(3) I > II > III > IV (4) IV > III > II > I

CHEMISTRY
31. The IUPAC name of the compound HO  CH 2  CH 2  F
36. (2) (3)
H 3C  CH 2  CH  CH 2  CH  CH 2 CH 3 Which conformer of above compound is most stable
| | across C2 –C3
CH 2 CH 3 CH3
(1) staggred (2) eclipsed
(1) 3-Ethyl-5methyl heptane (3) gauche (4) fully eclipsed
(2) 5-Ethyl-3-methyl heptane 37. Match the column
(3) 3,5-Diethylhexane Compound No. of Isomer
(4) 1,1-Diethyl-3-methylpentane (a). Number of p. 4
32. The correct IUPAC name for the compound diastereomer of
C2FClBrI
(b). No. of isomeric q. 4
is alcohole of C4H10O
(c). No. of isomeric r. 6
ester
(1) 3-(1-Ethylpropy) hex-1-ene
(2) 3-Ethyl-4-ethenyl heptane Mo
(3) 3-Ethyl-4-propyl hex-5ene (d). No. of s. 3
(4) 4-Ethyl-3-propyl hex-1-ene Me
33. The IUPAC name of stereo Isomer
(1) a (p) , b (q), c (r), d (s)
CH 3  CH 2  CH  C  CH 2 (2) a (r) , b (p), c (q), d (s)
| |
CH 2 CH 3 (3) a (q) , b (p), c (r), d (s)
| (4) a (s) , b (q), c (s), d (p)
CH 3 38. Correct order of enol content of given compound will
be
(1) 2-Methyl-3-ethyl-1-pentene
(2) 3-Ethyl-4-methyl-4-pentene O O
O O
(3)3-Ethyl-2-methyl-1-pentene I. II.
H 5 C2 O OC2H5
(4) 3-Methyl-2-ethyl-1-pentene
34. Which of the following carbocation is most stable O O
O O
OCH 3 III. IV.
OCH3 Ph Ph OC 2H 5
(1) (2) (1) III > I > IV > II (2) IV > II > I > III
+
(3) II > III > I > IV (4) I > III > II > IV
H 3CO 39. Which of the following has negligiable enol content
(3) (4) H CO
3
O O
35. Decreasing order of stability of following free radical (1) || ||
CH 3  C  CH 2  C  CH 3
Me Me

O
I. II. O
(2)
O
Me Me
O
III. IV. O
(3)
(1) III > I > II > IV (2) I > II > IV > III

IIB-PCM EXAM AKOLA PAGE NO. 2

 O
(x) NH (y) N H (z) N
(4)
O
O
(1) x > y > z (2) z > x > y
40. Which of following will show geometrical Isomer’s (3) x > z > y (4) y > z > x
Br Cl CH3 46. Increasing order of acidic strength of given compound
(1) C C (2) C is
I Cl CH3
OH OH
Et I. II
F CH3
H3 C H3 C NC
(3) C C (4) H C
Cl 3 CH3
Et OH OH
41. The name of the compound is
III. IV.
CH3 O
(1) III < I < IV < II (2) II < I < IV < III
(3) I < III < IV < II (4) I < III < II < IV
(1) (2z, 4z) 2, 4 - Hexadiene
47. The absolute configuration of the following compound
(2) (2z, 4E) 2,4 Hexadiene
is
(3) (2E, 4z) 2,4 Hexadiene
(4) (2E,4E) 2,4 Hexadiene CH 3
42. Heat of hydrogenation is maximum for 2
H Cl
CH3 Me 3 H
Cl
(1) (2) CH3

(1) 2S, 3R (2) 2R, 3S

CH 2 CH 3 (3) 2S, 3S (4) 2R, 3R
(3) (4) 48. Energy order of conformation of cyclohexane
chair half-chair boat
  
I II III
43. Arrange the anions (p) C H 3 , (q) N H 2 , (r) O H , twist boat
IV
(s) F decreasing order of basic strength (1) I > II > III > IV (2) I > IV > III > II
(1) p > q > r > s (2) q > p > r > s (3) II > III > IV > I (4) III > IV > II > I
(3) r > q > p > s (4) r > p > q > s 49. IUPAC nomenclature of the following compound

H H H OH

x z
44. y
CN
H H Br

Arrange the (C–H) bonds x,y,z in decreasing order of (1) 4-Bromo-3-cynophenol

their bond dissociation energies (2) 2-Bromo-5-hydroxybenzonitrile
(1) y > x > z (2) z > x > y (3) 2-cyano-4-hydroxybromobenzane
(3) z > y > x (4) y > z > x (4) 6-Bromo-3-hydroxybenzo-nitril
45. The correct order of decreasing basic strength of x, y
and z is

IIB-PCM EXAM AKOLA PAGE NO. 3

50. IUPAC name of the following compound
CH 3  CH  CH  C  CH 59. CH2 NH

(1) pent-4-yn-2-ene   
(2) pent-2-en-4-yne C H 3 , C H 3 , C H 2  CH  CH 2 , CH  CH
(3) pent-3-en-1yne Total number of above species show SP2 hybridization
(4) pent-1yn-3-ene
51. Total number of stereo Isomer for the following 60. No. of following compound are Quasi-aromatic
compound are
O

52. Number of following compound are aromatic

+ +
,
+

NH

53. No. of sigma and pi bond in tetracyno ethylene

54. No. of geometrical Isomer

CH C C CH

55. CH 3  CH  C  CH  CH  CH  CH 3

56. How many chiral center in following compound

Cl

57. Degree of unsaturation in the following compound

NC

CH=O

58. The most basic Nitrogen in given compound is

1N
3
2 NH N

IIB-PCM EXAM AKOLA PAGE NO. 4