JEE (Main + Advanced) 2025

JEE (MainNURTURE
+ Advanced) 2025
COURSE
NURTURE COURSE
RACE # 14 ORGANIC CHEMISTRY
M.M. : 26 TIME : 25 Min.
Q.1 Arrange the groups or atoms according to their priority order using CIP sequence rules ? [5]

(i) , , – CH2 – CH3, – CH = CH2, –C  CH

(ii) – COOH – COCl, – CONH2, – CHO, –COCH3

(iii) – CH2 – NH2, – CH2 – Cl, – CH2 – Br, – CH2 – CN, – CH2 – CH2 – Cl, – CH2 – OH

®
(iv) – CN, – OH, Cl, – D, – H, –SO3H, –SH, – F, Br, I, – NH2

O O O
(v) O, , ,

Q.2 Assign priority number to the following groups as per Cahn, Ingold, Prelog sequence rule [7]

(i) – CH2OH, – CH3, – CH2CH2OH, –H

(ii) – Cl, – Br, – CH = CH2, – CH3

(iii) – C – H, – OH, – CH3, – CH2OH

(iv) – CH(CH3)2, – CH2CH2Br, – Cl, – CH2CH2CH2Br

(v) – CH = O, – CH2,CH3 – CH3

CH3 CH3
(vi) – CH = CH2 – C  CH –CH – CH2
– C – CH
CH3 CH3
CH3 CH3

(vii) –CH2CH2CH2I – CH – CH – CH3 – CH – CH2CH3 –F

Br Cl

E-38/56 Organic / R#01-20 (Book)

 JEE (Main + Advanced) 2025

NURTURE COURSE

Q.3 Assign E and Z configuration to following compounds : [14]

HOH2C CH2Cl
(i) C=C Me (ii) C=C
NC CH3

CH3
F Cl
(iii) (iv) C=C
H Br

®
I
C
Me

O
O
D C–H
(v) C=C (vi) C=C
H CH2 – CH2 – OH
O

T CH2 – CD3 Cl CH = CH2

(vii) C=N (viii) C=C
D3C CD3 Br C  CH

H–C CH = CH2
C=C
(ix) C=C (x) Cl–H2C CH – CH2

CH3 CH3
OH

H Cl H3 C Et
(xi) C=C=C=C (xii) C=C=C=C
H3 C H H CH3

Organic / R#01-20 (Book) E-39/56

 JEE (Main + Advanced) 2025

NURTURE COURSE

Br F
(xiii) (xiv)
H CH3

FILL THE ANSWER HERE

1. (i) (ii) (iii)
(iv) (v)
2. (i) (ii) (iii) (iv)
(v) (vi) (vii)
3. (i) (ii) (iii) (iv) (v) (vi) (vii)
(viii) (ix) (x) (xi) (xii) (xiii) (xiv)

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