio (CR) MF BTE CO emission HC emission NOx emission Opacity
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being determined and results of the present statistical analysis 4. In this study, the values of adequate precision for BTE,
are presented in Tables 15, 16, 17, 18, 19. CO emission, HC emission, NOX emission, and opacity are
In Tables 15, 16, 17, 18, 19, the R2 value for BTE, 31.065, 64.594, 31.802, 50.452, and 55.44, respectively, indi-
CO emission, HC emission, NOx emission, and opacity is cating the good adequacy of all RSM models in predicting
99.38%, 99.81%, 99.22%, 99.78%, and 99.01%, respec- the output parameters.
tively, which indicates that the RSM model is well fit and In statistical ANOVA, the p-value and F-value have impor-
competent in calculating engine performance and emission tance in determining the significance of the RSM model and
parameters. different model terms. The p-value is the probability value
For the responses BTE, CO emission, HC emission, NOx less than 0.05 indicates the RSM model or model terms are
emission, and opacity in Tables 15, 16, 17, 18, 19, there significant. The lower the p-value, the higher is the statis-
is a fair agreement between the predicted R2 value and the tical significance of the predicted RSM model and model
adjusted R2 value as the difference between these values is terms. For the current study, 95% confidence, 5% error, and
less than 0.2. 0.05 level of significance (α) were used. F-distribution or
The signal-to-noise ratio (S/N), which is a measure of F-statistical formula is used for finding out the F-value. The
adequate precision in RSM, should always be larger than F-value can be calculated by dividing the two mean squares
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as mentioned in Eq. (4). The formula gives the ratio of the where α significance level, k sample number, and N
explained and unexplained variances. During statistical anal- number of numerical data.
ysis, the F-value greater than one and P-value is less than 0.05 The model is significant when the value of F-statistical is
are required, else the predicted model is treated as insignifi- greater than F-critical. The Design-Expert version 11 ana-
cant. lytical software has calculated the value of F-critical for all
models is 1. The calculated F-values for BTE, CO emis-
MST sion, HC emission, NOX emission, and opacity are 89.16,
FStatistical or FDistribution (4)
MSE 291.55, 70.79, 247.06, and 55.44, respectively, are observed
greater than one, which indicates the formulated models are
where MST is mean square treatment and MSE is mean significant. The probability value or p-value of formulated
square error. RSM models for predicting BTE, CO emission, HC emis-
The value of F-critical is found from the F-distribution sion, and NOX emission is less than 0.0001, and for opacity,
table by using the following relation it is equal to 0.0002. In this statistical analysis, the calculated
F-values are greater than 1 and p-values are less than 0.05,
FCritical Fα(k−1,N −k) (5) so the models formulated by response surface methodology,
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RSM, are significant and proficient enough to determine the Table 20 Estimated coefficients of various output responses
performance and emission parameters for the test engine. Coefficient of HC Coefficient of NOx Coefficient of
emission emission opacity
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The effect of input parameters on BTE, CO emission, HC in certain combination of control factors of L-CR, L-MF, and
emission, NOx emission, and opacity are shown in Figs. 8 and CR-MF by 3D surface graphs as shown in Figs. 8, 9, 10, 11,
13, respectively. The results of the current study are presented 12.
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The highlights of the following results are listed below: the highest value of BTE is attained at the highest level
(+ 1) of L, i.e., 12 kg, and the highest level (+ 1) of CR
i.e., 18 at 50% Calophyllum Inophyllum biodiesel blend
1. The effect of load L and compression ratio CR on brake and producer gas mixture.
thermal efficiency BTE is illustrated in Fig. 8a for the
hold value 50% of multi-fuel, MF. Figure 8a shows that
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Similarly, the effect of load L and multi-fuel MF on brake highest level (+ 1) of CR, i.e., 18, and the lowest level
thermal efficiency BTE is illustrated in Fig. 8b for the (− 1) of MF, i.e., 0% Calophyllum Inophyllum biodiesel
hold value 16 of compression ratio, CR. Figure 8b shows blend and producer gas mixture at 8 kg load.
that the highest value of BTE is attained at the highest From ANOVA Table 14, it has been calculated that load
level (+ 1) of L, i.e., 12 kg, and the lowest level (-1) of has the highest contribution of 58% followed by the com-
MF, i.e., 0% Calophyllum Inophyllum biodiesel blend pression ratio of 18.1% and multi-fuel of 17.89% on BTE.
and producer gas mixture at 16 compression ratio. 2. The effect of load L and compression ratio CR on CO
Similarly, the effect of compression ratio CR and multi- emission is illustrated in Fig. 9a for the hold value 50%
fuel MF on brake thermal efficiency BTE is illustrated of multi-fuel, MF. Figure 9a shows that the lowest CO
in Fig. 8c for the hold value 8 kg of load, L. Figure 8c emission is achieved nearly at the mid-level (0) of L, i.e.,
shows that the maximum value of BTE is attained at the 8 kg, and the highest level (+ 1) of CR, i.e., 18 at 50%
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Calophyllum Inophyllum biodiesel blend and producer Calophyllum Inophyllum biodiesel blend and producer
gas mixture. gas mixture at 8 kg load.
