https://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon BAL TAP TONG HOP Su lén men tinh bt véi mach nha duge dig dé sin xudt ancol etylic. Trong quia trinh nay ste trong mach nha dé tao thinh disaccarit mantozo. Mantozo (CypH2:0i1) khit duroe thude thir Tollens va dung dich Fehling, dé bi oxy h6a boi 1c) COOH) mét axit monocacboxylic, Dé xée dinh cdu mantozc theo con dmg nhir sau: thuy phan tinh bot duoe xtie téc boi enzym diata Bri/H,0 dé sinh ra axit mantobionie ((C) He: {nde ctia mantozo thi nguoi ta da chuyen hi HNO, smatose — Yap catt09 N (GBOy) RO GHgOo fi ntically eetive HO Mes$O. € tmaltobionic ail > € (Cy 09}C00H) z 08 < | Ho a se as D + E a2 (CyHy09” — (Coa0,) ae x0 Fe G Be Be alt (Cali) 26 oxi ge ace u eo 38 1 sama fe 8 ges Opreso. 35 NOP] seon 2 Bed M es (Cat400 BE pialy active a2 °6 tinh quang hogt 3 4 Intermediat .im trung gian, & 1, V@ cdc céng thyte chiéu Fischer cho chat B va tir chat D dén N. § 2. Vecong t orth eiia mantozo, axit mantobionie va chat C. : 5 3 1G a © 4O B D Ee ~ HO HO GooH x iP ue u f ‘OMe Q HOH H--OMe CHOH —CHOMe © CHOMe $ ei 3 5 8 g i i htlps://daykemquynhonofficial. wordpress com/blog! DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON www.facebook.com/daykem.quynhon https://daykemquynhon. blogspot.com www.facebook.com/daykemquynhonofficial Dong gép PDF béi GV. Nguyén Thanh Ta www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon www.facebook.com/daykem.quynhon plus.google.com/+DayKémQuyNhon https://daykemquynhon. blogspot.com ¥ iF G H cHo oH |= GOO Loe ome HOM: Meo} 00H coon CH,OMe coor ome Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM http://daykemquynhon.ucoz.com Noi bd dung kién thre Toan - Ly - Héa cho hoe sinh cp 2+3/ Din Ban Toan - Ly - Héa Quy Nhon 10008 Trén Hung Deo Tp.Quy Nhon Tinh Binh Binh DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON www.facebook.com/daykemquynhonofficial Dong gép PDF béi GV. Nguyén Thanh Ta www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon, XIX. Qua cacbon vi lu huynh thi Ong thye hign mot heat C + Ss Cp acetic acid —_ A heat: dun néng light: anh sng _ Trong t6ng hgp hitu co hign dai thi mot phuong phégdon gidn sau di duge sir dung trong vige ting hgp ede aminoaxit, * ‘coy —“ |B | ccetoorn |» MeOH [©] (Catnsoc i) HO fi) Hp, Pac http://daykeme Noi bd dung kién thre Toan - Ly - Héa cho hoe sinh cp 2+3/ Din Ban Toan - Ly - Héa Quy Nhon 10008 Trén Hung Deo Tp.Quy Nhon Tinh Binh Binh 4’ D (CsHsN02) i E (CoHtsNO3) vided thife cau tgo cdc chat tir A dén E va xc dinh cau hinh tuyét d6i cia céc trung tim bait x trohg D va E sir dyng danh phap R, S. contguraton: S “Enamin durge hinh thanh trong phan ting gitta mét xeton va mét amin bac 2 duéi xtic tée axit: Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM THOTUNE "84305779994 (MOBILEZ2AL} htlps://daykemquynhonofficial. wordpress com/blog! DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON www.facebook.com/daykem.quynhon https://daykemquynhon. blogspot.com www.facebook.com/daykemquynhonofficial Dong gép PDF béi GV. Nguyén Thanh Ta www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon www.facebook.com/daykem.quynhon plus.google.com/+DayKémQuyNhon https://daykemquynhon. blogspot.com ° ue O PG=2 BE nghj co ché cita phan img (1) “ PE GREP AES Bai 4: Coniin 1a hgp chat rat dc duge tim thay trong cay de sim (conium maculatum), rei tS dai ngudi Hy Lap Socrates 48 bj gist boi chat nay. Coniin 18 m9t hyp chat ehita nite va 18 (> a) ancaloit Xe dinh héa tinh va héa lap thé ctia coniin bang c’ich ho’n thinh eée “ue ‘ing sau, Ve CTCT A,B,C. LW (itor eas et 2. Ag:0 H20, 4 optically x 2.40.0 1.0, 4 occ Kao, Conine CAWCHOCCH nO oot, (S)-S-aminoctanoie acid NaOH, 0°C A ‘Hofmann exhaustive methylation: sur neg acre dé theo Hofmann Optically active: hoat ding quang hoe ‘Ly - Hoa cho hge sinh cp 2+3 / Din Ban Toan - Ly - Ha Quy Nhon 1000B Tran Hung Bgo Tp.Quy Nhon Tinh Binh Binh HOTLINE. 104905779896 (MODILEZZALO) Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM http://daykemquynhon.ucoz.com Not bBi dung kién thie Toan - DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON www.facebook.com/daykemquynhonofficial Dong gép PDF béi GV. Nguyén Thanh Ta www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon http://daykeme Noi bai dung Kién thire Toan - Ly - Hoa cho hge sinh cp 2+3 / Din Ban Toan - Ly - Ha Quy Nhon 1000B Tran Hung Bgo Tp.Quy Nhon Tinh Binh Binh Dong gép PDF béi GV. Nguyén Thanh Ta LG io BD nas (CH;CH2CHY ~N’ 20.10 (CH3CH,CH;* ma erchseas 'N(CHa)> cu oo, ° —— | \ 4. Chal a Stl H, 14: 2920, AZO ee +, )\ octadi > cHycH,cH 7 SM* oy, ud Me CHCH:CHs 4 catscrsocoe1 zc Wi) os \5~ coon CHyCH2CH2* N TNa0H,OTC CHCH.CHY tS tuscan & & i CHSCHACHS Ye Oy sannenct a Buc oxy héa bing KNinO, tham khio trong tai ligu: A. M, Castano, JIM. Cuerva, A. M. Echavarren, Tetrahedrak eters, 35, 7435-7438 (1994) Bai $: Mot ankin A auung Hoot 2 C= 89,5% Va 10,4%H. Sau khi d& hydro hoa hodn toan bing mgty¥— 4 — propylniclohexan. Khi cho A phan ting voi CHsMgBr ta khong thu s Hydro héa A trén xe téc Lindlar tiép theo 18 ozon phan va phan img véi KMn0, sinh PB? San phim B phan tmg véi /NaOH cho ra két tla mau vang, Loc két tha, axit héa dich loc RG san pham C quang hogt, Xac dinh céng thire cau tao A, B, C. Ha, Pac : 8 ei 2 5 3 Q a i i htlps://daykemquynhonofficial. wordpress com/blog! DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON www.facebook.com/daykem.quynhon https://daykemquynhon. blogspot.com www.facebook.com/daykemquynhonofficial www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon, www.facebook.com/daykem.quynhon https://daykemquynhon. blogspot.com Gls ¢ a CH.CH.CH, aH HyPaIC Z ~ CHy CHs_|iay HeLindlar COOH st COOH Os KinO. CH CHs o (8) Bai gay ra ung thir. Trong hang logt cfc :{daykemquynhon.ucoz.com Noi bai dung Kién thire Toan - Ly - Hoa cho hge sinh cp 2+3 / Din Ban Toan - Ly - Ha Quy Nhon 1000B Tran Hung Bgo Tp.Quy Nhon Tinh Binh Binh CO;,N, i. 0: i. CO: ih phan img xay raz : CAC HOP CHAT CUA MAGIE ‘Magie [2 m9t nguyén 16 quan trong trong co hang trim cdc phan img sinh héa diéu khién c: chita AND. Magie ¢6 vai (rd hoat héa hon 300¢eizim khic nhau, Magie duy i huyé lam gidn cde mgch mau, Sy thiéu magic 5 dyng sinh hge kha quan hon oxit magie"(hgp chat durge ding phd Mg 1 kim logi dé chy Khé dap tit dam chéy Mg do kha nang chay trong nuée, a) Vidét va cn bang phuong trinh phan img tao thanh MgO tir Mg véi May #202) —> MeO Me + CO —> 2Mg0n + Cin b) Magie hi ‘duge tao thanh tir phan img cia Mg hoac MgO véi HO. Viét va can bing én sy ‘on ngudi, Magie 1A nhién ligu cha tinh chuyén héa nang Iuong va stra am chite nang sinh If ctia ede ng dudng chat magie thi magie xitrat c6 tée nha), co; Ox Mga) + 2H20 — Mg(OH)ry + Hou MgO: MgOq + H:Oy, > Mg(OH)r Ohi dét kim loai magie trong khi N; thi tao thanh hgp chat A mau tring nga. Thiy phan ‘A sinh ra khi B khéng mau va c6 tinh bazo khi hda tan trong née. Phan img cia B voi dung dich nuéc ciia ion hypoclorit CIO” tao