2023-46 TS/Iff.rCiT *1*"6aq!

ff
ANSWER KEY
,l-{rii. ( ) (c) (c) (a) 65 (c) 8t (a) 97 (b) 113 (a) t29 (c) I4$ (a)
'u, I

(b) r8 (b) 34 (d) so I rar 66 (b) 82 (c) 98 (d) 114 (a) 130 (c) l4s (a)

:'5'tt;, (d) ls
.,) (c) 35 (a) 5l (d (d) 83 (b) (c) 115 (a) I31 (a) i47 (d)

tf; (c) 2rt (d) 36 (d)

I
(b) 68 (d) 84 (d) 100 (b) tt6 (c) r32 (a) 148 (b )

(d) 2t (d) .a1 (b) srl (d) 69 (b) E5 (a) I (c) ,17 (d) (d) I49 (c)
',f, ' (c) (b ) 38 (b) (c) 70 (d) (a) 102 (b) 1:8 (a) (c) I5S (b)
rl I

..,tr' (c) (b) 39 (c) ss I rcr 'll (c) 8? (b) 103 (a) r19 (a) r95 (d) r51 (c)
'2;4
s (d) (a) 40 (a) 56 (b) (d) 88 (d) 104 (a) 120 (d) t36 (a) t52 (d)
I

(a) 25 (c) (c) '5? I

(d) 71 (a) E9 (a) 105 (a) tzt (b) 137 (d) 155 (a)

r0 (a) 26 (c) 42 (a) st I r.rt (c) 90 (b) r06 (a) 122 (c) 138 (b) (b)
(c) (b) 43 (a) sr I rar ?5 (c) 91 (a) $7 (b) 123 (d) 139 (a) rlt (b)

(c) 2* (c) 44t' (d) (c) 76 (c) o1 (d) 108 (d) t24 (a) L40 (c) r56 (a)

I3 (d ) 29 (a) 45 (a) (b) 77 (d) 93 (a) 109 (d) (d) 141 (a) t51 (a)

t* (b) (a) ;46 (b) 62 (c) ?8 (c) 94 (d) 110 (c) 126 (b) 142 (a) 158 (d)

(c) rd) 47 (d) rrIr,r (a) 95 (c) ltl (c) ,27 (c) r43 (b) r59 (a)

1f (a (b) 48 (b) 64 (b) EO (c) (c) lt2 (c) r28 (a) 144 (b) (a)
1
 2023-47

• then 2 (B T AT) = 2BA

and if bothare skew s�etric then
MATHEMATICS
1. (a) g(x)= 16-xc2x-l
16-x > 0 and2x-1 � 0 and 16-x � 2x - 1 AT = -A,B T = -B
• 2 (B T AT)= 2 (-B x -A)= 2 (BA)
1 17
x< 16and x�- and x�- :. A and B are both symmetric and skew symmetric.
3
Also x must be integer
2

6. (c) adj [�l � �2]

:. x E {l,2,3,4,5}
0 .2 1
2. =A
(b) x [: :] Cu = 5,
C 21 = 4, C31 = -2
C 12 1,C 22 1,C 32 = 0
=

detA = f(A) = ad-be

Let a = 1,d = 1,b = 0,c= 1 C 13=- 2,C 23 = -2,C33 = 1
= =

.f{A) = 1
Also ifa = 2,d = 1,b l,c = 1 :. adj [�1 � �2 ]= [ � ; � ]
2

.f{A) = 1 0 2 1 -2 -2 1
=

:./is not one-one m = 4,n 1

but we know that c orresponding to any ;number in real :. m+ n= 5
=

number set,we can define an determin�t.

:./is onto 7. (c) A=[
� �]
(d) .f{x + y) =.f{x) + fly)
.f(l) = 7 A2
3.

putx= l,y = O =[� �][� �]=[� �]

.f(l)=.f(l) +.f{O) ⇒ .f{O) = 0
.f(A)=A+ A 2+ A3+ ....+ A 2023
:. An= 0,n�2
Putx= 1,y = 1
.f{A) a=A
.f{ 2)= 2.f{l)= 2.7= 14
.f{A) + I = A+ I
and.f{3) =.f{ 2) + .f{ l) = 14 + 7 = 21

:. Lf(r) = f(l)+/( 2)+ .....+ f(n) =[� �]+[� �] '=[� :]

7+ 14 + 2 1 + .... n terms
r=I

(d) (½) +(½)l+ (½J + ••••oo

° 2

= 7 (1 + 2+ 3 + .... n terms
)
=
8.

= l+
2 ½+ Gr + ••••oo = �I = 3�i
n n l)
=1. ( +
1
4. ( ) l (adj A 2)l=
adj 3
ladj Al = IAl -l IAl
c
3 3+i 3(3+i) 9+ 3i
= -x- =-- = --
ladj A 1 = ladj Al = (IAl 2) 2= IAl 4
l
n 2

3-i 3+i 10 10
=

ladj (adj A 2)1= (IAl4) 3-1

2 2

= (IAl 4) 2= IAl 8 (l+ ;)

(a) arg[
2025

(d) (AB+ BA?+ (AB - BA?= 2BA (1-i) 2022

9.
s.
⇒ (AB? + (BA? + (AB?-(BA) T
✓2 2025 _1_ •
= 2 (AB? ( ) ✓2 + _z_ )
2025

2 (B T AT) (1+i) 2025 ( ✓2

(1-i) 2022 • 2022
IfA and B are symmetric ✓2 _12__✓
( ) 2022( ✓ _.!___
=

⇒ B T=B andAT=A
2
)
mix,.48

t TC t2O25 13. (d) For any quadratic expression P(x)

I 7rl 'P(x)>0 VxR=D<0,a>0
I COS-+rSrn-
(J')3
\44) |

= r ;2022 D:(2p)2-4(8-2p)<o
4p2-32+8p<0
[*'l-,',,;J (p+4)(p-2)<0
2025n 2022n
,( -fa
:. p e(4,2)
='f'}( 4
J-2"
4
14. ft) ",= (x (x+3)
.arS(4=-; - l)(.r + 2)
(x- l) (x +2)y:v+f
10. (a) l=.1=, xzy+(J-l)r-(2y+3):0
+tl
lz
'.'xeR
r -r2 .'. D>0
l'-'l =2, O-D2+4y(2y+3)>0
lz+il (9y + t) (/ +.1) > 0

+ z-7+zi-Vi+l y e (-co,-rlu[-i,-) + v e.-(-,,r')

