KHOA: QUỐC TẾ CỘNG HÒA XÃ HỘI CHỦ NGHĨA VIỆT NAM

BỘ MÔN: KHOA HỌC TỰ NHIÊN Độc lập – Tự do – Hạnh phúc

NGÂN HÀNG CÂU HỎI THI

Tên học phần: Hoá đại cương Mã học phần: CHE 101
Số tín chỉ: 03 Hình thức thi: Trắc nghiệm
Học kỳ: 3 Năm học: 2023 - 2024

Chapter 1. Matter, Measurement, and Problem-Solving

Which of the following as a law? (Choose only one correct answer)

a. If elements are listed in order of increasing mass of their atoms, their chemical
reactivity follows are pleating pattern.
b. Chlorine is a highly reactive gas.
c. No change in the total mass of material within the container during
combustion
d. There activity of elements depends on the arrangement of their electrons.

Which of the following as a theory ? (Choose only one correct answer)

a. If elements are listed in order of increasing mass of their atoms, their chemical
reactivity follows are pleating pattern.
b. There activity of elements depends on the arrangement of their electrons.
c. No change in the total mass of material within the container during
combustion
d. Chlorine is a highly reactive gas.

A chemist mixes sodium with water and witnesses a violent reaction between the
metal and water. What is this best classified?
a. a hypothesis b. a law c. an observation d. a
theory
Which of the following as a pure compound?
a. iron b. beef stew
c. carbon monoxide d. wine

Which of the following as a homogeneous mixture?

a. beef stew b. wine
c. iron d. carbon monoxide

Which of the following as heterogeneous mixture?

a b

c d

Which of the following properties as chemical?

a. The tendency of iron to rust
b. The temperature at which dry ice evaporates
c. The boiling point of ethyl alcohol
d. The color of gold

Which of the following changes as physical?

a. A platinum ring becomes dull because of continued abrasion.
b. Ozone decomposes on exposure to ultraviolet light
c. Sugar burns when heated on a skillet
d. A silver surface becomes tarnished after exposure to air for a long period of
time

Which property of rubbing alcohol is a chemical property?

a. its flammability b. its density (0.786 g>cm3)
c. its boiling point (82.5 °C) d. its melting point (-89 °C)

What is the mass of a 1.75 L sample of a liquid that has a density of

0.921g/mL?
a. 1.90 x 103 g b. 1.61 x 10-3 g c. 1.61 x 103 g d. 1.90 x 10-3 g

A titanium bicycle frame displaces 0.314 L of water and has a mass of 1.41 kg.
What is the density of the titanium in g/cm3?
a. 5.29 g/cm3 b. 3.49 g/cm3
c. 4.49 g/cm3 d. 2.39 g/cm3

A piece of metal is tested to determine its density. It is found to displace 19.3

mL of water and has a mass of 371 grams. What is the metal?
a. Gold b. Zinc c. Iron d. Silver
Ethylene glycol (antifreeze) has a density of 1.11 g/cm 3. What is the mass in g of
417 mL of this liquid?
a. 463 g b. 453 g c. 363 g d. 263 g

Acetone (nail polish remover) has a density of 0.7857 g/cm3. What is the mass
in g of 28.56 mL of acetone?
a. 25.29 g b. 21.49 g c. 22.44 g d. 23.39 g

Acetone (nail polish remover) has a density of 0.7857 g/cm3. What is the
volume, in mL, of 6.54 g of acetone?
 a. 9.44 mL b. 8.32 mL c. 7.31 mL d. 6.38 mL

Which the following numbers has one significant zero?

a. 0.005710 mi b. 0.001040 m
c. 180,701 km d. 90,201 m

Which the following number has unlimited number of significant figures?

a. 10 dm = 1 m b. 0.007 m
c. 0.1111 s d. 1.563300 x1011 m

Which the following number has ambiguous significant figures?

a. 1.0201 x105 b. 0.0261 m
c. 5.200 cm2 d. 30,800 m

Which the following numbers has three significant figures?

a. 2.54 cm = 1 in b. 11.4 g/cm3 (density of lead)
c. 284,796,887 (2001 U.S. population) d. 12 = 1 dozen

The density of titanium is 4.51 g/cm 3. What is the volume (in cubic inches) of
3.5 lb of titanium?
a. 22 in3 b. 12 in3 c. 32 in3 d. 20 in3

The proton has a radius of approximately 1.0 x 10 -13 cm and a mass of 1.7 x 10 -24
g. What is the density of a proton (for a sphere V = (4/3)πr3)?
a. 0.78x 1015 g/cm3 b. 0.34x 1015 g/cm3
c. 0.63x 1015 g/cm3 d. 0.41x 1015 g/cm3

A solid metal sphere has a radius of 3.53 cm and a mass of 1.796 kg. What is the
density of the metal in g/cm3? (The volume of sphere is V = 4/3πr3.)
a. 9.75 g/cm3 b. 0.103 g/cm3 c. 121 g/cm3 d. 34.4 g/cm3
Glycerol is a syrupy liquid often used in cosmetics and soaps. A 3.25 L sample
of pure glycerol has a mass of 4.10 x 10 3 g. What is the density of glycerol in
g/cm3?
a. 1.26 g/cm3 b. 1.36 g/cm3 c. 1.16 g/cm3 d. 1.46 g/cm3

The density of iron is 7.86 g/cm3. What is its density in pounds per cubic inch
(lb/in3)? (1 lb = 453.59 g; 1 in = 2.54 cm)
a. 0.214 lb/in3 b. 0.365 lb/in3
c. 0.284 lb/in3 d. 0.584 lb/in3

A solid aluminum sphere has a mass of 85 g and the density of aluminum is 2.70
g/cm3. What is the radius of the sphere in cm?
a. 1.96 cm b. 0.96 cm c. 1.57 cm d. 1.26 cm

An iceberg has a volume of 7655 cm 3, the density of ice: d = 0.997 g/cm 3. What
is the mass of the ice (in kg) composing the iceberg?
a. 7.632 kg b. 4.632 kg c. 5.786 kg d. 9.543 kg

A small airplane takes on 245 L of fuel. If the density of the fuel is 0.821 g/mL,
what mass of fuel has the airplane taken on?
a. 201 x 103 g b. 101 x 103 g c. 301 x 103 g 102 x 103 g

A backyard swimming pool holds 185 cubic yards (yd3) of water. What is the
mass of the water in pounds?
a. 3.11 x 105 lb b. 2.11 x 105 lb c. 1.11 x 105 lb d. 4.11 x 105 lb

The Honda Insight, a hybrid electric vehicle, has an EPA gas mileage rating of
57 mi/gal in the city. How many kilometers can the Insight travel on the amount
of gasoline that would fit in a soda pop can? The volume of a soda pop can is
355 mL, 1 gl = 3.785 L, 1 km = 0.6214 mi
a. 8.6 km b. 8.3 km c. 7.6 km d. 5.3 km

A sample of gaseous neon atoms at atmospheric pressure and 0 °C contains 2.69

x 1022 atoms. The atomic radius of neon is 69 pm. What is the total volume of
the neon atoms?
a. 3.69 x10-8 L b. 1.53 x10-8 L c. 2.69x10-8 L d. 4.53 x10-8 L