thanh ion clorua Cr, muse, va hop chat phan tir C tan duge trong mréc. B phan img véi hidro peroxit cing tao thanh hop chat C va nude, Dun néng khf B véi kim loai natri, sinh ra mét hop chat ran D va khf hidro. Phan itng giita D véi oxit nito N30 tao thanh khi amoniac, NaOH rin va mt hgp chat rin E. Khi nung néng, E bi Dong gop PDF béi GV. Nguyén Thanh Ti Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM OTUNE: 84805779904 (WOBILE?ZALO) htlps://daykemquynhonofficial. wordpress com/blog! DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON www.facebook.com/daykemquynhonofficial www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon phan hay thanh kim Jogi natri va khi nite. Viét va can bing phyong trinh phan img tao thanh méi chat A, B,C, D, va E. ‘A: MgsNo; B: NH; C: NH; D: NaNH>; E: NaNs 3 Ma(s) + No(@) > Mass) MeNi(s) + 6 H:0(2)-+ 3 Mg(OH)(s) +2.NEL(g) 2 NHs(aq) + OCE(aq)-+ Cl(ag) + HzO(0) + NeH(aq) 2 NHIs(g) + H:04(aq) > NaHs(aq) + 2 Hs0() 2 NHA(g) + 2 Na(s) -+2 NaNHL(5} + Hl) 2 NaNI(s) + N:O(g) > NHG(g) + NaOH(s) + NaNs(5) & 2NaNy —t 5 2Nayy + 3Noie) C d) Viet céng thire cau tao Lewis ca anion c6 trong hgp chat E va hay abu tric cOng hung bén nhat. Dang dau tién 1a bén nhat. SS e) Hop chat © dug sir dung dau tién 18 dé 1am nhién sie jira trong Dai chién Thé gidi Il. Ngay nay C duge str dung nhu li chat né c6 cong suat Who trong Qu vii tru. Véi su e6 mat cla chat xc te 1A sgi nano cacbon hoe molypdeniaitait trén chét mang nhom Oxit (ALOs), hop chat C phan hy tao thanh amoniac BS ‘ito. Viét phuong tinh phan img phan hhuy hop chit C. eo 3NaHyy > 3NaHiyo6S>” 4 Hau + Naw 1) Tinh nang Iugng ctta phan tng pl hop chat C thanh amoniac va khf nito_ va entanpi hinh thanh tiéu chudn ciia NH3 Cho biét, 6 298 K: - Entanpi hinh thi tigu chudnetla Cyog Va Cy Min hurt 18 50,6 kJ/mol va 95.4 ki/mol. x ig, 7 2 ~ Nang long plign'li lién két (nding hagng lign két trung binh) cia N=N, N=N, N- N va N-H Kan lugt (Ruohg img) la: 946, 418, 163, va 389 ki/mol. Bdd2 SS; D 4 [2n(OH)e}*(aq) + NHL(a) We thém din din bazo manh vio dung dich chira ion Zn’*, mot két ta tring Za(OH), tao om (Ky ome = 1.2.10). Cho 0,1 mol OH” vio 1,0 Iit dung dich chia 5.107 mol Zn”. Shas pH cia dung dich thu duge. Zn* + 20H — Zn(OH);| n'(mol) 0.05 OL n(mol) 0 0 0.05 HG thu dirge: 0,05(mol/it) Zn(OH)s | OTUNE: 84805779904 (WOBILE?ZALO) htlps://daykemquynhonofficial. wordpress com/blog! Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON www.facebook.com/daykem.quynhon https://daykemquynhon. blogspot.com www.facebook.com/daykemquynhonofficial Dong gop PDF béi GV. Nguyén Thanh Ti www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon Zn(OH); = Zn’? + 20H” sp ss + 4s'= — [OH] = 2,88.10° (M) — pH = 8,46. d) Khi thém tiép bazo vao dung dich, Zn(OH);- . Hing sé tao phtie (hay hing sé bén) ctia ion phite 1 4,6.10"”, Tinh pH cua hé thu dugc khi thém tiép 0,1 mol OH” vao dung dich trong phan (C). (Coi tang thé tich khong thay 2.107 (2.107 — s = 1,44.10°M ta tring Zn(OH): tan tao thanh ion phite didi). a Zn(OH)> () => Zn* ay) + 2OH (ayy Ky= 12.107 a's Zn) +40H ay) = ZN(OH)2 wy B= 4.6.10” © Zn(O)ag + 20H any = ZMOW)} fay K=Kyye B n (mol) 0,05 OL n’(mol) : a 0,05 mol/l HG thu duge: Zn(OH) >> (aq) 0,05 M ZnOW)} (ay) = ZO): (4 + 20H aq) WD = 0,182 x 2% )3. —» [OH] = 0,06 M — pH €) Dé phan tich ham lugng NaNO trong, thf nghiém ngudi ta hoa tan hoan toan 5 hop chi gdm NaCl va NaNO), trong mot in hgp vdeo nuée va pha thanh 100 ml dung dich, sau dé lay 10 ml dung dich thu ‘ir ly voi Zn, Cho khf NH; sinh ra trong qué trinh phan ing di qua 50,0 ml dung dich HiGT0, 150 M. Dé chudn d6 HCI dur cin ding hét 32,10 ml dung dich NaOH 0,100 M. Ti Phan img: xX 4 2n+ 40H a Zn(OH).” + 2€ 10; + 6FNQF 8e > NH, + 90H 4Zn +NQ;+ 70H + 6H;0 — 4Zn(OH),” +NHs Trong 109 feiss Tyxuno,= Avi, = Muci Mxson Goi s6 Gan NaNO; trong 100 ml dung dich Ra, ta c6: idaykemquynhon.ucoz.com Noi bai dung Kién thire Toan - Ly - Hoa cho hge sinh cp 2+3 / Din Ban Toan - Ly - Ha Quy Nhon 1000B Tran Hung Bgo Tp.Quy Nhon Tinh Binh Binh ‘Khdi hong cia NaNO, trong mau rin. = 8. 100.55 0,15 - 32,10.0,1).10° — a=3,6465 = 3,65 (g). 85°10 %NaNO3 = 2.100 = 72.9% 5,00 Q f) Ca 2 chat NaCl va NaNO; déu 1a nhittng chat dign ly manh, Sy c6 mat cla hai chat nay trong dung dich lm gidm 4p suat hoi bao hoa ciia dung méi, din dén sy gidm nbigt 46 déng bang. D6 ha bang di ban chat cia dung méi, Hing n khong chi phy thudc vao sé tigu phan chat tan ma cdn phu thude vaio nghiém lanh déi véi HjO la K, = 1,86 1C/molan i i 3 8 = 3 2 3 89 33 a $3 2 38 =2 3 3 i: 4 ‘ : i 3 é § i www.facebook.com/daykem.quynhon https://daykemquynhon. blogspot.com www.facebook.com/daykemquynhonofficial Dong gop PDF béi GV. Nguyén Thanh Ti www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon :{daykemquynhon.ucoz.com Noi bai dung Kién thire Toan - Ly - Hoa cho hge sinh cp 2+3 / Din Ban Toan - Ly - Ha Quy Nhon 1000B Tran Hung Bgo Tp.Quy Nhon Tinh Binh Binh Dong gop PDF béi GV. Nguyén Thanh Ti (C/mol/kg). Xée dinh nhigt 49 d6ng bang cia dung dich thu duge khi hoa tan 1,50 g hon hop (in6 ta trong mye (e)) gm NaCl va NaNO vio nude dé thu duge 100,0 mi dung dich. Cho khdi Luong riéng ciia dung dich nay la d = 0,985 g/em*, Tur d = 0,985 g/cm’ trong 100 mL dung dich c6 98,5 g (gdm 1,50 g hén hyp va 97,0 g nue). Theo két qua tinh duge 6) > Nano, 1.50 - 1.09 = 6.94 10° mol 585 AT/= i+ Kem=- 1.86) Vay nhigt d6 déng bang cua dung dich 1a - 0,761°C g) NoH, 1 mot tong nhiing hop chat cla Nito e6 thé ding lam nhién ligu, Hay tinh bién thién nding Iwgng ty do tiéu chuan cho phan img cia pin nl NoHy (g) + Ox(g) > Na(g) + H20(1) Cho thé tiéu chudin: 0,(g) + 2H,O(1) + de > 40H (aq) No(g) + 4H,O(1) + de + NoHA(g) +40H (aq) E25 (O,(g) + 2H,0(1) + de > 40H (aq) h) Bién thién nang lugng ty do lién quam toi cong cye dai ma hé thy hign trong thai gi ip sudt ange trong diéu kién thudn nghich nhiét dong. Méi lién hg gitta cong eye dai va bién atin: Iugng ty do AG nhur sau: -AG = Wag. Tinh cong cue si iét Itong NH, tiéu thy 1a 0,32 gam (6 diéu kién tiéu chudn). ‘Waa cong cue dei sinh ru tr 1 mol NaH, la 602 1. Vey tidu thy 1a 0, (tite 0,010 mol) thi céng eye dai sé 1a 6.0 KJ, Bai 8: Hi mpc SAT 1a mt trong nhimg nguyén éu lugng NoHs hd bién nhit trong vo trai dat va duoc khai thie * khodng chat cromit: FeCr,O, (dicrom sat tetra oxit). Dé san xuit crom tinh khiét, & Fe tir khosing theo 2 qué trinh nung va loc: {4FeCrs0,(r) + 8NajCO4(1) + 70,(kh) —> 8NajCrO4(1) + 2Fe,Os(r) + 8CO%(K) 2NayCrO,(r) + HySOu(dd) + NagCrs07) + NarSOu(dd) + 100) Dicromat duge chuyén vé CryOy bang qua trinh khir béi cacbon, sau 46 Khir thinh Cr bang phan «mg nhiét nhhom: NasCrsO4(1) + 2C(2) + CrsO,(r) + NaxCO(r) + COKK) Crs05 + 2Al(1) + ALOx(r) + 2Cr(r) OTUNE: 84805779904 (WOBILE?ZALO) htlps://daykemquynhonofficial. wordpress com/blog! DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM www.facebook.com/daykem.quynhon https://daykemquynhon. blogspot.com www.facebook.com/daykemquynhonofficial www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon www.facebook.com/daykem.quynhon plus.google.com/+DayKémQuyNhon https://daykemquynhon. blogspot.com http://daykeme Noi bd dung kién thre Toan - Ly - Héa cho hoe sinh cp 2+3/ Din Ban Toan - Ly - Héa Quy Nhon 10008 Trén Hung Deo Tp.Quy Nhon Tinh Binh Binh ~ a) Tinh khi lugng Cr thu duge theo ly thuyét tir 2,1 tn quang chita 72,0 % kho’ing FeCr,0,. 