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COMPARATIVE POLICING SYSTEM 2.1
COMPARATIVE POLICING SYSTEM 2.1
CARBON COMPOUNDS
Carbon compounds, known as organic compounds, are the backbone of all known life on Earth.
Carbon's unique ability to form four stable covalent bonds with other atoms allows for an
immense variety of structures, ranging from simple molecules like methane to complex
macromolecules like proteins and DNA.
Here are some notable examples of carbon compounds, along with explanations of their
structures and functions:
1. Methane (CH4)
Structure: Methane consists of a single carbon atom bonded to four hydrogen atoms in a
tetrahedral shape.
Function/Uses: Methane is the simplest hydrocarbon and a primary component of natural
gas. It is widely used as a fuel.
2. Ethanol (C2H5OH)
Structure: Ethanol consists of two carbon atoms, six hydrogen atoms, and one hydroxyl
group (-OH). It has a linear chain of two carbons with an -OH group attached to the end
carbon.
Function/Uses: Ethanol is commonly known as alcohol and is used in beverages, as a
solvent, and as a biofuel.
3. Glucose (C6H12O6)
Structure: Glucose is a six-carbon sugar with a ring structure and hydroxyl groups
attached to each carbon except one, which is part of an aldehyde group.
Function/Uses: Glucose is a crucial energy source for living organisms and a key
intermediate in cellular respiration.
4. Benzene (C6H6)
Structure: Benzene has a ring structure composed of six carbon atoms with alternating
double bonds, making it an aromatic compound.
Function/Uses: Benzene is a precursor to many important chemicals and is used in the
production of plastics, resins, synthetic fibers, and rubber.
Structure: Acetic acid consists of a methyl group (CH3) attached to a carboxyl group
(COOH).
Function/Uses: Acetic acid is the main component of vinegar and is used in the
production of plastics and as a food preservative.
6. Proteins
Structure: Proteins are large, complex molecules composed of amino acids linked by
peptide bonds. Each protein has a unique 3D structure determined by its amino acid
sequence.
Function/Uses: Proteins serve a variety of functions in organisms, including as enzymes,
structural components, and signaling molecules.
Carbon compounds are integral to the chemistry of life, forming the basis of biochemical
processes. The versatility of carbon allows it to form complex and diverse molecules, enabling
the existence of the vast array of organic matter found in nature.
Organic compounds are typically defined as those compounds that contain carbon atoms bonded
to hydrogen atoms and often include other elements such as oxygen, nitrogen, sulfur, and
halogens. The defining characteristic of organic compounds is the presence of carbon-hydrogen
(C-H) bonds.
1. Lack of C-H Bonds: CO2 does not contain any C-H bonds. It consists of one carbon
atom doubly bonded to two oxygen atoms (O=C=O). The absence of hydrogen atoms
bonded to carbon is a primary reason why CO2 is considered inorganic.
2. Simple Structure: CO2 has a simple, linear molecular structure with the formula
O=C=O. Organic compounds, on the other hand, generally have more complex structures
with various functional groups and carbon chains or rings.
3. Origin and Usage: CO2 is often produced by inorganic processes, such as the
combustion of carbon-based fuels and the respiration of organisms, where organic
compounds are broken down. Organic chemistry, however, traditionally focuses on
compounds synthesized by living organisms or those that can form complex structures in
the lab.
Classification System
The distinction between organic and inorganic compounds is based on historical and structural
considerations:
Historical Context: Originally, organic compounds were defined as those derived from
living organisms. With the synthesis of urea (an organic compound) from ammonium
cyanate (an inorganic compound) by Friedrich Wöhler in 1828, the line between organic
and inorganic compounds began to blur, but the classification based on C-H bonds
remained.
Structural Basis: Modern classification focuses on the presence of C-H bonds and the
complexity of the molecular structures. Compounds like CO2, carbonates (e.g., CaCO3),
and cyanides (e.g., NaCN) are considered inorganic because they lack the typical features
of organic molecules.
SLIDE 2
Palytoxin is one of the most complex and toxic natural substances known. Here is an in-depth
discussion of its complexity:
Chemical Structure
Biological Activity
1. Mechanism of Action:
o Palytoxin binds to and disrupts the function of the Na+/K+-ATPase pump, an
essential protein for maintaining the electrochemical gradients of sodium and
potassium ions across the cell membrane.
o This disruption leads to cell depolarization, which can cause massive cell damage
and death.
