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Twelve C-07 Chapter-02 10.07.2020 EV Sadat Ahmed Dipro 2
Twelve C-07 Chapter-02 10.07.2020 EV Sadat Ahmed Dipro 2
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Isomerism of Organic Compounds
The compounds with same molecular formula but different structural formula or different 3d
arrangement of atoms because of which their properties differ are called Isomers of one another
and this property is called Isomerism.
CH − CH − CH
CH − CH − CH − CH |
( ) CH
CH
CH − CH − CH − CH |
CH − CH − CH − CH − CH CH − C − CH
|
( )
CH |
CH
( ) !"
( )
Structural Stereo
isomerism Isomerism
Geometrical Optical
Isomerism Isomerism
Chain Position
Isomerism Functional Group Metamerism Tautomerism Ring Chain
Isomerism Isomerism
#, %)* '
#( %)* '
1.Determining homologues
2. after determining homologous series, establish as many carbon chains as possible by the number of
carbons given in the formula
/! 0 !
/! 0 ! + 3
/! 0 ! 3
/! 0 !14 30
H CH3 H
H H H
H H
Nicol Prism
Polarizer
Polarimeter
Chemistry 2nd Paper
Chapter 2 : Organic Chemistry
Optical Activity
To compare the optical activity of different compounds specific rotation is used. specific rotation [α] is
expressed through the equation-
9 4<<<=
=
: >?
Here, a = observed rotated angle;
@= length of light’s travelled distance inside solution, dm
c = conc. of solution, ABC 4 ; t = temperature ℃
So the solution with conc. 1 ABC 4 kept in a tube of length 1 dm in polarometer if plane polarized kight is
passed the amount of rotation visible is called Specific Rotation of that compound
like, at 25°C if in monochromatic sodium light the relative value of rotated angle in an assymetric
25
compound is = + 37° Then the compound will be called Dextro-Rotatory
D
Y CHO H H
| | | |
X − C∗ − Z H − C∗ − OH H3 C − C∗ − COOH H3C − C∗ − COOH
| | | |
W CH2OH OH Br
Asymmetric Carbon glyceraldehyde lactic acid 2 bromopropanoic acid