(6001CJA10102124006) Test Pattern

CLASSROOM CONTACT PROGRAMME JEE (Advanced)

MAJOR
(Academic Session : 2024 - 2025)
07-07-2024

JEE(Main + Advanced) : ENTHUSIAST_MOR/AFT BATCH (PHASE : 1 & 2)

INTERNAL TEST - 03 (MAJOR)
ANSWER KEY
PHYSICS
Q. 1 2 3 4 5 6
SECTION-I(i)
A. D B C A B C
Q. 7 8 9 10 11 12
SECTION-I(ii)
A. A,B,C A A,D A,B,C A,C,D A,B

Q. 1 2 3 4 5 6
SECTION-II
A. 4.00 4.00 4.00 3.00 8.00 6.66 to 6.67

CHEMISTRY
Q. 1 2 3 4 5 6
SECTION-I(i)
A. C B B A C D
Q. 7 8 9 10 11 12
SECTION-I(ii)
A. B,C A,B,C,D A,D A,C,D A,B,C A
Q. 1 2 3 4 5 6
SECTION-II
A. 1.00 7.00 9.20 0.22 to 0.23 5.00 4.00

MATHEMATICS
Q. 1 2 3 4 5 6
SECTION-I(i)
A. C B A D A B

Q. 7 8 9 10 11 12
SECTION-I(ii)
A. A,B,C A,B,D A,B,C A,C A,C,D B,C,D

Q. 1 2 3 4 5 6
SECTION-II
A. 150.00 4.00 8.00 10.00 10.00 5.00

HINT – SHEET

6001CJA10102124006 HS-1/9
 Target : IIT-JEE (M + A) 2025
PHYSICS 3. Ans ( C )
Q
SECTION-I(i) ϕbase + ϕCSA =
∈0
1. Ans ( D ) Now when the second charge is placed. Because
We consider two differential elements on the of this the flux from the base is same as ϕbase as
rod as shown in figure. These elements in the previous case which passes through the
constitute an electric dipole whose dipole curved surface. Hence,
moment is Q
ϕ1 + ϕ2 = QCSA + Qbase =
∈0
4. Ans ( A )
KS
(T − 400) = eσS (4004 − 3004 )
L
= eσS (108 ) (256 − 81)
σeL 8
T − 400 = 10 × 175
K
0.8 × 5.67 × 10−8 × 1 × 108 × 175
=
∣d P
→∣ 0.0567
∣ ∣ = (λRdθ) (2R sin θ) ⇒ T = 14400K
Net dipole moment of the system is
= 2λR2 (1 − cos θ1 ) = 4λR2 sin2 (θ0 /2) 6. Ans ( C )
Time period of oscillation of a dipole in a Rate of cooling (− dT ) ∝ emissivity (e)
dt
uniform magnetic field is From the graph,
T = 2π√
I dT dT
(− ) > (− ) ∴ ex > ey
pE dt x dt y
= 2π√
mR2 further emissivity (e) ∝ absorptive power (a)
4λR2 sin2(θ0 /2) E (good absorbers are good emitters also)
m
= π√ ∴ ax > ay
λsin2 (θ0 /2) E
PHYSICS
2. Ans ( B )
The distance between the orbiting stars is SECTION-I(ii)

d = 2r cos 30∘ = √3r. The net inward force on 7. Ans ( A,B,C )

orbiting stars is (A) charge enclosed = 0 if d > R Hence flux is
zero
2
L2
(B) ( ) = R2 − d 2 L = 2√R2 − d 2 , charged
2
enclosed = λL F lux ϕ = q/∈0
d −R
→ d→l = ∫
(C) E = λ , ΔV = ∫ E. λ
dr
Gm2 Gm2 mv2 2πε0 r 2πε0 r
GMm
cos 30∘ + + cos 30∘ = d+R
d2 r 2 d 2 r (D) W is zero only between equipotential points.
∴ G[
m 4π 2 r3
+ M] = or
√3 T2


T = 2p
r3
⎷ G (M + m )
√3

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8. Ans ( A ) 12. Ans ( A,B )
By node analysis, x = 0
⇒ ΔQ through S, is zero
Q0
ΔQf on C = CV =
2
Q
⇒ ΔQ through S2 = 0
6