2. Toxicity:
o Palytoxin is extraordinarily potent. Even minute amounts can be lethal to humans
and other animals. The lethal dose (LD50) for mice is approximately 150 ng/kg
when injected intravenously, highlighting its extreme toxicity.
o Symptoms of palytoxin poisoning in humans include muscle weakness,
respiratory distress, and cardiovascular collapse, often leading to death if
untreated.
Biosynthesis
1. Natural Source:
o Palytoxin is primarily found in marine organisms, specifically certain species of
zoanthid corals like Palythoa toxica. It is also produced by certain marine
dinoflagellates.
2. Biosynthetic Pathway:
o The biosynthesis of palytoxin is thought to involve a complex pathway that
includes polyketide synthases (PKSs) and non-ribosomal peptide synthetases
(NRPSs). These enzymes assemble the molecule in a highly regulated, stepwise
manner.
Chemical Synthesis
1. Challenges:
o Synthesizing palytoxin in the laboratory is extremely challenging due to its size,
complexity, and the need for precise control over stereochemistry.
o The first total synthesis of palytoxin was achieved by K. C. Nicolaou and his team
in 1994 after extensive efforts. This synthesis required over 100 steps and remains
one of the most impressive feats in synthetic organic chemistry.
2. Synthetic Applications:
o Synthetic studies of palytoxin have provided insights into its structure-activity
relationships, helping scientists understand which parts of the molecule are
critical for its toxic effects.
1. Biological Research:
o Palytoxin is used as a tool in biological research to study ion transport and
membrane dynamics due to its specific action on the Na+/K+-ATPase pump.
2. Potential Therapeutic Uses:
o Understanding palytoxin's mechanism of action can contribute to the development
of novel therapeutic agents targeting similar pathways. However, its extreme
toxicity limits direct therapeutic applications.
SLIDE 4
Four examples of carbon compounds where carbon forms four covalent bonds to fill its octet:
1. Methane (CH4)
2. Ethylene (C2H4)
Structure: Each carbon atom forms three single bonds (two with hydrogen atoms and
one with another carbon atom) and one double bond (with another carbon atom).
Description: Ethylene is a hydrocarbon with a double bond between the two carbon
atoms. This allows each carbon atom to complete its octet with a combination of sigma
and pi bonds.
Formula: C2H4
3. Ethanol (C2H5OH)
Structure: Carbon atoms form single bonds with hydrogen atoms, one carbon atom
forms a single bond with an oxygen atom, and the oxygen atom forms a single bond with
a hydrogen atom.
Description: Ethanol is a simple alcohol used in beverages and as a solvent. Each carbon
atom has four bonds to complete its octet: three C-H bonds and one C-C bond for the first
carbon, and two C-H bonds, one C-C bond, and one C-O bond for the second carbon.
Formula: C2H5OH
Structure: Carbon forms two double bonds with two oxygen atoms.
Description: In carbon dioxide, the carbon atom forms two double bonds with two
oxygen atoms, creating a linear molecule. This bonding allows carbon to achieve its octet
by sharing four electrons with each oxygen atom.
Formula: CO2
Visualization of Structures
Methane (CH4)
H
|
H-C-H
|
H
Ethylene (C2H4)
H H
\
/
C=C
/ \
H H
Ethanol (C2H5OH)
H H
| |
H-C-C-O-H
| |
H H
O=C=O
Organic chemistry plays a crucial role in our everyday lives, impacting everything from the food
we eat to the products we use and the biological processes that sustain us. Here are some
common examples of organic compounds and their significance in everyday life:
1. Carbohydrates
2. Proteins
Example: Hemoglobin
Description: Hemoglobin is a protein in red blood cells that carries oxygen from the
lungs to the rest of the body.
Significance: Proteins are vital for numerous biological functions, including enzyme
catalysis, transport, structural support, and immune response.
3. Lipids
4. Nucleic Acids
5. Vitamins
6. Hormones
Example: Insulin
Description: Insulin is a peptide hormone produced by the pancreas that regulates blood
glucose levels.
Significance: Hormones are chemical messengers that coordinate various physiological
processes, including growth, metabolism, and reproduction.
7. Pharmaceuticals
8. Polymers
SLIDE 6
Samples of organic materials
Organic materials are widely present in everyday life and encompass a broad range of substances
that are derived from living organisms or synthesized from carbon-based compounds.
1. Natural Fibers
Cotton (Cellulose)
o Description: Cotton is composed of cellulose, a polysaccharide consisting of
glucose units.
o Uses: Used in textiles, clothing, and household items like towels and sheets.