21.72 ——— . 108 100 . 224 I Mer 2Me,0,= 2Nr,C40, =F» 2ANn:C40, = 2FeCHO, 21.72 “100 . 224 b) Do c6 kha nang chéng an mon tét, nén crom 1a vat ligu tao hop kim quan trong déi voi thép. Dé phan tich ham lugng Mn va Cr trong 1 mau thép c6 khdi hrgng 5,00 g, ngudi ta oS ha Mn thanh MnOj va Cr thanh Cr,0}. Sau qué trinh xir ly thfch hop thu durge 100.9% dung dich va duge chia thanh 2 phan bing nhau: = me,= 1G, = - 10° . 52,0 =7,0.10° (g) = 7,0.10° (kg). ~ Léy 50,0 ml dung dich cho vao dung dich BaCl, va diéu chinh pH dé en hodn toan va thu duge 5,28 g BaCrO, @ chuan d6 50,0 ml dung di dung dich Fe" 1,6 M. Phuong trinh chua can bang ciia phan mg con Iai trong mdi trong axit ci yiung hét 43,5m duge cho dus day: MnO. (aq) + Fe"(aq) + H'(aq) > Mn"*(aq) + Fe C10? (aq) + Fe™(aq) + H"(aq) > Cr(aq) + ‘Hay cfin bing cdc phuong trinh phan ting aw MnOy(ag) + 5 Fe*(aq) + 8 Ho(ag) > Mn*( (aq) +4 H20(0) Cr,0;? (aq) + 6 Fe® (aq) + 14 Hr(aq) > 8 fag) + 6 Fe%*(ag) +7 H,0(/) c) Tinh % Mn va % Cr (vé khdi Iugng) wnieaidu thép. ‘Thi nghiém 1: 2Ba* + CrOF + ho 2BaCrO,l + 2H* THOTUNE "84305779994 (MOBILEZ2AL} I 5,82 Mexia 0m) = 2M, gor plncr0,= Micro, 9553 ~ 0,023 (mol) — Mee cuong, 1009 mi dung dehy = 52,0... 0,023 . 2 = 2,39 (g) Thi nghigm 2: MnOe(ag) ¥S Fe*(aq) + 8 H-(aq) > Mn2(ag) + 5 Fe*(aq) + 4 H20(1) Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM Shae sc eon) t4itgan) 42.0809) Ferg) 71,00) Trong alex dich: Dayo 5M h40, 7 8 7 CROF htlps://daykemquynhonofficial. wordpress com/blog! DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON 1 wa s00.0 = Dyyyoz= gD Mpger ~ Oe, g2.) Lin ) 5 «Petron 500m) = a" 1 Mata ng S00.) = 52M = > $35.10". 1,60 - 3 0,023) = 1,2.107 (mol) > My49 rong 10000 mi dine dich) = 54,9 . 1,210" . 2 = 0,013 (g) www.facebook.com/daykemquynhonofficial Dong gop PDF béi GV. Nguyén Thanh Ti www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon idaykemquynhon.ucoz.com Noi bai dung Kién thire Toan - Ly - Hoa cho hge sinh cp 2+3 / Din Ban Toan - Ly - Ha Quy Nhon 1000B Tran Hung Bgo Tp.Quy Nhon Tinh Binh Binh Dong gop PDF béi GV. Nguyén Thanh Ti ~ 2:39 199 489%; % Mn trong thép ta: &9!3 199 =0,26% 5,00 5,00 Bai 9: CAC HOP CHAT CUA XENON Mac di c6 mat trong khi quyén tréi dat chi lugng vét song xenon cing duge ding trong linh vue chiéu sing va quang hoc trong dén nhdy va dén hd quang. Nguoi ta str dung xenon nhw nhién ligu phan lye cho déng co day ion cua tau vii tru. Thém vao dé, xenon cing c6 mét vai img dung trong y té. MGt mém nhu tim, phéi va nao. Xenon duge ding lam thuée gay mé va gin % Cr trong thép ig phan cia xenon duge ding dé tao anh ce mo. y ngudi ta ‘iém nang 1én trong viée st: dung xenon dé diéu ti chan thuong nao trong d6 cé 5 én mach miu nao (chimg d6t quy). GS Xenon 14 mot khi tro, hoat déng héa hoe rit yéu, Tuy nhién ngudi ta daBiét dén moe vai hgp chat eiia Xenon véi cde nguyén tit e6 dé am dign cao nh flo va 0} esi phan img ‘Gi flo tg0 thinh 3 florua xenon khéc nhau: XeF>, XeF, va XeF,, Tat ui Florua nay dé dang phan img véi nude, giai phéng ra khi xenon tinh khiet, flora hi idro va oxy phan tir. Cée oxit va oxoflorua ciia Xenon duge tao ra khi thay phan kh in toan hodc thiiy phan hoan toan cdc floruaxenon. Xenon trioxit (XeO3) c6 thé thu’ 1c khi thay phin XeF, hoac XeFs. Qué trinh thiy phan XeF, sinh ra XeOs, Xe, HE, 08 khi 46 XeF, bi thay phin tao thanh san pham chi c6 XeO; va HF. Khi thay phi shine hoan toan XeF, va XeF, ngoai HF, cén lan uot tao ra XeOF va XeOFy, ow a) Viét va cn bing phuong trinh phan img tao’ 1. XeO, bing cach thay phan XeF,: Ko 2XeFs 210 Ken Xe0; 6+ RED 2. XeO biing cdch thiy phan XeF,: XeFe + 3 HO + Xe0s + 6 HO) 3. XeOF, bing cach thiiy pha khong hoan toan XeF, XeFs + HO + XeOR] + ZHF 4. XeOF, bing céchthity phan khong hoan toan XeF, Keke + HON XeOFy +2 HF b. Vidt cor ite cu tao Lewis va cho biét dang lai héa cia nguyén tir trung tim cia’ A 2. XeF, oF) x EXe-F* spa 3. XeO3, 4. XeOF: es OTUNE: 84805779904 (WOBILE?ZALO) htlps://daykemquynhonofficial. wordpress com/blog! DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM www.facebook.com/daykem.quynhon https://daykemquynhon. blogspot.com www.facebook.com/daykemquynhonofficial www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon «] i 5. XeOF,: spsd? Bai 10: CAU TRUC CAC HOP CHAT CUA PHOTPHO Photpho rit hoat dong vi vay khong thé tim thay dang don cl trong lop vo tréi dat, Photpho 1a mot nguyén (6 edn thiét d6i v6i moi si la thanh phin cu tgo chinh cia xuong dudi dang Cax(PO,)2 va ci photpholipit. Hon nia photpho 1 thanh phiin ciia ef ADN, ARN trong céc té bao héng céu va anh huréng dén sur vi /én cita oxi, Photpho cd Se héa tri ging nhu nito, 2 orbital d trdng, c6 thé tao cae hop chat dat photpho tring cé dang sp rin, gim dong va d8 chay thanh ngon lita tro :{daykemquynhon.ucoz.com Noi bai dung Kién thire Toan - Ly - Hoa cho hge sinh cp 2+3 / Din Ban Toan - Ly - Ha Quy Nhon 1000B Tran Hung Bgo Tp.Quy Nhon Tinh Binh Binh ane 2 ign li trong cée pin ion liti. io ‘an bing phwong trinh phan img tao thanh: Pals)+3 H:0(0) +3 OH (ag)-+ PHa(g) + 3 H:POx(ag) 1: Pals) + 6ChLg)-+ 4 RCRD 4. P.O: Pals) +3 0x9) + P08) (thidu oxi) S.PiOyo: Pd) +0360) +0048) (4a oxi) 6. HPs; MOxls) +610(1) + 4 H5POs (ag) T.HjPOg: Puls) +6H:0(0) +4204 9) TP... Tat ca cdc phan tir c6 vai trd sin xuat va dy tri nang long, hoat héa ede enzi cic hooe mén, truyén tin higu gitta cdc t8 bao déu phy thuge vao céc hop chat va yd@trinh phophoryl héa. Céc hop chit coia photpho déng vai td nhur mgt hg gm dé duy i pH cia mau va gin két hemoglobin 1a nguyén t6 thude chu ki 3, né c6 cdc phoi tri 6. Mot dang thit hinh ciia photpho Ia phan tir P, hinh tt dién. Photpho tring rat hoat ing kh, ao thanh photpho (V) oxit PsOyo. Oxi hda khéng hoan t pho (trong diéu kign thiéu oxi) tao ra photpho (III) oxit P,Qg. Phin ting dj li ciia 0 tring trong dung dich c6 moi tung bazo tao ra khi photphin PH va ion hypophdtphit HPO. . Axit photphoro HsPOs va axit photphoric HPO, theo thir uy c6 thé thu@tege bing phan img ctia P,Og va P{O,o vai nue. Photpho tring phan img vGi haloge NM cde hyp chit halogennua v6i cong thite tong quét Ia PX; va PXs. Oxi héa PCls iii triclorua POCI5. Phan ng cia PCls v6i LiF sinh ra LiPF, duge OTUNE: 84805779904 (WOBILE?ZALO) htlps://daykemquynhonofficial. wordpress com/blog! DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM www.facebook.com/daykem.quynhon https://daykemquynhon. blogspot.com www.facebook.com/daykemquynhonofficial Dong gop PDF béi GV. Nguyén Thanh Ti www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon, http://daykeme Noi bd dung kién thre Toan - Ly - Héa cho hoe sinh cp 2+3/ Din Ban Toan - Ly - Héa Quy Nhon 10008 Trén Hung Deo Tp.Quy Nhon Tinh Binh Binh Dong gop PDF béi GV. Nguyén Thanh Ti B.POCI;: — 2PCLIM) + 0xlg) +2 Poch«) O.LIPF,: POL + 6 LiFls) + LiPFy(s)+ 5 Licks) b) Viét cong thie cdu tao Lewis cita ci ion sau bao gdm ci hudmg néu ¢6: 1. PCly; 2. Pls; 3. PO}; 4. POCI:: 5. PF; phan tir va dang cOng 1 Pel 2. PCls: ) Vé cae céng thire cAu tao ca cdc oxit phy EN PO, va P,O,o bat dau tir khung tir dién P,. Déi vGi P.O, mdi nguyén ut trong 6 ngu} oxi sé lién két voi 2 nguyén tir photpho trén ‘mét canh. Trong tng hop PO), 61 nguyén tir photpho s& é nguyén tir oxi. NK 4) Sir dun, nh lye dy ciia cée ep electron héa phan tifftoge cée ion sau: 1. PCls; 2. POCls; 3. PCls: 4. PR, [3! nguyén wr trung tim P 6 4 c§p electron, trong 46 ¢6 1 cp electron khdng lién két electron tyr do) va 3 ep electron lign két. Nhur vay dang hinh hoc ede ep electron Ia tir dign, Dang hinh hoc phan tir la thép tam gide, 2. POCIs: P c6 4 cap electron lign két. Nhu vay ca dang hinh hoc electron va dang hinh hoc phan tir 1a tir did 3. PCls: P c6 5 phan tir 1a luéng thap tam gid. , hay xc dinh dang hinh hge cia cdc electron lign két. Nhu vay ci dang hinh hge electron va dang hinh hoe i : : 3 f i E : z 3 3 z 3 z 8 i 8 =2 g 82 2358 $228 3330 EES Go BBS. ae a ee 8 88 a5 3 £ : a www.facebook.com/daykem.quynhon https://daykemquynhon. blogspot.com www.facebook.com/daykemquynhonofficial www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon, 4. PF: P c6 6 c&p electron phan tir fa bat dign, ©) Cho biét dang lai héa ciia nguyén tir photpho trong cde phan tir va ede ion sau: 1. PCls: sp" 3. PCls: dsp* Bai 10: ASEN TRONG NUGC Asen durge dén nhu mét chat biét gay 6 nhiém méi trudng va 1A mét nguyén hai. Tuy nhién gin day trong 1 cOng trinh nghién ciru cua NASA (Mf) di ae n-két, Nhur vay cd dang hinh hoe electron va dang hinh hoe 6 1 loai vi khudn & Mono Lake, California e6 thé str dung asen thay cho phot ph inde phan tir sinh hoc. : Trong nude ty nhién, asen e6 mat 6 dang oxo axit: HAsO, va sachet trang thai oxi héa lin luot 14 +3 va +5. Hang s6 cén bing cla 2 axit nhu sau: Oo HAsO; Ku 10” 2 HyASO, Ky = 5,8.10°; Ko = 11107) Ky = 3.2.10 Trong dung dich, trang thai oxi héa ca asen phy thu SOD st c6 mat cila cée chat oxi héa va cde chat khir, trong 46 oxi hda tan déng vai tro aut . Theo WHO ting néng d6 16i da cia asen trong mrde udng cho phép 1a 10 nell Trong mét mau nude duge Liy tit mot dong,sAE duge coi 1a ngudn nude uéng, gid tri pH = 6,50. Két qua phan tich bing phuong php quang phé hap thy nguyén tir cho Cyan 108 pall: Cas) = 43 nell & a) Tinh téng néng 46 mol déi voi dang I) va As(V) v6 co trong hé, gia thiét ring day 1 nhitng dang t6n tai duy nhat cla asets> Vio,s.10-% Cas = 1,44.107 (MP Lrg 74,92 oo ’ . 106 a Ast) gg EM b) Déi voi Asti, dang phan tirhay ion nao chiém wu thé 6 pH = 6,5. Viét cong thitc, Di 1,AsO3 06 pK = 9,29; gid tri pH = 6,50 nhé hon dang ké so v6i 9,29-> d6i véi As(fil)ydang chiém wu thé 6 pH = 6,5 1a HyAsOj, ogee phan tir hay ion nado déi vi As(V) chiém uu thé & pH = 6,5. Viét cOng thite. DOi véi HsASO4 6 pK, = 2,23; pK,2 = 6,96; pK = 11,49. http://daykemquynhon.ucoz.com Noi bai dung Kién thire Toan - Ly - Hoa cho hge sinh cp 2+3 / Din Ban Toan - Ly - Ha Quy Nhon 1000B Tran Hung Bgo Tp.Quy Nhon Tinh Binh Binh (HyAsO4] _ 10°° 1, HAsO) _ 1065 [H,AsO4] 10 *THASOy] 10° (HAsOF] __ 10° {Asop] 101? H,AsO3 va HAsO G pH =65: > 1 déi véi As(V) dang chiém wu thé 6 pH = 6,5 1a céc ion OTUNE: 84805779904 (WOBILE?ZALO) htlps://daykemquynhonofficial. wordpress com/blog! DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM www.facebook.com/daykem.quynhon https://daykemquynhon. blogspot.com www.facebook.com/daykemquynhonofficial Dong gop PDF béi GV. Nguyén Thanh Ti www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon, :{daykemquynhon.ucoz.com Noi bai dung Kién thire Toan - Ly - Hoa cho hge sinh cp 2+3 / Din Ban Toan - Ly - Ha Quy Nhon 1000B Tran Hung Bgo Tp.Quy Nhon Tinh Binh Binh Dong gop PDF béi GV. Nguyén Thanh Ti 4) Tinh C(moW/!) cita dang As(IIL) da durge dé xuat trong edu (b) D6i vGi As(IM), chi ¢6 | dang chiém wu thé li H3AsO3, do d6: Chr,aso, = 144.107 (M) ) Tinh C(mol/I) cita cde dang As(V) chiém wu thé di duge dé xuat trong cau (c) ple pk. IWASOF | +18, A804) = 5.74% 10 mol") x = [HASOF] 6.502696¢ log x=[HASO@] = 148x108 mol-L* (HyASO{) =5.74% 10° - 1.48 « 10° = 4.26 « 10° mol -L* Nang 46 ctia nhiing dang khac 1 khong dang ké. 1 Déi véi con ngudi thi Asi} dgc hon so véi As(V). Khi 06 tée nhan oxi hoa ag hoa tan trong nude thi sé ¢6 Igi hay bat li? Q . Néu thém céic chat oxi héa vio dung dich As(III) thi As(II}) sé bj oxi.héd'thinh As(V). Luong dc 6 sé giam, nhu vay sé c6 Igi khi c6 cdc chat oxi héa trong gon Bai 11: OXIT CHI LUONG TINH Q Trong méi truéng nude ion Pb’ tao két tha PbO 1 mi Gr ludng tinh. Trong méi trudng axit chi c6 dang Pb” tn tai. Khi ting dan pH, Pb¢ d(H); duge tgo thinh véi lugng dang ké. Cfn bing chi: yéu cia ede dang chi trong moi trudng nude duge cho duéi day: PHO jy + HO, = Pay) + 20H ay 8.0.10" a PbO(, + 3H:0q, = Pb(OH)s as) + 0.10% Q) a) PbO Iudng tinh bj hda tan hodn toan@\pH da thép. Néu ndng d9 ban dau cua Pb** 1a 1,00.107 mol/l thi pH dé PbO bat ding ia I bao nhiéu? 2 rp ae? K, 8.0.10" Dé PbO bat dau két tae AR ea = — pH=7.45 ne yf . tit gi tr] pHLyinh durge trong (a), khi pH tang dén mot gid tri nt di tan ra. Tai pH ban; nhiéu thi két tia tan hoan toan? 10% . ket tha Tai G pH wifeng déi cao, két tia tan chi yéu tgo thanh ion Pb(OH)3. Khi két ta toan thi POOH 31 = 1,00.107 M. tan hoan * ir (2) ta c6: [Pb(OH)3 |[H30°]= K, = 1,0. 10° Sao" ,0.10"" + pH = 13,00 thi két tia tan hoan toan. ©) Viét biéu thite tng quat tinh d6 tan § ciia PbO Siro = [Pb™*] + [Pb(OH)31 d) Theo Ii thuyét d@ tan t6i thiéu dat duge khi pH=9,40. Tinh C(mol/) ct 49 tan tai pH nay. tat ci ede dang va yy, Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM OTUNE: 84805779904 (WOBILE?ZALO) www.facebook.com/daykem.quynhon https://daykemquynhon. blogspot.com htlps://daykemquynhonofficial. wordpress com/blog! DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON www.facebook.com/daykemquynhonofficial www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon, ‘i me Noi bai dung Kién thire Toan - Ly - Hoa cho hge sinh cp 2+3 / Din Ban Toan - Ly - Ha Quy Nhon 1000B Tran Hung Bgo Tp.Quy Nhon Tinh Binh Binh Dong gop PDF béi GV. Nguyén Thanh Ti [30%] = 100 = 4.0210: moLL%, Using Ka = 1.00*1044, [0H] = 2510 mol-L* From Kip [Pb] = 1.3+10¢ mol-L, From Ka, (Pb(OH)s] = 2510¢mol-Lt For molar solubility,5 = [Pb%| + [Pb(OH)], = 13«10*+ 2.5+104=3.8«10¢molL:* e) Tinh khoang pH dé Spyo $1.10°(M) G pH twong déi thip, Pb** sé chiém uu thé, do dé [Pb™] =Spyo = 1,0.10° M Kep= [Pb?