9. Ans ( A,D )
2
Ui = ε0 E 2 (initial volume)
3 For null point current flow in the loop CD only
1 Q2 Q2 a
Ui = ε 0 (AQ) = 3V
2 A2 ∈20 2a∈0 i= = 1A
2Ω + 1Ω
2
Q a Q2a VCD = 1V − 1(1) = 0
Uf = ⇒ Wext = Uf − Ui = = Ui
A∈0 2A∈0 ∴ option (A) is correct.
⇒ A and D are correct.
When Jockey touches to B current flow from A
10. Ans ( A,B,C ) to B to increase the P.D. across the secondary
circuit.
For (A) : Orbital speed v0 = √ GM
r ∴ option (B) is correct.
For (B) : Time period of revolution T 2 ∝ r3
PHYSICS
For (C/D) : Total energy = − GMm
2r SECTION-II
11. Ans ( A,C,D )
Using Kirchhoff’s junction rule and considering 1. Ans ( 4.00 )
5 Ω and 10 Ω to be in parallel, the current Total flux crossing the closed cylinder is
ϕ = ϕ1 + ϕ2 + ϕ3
distribution will be as follows.
Where, ϕ1 , ϕ2 , ϕ3 are the flux linked with
surfaces 1,2, and 3, respectively

→ 1 = 200i^ ⋅ 10−2 ^i = 2N − m2 /C
→ ⋅A
ϕ1 = E
→ ⋅A
ϕ2 = E → =0
2
Using KVL in Left upper loop : → = 200i^ ⋅ (10−2 ^i ) = 2N − m2 /C
→ ⋅A
ϕ =E
3 2
ε 1 – 3 – 20 – 50 = 0 ⇒ ε ​1 = 73 V
qin
Using KVL in Right upper loop : So, from Gauss’s law, ϕ =
ε0
ε2 − 24 + 12 − 60 − 550 = 0 ⇒ qm = ϕ × ε0 = 4ε0
⇒ ε2 = 122V
Using KVL in the Lower loop :
2. Ans ( 4.00 )
−2R − 73 + 3 − 24 + 122 = 0
dτ = x. dF . sin θ = x (λ. dx. ) sin θ
σ
⇒ 2R = 28V 2ε0
R = 14Ω σ L2
τ=λ sin θ
2ε0 2
σL2
τnet = 2τ = λ sin θ
2ε0

6001CJA10102124006 HS-3/9
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3. Ans ( 4.00 ) 6. Ans ( 6.66 to 6.67 )
with switch open, C2 & C3 are in series and The given circuit forms a balanced Wheat Stone
then short circuited ⇒ Q2b + Q3a = 0 (with S Bridge as shown
open)
With S closed – Node analysis at P
C (x − V ) + C (x − V ) + C (x − V ) + C (x − 0) = 0
3V
3x − 3V + x = 0 ⇒ x = P R
4 Since =
⇒ Q2b + Q3a = C (V − x) + C (V − x) Q S
V CV
= 2C [ ] = 4 ( )⇒K=4
4 8
4. Ans ( 3.00 )
GMm G4Mm
− − So, resistance between A and B is ignored.
2R 4R
GMm G4Mm 1 The voltmeter will read the potential difference
=− − + mV 2
5R R 2 across resistance Q.
⇒ V = 3√
3GM
10 1
5R Current i1 = i2 = = A
100 + 200 30
Potential difference across voltmeter
5. Ans ( 8.00 ) 1 20
= Qi1 = 200 × = V
30 3
In Δ AOB, cos 60o = R ⇒ OB = 2R
OB Reading of voltmeter = 20 V
(where OB is orbital radius) 3
CHEMISTRY
SECTION-I(i)

1. Ans ( C )
1. MnO2Θ 4 ion is stable in high alkali medium or
high pH and on decreasing pH it
disproportionate in MnOΘ4 and MnO2
Here gravitational force will provide the 2. In Acidic medium, MnOΘ4 reduced to Mn2 ⊕
required centripetal force. and in neutral or slight alkali medium it reduced
GMm to Mn4 ⊕ that’s why it is a good oxidising agent
Hence = m (OB) ω2
2
(OB) in acidic medium,
⇒ω=√ =√ ⇒ω=√
GM GM GM 3. KMnO4 can acts as oxidising agent in
3 3
(OB) (2R) 8R3 alkaline medium and form Mn4 ⊕ .
In
Mn7⊕ + 3eΘ −−−−−−−−−−→ Mn4⊕
alkaline medium
F usion electrolytic
4. MnO2 −−−−−− → MnO2Θ 4 −−−−−−→ MnOΘ4
O2 +KOH oxidation