E)F)=22 E +l -iz+iV
-A

z:x+iy tl - -l
I

,2 +l+i(2yi)
+ y2
B=j
_l
4 ,9
,2 + y2 +l-i(Zyi)
ox+p/+l=0
3*+lf+loy+3:o
/ n) -x-!ny+t=o = i*t=,
11. (c) ,, =[.os*+ tsin:)
Sum ofintercepts: I + 9: l0
I
.-n 1
(.6-r) 2- 6'2''15 -./5
=(cosn+isinr)-
Ir]
3
15. (c) sin2l8" =
l6 8
.oll
flr,
n=l
= (cosn+ lsinn)z .(cos n + is hn)22 ...*
aor2 36o =
(S*r) -1_ r+Js
[.] 8

2 Required equation is

=(cosrc+isinn)
,-1
2
,2-
3-.6 :+",6 3-.6 :+.6 =0
88 ),.I 88
:(cosn+lsinr)l:-1
-+-
t2. @) *-i=0 *'-2r*L=o = t;xz- lzx+ l:0
416
_2 _:_ cos-TE+, srn-IC 16. @) #+x3-4*+x+l=0
22 =(x-l)2(*+3x+l):0
I
-3r.6
t("o, n *irin n) .'. roots are 1, l. -;
\ "o"L2*irinl)I
, = +(
, = \ 4 4)
( n .. rr)( ^r=^r: -'1"
j]9,5
rc .. n) Let cr: l, P: l, y: =
=iCOS-+lsln-
\44)'\44)
l-l -COS--ISln- I
22
x2: Xop
Coefficient of
.n .5n
=cr0+Fy+oy+cr6+B6+y6
- "t{,"'T when roots are diminished by h
-5nn
arBF= coefficient of x2: 0
4,*gr=i (a - - h) (y * ft) + (cr - h) (y - h) +
h) (P - h) + (B
(a-h) (6-ft)+ (p-h) (6-i) +(y-h) (6-r):0
larsB-argcr,=l+{l=" : (r - 112 + Q - h)(cl, + F - 2h) + (6 - h) (a + P - 2h) +
 202!-49
(y ,r)(6-r)=0 22. O) (1 +r) (l -r)i
=( - hr + @ + F -2r) (y+6-2n) + (y6 +P-n (1, + 6) = 0 Coefficient of = / I x coefficient of r" iz (l - x)a
Clearly0.+P=l+l:2 + I x coemcient offl in 1l -xy
6+l=-3=16=l = (-lr .
,c,t + (-l),-t . "c*, = 1-ry + 1_r1*r .n
)(r hY+Q-2h\(S-zh)+(h2+ r +3r)=0 .'.flz): (
lf + (-lf-r. z
) I+h2 -2h -6 + 2h + 4h2 + h2 + 3h + I = O f(2023): ( + (-D2022.2023
112023

=6h2+3h-4:O : -l + 2023 = 2022

Here ifroots now are o, & p

-t -1
-^ _)
23. (br v=1+I*fia*....-
4 4.8 4.8.t2
cr+B = -j = --. = --:
'6263 .r0 = --l
3 3.5 I
2
3.s.7 l\3
+-l
(
r2(a-P\2 = l2[(g + P)2 -4oB] ' 4.| 2l 4 ?t I -l+ 4)
f35\
=,,(;.N =12 3.5 /' I \2
',*r=r*1[1)
3.5.7
Irz./ l!\ 4,
+
2tl4 ) 3! (i)'
17. (c) (!+B+I:-2; op+py+yo:-l; cpy=2 Comparing with
l+2*-x-2=o I 2
+ l) (r 2): a1a + b1 x
= (x - l) (x + 0 l+ a (;) +
.'. x= l,-1,1 2l b
c6 + P5 +,yo = 1 (\6 + (J)6 : 66 x I
18.
1111
(b) Number of diagonals ='Cz-z
a =3,b = 2,
b i
n(n-l\'-z=35
=' ,=1,2=1
2
.lO=O
42
+n2-n-2n=35x2 + n2-3n 3 3

= (/t - l0) (rl + 7):0; .'. z:10 ,*r=(r-1)' _r1) t

To form triangle we need 3 vertices out ofwhich 2 are A '\2) -[2./
and B
(v + D2:23
.'. 8 triangles can be formed by selecting 3rd vertex
= f +zy-t =o
as
remaining 8 verticas ofpolygon.
19. (c) Number ofrequired triangles: 24. bl
3'+1 A,. e=*C
(Setect I point from 4 collinear and 2 frorn remainiog 6)
' ' 1x +l)12x2 +3)=x+l 2x2 +3
OR (select 2 from collinear poinS & I from remaining 6)
(3x + 2) = A(2* + 3) + (r + l) @r + C)
= (4cl ,, 6c2) + (4c2 , 6cl)
(3x + 2\ : A. 2* + 3A + B.P + Cr + Etx + C
=(4 x 15)+(6x6)=96
=(2A+B)l+ (B + C)r+(3A + C)
20. (d) (sC4,.8Cd + (5C5,. 8C5)
:(s x28)+(l 2A+B=0 ...(0
x 56)= 196
B+6=3 ...(i0
-2
21. (d) (7-5r): 3A+C=2 ...(iii)
From (i), (ii) and (iii)
2

7 a l-5' 3
e= -l.s = 2." - t:
7 ))5
To make expansion valid
4-g*g=1-2*13 =2
555
l7l.r = lrt.1s
llll
25. (c) '7(r) elosGi*)
+ (tanr)3 - cosec (3.r - 5)
ie (-1 1 = sin r + (tanr)3 - cosec (3r - 5)
ls 5
flx) = f ,(x) + fr(x) + fr(x)
C 1 .'. 5C+7 = 14 Period o/lr) = LCM of period of{(r),[(x) &.fzk)
5 = LCM (2x, n, 2n) = 2n
2oB-50

1 = 2 (sinA + sin B + sin C) = 2R./sin A+ sin B + sin C)

26. (c) -:
.5 coso = 2R= 2
c: l;a = 2R sinA
^3r
'r<U<- l=2sinA
2

n03n ie
_<_<_ quadrant
sin e =1
2
2dd
22 4 A=30.
31. (d) laF4, bl=5
,in! t 0,"o.9. o,*!. o
ld-E)=3 V-612=s >
cosg=l-2sin29
j=l-zsin2 0 @-b).@-b=e
=
2s2 la 12 -2 la ll , lcoso +1612=s
.ing=3
2Js = coro=2cos29-t
2 16 + 25 - 2 (4) (5) coso : 9

l=z"o.r9-t = "or!=-{ 9656 = 13 sq16 = 1: cot2 e = !!