Chapter 2. Atoms and Elements Modern Atomic Theory

2.1.0,25.37. An automobile gasoline tank holds 21 kg of gasoline. When the

gasoline burns, 84 kg of oxygen is consumed, carbon dioxide and water are
produced. What is the total combined mass of carbon dioxide and water that is
produced?
a. 100 kg b. 105 kg c. 120 kg d. 135 kg
2.1.0,25.38. Upon decomposition, one sample of magnesium fluoride produced
1.65 kg of magnesium and 2.57 kg of fluorine. A second sample produced 1.32
kg of magnesium. How much fluorine (in grams) did the second sample
produce?
a. 3.215 b. 2.056 c. 2.015 d. 3.056
2.1.0,25.39. Two samples of a compound containing elements A and B were
decomposed. The first sample produced 15 g of A and 35 g of B. The second
sample produced 25 g of A and what mass of B?
a. 21.3 g b. 11.3 g c. 58.3 g d. 45.3 g
2.1.0,25.40. A compound containing only carbon and hydrogen has a carbon-to-
hydrogen mass ratio of 11.89. Which carbon-to-hydrogen mass ratio is possible
for another compound composed only of carbon and hydrogen?
a. 3.97 b. 2.50 c. 4.66 d. 7.89
2.1.0,25.41. The mass ratio of sodium to fluorine in sodium fluoride is 1.21:1. A
sample of sodium fluoride produces 28.8 g of sodium upon decomposition. How
much fluorine (in grams) is formed?
a. 20.8 g b. 22.8 g c. 21.8 g d. 23.8 g
2.1.0,25.42. Sulfur and oxygen form sulfur trioxide. When the sulfur trioxide
was decomposed, it produced 6.75 g oxygen and 4.50 g sulfur. Calculate the
mass of oxygen per gram of sulfur in sulfur trioxide?
a. 1.5 g O2/ 1.0 g S b. 1.3 g O2/ 1.0 g S
c. 1.1 g O2/ 1.0 g S d. 1.0 g O2/ 1.0 g S
2.1.0,25.45. Which of the following statements is inconsistent with Dalton’s
atomic theory as it was originally stated?
a. Two oxygen atoms combine with a carbon atom to form a carbon dioxide
molecule.
b. All carbon atoms are identical.
c. An oxygen atom combines with 1.5 hydrogen atoms to form a water
molecule.
d. The formation of a compound often involves the destruction of one or more
atoms.
2.1.0,25.46. Which of the following statements is consistent with Ruther- ford’s
nuclear theory as it was originally stated?
a. A nitrogen atom has seven protons in its nucleus and seven electrons outside
of its nucleus.
b. Since electrons are smaller than protons, and since a hydrogen atom contains
only one proton and one electron, it must follow that the volume of a hydrogen
atom is mostly due to the proton.
c. A phosphorus atom has 15 protons in its nucleus and 150 electrons outside of
its nucleus.
d. The majority of the mass of a fluorine atom is due to its nine electrons.
2.1.0,25.47. Imagine a unit of charge called the zorg (z). A chemist performs the
oil drop experiment and measures the charge of the drop in zorgs. The result
shows that the charge of the drop is - 9.6 x 10 -9 z. How many electrons are in
drop (the charge of the electron is -1.6 x 10-9 z)?
a. 7 b. 6 c. 5 d. 9
2.1.0,25.48. How many electrons are necessary to produce a charge of -1.0 C?
a. 6.2 x 1020 b. 3.4 x 1020 c. 5.2 x 1020 d. 4.3 x 1020
2.2.0,25.49. Which of the following statement about subatomic particles is
false?
a. Protons and electrons have charges of the same magnitude but opposite sign.
b. Protons have about the same mass as neutrons.
c. Some atoms don’t have any protons.
d. The charge of neutron is zero
2.2.0,25.50. A helium nucleus has two protons and two neutrons. How many
electrons would it take to equal the mass of a helium nucleus?
a. 7.33 ×103 b. 5.32 x 103 c. 6.23 x 10 3 d. 8.63 x 10 3
2.2.0,25.51. Which of the following isotope has 145 neutrons?
a. 19 9F b. 4018Ar c. 31 15P d. 239 94Pu
2.2.0,25.52. Which of the following isotope has 88 protons and 138 neutrons?
a. 22688Ra b. 4019K c. 9943Tc d. 3115P
2.2.0,25.53. Uranium-235 is used in nuclear fission. What is the symbol in the
form AZX of uranium-235?
a. 235 90U b. 235 92U c. 230 92U d. 230 90U
2.2.0,25.54. Which of the following ion has 34 protons and 36 electrons?
a. Se2- b. Al3+ c. Ga3+ d. Sr2+
2.2.0,25.55. Which of the following pairs of elements do you expect to be most
similar?
a. nitrogen and oxygen b. argon and bromine
c. lithium and sodium d. germanium and arsenic
2.2.0,25.56. Which pair of elements do you expect to be most similar in their
chemical properties?
a. Br and I b. O and Si c. Ne and N d. K and Fe
2.2.0,25.59. Which sample contains the greatest number of atoms?
a. 202 g Pb b. 49 g Cr c. 102 g Ag d. 14 g C
2.2.0,25.60. Determine the number of atoms in 1.85 mL of mercury. (The
density of mercury is 13.5 g/mL)
a. 7.50 x 1027 atoms b. 4.11 x 1020 atoms
c. 3.02 x 1022 atoms d. 1.50 x 1025 atoms
2.3.0,25.61. The ratio of oxygen to carbon by mass in carbon monoxide is
1.33:1.00. Find the formula of an oxide of carbon in which the ratio by mass of
oxygen to carbon is 2.00:1.00
a. C2O b. C2O3 c. CO2 d. CO
2.3.0,25.62. How many moles of aluminum do 5.8 x 10 24 aluminum atoms
represent?
a. 9.6 mol b. 8.6 mol c. 9.2 mol d. 6.8 mol
2.3.0,25.63. What is the mass of 4.91 x 1021 platinum atoms?
 a. 1.59 g b. 2.59 g c. 1.50 g d. 0.59 g
2.3.0,25.64. How many helium atoms are there in a helium blimp containing 536
kg of helium?
a. 7.44 x 1020 atoms b. 6.06 x 1028 atoms
c. 8.06 x 1028 atoms d. 5.44 x 1020 atoms
2.3.0,25.65. Lithium has only two naturally occurring isotopes. The mass of
lithium-6 is 6.01512 amu and the mass of lithium-7 is 7.01601 amu. Calculate
the relative abundances of the two isotopes?
a. Li-6: 7.594 %; Li-7: 92.406 % b. Li-6: 92.406 %; Li-7: 7.594 %
c. Li-6: 7.0 %; Li-7: 93.0 % d. Li-6: 6.494 %; Li-7: 93.506 %
2.3.0,25.66. Silver is composed of two naturally occurring isotopes: Ag-107
(51.839%) and Ag-109. The ratio of the masses of the two isotopes is 1.0187.
What is the mass of Ag-107?
a. 91.96 amu b. 96.91 amu c. 100.91 amu d. 106.91 amu
2.3.0,25.67. A 7.83 g sample of HCN contains 0.290 g of H and 4.06 g of N.
Find the mass of carbon in a sample of HCN with a mass of 3.37 g?
a. 1.5 g b. 0.5 g c. 1.3 g d. 0.8 g
2.3.0,25.68. Using scanning tunneling microscopy, scientists at IBM wrote the
initials of their company with 35 individual xenon atoms (as shown below).
What is the total mass of these letters in grams?

a. 7.6 x 10-21 g b. 6.7 x 10-21 g

c. 6.7 x 1021 g d. 7.6 x 1021 g
2.3.0,25.69. Naturally occurring iodine has an atomic mass of 126.9045 amu. A
12.3849 g sample of naturally occurring iodine is accidentally contaminated
with an additional 1.00070 g of 129I, a synthetic radio isotope of iodine used in
the treatment of certain diseases of the thyroid gland. The mass of 129I is
128.9050 amu. What is the apparent “atomic mass” of the contaminated iodine?
a. 120.06 amu b. 127.06 amu c. 125.06 amu d. 120.26 amu
2.3.0,25.72. Boron has only two naturally occurring isotopes. The mass of
boron-10 is 10.01294 amu and the mass of boron-11 is 11.00931 amu. Use the
atomic mass of boron to calculate the relative abundances of the two isotopes.
a. % boron-10 is 22% ; % boron-11 is 78%
b. % boron-10 is 80% ; % boron-11 is 20%
c. % boron-10 is 21% ; % boron-11 is 79%
d. % boron-10 is 20% ; % boron-11 is 80%

Chapter 3. Compounds
3.1.0,25.73. Which of the following elements have molecules as their basic
units?
a. lead b. iodine c. hydrogen d. oxygen
3.1.0,25.74. Which of the following compounds as ionic?
a. PtO2 b. CCl4 c. CF2Cl2 d. SO3
3.1.0,25.75. Which substance is an ionic compound?
a. CCl4 b. N2O4 c. He d. SrI2

3.1.0,25.78. What is the formula for manganese(IV) oxide?