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2. Ans ( B ) 6. Ans ( D )
(a)
I. Ethyl ether + acetone : shows positive
deviation from Raoult’s law so final
volume will be more than initial total volume.
II. Chloroform + acetone : shows negative
deviation from Raoult’s law so final
volume will be less than initial total volume.
III. n – Hexane + h – heptane: ideal solution so
final volume will be equal to sum of initial
volume.
So, VI > VIII > VII
(b) For an ideal solution and non-ideal solution
Δ Smix > 0.
(c) For ideal solution Δ Hmix = 0 CHEMISTRY
For positive deviation Δ Hmix > 0
SECTION-I(ii)
For negative deviation Δ Hmix < 0
7. Ans ( B,C )
3. Ans ( B )
For the complex ion to get oxidised, its (Fact)
reduction potential should be low. 8. Ans ( A,B,C,D )
Correct options are A) , B) , C) and D)
4. Ans ( A )
(A) Conductivity cells have cell constant values
pH = Cα = 10−4
independent of the solution filled into the cell.
10−4 1
α= = The value of the cell constant depends on the
0.0015 15
ℓ length and the area of the electrodes. It is the
K = G. ( )
A ℓ
120 ratio Hence, the option (A) is correct.
−7
= 5 × 10 × = 6 × 10−5 Scm – 1 a
1 (B) DC (direct current) is not used for measuring
K × 1000 6 × 10−5 × 1000 the resistance of a solution. A.C current is used
Λm = =
C 0.0015
Λ 6 × 10 −5
× 1000 0.0015
for this purpose. Hence, option B is correct.
m
Λ0m = = × (C) Kohlrausch law is valid both for strong and
α 0.0015 10−4
2 –1 weak electrolytes. However, the law is
= 600 S cm mol .
5. Ans ( C ) particularly valuable to calculate Λ o​of weak
electrolytes.
Hence, option C is correct.
(D) The specific conductivity k decreases but the
molar conductivity λ M​and the equivalent
conductivity λ E​increase on dilution. This is
because, on dilution, the total number of ions
increases (due to an increase in the degree of
dissociation) and the number of ions per unit
volume decreases.
Hence, option D is correct.
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 Target : IIT-JEE (M + A) 2025
9. Ans ( A,D ) 2. Ans ( 7.00 )

25m + 100p = 250

m + 4p = 10 ......(1)

100m + 80n = 440

5m + 4n = 22 ......(2)
From graph it is clear that there is +ve
deviation w.r.t. L. Therefore, option (a) is
correct. When xL → 1, then z will have value
equal to PL∘ (vapour pressure of pure L).
Therefore, option (d) is also correct.
10. Ans ( A,C,D )
(A) In 3d-series, from left to right (across the
period) stability of +3 oxidation state decreases
and stability of +2 oxidation state increases
(B) In 3d series, from Sc to Fe atomic size
decreases, Fe, Co and Ni have almost same From the extrapolation of curve
radius. and from Ni to Zn atomic radius Λ∘ (Zm Xn ) = 340
increase
(D) [Ni(CO)4] → Ni0 50m + 80n = 340
[Fe(CO)5] → F e0 5m + 8n = 34 .......(3)
[Cr(CO)6] → Cr0 (3) — (2) ⇒ 4n = 12 ⇒ n = 3
11. Ans ( A,B,C ) Putting in (2) we get m = 2
In option – D, Acid / base reaction will take Putting in (1) we get p = 2
place m+n+p=2+3+2=7
12. Ans ( A ) 3. Ans ( 9.20 )
Conceptual Δ Tf = iKfm
0.2/60
CHEMISTRY 0.45 = [1 – α (1/2) ] × 5
20/1000
SECTION-II α = 0.92
1. Ans ( 1.00 ) 4. Ans ( 0.22 to 0.23 )
(110 + 230 – 196.5) = (2.4 × 10 – 6 – 1.4 × 10 – 6) 2Cu(NO3 )2 + 5KI → Cu2 I2 + KI3 + KNO3
3 0.02 0.01
10
× H2 S + KI3 + H2 O → S ↓ + KI + 2HI
C ( litre
mol
) 0.01 0.01
S + O2 → SO2
10−3 mol 0.01 0.01
C= ∴ vol. of SO2 at STP= 22.7 × 0.01 = 0.227L
143.5 litre
10−3 1mg
S= × 143.5gm = = 1.00
143.5 litre