Wool (Keratin)
o Description: Wool is made of keratin, a fibrous protein.
o Uses: Used in clothing, blankets, and insulation.
2. Natural Polymers
Cellulose
o Description: A polysaccharide found in the cell walls of plants.
o Uses: Used to make paper, textiles, and as a food additive.
Natural Rubber (Polyisoprene)
o Description: A polymer of isoprene derived from the latex of rubber trees.
o Uses: Used in tires, gloves, and elastic materials.
3. Biomolecules
Proteins
o Example: Casein in milk
o Description: Casein is a protein found in milk and dairy products.
o Uses: Used in food products and as a binding agent in adhesives and paints.
Lipids
o Example: Oleic Acid
o Description: A monounsaturated fatty acid found in olive oil.
o Uses: Used in cooking, cosmetics, and pharmaceuticals.
4. Organic Chemicals
5. Pharmaceuticals
Polyethylene (PE)
o Description: A polymer of ethylene, commonly used in packaging.
o Uses: Used in plastic bags, bottles, and containers.
Polystyrene (PS)
o Description: A polymer of styrene, often used as a foam.
o Uses: Used in disposable cutlery, insulation, and packaging materials.
Indigo
o Description: A natural dye extracted from plants of the genus Indigofera.
o Uses: Used to dye textiles, particularly denim.
Chlorophyll
o Description: The green pigment found in plants that is essential for
photosynthesis.
o Uses: Used in food coloring and as a nutritional supplement.
8. Food Additives
Citric Acid
o Description: An organic acid naturally found in citrus fruits.
o Uses: Used as a preservative, flavoring agent, and in cleaning products.
Lactic Acid
o Description: An organic acid produced in sour milk products and during
anaerobic respiration.
o Uses: Used in food preservation, flavoring, and as a cosmetic ingredient.
9. Everyday Products
SLIDE 7
General Formula and examples
The general formula for alkanes is CₙH₂ₙ₊₂, where n represents the number of carbon
atoms in the molecule. Alkanes are saturated hydrocarbons, meaning they consist
entirely of single bonds between carbon atoms and have the maximum number of
hydrogen atoms bonded to the carbon chain.
Examples of Alkanes
1. Methane (CH₄)
o Formula: CH₄
2. Ethane (C₂H₆)
Formula: C₂H₆
3. Propane (C₃H₈)
Formula: C₃H₈
4. Butane (C₄H₁₀)
Formula: C₄H₁₀
5. Pentane (C₅H₁₂)
Formula: C₅H₁₂
Higher Alkanes
As the number of carbon atoms increases, the complexity of the molecule increases, but they still
follow the general formula CₙH₂ₙ₊₂. Here are a few more examples:
Hexane (C₆H₁₄)
o Used as a solvent in laboratories and in the formulation of adhesives.
Heptane (C₇H₁₆)
o Used in the petroleum industry and as a standard in octane rating.
Octane (C₈H₁₈)
o Known for its use in gasoline ratings (e.g., "octane rating").
The general formula for alkenes is CₙH₂ₙ, where n represents the number of
carbon atoms in the molecule. Alkenes are unsaturated hydrocarbons, meaning they
contain at least one carbon-carbon double bond (C=C). This double bond is the
defining feature of alkenes and impacts their chemical properties and reactivity.
H₂C=CH₂
H₂C=CH-CH₃
H₂C=CH-CH₂-CH₂-CH₃ (1-pentene)
or
CH₃-CH=CH-CH₂-CH₃ (2-pentene)
H₂C=CH-CH₂-CH₂-CH₂-CH₃ (1-hexene)
or
CH₃-CH=CH-CH₂-CH₂-CH₃ (2-hexene)
Visual Representation
H H
| |
H-C=C-H
| |
H H
H H H
| | |
H-C=C-C-H
| |
H H
Properties of Alkenes
Unsaturation: The presence of a double bond makes alkenes unsaturated, allowing them
to participate in addition reactions, such as hydrogenation, halogenation, and
hydrohalogenation.
Reactivity: The double bond in alkenes makes them more reactive than alkanes. They
readily undergo polymerization, forming long-chain polymers like polyethylene.
Geometric Isomerism: Alkenes can exhibit cis-trans (or E-Z) isomerism due to the
restricted rotation around the double bond. This isomerism affects their physical and
chemical properties.
Applications of Alkenes
1. Polymer Production: Alkenes like ethylene and propylene are essential monomers in the
production of plastics such as polyethylene and polypropylene.
2. Chemical Intermediates: Alkenes serve as intermediates in the synthesis of alcohols,
aldehydes, and other organic compounds.