Similarly, the influence of load, L, and multi-fuel MF on From ANOVA Table 16, it has been calculated that com-
CO emission is illustrated in Fig. 9b for the hold value pression ratio has the highest contribution of 58.9%
16 of compression ratio, CR. Figure 9b shows that the followed by % multi-fuel blend of 5.78% and the load
lowest CO emission is attained at the mid-level (0) of of 1.31% on HC emission.
L, i.e., 8 kg, and the lowest level (− 1) of MF, i.e., 0% 4. The effect of load L and compression ratio CR on NOx
Calophyllum Inophyllum biodiesel blend and producer emission is illustrated in Fig. 11a for the hold value 50%
gas mixture at 16 compression ratio. of multi-fuel MF. Figure 11a shows that the lowest NOx
Similarly, the influence of compression ratio CR and emission is attained at the lowest level (− 1) of L, i.e.,
multi-fuel MF on CO emission is illustrated in Fig. 9c 4 kg, and the lowest level (− 1) of CR, i.e., 14 at 50%
for the hold value 8 kg of load, L. Figure 9c shows that Calophyllum Inophyllum biodiesel blend and producer
the lowest CO emission is achieved at the highest level gas mixture.
(+ 1) of CR, i.e., 18, and the lowest level (− 1) of MF, Similarly, the effect of load, L, and multi-fuel MF on NOx
i.e., 0% Calophyllum Inophyllum biodiesel blend and emission is illustrated in Fig. 11b for the hold value 16 of
producer gas mixture at 8 kg load. compression ratio CR. Figure 11b shows that the lowest
From ANOVA Table 15, it has been calculated that multi- NOx emission is achieved nearly at the lowest level (−
fuel has the highest contribution of 41.8% followed by a 1) of L, i.e., 4 kg, and the mid-level (0) of MF, i.e., 50%
load of 12.72% and a compression ratio of 3.63% on CO Calophyllum Inophyllum biodiesel blend and producer
emission. gas mixture at 16 compression ratio.
3. The effect of load L and compression ratio CR on HC Similarly, the effect of compression ratio CR and multi-
emission is illustrated in Fig. 10a for the hold value 50% fuel MF on NOx emission is illustrated in Fig. 11c for
of multi-fuel, MF. Figure 10a shows that the lowest HC the hold value 8 kg of load, L. Figure 11c shows that the
emission is attained at the lowest level (− 1) of L, i.e., lowest NOx emission is achieved at the lowest level (−
4 kg, and the highest level (+ 1) of CR, i.e., 18 at 50% 1) of CR, i.e., 14, and the mid-level (0) of MF, i.e., 50%
Calophyllum Inophyllum biodiesel blend and producer Calophyllum Inophyllum biodiesel blend and producer
gas mixture. gas mixture at 8 kg load.
Similarly, the influence of load, L, and multi-fuel MF on From ANOVA Table 17, it has been calculated that load
HC emission is illustrated in Fig. 10b for the hold value has the highest contribution of 67.5% followed by the
16 of compression ratio CR. Figure 10b shows that the compression ratio of 17% and % multi-fuel blend of
lowest HC emission is achieved nearly at the mid-level 0.78% on NOx emission.
(0) of L, i.e., 8 kg, and the mid-level (0) of MF, i.e., 50% 5. The effect of load L and compression ratio CR on smoke
Calophyllum Inophyllum biodiesel blend and producer opacity is illustrated in Fig. 12a for the hold value of
gas mixture at 16 compression ratio. 50% of multi-fuel, MF. Figure 12a shows that the lowest
Similarly, the influence of compression ratio CR and opacity is attained at the lowest level (− 1) of L, i.e.,
multi-fuel MF on HC emission is illustrated in Fig. 10c 4 kg, and the lowest level (− 1) of CR, i.e., 14 at 50%
for the hold value 8 kg of load, L. Figure 10c shows that Calophyllum Inophyllum biodiesel blend and producer
the lowest HC emission is achieved at the highest level (+ gas mixture.
1) of CR, i.e., 18, and the mid-level (0) of MF, i.e., 50%
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contribution on HC emission of 58.9%, followed by fuel calorific value, and more. As a result, the torque,
multi-fuel of 5.78% and load of 1.31% of contribution, power, brake-specific fuel consumption, and emissions
respectively. CO, HC, and NOx associated with the engine vary.
iv. The NOx emission increases with an increase in However, real aspect of speed variation has not been
load and compression ratio, whereas decreasing and tested in this work, limiting its scope. So, the impact
increasing trend is observed for the increment in % of variation in engine speed on performance, emission,
Calophyllum Inophyllum biodiesel blend in multi-fuel and economic characteristics of a VCR CI engine may
mode of operation. The lowermost value of NOx emis- be tested as the future scope of the current research
sion is attained at 4 kg load, 14 compression ratio, work.
and 50% Calophyllum Inophyllum biodiesel blend and
producer gas mixture in multi-fuel mode of operation.
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