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5. Ans ( 5.00 ) 3. Ans ( A )
Put y = 0 ⇒ f(x) = f(x) + f(0)
The reactant will be more reactive than
⇒f(0) = 0 ⇒ c = 0
in a SN2 reaction which have following Put y = – x ⇒f(0) = f(x) + f( – x) – x2
characteristics. 0 = ax2 + bx + ax2 – bx – x2
(i) Have better leaving group than Cl 2
⇒x (2a – 1) = 0 a = 1/2
(ii) Have less sterically alkyl halide than 2º R – ⇒ b = 5/2
X
4. Ans ( D )
(a) (I is good L.G. than Cl) 1 | sin x|
lim
(c) (1º aklyl halide) x→0 √2 x
1 sin x 1
(d) (1º alkyl halide + Br is good R. H. L ⇒ lim+ =
x→0 √2 x √2
L.G. than Cl) 1 (− sin x) −1
(f) CH3 – Cl (Less bulky) L. H. L ⇒ lim− =
x→0 √2 x √2
(g) CH3 – CH2 – Br(1º alkyl halde + good L.G.) 5. Ans ( A )
6. Ans ( 4.00 ) R.H.L = L.H.L. = f(0)
I, III, IV, V tan 2x⋅2x
2x⋅
tan 3x −a
⇒ lim+ e 3x
⋅3x
= lim− (1 − sin x) sin x = b
MATHEMATICS x→0
−a
x→0
2 lim sin x
(− sin x)
⇒e =e 3 x→0− =b
SECTION-I(i)
2 2
⇒ a = ,b = e3
1. Ans ( C ) 3
T1 = sin−1 ( ) = tan−1 ( ) = tan−1 2 − tan−1 1 6. Ans ( B )
1 1
√10 3
(3π − 8) − (10 − 3π) + 4π − 12 − (9 − 2π) + 6 − π
T2 = sin ( ) = tan ( ) = tan−1 3 − tan−1 2
−1 1 1 −1 = 11π − 33
√50 7
T100 = tan−1 101 − tan−1 100 MATHEMATICS
100 50
sum = tan−1 101 − tan−1 1 = tan−1 ( ) = tan−1 ( ) SECTION-I(ii)
102 51
p + q = 50 + 51 = 101 7. Ans ( A,B,C )
xa − 2x + 1 − x + 1 xa − 3x + 2
2. Ans ( B ) b = lim
x→1 (x − 1) (xa − 2x + 1)
= lim
x→1 (x − 1) (xa + 1 − 2x)
;x = 1 + h
a
x2 (1 + h) − 3 (1 + h) + 2 (1 + ah+. . . . . .) − 3h − 1
2
+ 1 − √1 + x 2 b = lim = lim
lim h→0 h [(1 + h)a + 1 − 2 (1 + h)] h→0 h [1 + ah. . . . −1 − 2h]
x→0 (cos x − ex2 ) sin(x2 ) (a − 3) h + 2 h
a(a−1) 2

( x2 + 1) − (1 + )
2
x2 x4 = lim
−
2 8 1 h→0 (a − 2) h2 +. . . . . .
lim =−
(1 − 12 a = 3 and b = 3 ⇒ a + b = 6
x→0 x2
2
− (1 + x2 )) (x2 )

