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    MSDS

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    PETRON INDUSTRIAL DIESEL FUEL Maen sa ‘SECTION 4: ‘PRODUCT AND COMPANY IDENTIFICATION Product Name PETRON INDUSTRIAL DIESEL FUEL ‘Manufacturer PETRON CORPORATION JESUS ST., PANDACAN, MANILA Chemical Family Petroleum Hydrocarbons Product Type Petroleum Distillate Emergency Phone No. (632) 563-31-21 Hazard Degree of Hazard NFPA Hazard Identification Blue - Health 0- Least Red--Flammability 1 Slight >» Yellow - Reactivity 2-Moderate White Special 3 High, 4 Extreme SECTION 2 Hazardous Ingredients ‘COMPOSITION / INFORMATION ON INGREDIENTS ‘The product predominantly consists of aliphatic, alicyclic and aromatic hhydrocatbons. In general, the product is combustible and may contain carcinogenic components. However, as long as normal precautions in handling petroleum products are observed and good standards of industrial ‘and personal hygiene are maintained, no significant safety and health hazard is expected. SECTION 3: HAZARDS IDENTIFICATION Primary Entry Routes Inhalation of vapors, eye contact, skin contact/absorption ‘Target Organs Respiratory system, eyes, skin Bye Contact ‘May cause eye fritation upon direct contact. Skin Contact Low order of toxicity under normal use. However, avoid prolonged or repeated contact with the product to prevent defatting and dermatitis. Carcinogenic materials are also present. Ingestion Ingestion fs an unlikely event. However, accidental ingestion can lead to vomiting and aspiration into the lungs. This can result in chemical ‘pneumonitis, which can be fatal. Revd cauaae leave Date: 04/2006 Page 1 of 5 Scanned with CamScanner PETRON INDUSTRIAL DIESEL FUEL Inhalation Workplace Exposure Limits [Not expected to present an inhalation hazard under normal conditions. Exposure to high vapor concentrations can lead to nausea, headache and dizziness. Prolonged and excessive exposure to mists may cause chronic {inflammatory reaction of the lungs and a form of pulmonary fibrosis. There ts no known limit for the product. However, available information recommends a maximum exposure Umit of 100 ppm (8-hour Time Weighted Average) for aromatic and aliphatic compounds, which may be present as. ‘mixed hydrocarbons in alr Oil mists must nat exceed § mg/m’, SECTION 4 FIRST AID MEASURES Eye Contact Rinse eyes immediately with plenty of water for at least 15 minutes or Until tritatlon subsides. If fretation persists, get prompt medical attention, ‘Skin Contact Immediately clean contaminated skin with soap and water. Remove ‘contaminated clothing, including shoes, and launder before reuse. Ingestion If swallowed, DO NOT induce vomiting due to risk of aspiration into the lungs. Give plenty of water to drink. Keep at rest and seek medical attention immediately. Inhalation, If overexposed to oll mist, remove affected person immediately to fresh air. Administer artificlal respiration if breathing is irregular or has stopped. Call for prompt medical attention. SECTION 5: FIRE FIGHTING MEASURES Flash Point, PM, °C. B ‘Autoignition Temp., °C 220 Extingutshing Media Special Fire-fighting Incase of fire use foam, carbon dioxide or dry chemical extinguishers. Do not use water to extinguish fire unless in conjunction with Procedures foam compound or in cooling exposed surfaces or containers. Vapors are heavier than air and may travel considerable distances to a source of {ignition and flashback. Decomposition Products Carbon dioxide, carbon monoxide, particulate matter, water, polycyclic under Fire Conditions aromatic hydrocarbons, nitrogen oxides, hydrogen sulfide, unburnt hydrocarbons, unidentified organic and inorganic compounds are expected from normal combustion, SECTION "ACCIDENTAL RELEASE MEASURES Land Spill ‘Taking normal safety precaution, shut off source of product. Prevent the Liquid from entering sewers, water courses of low: lying areas. Advise the relevant authorities, taking measures to minimize the effects on ground water. Recover from surface by skimming or pumping using explosion-proof Revd eaudde Issue Date: 04/2006, age Zot S Scanned with CamScanner PETRON INDUSTRIAL DIESEL FUEL, equipment, booms or other suitable absorbent and remove mechanically {nto containers. If necessary, dispose material according to regulations of local authorities and environmental agencies. Water spilt Use booms to confine spills immediately. Remove from the water surface by skimming or with suitable absorbents. If permitted by local authorities and environmental