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ACIDS BASES SALTS CLASS 10
ACIDS BASES SALTS CLASS 10
Questions
Question 1
Define the following as per ionic theory with examples and ionic equations wherever relevant :
Answer
(i) Acid — An acid is a compound which when dissolved in water yields hydronium ions [H3O+]
as the only positively charged ion.
(ii) Base — A base is a compound which reacts with hydronium ions of an acid to give salt and
water only.
Examples of insoluble bases [i.e., not alkalis] — ZnO, PbO, CuO, Fe(OH)2, Pb(OH)2,
Cu(OH)2
(iii) Alkali — An alkali is a compound which when dissolved in water yields hydroxyl ions
[OH-] as the only negatively charged ions.
Alkali is a base, soluble in water. [All alkalis are bases, but all bases are not alkalis.]
Examples of soluble bases [i.e., alkalis] — KOH, NaOH [strong alkalis] , Ca(OH)2, NH4OH
(weak alkalis).
(iv) Neutralization — It is the process due to which [H+] ions of an acid react completely or
combine with [OH-] ions of a base to give salt and water only.
Acid + Base ⟶ Salt + Water
Question 2
Differentiate between:
Answer
Acids derived from plants, e.g., citric acid, tartaric acid, acetic acid. Acids derived from minera
Hydracids O
Acids containing hydrogen and a non-metallic element other than oxygen, Acids containing hydrogen,
e.g. HCl, HBr, HI. HNO3, H2SO4.
Question 3
State on what basis does the strength of an acid and an alkali depend on.
Answer
Strength of acids depends on the concentration of hydronium ion [H3O+] present in an aqueous
solution of an acid.
Strength of alkali depends on the concentration of the hydroxyl ions [OH-] present in an aqueous
solution of the alkali.
Question 4
Differentiate between (i) strong and weak acid (ii) strong and weak alkali with suitable examples
and ionic equations.
Answer
Strong Acid is an acid which dissociates almost completely in aqueous Weak Acid is an acid which disso
solution there by producing a high concentration of hydrogen [H+] ions solution thereby producing a low
[or H3O+ ions] [or H3O+ ions].
HNO3 + H2O ⇌ H3O+ + NO3- [contains almost only ions] CH3COOH ⇌ CH3COO- + H+ [co
Examples : Hydrochloric, Sulphuric and Nitric acid. Examples : Acetic, citric, carboni
(ii) Differences between strong alkali and and weak alkali are as follows :
Strong Alkali is an alkali which dissociates almost completely in Weak Alkali is an alkali which di
aqueous solution thereby producing a high concentration of hydroxyl solution thereby producing a low
[OH-] ions. ions.
NaOH [aq.] ⇌ Na+ + OH- [contains almost only ions] NH4OH [aq.] ⇌ NH4+ + OH- [con
Question 5
Name the ions formed when — HCl; HNO3; H2SO4; CH3COOH; NaOH and NH4OH ionise in
aq. soln.
Answer
(i) When HCl is dissolved in water, it is ionised into hydrogen ion [or H3O+ ion] and chloride ion.
HCl ⟶ H+ + Cl-
The H+ cannot exist independently, therefore, it combines with water molecule to form
hydronium ion (H3O+)
H+ + H2O ⟶ H3O+
(ii) When HNO3 is dissolved in water, it is ionised into hydronium ion and nitrate ion.
HNO3 ⟶ H+ + NO3-
H+ + H2O ⟶ H3O+
(iii) When H2SO4 is dissolved in water, it is ionised into hydronium ion and sulphate ion.
H+ + H2O ⟶ H3O+
(iii) When CH3COOH is dissolved in water, it is ionised into hydronium ion and acetate ion.
CH3COOH ⟶ CH3COO- + H+
H+ + H2O ⟶ H3O+
(iii) When NaOH is dissolved in water, it is ionised into sodium ion and hydroxyl ion.
(iv) When NH4OH is dissolved in water, it is ionised into ammonium ion and hydroxyl ion.
Question 6
State giving reasons which is a stronger acid — dil. HCl or conc. H2CO3.