a. MnO2 b. MnO4 c. Mn2O d. Mn4O
3.1.0,25.79. Which of the following formulas has the name “Strontium cloride”?
a. SrCl2 b. SrCl c. Sr2Cl2 d. Sr2Cl
3.1.0,25.80. Which of the following formulas has the name “Potassium
hypochlorite”?
a. K2ClO b. KClO2 c. KClO d. K(ClO)2
3.1.0,25.81. Which of the following names corresponds to the formula “P2I4”?
a. diphosphorus tetraiodide b. phosphorus diiodide
c. phosphorus(II) iodide d. phosphorus iodide
3.1.0,25.82. Which of the following names corresponds to the formula
“PbCrO4”?
a. Lead chromate b. Lead(I)chromate
c. Lead(II) chromate d. Lead(II) chromic
3.1.0,25.83. Which of the following names corresponds to the formula “XeO3”?
a. Xenon trioxide b. Xenon dioxide
c. Xenon oxide d. Xenon monooxide
3.2.0,25.84. Which of the following names corresponds to the formula
“HClO2”?
a. Chloric acid b. Chlorous acid
c. Hydrochlorous acid d. Hydrochloric acid
3.2.0,25.85. What is the mass (in g) of 5.94 x 1020 SO3 molecules?
a. 0.079 g b. 0.039 g c. 0.019 g d. 0.239 g
3.2.0,25.86. What is the mass (in g) of a single glucose molecule (C6H12O6)
a. 175.156 g b. 185.156 g c. 170.156 g d. 180.156 g
3.2.0,25.87. A salt crystal has a mass of 0.12 mg. How many NaCl formula units
does it contain?
a. 12.36 x 1017 b. 20.36 x 1017 xc. 9.36 x 1017 d.22.36 x 1017
3.2.0,25.88. Determine the number of CH2Cl2 molecules in 25.0 g CH2Cl2
a. 1.77 x 1023 molecules b. 0.294 molecules
27
c. 1.28 x 10 molecules d. 1.51 x 1025 molecules
3.2.0,25.91. Iron is mined from the Earth as iron ore. Common ores include
Fe2O3 (hematite), Fe3O4 (magnetite), and FeCO3 (siderite). What are the mass
percent composition of iron for Fe2O3, Fe3O4 and FeCO3, respectively?
a. 60.94%, 72,36%, 48,20% b. 69.94%, 72,36%, 48,20%
c. 69.94%, 62,36%, 48,20% d. 69.94%, 72,36%, 40,20%
3.2.0,25.92. Silver chloride, often used in silver plating, contains 75.27% Ag.
What is the mass of silver chloride required to plate 155 mg of pure silver?
a. 206 mg b. 106 mg c. 96 mg d. 86 mg
3.2.0,25.93. The American Dental Association recommends that an adult female
should consume 3.0 mg of fluoride (F-) per day to prevent tooth decay. If the
fluoride is consumed as sodium fluoride (45.24% F), what amount of sodium
fluoride contains the recommended amount of fluoride?
a. 8.23 mg b. 5.63 mg c. 6.63 mg d. 7.23 mg
3.2.0,25.94. A compound is 52.14% C, 13.13% H, and 34.73% O by mass. What
is the empirical formula of the compound?
a. C2H6O b. C2H8O3 c. C4HO3 d. C3HO6
3.2.0,25.95. How many number of moles of oxygen atom in 4.48 mol H2O2?
a. 8.96 mol O b. 4.48 mol O c. 8.96 mol O2 d. 4.48 mol O2
3.3.0,25.96. How many kilograms of chlorine are in 25 kg of C2F2Cl3?
a. 13.29 kg b. 18.29 kg c. 19.79 kg d. 15.79 kg
3.3.0,25.97. Calculate mass (in grams) of sodium in 8.5 g of NaC 7H5O2 (sodium
benzoate)
a. 1.4 g b. 0.4 g c. 2.4 g d. 2.1 g
3.3.0,25.98. Methyl butyrate (component of apple taste and smell) has the
elemental mass percent composition : C 58.80%, H 9.87%, O 31.33%. What is
the empirical formula for methyl butyrate?
a. C2H5O b. C5H10O2 c. C6H10O2 d. C5H5O
3.3.0,25.99. Vanillin (responsible for the taste and smell of vanilla) has the
elemental mass percent composition : C 63.15%, H 5.30%, O 31.55%. What is
the empirical formula for vanillin?
a. C8H8O3 b. C8H8O c. C6H10O2 d. C8H10O2
3.3.0,25.100. The empirical formula and molar mass of compound are CCl and
284.77 g/mol. What is the molecular formula of this compound?
a. C2Cl4 b. C2Cl6 c. C6Cl6 d. CCl4
3.3.0,25.101. Combustion analysis of a 13.42 g sample of equilin (which
contains only carbon, hydrogen, and oxygen) produces 39.61 g CO2 and 9.01 g
H2O. The molar mass of equilin is 268.34 g/mol. Find its molecular formula?
a. C18H20O2 b. C18H19O3 c. C18H16O2 d. C16H20 O2
3.3.0,25.102. Combustion of 30.42 g of a compound containing only carbon,
hydrogen, and oxygen produces 35.21 g CO2 and 14.42 g H2O. What is the
empirical formula of the compound?
a. C4H8O6 b. C2H4O3 c. C2H2O3 d. C6HO12
3.3.0,25.103. Combustion analysis of naphthalene, a hydrocarbon used in
mothballs, produced 8.80 g CO2 and 1.44 g H2O. What is the empirical formula
for naphthalene?
a. C2H4 b. CH4 c. C5H6 d. C5H4
3.3.0,25.106. A Freon leak in the air-conditioning system of an old car releases
25 g of CF2Cl2 per month. What mass of chlorine does this car emit into the
atmosphere each year?
a. 1.4 x 102 g b. 1.5 x 102 g c. 1.8 x 102 g d. 1.3 x 102 g
3.3.0,25.107. The chloride of an unknown metal is believed to have the formula
MCl3. A 2.395 g sample of the compound is found to contain 3.606 x 10 -2 mol
Cl. Find the atomic mass of M.
a. 92.9 amu b. 90.1 amu c. 82.8 amu c. 95.6 amu
3.3.0,25.108. A metal (M) forms a compound with the formula MCl 3. If the
compound contains 65.57% Cl by mass, what is the identity of the metal?
a. Cu b. Fe c. Zn d. Co
3.3.0,25.109. Tartaric acid is the white, powdery substance that coats sour
candies such as Sour Patch Kids. Combustion analysis of a 12.01 g sample of
tartaric acid, which contains only carbon, hydrogen, and oxygen produced 14.08
g CO2 and 4.32 g H2O. What is the empirical formula for tartaric acid?
a. C2H3O3 b. C2H5O3 c. CH3O3 d. C2H3O
3.3.0,25.110. A drop of water has a volume of approximately 0.05 mL. How
many water molecules does it contain? The density of water is 1.0 g/cm 3
a. 26.12 x 1020 b. 26.71 x 1020 c. 16.11 x 1020 d. 16.71 x 1020
3.3.0,25.111. A Freon leak in the air-conditioning system of a large building
releases 12 kg of CHF2Cl per month. If the leak were allowed to continue, how
many kilograms of Cl would be emitted into the atmosphere each year?
a. 59.04 kg b. 58.29 kg c. 59.79 kg d. 59.04 kg
3.3.0,25.112. Fructose is a common sugar found in fruit. Elemental analysis of
fructose gave the following mass percent composition: C 40.00%, H 6.72%, O
53.28%. The molar mass of fructose is 180.16 g/mol. What is the molecular
formula of fructose?
a. C5H12O5 b. C6H12O5 c. C6H12O6 d. C5H10O5

