NEET

ARJUNA NEET 2025

Practice Sheet
Physical Chemistry
Some Basic Concepts of Chemistry

Q 1 The total number of electrons in 1.6 g of CH4 to that Q 10 The atomic composition of the entire universe is
in 1.8 g of H2O approximately given in the table below:
Atom % of total number of atoms
(A) Double (B) Same
H 93
(C) Triple (D) One fourth He 7
what percentage of the universe hydrogen atoms
Q 2 A gas has a vapour density 11.2. The volume occupied
constitute by mass?
by 1 g of the gas at NTP is:
(A) 77 % (B) 23 %
(A) 1 L (B) 11.2 L
(C) 37 % (D) 73 %
(C) 22.4 L (D) 4 L
Q 11 Which of the following alkanes has 75% of carbon?
Q 3 3 g of hydrocarbon on combustion with 11.2 g of
(A) C2H6 (B) CH4
oxygen produce 8.8 g of CO2 and 5.4 g of H2O. The
(C) C3H8 (D) C4H10
data illustrate the law of:
(A) conservation of mass Q 12 An organic compound contains 49.30% carbon,
(B) multiple proportions 6.84% hydrogen and its vapour density is 73.
(C) constant proportions
Molecular formula of the compound is:
(D) reciprocal proportions
(A) C3H8O2 (B) C3H10O2
Q 4 The maximum number of molecules is present in: (C) C6H9O (D) C6H10O4
(A) 15 L of H2 gas at STP
Q 13 The crystalline salt Na2SO4 .xH2O on heating loses
(B) 5 L of N2 gas at STP
55.9% of its mass. The formula of crystalline salt is:
(C) 0.5 g of H2 gas
(A) Na2SO4.5H2O (B) Na2SO4.7H2O
(D) 10 g of O2 gas
(C) Na2SO4.2H2O (D) Na2SO4.10H2O
Q 5 Insulin contains 3.4% sulphur. Then, the minimum
Q 14 x gram of CaCO3 was completely burnt in absence of
molecular mass of the insulin is about:
(A) 940 amu (B) 9400 amu air. The mass of the solid residue formed is 28 g. What
(C) 3600 amu (D) 970 amu is the value of ‘x’ in gram?
(A) 44 (B) 200
Q 6 25 g of MCl4 contains 0.5 mol chlorine then its gram (C) 150 (D) 50
molecular mass is:
Q 15 The mass of carbon anode consumed (giving only
(A) 100 g mol-1 (B) 200 g mol-1
carbon dioxide) in the production of 270 kg of Al
(C) 150 g mol-1 (D) 400 g mol-1
metal from bauxite by Hall process is:
(A) 270 kg (B) 540 kg
Q 7 An unknown element forms an oxide. What will be
(C) 90 kg (D) 180 kg
the equivalent mass of the element if the oxygen
content is 20% by mass? Q 16 The equivalent mass of an element is 4. Its chloride
(A) 16 (B) 32 has vapour density 59.25. Then the valency of the
(C) 8 (D) 64 element is:
(A) 4 (B) 3
Q 8 A metal M of equivalent mass E forms an oxide of
(C) 2 (D) 1
molecular formula MxOy. The atomic mass of the
metal is given by the correct equation: Q 17 Sulphur trioxide is prepared by the following two
(A) 2E(y/x) (B) xyE reactions:
(C) E/y (D) y/E S 8 (s) + 8O 2 (g) → 8SO 2 (g)

Q 9 A gas mixture contains 50% helium and 50% methane 2SO 2 (g) + O 2 (g) → 2SO 3 (g)

