Professional Documents
Culture Documents
32181
32181
https://ebookmass.com/product/lignin-in-polymer-composites-1st-
edition-faruk/
https://ebookmass.com/product/epoxy-composites-jyotishkumar-
parameswaranpillai/
https://ebookmass.com/product/explosion-blast-response-of-
composites-mouritz/
https://ebookmass.com/product/green-composites-for-automotive-
applications-koronis/
Non-Thermal Plasma Technology for Polymeric Materials:
Applications in Composites, Nanostructured Materials,
and Biomedical Fields Thomas
https://ebookmass.com/product/non-thermal-plasma-technology-for-
polymeric-materials-applications-in-composites-nanostructured-
materials-and-biomedical-fields-thomas/
https://ebookmass.com/product/multiscale-modeling-approaches-for-
composites-1st-edition-george-chatzigeorgiou/
https://ebookmass.com/product/design-and-manufacturing-of-
structural-composites-lee-harper/
https://ebookmass.com/product/encyclopedia-of-materials-
technical-ceramics-and-glasses-3-volume-set-michael-pomeroy/
https://ebookmass.com/product/polymer-composites-for-electrical-
engineering-xingyi-huang/
ENCYCLOPEDIA OF MATERIALS:
COMPOSITES
Volume 1
ENCYCLOPEDIA OF MATERIALS:
COMPOSITES
EDITOR IN CHIEF
Dermot Brabazon
I-Form, Advanced Manufacturing Research Centre, and Advanced Processing Technology
Research Centre, School of Mechanical and Manufacturing Engineering,
Dublin City University, Dublin, Ireland
Volume 1
Section Editors
Section 1: Metal Matrix Composite Materials, Edited by Manoj Gupta
Section 2: Polymer Matrix Composite Materials, Edited by Dermot Brabazon
No part of this publication may be reproduced or transmitted in any form or by any means, electronic or mechanical, including
photocopying, recording, or any information storage and retrieval system, without permission in writing from the publisher.
Details on how to seek permission, further information about the Publisher’s permissions policies and our arrangements
with organizations such as the Copyright Clearance Center and the Copyright Licensing Agency, can be found at our website:
www.elsevier.com/permissions.
This book and the individual contributions contained in it are protected under copyright by the Publisher (other than as may be
noted herein).
Notices
Knowledge and best practice in this field are constantly changing. As new research and experience broaden our understanding,
changes in research methods, professional practices, or medical treatment may become necessary.
Practitioners and researchers may always rely on their own experience and knowledge in evaluating and using any information,
methods, compounds, or experiments described herein. In using such information or methods they should be mindful of their
own safety and the safety of others, including parties for whom they have a professional responsibility.
To the fullest extent of the law, neither the Publisher nor the authors, contributors, or editors, assume any liability for any injury
and/or damage to persons or property as a matter of products liability, negligence or otherwise, or from any use or operation of
any methods, products, instructions, or ideas contained in the material herein.
ISBN 978-0-12-819724-0
.
CONTENTS OF VOLUME 1
Contents of Volume 1 v
Preface xix
VOLUME 1
v
vi Contents of Volume 1
Metal Matrix Composites for Automotive Components in Depth Case Study: Development
of Automotive Brake Disc
Nanang Fatchurrohman and Shamsuddin Sulaiman 540
Application of Metal Matrix Composites in Non-Structural Applications
Mubarak Ali M, Mohamed Thariq, Vishwesh Dikshit, and Bhudolia S Kumar 557
xi
xii List of Contributors for Volume 1
Section Editors
Manoj Gupta, Section 1: Metal Matrix Composite Materials
Department of Mechanical Engineering, NUS, Singapore
xvii
PREFACE
This is the first Encyclopedia of Materials: Composites published by Elsevier which presents a vast and widely encompassing content in
the area of composite materials science and engineering. Composite materials have become even more important and ubiquitous
over the recent decades due to the many advantages that they can provide over single monolithic materials. This includes
improvements in the properties such as the physical, electrical, chemical, optical and magnetic properties which can be achieved by
combining two or more materials.
The two main types of composites, Metal and Polymer matrix based, are presented in detail within Sections 1 and 2 respectively
while Ceramic matrix composites are presented in Section 3. Smart composites which is an area that is growing fast with increasing
industrial relevance is covered in Section 4. Assessing the properties of composite materials thereby enabling their application is a
crucial aspect of composite materials development and usage. As such, Section 5 presents the testing methods used and property
results from the testing of composite materials. The design of composite materials is covered in Section 6. The recyclability and
sustainability of materials used in products is an ever more important topic. There are some challenges to achieve well the
recyclability of composite constructs. The Encyclopedia presented two Sections covering this one (Section 7) covering nature based
composites and another covering the life cycle analysis of composite materials (Section 8). In the last section of the Encyclopedia,
Section 9 covers how to join composite materials together and with more conventional monolithic materials.
As an Encyclopedia, these sections were prepared to be the primary central source of background knowledge for undergraduate,
postgraduate and researchers studying or working with composites. The audience of this work covers both academic and industrial
researchers. In todays’ composite materials market, engineers, architects, and even policy makers, need reference literature where to
find definitions, concepts and state-of-the-art knowledge. As such this Encyclopedia will be an invaluable reference for engineers,
architects, scientists, and policy makers.