6001CJA10102124006 HS-7/9
 Target : IIT-JEE (M + A) 2025
8. Ans ( A,B,D ) 11. Ans ( A,C,D )
When x < −1, lim 2 (√25x2 + x − 5x)
x→∞
2x 1 − x2 2x
sin−1 ( ) + cos−1 ( ) + tan−1 ( )
⇒ lim 2 ( )=
1+x 2 1+x 2 1 − x2 x 1
−1 −1 −1 −1 x→∞ √25x2 + x + 5x 5
= −π − 2tan x − 2tan x + π + 2tan x = −2tan x
When −1 < x < 0, then sum of the above three 2x − 2ℓn(1 + x)
(A) lim
terms = 2tan−1 x − 2tan−1 x + 2tan−1 x = 2tan−1 x x→0 5x2
When 0 < x < 1, the sum of three terms 2 (x − (x − x2
2
+ x3
3
. . . .))
⇒ lim
= 2tan−1 x + 2tan−1 x + 2tan−1 x = 6tan−1 x x→0 5x2
When x > 1, the sum of three terms (B)
= π − 2tan−1 x + 2tan−1 x + 2tan−1 x − π = 2tan−1 x
So, a = 6, 2, −2
If we check at terminal points at x = ±1, 0 then (C)
we geta = 6, 2
9. Ans ( A,B,C )
The function in (a) is periodic with period, 1
The function in (b) is periodic with period π .The (D)
function in (c) on simplification is equal to (l /2) sin
2x, which is periodic with period π.The function in
(d) is non-periodic as g(x) = x is non-periodic. So, A, C, D are correct
10. Ans ( A,C )
Given f is continuous in [a, b] ..........(i)
12. Ans ( B,C,D )
g is continuous in [b, c] ..........(i) If a < b, then
f(b) = g(b) ..........(iii)
⎛ b + bx ⎞
a 1 x
h (x) = f (x) for x ∈ [a, b) ⎫
x
⎪
ax + 1
lim ( ) = lim
x→∞ ⎝ 2 ⎠
=0
⎬ .........(iv)
x→∞ bx + 2 1 + bx
⎭
= f (b) = g (b) for x = b
⎪ ∞
a a
<1 ∴( ) =0
= g (x) for x ∈ (b, c]
since a < b ⇒
h(x) is continuous in [a, b) ∪ (b, c] b b
∞
[Using Eqs. (i) and (ii)] If a > b, then > 1 ∴ ( ) = non-existent
a a
Also, f (b− ) = f (b) and g (b+ ) = g (b) [Using b b
a
Eqs. (i) and (ii)]........(iv) If a = b, then = 1
b
ax+1 x
ax + 1 lim ( bx+2 )
∴ h (b− ) = f (b− ) = f (b) = g (b+ ) = h (b+ ) ∴ lim( )x = e x→∞
x→∞ bx + 2
[Using Eqs.(iv) and (v)]
lim ( bx+2 )× x
−1 1
Now, verify each alternative. Of course g(b – )
1
= ex→∞ = e− b = e− a (sin ce b = a)
and f(b+) are undefined.
h (b− ) = f (b− ) = g (b) = g (b+ ) = h (b+ ) = g (b+ ) = g (b) = f (b) = f (b− )

Hence, h (b− ) = h (b+ ) = f (b) = g (b)

and h(b) undefined

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MATHEMATICS 4. Ans ( 10.00 )
α + β = −5 αβ = −49
SECTION-II
1 1
1. Ans ( 150.00 ) cot(tan−1 + tan−1 )
α β
Number of onto functions = Number of cot(cot−1 10) = 10
functions for which mapping is 5. Ans ( 10.00 )
5 5
35 − 3(2) + 3(1) f (x)
= 243 − 3 (32) + 3 = 150 Given lim =5
x→3 x − 3
lim f (x) = 0 ⇒ f (3) = 0
2. Ans ( 4.00 ) x→3

sin[π(1 − sin x)] 2 g (x) g (x)

lim = 5 ⇒ lim = 5, ⇒ g (0) = 0
lim x→f(3) x2 x→0 x2
x→0 x2
sin(πsin x)2
sin(πsin2 x) ⋅ (πsin2 x) tan 10x
lim = lim
So, lim = 10
x→g(f(3)) x
x→0 x2 x→0 x2 ⋅ (πsin2 x)
sin(πsin2 x) sin2 x 6. Ans ( 5.00 )
⎛ ⎞
= lim ⋅ (π) ⋅ =π 1 1
3 2 1 3 2 3 2
πsin2 x lim n (1 + + ) + (1 − + ) −2
x→0 x2 2
⎝ ⎠
+
n→∞ n n 2 n 3 n n 2
3. Ans ( 8.00 )
1 − cos 4x ⎡⎛ (
1 1
− 1) 2⎞
⇒ lim n ⎢
⎢⎜⎜+ (+ ) ⎟
⎟
1 2 1 3 2 1
)+ (
3 3
L.H.L ⇒ lim− 2
+ + +
⎣⎝ 3 1.2 n n3 ⎠
n→∞ 2 3
x→0 x2 n n n2
2sin2 2x 4
lim × =8
x→0− x2 4
R.H.L ⎛ (
1 1
− 1) 2⎞ ⎤
+⎜
⎜+ (+ 2 ) + ⎟ −⎥
) ⎟ ⎥
1 3 −2 3
(
2 2
+
⎝ n2 ⎠ ⎦
√x (√16 + √x + 4) 2 n 1.2 n
⇒ lim+ ×
x→0 (√16 + √x − 4) (√16 + √x + 4)
√x(√16 + √x + 4)
lim =8
x→0+ 16 + √x − 16
⇒ f(0) = R. H. L = L. H. L ⇒ a = 8
So, p = 2, q = 3 ⇒ p + q = 5

6001CJA10102124006 HS-9/9