Answer
Question 7
State why the basicity of acetic acid is one and acidity of calcium hydroxide is two.
Answer
Basicity of acid — is the number of hydrogen ions [H+] which can be produced per molecule of
the acid in aq. soln. Acetic acid [CH3COOH] ionises in aq. soln. and gives one hydrogen ion per
molecule of the acid, hence acetic acid is monobasic i.e., it's basicity is one.
Acidity of base — is the number of hydroxyl ions [OH-] which can be produced per molecule of
the base in aq. soln. Calcium hydroxide Ca(OH)2 ionises in aq. soln. and gives two hydroxyl ions
per molecule of the base, hence calcium hydroxide is a diacidic base i.e., it's acidity is two.
Question 8
Give three reasons with equations wherever required, why Sulphuric acid is a dibasic acid.
Answer
1. It ionises in aq. soln. to produce two hydrogen ions per molecule of the acid.
2. It dissociate in two steps in aq. soln. as shown below:
H2SO4 + H2O ⇌ H3O+ + HSO4-
HSO4- + H2O ⇌ H3O+ + SO42-
H2SO4 + 2H2O ⇌ 2H3O+ + SO42-
3. It contains two replaceable hydrogen ions per molecule of the acid so forms two types of
salt [acid and normal salt] :
NaOH + H2SO4 ⟶ NaHSO4 (Acid Salt) + H2O
2NaOH + H2SO4 ⟶ Na2SO4 (Normal Salt) + 2H2O
Question 9
State how acids are defined as per Arrhenius's and Lowry – Bronsted's theory.
Answer
Arrhenius Theory — Acids are substances which dissociate in aqueous solution to give H+ ions.
Strong acids dissociate almost completely, while weak acids dissociate partially.
Lowry – Bronsted's theory — Acids are proton donors and bases are proton acceptors [proton
= H+].
HCl [aq.] ⟶ H+ + Cl- [acid - proton donors]
NH3 + H+ ⟶ NH4+ [bases - proton acceptors]
Question 10
Oxygen atom in water has two 'lone pair of electrons'. Explain the meaning of the term in italics.
With the help of an electron dot diagram show the formation of hydronium ion and ammonium
ion from a water molecule and an ammonia molecule respectively.
Answer
Oxygen atom in water has two 'lone pair of electrons' implies that two pairs of electrons on
oxygen are not shared with any other atom as shown below:
Question 11
Answer
Question 12
Answer
Question 13
Give equations for the decomposition of a metallic (i) chloride (ii) nitrate with conc. H 2SO4.
Answer
NaCl+H2SO4[conc.]→<200°CNaHSO4+HClNaCl+H2SO4[conc.]<200°C
NaHSO4+HCl
(ii) Decomposition of a metallic nitrate with conc. H2SO4 —
NaNO3+H2SO4[conc.]→<200°CNaHSO4+HNO3NaNO3+H2SO4[conc.]<200°C
NaHSO4+HNO3
Question 14
State in the above reactions a reason for the formation of the respective acids from conc. H 2SO4.
Answer
As H2SO4 is a less volatile acid and displaces the more volatile acid on heating with the salt,
hence the respective acids are formed.
Question 15
Convert (i) NaHCO3 (ii) Na2CO3 to unstable carbonic acid by action with dil. H2SO4.
State the reason why ammonia is evolved when an ammonium salt and alkali are heated.
Answer
Ammonia is evolved when an ammonium salt and alkali are heated because a less volatile base
(e.g.,NaOH) displace the more volatile base, NH4OH and we get the products NH3 and H2O.
Question 16
Define pH value. What would you say about the pH of a solution in which
Answer
pH is defined as the negative logarithm [to the base 10] of the hydrogen ion concentration
expressed in moles/litre. Thus, pH = -log10H+. It represents the strength of acids and alkalis,
expressed in terms of hydrogen ion concentration [H+ aq.]
(ii) When the solution evolves CO2 when heated with Na2CO3, it is acidic in nature with pH less
than 7.