52z\t5 539
.e 32. O) A(r, 2, 3); B (3, 7, 2\: C (6,'1, 7): D (-1, 0, -l)
0
sln -,|
'. tan
0 e- e
- srn- cos-
Centroid ofAABD = (1, 3, 0)
-2 = + +z
tstr
cos I
2
2
222 Centroid ofAACD: (2, 3, 3)
Equation of vector passing through d and D-

:-,- r=o+Llb-a)
---,-2
-' t= -2l-
v5 v) i = (i +3h+1',(i +3i{)
21. (b) *+ax-c=0 i = (r + )'); + 3i+3r, i or t =(t+t)i+3j+3tt
sin20, cos20 are roos
33. (c) a+D-+d=0
sin20 + cos 20 = -a
sin26.cos20=-c
Possible if d,6',d represents sides ofa triangle

(sin 29 + cos 20)2 : sin22e + cos22o + 2sin2e cos2o lql=3'lbl=s'1eF7

(-a)2=l-2c o2 +b2 -"2 g+2s-4g
-2- t .^ costl=-
2ab 2x3x5
a2+2c-l=o
t- cose=:1+e=tzo=?1
2E, (c) 5=lqg1y+{y'+l) 23
v+J7i="' '. angle between a &6=@-g)=1c-+ = n/3
'.'rinlr-', = log(r* ffli) 34. (d) A:2i-j+3i; a:-r2i -i -ti
sinn-ry=teg1y,'ffi1 c:-i +2i -ai; D:)"i +2i -i
en = -r+i-ol ; 3g = t L"+:j-[
sin h ly:,
= sin [x =y ft = -ti + zj -t t ; lrY:' = 1x - z1i +ti - &
29. (a) a:b:c:4:5:6 for coplanar vectors,
-abcA
R=-: r=- E.1ac,eoy=o
4Lr
Robcs abcxs -14 0 -61

r4LL, 4s(s -c)(s -DXs-c) -33 -l =0

4.5.6 l6 ?^.-2 3 -41

l5 15 _ 5 7 9 (-14 + 2 (3 + )' -2))=0 ."

4 -4 --5 6 -
2 )( ) 2 ^.=6
sln + stn B + s m C
35. (e) orthogonal projection of d on5 =9!)E
30. (a) 6 =a+b+c lbr
3
 208-51

0.88+K=l
- 4:
x=-b K: 0.12
9
(a.b) B : {x : x is aprime number}
Orthogonal projection of b'on d = a
tar E-- 12,3,5,7)
v =-a
4 F: {1,2,3}
9 EUF: {1,2,3,5,7}
li-il= !9 b-a P (E u F) : P(x : l) + P (x = 2) + P (x: (x= s)
3) + P
+P(X:7)
:
=li
9' -t; t =1Jro
9 40.
0.15 + 0.23 + 0.12 + 0.20 + A.0'l = 0.77
(a) Total floors = 7
36. (d) z=50 Total number of ways to exit = 75
o2 1x;: 7 If 5 persons leave at 5 different floors then number of ways
': & (*+ q= a2.d2@). : arranging 5 people in 7 ways = 7P,
o216x - $ = 62. o2@):36 x7 :252
37. (b) Let the events are Required probability =
"75 t
E : Two drawn balls are white; Er: All ball-s are white 7t 360
Er: 3 white balls and I other; Er: 2 balls white and 2 others 2t.7s 2401
41. (c) P(x, y), A (0, 2), B (-!, 0)
P(Er) =i, r,tr, = *,t,tr, = i t

oc, P4 =-!ln
,[+)= oc, =l ;.2p62=pgz
'12

2 [(r - 0)2 + (y : @ + t)2 + f

- 421
-(+)= \oc, 3l *+f -Lr-8y+7:o
62 It is a circle

,[+)= oc, r, 6
centre

radius=
(1,4)
tlf +q2 -7 =J0
E
42. (a) Distance between 3x - 2y+ 5 = 0 and
P(Er).P
E 3x_ 2y+5+ 2JiJ=0
E1
):
'( E ) P(Er ).P
E
+P(E2).P
E
+P(E3)x
E ,-:-:--
s+2JB-5 z,lB
El E E3
J* +22 Jtr
I x- Lr: 3x - 2y + kr; Lr: 3x - 2y + kz
J L:3x-2y+ 5
ll + ll
I r&L= 4d
5
t+1 + -x- -x- 8
3 23 63 Distance between
E=E
38. O) l+ax+b=0 lrr -51 8

D>0 Jr3 Jr3

a2-4b> o lkr-51:8 >k,=13
a:3, b = 1,2 3d 6
a= 4, b= 1,2,3,4 Distance between r,randL= JE=15'
a=5, b=1,2,3,4 lkz-sl L
Possible pairs = l0
Total pairs = 12
Jr: =Jrs
lk2- sl:6
105 .'. kz= ll .'. Lt=3x -2y +
Probability: 13 =0
TZ=i Lz=3x-2y+ll=0
39. (c) xP= I
: Combined equation of L, and L,
0.15 + 0.23 + K+ 0.10+0.20+0.08 + 0.07 +0.05 I
mz:t-52

(3x-2y+ l3) (3x - ll) =a

=
- (3x - 2y\2 + 24 (3x -
2y +
2y\ + 143 = 0
.. tr
, - -------
t Q.lt-t)
______F-^_______F

h-3 k+4 2rl3 + I - 2V3+l (2V3-l)

43. (e) -2(3.2-3(4\-5)
z -s 2. + (_3).
..PQ=r=lli-1
(3,
45. {a) ar + 2y = * is perpendicular to 2x - 3y + 7 :0
-4)
:. mr. mr= -l
-o ,2 =_1 _ ,=3
23
2x-3y-5 = 0 .. 3r + 2), = * forms triangle of area 3 sq. units
3x+2y=k
xv
(h, k)
rr)'r*)-'
h-3 k+4 -2x13 '.h-3 = -z k+4
-z
Is] [2./
2 -3 13 2 ^rra -3
= Irlx x
Ar (AOAB) = l; OA OBI = 3
h =-l andk=2 t. I

