Paper of Cl Xii Cm 25 (Cm1+Cm2) Wt 8

CM25–XII-CM-1+CM-2– WT – 8
CM1 + CM2 – WT – 8
XII Syllabus
Test Date: 01 July 2024
Test window: 10:00 am to 11:59 pm
MATHEMATICS
CONTINUITY & DIFFERENTIABILITY
& CIRCLE
CHEMISTRY
PHENOLS, PREPARATION OF
ALDEHYDES & KETONES
PHYSICS
CAPACITOR & DIELECTRIC
FIITJEE KOLKATA NORTH CENTRE: Ganga Apartment, 86, VIP Road, Golaghata, Ultadanga, Kolkata–7000 48,Tel.40221300 (16 lines)
E-Mail: northkolkata@fiitjee.com URL: www.fiitjeekolkatanorth.com
-2-
Total Mark: 120 Min: 90
Chemistry
Marking Scheme
Single correct type
SOC – 4 – Each question carries +4, - 1 = 16
One or More than one option correct type
MOC – 4 – Each question carries +4, -1 = 16, Partial marks (+1)
Comprehension type – (Numerical Type)
COM-1-2Q– Each question carries +4, -1 = 8
Single option correct type

1.
(A) (B)
(C) (D)
C
C121205
2. Reactant P labeled with 14C (labeled carbon marked with asterisk) rearranged to product Q on heating
(A) (B)
(C) (D)
FIITJEE KOLKATA NORTH CENTRE: Ganga Apartment, 3rd. Floor, 86, VIP Road, Golaghata, Ultadanga, Kolkata–7000 48, Tel.40221300 (16 lines)
-3-
C121205
3.
(A) 22.40 gm (B) 11.20 gm (C) 22 gm (D) 11 gm
A
C121203
4.
(A) 5 (B) 4 (C) 3 (D) 6
B
C121801

5. Which of the following is correct for the final product of the given sequence of reaction
CM- MgBr
24-
WT- (i)
CH 2 OH HIO4 (i) PCC
8-Q-4
P1 P2 P3 (Final product)
(ii) H2O (ii) CH3MgBr
CH 2 OH
(iii) H2O
(A) Compound P3 on oxidation with (CrO3 + H2SO4) gives a compound which gives 2, 4 DNP test
(B) Compound P3 on reaction with I2 + NaOH gives yellow ppt
(C) Compound P3 on reaction with ceric ammonium nitrate gives red colouration
-4-
(D) Compound P3 on reaction with MnO2 gives carboxylic acid
ABC
C121203
6.
CM-24- Identify correct method of preparation of acetaldehyde from reaction of cyanide
WT-8-
Q-5
 i DIBAL  i SnCl  HCl
(A) Me  C  N 
ii  H O 
 (B) Me  C  N  2
 ii  H O

3 3
 i  Conc.H 2SO4  i  Pd/ BaSo4 /H 2

(C) Me  C  N 
 ii  dill.NaOH  (D) Me  C  N   ii  H3 O
ABD
C121801
7. Which of the following compounds react with NaHCO3 to give CO2?

OH OH
O OH O 2N NO 2 O2N
(A) (B) OH (C) (D)
O OH
COOH NO 2
NO 2
ABCD
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8.
ABC
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Comprehension Type – (Numerical Type)

COMPREHENSION – 1
Phloroglucinol is obtained when many plant resins are fused with alkalis. It may be prepared by
fusing resorcinol with sodium hydroxide in the air. But a convenient laboratory method is to reduce
2, 4, 6 trinitro benzoic acid and heat the resulting amino derivative with HCl.
CO2H CO2H
H2N NH2 HO
NO 2 NO 2 OH
Sn HCl
HCl
NH2 OH
NO 2
Phloroglucinol
-5-
9. Number of – CH3 group (s) present when phloroglucinol is treated with excess of CH3I in presence
of KOH is
6
C121205
10. HO OH
(i) ZnCl2
CH 3CN Pr oduct
HCl
(ii) H3O+
OH
No of ‘O’ atoms in the product
4
C121205
Physics
Marking Scheme
Single correct type
Comprehension type – (Numerical Type)