Chapter 4. Chemical Quantities and Aqueous Reactions

4.1.0,25.113. Which is the following compound is nonelectrolyte?
a. C12H22O11 b. MgBr2 c. Na2CO3 d. KOH
4.1.0,25.114. Which is the following compound is insoluble in water?
a. AgNO3 b. Cu3(PO4)2 c. CoCl2 d. K3PO4
4.1.0,25.115. Which solution will form a precipitate when mixed with a solution
of aqueous Na2CO3?
a. CuCl2(aq) b. NaBr(aq) c. NH4Cl(aq) d. KNO3(aq)
4.1.0,25.116. What is the net ionic equation for the reaction that occurs when
aqueous solutions of KOH and SrCl2 are mixed?
a. K+(aq) + Cl-(aq) → KCl(s)
b. Sr2+(aq) + 2 OH-(aq) → Sr(OH)2(s)
 c. H+(aq) + OH-(aq) → H2O(l)
d. None of the above because no reaction occurs
4.1.0,25.117. What is the net ionic equation for the reaction that occurs when
aqueous solutions of KOH and HNO3 are mixed?
a. H+(aq) + OH-(aq) → H2O(l)
b. NO3(aq)- + OH-(aq) → NO3OH(s)
c. K+(aq) + NO-3(aq) → KNO3(s)
d. None of the above because no reaction occurs
4.1.0,25.120. What is the net ionic equation for the reaction that occurs when
aqueous solutions of AgNO3 and NaCl are mixed?
a. Ag+ (aq) + Cl-(aq) → AgCl(s)
b. NO3-(aq) + Na+(aq) → NaNO3(aq)
c. Na+(aq) + Cl-(aq) → NaCl(aq)
d. None of the above because no reaction occurs.
4.1.0,25.121. What is the oxidation state of Cl in ClO4-?
a. + 1 b. +3 c. + 7 d. +5
4.1.0,25.122. Manganese (IV) oxide reacts with aluminum to form elemental
manganese and aluminum oxide:
3 MnO2 + 4 Al → 3Mn + 2 Al2O3
What mass of Al is required to completely react with 25.0 g MnO2?
a. 10.3 g Al b. 5.82 g Al c. 33.3 g Al d.7.76 g Al
4.1.0,25.123. Calculate the theoretical yield of the product (in moles) with an
initial amount of reactants including 12.4 mol of Ti and 18.8 mol of Cl2?
Ti(s) + 2 Cl2(g) → TiCl4(s)
a. 9.4 mol b. 8.4 mol c. 7.4 mol d. 6.4 mol
4.2.0,25.124. A reaction has a theoretical yield of 45.8 g. When the reaction is
carried out, 37.2 g of the product is obtained. What is the percent yield?
a. 123% b. 44.8% c. 81.2 % d. 55.1%
4.2.0,25.125. For the reaction shown, calculate the theoretical yield of product
(in grams) with an initial amount of reactants including 2.0 g of Al and 2.0 g of
Cl2
2 Al(s) + 3 Cl2(g) → 2 AlCl3(s)
a. 2.5 g b. 1.5 g c. 3.5 g d. 0.5 g
4.2.0,25.126. A laboratory procedure calls for making 400.0 mL of a 1.1 M
NaNO3 solution. What mass of NaNO3 (in g) is needed?
a. 37 g b. 27 g c. 17 g d. 10 g
4.2.0,25.127. Aluminum reacts with silver ion according to the reaction:
Al(s) + 3 Ag+(aq) = Al3+(aq) + 3 Ag(s)
Identify the oxidizing agent?
a. Ag(s) b. Al(s) c. Al3+(aq) d. Ag+(aq)
4.2.0,25.130. Sulfuric acid dissolves aluminum metal according to the following
reaction:
2Al(s) + 3H2SO4(aq) = Al2(SO4)3(aq) + 3H2(g)
Suppose you wanted to dissolve an aluminum block with a mass of 15.2 g. What
minimum mass of H2SO4 (in g) would you need?
a. 80.1 g b. 82.9 g c. 72.9 g d. 70.1 g
4.2.0,25.131. Sulfuric acid dissolves aluminum metal according to the following
reaction:
2Al(s) + 3H2SO4(aq) = Al2(SO4)3(aq) + 3H2(g)
Suppose you wanted to dissolve an aluminum block with a mass of 15.2 g. What
mass of H2 gas (in g) would be produced by the complete reaction of the
aluminum block?
a. 1.70 g b. 1.79 g c. 1.60 g d. 1.75 g
4.2.0,25.132. Consider the precipitation reaction:
2 Na3PO4(aq) + 3 CuCl2(aq) → Cu3(PO4)2(s) + 6 NaCl(aq)
What volume of 0.175 M Na3PO4 solution is necessary to completely react with
95.4 mL of 0.102 M CuCl2?
a. 37.1 mL b. 30.1 mL c. 27.1 mL d. 20.1 mL
4.2.0,25.133. Sulfur and fluorine react to form sulfur hexafluoride:
S(s) + 3 F2(g) → SF6(g)
If 50.0 g S is allowed to react as completely as possible with 105.0 g F 2(g), what
mass of the excess reactant is left?
a. 15.0 g S b. 45.7 g F2 c. 20.5 g S d. 36.3 g F2
4.2.0,25.134. For the reaction shown, calculate the mass (in grams) of the
product formed when 10.4 g of the O 2 completely reacts. Assume that there is
more than enough of the other reactant.
4Cr(s) + 3O2(g) = 2Cr2O3(s)
 a. 32.93 g b. 23.93 g c. 20.90 g d. 30.90 g
4.3.0,25.135. Potassium iodide reacts with lead(II) nitrate in the following
precipitation reaction:
2 KI(aq) + Pb(NO3)2(aq) → 2 KNO3(aq) + PbI2(s)
What minimum volume of 0.200 M potassium iodide solution is required to
completely precipitate all of the lead in 155.0 mL of a 0.112 M lead(II) nitrate
solution?
a. 174 mL b. 86.8 mL c. 348 mL d. 43.4 mL
4.3.0,25.136. Hydrobromic acid dissolves solid iron according to the reaction:
Fe(s) + 2 HBr(aq) → FeBr2(aq) + H2(g)
What mass of HBr (in g) do you need to dissolve a 3.2 g pure iron bar on a
padlock?
a. 7.3 g HBr b. 6.3 g HBr c. 8.3 g HBr d. 9.3 g HBr
4.3.0,25.137. For the reaction shown, initial amounts of reactants are 1 mol Al, 1
mol O2. What is the limiting reactant?
4 Al(s) + 3 O2(g) = 2 Al2O3(s)
a. Al b. 1 mol O2 c. 1 mol Al d. O2
4.3.0,25.138. Consider the following reaction:
Li2S(aq) + Co(NO3)2(aq) = 2 LiNO3(aq) + CoS(s)
What volume of 0.125 M Li2S solution is required to completely react with 125
mL of 0.150 M Co(NO3)2?
a. 150 mL b. 135 mL c. 125 mL d. 120 mL
4.3.0,25.141. What is the molarity of a solution containing 55.8 g of MgCl 2
dissolved in 1.00 L of solution?
a. 0.586 M b. 1.71 M c. 1.58 M d. 0.558 M
4.3.0,25.142. What mass (in grams) of Mg(NO3)2 is present in 150 mL of a
0.150 M solution of Mg(NO3)2?
a. 143 g b. 0.022 g c. 1.88 g d. 3.34 g
4.3.0,25.143. Urea (CH4N2O) is a common fertilizer that is synthesized by the
reaction of ammonia (NH3) with carbon dioxide:
2 NH3(aq) + CO2(aq) → CH4N2O(aq) + H2O(l)
In an industrial synthesis of urea, a chemist combines 136.4 kg of ammonia with
211.4 kg of carbon dioxide and obtains 168.4 kg of urea. Determine the
theoretical yeild of ure?
 a. 240.5 kg CH4N2O b. 140.5 kg CH4N2O
c. 340.5 kg CH4N2O c. 210.5 kg CH4N2O
4.3.0,25.144. For the reaction shown, initial amounts of reactants are 4 mol Al,
2.6 mol O2. What is the limiting reactant?
4 Al(s) + 3 O2(g) = 2 Al2O3(s)
a. O2 b. 4 mol Al c. Al d. 2.6 mol O2
4.3.0,25.145. Consider the following reaction:
2 CH3OH(g) + 3 O2(g) = 2 CO2(g) + 4 H2O(g)
The following molecular diagrams represents an initial mixture of the reactants.
How many CO2 molecules would be formed from the reaction mixture that
produces the greatest amount of products?

a. 2 molecules CO2 b. 1 molecules CO2

c. 1.5 molecules CO2 d. 3 molecules CO2
4.3.0,25.146. Consider the following reaction:
2 CH3OH(g) + 3 O2(g) = 2 CO2(g) + 4 H2O(g)
The following molecular diagrams represents an initial mixture of the reactants.
How many CO2 molecules would be formed from the reaction mixture that
produces the greatest amount of products?

a. 3 molecules CO2 b. 1 molecules CO2

c. 2 molecules CO2 d.1 molecules CO2
4.3.0,25.147. Potassium iodide reacts with lead(II) nitrate in the following
precipitation reaction:
2 KI(aq) + Pb(NO3)2(aq) → 2 KNO3(aq) + PbI2(s)
What minimum volume of 0.200 M potassium iodide solution is required to
completely precipitate all of the lead in 155.0 mL of a 0.112 M lead(II) nitrate
solution?
a. 174 mL b. 86.8 mL c. 348 mL d. 43.4 mL
4.3.0,25.148. What is the percent by mass of sodium chloride in a 1.35 M NaCl
solution? The density of the solution is 1.05 g/mL
a. 7.51% b. 7.01% c. 6.51% d. 6.01%
4.3.0,25.149. A liquid fuel mixture contains 30.35% hexane (C6H14), 15.85%
heptane (C7H16), and the rest octane (C8H18). What maximum mass of carbon
dioxide is produced by the complete combustion of 10.0 kg of this fuel mixture?
a. 10.8 kg CO2 b. 20.8 kg CO2 c. 30.8 kg CO2 d. 15.3 kg CO2
4.3.0,25.150. Many computer chips are manufactured from silicon, which occurs
in nature as SiO2. When SiO2 is heated to melting, it reacts with solid carbon to
form liquid silicon (Si) and carbon monoxide gas. In an industrial preparation of
silicon, 155.8 kg of SiO2 is allowed to react with 78.3 kg of carbon to produce
66.1 kg of silicon. What is the limiting reactant?
a. 155.8 kg SiO2 b. 78.3 kg C c. SiO2 d. C
4.3.0,25.151. Many computer chips are manufactured from silicon, which occurs
in nature as SiO2. When SiO2 is heated to melting, it reacts with solid carbon to
form liquid silicon and carbon monoxide gas. In an industrial preparation of
silicon, 155.8 kg of SiO2 is allowed to react with 78.3 kg of carbon to produce
66.1 kg of silicon. What is the theoretical yield and percent yield for the
reaction?
a. 82.83 kg Si and 90.76% b. 72.83 kg Si and 90.76%
c. 67.52 kg Si and 97.89% d. 77.53 kg Si and 85.26%
4.3.0,25.152. A 25.0 mL sample of a 1.20 M potassium chloride solution is
mixed with 15.0 mL of a 0.900 M barium nitrate solution and this precipitation
reaction occurs:
2 KCl(aq) + Ba(NO3)2(aq) → BaCl2(s) + 2 KNO3(aq)
Determine the limiting reactant?
a. 0.0135 mol barium nitrate solution b. Barium nitrate solution
c. 0.03 mol potassium chloride solution d. Potassium chloride solution
4.3.0,25.153. The density of a 20.0% by mass ethylene glycol (C2H6O2) solution
in water is 1.03 g/mL. Find the molarity of the solution.
a. 2.32 M b. 3.02 M c. 3.32 M d. 1.32 M
4.3.0,25.154. Many home barbeques are fueled with propane gas (C 3H8). What
mass of carbon dioxide (in kg) is produced upon the complete combustion of
18.9 L of propane (approximate contents of one 5 gallon tank)? Assume that the
density of the liquid propane in the tank is 0.621 g/mL
a. 31.14 kg b. 34.74 kg c. 30.14 kg d. 35.14 kg
4.3.0,25.155. The combustion of liquid ethanol (C2H5OH) produces carbon
dioxide and water. After 4.62 mL of ethanol (density = 0.789g/mL) was allowed
to burn in the presence of 15.55 g of oxygen gas. What are the limiting reactant
and theoretical yield of H2O?
a. 3.64 g C2H5OH and 4.27 g H2O b. 3.36 g C2H5OH and 4.94 g H
c. 2.64 g C2H5OH and 3.94 g H2O d. 4.36 g C2H5OH and 4.94 g H2O