(iii) when, OH-ions > H+ aq. ions, the solution is basic in nature with pH more than 7.
Question 17
Litmus is a common acid-base indicator and not a universal indicator. It only indicates whether a
solution is acidic or alkaline. It cannot be utilized for determining the strength of the acidic or
alkaline solution.
Question 18
State the colour change in a neutral litmus in presence of (i) acidic (ii) alkaline medium.
Answer
(i) A neutral litmus is purple in colour. In presence of an acidic medium, the colour of neutral
litmus changes from purple to red.
(ii) In an alkaline medium, colour of neutral litmus changes from purple to blue.
Question 19
Answer
(iv) The pH paper changes to green colour in human blood tested for medical diagnosis.
Question 20
Define (i) salt (ii) normal salt (iii) acid salt – with relevant examples and equations.
Answer
(i) Salt — A salt is a compound formed by partial or complete replacement of the replaceable
hydrogen ions of an acid by a metallic ion or ammonium ion [basic radical].
NaOH + H2SO4 ⟶ NaHSO4 + H2O [Partial replacement]
(ii) Normal salt — The salt formed by complete replacement of the replaceable hydrogen ion of
an acid molecule by a basic radical [metallic or ammonium ion].
For example,
[Both H ions in sulphuric and sulphurous acid are replaced by metallic radical — sodium. ]
(3) Acid salt — The salt formed by partial replacement of the replaceable hydrogen ion of an
acid molecule by a basic radical [metallic or ammonium ion]. For example,
[Only one H ion in sulphuric and sulphurous acid is replaced by metallic radical — sodium. ]
Question 21
(viii) alum
Answer
(i) Formation of a basic salt — A basic salt is formed by partial replacement of hydroxyl
radicals of a diacidic or triacidic base with an acid radical.
(ii) Components of a basic salt — A basic salt contains a cation [metallic], a hydroxyl ion [of
a base] and an anion [of an acid].
For example — Basic copper nitrate Cu[OH]NO3 , basic copper chloride Cu[OH]Cl
Question 22
Name three (i) sulphates (ii) chlorides insoluble in water and two (i) oxides (ii) carbonates
soluble in water.
Answer
Insoluble in Water
Soluble in Water
Question 23
State the method only, generally used for the preparation of the following salts
(i) Zn(NO3)2
(ii) NH4Cl
(iii) ZnSO4
(iv) ZnS
(v) CaCO3
(vi) FeCl3
(vii) PbCl2
(viii) Pb(NO3)2
Answer
Question 24
(ii) NaHSO4
(iii) Na2SO4
(iv) FeSO4
(v) BaSO4
Answer
1. Preparation of CuSO4:
CuO + H2SO4 ⟶ CuSO4 + H2O
2. Preparation of NaHSO4:
NaOH + H2SO4 ⟶ NaHSO4 + H2O
3. Preparation of Na2SO4:
Na2CO3 + H2SO4 ⟶ Na2SO4 + H2O + CO2
4. Preparation of FeSO4:
Fe + H2SO4 ⟶ FeSO4 + H2
5. Preparation of BaSO4:
BaCl2 + H2SO4 ⟶ BaSO4 + 2HCl
6. Preparation of PbSO4:
Pb(NO3)2 + H2SO4 ⟶ PbSO4 + 2HNO3
1. Preparation of NaHSO4:
NaCl+H2SO4[conc.]→<200°CNaHSO4+HClNaCl+H2SO4[conc.]<200°C
NaHSO4+HCl
2. Preparation of CuSO4:
CuO + H2SO4 ⟶ CuSO4 + H2O
Question 25
Starting from insoluble ZnO how would you obtain insoluble ZnCO3 by precipitation.
Answer
Dissolve zinc oxide in dil. HCl. Add to it a saturated solution of Na2CO3. The precipitate formed
by the interchange of radicals is filtered. It is dried to obtain the zinc carbonate.
Question 26
Answer
Question 27
Answer
Question 28
State what will be the effect of each of the following solution on blue litmus —
Answer
(i) As K2CO3 is a salt of a strong base (KOH) and weak acid (H2CO3), it hydrolyses in water to
give alkaline solutions. They have pH more than 7, hence it will have no effect on blue litmus.
