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Subject Code :34 (NS)

CHEMISTRY
(Kannada and English Versions)

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Time : 3 Hours 15 Minutesl [Total No. of questions : 37] [Max. Marks:70

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(Kannada Version)

draaldrJ$ : 1. * €dcdg8o$q ooe:e Sqrorirl€d. ae4 SqrrirJddq

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eru$Odz3ed:.

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2. Sqpd-Aol: {d*oSooddo e-od: epoddod 10 ePodrJdl,
Sqprl-Bo$ $ofooa*. 2 epoddod 10 ercdrJq;fu,

SgnrJ-Don
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Sqrori-Cob {doofnoddo 3 eroddod 15 ePodrJdl,
ffiofooa{ S elodrJdod 35 ePodrJq*:.
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3. elrfdrecbo3e| . epodaad aggrJd&d drq d&:eddcorJd&4
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aldogoO.

4. errfdrzsde] sorf &,Sea:ef drdl ddd aororordeoJddco CIdtu'

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(drElt0d u-orqrde0Jd a:dfr3 elduod$g)

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Sqrorf-A

t. * ddnd oe8 €{,Jddq z-od: epodsd. (€e €{olrdq

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en:$otu. €e€{rr"
e.odr # eo$ao e,odr oodrde9- wgiofu) : (10 x 1 = 10)
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1) d}o$ ooJrd:dd; 8eru.

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2) uocb qdead q,oztr oa66 Qardd e.odlod dadb qdd, erd: DdQ
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eed>rOfo{d?

P.T.O.

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34 (NS)
-2- lil{illrtiltttliillllt
3) z,od: doeef MnOo erouddddg Mn2* soJndddqn doaierie'u cd'g
4 JJ^ q-)- J!.
ccdduoet ad;rgQ aaobJaJerad:Qd ?
- -a6rJn{"-z?r?*O

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. 4) aod: gCJoi g,oJD
Xoodd sdd mol-t
LS-' , u !,c3.:C; drlr 89,1.

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5) a"do6 sdrer df;eou:od d.:Qeddsartogi'rd z.od: eloeddQ dio,l.

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6) dr ddnd goJrolrQ dPearrtoe:r.
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7) eru?.Jo1; doSd Oriocf aodded>?

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8) €r ddnd gofroJrQ dio:r.

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HeC - Br + AgF + H3C - F + AgBr

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9) adoas"dl (cH3cHo) (J%ef (AIdol) xaog,eddeo golrri udddJ{d'

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aadeod,oB.
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10) o$ad at:tu6fd doddoo:od odq (Rickets) doeddl ud:{d?

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^
-J- 34 (NS)
fiilillll{iltll fiil lll
Sqrori-B

!r. * ddnd oindcmddn ocd) €EcrJer3 erudOfu.

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qi8olnod: €d4oira
2 elodrJd&d d.ooBd:dd (5x2=10)

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11) qgoder d,n dd ooddeoS? ed> dda mo{doJ: d:ee3 o$ad domaab zredodd?

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12) €@oo'-u!ror "aodd doedd z3$ udcb enarlridQ dio:,. doedd dd Q*ag
ddobd gCroJrQ udou:0.

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13) r.od: ddal !,ohdrlrd dd Soaodd K:5.5'10-laS-1 uRqd, edd erdr
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deaaodoo$Q dodl &aobo.
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14) aadea Eoa.

a) &oo$o (Ce) ++ w{drea

eeoJrQ doeoio{d.
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b) pd:aood pod:Ari, og{a" (Actinoid) er#ozddd) orod{a'

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(Lanthanoid ) erdcoe3dgod dagnd.

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15) .addoobr u{dp&d

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?,igtuarcdl erOioef (Anisole) d drod deri d.9rd:{d?

.add mrro$ed goJJo$Q udou:o.
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34 (NS) -4- llllllillilfiliiilltrit

16) o-omoJ:&d ia:eddmC dodd ryzrdcosr (Grignard) ez.praddd iaaC:Ood
razrorSdd (Ca rboxyl ic) vQdd dofno*oCQ ado,r,.

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17) d* ddndd)rlqrl uoC>'erumddd dna.

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a) drdd mrad*

b) uodoru3f dedandmo

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18) uaror erCnpto (Cationic) d>ardddodded:? z.od: erumddd doa.