Chapter 5. Gases

5.1.0,25.156. The pressure on top of Mt. Everest averages about 235 mmHg.
How many is this pressure in atm unit?
a. 0.109 atm b. 0.209 atm c. 0.309 atm d. 0.009 atm
5.1.0,25.157. The world record for lowest pressure barometric (at sea level) was
652.5 mmHg recorded inside Typhoon Tip on October 12, 1979, in the Western
Pacific Ocean. How many is this pressure in psi unit?
a. 12.62 psi b. 10.62 psi c. 9.62 psi d. 11.62 psi
5.1.0,25.158. A sample of gas has an initial volume of 32.6 L at a pressure of 1.3
atm. If the sample is compressed to a volume of 13.8 L, what will its pressure
be?
a. 1.07 atm b. 3.07 atm c. 4.07 atm d. 2.07 atm
5.1.0,25.159. A cylinder with a moveable piston contains 0.87 mol of gas and
has a volume of 334 mL. What will its volume be if an additional 0.22 mol of
gas is added to the cylinder? (Assume constant temperature and pressure.)
a. 84.46 mL b. 84.40 mL c. 80.46 mL d. 74.46 mL
5.1.0,25.162. What is the density of a sample of argon gas at 55 °C and 765
mmHg?
a. 1.49 g/L b. 1.13 x 103 g/L c. 8.91 g/L d. 2.99 g/L
5.1.0,25.162. Which gas sample has the greatest volume at STP?
a. 10.0 g Xe b. 10.0 g Kr
c. 10.0 g Ar d. None of the above (They all have the same volume.)
5.1.0,25.163. A weather balloon is inflated to a volume of 28.5 L at a pressure of
748 mmHg and a temperature of 28.0 °C. The balloon rises in the atmosphere to
an altitude of approximately 25,000 feet, where the pressure is 385 mmHg and
the temperature is -15.0 °C. Assuming the balloon can freely expand, what is the
volume of the balloon at this altitude?
a. 51.3 L b. 42.8 L c. 50.9 L d. 47.5 L
5.1.0,25.164. An experiment shows that a 113 mL gas sample has a mass of
0.171 g at a pressure of 721 mmHg and a temperature of 32 °C. What is the
molar mass of the gas?
a. 39.94 b. 29.93 c. 29.90 d. 39.20
5.1.0,25.165. A sample of gas has a mass of 0.555 g. Its volume is 117 mL at a
temperature of 85 °C and a pressure of 753 mmHg. What is the molar mass of
the gas?
a. 120.7 b. 130.7 c. 140.7 d. 135.7
5.1.0,25.166. A gas mixture with a total pressure of 755 mmHg contains each of
the following gases at the indicated partial pressures: CO 2, 255mmHg; Ar, 124
mmHg; and O2, 167 mmHg. The mixture also contains helium gas. What is the
partial pressure of the helium gas?
a. 209 mmHg b. 109 mmHg c. 309 mmHg d. 100 mmHg
5.2.0,25.167. A gas mixture with a total pressure of 755 mmHg contains each of
the following gases at the indicated partial pressures: CO 2, 255mmHg; Ar, 124
mmHg; and O2, 167 mmHg. The mixture also contains helium gas. What mass
of helium gas is present in a 10.0L sample of this mixture at 273 K?
a. 0.291 g b. 0.491 g c. 0.191 g d. 0.091 g
5.2.0,25.168. A 248 mL gas sample has a mass of 0.433 g at a pressure of
745 mmHg and a temperature of 28 °C. What is the molar mass of the gas?
a. 44.0 g/mol b. 45.0 g/mol c. 43.0 g/mol d. 42.0 g/mol
5.2.0,25.171. The oxygen molecules in air exert a certain pressure 21% of the
total pressure. What volume of air contains 10.0 g of oxygen gas at 273 K and
1.00 atm?
a. 35.42 L b. 32.34 L c. 30.12 L d. 33.33 L
5.2.0,25.172. A gas sample at STP contains 1.15 g oxygen and 1.55 g nitrogen.
What is the volume of the gas sample?
a. 2.04 L b. 1.26 L c. 4.08 L d. 61.0 L
5.2.0,25.173. A piece of dry ice (solid carbon dioxide) with a mass of 28.8 g
sublimes (converts from solid to gas) into a large balloon. Assuming that all of
the carbon dioxide ends up in the balloon, what is the volume of the balloon at a
temperature of 22 °C and a pressure of 742 mmHg?
a. 13.2 L b. 16.2 L c. 14.2 L d. 15.2 L
5.2.0,25.174. Aerosol cans carry clear warnings against incineration because of
the high pressures that can develop upon heating. Suppose that a can contains a
residual amount of gas at a pressure of 755 mmHg and a temperature of 25 °C.
What would the pressure be if the can were heated to 1155 °C?
a. 4.76 atm b. 7.46 atm c. 5.76 atm d. 6.47 atm
5.2.0,25.175. A sample of gas has a mass of 38.8 mg. Its volume is 224 mL at a
temperature of 55°C and a pressure of 886 torr. Find the molar mass of the gas?
a. 4.5 g/mol d. 6.0 g/mol c. 7.0 g/mol d. 4.0 g/mol
5.2.0,25.176. A 248 mL gas sample has a mass of 0.433 g at a pressure of 745
mmHg and a temperature of 28 °C. What is the molar mass of the gas?
a. 23.0 g/mol b. 62.0 g/mol c. 27.0 g/mol d. 44.0 g/mol
5.2.0,25.177. A sample of neon effuses from a container in 76 seconds. The
same amount of an unknown noble gas requires 155 seconds. Identify the gas
a. Ar b. Kr c. Cl d. N2
5.3.0,25.178. Consider the following chemical reaction.
 2 H2O(l) → 2 H2(g) + O2 (g)
What mass of H2O is required to form 1.4 L of O 2 at a temperature of 315 K and
a pressure of 0.957 atm?
a. 1.80 g b. 0.87 g c. 1.56 g d. 1.87 g
5.3.0,25.179. Lithium reacts with nitrogen gas according to the following
reaction:
6 Li(s) + N2(g) → 2 Li3N (s)
What mass of lithium (in g) is required to react completely with 58.5 mL of gas
nitrogen at STP?
a. 0.109 g b. 0.209 g c. 0.129 g d. 0.102 g
5.3.0,25.180. Lithium reacts with nitrogen gas according to the following
reaction:
6 Li(s) + N2(g) → 2 Li3N (s)
What volume of nitrogen gas (in ml at STP) is required to react completely with
0.5 g lithium?
a. 260 mL b. 169 mL c. 269 mL d. 160 mL
5.3.0,25.181. A 2.85g sample of an unknown chlorofluorocarbon is decomposed
and produces 564 mL of chlorine gas (Cl 2) at a pressure of 752 mmHg and a
temperature of 298 K. What is the percent chlorine (by mass) in the unknown
chlorofluorocarbon?
a. 46.14 % b. 56.92 % c. 58.32% d. 68.40%
5.3.0,25.182. A 118mL flask is evacuated and found to have a mass of 97.129 g.
What is the mass of the flask if it is filled with 768 torr of pure helium gas at 35
°C?
a. 97.147 g b. 97.129 g c. 96.129 g d. 96.147 g

5.3.0,25.185. Consider the chemical reaction:

 C(s) + H2O(g) → CO(g) + H2(g)
How many liters of hydrogen gas are formed from the complete reaction of 15.7
g C? Assume that the hydrogen gas is collected at a pressure of 1.0 atm and a
temperature of 355 K.
a. 36 L b. 38 L c. 34 L d. 35 L
5.3.0,25.186. The following reaction forms 15.8 g of Ag(s):
2 Ag2O(s) → 4 Ag(s) + O2 (g)
What total volume of gas forms if it is collected over water at a temperature of
25 °C and a total pressure of 752 mmHg?
a. 900 mL b. 800 mL c. 750 mL d. 905 mL
5.3.0,25.187. Ammonium carbonate decomposes upon heating according to the
balanced equation:
(NH4)2CO3(s) → 2 NH3(g) + CO2(g) + H2O(g)
Calculate the total volume of gas produced at 22 °C and 1.02 atm by the
complete decomposition of 11.83 g of ammonium carbonate.
a. 11.7 L b. 14. L c. 15.0 L d. 13.3 L
5.3.0,25.188. Automobile air bags inflate following a serious impact. The
impact triggers the chemical reaction:
2 NaN3(s) → 2 Na(s) + 3 N2 (g)
If an automobile air bag has a volume of 11.8 L, what mass of NaN 3 (in g) is
required to fully inflate the air bag upon impact? Assume STP conditions
a. 20.8 g NaN3 b. 22.8 g NaN3 c. 24.3 g NaN3 d. 19.8 g NaN3
5.3.0,25.189. Consider the following reaction:
2 SO2(g) + O2 (g) → 2 SO3 (g)
If 285.5 mL of SO2 is allowed to react with 158.9 mL of O2 (both measured at
315 K and 50.0 mmHg), what is the theoretical yield of SO3?
a. 0.0581 g b. 0.0181 g c. 0.0381 g d. 0.0581 g
5.3.0,25.190. Consider the following reaction:
2 SO2(g) + O2 (g) → 2 SO3 (g)
In the particular reaction, 285.5 mL of SO 2 is allowed to react with 158.9 mL of
O2 to produce 187.2 mL of SO3 (all gases measured at 315 K and 50.0 mmHg).
What is the percent yield for the reaction?
a. 50.57% b. 55.57% c. 45.57% d. 65.57%

Chapter 6. Thermochemistry

6.1.0,25.191. If we has energy 1.58 x 103 kJ. What is this energy in kcal unit?

a. 377.63 kcal b. 277.63 kcal c. 177.63 kcal d. 187.63 kcal

6.1.0,25.192. A frost free refrigerator uses about 655 kWh of electrical energy

per year. What is this amount of energy in kJ unit?

a. 0.358 x 106 kJ b. 3.358 x 106 kJ c. 1.358 x 106 kJ d. 2.358 x 106 kJ

6.1.0,25.193. A frost free refrigerator uses about 540 kWh of electrical energy

per year. What is this amount of energy in kcal unit?

a. 464.63 x 106 kcal b. 264.63 x 103 kcal

c. 164.63 x 103 kcal d. 364.63 x 103 kcal

6.1.0,25.194. A system absorbs 214 kJ of heat and the surroundings do 110 kJ of

work on the system. What is the change in internal energy of the system?

a. 224 kJ b. 424 kJ c. 324 kJ d. 104 kJ

6.1.0,25.195. Which sample is most likely to undergo the smallest change in

temperature upon the absorption of 100 kJ of heat?

a. 50 g water b. 15 g lead c. 15 g water d. 50 g lead

6.1.0,25.196. Two substances, A and B, of equal mass but at different

temperatures come into thermal contact. The specific heat capacity of substance

A is twice the specific heat capacity of substance B. Which statement is true of

the temperature of the two substances when they reach thermal equilibrium?