agencies, disperse the residue in unconfined waters. Consult an expert on disposal of recovered material and ensure conformity, to local aisposal regulations. SECTION 7 HANDLING AND STORAGE Handling Procedures Keep away from potential sources of ignition. Open container in a well- ventilated area. Avold breathing vapors. Keep containers closed when not jn use. Prevent small spills and leakages to avoid slip hazard. Wash ‘thoroughly after handling. “Empty” containers and retain product residue (Wiquid or vapor) can be dangerous. Do not pressurize, cut, weld, braze, solder, dril, grind or expose containers to heat, flame, sparks, static electricity of other sources of ignition; they may explode and cause death or injury. Empty drums should be completely drained, properly bunged and. ‘Promptly returned to a drum reconditioner, or property disposed of Storage Procedures ‘Store in cool, well-ventilated areas, away {rom sources of Ignition. SECTION 8: EXPOSURE CONTROL/PERSONAL PROTECTION Ventilation Procedures Use local exhaust ventilation to control mists or vapors. Additional Ventilation or exhaust may be required to maintain air concentrations below exposure limits. Gloves Protection Use chemical resistant gloves. Eye Protection In case of splashing, wear safety glasses with side shields, Respiratory Protection Use NIOSH/MSHA approved full-face respirator with a combination organic vapor and high efficiency filter cartridge if the recommended exposure limit fs exceeded. Use self-contained breathing apparatus for entry into confined space, for other poorly ventilated areas and for large spill clean- up sites, (Clothing Recommendation Wear either a chemical protective suit or apron when potential for contact with material exists. Use neoprene or nitrile rubber boots when necessary to avoid contaminating shoes. Do not wear rings, watches or similar apparet that could entrap the material and cause a skin reaction, SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Density at 15°C, kg/m3 837.4 Water Solubitity Insoluble Revd cavade Issue Date: 04/2008 Page 30f 5 Scanned with CamScanner QP Ta PETRON INDUSTRIAL DIESEL FUEL ‘Odor Characteristic of petroleum products Appearance Clear Color, ASTM 5.0 kv at 40°C, cst 3.740 SECTION 10: ‘STABILITY AND REACTIVITY Stability Material fs normally stable at ambient temperature Incompatibility ‘Strong oxidizing agents Polymerization Will not occur. Hazardous Decomposition In case of combustion or thermal decomposition, carbon Products monoxide and other toxic and tritant fumes may be formed. SECTION ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic organisms and may cause long-term adverse effects to the aquatic environment; biodegradable in aerobic conditions; non biodegradable in anaerobic conditions with high potential to bioaccumulate. SECTION T DISPOSAL CONSIDERATIONS ‘Waste Disposal Material, if discarded, is expected to be hazardous waste. The product ‘may be burned under controlled conditions and should be in compliance with local and national waste management regulations. SECTION 13: "TRANSPORT REGULATIONS, uN UN Number 1202 Packing Group i Hazard Class 3 Road / Rail (ADR / RID) ‘ADR UN Number 1203 ‘ADR Item Number 310) ‘Tremeard TECIR)27 ‘ADR Hazard Class 3 ‘ADR / RID Number 0 Sea (WADG) TMOG UN Number s202 MDG Page Number 3375. MOG Hazard Class 07 Scanned with CamScanner if PETRON INDUSTRIAL DIESEL FUEL UNDG Pack Group 33 IMDG MFAG iW Air (ICAO / IATA) ICAO UN Number 1202 ICAO Packing Group m ICAO Hazard Class, 3 SECTION 14 [APPROVALS Approvals ‘Technical Department Petron Corporation This is a computer-generated form and does not require a signature. “The information prevented heratn has bean compiled fram sources considered to be dependable and f accurate to the best of Petron Corporation's knowledge. This lnformation relates only to the specific material designated and may not be valid when this material ts combined with aay other material or In any process. However, Petron Corporation makes 90 warranty or guarantee as to fts accuracy, rellablity or completeness. Its the user's responsiblity to satisfy himself as to the suitability and Zompleteness of such information for his own particular use. Petron Corporation assumes no responsibility for Injury to recipient (oF to third persons or for any damage to any property that may occur from the use ofthis nfermation. Revd cauiee Issue Date: 04/2005 Page Sof 5 Scanned with CamScanner Safety Data Sheet D COM NTIFICATION Chevron (Philippines) Diesel Fuel Oil Product