1. Two capacitors A and B with capacitors 3 F and 2 F are charged to a potential difference of 100 V
cm- and 180 V respectively. One plate of two capacitors are connected as shown. Now switch S is closed
23- so as to connect a cell of 100 V to the free plates of two capacitors. Calculate heat generated in the
WT- circuit
6-Q-
1
(a) 21.6 mJ (b) 19.44 mJ (c) 41.04 mJ (d) 32.4 mJ
B
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2. Lower plate of a parallel plate capacitor is fixed on a horizontal insulting surface. The upper plate is
cm- suspended above it using on elastic cord of force constant K. The upper plate has negligible mass
23- and area of each plate is A. When there is no charge on the plates the equilibrium separation between
WT- them is d. When a potential difference = V is applied between the plates the equilibrium separation
6-Q- changes to x. Find the value of x for which V is maximum.
3
-6-
d d 2d d
(a) (b) (c) (d)
3 6 3 2
C
P120112
3. 20X amount of heat in J will be generated in the circuit shown in the figure after the switch is
shifted from position 1 to position 2? (given that C  2F, e1  20 V,e 2 10 V ). Find X.
(A) 1 (B) 3 (C) 5 (D) 7

C
P120112
4. The plates of a parallel plate capacitor are inserted into a liquid dielectric of dielectric constant K and
density  . If a battery of voltage V is connected across the plates, the pressure difference two points
P and Q just above and below the lower plate is
V
K
P
Q
0 K  K 1 V 2 0 K  K 1 V 2 0 K  K 1 V 2 2 0 K  K 1 V 2
(A) (B) (C) (D)
d2 2d 2 4d 2 d2
B
P120114

5. A parallel plate capacitor of capacitance C0 is charged to a voltage V and then the battery is
disconnected. A dielectric convering one-third area of each plate is now inserted as shown in the figure.
If charges on the capacitor plates get redistributed such that the portions convered with dielectric and
not covered with the dielectric share equal amounts of charge, which of the following statements is/are
true?
(A) Dielectric constant of the dielectric is 2.0

(B) Charge appearing due to polarization on the surface of the dielectric is 0.25 CoV.
-7-
(C) Force of electrostatic interaction between portions of the plates covered with dielectric is equal to
that between uncovered portions
(D) Force of electrostatic interaction between the plates after insertion of the dielectric becomes 9/8
times of its value before insertion of the dielectric.
ABD
P120114
6. Consider two identical dielectric slabs that are inserted into two identical capacitors A and B connected
to the battery as shown in the figure. Now the dielectric slab of capacitor B is pulled out slowly from it
with the battery still remaining connected. Then during the process of removing the dielectric slab, we
observe the following statement(s) to be correct.
(A) Positive charge flows from a to b.

(B) Final charge on capacitor B will be less than that on capacitor A.
(C) Work is done by the external force F appears completely as heat in the circuit.
(D) Internal energy of the battery increases.
AD
P120114
7.
BD
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8.
BC
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-8-
Comprehension Type – (Numerical Type)
COMPREHENSION – 1
cm- Two capacitors of capacity 6 μF and 3 μF are charged to 100 V and 50 V separately and connected
23- as shown in figure. Now all the three switches S1, S2 and S3 are closed.
WT- 6F 3F
1 + 2 3 + 4
7-Q- +
+ S2
+
+
2,3 100 V 50 V
S1
S3
200V
9. Charges on the 6μF capacitor in steady state will be
(a) 400 μC (b) 700 μC (c) 800 μC (d) 250 μC
B
P120112
10. Suppose q1, q2 and q3 be the magnitudes of charges flown from switches S1, S2 and S3 after they are
closed. Then
q2
(a) q1  q3 and q2  0 (b) q1  q3  (c) q1  q3  2q2 (d) q1  q2  q3
2
D
P120112
Mathematics
Marking Scheme
Single correct type
Comprehension type

1.
CM-23-
WT-9-Q-

Numbers of points where f (x) = 

max x 2  x  2 , x 2  3x
 ; x0
is non differentiable will be
2


max In   x  , e x   ; x 0
(a) 1 (b) 2 (c) 3 (d) none of these
2. Let f (x) = signum (x) and g (x) = x (x2 – 10x + 21), then the number of points of discontinuity of
f g  x   is
CM-23-
WT-9-Q-
3
(a) 0 (b) 1 (c) 2 (d) 3
3. If [x] denotes the integer part of x and in (0, ), we define