(Assume no heat loss other than the thermal transfer between the substances.)

a. The final temperature of both substances will be closer to the initial

temperature of substance B than the initial temperature of substance A.

b. The final temperature of both substances will be closer to the initial

temperature of substance A than the initial temperature of substance B.

c. The final temperature of both substances will be exactly midway between

the initial temperatures of substance A and substance B.

d. The final temperature of substance B will be greater than the final

temperature of substance A.

6.1.0,25.197. Which process is endothermic?

a. The evaporation of water from the skin.

b. The burning of candle wax.

c. The oxidation of iron in a chemical hand warmer.

d. The combustion of natural gas in a stove.

6.1.0,25.198. How much heat is required to warm 1.50 kg of sand from 25.0 °C

to 100.0 °C? Specific heat capacity of sand is 0.84 J/g.0C.

a. 84.5 kJ b. 94.5 kJ c. 90.5 kJ d. 80.5 kJ

6.1.0,25.199. During a breath, the average human lung expands by about 0.50 L.

If this expansion occurs against an external pressure of 1.0 atm, how much work

(in J) is done during the expansion?

a. -50.65 J b. -40.65 J c. -55.60 J d. -45.65 J

6.2.0,25.202. A 12.5 g sample of granite initially at 82.0 oC is immersed into

25.0 g of water initially at 22.0 oC. What is the final temperature of both

substances when they reach thermal equilibrium? (For water, Cs = 4.18 J/g oC

and for granite, Cs = 0.790 J/g oC.)

 a. 52.0 oC b. 1.55 x 103 oC c. 15.7 oC d. 27.2 oC

6.2.0,25.203. What mass of natural gas (CH 4) must you burn to emit 267 kJ of

heat?

CH4(g) + 2O2 (g) → CO2 (g) + 2H2O (g) H rxn = - 802.3 kJ

a. 5.34 g b. 10.34 g c. 3.34 g d. 6.34 g

6.2.0,25.204. How much heat is evolved by the complete combustion of 7.5 g of

O2?

CH4(g) + 2O2 (g) → CO2 (g) + 2H2O (g) H rxn = - 802.3 kJ

a. 84 kJ b. 94 kJ c. 90 kJ d. 74 kJ

6.2.0,25.205. When a 3.80 g sample of liquid octane (C 8H18) is burned in a bomb

calorimeter, the temperature of the calorimeter rises by 27.3 oC. The heat

capacity of the calorimeter, measured in a separate experiment, is 6.18 kJ/ oC.

Determine the enthalpy of combustion for octane in units of kJ/mol octane.

a. -5.07 x 103 kJ/mol b. 5.07 x 103 kJ/mol

c. -44.4 x 103 kJ/mol d. -16.7 x 103 kJ/mol

6.2.0,25.206. A 25.5 g aluminum block is warmed to 65.4 oC and plunged into

an insulated beaker containing 55.2 g water initially at 22.2 oC. The aluminum

and the water are allowed to come to thermal equilibrium. The specific heat

capacity of aluminum is 0.903 J/g.°C and of water is 4.18 J/g.°C. Assuming that

no heat is lost, what is the final temperature of the water and aluminum?

a. 20.3 oC b. 17.1 oC c. 26.1 oC d. 15.4 oC

6.2.0,25.207. Charcoal is primarily carbon. What is the mass of CO 2 produced

by burning enough Carbon (in the form of charcoal) to produce 5.00 x 10 2 KJ of

heat?

C(s) + O2 (g) → CO2 (g) H rxn = - 393.5 kJ

a. 55.9 g b. 50.9 g c. 45.9 g d. 40.9 g

6.2.0,25.208. Manganese reacts with hydrochloric acid to produce

manganese(II) chloride and hydrogen gas.

Mn(s) + 2HCl(aq) → MnCl2(aq) + H2(g)

When 0.625 g Mn is combined with enough hydrochloric acid to make 100.0

mL of solution in a coffee-cup calorimeter, all of the Mn reacts, raising the

temperature of the solution from 23.5 oC to 28.8 oC. Find Hrxn for the reaction as

written. (Assume that the specific heat capacity of the solution is 4.18 J/g C and

the density is 1.00 g/mL.)

a. -2.21 kJ b. -3.54 kJ c. -1.22 kJ d. -195 kJ

6.2.0,25.211. Consider the following generic reaction:

A + 2B → C + 3D H = 155 kJ

What is the value of H for the following related reaction?

3A + 6B = 3C + 9D

a. 465 kJ b. 450 kJ c. 460 kJ d. 365 kJ

6.3.0,25.212. Consider the following generic reaction:

A + 2B → C + 3D H = 155 kJ

What is the value of H for the following related reaction?

1/2 C + 3/2 D → 1/2A + B

a. -75.5 kJ b. -70.0 kJ c. -77.5 kJ d. -65.5 kJ

6.3.0,25.213. The following reactions and given H’s:

C(s) + 2H2 (g) → CH4 (g)

C(s) + 2Cl2 (g) → CCl4 (g)

H2 (g) + Cl2 (g) → 2HCl(g) H = - 92.3 kJ

What is H rxn for the following reaction?

CH4(g) + 4Cl2 (g) → CCl4 (g) + 4HCl(g)

 a. -205.7 kJ b. -105.7 kJ c. 205.7 kJ d. 105.7 kJ

6.3.0,25.214. The following reactions and given H’s:

C3H8(g) + 5 O2(g) 3 CO 2(g) + 4 H2O(g) ∆ H =−2043 kJ

C(s) + O2(g ) CO 2(g) ∆ H =−393.5 kJ

2 H2(g) + O2(g ) 2 H O(g)

2 ∆ H =−483.6 kJ

What is H rxn for the following reaction?

3 C(s) + 4 H2(g) C 3H8(g)

a. 205 kJ b. 105 kJ c. -205 kJ d. -105 kJ

6.3.0,25.215. Hydrogen gas reacts with oxygen to form water

2 H2(g) + O2(g) 2 H 2O(g) H = -483.5 kJ

Determine the minimum mass of hydrogen gas required to produce 226 kJ of

heat

a. 1.88 g b. 8.63 g c. 0.942 g d. 0.935 g

6.3.0,25.216. What is Hrxn for the reaction:

Fe2O3(s) + 3 CO(g) 2 Fe (s) + 3 CO2(g)

Use the following reactions and given H’s:
2Fe(s) + 3/2O2(g) Fe 2O3
CO(g) + ½ O2(g) CO 2(g) H = -282.7 kJ

a. -13.9 kJ b. -23.9 kJ c. -21.9 kJ d. -20.4 kJ

6.3.0,25.217. Natural gas burns in air to form carbon dioxide and water,

releasing heat.

CH4(g) + O2(g) CO 2(g) + H2O(g) Hrxn = -802.3 kJ

What minimum mass of CH4 is required to heat 55 g of water by 25 oC?