by volume. What is the percentage by mass of How many grams of SO3 are produced from 1 mole
methane in the mixture? S8?
(A) 19.97 % (B) 20.05 %
(A) 1280 (B) 640
(C) 50 % (D) 80 %
(C) 960 (D) 320
Q 18 Calculate the number of millilitres at STP of H2S gas (A) A-Q , B-S , C-P , D-R
needed to precipitate cupric sulphide completely from (B) A-S , B-R , C-P, D-Q
100 mL of a solution containing 0.75 g of CuCl2 . (C) A-S , B-R , C-Q , D-P
(D) A-R , B-S , C-P , D-Q
(A) 21.4 (B) 14.2
(C) 41.2 (D) 124 Q 24 Match the Column-I with Column-II for the reaction:
A + B2 →AB2
Q 19 In the reaction,
3As 2 S 3 + xH N O 3 + 4H 2 O → 9H 2 SO 4 + yN O
Column I Column II
+ 6H 3 AsO 4 300 atoms of A +
A. B2 is limiting reagent
the values of x and y are: 200 molecules of B2 P.
(A) 28, 28 (B) 10, 10 100 atoms of A +
B. 100 molecules of B2 Q. A is limiting reagent
(C) 30, 30 (D) 20, 20
5 mol of A +2.5 mol None of the reactant
C. of B2 R.
Q 20 Match the Column I with Column II. is in excess
Column I Column II 2.5 mol of A + 5 mol 200 molecules of A
D. of B2 S. B will be formed
Equal volumes of all 2
gases contain equal Dalton's atomic (A) A-R , B-S , C-Q , D-P
A. (i)
number of molecules theory (B) A-S , B-R, C-P, D-Q
at NTP.
The atom is Law of conservation (C) A-S , B-R, C-Q , D-P
B. (ii)
indestructible. of mass (D) A-R , B-S , C-P , D-Q
All pure samples of
the same compound Q 25 Number of atoms in 4.25 g of NH3 is:
contain the same
C. (iii) Avogadro's law (A) 6. 023 × 10 23
elements combined
in the same (B) 4 × 6. 023 × 10 23

proportion by mass.
(C) 1. 7 × 10 24

Total mass before

and after the Law of constant (D) 4. 5 × 6. 023 × 10
23

D. (iv)
chemical reaction is proportions
same. Q 26 0.32 g of a metal gave, on treatment with an acid, 112
Gases react in simple mL of hydrogen at NTP. Calculate equivalent mass of
E. ratio of their (v) Gay-Lussac’s law
volumes. the metal:
(A) A – (ii), B – (iii), C – (v), D –(i), E – (vi) (A) 58 (B) 32
(B) A – (iii), B – (i), C – (iv), D –(ii), E – (v) (C) 11.2 (D) 24
(C) A – (v), B – (iv), C – (ii), D –(iii), E – (i)
Q 27 Statement-I: Avogadro’s number is a dimensionless
(D) A – (ii), B – (iii), C – (iv), D –(v), E – (i)
quantity.
Q 21 Match the Column I with Column II Statement-II: It is a number of atoms or molecules in
Column I Column II one gram mole.
A. Vapour density P. Unitless (A) Statement I and Statement II both are correct.
B. Mole Q. 2 moles (B) Statement I is correct but Statement II is incorrect.
Collection of 6.023 × (C) Statement I is incorrect but Statement II is correct.
C. 24 g carbon R.
1023 atoms (D) Statement I and Statement II both are incorrect.
D. Equivalent S. Molecular mass × 1

(A) A-R , B-S , C-Q , D-P Q 28 Statement-I: An element has variable equivalent

(B) A-S , B-R, C-P, D-Q mass.

(C) A-S , B-R, C-Q , D-P Statement-II: The valency of element is variable. .
(D) A-R , B-S , C-P , D-Q (A) Statement I and Statement II both are correct.
(B) Statement I is correct but Statement II is incorrect.
Q 22 Match the Column I with Column II (C) Statement I is incorrect but Statement II is correct.
Column I Column II (D) Statement I and Statement II both are incorrect.
A. 16g CH4 P. 0.1 mol
B. 1.7g NH3 Q. 6 moles of C Q 29 Statement-I: Vapour density of CH4 is half of O2.
C. HCHO R. 40% carbon Statement-II: 1.6 g of CH4 contains same number of
1 mole of
D. S. 1 mole electrons as 3.2 g of O2.
C6H12O6
(A) A-S , B-P , C-R, D-Q (A) Statement I and Statement II both are correct.

(B) A-R , B-S , C-Q , D-P (B) Statement I is correct but Statement II is incorrect.
(C) A-R , B-S , C-P , D-Q (C) Statement I is incorrect but Statement II is correct.
(D) A-S , B-R , C-Q , D-P (D) Statement I and Statement II both are incorrect.

Q 23 Match the Column I with Column II. Q 30 Match the Column-I with Column-II:
Coumn I Coumn II
Column I Column II
Heaviest particle of A. N2 P. 27 % carbon by mass
A. 1 amu P.
atom B. CO2 Q. Empirical formula CH2O
B. Proton Q. 1.66 ×10-27 kg C. C6H12O6 R. 22 NA electrons in one mole
C. Neutron R. 4
2
He D. N2O S. 14 NA electrons in a mole
D. α -particle S. Positively charged
 (A) A-R , B-S , C-Q , D-P Reason (R) : Equivalent weight = M olecular weight