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Sqnrl-C
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lll. * dd8ddrJde} ohdoodo 6cd) €{rJed eru$otu. qi8oloodo €{olr^
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3 erodrldd:o odooAd:gid (5 x 3 = 15)

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19) oo;oo:.:Od dareddcorid dradri 6d{d dB€ (Copper matte) oe:od Bdd
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o{ddi ddobd dgobctdi adotu. (3)

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2A) uxoaagd aOadd ,r*d doiDodo$g e^,drlood da:eddcoridd;

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d,rjot
ouoddzldooori sJdobo. (3)
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21') a) udoe{co' ufrro"d; qio3oenae.:$dg deri dolnoioqd? ia:eddea

udou:o. (21

b) 'z^,OoJ:o"d (Oleum) JooJoerdof:d; dna (1)

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_6_
34 (NS)
fi!ril i*ffi ilti fiil fiI
22) dr ddnd da:eddeadd.{ dnrarrkop,r,.

a) 2NaOH + Clr+ NaCl +.... + HrO (1)

b) NarSO, + 2HCl+ 2NaCl + HrO +.... (1)

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c) Ct, + 3% --!4I-+ .. (1)

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23) MnO2 &od KMnOo Q (Potassium Permanganate) derl dohoiodd:r

Ja:eddeoddd; dor:0, (3)

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24) a)
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3d- ddsdob dme-tdfgddc u{c1> gohddrddqnn derio{d ad? (2)
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b) Ti4* e.:deorldc deordadamnd, sdd Cr3* odearidc dearob{a"n&qd.
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uadea doa. (1)

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25) d.d* uofr tuqod (VBT) d iaaoJ:CIod [NiCl4]2-d erora:8, ioddea d:d?
ado:r.
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rao3eC: rbearldd: (3)

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didQ udouo.
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26). a) [Co(NH. )4 (H2O)C|]Cl2 d IUPAC (1)

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b) draado$ (Linkage) Jd>orldc:Q wzmdddoi dEod ado&. (21

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34 (NS) -6-
llNllllIIil llll iif Illf
SzPrJ-D

!v. * ddnd ohdcmddn dlJo& €dcrid&{ en:$Otu. {edood: €d{oira ocdl

elodrJdd)4 dooadrgid. (3 x 5 = 15)

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27) a) idd doa68 zoerd Jode;d dddo$Q (Packing efficiency) eJ{ aaao. (3)

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b) *)o deoQd zroe-:d #ddO e-od> pod:ad ddd>ea: dod
107.9 rgo/diaef erndrqd. €r +ila{eC: eroz3d *dd 408.6 pm un{d,

g.
'add ;oo{do3rQ el{oaa INn : 6.022*1023 mol-1]. (2t

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2S) a) dcaoUd zeod: 353.23K ad:{d. 1.80 r9o doddg ercolrrrld,
aJoS&d
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erolrreddcorlodd dddddi 90 q9o zJodo' ogddd$ ddn:,esad agdead
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d;aoUd asod) 354.11 K rl dErf:{d. er ogdeadQ&d ddrd
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b) aadaDr0e.
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i) ogdead d:oore-:d (Molality) (1)

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ii) iabdoaid e-{d (lsotonic) agdearidc (1)

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29) a) €l ddnd Ja:eddead$ doed D?.Jd (EMF) d{ aaEo.

"Q
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Mgr.l + Cu2* (0.0001 M) -+ Mg'* (0.001 M) + Cu151

- Eilnr.^n = -2.37 V
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dqd

ESrr*lc,=+0'34V' (3)
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b) i) doeepdq eobdrdd.i udoo:o. (1)

ii) dda:eeob dPe>d aoddd erodded:? (1)

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t]tri it i$$it tili tit I IlI -7- 34 (NS)

30) a) d**, gmadrlrd oaxaoJ:&d goiJo$ ed:dO,r,d (integrated) dg 6cnod

b) duuddeo dqcb (E" ) d.:eeJ derl$rdd doaad:dd.; aqJd dq V/S

dsgolrr JdoSoea;dd df,c:g udd: doeo:,. (21

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31) a) cgdua4dDo dJQ Bdd de
a
& dOe.:dd dd:ad oln$coddo add:
d^o^Jdd& udouo. (21

g.
ao.t

.)eoBC: derl dt'rd aodded>? rod: en:mddd doc

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b) (21

c) deer eQdoededC: ndoeidol: (expression)

udobo. ib r{sadoeg

({)
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V. Ednd€rrJde} olDdoodd/a doeDo d{rJ€r3 erudOfu.
J {Solood: €{d*
6cc$ erodrJd&c doo6d:gld. (4x5=201
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32) a) rr&rc)o *r€s z,igd.3""Q (tert-butyl bromide) $&ro3ro zaoruf,er

ueJ4eaaenn doderiDd S* 1 !,o$do$d dodrld ia:eddearldQ udou:o.