+t m-2 ..loAxOBI:6
I -(3(-r)+2(2)+r2)
32 32 +22
lk kl
l-x-l=6 + k=i6
l+l m-2 13 2l
-13
product ofvalues:6 x (_6)=_36
3213
(-r,2) 16. O) Lr:r+Jr'+10=0; Lr:x-y-2:0
Lr:2t + y - 7 :0
.: Lt rL2
.'. orthocentre will be point of intersection of Lr&L,
r +/ + l0:0 ...(i)
x -y - 2:0 ...(ii)
(1, n) 3x+2y+124' Add (i) and (ii)
l=4,m=0 2r+8:0
... lh + mk+ I =+ (_l) + (0)(2)+ I = 5
44. (d) Slope ofparallel lines 8re equal :-Y=x-2=1i:
. . stope of line parallel to fq = ,/l . . orthocentr¤ : (-4, -6)
..0=60' 47. (q a*+2hxy+bl= O

represents distinct lines if

a(x,3) sb>o .. ,2+(2/-3)>0
h2.
P+2t-3>o
(/+3)(/-l)>0
.. / e(- o, -3) u (1, co) br f eR - [-3, l]
4t, (b) Circle passing tbroueh (3, 4), (3,2), (l,4)
S+l,L=0
P is a point at r distance from Q (r 3) (.x-3) + (),-a) @-2) +X (x-3! =0
.. Co-ordinates ofQ It passes tbrough (1, 4)
(2 + rcos 60', 3 + rsin 60') .. (1 -3F+ (4-4) (4-2) + 2," (l -3)=0
-2
(r*r r.rEl ?,r

. . Equation ofcircle is
[ 2 2) (x - 3f + (y - 4) b/ - 2) + 2(x 3\ = 0
.'Plieson2x+4y-27=0 * - 6x + 9 + )? - 6y+ 8 + 2r- 6 = o
..2 rEl-rr=o *+f-+x-ay+t=o
2+L 3+
2 )..( 2) clear, centre = (2, 3)

4+r+12+2.f3r-27 = 0; (2JJ+l)r=ll radius = f

 208-53
.'. paramekic equation
116 8 ^ 15
x =2+ Jicos0 ; Y = 3+ JTsino
= -x-
zls 15 cot0 =
-8
a:2, r=Ji 51. (d) Circles are orthogonal
b:3 + 2ggz+ zftfz: Cr+ C2
: ll
6.,n= 12.{Ji)2 = l8 = 2 (1) (4) + 2 (-3) C 2) r+
49. (a) Equationoftangentto circleT=0 +- 16 + 12: k+ 11
= /c:-15
52. (b) Clearly the required circle have circle with centre at
y 4
=T.,f-3x+ = ..(i) origin
mr =-tl3 (1., 1.)
(-1., l,)
.'. Slope of liire perpendicular to pT = B'
'.' L is tangent of (x -
J'
3)2 + f = 1

i.e.*+f-6r+8:0
I-et equation of tangent be

y= !r*g = *-,lly+c.6-o A"

'Jt ...(iD
(-1., -1.) (x., -1.)

kngttt ofperpendicular on (i) from cente (3, 0): radius: I

:+CrE In figure,
1.-
2
+ CJJ=-1,-5 Ifradius ofsuch circle: r
then OB : r
+ L=-_p0f _p r*r*1,+1,=A'B'
V3 ./3
2(r +X) = (2)")2 +(2?")2
.'. Equation of L: y=*r-*
J: JT ) r =(Jt-l)i.
(d) S,: x2+f - I =0; Sr:*+f -?9--3:O
= Jly=*-l 53.
Sr:x2+1?-2y-3:0
50. (d) *+f-2x+4y+3:0 Sr - Sz= 0 (Equation ofradical axis)
PA: length oftangent 2x+2=0
*-- |
1

L S,-sr:g
2y + 2:0
v=-l
(6, -5)
.'. Radical centre is (-1, -l)
rr: l, rr:2, rr:2
B .'. Required circle liave radius: 5
.'. Equation of circle : (x + 1)2 = (l + t1z -- rt
=.8 54. y=nu*c+r-2y+k:0
(c) ...(i)
tk
m=-.c=-
+(-s)2 -2(6)+4(-s) +3 = Ji = 4Ji 2'2
r 2
*(-2)2 4 =Ji f-q**4y+8=o
(y - 42:4 (x - l)
EL4J' From(i),x=2y-k
COt-
2r=- =:=4
Jz (y -42:4 ey - k- r)

el= f-rzy+(8-4D:o
tan- '.' line is tangent
24- .'. Above quadratic equation must have equal roots

-
2-
tanO= t0
2ral9

l-tan--
i(J 55.
D:0
i.e.
042-4$-4k):0 = k=7
@) f:sx ...(i)
2
'-(i)' x2:5v ...(ii)
2023.54

Solving (i) & (ii) Equation oftangent at P (xl,)l)

2xxr+ 3yyr=k ..(iD

[*l='
f : x.53
If (i) and (ii) represents the same line
l #3
2xt 3yt
.'.x=0,5 +y=0,5
Point ofintersection (0, 0), (5, 5) kk
xt=G,lt=
:.L=y=x ..(l) 3J,
P
Slopeoftang"ntut r=f,
.'. Slope of normal : .r[
5 .'. Equation of normal avP (xp y)
v
k r( r) 3Jlv-k 6x-k ..(iii)
IB
I
"3$ \
--t<tv__t--=_
il 3 2
I
I
I
(t k )
Now, since (xr,.vr ) = , lies on ellipse
-5 [ U ,.,6J
Pr,f:5x
4

:r =J
Equation of directix of P,
;.2( L)'
\
-!:\'i
6, *r(\.:Js =o

Equation oflatus rectum ofPr:

k2 k2 k
y=-5 189
"4
:. k-- 6
(-s l) -5 l:: 6 in (3)
,4 Put
"(;';),,(? )," I +'q) z}"fzy -o) =3(6x -6)
I
4
T
4
+ zx-,!-ly-t=o
-5 l5 5 25 58. (d) Angle between aslmptotes of hyperbola:2 sec-l1e;
Ar(AenC; = 1 -5 22 2 8 30o:2sec-le + sec-l e=15"
4 4
.'. e=sec l5o
-5 5
4 4
"=Ja-Ji
56. O) xcoscr+ysin a=ZJl 59. (d) rr + xr-- 6 A(xr,yy z)
xz* xz: o
*2 ,2 xr*xr=0
168 x'=x'=3
ifx */ "' (0,0, 5)
We know that coscr sin o = p is tangent to ellipse xt: -3 (3,0, 0)
,2 ,2
-=* Similarly
. =I then
at b' 11+ Yr: o
p2 = oz cos2cr + b2 sir?a !2+ Yr= 8 B (0,4,0) C
tf yr=o (x2, !2, zz) (4,y3,\)
QJr2=l6cos2o+8sin2cr
:' lz= lz:4
12: 16- 16 sin2cr + 8 sin2a
:4 *-| \=-4
8 sin2g
= ,iro = Jz and zr+ zr:0
but cr is acute z'* z':0
.ln zr+ zr-- l0
.'. smo =T, * o=
4