n− f actor

(B) A-S , B-P, C-Q, D-R (A) If both Assertion & Reason are true and the
(C) A-S , B-R , C-Q , D-P reason is the correct explanation of the assertion.
(D) A-R , B-S , C-P , D-Q (B) If both Assertion & Reason are true but the reason
is not the correct explanation of the assertion.
Q 31 Match the Column-I with Column-II:
Column I Column II (C) If Assertion is true statement but Reason Is false.
A. 1 L P. 10-5 N (D) If both Assertion and Reason are false statements.
B. 1 J Q. 0.2389 cal
Q 37 Assertion (A) : Mass of 1 gram molecule of H2SO4 is
C. 1 mole R. 10-3 m3
98 gram.
D. 1 Dyne S. 6.022 × 1023
particles Reason (R) : One gram atom contains NA atoms
(A) A-R , B-S , C-Q , D-P (A) If both Assertion & Reason are true and the
(B) A-S , B-R , C-P, D-Q reason is the correct explanation of the assertion.
(C) A-R , B-Q , C-S , D-P (B) If both Assertion & Reason are true but the reason
(D) A-S , B-R , C-Q , D-P is not the correct explanation of the assertion.
(C) If Assertion is true statement but Reason Is false.
Q 32 Match the Column-I with Column-II:
(D) If both Assertion and Reason are false statements.
Column-I Column-II
A. 1 mole of O2(g) P. 32 g Q 38 Assertion (A) : One mole of sucrose reacts
B. 1 mole of SO2(g) Q. 64 g completely with oxygen produces 268.8 litre of
carbon dioxide at STP.
C. 1 g of H2(g) R. 11.2 L at STP
Reason (R) : Amount of oxygen required for reaction
D. 0.5 mole of O3(g) S. 1.5 6.023
× × 1023 is 268.8 litre.
atoms
(A) If both Assertion & Reason are true and the
(A) A-P , B-Q , C-R , D-S
reason is the correct explanation of the assertion.
(B) A-S , B-R, C-P, D-Q
(B) If both Assertion & Reason are true but the reason
(C) A-S , B-R, C-Q, D-P
is not the correct explanation of the assertion.
(D) A-R , B-S, C-P, D-Q
(C) If Assertion is true statement but Reason Is false.
Q 33 Assertion (A) : 1 a.m.u. = 1.66 × 10-24 gram. (D) If both Assertion and Reason are false statements.
Reason (R) : Actual mass of one atom of C-12 is
Q 39 Assertion (A) : In the reaction
equal to 1.99 x 10-23 g 2N aOH + H 2 SO 4 → N a 2 SO 4 + 2H 2 O ,
(A) If both Assertion & Reason are true and the equivalents of NaOH. Na2SO4 and H2SO4 are equal.
reason is the correct explanation of the assertion.
Reason (R) : Number of equivalents = number of
(B) If both Assertion & Reason are true but the reason
moles × n-factor.
is not the correct explanation of the assertion.
(A) If both Assertion & Reason are true and the
(C) If Assertion is true statement but Reason Is false.
reason is the correct explanation of the assertion.
(D) If both Assertion and Reason are false statements.
(B) If both Assertion & Reason are true but the reason
Q 34 Assertion (A) : Unit of specific gravity is gram-cc-1. is not the correct explanation of the assertion.
(C) If Assertion is true statement but Reason Is false.
Reason (R): Specific gravity is same as density of a
(D) If both Assertion and Reason are false statements.
liquid in normal conditions.
(A) If both Assertion & Reason are true and the Q 40 Assertion (A) :When 4 moles of H2 reacts with 2
reason is the correct explanation of the assertion.
moles of O2. then 4 moles of water is formed.
(B) If both Assertion & Reason are true but the reason
is not the correct explanation of the assertion. Reason (R) : O2 will act as limiting reagent.

(C) If Assertion is true statement but Reason Is false.
(D) Assertion is false and Reason is true.
Q 35 Assertion (A) : Number of atoms in 2 mole of NH3 is
equal to number of atoms in 4 mole of CH4.
Reason (R) : Both are chemically similar species.
(A) If both Assertion & Reason are true and the
Q 41 Assertion (A) : 50 ml decinormal H Cl when mixed
reason is the correct explanation of the assertion.
(B) If both Assertion & Reason are true but the reason
(A) If both Assertion & Reason are true and the
reason is the correct explanation of the assertion.
(B) If both Assertion & Reason are true but the reason
is not the correct explanation of the assertion.
(C) If Assertion is true statement but Reason Is false.
(D) If both Assertion and Reason are false statements.
with 50 ml decinormal H2SO4. then normality of H+

is not the correct explanation of the assertion.
(C) If Assertion is true statement but Reason Is false.
(D) If both Assertion and Reason are false statements.
Q 36 Assertion (A) : In the reaction;
2N aOH + H 3 P O 4 → N a 2 H P O 4 + 2H 2 O
equivalent weight of H3PO4 is M
ion in resultant solution is 0.1 N.
Reason (R) : Here. M V = M1 V1 − M2 V2 .
(A) If both Assertion & Reason are true and the
reason is the correct explanation of the assertion.
(B) If both Assertion & Reason are true but the reason
is not the correct explanation of the assertion.

