Subject Topic Practice Paper Date

Basic Principles in Chemistry-1,

Chemistry JEE-NEET&CET – 11
Atomic Structure-1

Useful Data
At. Wt.:
N = 14; O = 16; H = 1; S = 32; Cl = 35.5; Mn = 55; Na = 23; C = 12; Ag = 108; K = 39; Fe = 56; Pb = 207
Physical Constants:
h = 6.626  10 −34 Js , N a = 6.022  1023 mol-1 , c = 2.998  108 m s-1 , me = 9.110−31 kg , R = 8.314 J mol-1 K -1

The OMR sheet for 200 questions is to be used

Duration: 1 Hour
Answer all the questions.
1. The molar volume of any gas at 273K and 1 atm is given by

(a) 1 L (b) 22.4 L (c) 6.02  1023 L (d) 22.4 mL

2. The mass of a mole of hydrogen atoms is.

(a) 1.008g (b) 2.016g (c) 6.02  1023 g (d) 10 g

3. How many moles of hydrogen molecules are there in 12g of hydrogen gas?
(a) 1 (b) 6 (c) 2 (d) 12
4. One mole of molecules of nitrogen represents

(a) 6.02  1023 molecules of nitrogen

(b) 28g of nitrogen

(c) 14g of nitrogen

(d) Both (a) and (b)

5. The number of molecules in 1L of neon is.

6.022  1023
(a) (b) 6.022  1023 (c) 3.011 1023 (d) 6.022  1024
22.4
6. The number of molecules in 8.5g of NH 3 is

(a) 1025 (b) 1.5  1023 (c) 2  1023 (d) 3.011 1023
7. Calculate the volume occupied by 3 moles of methane at STP conditions?
(a) 112 L (b) 5L (c) 67.2 L (d) 22.4 L

8. What is the number of molecules present in 112 L of carbon dioxide at STP?

(a) 1.344  1023 (b) 6.022  1023 (c) 3.011  1024 (d) 1.344  1020

9. The number of atoms in 1.15 g of Na is approximately [Given Molar massof Na=23g mol-1]

(a) 1  1023 (b) 3  1024 (c) 4  1023 (d) 3  1022

10. The number of atoms of carbon present in 34.2g of sucrose is [Given Molar massof sucrose=342g mol-1]

(a) 12  6.022  1024 (b) 12  6.022  1020 (c) 12  6.022  1022 (d) 12  6.022  1023

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11. Find the charge on 27 g of Al 3+ ions in coulombs. (Molar mass of Al = 27 g mol−1 )

(a) 193096 C (b) 93096 C (c) 289500 C (d) 45096 C

12. How many grams of H 2 SO4 are present in 0.5 mole of H 2 SO4 ?

(a) 4.9 (b) 49 (c) 0.49 (d) 0.25

13. The number of atoms of oxygen present in 106 g of Na2CO3 ( Molar mass = 106 gmol −1) will be

(a) 1.806 1022 (b) 12.04 1022 (c) 1.806 1024 (d) 31.8
14. Which has maximum number of molecules?
(a) 7g N 2 (b) 2g H 2 (c) 35.5 g Cl2 (d) 16 g O2

15. What is the mass of 5.6 L of methane at STP?

(a) 16 g (b) 4 g (c) 8 g (d) 40 g

16. Which of the following is incorrect?

(a) Mass of electron = 9.1  10−31 kg

(b) Mass of proton = 1.673  10−31 kg

(c) Charge of electron = −1.602  10−19 C

(d) e / m for an electron = 1.76  108 C/g

17. Which of the following observations is correct regarding Rutherford’s scattering experiment?
(a) Most of the  − particles passed through the gold foil undeflected.
(b) A large fraction of the  − particles was deflected by small angles.
(c) A large number of the  − particles were bounced back.
(d) Very few of the  − particles passed through the gold foil undeflected.
18. What is the maximum number of emission lines when the excited electron of a hydrogen atom in
n = 4 drops to ground state?
(a) 6 (b) 15 (c) 12 (d) 4
19. Given below are the spectral lines for an atom of hydrogen. Which of the following not correctly
matched with the value of n1 and n2 ?

Series n1 n2 Region

(i) Lyman 1 2, 3,… Ultraviolet

(ii) Balmer 2 3, 4, … Infrared
(iii) Paschen 3 4, 5, … Infrared
(iv) Pfund 5 6, 7, … Infrared

(a) (i) (b) (iii) (c) (ii) (d) (iv)

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20. The energy per quantum of light associated with the wavelength 600 nm is ( Given h = 6.625  10−34 Js )

(a) 3.3125  10−19 J (b) 3.3125  10−17 J (c) 3.3125  10−18 J (d) 3.3125  10−21 J

21. The work function of a metal is 9.0  10−19 J . The longest wavelength of light that can cause

photoelectric emission from the metal approximately is (Given h = 6.6  10−34 Js )

(a) 540 nm (b) 412 nm (c) 220 nm (d) 660 nm

22. Electrons make a transition from 7th energy level and 3rd energy levels to produce bands in the

spectrum. Total number of lines obtained will be

(a) 10 (b) 8 (c) 3 (d) 4

23. The energy of an electron in the 2 nd orbit of Li 2+ ion is

(a) −4.905  10−18 (b) −0.4905  10−18 (c) −4.905  1018 (d) −4.905  10−20

24. A bulb emits light of wavelength 3.0  10−7 m , which can provide 20 J of energy. How many photons

are emitted by the bulb per second? (Given h = 6.625  10−34 Js )

(a) 3.01  1021 (b) 3.01  1019 (c) 3.01  1020 (d) 3.01  1022
25. Calculate the radius of an electron in the 4th Bohr orbit of H atom?

(a) 4.232  10−10 m (b) 8.464  10−9 m (c) 4.232  10−11 m (d) 8.464  10−10 m
26. Bohr’s theory can also be applied to the ions like

(a) He2+ (b) Li + (c) Be3+ (d) H +

27. According to Bohr’s theory, the angular momentum of an electron in 7th orbit is
10h 35h 1.5h 3.5h
(a) (b) (c) (d)
   
28. The negative electronic energy (negative sign for all values of energy) for hydrogen atom means
(a) The energy of an electron in the atom is lower than the energy of a free electron at rest which
is taken as zero
(b) When the electron is free from the influence of nucleus it has a negative value which becomes
more negative.
(c) When the electron is attracted by the nucleus the energy is absorbed which means a negative
value.
(d) Energy is released by hydrogen atom in ground state.
29. Which of the following statements is not correct regarding cathode rays?
(a) The rays carry negative charge
(b) The charge/mass of these rays is considerably larger than for positive rays
(c) The rays produce mechanical effect
(d) The charge/mass ratio is dependent of the nature of the gas taken in the discharge tube.

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30. Which of the following statements is not correct regarding electromagnetic spectrum?
(a) The velocity of UV − rays is more than that of microwaves
(b) Infra-red radiations have larger wavelength than cosmic rays
(c) The frequency of microwaves is less than that of ultra-violet rays
(d) X − rays have larger wave number than micro-waves.