57. (d) x +,!-3Y =3 ...(i)

... AB2 + BC2 + CA2
x2+3f =k
 2023-55
: (xr- xr)2 + (tt- y)2 + 1zr* z2)2
dy _4x-3y+l
+ 1xr- 4)2 + (yz- y)2 + (zr-
+ (xr- xr)2 + (\- y)2 + 1zr-
4)2 dx 3x-2y-2
4)2 g(x,y)=4x-3y+l
= 0+ 6 4 + 100 + 36 + 0 + 100 + 36 + 64+ 0 =400
60. (c) Lr: (1, m, n); Lr: (a, b, c) JV,i:3x -2y -2
g(2,2) _ 4(2) -3(2)+l 3 _3
The direction cosine of angle bisector are I * a, m * b, n * c =
61. @) Let equation of plane be .f0,r) 3(t)-2(t)-2 -l =
ax+bY+cz+d=0 6s. (c) lU) = d
Where a, b, c are direction ratios of line perpendicular to h(x):ffix)) = se'
plane
(0, 0, 0)
h'(x)=""' ."'=h(x).ex = #=*
log lr(r) = loge"' = e* .loge = e,

!9.= roefr(x)
h(x)

(2, - l, 3) 66. (b) siny = sin 3t

t:3t
a=2-0:2, /: 3 sin-lx
D:-1-0=-l dy=d3sin-tx
c=3- 0=3 dx dx
:.?-r-y+32+d:0 3
'.' It passes through (2, -1,3)
.h- *'
2(2)-(-l)+3(3)+d=0
d=-14 67. (d) y:xa- 6S + l3f -l0r+5
.'.b-y+32-14=0 Slope of tang *r= *= 4x3 -18x2 +26x- 10

62. (c) rim {n' k-l

iO,2*l ..dy _n
n-)@
dx
I 4x3-t8*+26x- to:2
= lim (12 +22 +....+n21,
n-+@ ,3 (r- l) (r - 2) (2r -3):0
I n(n+l)(2n+l) .'. 2 points can be taken as x : I and x = 2
= lim x.tr
if xr= 2
n)@ n 6

2xx
y;- Q)1 - 6 (2)3 + t3 Q)2 - lo(2) + i = s
,g;('.;.;) 63
whenxr: I
y;-- Q)4 -6 (l)3 + l3 (l)2- lo(l) + s : 3
(r.ioe-+rin'e) !!z: (1 x 2) - (3 x S1 = -13
63. (a) /=lim lim ,( sin30) .
l-J
.'. xrx2-
68. (d) x= P-lt+l
0-+0
['] 0+0 30)
- dx _ n. 1
z= lim ( ztn'e^
I =,,- z(^20\=z dt
e-+0[0(l-tan'0)/ 0-+0 \ 20 ) y:t2-4t- l0
.'. Equation with roots 3 and 2 is 9=2t-4
*-sx+6:o dt
dy 2t-4
G. (b) *=#3 dx 2t-7
7 -2t
Z*-llry+y2+r+2y-8:0 ... Slope of normal = 2t 4
'.'Now, at(1,2):
zrro-t(, fr* )*rrff*t+zL*= o
:.x=P-7t+7:l
208-56

P-lt+e=o
t= 1,6 =
f ooe,)' -!rl o'sa' so a.

y=P-4t-to=2 sl
I-arl
P-qt-n=o
t:6,-2
=
f ooe,)' -l[,.rr"'- PY 6.1 -

.'. t = 6 is common solution -t

oos,)' -i[**',r' -]l.r' *trld*l
.'.Slope of normal
2(6)-4=-!8
='. ,?(u), =
f
**[f ,"r, - li +-]
Equation of normal
8y-16=-J1+5
; y -2 =ftr-rl
8' =
f [o*r' -]o"s,f ]
5x + 8y -?l =0
*'
a--5,b=8,c---21 =
f [o"r'r'
-l{to'o2.*'""]-.* !
*'

a+b+c= 5+ 8-21:-8
m(a+b+c1= t'r-A=S =
f -]ooe*t2*1"r' -*] * o
=*[W].-
.'. [r,or,1'
8
69. (b) flx) = x.e-x
e-x * e-x
"f '(x): -x.
= - x\
"_,11
f'(x):0=x:l
andf ' (x\ = x' e' - e-x - e-x = 16s-x -) s-x = LSruOog x;3 - I sllog x)2 + 6(lo9 xl - r] + r

ee 'o
"''f"(l)=L-2 A=2t6,B:36,C:-18,D=6
.'. maxima is attained at x: I A-(B+C+D)
:216- (36- l8 + 6)=192
I
/(r)r"*= l.{t: -e ,dx
72. (d) J77;6r*
f",Ol =
[r,!)
, r49 trn-l x5o
=
il( x2+l *2+
dx

J-r.'r* *
.
70. (d) dx l-e dx I
=+[i I

t+x2 J q**2 )
Let tan-l x5o: t
I I
50x49 =J,* -r'.r--tan-r' (;)..
= at
Ta1*NVdx
dx
73. (a)
Ll,a,=l-t1*c ='100\( tan ,50
r2
)*c
Let 1 =
J 11
50r 50 2 (x ge @ +2)4
-3
.'.t=100I @-t1t 4*
J .J

71.. (c) JCosrl'Ja, 1x+2)t (x+22)

= llogr)3.Jxs *-!( *u,r.r').(! ,'*Y. =I(#J?(*.,'*

=frroe,r' I[*# {)* r"t (,'-l)=r
\x+2)
 mB-s7
+2)-(x-l) , dx dt 76. (c) y:(sin2x)
ui, =>
(x
___-_-___
= =_
(x+Z)z
-_________=_uI (x+2)2 3
-3
. t=L I t4 dt
J TE TE

2
=!,i
3
*c=1frl)
3\x+2)
a+C
xel0,Znl
e 2tt
74' C) I xlxldx Jo lsin2xldr
lt
0 I
= a!&'inz'a'
= l r1-x1a, +J x.x dr
-l 0 fi
-cos 2r 1'
0 I
-!
=-l,r* +l*2a, 2 jn
-l 0
1["oro-"o sn1 =4 ,Z = 4
[,'lo .[+],
=
2'2
--LTj_,
77 (d) f;O*'-4x+2)dx
=-(o.f .(+-, =,
,'
=fLlo -2*'*2rl'