Use: Fuel Product Number(s): 850032, 850332, 850732, 850832, 851232, 851332, 851432, 851532 ‘Company Identification Chevron Philippines, Inc. 6/£6750 Ayala Avenue 1226 Makati City ‘Metro Manila Philippines +63 2841 1000 ‘Transportation Emergency Response 1. Transportation Emergency: 911 b. CHEMTREC: +1 (800) 424-9300 or +1 (703) $27-3887 Health Emergency a. Health Emergency: 911 ’b. Chevron Emergency Information Center: Located in the USA. International collet calls accepted. (800) 231- (0623 or ($10) 231-0623, (SECTION? TAZARDS IDENTIFICATION ] CLASSIFICATION: Flammable liquid: Category 3. Aspiration toxicant: Category 1. Carcinogen: Category 1B. Skin irtation: Category 2. Target organ toxicant (repeated exposure): Category 2. Target organ toxicant (central nervous system): Category 3. Acute inhalation toxicant: Category 4. Acute aquatic toxicant: Category 1. Chronic aquatic toxicant: Category 1. DODD Signal Word: Danger Physteal Hazards: Flammable liquid and vapour (11226) Health Hazards: May be fatal if swallowed and enters airways (11304). May cause cancer (11350). Causes skin invitation (H315). Harmful iC inhaled (H332). May cause drowsiness or dizziness (H336). fay cause damage to organs (Blood/Dlood Forming Organs, Liver, Thymus) through prolonged or ‘Target Organs: 59) Diesel Fuel Ot Revision Number: 6 Cheveon Phil Revision Date: July 26,2018 les SDs: 18562 Scanned with CamScanner repeated exposure (H373), Environmental Hazards: Very toxic to aquatic life with long lasting effects (H410). PRECAUTIONARY STATEMENTS: General: Keep out of each of children (P102). Read label before use (P103).. Prevention: Obtain special instructions befor use (P201). Donot handle until al safety precautions have been read and understood (P202), Keep away from heatparks/open Nameshot surfaces. ~ No smoking (P210). Use conly non-sparking tools (P242). Take precautionary measures agains static discharge (P243). Keep container tightly closed (P233). Use explosion-proof clectrical/venilating/lighting/equipment (P241). Do not breathe benzene solubles] ‘Consult local authorities for appropriate values. ‘SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES ] Attention: the data below are typical values and do not constitute a specification. Varies depending on specification Physical State: Li Odor: Petroleum odor Odor Threshold: No data available pH: Not Applicable Vapor Pressure: 0.04 kPa (Approximate) @ 40°C (104% Vapor Density (Air= 1): >I Boiling Point: 175.6°C (348°F) ~370°C (698°F) Solubility: Soluble in hydrocarbons; insoluble in water Freezing Point: Not Applicable Melting Point: Not Applicable Specific Gravi 0.80 - 0.88 @ 15.6°C (60.1°F) (Typical) 860 ke/m3 @ 15°C (59°F) Viscosity: 2 St @ 40°C (104°F) Coefficient of Therm. Expansion /°F: Evaporation Rate: No data available Octanol/Water Partition Coefficient: No data available Combustion Characteristics (Solids/Gases): No data available inimum, ‘No data available smber: 6 . Chevron (Pit Sly 26,2018 4a SDS! 14562 Scanned with CamScanner Decomposition Temperature: No data available Boiling Range: Not Applicable FLAMMABLE PROPERTIES: Flashpoint: (Pensky-Martens Closed Cup) $$°C (131 °F) Minimum Autoignition: 257°C (494°F) Flammability (Explosive) Limits (% by volume in alr): Lower: 0.6 Upper: 4.7 ‘SECTION 10_ STABILITY AND REACTIVITY ] Reactivity: May react wit strong acids or strong oxidizing agents, such as chloraes, nitrates, peroxides, etc. Chemical Stability: This material is considered stable under normal ambient and anticipated storage and hhandling conditions of temperature and pressure. Incompatibility With Other Materials: Not applicable Hazardous Decomposition Products: None known (None expected) Hazardous Polymerization: — Hazardous polymerization will not occur. ‘SECTION 11 TOXICOLOGICAL INFORMATI IMMEDIATE HEALTH EFFECTS Eye: Not expected to cause protonged or significant eye iitton Eye Irritation: The eye iitation hazard is based on evaluation of data for product components, Ski ‘ontact with the skin causes imitation. Skin contact may eause drying or defating ofthe skin. Symptoms ude pai, itching, discoloration, swelling and blistering. Contact with the skin is not expected fo cause an allergic skin response. ‘Acute Dermal Toxicity: The acute dermal toxicity hazard i based on evaluation of data for similar materials, Skin Irritation: | The skin invitation hazard is based on evaluation of data for product components. Skin Sensitization: |The skin sensitization hazard is based on evaluation of data for similar