3. Fuel: Some alkenes are used as components of fuel and as starting materials in the
petrochemical industry.
The general formula for alkynes is CₙH₂ₙ₋₂, where n represents the number of carbon atoms in
the molecule. Alkynes are unsaturated hydrocarbons that contain at least one carbon-carbon
triple bond (C≡C). This triple bond is the defining feature of alkynes, giving them distinct
chemical properties and reactivity.
Examples of Alkynes
H-C≡C-H
H-C≡C-CH₃
H-C≡C-CH₂-CH₃
CH₃-C≡C-CH₃
H-C≡C-CH₂-CH₂-CH₃
Visual Representation
H-C≡C-H
H-C≡C-CH₃
Properties of Alkynes
Unsaturation: Alkynes are unsaturated hydrocarbons with at least one triple bond,
making them more reactive than alkanes and alkenes.
Reactivity: The triple bond in alkynes allows them to undergo various addition reactions,
such as hydrogenation, halogenation, and hydrohalogenation.
Acidity: The hydrogen atoms attached to the carbon atoms in the triple bond are slightly
acidic, allowing alkynes to participate in reactions that alkanes and alkenes cannot.
Applications of Alkynes
1. Welding and Cutting: Acetylene is widely used in oxy-acetylene welding and cutting
due to its high flame temperature.
2. Chemical Synthesis: Alkynes serve as intermediates in the synthesis of various organic
compounds, including pharmaceuticals and polymers.
3. Fuel: Some alkynes are used as components of fuel due to their high energy content.
4. Polymer Production: Alkynes are used in the production of certain polymers and
materials.
SLIDE 12
Carbonyl Group
Carbonyl compounds are organic molecules that contain a carbonyl group
(C=O). This group is characterized by a carbon atom double-bonded to an oxygen atom.
Carbonyl compounds are broadly classified into aldehydes and ketones based on the
position of the carbonyl group within the molecule.
General Characteristics
Aldehydes: The carbonyl group is bonded to at least one hydrogen atom.
Ketones: The carbonyl group is bonded to two carbon atoms.
Examples of Carbonyl Compounds
1. Formaldehyde (Methanal)
o Formula: CH₂O
2. Acetaldehyde (Ethanal)
Formula: C₂H₄O
3. Acetone (Propanone)
Formula: C₃H₆O
4. Benzaldehyde
Formula: C₇H₆O
Formula: C₄H₈O
Reactivity: The carbonyl group is highly reactive, making aldehydes and ketones
important intermediates in organic synthesis.
Polarity: The carbonyl group is polar, leading to higher boiling points and solubility in
water compared to hydrocarbons of similar molecular weight.
Chemical Reactions: Carbonyl compounds undergo nucleophilic addition reactions,
oxidation, and reduction reactions.
1. Industrial Solvents: Acetone and butanone are widely used as solvents in paints,
coatings, and adhesives.
2. Flavorings and Fragrances: Benzaldehyde and other aromatic aldehydes are used to
impart flavors and scents in food and cosmetic products.
3. Pharmaceuticals: Many drugs and active pharmaceutical ingredients are synthesized
using carbonyl compounds as intermediates.
4. Polymer Production: Formaldehyde is used in the production of phenol-formaldehyde
resins, urea-formaldehyde resins, and other polymers.
SLIDE 13
Polyethylene
olyethylene is composed of repeating units of ethylene (C2H4), which are linked together to
form long chains. Each ethylene unit consists of two carbon atoms and four hydrogen atoms.
CH2-CH2-CH2-CH2-CH2-CH2-
| | | | | |
H H H H H H
Description:
o Each "-CH2-" represents an ethylene unit, consisting of one carbon atom double-
bonded to another carbon atom and each carbon atom bonded to two hydrogen
atoms.
o The repeating units are linked together through single bonds between the carbon
atoms, forming a long chain structure.
o Hydrogen atoms are attached to each carbon atom but are typically not shown in
structural diagrams for simplicity.
Flexibility: Polyethylene is known for its flexibility and resilience, making it suitable for
applications where durability and impact resistance are important.
Versatility: It is widely used in packaging (plastic bags, containers), construction (pipes,
insulation), consumer goods (toys, furniture), and various industrial applications.
Types: Different types of polyethylene (e.g., LDPE, HDPE, LLDPE) vary in density,
strength, and flexibility, catering to different requirements across industries.
Environmental Impact: Efforts are ongoing to improve recycling rates and develop
more sustainable practices due to the material's persistence in the environment.