CM-23-
WT-9-Q-4
-9-
  2(sin x – sin x)  | sin x – sin x | 
n n
 ,x/2
 n n
f(x) =   2(sin x – sin x) – | sin x – sin x | 
 
 3 , x

Then for n > 1

(a) f  x  is continuous but not differentiable at x 
2
(b) Both continuous and differentiable at x = /2
(c) Neither continuous nor differentiable at x = /2

(d) lim f  x  exist but lim f  x   f  
x

2

x
2
2
B
4.
CM-23-
WT-9-
Q-7
(a) f(x) is continuous and differentiable for all x ϵ R

(b) f(x) is continuous but not differentiable for all x ϵ R
(c) f(x) is discontinuous at infinite number of points
(d) f(x) is discontinuous at finite number of points

5. Three circles C1 , C2 , C3 with radii r1 , r2 , r3  r1  r2  r3  touches
CM-24-
WT-6-
Q-9 each other externally as shown and L1 , L2 are two common
tangents to these circles from P. Which of the following is
(are) correct?
r 2  r32
(A) r2  1 (B) r22  r1r3
r1  r3
(C) DE  2 r1r2 (D) DE  r22  r12
BC
6. Let S1 : x 2  y 2  10 x  16  0 and S 2 be images of S1 w.r.t. line y  x and S3 be image of S 2
CM-24-
WT-6-
Q-10
w.r.t. y  0 . If S ' be the circle which cuts all three circles orthogonally, then
(A) S ' : x 2  y 2  16 (B) S2 : x 2  y 2  10 y  16  0
(C) S3 : x 2  y 2  10 y  16  0 (D) Radius of director circle of S ' is 8 2
ABC
7. If a function satisfies (x – y) f (x + y) – (x + y) f(x-y) = 2(x2y – y3)  x, y  R and f (1) = 2, then
(A) |f(x)| is non differentiable at two points (B) |f(x)| is continuous everywhere
(C) f(-4) = 12 (D) f(4) = 18
ABC
- 10 -
8. In a question, a student was given to find the derivative of the product of two functions ‘f’ and ‘g’.
x 1
The student by mistake thought  fg   f .g for his question f  x   and he got the correct
x 3
answer. Given that g(1) = e. Which of the following options is/are correct?
(A) g(x) is discontinuous at one point

(B) lim g  x  1
x
x3 8
(C) lim 12 where  is the number of points of discontinuity of g(x)
x  x  2
(D) g(x) is discontinuous at two points

AB
Comprehension Type
COMPREHENSION – 1
Let f(x), f : R → R be a non-constant continuous function that f ( 2x)  (e  1) f (x).
x
9. The value of f '(0) is

f (h) f (h) f (h) f (h)
(A) lim (B) lim (C) lim (D) lim
h 0 eh  1 h 0 eh  1 h 0 e  h 1
h h 0 eh  1
B
M120402
10. If f '(0)  1 , then number of points where g(x)  [ln(1  f (x))]  {x} , is discontinuous (where [.]
2
denotes the greatest integer function and {.} represents functional part function)
(A) 0 (B) 1 (C) 2 (D) infinite
A
M110902
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CM25–XII-CM-1+CM-2– WT – 8

Single option correct type

(A) 22.40 gm (B) 11.20 gm (C) 22 gm (D) 11 gm

(A) 5 (B) 4 (C) 3 (D) 6

One or More than one option correct type

 i  Conc.H 2SO4  i  Pd/ BaSo4 /H 2

7. Which of the following compounds react with NaHCO3 to give CO2?

(A) (B) OH (C) (D)

Comprehension Type – (Numerical Type)

Single option correct type

(a) 21.6 mJ (b) 19.44 mJ (c) 41.04 mJ (d) 32.4 mJ

(A) 1 (B) 3 (C) 5 (D) 7

One or More than one option correct type

(A) Dielectric constant of the dielectric is 2.0

(A) Positive charge flows from a to b.

Single option correct type

(a) 0 (b) 1 (c) 2 (d) 3

3. If [x] denotes the integer part of x and in (0, ), we define

(a) f(x) is continuous and differentiable for all x ϵ R

One or More than one option correct type

(A) g(x) is discontinuous at one point

(D) g(x) is discontinuous at two points

9. The value of f '(0) is

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