materials, Ingestion: Highly toxic; may be fatal swallowed. Because ofits low viscosity, this material can directly enter the lungs, if swallowed, or ifsubsequently vomited. Once in the lung itis very difficult to remove and can cause severe injury or death, "May be iritating to mouth, throat, and stomach. Symptoms may include pain, nausea, vomiting, and diarthea. ‘Acute Oral Toxicity: |The acute oral toxicity hazard is based on evaluation of data fr similar materials Inhalation: May be harmful if inhaled. Excessive or prolonged breathing of this material may cause central nervous system effects, Central nervous system effects may include headache, dizziness, nausea, vomiting, ‘weakness, loss of coordination, blurred vision, drowsiness, confusion, or disorientation. ‘At extreme exposures, central nervous system effects may include respiratory depression, tremors or convulsions, loss of consciousness, ‘coma or death ‘Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for similar materials. Acute Toxielty Estimate: Not Determined DELAYED OR OTHER HEALTH EFFECTS: Cancer: Whole diese engine eshaust has been classified as a Group 2A carcinogen (probably carcinogenic to humans) by the Intemational Agency for Research on Cancer (IARC). Prolonged or repeated exposure to this material may cause cancer. Contains naphthalene, which has been classified as a Group 2B carcinogen (possibly carcinogenic to humans) by the Intemational Agency for Research on Cancer (IARC). Diesel exhaust particulate has been classified as reasonably anticipated tobe a human carcinogen inthe National Toxicology Program's Ninth Report on Carcinogens. The National Institut of Occupational Safety and Health (NIOSH) has recommended that ‘whole diesel exhaust be regarded as potentially causing cancer, Diese! engine exhaust is known to the State of California to cause cancer. Revision Number: 6 Revsln Date: July 26,2018 oat Scanned with CamScanner ‘Target Organs: Contains material that may cause damage to the following organ(s) following repeated contact based on animal data:Liver Blood/Blood Forming Organs Thymus 11 for additional information. — Risk depends on duration and level of exposure. NAL TOXICOLOGY INFORMATION: ‘Cat Cracked Distillate, Light was found to bea skin carcinogen after twice a week application to C3H mice over their lifetime. This material was also determined to be a skin tumor promoter with weak initiating activity in CD-1 ‘This product contains naphthalene GENERAL TOXICITY: _ Exposure to naphthalene has been reported to cause methemoglobinemia and/or hemolytic anemia, especially in humans deficient in the enzyme glucose-6-phosphate dehydrogenase. Laboratory ‘animals given repeated oral doses of naphthalene have developed cataracts. REPRODUCTIVE TOXICITY AND BIRTH DEFECTS: Naphthalene didnot eause bin defects when administered orally to abbits, rats, and mice during pregnancy, but slightly reduced litter size in mice at dose levels that were lethal to the pregnant females. Naphthalene has been reported to cross the human placenta. GENETIC TOXICITY: Naphithalene caused chromosome aberrations and sister chromatid exchanges in Chinese hamster ovary cells, but was not a mutagen i several other in-vitro tests CARCINOGENICITY: In a study conducted by the National Toxicology Program (NTP), ‘mice exposed to 10 or 30 ppm of naphthalene by inhalation daily for two Years had chronic inflammation of the nose ‘and lungs and increased incidences of metaplasia in those tissues. The incidence of benign lung tumors (alveolar/bronchiolar adenomas) was significantly increased in the high-dose female group but not in the male groups. In another two-year inhalation study conducted by NTP, exposure of rats to 10, 30, and 60 ppm naphthalene ‘caused increases in the incidences of a variety of nonneoplastc lesions in the nose, Increases in nasal tumors were seen in both sexes, including olfactory neuroblastomas in females at 60 ppm and adenomas of the respiratory epithelium in males at all exposure levels, The relevance of these effects to humans has not been established. No carcinogenic effect was reported in a 2-year feeding study in rats receiving naphthalene at 41 mg/kg/day. This product contains gas oils CONCAWE (product dossier 95/107) has summarized current health, safety and environmental data available for a number of gas oils, typically hydrodesulfurized middle distillates, CAS 64742-80-9, straight-un middle distillate, ‘CAS 64741-44-2, andor light eat-

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