*] - [OH™? =8.0% 10-6 [ow LPoconi] = 7 = 8.94 10° mob Oy eS [ Pb(OH)3 | <« [Pb"*]. Nhu vay trong moi trutmg axit | Pb(OH)3 | 1a khong a: Kol va Pb 1a dang chit yéu. G moi trudng bazo hon, Pb(OH)3 sé chiém wu thé, Khi a6: [Pb(OH);] = 1.0010 fromK, — [H,0*] = 1.00 « 10 pH= 12.00 and [OH] = 1.00 « 10-7 Vay khoang pH dé Sio $1.10" (M) la: 7,95 8 (Hoge: ry K. Smo = [Pb] + [Pb(OH)31 = 2 4 KelOH) ‘ee Sat | (OH kK 1 10 '[OH'} -10°[OH}’ +8.10° = 2,00 7,95 Vay khoding pH. d8.8% <1.10°(M) a: 7.95- 12,00) Bai 12: nate HON HOP MUOI Ca” néng 5,000 g hin hop gdm CaCOs, Ca(HCO,)s, CaCl va CaC10s)> 6 nhiét Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM 4 khi COs, HO va O» duge thodt ra, Cée khi nay to mot ép sudt P =1,312 atm len pre 1 binh khf dung tich 1,000 lit d3 durge hut chan khong 6 400.0 K. Khi nhigt 46 trong “eh giam xudng 300 K thi ép suit gidm xuéng cdn 0,897 atm. Ap suit hoi nude tai nhigt 46 nay 1a 27,0 torr, Khf tong binh duge sit dung dé dét chay mOt lugng chua biét axetylen Ch. Bién thién entanpy trong qué trinh chdy duge xée dinh [a -7,796 kJ voi A,H°(C,H,(g)) = 226,8kJ/ mol; A, H” (CO, (g)) =-393,5kJ/ mol A,H°(H,O(g)) =—241,8kI/mol;Ay,,.H’ (H,O()) = 44,0kI/mol van THOTUNE "84305779994 (MOBILEZ2AL} htlps://daykemquynhonofficial. wordpress com/blog! DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON www.facebook.com/daykem.quynhon https://daykemquynhon. blogspot.com www.facebook.com/daykemquynhonofficial www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon a. Viet va cain bang phuong trinh cho cdc phan img phn huy c6 thé xay ra dé tao ra cic khi. CaCO,(s) + Ca0(s) + COx(g) Ca(HCOs)(8) ~Ca0(s) + 2.COAg) + H:0(@) CaCl; + Noreaction Ca(Cl0),(s) > CaCl(s) + 3 04g) b) Viét va can bing phuong trinh phan tg dét chay CH> 2.Caltalg) +5 O2(g) > 4 COa(g) + 2 1200) c) Tinh téng sé mol khf tao thanh trong binh at SE 8 = 0.0399 mol = 0.040 mot d) Tinh s6 mol oxi cé trong binh aH = 2 Aat(CO3(g) + Ad (HSO(D) ~ AA (CH(R)) H,0(2) == #,0(0) “Argll®= AdH*(H:0(0)) - Ad?(H:0(2)) AdH°(H20(1)) = - 44.0 + - 241.8 =-285.8 kJ/mol Alt = 2x(-3935)- 2858 - (226.8)=- 1299.64) 3/2 x (-7.796}/(-1299.6) = 0. e) Tinh s6 mol CO) va HO two thanh 4300 HO) condeses MCD 03) =P f= 0097 - FE = 0861 tm wee 0-2 -amag QV a \(c0¥) = 0.035 -0.015 = 0.020 (1:0) = 2040 -0.035- 000s f) Tinh % khdi lung cita CaCO, va CaGdirong hn hop ban dau oe ae fC2a(C10,)3) = (03) = 20.015 5-QHBS mot ‘(CaC03) = n(COzJxcon, Wc) ene (C02) =m(CO:)acas #2 n(foOF. 0.0200 = n( COs #2% 0.0050 (€3€03) = n(C0,acos 9G2020 0.010 = 0.010 mal saron se sonore sacsiigle a vistas ibn Ses a a electing 233100=430% %caCo= “2 <100=200% ii 13: PHAN TICH HAM LUQNG CON TRONG HOI THO. x) Ethanol hda tan duge trong méu va phén bé téi cdc b6 phan trong co thé. LA mét hop > chat dé bay hoi, ethanol cé thé bi lam cho béc hoi mét cach dé dang. Trong phdi, ethanol cé thé chuyén pha tir long sang khi va ta ra ng http://daykemquynhon.ucoz.com Noi bd dung kién thre Toan - Ly - Héa cho hoe sinh cp 2+3/ Din Ban Toan - Ly - Héa Quy Nhon 10008 Trén Hung Deo Tp.Quy Nhon Tinh Binh Binh cing voi khéng khf. Do d6, néng dé cia ethanol bay hoi trong phdi lién hé truc tiép vai néng dé ethanol trong mu. Do dé, néng d6 ethanol trong mdu cé thé do duoc bang thiét bi cé tén 1A thiét bi phan tich hoi thé Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM www.facebook.com/daykem.quynhon https://daykemquynhon. blogspot.com THOTUNE "84305779994 (MOBILEZ2AL} htlps://daykemquynhonofficial. wordpress com/blog! DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON www.facebook.com/daykemquynhonofficial Dong gép PDF béi GV. Nguyén Thanh Ta www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon www.facebook.com/daykem.quynhon plus.google.com/+DayKémQuyNhon https://daykemquynhon. blogspot.com “breathanlyser” (thiét bj do ndng 6 cén trong mau), Voi kiéu cit cua breathalyze, ngudi bj nghi ng sé the vao trong thiét bj va hoi d6 sé duge din qua dung dich kali dichromate va tai day ethanol sé bj oxi ha thanh axit axetic. Sy oxi hoa nay duge kem theo sy chuyén mau tir da cam sang mau xanh 1a cdy va m6t bd phan nhan biét sé ghi lai cuong d6 cua sur chuyén mau nay, dia trén sur thay doi mau, e6 thé tinh durge ham hgng cia alcohol trong hoi thé. Khi qué trinh oxi héa alcohol béi kali dichromate xay ra trong mOt binh dign héa, hoge 1a dong dign durgc tao ra béi phan tmg hodc la sur thay doi trong site dign dong 6 thé do duge, aes va str dung dé danh inh ham lugng alcohol trong mau, phan tig oxi héa ethanol bai ion dichromate xay rahe a) Viét phuomg bang ct mdi trudng axit: 3CH;CH,OH(g) + 2Cr,0;"(ag) + 16H*(aq)— 3CH;CO,H() + 4Cr™ (aq) KHZ) b) Néu thé Gu chudn cia qud tinh Khir ion CrO;” think Cr 1a 1,330 V thanh ethanol 1 0,058 V, hi ire dign dong tiéu chudn B” cua phanat ring phan img trén ty xay ra 6 diéu kign nhiét 46 25 °C va dp sudt EYS1,330-0,058 = 1,272 V Go E° > 0 nén phan img ty xay rao i ai = ©) Trong thigt bi phan tich hoi thé sir dung qua tinh = raat thé tich dung dich can dmg 1a 10,0 ml. Khi mot gu ootrong thiét bi, mot dong dign duge ehi ph khdi lurgng alcohol trong thé tich hoi ‘axl axetic lai vai eudg d6 0,1 A trong th duge the ra. Q=T-1=01 Ax 605= 60As Theo phuong trinh phan ing trén srtsein 6 mole" dé tao ra 2 mol Cr”, do vay: Ve 2mol Cr _, 5 molCr* n(Cr 0c ease molCr 4:mol Ce £9 3 mol CRSCH2OH OTUNE: 84805779904 (WOBILE?ZALO) Noi bai dung Kién thire Toan - Ly - Hoa cho hge sinh cp 2+3 / Din Ban Toan - Ly - Ha Quy Nhon 1000B Tran Hung Bgo Tp.Quy Nhon Tinh Binh Binh Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM n(aleohoVthé tich lidi the ra) = 1,55 10° mol m(alcohol/ = 1,55x10°%46,0 g.mol! = 7.15 x 10™ g, d) Trong viée ih todn ham lurgng alcohol trong mau tir ngng alcohol trong khi hoi thé ra, ti htlps://daykemquynhonofficial. wordpress com/blog! DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON IEEE Fn ratio” 2100:1 cin duge tinh dén. Ti sé trén cho ta biét ring cir 2100 ml khi hotiérta chita long ethanol tong dong hong ethanol c6 trong 1 ml mau. Hay néi se khéc, cit mdi ml mau chita lugng ethanol gép 2100 fan Iugng ethanol c6 trong 1 ml hoi tho ra. Néu thé tich hoi thé ra m6 ta trong phan (c) 1 60,0 ml, hay tinh ham long [cohol c6 chita trong 1 ml mau. 7,15x10" g alcohol trong 60 mL khi hoi thé ra. 1,19x10° g/mL khi hoi thér ra. 1,19x10-5 g/ml khf hoi thérra x 2100 ¢) Trong moi rung kiém, Cr” két tia dudi dang Cr(OH)s. D6 tan cua chromium(I) ,025 g aleohol trong ImL. mau. www.facebook.com/daykemquynhonofficial Dong gop PDF béi GV. Nguyén Thanh Ti www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon www.facebook.com/daykem.quynhon plus.google.com/+DayKémQuyNhon https://daykemquynhon. blogspot.com hydroxide I 6,3x10™ at 25 °C. Hay tinh thé tiu chun cia qué trinh khir Cr(OH); thanh Cr. Cho biét, thé tiéu chuan eta qué trinh khtr Cr°* thanh Cr Ia -0,74 V. (Ce qua tinh xay ra nhur sau: Cr(OH),(s) > Cr“(aq) + OH" (aq) Pin dign thich hgp véi phan img nay 1: Cr(s)l Cr“(aq)l OH’ | Cr(OH),(s)! Cr(s)l AG® =—3x96485x E®,, =-8.314 298 InKsp FE, (S22 396485 $0,595 = ES py (0.74) 9 Eoygug, = SAV Incaix10” 05980 htlps://daykemquynhonofficial. wordpress com/blog! Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON http://daykemquynhon.ucoz.com Noi bd dung kién thre Toan - Ly - Héa cho hoe sinh cp 2+3/ Din Ban Toan - Ly - Héa Quy Nhon 10008 Trén Hung Deo Tp.Quy Nhon Tinh Binh Binh www.facebook.com/daykemquynhonofficial Dong gép PDF béi GV. Nguyén Thanh Ta www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon ‘Ly - Hoa cho hge sinh cp 2+3 / Din Ban Toan - Ly - Ha Quy Nhon 1000B Tran Hung Bgo Tp.Quy Nhon Tinh Binh Binh http://daykemquynhon.ucoz.com Not bBi dung kién thie Toan - Dong gép PDF béi GV. Nguyén Thanh Ta Draw the structure(s) of the most probable 1,4-dioxane derivative(s) when the starting compound is (S}-2-methyloxirane ((S)-1,2-epoxypropane). Give the structure of the reactant as well. 9. i Het H (S)-2-methyloxirane H3C Hea? CS sy or 4 ° H3C- ° 07 CH; Draw the structure(s) of the substituted 1,4-dioxane(s) when sas reacting is. (R}1,2-epoxy-2-methylbutane ((R}-2-ethyl-2-methyloxirane). Give the structure of the reactant as well (R)-1,2-epoxy-2-methylbutane: H3C,, 0. HC Hc, -9 wer 1, HL® Hs jC CoH "Cas O° Hs S O°” CHy ‘0 CHa or of or HC o He HC om pos QO” op oily a HeCap 0 ae Wee Het. 8 4 Colts CH, —_ Each sterec ia Ps - Rg if two struct : "SRS (meso) Give th ture(s) of the substituted 1,4-dioxane(s) when this reaction is carried out wit ic 1,2-epoxy-2-methylbutane (2-ethyl-2-methyloxirane). Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM HOTLINE. 104905779896 (MODILEZZALO) www.facebook.com/daykem.quynhon https://daykemquynhon. blogspot.com DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON www.facebook.com/daykemquynhonofficial www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon, 203/ ofp me Not bai durong kién thie Toan - Ly - Hoa cho hoe sinh Din Ban Toan - Ly - Ha Quy Nhon 1000B Tran Hung Bgo Tp.Quy Nhon Tinh Binh Binh Dong gop PDF béi GV. Nguyén Thanh Ti Hs ° or or Hac, -0 H.C, -O H,C,, 0. wer iG HC: "CH “CoH 'CoHs oO H ‘0 3 or HsC2 Hse OW CH Om yp Salts HsCap 0 yc 0 HC. RR ss Bai 8: Tinh thé sit Dang tinh thé cia sit (ot - Fe) cé mang tinh thé lap phuong tim khéi voi d6dai'canh 1 287A, dare (25°C) = 7,86g/em'. Mot dang khée tn tai 6 nhigt d6 cao IY reo tinh thé kigu lap phuong tam dign véi dé dai canh 1a 3,59A, . 2) Tinh ban kin nguyen tea sit ong o - Fe. Gi sirving cfc npayS6 Xr Fe ip nc Wi nha theo durimg chéo chinh B 'b) Tinh ban kinh nguyén ur cita sit trong y- Fe. Gia sit ring en tir Fe tiép xic vei nhau. theo durimg chéo ciia mat 6 mang. ca hai truong hgp Na = 6,02214199mo!" ©) Gia sit ring ¢6 mOt dj nguyén tir nim khit mot ¢: 1n hao tai trung tam 6 mang co s6 cla mang tinh thé a - Fe (c6 nghia d6 1 vi tri (12, 0, 4). Chinh vi vay né sé tiép tie véi ede nguyén tir Fe khde nim étim ems ca sé. Xée dinh bain kinh cia dj nguyén ti? . 4) Cling du hoi nhur 6 edu (¢). Tinh ban kffieua di nguyen tir néu nh n6 nm vita khit v6i vi Uf trung tam ciia 0 mang co s6 ciia nbsihé Fe. ¢) Cie dj nguyén tir 6 cfu (c) va Qe in kinh Ién gap bao nhiéu lin ban kinh cua nguyén wr cacbon. Biet R= 0,077nm. Bai 8: Tinh thé sit : e a) Tachinhvé sau: O) i 4 ’ —:1—— Goi R 1a ban kinh ca tinh thé sit va a= 2,87A 1a canh cua 6 mang co so. Nhu vay, mdi nguyén tir o6 thé tiép xic voi nguyén tir khdc trén dutmg chéo chinh cia 6 mang. Ap dung dinh ly Pythagore vao trong truéng hop nay ta tinh duge R = 1,24A, Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM THOTUNE "84305779994 (MOBILEZ2AL} htlps://daykemquynhonofficial. wordpress com/blog! DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON www.facebook.com/daykem.quynhon https://daykemquynhon. blogspot.com www.facebook.com/daykemquynhonofficial www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon :{daykemquynhon.ucoz.com Noi bai dung Kién thire Toan - Ly - Hoa cho hge sinh cp 2+3 / Din Ban Toan - Ly - Ha Quy Nhon 1000B Tran Hung Bgo Tp.Quy Nhon Tinh Binh Binh Dong gop PDF béi GV. Nguyén Thanh Ti > $6 Avogadro (Na) ¢6 thé duge tinh tir khdi long riéng cia 6 mang. Két qua sau cing 6 thé nnhdn durge bing eich tinh s6 nguyen tir e6 trong mgt 6 mang ca sa. Nhiin con s6 vira mai tim dusge nay véi khdi lung thyc cia méi nguyén tir (khdi Iueng thyte = kh6i Tung phan tit Na) va hay chia ét qi thu duoc cho thé tfch cua 6 mang (a°). Luu ¥ ring trong mang tinh thé ip phuong tim Khoi (bce) 6 chita hai khdi cu chinh 1a hai nguyén tir Fe, Nhu vay: 3) _ 2x(55.847/Na)g a vm) 255.8478 Ni ——=Na~ 60010" 7.86x (2.8710) ear b) Bang céch 4p dung dinh ly Pythagore trong 6 mang lip phuomg, ta e6 thé tim duge: as ata? = GRY > R= 127 S6 ligu nay khée so v6i 86 ligu tinh 6 6 mang lap phurong tm Khoi boi vi c6 sy sng hau dn dén sy anh huéng dén ban kinh nguyén tr hay f¢ nhat fa se ude Ivong gid tr vi khoi Luong riéng thi trong 6 mang cor s6 lip phurong tim dign ¢6 4 qua’edu, nguyen ti Fe. Nhu vay ta 6 thé tinh durge: 4x(55.847, Fea x 8,02g/em> Gia tri cao hon ctia y - Fe so véi o.- Fe c6 thé durge gidi thich {ch céu tnic tinh thé lap phuong tam dign dic khit hon so voi lap phuong tam khoi. durge 3 1 tric sip xép Ip phuong, p(giem’) = ‘khit nhat cing v6i cau tric sip xép luc phuong khit nhat 1a hi ap xép c6 d6 dc khit bang nha va cao nhat trong khong gian ba chigu. (c) va (d). Cac hinh ve phia diréi duge minh hoa g cacti ‘gidm bét di kich thuée cia khéi cau, Luu § ring: & dang khdi dc thi nguyén tr dai dign ph; tgp xe vi cde nguyén tr khie. 8 3.9 4 2.87 A xR “Nore : e.g 1-Fe Dura vao so dd beh tri thi di nguyén tir sip xép hod iio nhit vio trung tim cia 6 mang & .24A. Nhu vay ban kinh cua di nguyén tinh thé ct - Fe (Yd 6, %) sé c6 ban kinh Ri fen = Ya — Ree, VOI a= 2,87A Va Rre= tir tinh ay 0,204, NigiTVa0 so dé & phia ben phai thi di nguyén tir nim khit mot ech hodn hao 6 trung tam phai £6 vieihi(¥2, 4%, 4) trong mot 6 mang eo sary Fe s@ e6 bain kinh tho’ man hé thie: va R(dj nguyén tit) = Yaa — Rye, voi a= 3,59A va Rye = 1,27A. Nhu vay bain kinh cia dj nguyén inh duge la = 0,534, ‘¢) Mot nm = 10A. Nhu vay bi voi o- Fe: Res 077A R, mes 020A Di voi y- Fe OTUNE: 84805779904 (WOBILE?ZALO) htlps://daykemquynhonofficial. wordpress com/blog! DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM www.facebook.com/daykem.quynhon https://daykemquynhon. blogspot.com www.facebook.com/daykemquynhonofficial www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon Rese _ OITA _1 45 Rae 053A Nhu vay nguyén tir cacbon thi qda lin gip 4 Lin dé c6 thé nim khit mot eich ho’n hao vao tinh thé ct - Fe ma khdng thé khOng din dén sy x6 léch va n6 vurot gia kch e@ 1.5 kin dé nim kit inh thé y - Fe, Cac két qi trén c6 thé giai thich duge d6 tan thap etia eachon vao trong tinh thé y - Fe (< 0,1%). Bai 12: Xae djnh cacbon 'C 1a déng vi phéng xa B c6 chu ky ban hy t = 5700 nim. N6 tin tai trong ty nhién do nd lién tue duge sinh ra trong Khf quyén nhur fa mét san phém cia phan img hat nhain gira nguyén tir nite va notron sinh ra boi tia vi try. | Ching ta gia ste ring tbe d9 eta gia tinh inh thin fa hiing s6 trong hang ngan nim ve-bing vai te d6 phiin 13. Chinh vi viy lung ''C wong khi quyén lu6n ludn khOng