7s. (c) t = l'nsin2 xcos2 r(sinx + cosx)dx ...(D

=(27-18+6-0)=k
t +t: 15
:.3x2-4x+2=9
using
lb
y1r1=lb y{a+t-x) zf -4x-7 =0
It (x+l)(3x-7)=0
l= linsin2 xcos2 x(-sinx + cosx)dr ...(iD
:., = -l.Z
2 3
Eq. (i) + (ii) .'. integer root is -l
L 78. (c\ f=4a(x+a)
il= lisin2 xcos2 x(2cosx)dx
2v4=4a
2
"dx

t=J1rin2 x.cos3 xdx 'u2 =2rL 1,*ol=zuL(

' dx' ,*LL)
" dx\ zdx)
) 2
y2 =Zry :+ v2
dv dy
ft
xdx dx dx
=2[,j"i"2 x'cos3
order: l:m
.'.
Letsirx=, +cos.xdx=dt
rl r .
degree=2=n
=2lof 0-r)dt .'. m*n2=l+22:5
dy _2x+3y
4 7e. (a) A- 3x_U
=z!lo2 -ta1dt=r[+ +]: l5
Lety:vx
2023-58

dv
L=V+X.- dv y(x2 +2)-
"r(*2
+z-\lx e" dx+C
dx dx

vir-
dv 2x+3vx 2+3v - 2lx.e' - I e' a*)+ c
y(x2 + 2) = e' (x2 + 2)
dx 3x-2vx 3-2v y (x2 +2)= d (*+2)-b d + 2d+ a

x.
dv 2+3v 2+3v-3v+2v2 y(*+2):d(x2-2r+4)+C
dx 3-2v 3-2v
PHYSICS
dv 2vz +2 81. (a)
3 -2v Strong nuclear force
3-2v dx Ratio of the relative strength:
Weak nuclear.force
-';-dv=-
2v'+2 x
1,. :
3e dv lc2vdv adx = lgtl
,J f .t-rl S *r= l; l0-tr

+l tn
0.0 79000
)rur-' -)nlr,2 l= lr l+c 82. (c) 0.079000 + Non-ffiifi.-,
, r,*-l--"*,
Number of significant figure = 5
1,*-t v = ln lx l*1m tv2 +l l+c
2'2 83. (b) Acceleration due to gravity, g:9.8 m/s2
84. (d) The maximum horizontal distances is given by
f,un-'r=lnr.',6lii*c )1
: [sin - 80: ]:o
2
H--
"IIIax o
90'

)tun-'(z)=
r,f,' .,' .c ob

u2: 80 g
The ball will achieve the maximum height when it is
,*-'[1)=fh(r'*y2y*c
\x) 3 thrown vertically upward.
v2:u2 -2gh
Z=tan1m(xzty21+c
.x3 0:80g-2gh=h:40m.
85. (a) The apparent weight of the man
tan,f(x) = tanlloge(x'
1

*,' :m(g-a):50(9.8-9.8)
)
:0
E6. (a)
:. f (x) =!bs1*2 + y21
E7. O) As ball dropped from height h, then it will strike the
E0. (c) 1x2+21 dy+Zry dx= e (* +4 dx plane with velocity, u : Agh. Now after striking the
(xz + 2) dy = (d(xz + 2) - 2.xy) dx plane, it will bounce back with velocity, u: ev

dy 2x Now it will travel total 2h, distance before

_e'(x2'+2)._
-t+2Y )',
*= *\, Here h, :+
dy 2x
-:-*---;-!=e'-
zg

clx x" +2 So, total distance = h + 2hr

,2x I
- u2 2e2v2
E = eJ ;+2^ -
-dx "ln{x2+2\
--f
29 29

lF : *+2 )
= I-[r + 2"21
.'..y.IF =
JQ.Grlar*c 2gL J
y.(x2 + 2) = * z)a, * c
! {{*' =?l4.lr+2"2f
)oL I
y(xz +2)=1x2 +2).e'-!Qx).d ax+c
:h(l+2e2)
 20,,tFsl

93. (r) The velocity in which water is coming oul is

proportional to the beight of water as time increase. water
level decreases.
rr. (d)
"'tt'tz<l:
Fu
60.

!
v=vcosei+ysin0j
o
= l0cos 60i + l0 sin 60j

^ r -ll
= l0 x:; + l0 x la i
^

2 2' Fu

= si+ sJJ j 94. (d) From nemon third law, excess force acting on
the liquid is equal to force of buoyancy acting on the
E9. (8) Rl _ 2 cylinder.
R,3
') The increase in pressure
Moment of inertia. l=: MR2 .^ F Vog Vpog mog
IccRi-) AApApA
r -ll)' -(z\'-t m\
12-(R2J -\:l -s
9(). (b) The simple harmonic motion is given by 95. (c) The relation between Fahrenheit and kelvin is given
x=2cost by
Compaire with x: Acos o)t F-32 C-273
ro= I 95
2n F:C=X
T
=r (x-32)=e (x - 2'13)
s
Time period ofthe particle, 5){- 160 = 9X-2457
T:2n Second. 4](:24s7 - 160
91. (r) X: 2457 - 160
= 574.25" F =574.6"F
I 4
$d1= !6
e2. (d) youns Modutu., Y=+=# 96. (c) Ratio ofdensities of mo substance,

L
Ratio oftheir specific heat capacities, !L =1
C2 5
61 * ! , Here dis the diameter. AQ=mcAT:dcAT
AQ, : d, c, AT
100 AQ, : d, c, aT
(a) = 10000 AQr drcr 5 3 I
(0.1r ._
-) AQzdzcz652
200
(b) = 5000 97. (b) According to first law ofthermodynamics
(0 2)'
- dU=dQ-dw
(c). 300r =3333
Since,dW=-dU
(0.3r >dQ=o
Therefore, the process will be adiabatic process.
50
(d) = 20000 98. (d) The mean square velocity of gas molecule is given
(05r
- by
20z,-60

, 3KT
m
for gas A,
r
vA
3KT 102. (b)
--
m

,2 =u2**rl*uf, u?=utr ,l Spherical

wave font Plane wavefont
't v2 103. (a) Inside conducting, body, potential is same
a
v2= 3v? 3 vi =T
everywhere and equal to the potential at its surface.
3KT KT r04. (a) 2C 2C
u? = u2*
3mm A B

m
u,=t/; ..(l)

For gas B, C
r 3KT C
YB - -:_-
zm A B

., 3KT EKT
2m'' =.13
v: -:_::_ I vr ...(21
' Y2m
C
Divide equation (1) by (2), we have
C"r:C +C=2C
ET 105. (a) From wheat stone bridge, w9 have
v1 {;
R,=L
Y2
-=- EKT R3K
!z*
P:12R
99; (c) Transverse waves can propagate through solid.
100. (b) By Doppler effect fr.rmula P3_I2R3_K
./\ Pl I2R, L
f:f" l'-'"o I
106. (a) Resistance of wire, Rr = 2R
\v+vs,/
Heref: l980Hz Length of wire, Lr= 2L,