(ii) KCl is a salt of a strong acid (HCl) and a strong base (KOH). Hence it's aqueous solution will
be neutral in nature and will have no effect on blue litmus.
(iii) NH4NO3 is a salt of a strong acid (HNO3) and weak base (NH4OH), it hydrolyses in water to
give an acidic solution. They have pH less than 7, hence will turn blue litmus red.
Question 1
An example of an acid derived from a mineral is ............... [citric acid / nitric acid / acetic acid]
Answer
Question 2
An example of a base which is not an alkali is ............... [caustic soda / zinc hydroxide / liquor
ammonia / caustic potash]
Answer
Question 3
An example of a strong acid is dilute ............... [acetic acid / sulphuric acid / tartaric acid /
carbonic acid]
Answer
Question 4
Answer
Question 5
An acid having basicity 1 is ............... [carbonic acid / acetic acid / sulphurous acid]
Answer
Question 6
An acid obtained by dissolving sulphur trioxide in water is ............... [sulphurous acid / sulphuric
acid / oleum]
Answer
Question 7
A volatile acid obtained when nitre reacts with non-volatile concentrated sulphuric acid on
heating is ............... [hydrochloric acid / sulphuric acid / nitric acid]
Answer
A volatile acid obtained when nitre reacts with non-volatile concentrated sulphuric acid on
heating is nitric acid.
Question 8
A base obtained when lead nitrate undergoes thermal decomposition is ............... [trilead
tetroxide / lead (IV) oxide/ lead (II) oxide].
Answer
A base obtained when lead nitrate undergoes thermal decomposition is lead (II) oxide.
Question 9
An acid obtained when concentrated nitric acid is heated with sulphur is ............... [sulphurous
acid / sulphuric acid / nitrous acid]
Answer
An acid obtained when concentrated nitric acid is heated with sulphur is sulphuric acid.
Question 10
The more volatile acid obtained when the less volatile acid reacts with sodium bicarbonate
is ............... [sulphuric acid / carbonic acid / nitric acid]
Answer
The more volatile acid obtained when the less volatile acid reacts with sodium bicarbonate
is carbonic acid.
Question 11
The insoluble base obtained when sodium hydroxide reacts with iron (III) chloride is ...............
[iron (II) hydroxide / iron (III) hydroxide / iron (II) oxide]
Answer
The insoluble base obtained when sodium hydroxide reacts with iron (III) chloride is Iron (III)
hydroxide.
Question 12
Question 13
The salt formed when sulphuric acid reacts with excess caustic soda solution is ...............
[sodium bisulphite / sodium sulphate / sodium sulphite / sodium bisulphate].
Answer
The salt formed when sulphuric acid reacts with excess caustic soda solution is sodium sulphate.
Question 14
Answer
Question 15
Answer
Question 16
Answer
Question 17
Answer
Question 18
An insoluble salt prepared by direct combination or synthesis is ...............
[FeCl3/FeSO4/FeS/Fe(NO3)2]
Answer
Question 19
A salt prepared by precipitation i.e. by double decomposition of two salt solutions is ...............
[Na2SO4/PbSO4/ZnSO4/CuSO4]
Answer
A salt prepared by precipitation i.e. by double decomposition of two salt solutions is PbSO4.
Question 20
A salt prepared by simple displacement i.e. action of dilute acid on a metal is ...............
[PbCl2/CuCl2/AlCl3/HgCl]
Answer
A salt prepared by simple displacement i.e. action of dilute acid on a metal is AlCl3.
Question 21
Decomposition of calcium hydrogen carbonate with ............... [dil. HNO3 / dil. HCl / dil. H2SO4]
results in formation of calcium chloride.
Answer
Decomposition of calcium hydrogen carbonate with dil. HCl results in formation of calcium
chloride.
Question 22
Action of dilute acid on a metallic sulphide results in evolution of ............... [SO2/H2S/CO2] gas.
Answer
Question 23