doi. Ket qua 1 SChrong hf quyén lu6n di cing véi ede déng vi bén °C va SC trong khf quyén va tham gia véi vahund-nine ‘hau trong cée phin ‘img héa hge eita cacbon. N6 sinh ra CO» vei oxy va di vao ede qiiirinh s6ng qua céc phan img quang héa dudi ti 1¢ 4C/7C luén duge gitt khéng déi trong cac ph hitu co. nay duge sir dung dé xée dinh tudi cia cée nguén gde sinh hoe (9A: t6e, va. Ching duge phan lip bing vai con dung sau cdi chét cla vat thé hitu co (vi. ng céic ing m6). Tile “C/"C trong cae mau trén khOng phai lun 14 mot hing s6 nhat dink. 10n gidm di theo thoi gian vi “C figm te bi phan Lung ''C c6 trong cdc vat thé séng (tinh trén tng sé nguyé wld 06.46 phan ra 0.277Balg (1Bg = IDps (phan 12/ giay)). a) Tinh tudi ca mt mau chat ¢6 ti 1g “C/?C = 0,25 b) Chuyén ei xay ra voi nguyén tir “C khi né bj phan "oe ©) Néu C nam trong cdc phan ti hitu co (nhr DN, phan ri thi sé xy ra hign twong gi? 4) Tinh d6 phéng xa cia mt ngudi 75k ea sy phéng xa trong co thé con ngudi chi do “C thye hign va lugng C tro 18.5%. in v,v...) trong co thé séng ma bj Bai 12: Xée dinh cachon a) Goi No la tile “C/7C trong vat ay ‘va N ciing 18 ti Ig trén sau khi vat chét mot khoding thoi gian t :{daykemquynhon.ucoz.com Noi bai dung Kién thire Toan - Ly - Hoa cho hge sinh cp 2+3 / Din Ban Toan - Ly - Ha Quy Nhon 1000B Tran Hung Bgo Tp.Quy Nhon Tinh Binh Binh Ta c6: Y hing nay dan dén hé tl Noo? -n 2 tn® =11400 nam. in2 b) Pre phéng xa chung etia sy phan ra B li: n— p+ B + Oe v6i p Ia proton va De la leg Phan notrino (electron antineutrino). Voi MC ta 06: Napa Ses m@t phan tir hitu co chita '“C thi néu '“C bj phan ra sé gy ra mét anh huong rit lon jén cau tnic phan tir do C s& bi thay thé bang N (mét nguyén tir hodn ton khie C ve ban chat JY a ne), didn nay din dé sc hinh than cde ght do, @) me=75.0,185 = 13.9kg Do phong xa R = 13900.0,277 = 3850Bq aN Lynn apst di a In? = 10" nguyén ti = 1,66nmol. Bai 13: Uran Uran (Z= 92) fa mot nguyén 16 phéng xg ton ti trong ty nin. Né fa mat hn hap iia a ding vj “*U (99,3%, T = 4.47.10" nam) va ~°U(0,7%, T = 7,04.10* nam). Ca hai déng vj nay déu OTUNE: 84805779904 (WOBILE?ZALO) htlps://daykemquynhonofficial. wordpress com/blog! Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON www.facebook.com/daykem.quynhon https://daykemquynhon. blogspot.com www.facebook.com/daykemquynhonofficial Dong gop PDF béi GV. Nguyén Thanh Ti www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon, anh hung eta sr chuyén hoa 'U kém bén hon **U va phan img dién ra dé dang hon v6i sy tham gia cia notron nhiét. Phan ding phan hach duge din ra du6i day: °SU +n Ut — sim phim phan hach + 2 —3n +200MeW/I hat? hat ot va B sinh ra trong hai chudi phéng xa Ou Pp Giai thich tgi sao trong hai chudi phéng xa mot s6 nguyén t6 hod hoe xuat hign nhicu hon mé Tin, ©) Gia sirring ede ding vj khong Tién quan ban du (hic bi biing voi hugng hai dong vj ca uran 7°U : *U = 1 : 1). Tih di cua quia dat thei He ra khi phan tir hic bat du phan img phan hgch). hach 1g *"U bing notron, Str dung phan ting: C +02 CO) + 393,5ki/mol (hay 4,1eV/nguyén ti). Bai 13: Uran a) **U > ™ Pb: 8 hat ot va 6 hat B "Pb: 7 hat a va hat B nay xay ra khi tigp saw mot phiin 1a o(Z =-2) ki v6i mdi déng vj cia uran ta e6 thé viet b) ©) ‘Tai thoi diém t= O thi *°N, a. Niu vey a we ‘i me Noi bai dung Kién thire Toan - Ly - Hoa cho hge sinh cp 2+3 / Din Ban Toan - Ly - Ha Quy Nhon 1000B Tran Hung Bgo Tp.Quy Nhon Tinh Binh Binh 28y d) Nang lugng sinh 0d ‘Nang Iwong sintt Nhu vay khoi lueng cacbon can se e om hain 1 ho’ toan 1g 49.10" kg C Dong gop PDF béi GV. Nguyén Thanh Ti ) Tinh Iugng cacbon edn (g) dé sinh ra nding Iugng bing v6i nang legng gia © on B(Z=42)lign tigp. gee Neexp(-Aasst) oN Yexp(-Arsst) * s at chay hoan toan 1g U = 2,06.10" MeV THOTUNE "84305779994 (MOBILEZ2AL} htlps://daykemquynhonofficial. wordpress com/blog! Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON www.facebook.com/daykem.quynhon, https://daykemquynhon.blogspot.com phong x9 ova déu duge tao ra 6 eae phan (ing tng hop hat nbn. Sy phan rd ella ching sinh ra ce uong khde nhau cita cde hot ot va B, qua nhieu qua trinh phan ra khde nhaw thi sé dai thanh cfc dng vi bén ”*Pbg va “”’Phyo mot ech twong img, Cac quia trinh nay durge goi LA hai chudi phong xa. Sur phOng xg ot - khong chiu anh husmg eta esc qua trinh phn ra khie nhau ~ KROng chiu www.facebook.com/daykemquynhonofficial www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon . oF BAI TAP TONG HOP PHAN HOA HUU CO Cau 1: 1. Hgp chat A 6 cong thite phan tit CHNO, 6 thé khi, d9 dai lien két CN bang 121 pm (1 pm = 10m), do dai lien két CO bang 117 pm. A tan trong nude tgo thanh dung dich axit vai K, = 1.2. 10%, 60°C, A tbién déi than chat rin X khong tan trong cdc dung moi thong thutmg, do dai lien két CN bing 140 pm, Trong dung dich dac, A ty bién d6i thanh chat rin Y c6 vong 6 canh v6i dQ dai lién ket CN bang 135 pm. Biét d6 dai lien két trung binh 6 ede hgp chat nhu sau: Lienk&t | C-C] C-N ] CO] CN | GO] GN |ecacbonoxit Ss Dodai,pm | 154 | 147 133 30 | 123 | 116 TAS} a. Hay viet cong thiic edu tao ede déng phan tmg véi cong thie phan tit cuno Cone thie no phi hop véi A 6 thé khi, vi sao ? b. Viet cong thifc ediu tao va phutong trinh phan ting dién li ciia A trong dung-dich. c. Hay dé nghi phuong trinh phan tng tao thanh X, Y va cong thie caa{T46 eta chiing. 2. Viet cong thiie ede sin phim c6 thé tao thanh khi thye hign axa d6ng phan hos B (e6 tg ee a cha nS) nigel tet ah: ek ten Me MUNG 8) cha ese ch Aico biét déng phan nao cé tinh quang hoat. B CD & x DAP AN Re . v :{daykemquynhon.ucoz.com Noi bai dung Kién thire Toan - Ly - Hoa cho hge sinh cp 2+3 / Din Ban Toan - Ly - Ha Quy Nhon 1000B Tran Hung Bgo Tp.Quy Nhon Tinh Binh Binh a. Céc déng phan Ss S a HN=C=0 HO—C=NAQ-HO-NEC HCEN>O cn o m Qa avy ” A, dex= 121 pm, trung gian gitta lign két C=N (130 pm) vi C=N (116 pm); deo = 117 pm, trung iat ita lign két C=O (123 pm) va C=O (112 pm). Vay e6ng thie (I) 1a phi hgp hon cé (eacbov trang thai lai hod sp), cOng thie (IV) va (V) Khong phi hop v6i gid tri pK, b. Gid tri K, pos Ion hon ca axit axetic, chimg 16 phan li theo kiéu axit oxi (-O-H) chit khong chi ki exit nity -N -H) do.e6 can bing hé bién va cong huging cau tao — = =NSc—o-n I —_— n=c—o} He HN | (X): d6 1a polime kiéu poliamit nén khé tan, n Dg dai lien két CN (140 pm) [a trung gian gitta lien két doi (130 pm) va lien két don (147 pm). OTUNE: 84805779904 (WOBILE?ZALO) htlps://daykemquynhonofficial. wordpress com/blog! DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM www.facebook.com/daykem.quynhon https://daykemquynhon. blogspot.com www.facebook.com/daykemquynhonofficial Dong gop PDF béi GV. Nguyén Thanh Ti www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon, ‘i me Noi bai dung Kién thire Toan - Ly - Hoa cho hge sinh cp 2+3 / Din Ban Toan - Ly - Ha Quy Nhon 1000B Tran Hung Bgo Tp.Quy Nhon Tinh Binh Binh Dong gop PDF béi GV. Nguyén Thanh Ti O NH HO. LN. OH oN, se a © ro i 3N ‘— OH HIN C=O—nuk NN f oO (Y) bn mY) tgo ra tir dung dich dac nén ket tia thanh chat rin Y, Bo dai lien két CN (135 pm) ldn han CN 6 lip (khong thom, 130 pm) nhur vay Y phat hop hon Y. 2. C64 déng phan a A — SS RS cis, trans Quang hoat Cau 2. (2) lysergic theo ba gi Giai doan 1: CoN Hexandial —+ 2-cacbetoxixiclopentanon —— cy By Hay vigt so d6 phin tng thye hign ce chuyén h&MA— B va BC. Giai doan 2 i CaHsCOCVOH , SOC 2 He BryCH,COOH a. Hay viet cong thie edu tao cla B, PYG, H vad. b. Trinh bay ex che cia phan vingyG—> H. Giai doan 3 a r/c HOOK CHANH, (ony :co™™ H. Ly CHEE, buy Sou, w NiJ/natri arsenat HON axit (4) lysergic viét cong thie cau two cia K, L, M,N, P va Q. thich tai sao phai chuyén K thanh L. va néu ban chat ctia phan img P > Q. Viet cong thifc cau tao ciia W va néu cach téng hop W tir Q. LAB HO COOH a ao oxi hod este hod ‘OH 0 OTUNE: 84805779904 (WOBILE?ZALO) htlps://daykemquynhonofficial. wordpress com/blog! Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON www.facebook.com/daykem.quynhon https://daykemquynhon. blogspot.com www.facebook.com/daykemquynhonofficial www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon plus.google.com/+DayKémQuyNhon, Boc CoHsNH2 + NaNOz + HC —2°S > CysNZCL COOC:Hs GotisNF C1 — ——* OH 2. a Hi b. Corché phan ting G > Hla S.2Ar ©, Lo Preo-sy ore Ad bocaits BY K — CH3COCH.Br http://daykeme Noi bai dung Kién thire Toan - Ly - Hoa cho hge sinh cp 2+3 / Din Ban Toan - Ly - Ha Quy Nhon 1000B Tran Hung Bgo Tp.Quy Nhon Tinh Binh Binh B coon “CH IN www.facebook.com/daykem.quynhon https://daykemquynhon. blogspot.com Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM THOTUNE "84305779994 (MOBILEZ2AL} htlps://daykemquynhonofficial. wordpress com/blog! DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON oat K thanh L dé bio vé nhém che C=O hit cia phiin tmg P + Q 1a ngung tu croton noi phan tir (déng vong) va thuy phan amit. Chuyén hod Q > W c6 thé lim nhiéu cach, mign sao hgp Ii. Thi dy : khi¢ CO ancol — dain xudt halogen —> cg magie cacbonyl hod bing CO,—> thuy phan. Dong gép PDF béi GV. Nguyén Thanh Ta www.facebook.com/daykemquynhonofficial www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon www.facebook.com/daykem.quynhon plus.google.com/+DayKémQuyNhon https://daykemquynhon.blogspot.com Cau 3: Cho 2-cabetoxixiclopentanon phan ting véi 1,3-dibrompropan khi cé mat NaH trong DMEF. Sin phim A nhan duge durge dun néng véi mot duong lugng NaH trong hén hgp benzen - DME cho phép thu duge din xuat bixiclic B, C,,H\Os. B chu téc dung ciia etandithiol khi ¢6 mat BF, va Ni Raney trong metanol dé hinh thanh san phim C. Xa phng hod C bang NaOH, sau d6 thuy phan réi xit If véi thionyl clorua va cudi cing, bing NaN, trong axeton. Dun héi luu hén hgp trén khi c6 mat vét axit H” sé thu duge D, C,H)sN. Bang tac dung cita fomandehit trong axit fomic 6 100°C, D chuyén thanh E. Sau khi xir ICE bang metyl iodua, sau dé bang Ag,O trong nuGe, dun sin phim thu duge 6 200°C khi c6 1,3-diphenylisobenzofuran ngudi ta sé nhan duge hai déng phan C,.H,,0 14 (1) va (11) v6i suit thap. 1, Hay xéc dinh cOng thite ediu tric ctia cdc hop chat tren, 2. Trinh bay co ché cia qué trinh A Bva DE. fly dua ra ech tng hgp 2-cacbetoxixiclopentanon bing phuong phap ngdin n 1. 9 0 o Mie coors cry Ww 1 wat 2 BrcCHy)sBr | ‘COOEL A “nity at, Ea “aon “coors HCHO. Ltt hood OOOH icine 2 re ar CO) r me Noi bai dung Kién thire Toan - Ly - Hoa cho hge sinh cp 2+3 / Din Ban Toan - Ly - Ha Quy Nhon 1000B Tran Hung Bgo Tp.Quy Nhon Tinh Binh Binh OTUNE: 84805779904 (WOBILE?ZALO) Zz | Z & Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM Py fi 2. Coch RS TWA tao oF htlps://daykemquynhonofficial. wordpress com/blog! DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON TirD tao thanh E new RNH; MO, gxricroH sit» RNSCH, > RNIECH + CO: Ki bgot 8 www.facebook.com/daykemquynhonofficial Dong gop PDF béi GV. Nguyén Thanh Ti www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon www.facebook.com/daykem.quynhon plus.google. rere http: iam yep http://daykeme Noi bai dung Kién thire Toan - Ly - Hoa cho hge sinh cp 2+3 / Din Ban Toan - Ly - Ha Quy Nhon 1000B Tran Hung Bgo Tp.Quy Nhon Tinh Binh Binh _. AS HON (om “ (e000 _ C00 COOEL COOEt Cau 4: 1. Cho 8-metyinona-5,8-dienal tc dung v6i xiclohexan-1,3-dion (theo ti 1é mol 1 : 1) trong moi trang kiém duge chit A, CisH,O»- Dun néng A thu duge hon hop B gém ec chit 1k dng phag > ca nhau c6 cong thie phan tit CHO. . Viet cong thiic cau tgo cia A va cae chat trong B. A b. Chi r0 cae trung tam bat di trong phan tit cdc chat tren x» 2. Tir mety xiclopropyl xeton va hop chat cor magie wy ¥ chon, vigt so dé me 2,6-dimetyl-9-bromnona-2,6-dien. 3. Thue hign day chuyén hod sau: on Hiéu che 1. NaOH 2-cHCO , BR AICls (A 66 lién két hidro ndi phan tt). Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM THOTUNE "84305779994 (MOBILEZ2AL} htlps://daykemquynhonofficial. wordpress com/blog! DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON www.facebook.com/daykemquynhonofficial Dong gép PDF béi GV. Nguyén Thanh Ta www.facebook.com/boiduonghoahocquynhonofficialhttps://twitter.com/daykemquynhon www.facebook.com/daykem.quynhon plus.google.com/+DayKémQuyNhon https://daykemquynhon. blogspot.com | f ° 8 5 4 2 Eto Rm mene Wo HK pes Dlg Hs 1 Mg HH 2 not e Hs _Hbe Oo crncHscHce TP BS Br cHaCHaCH=* mies + — CH -OMgbr | 18O= I> = CH-CH z thu phan [ CHy=CH-CHy-CHy-CH=CH-OH ] 22h, yy, CH.CHy-CH)-CH»-CH-O. c Hoac CH-CH-CE Mabey ecuGe ame rT CH-CH-CHL-CH-CH=CH, EEA CH=CH.CHy FH ais CH. ww BOMep | MEROND c r [Cy | “HO big Cn CHL SS on] soa Ce o oO Ho, Cos vetiae H ee Cols E On Ov F cé cfiu hinh (E) bén hom. Tuy vay. phin tig cing tgo thinh mot lugnieah Cau 6 Khi nhiet phan cac hgp chat (A), (B), (©), (D) ngudi ta ce sin phim khée nhau, Hay viet cong thie va tén sin phém; giai thich (ding mii tén gong) vi sao c6 su tao thanh céic sin phdm dé 1. (A) CH,CH,COOCH,CH,CH,CH, SS 2. (B) CHCH,],CH(OHNCH,CH=CH{CH.},COOr PS 3. (C) (CH,),CCH(CH,)OCSSCH, 4. (D) CH,[CH,],C(OH)(CH,)CH.CH=CH[CH,],COOCH(CH,)[CH.1,CH, Huéng din gidi 1. CH,CH,COOCH.CH,CH. 16°F c6 cau hinh (Z). it propanoic OTUNE: 84805779904 (WOBILE?ZALO) htlps://daykemquynhonofficial. wordpress com/blog! DAY KEM QUY NHON OFFICIAL ST> : BIC 10008 TRAN HUNG DAO TP_QUY NHON Co ché vong trung gian 6 canh, eu Hy, Heer ° & ——* GH;COOH + CH3=CHCH,CH; Ye I-GHs .CH,[CH,},CH(OH)CH,CH=CH[CH,,COOH — ~ — CH,[CH,];CHO + CH,=CH[CH,],COOH Heptanal Axit undex-10-enoic Ca ché voneng ian 6 canh, tach Hp.on ls ween oe oD |, Sifeni,coon Mol YEU CAU GUT VE HOP MAIL DAYKEMGUYNHONGUSINESS@GMAL COM 8» cufon.cn-0 + cHcH[CH],cooH 3. (CHy),CCH(CH,)OCSSCH; "> (CH,,)CCH=CH, + OCS + CHSH 3,3-Dimetylbut-I-en Cacbonsunfuaoxit Metanthiol Co che vong trung gian 6 canh, tich Hy WD (Sch (CH3)3C nese ™ (CH3);CCH=CH, + OCS +CH;SH 4. CH,[CH,],C(OH)(CH,)CH,CH=CHICH,],COOCH(CH,)[CH,],CH; www.facebook.com/daykemquynhonofficial Dong gop PDF béi GV. Nguyén Thanh Ti www.facebook.com/boiduonghoahocquynhonofficial