(Assume 100% heating efficiency)

a. 0.115 g b. 2.25 x 103 g c. 115 g d. 8.70 g

6.3.0,25.218. We have the standard enthalpies of formation according the

following table:

What is ∆ H °rxn for the reaction 4 NH3(g) + 5 O2(g ) 4 NO( g) + 6 H2O(g)?

a. -902.0 kJ b. 902.0 kJ c. -802.0 kJ d. 802.0 kJ

6.3.0,25.219. Pentane (C5H12) is a component of gasoline that burns according to

the following balanced equation:

C5H12(l) + 8 O2(g) → 5 CO2(g) + 6 H2O(g)

The standard enthalpies of formation of the compounds: O 2(g): 0.0 kJ/mol; liquid

pentane: 146.8 kJ/mol; CO2(g): -393.5 kJ/mol; H2O(g): -241.8 kJ/mol. What is
H o
for this reaction using standard enthalpies of formation?
rxn

a. -3565.1 kJ b. 3565.1 kJ c. -3025 kJ d. 3025 kJ

6.3.0,25.220. The explosive nitroglycerin (C3H5N3O9) decomposes rapidly upon

ignition or sudden impact according to the following balanced equation:

4 C3H5N3O9 (l) → 12 CO2 (g) + 10 H2O(g) + 6 N2(g) + O2(g) H rxn

o
= - 5678 kJ

The standard enthalpies of formation of the compounds: O2(g): 0.0 kJ/mol; N2(g):

0.0 kJ/mol; CO2(g): -393.5 kJ/mol; H2O(g): -241.8 kJ/mol. What is the standard

enthalpy of formation ( H f
o
) for nitroglycerin?

a. 365.5 kJ b. -360.5 kJ c. -365.5 kJ d. 360.5 kJ

6.3.0,25.221. Zinc metal reacts with hydrochloric acid according to the balanced

equation:

Zn(s) + 2 HCl(aq) → ZnCl2(aq) + H2(g)

When 0.103 g of Zn(s) is combined with enough HCl to make 50.0 mL of

solution in a coffee-cup calorimeter, all of the zinc reacts, raising the

temperature of the solution from 22.5 oC to 23.7 oC. Find Hrxn for this reaction as

written. (Use 1.0 g/mL for the density of the solution and 4.18 J/g. oC as the

specific heat capacity.)

a. -1.6 x 105 J b. -1.2 x 105 J c. -2.6 x 105 J d. -3.2 x 105 J

6.3.0,25.224. When 0.514 g of biphenyl (C12H10) undergoes combustion in a

bomb calorimeter, the temperature rises from 25.8 oC to 29.4 oC. Find Erxn for

the combustion of biphenyl in kJ/mol biphenyl. The heat capacity of the bomb

calorimeter, determined in a separate experiment, is 5.86 kJ/ oC.

a. - 4.3 x 103 kJ/mol b. - 5.3 x 103 kJ/mol

c. - 6.3 x 103 kJ/mol d. - 3.4 x 103 kJ/mol

6.3.0,25.225. Evaporating sweat cools the body because evaporation is an

endothermic process:

H2O(l) H 2O(g) Hrxno = +44.01 kJ

Estimate the mass of water that must evaporate from the skin to cool the body

by 0.50 oC. Assume a body mass of 95 kg and assume that the specific heat

capacity of the body is 4.0 J/g. oC.

a. 68 g b. 78 g c. 64 g d. 58 g

6.3.0,25.226. LP gas burns according to the following exothermic reaction:

C3H8 (g) + 5 O2(g) → 3 CO2 (g) + 4 H2O(g) H rxn

o
= - 2044 kJ

What mass of LP gas is necessary to heat 1.5 L of water (density 1.0 g/mL) from

room temperature 25.0 °C to boiling 100.0 °C (specific heat capacity of water is

4.18 J/g.0C)? Assume that during heating, 15% of the heat emitted by the LP gas

combustion goes to heat the water. The rest is lost as heat to the surroundings.

a. 67.63 g b. 65.93 g c. 70.63 g d. 60.93 g

6.3.0,25.227. If 50.0 mL of ethanol (density 0.789 g/mL) initially at 7.0 °C is

mixed with 50mL of water (density 1.0 g/mL) initially at 28.4 °C in an insulated

beaker, specific heat capacity of water is 4.18 J/g. 0C, of ethanol is 2.42 J/g.0C,

and assuming that no heat is lost. What is the final temperature of the mixture?

a. 16.69 °C b. 30.49 °C c. 21.69 °C d. 20.69 °C

6.3.0,25.228. Methanol (density 0.7918 g/mL) has been proposed as alternatives

to hydrocarbon fuel. The reactions for the complete combustion of methanol

according to the following exothermic reaction:

CH3OH (l) + O2(g) → CO2 (g) + 2H2O(g)

The standard enthalpies of formation of the compounds: CH 3OH(l): - 238.6

kJ/mol; O2(g): 0.0 kJ/mol; CO2(g): -393.5 kJ/mol; H2O(g): -241.8 kJ/mol. What is

the amount of heat released per kilogram of the fuel?

a. 15.93 x 103 kJ b. 10.93 x 103 kJ c. 19.93 x 103 kJ d. 17.93 x 103 kJ

Chapter 7. The Quantum-Mechanical Model of the Atom

7.1.0,25.229. Which has the longest wavelength in the following types of

electromagnetic radiations?
a. radio waves b. gamma rays c. microwaves d. visible
light
7.1.0,25.230. Which has the highest energy in the following types of
electromagnetic radiations?
a. radio waves b. gamma rays c. microwaves d. visible
light
7.1.0,25.231. Which wavelength of light has the highest frequency?
a. 1 nm b. 10 mm c. 10 nm d. 1 mm
7.1.0,25.234. How much energy (in J) is contained in 1.00 mole of 552 nm
photons?
a. 5.98 x 10-43 J b. 3.60 x 10-19 J c. 3.60 x 10-28 J d. 2.17 x 105 J
7.1.0,25.235. Light from three different lasers (A, B, and C), each with a
different wavelength, was shined onto the same metal surface. Laser A produced
no photoelectrons. Lasers B and C both produced photoelectrons, but the
photoelectrons produced by laser B had a greater velocity than those produced
by laser C. Arrange the lasers in order of increasing wavelength.
a. B < C < A b. C < B < A c. A < B < C d. A < C < B
7.1.0,25.236. What is the wavelength of the electromagnetic radiation (in m) that
has a frequencie of 100.2 MHz?
a. 2.5 m b. 3 m c. 2 m d. 4 m
7.1.0,25.237. What is the wavelength of the electromagnetic radiation (in nm)
that has a frequencie of 1070 kHz?
a. 280.4 x 109 nm b. 250.4 x 109 nm
c. 160.4 x 109 nm d. 180.4 x 109 nm
7.1.0,25.238. Determine the energy of 1 mol of photons for infrared radiation
that has wavelength of 1500 nm
a. 69.8 kJ/mol b. 60.7 kJ/mol c. 79.8 kJ/mol d.89.4 kJ/mol
7.1.0,25.239. What is the energy of a photon of electromagnetic radiation that
has a frequencie of 1070 kHz?
a. 7089.8 x 10-31 J b. 5089.8 x 10-31 J
c. 6089.8 x 10-31 J d. 4089.8 x 10-31 J
7.2.0,25.240. A heat lamp produces 25.5 watts of power at a wavelength of 6.5
mm. How many photons are emitted per second? (1 watt = 1 J/s)
a. 5.33 x 1023 photons b. 7.33 x 1023 photons
c. 6.33 x 1023 photonsd. d. 8.33 x 1023 photons
7.2.0,25.241. A heat lamp produces 32.8 watts of power at a wavelength of 6.5
µm. How many photons are emitted per second? 1 watt = 1 J/s

a. 8.73 x 1020 photons b. 10.73 x 1020 photons

c. 7.65 x 1020 photons d. 6.71 x 1020 photons

7.2.0,25.242. How much energy is contained in 1 mol of X-ray photons with a

wavelength of 0.155 nm?
a. 772.3 x 105 J b. 572.3 x 105 J
c. 472.3 x 105 J d. 672.3 x 105 J
7.2.0,25.243. How much energy is contained in 1 mol of γ-ray photons with a
wavelength of 2.15 x 10-5 nm.

a. 3.6 x 1012 J b. 5.6 x 1012 J c. 4.3 x 1012 J d. 2.4 x 1012 J

7.2.0,25.244. What are the possible values of ml for the value of l is 1 (one)?
a. -1; 0; 1 b. -1; 0 c. 0; 1; 2 d. 0; 1
7.2.0,25.245. What values of l are possible for n = 3 ?
a. -1; 0; 1 b. -1; 0 ; 1; 2 c. 0; 1; 2; 3 d. 0; 1; 2
7.2.0,25.246. What is the full values of ml if l = 2?

a. -2; -1; 0 ; 1; 2 b. 0; 1; 2 c. -1; 0; 1; 2; d. -1; -2; 0; 1

7.2.0,25.249. Which set of three quantum numbers does not specify an orbital in
the hydrogen atom?
a. n = 3; l = 2; ml = 2 b. n = 2; l = 1; ml = -1
c. n = 2; l = 0; ml = 0 d. n = 3; l = 3; ml = -2
7.2.0,25.250. Which set of quantum numbers cannot occur together to specify
an orbital?
a. n = 3, l = 3, ml = 2 b. n = 3, l = 2, ml = 0
c. n = 2, l = 1, ml = -1 d. n = 4, l = 3, ml = 0
7.2.0,25.251. Which of the following is not a valid set of quantum numbers?
a. (4, 2, -1, -½) b. (2, 0, 0, +½) c. (2, 2, 1, -½) d. (3, 0, 0, +½)
7.2.0,25.252. Which of the following combinations of n and l is impossible?
a. 2p b. 1s c. 4s d. 2d
7.2.0,25.253. Which of the following combinations of n and l represents a real
orbital?
a. 1p b. 2f c. 3p d. 2d
7.3.0,25.254. The nearest star to our sun is Proxima Centauri, at a distance of 4.3
light-years from the sun. A light-year is the distance that light travels in one year
(365 days). How far away, in km, is Proxima Centauri from the sun?

a. 8.46 x 1012 km b. 9.46 x 1012 km

c. 7.46 x 1012 km d. 5.46 x 1012 km

7.3.0,25.255. A laser pulse with wavelength 532 nm contains 3.85 mJ of energy.