Each section contains articles written by world experts in their area. As well as providing the latest background information, the
state of the art in the niche areas is presented in the individual articles. A particular concern in preparing these articles by the
authors and Section editors was to make the content as accessible as possible to the reader. This is important given the multi-
disciplinary nature of people working on the development and implementation of composite materials.
I take this opportunity to thank the 337 authors from across the world who have contributed the 171 articles to this
Encyclopedia. It has been enjoyable to work with you are encouraging to see your expertise, interest and desire to help others from
your contribution. With the many co-authored articles, there has been extensive collaboration which has resulted in a more
informed and well-presented Encyclopedia content for the reader.
I am indebted also to the members of the Editorial team who have worked many long hours over the last couple of years to provide
feedback and iterate on articles with the authors. The Editorial team have collectively many years of expertise working in their research
areas. This team was formed via a variety networking events including conferences such as ESAFORM and Global Conference on
Nanomaterial Forming (Manoj Gupta, Robertt Valente, Antonella Astarita), EU research projects and COST Actions (Fatima Zivic and
Eva Maria Pellicer), and via other Dublin City University and sustainable engineering networking events (Mohamed El Mansori and
Lorna Fitzsimons). I thank the Elsevier Major Reference Works team who supported in a professional manner the compiling of this
work. In particular, I thank Laura Jackson, Sajana P K, and Ruth Rhodes for their direction and support throughout the preparation of
this Encyclopedia.
Dermot Brabazon
May 2021
xix
Introduction to Metal Matrix Composite Materials: An Introduction
Manoj Gupta, National University of Singapore, Singapore
r 2021 Elsevier Inc. All rights reserved.
Introducing Composites
Composite refers to a material that is an outcome of unification of two different class of materials (Fig. 1) (Ceschini et al., 2016;
Gupta and Sharon, 2011). To note that composites were used in making bricks in prehistoric times and more importantly by
nature in providing functionality to both plants and animals including humans. The keen observations made by humans led to
development of modern composites including MMCs.
Composites can traditionally be classified using two approaches:
(1) Matrix based.
(2) Reinforcement based.
Schematics of these approaches to classify composites are shown in Figs. 2 and 3, respectively. For matrix-based classifications,
there may be other matrices such as Carbon matrix but they are more specialized types and do not come under mainstream
composites.
Based on reinforcements, the composites can be classified as (see Fig. 4):
Metal matrix composites (MMCs) represent conscious unification of metallic matrix and at least one reinforcement. The rein-
forcement can be (Ceschini et al., 2016; Gupta and Sharon, 2011; Lloyd, 1994; Ibrahim et al., 1991; Jayalakshmi and Gupta, 2015):
(1) Metallic.
(2) Ceramic (oxides, carbides, nitrides, borides).
(3) Intermetallic.
(4) Carbon based (CNT, graphene, buckyball, graphene oxide).
(5) Hollow (cenospheres, metal or ceramic based).
(6) Hybrid (combination of above and combination of length scales).
(7) Amorphous.
(8) Multicomponent alloys.
Most commonly used metallic matrices include but not limited to the following:
Parcle
Reinforced
Composites
Interconnected
Reinforcement
Based
Composites
The major (not limited to) matrix and reinforcement related factors that govern the end properties of MMCs are shown in
Figs. 10 and 11, respectively (Ceschini et al., 2016; Gupta and Sharon, 2011; Lloyd, 1994; Ibrahim et al., 1991).
As indicated in Fig. 9, MMCs can primary processed using following economically viable routes (Lloyd, 1994; Ibrahim et al., 1991):
(1) Liquid phase methods.
(2) Solid phase methods.
(3) Two phase methods.
There are other methods that are being researched but those methods are still in the developmental stages for scalable and/or
economical production. The liquid, solid and two-phase methods are listed in Figs. 12–14.
Among the liquid phase methods, the one including ultrasonic probes/transmitters are relatively new developments that have
shown promising results.
4 Introduction to Metal Matrix Composite Materials: An Introduction
Liquid Phase
Processing
Fig. 12 Most commonly used/researched methods to synthesize MMCs using liquid phase processing.
Among powder metallurgy methods, use of microwave sintering (Gupta and Leong, 2007), spark plasma sintering (Azarniya
et al., 2017), flake powder metallurgy (Xu et al., 2017), molecular level mixing (Bakshi et al., 2010) and friction stir processing
(Eskandari et al., 2016) are relatively new processes with significant potential.
Two phase methods probably were most exciting from metallurgical point of view, however, their utility in industrial
processing is limited. Disintegrated melt deposition technique is the latest process in this category with potential of scalability at a
very low equipment and infrastructural costs.
6 Introduction to Metal Matrix Composite Materials: An Introduction
Solid Phase
Processing
Fig. 13 Most commonly used/researched methods to synthesize MMCs using solid phase processing.
Two Phase
Processing
Spray
Disintegrated
Rheocasng Atomizaon and Osprey Process
Melt Deposion
Deposion
Fig. 14 Most commonly used/researched methods to synthesize MMCs using two phase processing.