2
, where M is its (C) If Assertion is true statement but Reason Is false.
molecular weight.
 (D) If both Assertion and Reason are false statements. (A) If both Assertion & Reason are true and the
reason is the correct explanation of the assertion.
Q 42 Assertion (A) : 50 ml decimolar H2SO4 when mixed
(B) If both Assertion & Reason are true but the reason
with 50 ml decimolar NaOH. then normality of is not the correct explanation of the assertion.
resultant solution is 0.05 N. (C) If Assertion is true statement but Reason Is false.
Reason (R) : Here, NV = N1V1 - N2V2 . (D) If both Assertion and Reason are false statements.
(A) If both Assertion & Reason are true and the
Q 48 Match the Column I with Column II and choose the
reason is the correct explanation of the assertion.
correct option from the codes given below.
(B) If both Assertion & Reason are true but the reason
Column I Column II
is not the correct explanation of the assertion.
Mass of H2
(C) If Assertion is true statement but Reason Is false. produced when 0.5
A. 3.01 x 1023
(D) If both Assertion and Reason are false statements. mole of zinc reacts P.
molecules
with excess of
Q 43 Assertion (A) : Ratio of empirical formula mass and HCl.
molecular formula mass must be a natural number. Mass of all atoms
B.
of a compound
Q. 6.023 x 1023
Reason (R) : Molecular formula mass = n × with formula molecules
empirical formula mass, where n is the simplest whole C70H22
number. Number of
C. molecules in 35.5g R. 1.43 x 10-21g
(A) If both Assertion & Reason are true and the of Cl2.
reason is the correct explanation of the assertion. Number of
(B) If both Assertion & Reason are true but the reason D. molecules in 64 g S. 1g
is not the correct explanation of the assertion. of SO2.
(C) If Assertion is true statement but Reason Is false. (A) A-R , B-S , C-Q , D-P
(D) If both Assertion and Reason are false statements. (B) A-S , B-R , C-P, D-Q
(C) A-S , B-R , C-Q , D-P
Q 44 Assertion (A): For a given solution (density = 1 (D) A-R , B-S , C-P , D-Q
g/ml), molality is greater than molarity.
Reason (R): Molarity involves volume of solution Q 49 Match the items of Column I with Column II and
while molality involves mass of solvent. choose the correct codes from the options given
(A) If both Assertion & Reason are true and the below.
reason is the correct explanation of the assertion. Column I Column II
Mole
(B) If both Assertion & Reason are true but the reason A. P. M2 × V2
fraction
is not the correct explanation of the assertion.
B. Molarity Q. n×1000

(C) If Assertion is true statement but Reason Is false.

V(mL)

It is defined as the number of

(D) If both Assertion and Reason are false statements. C. Molality R. moles of solute present in 1
kg of solvent.
Q 45 Assertion (A) : 1 gram of salt in 1 m3 of solution has It is the ratio of number of
concentration of 1 ppm. moles of a partial component
D. M1 × V1 S.
to the total number of moles
Reason (R) : ppm is defined as number of parts by of the solution.
mass of solute per million parts of solution.
(A) If both Assertion & Reason are true and the (A) A-R , B-S , C-Q , D-P
reason is the correct explanation of the assertion. (B) A-S , B-Q , C-R, D-P
(B) If both Assertion & Reason are true but the reason (C) A-S , B-R , C-R , D-P
is not the correct explanation of the assertion. (D) A-R , B-S , C-P , D-Q
(C) If Assertion is true statement but Reason Is false.
Q 50 Match the Column I with Column II and choose the
(D) If both Assertion and Reason are false statements.
correct option from the codes given below.
Q 46 Assertion (A): Total charge on NA ions of CO 2−