How many photons are in the laser pulse?

a. 1.03 x 1016 photons b. 2.03 x 1016 photons

 c. 3.03 x 1016 photons d. 4.03 x 1016 photons

7.3.0,25.256. A heat lamp produces 32.8 watts of power at a wavelength of 6.5

µm. How many photons are emitted per second? 1 watt = 1 J/s

a. 8.73 x 1020 photons b. 10.73 x 1020 photons

c. 7.65 x 1020 photons d. 6.71 x 1020 photons

7.3.0,25.257. Which orbital is described by the set of quantum numbers n = 4, l

= 1, ml = –1?

a. 3p b. 2p c. 4p d. 1s
7.3.0,25.260. Which of the following transitions for an electron in a hydrogen
atom would release the largest quantum of energy?
a. n = 3 n = 1b. n = 4 n = 3
c. n = 1 n = 4 d. n = 4 n = 2
7.3.0,25.261. An electron in the n = 7 level of the hydrogen atom relaxes to a
lower energy level, emitting light of 397 nm. What is the value of n for the level
to which the electron relaxed?
a. 4 b. 3 c. 2 d. 5
7.3.0,25.262.
What is the frequency of the light emitted when an electron in a hydrogen ato

a. 16 x 1013Hz b. 14 x 1013Hz c. 10 x 1013Hz d. 12 x 1013Hz

7.3.0,25.263. What is the wavelength of the light (in nm) absorbed when an
electron in a hydrogen atom makes a transition from an orbital in which n = 2 to
an orbital in which n = 7?
a. 326.31 nm b. 295.5 nm c. 245.5 nm d. 397.52 nm
7.3.0,25.264. What is the wavelength of light (in nm) emitted when an electron
in a hydrogen atom makes a transition from a 6p orbital to a 1s orbital?
a. 91.8 nm b. 90.5 nm c. 93.8 nm d. 78.3 nm

Chapter 8. Periodic Properties of the Elements

8.1.0,25.265. What is the full electron configuration for Si?
a. 1s2 2s2 2p63s2 3p2 b. 1s2 2s2 2p63s2 c. 1s2 2s2 2p63s1 d. 1s2 2s2 2p6
8.1.0,25.266. What is the full electron configuration for Ca?
a. 1s2 2s2 2p6 3s2 3p6 4s1 b. 1s2 2s2 2p63s2 3p2
 c. 1s2 2s2 2p63s2 3p6 d. 1s2 2s2 2p6 3s2 3p6 4s2
8.1.0,25.267. What is the element corresponding to the electron configurations

[Ar]4s2 3d10 4p6?

a. Kr b. Br c. Xe d. Se
8.1.0,25.268. What is the element corresponding to the electron configurations

[Ar]4s2 3d2?
a. Cr b. Ti c. Ca d. Se
8.1.0,25.269. What is the name an element in the third period (row) of the
periodic table with four 3p electrons?
a. S b. Cl c. Si d. Al
8.1.0,25.270. What is the name an element in the third period (row) of the
periodic table with two 3s electrons and no 3p electrons?
a. Si b. Na c. Mg d. P
8.1.0,25.273. Which set of four quantum numbers corresponds to an electron in a
4 p orbital?
a. n = 4, l = 2, ml = 0, ms = 1/2 b. n = 4, l = 3, ml = 3, ms = -1/2
c. n = 4, l = 1, ml = 0, ms = 1/2 d. n = 4, l = 4, ml = 3, ms = -1/2
8.1.0,25.274. Which electron in sulfur is most shielded from nuclear charge?
a. An electron in the 1s orbital b. An electron in a 3p orbital
c. An electron in a 2p orbital d. none of the above
8.1.0,25.275. Which statement is true about electron shielding of nuclear charge?
a. Outermost electrons efficiently shield core electrons from nuclear charge.
b. Core electrons efficiently shield one another from nuclear charge.
c. Core electrons efficiently shield outermost electrons from nuclear charge
d. Outermost electrons efficiently shield one another from nuclear charge.
8.2.0,25.276. Which does arrange the atoms S, Mg, Al, Si according to
increasing effective nuclear charge experienced by their valence electrons?
a. Mg<Al <S <Si b. Mg<Si<Al<S c. Mg<Al<Si<S d. Mg<Si< S<Al
8.2.0,25.277. Arrange these elements in order of increasing first ionization
energy: Cl, Sn, Si.
a. Sn < Si < Cl b. Cl < Si < Sn c. Si < Cl < Sn d. Sn < Cl < Si
8.2.0,25.280. What is the electron configuration for Fe2+?
a. [Ar] 4s0 3d6 b. [Ar] 4s2 3d4 c. [Ar] 4s2 3d6 d. [Ar] 4s2 3d8
8.2.0,25.281. What is the full electron configuration for K+?
a. 1s22s22p63s23p64s0 b. 1s22s22p63s23p6
c. 1s22s22p63s23p64s1 d. 1s22s22p63s23p64s2
8.2.0,25.282. What is the full electron configuration for P3 -?
a. 1s22s22p63s23p3 b. 1s22s22p63s23p6
c. 1s22s22p63s23p5 d. 1s22s22p63s23p4
8.2.0,25.283. What is the electron configuration for Ti2+?
a. [Ar] 4s0 3d2 b. [Ar] 4s0 3d2 c. [Ar] 4s0 3d2 d. [Ar] 4s0 3d2
8.2.0,25.284. Name an element in the fourth period (row) of the periodic table
with five valence electrons
a. As b. Zn c. Cu d. Mn
8.2.0,25.285. Name an element in the third period (row) of the periodic table
with four 3p electrons
a. S b. P c. Al d. Mg
8.2.0,25.286. Which statement is true about effective nuclear charge?
a. Effective nuclear charge increases as you move to the right across a row in the
periodic table and decreases as you move down a column.
b. Effective nuclear charge increases as you move to the right across a row in the
periodic table and increases as you move down a column.
c. Effective nuclear charge decreases as you move to the right across a row in the
periodic table and decreases as you move down a column.
d. Effective nuclear charge decreases as you move to the right across a row in
the periodic table and increases as you move down a column
8.3.0,25.287. Which statement is true about trends in metallic character?
a. Metallic character decreases as you go to the right across a row in the
periodic table and increases as you go down a column
b. Metallic character increases as you go to the right across a row in the
periodic table and increases as you go down a column.
c. Metallic character decreases as you go to the right across a row in the
periodic table and decreases as you go down a column.
d. Metallic character decreases as you go to the right across a row in the
periodic table and increases as you go down a column.
8.3.0,25.288. For which element is the gaining of an electron most exothermic?
a. Li b. F c. N d. B
8.3.0,25.289. Which outer electron configuration would you expect to belong to
a reactive metal?
a. ns2 b. ns2 np6 c. ns2 np5 d. ns2 np2
8.3.0,25.290. Which outer electron configuration would you expect to belong to
a reactive nonmetal?
a. ns2 b. ns2 np6 c. ns2 np2 d. ns2 np5
8.3.0,25.291. Which is the element corresponding to the electron configuration
of [Ar] 4s23d104p6?
a. Kr b. Br c. Se d. Ni
8.3.0,25.292. Which special is diamagnetic?
a. C b. Cr2+ c. Mn d. Zn
8.3.0,25.293. Which does arrange the elements Cl, Sn, S, Pb in order of
decreasing first ionization energy?
a. Cl> S> Pb> Sn b. Cl> Sn> S> Pb c. Cl>S> Sn> Pb d. S>Cl>Pb> Sn
8.3.0,25.294. Which does arrange the elements Si, F, In, N in order of increasing
first ionization energy?
a. F < N< Si < In b. In < Si < F < N c. In < Si < N < F d. Si < In < N <
F
8.3.0,25.295. Life on Earth evolved based on the element carbon. Based on
periodic properties, which elements would you expect to be most like carbon?
a. B b. Si c. N d. O
8.3.0,25.296. Which does arrange th elements N, Si, P, Ga, Al in order of
decreasing metallic character?
a. Ga>Si> Al>P> N b. Al> Si> P> N> Ga
c. Ga>Al>Si>P> N d. Al>Ga> Si> P> N
8.3.0,25.299. Which of the following pairs of elements would you expect to have
the most similar atomic radii?
a. Si and Ge b. Si and Ga c. Si and As d. Si and Sb
8.3.0,25.300. Consider the following elements: P, Ca, Si, S, Ga. Which is srrange
the elements in order of increasing atomic radius?
a. S<P<Si<Ga<Ca b. P<S<Si<Ga<Ca
c. S<P<Si<Ca<Ga a. S<Si<P<Ga<Ca
8.3.0,25.301. Assume that all lower energy orbitals are fully occupied. Which is
statement is false?
a. An electron in a 3s orbital penetrates into the region occupied by core
electrons more than electrons in a 3p orbital.
b. An electron in a 3s orbital is more shielded than an electron in a 2s orbital.
c. An electron in an orbital that penetrates closer to the nucleus will always
experience more shielding than an electron in an orbital that does not penetrate
as far.
d. An electron in an orbital that penetrates close to the nucleus will tend to
experience a higher effective nuclear charge than one that does not.
8.3.0,25.302. The elements with atomic numbers 35 and 53 have similar
chemical properties. Based on their electronic configurations, predict the atomic
number of a heavier element that also should have these chemical properties.
a. 84 b. 54 c. 85 d. 86