Speed of sound in air, v = 340 m/s

A,L,: A,L,
vo: l0 m./s ArLr= ArZL,
v.: l0 m/s A2-- Arl2

re'o = fl9:-P)
r"\340+10/ R.:' oL''
'Ar
.330 pLz
1980=fox Rz:
A2
-
350

rto-
-
1980 x 35
z^100 Hz. R2 pLz At 2L1x2 Al
33- Rl A2 pl,r A1 Ll
l0f. (c) ft:20 cm; f, = 30 cm
The focal length of the combination is Rr:4R, =3P
The increase in resistance = Rz - Rr
lllll3+25 :8R-2R:6R.
Ffrf220 30 60 60 12
107. (b) The Biot savant law is used for finding magnetic
F: 12 cm. field B at position r generated by a
 2023-61

Steady current I is given by lf 4. (a) Work function,W = 2.2 ev

B=&-l lIdlxi - PoI ildlrsino Energy of incident radiation, , = 3. lev

4nJ .3 4rJ .3 #i=
E=W+K.E
If0:0 or 180 ev:E-W
'.'B=0 ev=3.1-2.2
108. (d) v: 0.9 v.
109. (d) For ferromagnetic substance 115. (a) Mass of the electron, m = 2m
1> >l EnergyofelectJon,E*
110. (c) The metal detection is based upon the principle of +n'
electromagnetic induction.
For first orbit, n: I
z x (-r:.0)
111. (c) Consider a small radial segment of dx at a distance . I
from the cenhe of the disc.
Velocity of this segment, v: olx :-27.2ev.
emf induced across this segment 116. (c) For element X,
de :: Blv 0.693
(tvz)*: -r
=Bxrodx
Total emf induced across radius of disc r. For element Y,

=+
1
(t.ouo)v: ,
.=]n^.a*
0
0.693 1 + I*:0.693 1,,
Here, B:0.1 T w: l0 revolution/s:20n rads. 1
Ax ny
^

r: 0.1 m
X*'I'
0 x 20n x 0. )' Hence, Y will decay faster rate than X.
¤
2 117. (d) Use of heavy water in a nuclear relctor to reduce the
:zrr0.lx0.l speed of fast moving neutrons.
e = lOn mv. 118. (a) The fractional change due to incident light on
f12. (c) At very high frequency, minority charge caries in reverse bias is much more than
I that over the majority charge carries in forward bias.
Xc: ^ =0 f19. (a) LED is a basic pn junction diode operator
o)c
when forward biased. It has very high threshold
Xr: rol-: o voltage.
4{'
120. (d) c.: l0 [l + 0.6 sin (250 t] sin (108 t)
Compair with
C. = A" [
+ p sin (r,1. 0J sin (rrl"t)
Modulation, index, p : 0.6
lo 4{l 2A
CI{EMISTRY
220V

R:l+2+2=5, 121. o) -r: o[4]"v

'":
220
Current, i: '-- = 444 Ir2l
1f3. (a) Radiation
5
pressure on the surface is given by
+ Er: -'3.6lFlev
o_ I 0.6 : - 122.4 eY
c
I
--=
3xlo8 : -122.4 x 1.602 x lQ-le 1
:2 x l0-e N/m2 = -1.962 x l0-17 J
2f,5-62
122. (c) Z = 24 meus the element is Cr A 1 : I mixture of NaOH and CH, COOH will have
cr = ls2 2s2 2p6 3s2 3p6 3d5 4sl unequal concentrations of CH,COOH and CHTCOONa
For (n + l) = 3, we have 2p and 3s so number of such so it will not act as a bufrer.
electsons=6+2=8. 130. (c) Etectron-precise hydrides are formed by group 14
For (n + l) = 4, we have 3p and 4s so number of such elements like CHo, SiHo, etc.
electrons=6+l:7 131. (a) The standard reduction poteDtial of Li+ is lowest
For (n + l): 5, we have 3d so mrmber of such electons:5. because of its exceptionally small size and high charge-
121. (d) Z = 56 represents barium (Ba) that betongs to 2nd to-mass ratio.It is highest for Na+ to Na due to its size,
goup and 6s period. electropositivity and hydration enthalpy.
Z = 50 represents tin(Sn) that belongs to 146 group aud 132. (s) Be and Mg both do not impan flame colours due to
56 period. high ionization energy that prevents the valence electrons
Z: 27 rcpreselts cobalt (Co) that belongs to 96 group to excite.
and 46 psriod. Thus, both (A) and (R) are true and (R) explains (A).
Z = 58 represents cerium (Ce) that b¤longs to 3d group 133. (d) 2At + 6HCl -+ 2AtCl, + 3H2 (A)
and 6h period. 2At + 2NaOH + 2HrO -+ 2NaAlO, + 3H2 (B)
124. (r) For C, ols2o*ls2 o2s2 o.2sz n}p2* n2p?, 134. (c) Due to inert pair effect, the oxidation state, two units
Thus, C, molecule contains only r- bonds between the less than the group oxidation state becomes more stable.
atoms. Thus, Pb2* is more stable than Pb4+ because of which
125, (d) The total number of electron pai$ Oond pairs + Pb2+ will not act as a reducing agent.
lone pairs) is the same for NH, and NHo+. 135. (d) The given compound has a parent chain of Seven
Thus, their hybridization is also the same that is sp3. carbon a lerms on which one - OH at C - 5, C : C
126, (b) rn= .,6 ', , Mn = * *o1-' bond at C - 3, -CH3 at C- 3 and C2Hsatc-2are
preseot.
.o
.s
E.*l''^)'-
--!Me -
-(.s/ MA
MB Thus, the IUPAC name will be 2-ethyl-5-hydroxy-3-
methylhept-3 -cnal.
t - :2 136. (r)
Js rs l MB
-[".J
-f x

=t: + =M":5x.
6g Naphlhalerre
127. (c) n (rLo)
18.0s 3
number of HrO
@ o
I
molecules = .
iNe
I
x Cyclopeota{icDyl
iN^ - tlo.
Total trrlmbef ofatoms in I{rO = 3 Cycloheptatrienyl
= anrcn
n (H2) = +=+
2.0s 2
rr number of H2 molecules 137. (d)
o
I
=tNn' il
o
+ Total number ofatoms m\=2x I *o=*o lt
12t. (r) AG = AH - TAS and AH = AU +a^v
CH=CH rcd hot cHl-c -cl
Anhyd. AlCl3
= AU + ANFT
+ AH: (2100) + (2 x 2 x 298):3292 cal (A)
> LG:3292 - 298 (20) Br
(B)
= 1668 cal: -2.67 k cal.
129. (c) A bufer solution is formed when we have a mixture The electrophile in friedel-crafts acylation ofA to B is the
of a weak acid or base and its corresponding salt with a e
strong base or acid.
acylinium ion CH, - CO .
 208-63
l3r. o) co.
/Rt or R l\ R3 145. (r) Pa + 3NaOH + 3 H2O -------r--+ 3 NaH2 pO2 + pHr