3
is Column I Column II
10 g CaCO3
1.93 × 105 coulomb. A. Δ P. 0.224 L CO2
−→
Reasons (A) : Charge on one electron is 96500 Decomposition

coulomb. 1.06 g Na2CO3

B. Q. 4.48 L CO2
(A) If both Assertion & Reason are true and the Excess H Cl

−→
reason is the correct explanation of the assertion Excess O 2
C. 2.4 g C R. 0.448 L CO2
−→
(B) If both Assertion & Reason are true but the reason Combustion

is not the correct explanation of the assertion. 0.56 g CO

(C) If Assertion is true statement but Reason Is false. D. Excess O 2 S. 2.24 L CO2
−→
(D) If both Assertion and Reason are false statements. Combustion

(A) A – Q, B – S, C – P, D – R
Q 47 Assertion (A) : Number of ions in 9 gram of N H +

4
is (B) A – R, B – P, C – P, D – Q
equal to Avogadro's number (NA). (C) A – R, B – S, C – P, D – Q
Reason (R) : Number of ions is equal to number of (D) A – S, B – P, C – Q, D – R
atoms.
Q 51 Match the following Column I with Column II and (A) 10 L (B) 7 L
choose the correct codes from the option given below. (C) 6 L (D) 5 L
Column I Column II
A. 46 g of Na P. 0.01 mol Q 59 Volume occupied by one molecule of water (density =

6.022 × 1023 1 g cm-3) is

B. Q. 2 mol
molecules of H2O (A) 5.5 ×10-23 cm3
0.224 L of O2 at
C. R. 1 mol (B) 9.0 ×10-23 cm3
STP
6.022 × 1023 (C) 6.023 ×10-23 cm3
D. 84 g of N2 S.
atom/molecules (D) 3.0 × 10-23 cm3
E. 1 mole of any gas T. 3 mol
(A) A – Q, B – R, C – P, D – T, E – S Q 60 116 mg of a compound on vaporisation in Victor
(B) A – R, B – T, C – P, D – Q, E – S Meyer’s apparatus displaces 44.8 mL of air measured
(C) A – T, B – S, C – P, D – Q, E – R at STP. The gram molecular mass(g/mol) of the
(D) A – S, B – T, C – P, D – R, E – Q compound is:
(A) 116 (B) 232
Q 52 Match the following physical quantities with their
(C) 58 (D) 44.8
units and choose the correct codes from the options
given below.
Column I Column II
(Physical quantity) (Unit)
A. Molarity P. mol
B. Mole fraction Q. Unitless
C. Mole R. mol L-1
D. Molality S. mol kg-1
(A) A - R, B - Q, C - P, D - S
(B) A - Q, B - P, C - S, D - R
(C) A - S, B - Q, C - P, D - R
(D) A - P, B - Q, C - S, D - R

Q 53 A sample of ammonium phosphate (NH4)3PO4

contains 3 moles of hydrogen atoms. The number of
moles of oxygen atoms in the sample is
(A) 0.265 (B) 0.795
(C) 1 (D) 4.00

Q 54 Two metallic oxides contain 27.6% and 30% oxygen

respectively. If the formula of the first oxide is X3O4.
that of the second will be
(A) XO (B) XO2
(C) X2O5 (D) X2O3

Q 55 Calculate the molality of solution containing 3 g

glucose dissolved in 30 g of water, (molar mass of
glucose = 180 g/mol)
(A) 0.50 m (B) 0.56 m
(C) 0.091 m (D) 0.05 m

Q 56 An element, X has the following isotopic composition

: 200X : 90% 199X : 8% 202X : 2.0%. The weighted
average atomic mass of the naturally occurring
element X is closest to
(A) 201 amu (B) 202 amu
(C) 199 amu (D) 200 amu

Q 57 Which has the maximum number of molecules among

the following?
(A) 8 g H2 (B) 64 g SO2
(C) 44 g CO2 (D) 48 g O3

Q 58 What volume of oxygen gas (O2) measured at 0°C

and 1 atm, is needed to burn completely 1 L of
propane gas (C3H8) measured under the same
conditions?
 Answer Key
Q1 B Q31 C
Q2 A Q32 A
Q3 A Q33 A
Q4 A Q34 D
Q5 A Q35 D
Q6 B Q36 B
Q7 B Q37 B
Q8 A Q38 A
Q9 D Q39 A
Q10 A Q40 C
Q11 B Q41 C
Q12 D Q42 C
Q13 D Q43 D
Q14 D Q44 B
Q15 C Q45 A
Q16 B Q46 C
Q17 B Q47 D
Q18 D Q48 B
Q19 A Q49 B
Q20 B Q50 D
Q21 C Q51 A
Q22 A Q52 A
Q23 A Q53 C
Q24 B Q54 D
Q25 A Q55 B
Q26 B Q56 D
Q27 A Q57 A
Q28 A Q58 D
Q29 B Q59 D
Q30 B Q60 C

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