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(21

b) dptiri" goSr"lrQ adOa. (21

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c) deloue{dd a€dgedeloeddddd gobo$9 erudoloenlod

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d.egoiDuadddq dJoe. (1)

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34 (NS) -B-
llllllllfillllttitltll
33) a) €idoaef (Ethanol) Ood diqed (Ethene)d; ddcDd u{ deddt'rd

d $o1nd o-gde.* adox,. (3)

&as r Oedd eo

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b) 4loiEef drQ eid€oaefd ddrd olDddJ d?*ri e'Qo$r ad? (21

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34) a) doerd d>:od (Rosenmunds) erdddrco gofuCrQ Ja:eddca dSod
''J

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(21
adox,.

b) dDddoN" .(CH3COCH3) ib d drodri €e*ar o$Ed oeg dario{d?

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(21
Ca:eddea doa.
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c) aucuer (Etard) goircbg erudCoeniod w{drd eeptadddQ diox,. (1)

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35) a) uazf,rer cdJrf (carbyl amine) go3rojrQ ia:eddea dEod adotu' (21
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b) eJn erddarir:dd: deri? ia:eddea doa

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{rsgerJoddd; ucoo'(Aniline)
(2)
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c) coHs -X;i-' d IuPAC didq udouro.

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(1)

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-9- 34 (Ns)
fifiiliiltil tIIilit flil
36) a) erord,ger (Lactose) d daadrd dddo$di udc:0. (2)

b) i) edrld, er.):edo uQrldodded:? (1)

ii) d,r&6fd (Glycine) Hrr,f eycb&d xadnd, f,ngdQ udou:0. (1)

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c) RNA c:g&d erdd DNA cigdd xadaddobd d-r*dQ dno,l. (1)

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37) a) d*ir -6,6 d dofnodC:Q na:eddeadooori adot. (2)

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b) frdoerq&u'rldodded;?
' 6eJ z.ocb eruaadd# doa. (2)

c) ib
ocdo.go' (2-methyl-l, 3-butadiene) d deJdo$d; r^:dou:o. (1)
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34 (NS) -'10-
fitiltlIgitrllliiil Ifil
(English Version)

lnstructions : 1. The question paper has four parts. Att parts are
compulsory.
2. Part-A carries 10 marks. Each question carries one mark.

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Paft-B carries 10 marks. Each question carries two marks.
Part-C carries 15 marks. Each question carries three

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marks.
ParT-D carries 35 marks. Each question carries five marks.

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3. Write balanced chemical equations and draw diagrams
wherever necessary.

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4. l,Jse tog tabtes and simple calculator if necessary. (Use of
scientific calculator is not altowed.)

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PART -A
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l. Answer all the questions. Each question carries one mark. (Answer each
question in one word or in one sentence) : (10 x 1 = 10)
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1) State Henry's law.

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2) Van't Hoffs factor for a solution is less than one, what is the conclusion
drawn from it.
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3) How many Faraday of electricity IS required to reduce 1 mole of MnOo

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ions to Mn2* ions?

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4) lf the unit of rate constant of a reaction is mol-lLS-1 then mention its

order.
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5) Name a metal refined by Van Arkel method.

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lillililljllllliil llll -11- 34 (NS)

6) Complete the following equation.
XeFu + HrO -+ .... . + 2HF .

7) What is an ambidentate ligand?

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B) Name the following reaction.

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H.C -Br+ AgF + H.C- F+ AgBr.

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9) Ethanal (CH3CHO) undergoes aldol condensation reaction. Give reason.

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1o) Deficiency of which vitamin causes the disease ,,Rickets,,.

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PART _ B
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ll. Answer any five of the following. Each question carries 2 marks : (5 x 2 = 101
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' 11) What is Frenkel defect? How does it affect density of the solid?
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' 12) Draw a neat labelled diagram of Hr-O, fuel cell. Write the reaction
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occurs at cathode of the cell.

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13) A first order reaction is found to have a rate constant, K=S.Sx10-145-1.

'' Find the half-life of the reaction.
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,, 141 Give reason :

,,
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d) Cerium (Ce) exhibits +4 oxidation state.

r b) Actinoid contraction is greater from element to etement than
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lanthanoid contraction.

15) How anisole reacts with bromine in ethanoic acid? Write the chemical
equation for the reaction.

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34 (NS) -12- fillllllfilllli lil ltl[

16) Explain the preparation of carboxylic acids from Grignard reagent. Give
equation.