:,>":. \1q c=o+o=c (x)

ozonolysis R./ & HCt .q.
}I gH:\ NaI{2PO2 H,PO, + NaCt

cH3/ c:o
We have, C=Oand (Y)
H The name of H.PO, is hypophosphorous acid or
phosphinic acid and not phosphoric acid.
Thus, .. H\
- -/CHt 146. (e) Ozone has a cent-al oxygen atom that forms a single
^= H/t=t\cH, bond and a double bond.
139. (a) Let x = number ofM3* ions Thus, it has one lone pair and other oxygen atoms have
y = number of M2+ ions two and three respectively.
Impue sample e
has M3+ ions. replacing M2* ioos.
=Y=0.96-x
Total charge of metal atoms = total charge of oxygan
,da
_z-(j
\?
_

atoms.
+ Total number oflor" puirr: 6
Total mrmber of bond pairs : 3
+2(0.96-x)+3x=2
+x=0.08 +Ratio=6:3ot2il
147. (d) The thermal stsbility of OF, at room temperature
Fraction of M2+ = I - 0.08 : 0.92
=
(c) is due to the small difference between th¤ electo
140. Pr"or*" = P'".o,.nJ"*"
negativities ofO and F.
and x^ n The order of stability of the oxides of halogens is
DBenzene * niolrt" I>Cl>Br.
IrO, being a very good oxidizing agent, is used for the
DBeozene
- nr",'or" and u**.o" = l. estimation ofco, and clo, is a good bleaching agent.
rBenren"
Thus, A, C and D are correct.
Ps"ro"n 161= 14E, (b) XeFo + 02 F2 -, XeF6 + Oz
Now, rF4,ene -
=
,"" Be,ene
- ;..,r8
= o.oz
G)
XeF6 + H2O -+ XeOFa + 2HF
+ n*,rr. = :I -I = 0,605 (1 mole) (y)
l4l. (8) XeFu = distorted octahedral shape.
From the rate law'
XeOFn : Square pyramidal shape.
mol L-ls-l 149. (c) Mn = [tu] 3d5 4s2
umts
2
:Lmollsl
Mn2+ = [tu] 3d5 and Mn3+ = [tu] 3d4
mol L-l
Thus, the hatf-flled configruation of Mn2* leads to its
142. (t) Clr+ 2e --> 2Cl- greater stability.

ixrxE 15.0x(45x60 x 35-5 150. (b) [CoF6]3 : Co is present as Co3+ and F is a weak-
fietd ligand.
96500 2 x96500
Thus, Co3+ = [Ar] 3d6 with four unpaircd electrons.
:7.M5 g
.. nRT 7 .445 x 0.082 x 273
n(n + 2) a.ru. = li@$=Ju
P 35.5x1 [Co (CrOa\lr : Co is present as Co]+ and CrOo2 is r
= 4.7 L. strong-field ligand.
143. (b) Sodium luvryl sulphate is a long-chain compound Thus, Co3+ = [Ar] 3d6 with all paired electrons.
with positive and negative poles that cause them to n(n + z) = o(o + 2) =o
aggregate together and form micelles.
1,14. @) Bauxite is a chief ore of Al that is concentrated [FeFu]3- : Fe is present as Fe3* and F- is a weak-field
tigand.
by leaching. Haematite is concentrated by magnetic
Thus, Fe3+ : [fu] 3d5 with five unpaired electrons.
separation and zinc blende and calamine are concentraled
by froth floatation process.
= p= -u61o* 4 = v6(5 - r) = J35
2023-64

[Mn(CN)u]3- : Mn is present as Mn3+ and CN is a strong- 158. (d) The reactivity of a substrate towards nucleophilic
field ligand with CN- pairing-up only two electrons. addition reactions depends on the groups attached to the
Thus, Mn3+ = lerl 3da with two unpaired electrons. carbonyl carbon that affect the charge density on it.
III is most reactive due to absence of electron-donating
p=rfi(n+z)= 2+2) =s {H, grouPs that are present on other compounds.
151. (c) Ziegler- Natta catalyst : TiCl4 + Al (CH2 CH:):. II is least reactive due - CH, and - NH, that $eatly
It is used for preparation of HDPE. increase the charge density on carbonyl carbon, making
152. (d) The deficiency of vitamin B,, causes pemicious it least prone to nucleophilic attack.
anemia. Among I and IY I is more reactive due to only one - CH,
153. (a) The given structure is of chloramphenicol which is group.
an antibiotic. Thus, the order will be III > I > IV > IL
154. (b) The reactivity towards Srl depends on the stability 159. (a)
of the carbocation formed in the first step. COOH COOH
Among the given options, the least stable carbocation is
the arenium ion (Ar+) and thus, C6 H5 Cl is least reactive (i)rcrano4 loH. (i) zn l sct.
towards Sul. (,t)rt*-
rss. (b)
(i)or (i) CHlMgBr/ether NO,
NO,
CH,: CH, (ii)Zn|H2O
2H20 + (P)
(P)
(ii)H,o/H
COOH COOH (ii) NaNOr/
PCC
cH3cH: o cH3cH2-oH HCI O'C
(R) cH2(-!' (i)cucN
(Q)
+-.-
(ii) H3o*
As we can see, R has o-hydrogens present so it cannot
undergo cannizaro reaction.
COOH
156. (a) ,cl
OH OH OH OH (R) (a)
R: Terephthalic acid
Monomers of Dacron : Terephthalic acid and ethylene
glycol.
OH
160. (a) cH3cH2 -31--x!r;CH3CH2 -NH2
Resorcinol Hydroquinol Catechol o-cresol
(a)
r57. (a)
Hrc\^,2 OH o
(i) CHrMgBr/ether SOCI" il B12/KOH
- c-
-----------+
cH3 - cH2
Xli>.=" (iD H2O/H
HrclL\
(A)
CH, A
(Srl)
NH2
Hoffmann-bromamide
degradation

cH3cH2 -NHz
Hrc CH.ONa CH3
____)
H,C >.<;i, o Hrc )c : CHZ (A)

(B) (c)