Classification and Nomenclature

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Exercise - I
1. IUPAC name of following compound is: 5. IUPAC name of:
NO2 Cl

Cl C2H5
CH3 CH3

(1) 4-Methyl-5-chloro-nitrobenzene (1) 3-Chloro-5-ethyl-5-methylcyclohex-1-ene

(2) 2-Chloro-1-methyl-4-nitrobenzene (2) 2-Chloro-4-ethyl-5-methylcyclohexene

(3) 1-Chloro-2-methyl-5-nitrobenzene (3) 6-Chloro-4-ethyl-3-methylcyclohex-1-ene

(4) 5-Chloro-3-ethyl-2-methylcyclohex-1-ene
(4) 1-Methyl-2-chloro-4-nitrobenzene
CH3
2. IUPAC name for following compound

CH2=CH–CH2–CH–C  CH 6. Cl Br
OH
IUPAC name of given compound is :-
(1) Hex-1-en-5-yn-4-ol (1) 2-Bromo-4-chloro-3-methyl-4-
(2) Hex-5-en-1-yn-3-ol phenylpentane
(3) 4-Hydroxyhex-1-en-5-yne (2) 2-Chloro-4-Bromo-3-methyl-1-
(4) 3-Hydroxyhex-5-en-1-yne phenylpentane
3. IUPAC name for given compound is:- (3) 4-Bromo-2-chloro-3-methyl-1-
phenylpentane
(4) 3-Methyl-2-bromo-4-chloro-5-
phenylpentane
7. IUPAC name of:
(1) 3-Ethyl-4-isopropylhex-1-ene
CH2=CH–C–CH2–CCH
(2) 3, 4-Diisopropylhex-1-ene
(3) 4-Ethyl-3-isopropyl-5-methylhex-1-ene CH2

(4) 3-Ethyl-4-isopropyl-2-methylhex-5-ene (1) 2-Propynylbuta-1, 2-diene

4. IUPAC name for given compound is :- (2) 4-Methylenehex-5-en-1-yne

CH2—COOH (3) 3-Methylenehex-1-en-5-yne

(4) 2-Vinylpent-1-en-4-yne
CH—OH
8. IUPAC name of the given compound
CH—COOH
CH3–C–CH2–CH–CH2–CH3
CH2—COOH
O CN
(1) 3-Hydroxybutane-1,3,5-trioic acid (1) 4-Cyanohex-2-one
(2) 3-Hydroxy-4-carboxyhexan-1,6- dioic acid (2) 2-Ethyl-4-oxopentanenitrile
(3) 2-Hydroxybutane-1,3,4-tricarboxylic acid (3) 2-Oxo-4-cyanohexane
(4) 3-Hydroxybutane-1,2,4-tricarboxylic acid (4) 2-Oxo-hexane-4-nitrile
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 NEET : Extra Edge [Chemistry]
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9. The IUPAC name of the compound 12. CH3—CH—CH2—CH—
O CH3 CH3
H Radical has IUPAC name–
(1) 4-methylpentyl (2) 1,3-Dimethylbutyl
NH2 (3) 2,4-Dimethylbutyl (4) 3-methylpentyl
13. One among the following is the correct IUPAC
(1) 3-Amino-2-ethyl-3-ethenylhexanal
name for the compound
(2) 3-Amino-2-ethyl-3-propylpent-4-en-1-al
H H
(3) 2-Ethyl-3-amino-3-propylpent-4-enal
CH3CH2—N—C=O
(4) 4-Propyl-3-oxo-5-hexen-4-amine
(1) N-Formylaminoethane
10. Number of carbon in parent carbon chain in
(2) N-Ethylformylamine
the following compound
(3) N-Ethylmethanamide
COOH (4) Ethylaminomethanal
C CH2CH3 14. The IUPAC name of the compound
CH3CH2 C OH
H is
O
CH3
(1) 4 (2) 5
(3) 6 (4) 3 (1) 4-Methylcyclopent-1-en-2-ol
(2) 2-Methylcyclopent-4-en-1-ol
11. The correct IUPAC name of following
(3) 3-Methylcylopent-1-en-2-ol
compound is :
(4) 5-Methylcyclopent-2-en-1-ol
Br 15. IUPAC name of given compound is :-
Cl
Cl

Me Me
(1) 2-Bromo-3-chloro-5,5-dimethylcyclohex
(1) 2-Chloro-5-methyl-3-(prop-1'-
-1-ene
enyl)hepta-1,4-diene
(2) 1-Bromo-6-chloro-4,4-dimethylcyclohex
(2) 4-(1'-Chloroethenyl)-6-methylocta-2,5-
-1-ene diene
(3) 4-Bromo-5-chloro-1,1-dimethylcyclohex (3) 5-(1'-Chloroethenyl)-3-methylocta-3,6-
-1-ene diene
(4) 1-Bromo-2-chloro-4,4-imenthylcyclohex (4) 4-(1'-Chloroethenyl)-6-ethylocta-2,5-
-1-ene diene

Exercise-I ANSWER KEY

Question 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Answer 2 2 3 4 3 3 3 2 2 2 2 2 3 4 2
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Classification and Nomenclature
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Exercise - II
1. Match list-I with list-II 3. Correct match is
List-I List-II
(Compound) (Number of (1) → 3-Bromo but-2-ene
Br
carbon in PCC)
C2H5
(2) → 3-Amino pent-2-ene
(a) CH3–C–CH2–CHO (p) 3C NH2
CH3
(3) → 2-Methyl but-2-yne
OH Br
CH3
(b) (q) 4C (4) → 1-Methyl cyclopentene
NO2
4. The hybridization of C2, C3 and C4
(c) (r) 5C
COOH 2
5
respectively
(d) CH3–C — C–CH2–CH2–CH3 (s) 6C 1
3
4

CH2 CH2 (1) sp2,

sp3, sp
Choose the correct answer from the options (2) sp3, sp2, sp
given below :- (3) sp2, sp, sp
(1) a–q b–p c–r d–s (2) a–r b–s c–p d–q (4) sp, sp3, sp2
(3) a–p b–q c–r d–s (4) a–r b–p c–s d–q 5. Which set of IUPAC name is wrong ?
2. Wrong IUPAC name is :-
(a) 3-Ethyl-1-pentene
(1) CH3–CH(Cl)–CH(Br)–CH2–CH(Cl)CH3
(b) 2-Hydroxy butane
2,5-Dichloro-3-bromohexane
(c) 2-Cyano-3-hydroxybutane
(2) CH3–CH=CH–COOH
(d) 2-Formyl ethanoic acid
But-2-enoic acid
(3) (CH3)3CCH2OH (1) a and c
2,2-Dimethylpropan-1-ol (2) c and d
(4) CH3CH2NHCH3 (3) a, b, c
N-Methylethanamine (4) b, c and d

Exercise-II ANSWER KEY

Question 1 2 3 4 5
Answer 2 1 4 1 4
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