17) Give an example each for

a)

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Artificial sweetening agents
:

b) Narcotic analgesics.

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18) What are cationic detergents? Give an example.

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PART - C

lll. Answer any five of the following. Each question carries 3 marks : (5 x 3 = 15)
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19) Explain the process of obtaining "blister copper" from "copper matte"
' with equations
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20) Write the equations involved in the manufacture of nitric acid by Ostwalds
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process by maintaining reaction conditions

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21) a) How is Ozonised oxygen prepared in the laboratory? Give equation.

(21
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b) Give the composition of "Oleum". (1)

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22) Complete the following equations :

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a) 2NaOH + Cl2 -+ NaCl + .... + HrO (1)

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b) NarSO. + 2HCl -+ 2NaCl+ HrO +.... (1)

c) Clr+3F2
-izgr(
-+..... (1)

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Iillillilllllililllll -13- 34 (NS)

24 How is potassium permanganate (KMnOo) prepared from MnOr? Write

the equations. (3)

24) a) Why 3d-series of elements acts as good catalyst? (21

: Ti4* salts are colourless where as Cr3* salts

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b) Given reason are
coloured. (1)

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25) With the help of Valence Bond Theory UBT), explain hybridisation,
geometry and magnetic property of [NiCl4]2-. (3)

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26) a) Write the IUPAC name of : [Co(NH3)4 (H2O)Cl]Cl2 . (1)

b) Explain linkage isomerism with example. (21

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PART - D
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lV. Answer any three of the following. Each question carries 5 marks :

(3x5=15)
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27) a) Calculate packing efficiency in simple cubic lattiee. (3)

b) An element having atomic mass 107.9 u has FCC lattice. The edge
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length of its unit cell is 408.6 pm. Calculate density of the unit cell.
[Given, NR : 6.022*1023mo1-11. (21
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28\ a) The boiling point of benzene is 353.23 K. When 1.80 g of a

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non-volatile, non-ionisable solute was dissolved in 90 g of benzene,

the boiling point raised to 354.11 K. Calculate molar mass of the
solute. [Ko for benzene = 2.53 K Kg mol-1]. (3)
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b) Define :
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i) Molality of a solution. (1)

ii) lsotonic solutions. (1)

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34 (NS) -14-
ilil iilIIiI l|tiiil Ittl
2e) a) Calculate e.m.f. of the cell for the reaction :

Mgr.l + cu2*(0.0001 M) -+ Mg'*(0.001 M)+ cu,,

Given that : Ei,nr.rrn = -2.37 V

m
ESrr*r., = +0.34 V. (3)

b) i) State Kohlrausch law. (1)

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What is meant by limiting molar conductance. (1)
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30) a) Derive an integrated rate equation for rate constant of a first order
reaction. (3)

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b) Draw a graph of potential energy ViS reaction co-ordinates showing
the effect of catalyst on activation energy (E, ) of a reaction (21.
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31) a) Write any two differences between lyophilic and lyophobic colloids.
(21

What is heterogeneous catalysis? Give an example.

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b) (21

c) Give an expression for Freundlich adsorption isotherm. (1)

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V. Answer any four of the following. Each question carries 5 marks : (4 x 5 = 20)
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32) a) Write the equations for the steps in Sru1 mechanism of the
conversion of tert-Butyl bromide into tert-Butyl alcohol. (21
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b) Explain Fittig reaction. (21

c) Name the reagent used in the dehydrohalogenation of hatoatkanes.

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(1)
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33) a) Write the mechanism of acid catalysed dehydration of ethano! to

ethene. (3)

b) Between phenol and alcohol which is more acidic? Why? (21

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-1 5- 34 (NS)
ilIri'ifiitilfiiixI;tl
34) a) Explain Rosenmund reduction with equation. (21

b) How does propanone (cH3cocH3 ) reacts with hydrazine? Give

equation. el
c) Name an oxidising agent used in the Etard's reaction. (1)

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35) a) Explain carbyl amine reaction with equation. (2)

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b) How does, nitrobenzene is reduced to aniline? Give equation. (21

c) Write the IUPAC name of

g.
coHs -f -cH. (1)
CH.

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36) a)

i)
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Write Haworth structure of "Lactose". (2)
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b) What are non-essential amino acids? (1)
ii) Write Zwitter ionic structure of "glycine". (1)
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c) Name the nitrogenous base present in RNA but not in DNA. (f)
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37) a) Explain the preparation of Nylon-6, 6 with equation. (2)

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b) What are thermoplastic polymers? Give an example- (21

c) Write the structure of isoprene (2-methyl-1, 3-butadiene). (1)

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