Secondary
Processing
Techniques
Severe Plasc
Rolling Forging Extrusion
Deformaon
Severe Plasc
Deformaon
Techniques
Depending on the end application, at times the MMC billets are also secondary processed to further enhance their micro-
structural characteristics and properties. Common secondary processing techniques are indicated in Fig. 15.
In more recent times, efforts are continuously made to significantly enhance the properties of MMCs using severe plastic defor-
mation methods. Some of the promising methods sever plastic deformation processes used on bulk materials are listed in Fig. 16.
Like other structural materials, MMCs are used where certain enhanced functionalities from metallic materials is expected in end
applications due to the more demanding nature of emerging end applications. Most commonly investigated properties where
enhancement is expected include (Ceschini et al., 2016; Gupta and Sharon, 2011; Lloyd, 1994; Ibrahim et al., 1991):
Introduction to Metal Matrix Composite Materials: An Introduction 7
Joining Methods
Fusion Welding Fricon Sr Welding Explosive Welding Diffusion Bonding Brazing Soldering
Vacuum Brazing
Ultrasonic Assisted
A detailed analysis of these properties can be found elsewhere in this encyclopedia and will not be discussed here.
For industrial applications, joining of MMCs with MMCs or other metallic materials is required. Welding is one of the common
practice for the same. Different joining methods that have evolved and used are indicated in Fig. 17 (Ellis, 1996; Prater, 2011).
More recent development in joining of composites can be referred to in another article in this encyclopedia.
Machining is an important operation before a part is assembled into a device. Machining is done on both the cast and wrought
parts to different extents. Conventional machining processes such as turning, milling, drilling and wire cutting (EDM) are used for
machining MMCs (Lane, 1992; Gururaja et al., 2013). As traditional MMCs are reinforced with ceramic reinforcements which are
typically harder than materials used for making conventional tools (e.g. tool steels), the wear or deterioration of tools increases
faster affecting the surface characteristics of material that is machined. The problem is more severe when the micron and higher
length scale ceramic reinforcements are used as they can be loaded to a higher extent. Similarly, reduction in particle diameter also
assist in reducing tool wear and in that context, it is anticipated that nano-composites will perform better than microcomposites
(Lane, 1992). Diamond coated tools in that respect display better machining performance.
While investigating a machining process, researchers typically focus and optimize on the following parameters (Gururaja et al., 2013):
(1) Workpiece material: Nature of metallic matrix and reinforcement associated variables.
(2) Type of tool used: Polycrystalline diamond tools are most favored.
8 Introduction to Metal Matrix Composite Materials: An Introduction
Surface
Protecon
Methods
Surface
Painng Coang
Treatment
Surface
Spray Electroplang
Hardening
Electroless Anodic
Electrostac
Plang Oxidaon
Chemical
Coang
Hot Dipping
Thermal
Spraying
Metallic
Cementaon
It was emphasized by researchers that due to above mentioned factors and complexity of machining processes, detailed
optimization of the parameters is important to ensure minimal tool wear and to realize desirable surface finish. Latest and detailed
information on high performance machining of MMCs can be referred to in another article on machining in this encyclopedia in
the Metal Matrix Composites section.
Surface protection of metallic surfaces is important and MMCs are no exception. The common purposes of providing surface
protection include:
Hydroelectric
power
Sports
plants/Power
transmission lines
Transportaon
Consumer (Automobiles,
Electronics trains and
marime)
Defense
Various types under these categories are shown in Fig. 18 and discussed in details elsewhere in this Encyclopedia.
Metal matrix composites are actively been looked into many structural and non-structural applications and most prominent of
them are indicated in Fig. 19 (Ceschini et al., 2016; Gupta and Sharon, 2011; Lloyd, 1994; Ibrahim et al., 1991). Main physical,
thermal, mechanical and surface properties that are actively looked for these applications are:
Most of the abovementioned properties can be easily tailored and realized using MMC technology. Besides investigators are
looking into the possibility of using MMC technology in many other more specific applications which include and not restricted to
the following:
Active research in MMCs has almost spanned five decades and tremendous lessons are learnt on the fundamental principles
governing their microstructure and properties. Researchers have convincingly established the efficacy of many formulations at lab
scale and certain leading multinational companies have shown the capabilities to convert them into industrial products. However,
the issue of scalability to synthesize MMCs using liquid metallurgy based high volume production routes with microstructural
consistency is still a big issue for many countries for their widespread use. More involvement of industry is required to take these
highly tailorable and property specific materials to the next level.
Another random document with
no related content on Scribd:
“Now we must have white rosemary. Wilt thou not gather it for
me?” she added, as Hugh, inert and dazed, was looking at her with
that weary longing, that infinite tenderness, which always made my
heart ache for his pain. “Dost know that white rosemary spells
remembrance?”
“Rosemary for remembrance!” he repeated, as quietly he turned
and with loving care picked the humble blossom from out the crowd
of its more gorgeous sisters. He looked at it, and as the light
flickered, I could see two great tears glistening in his eyes.
“Rosemary for remembrance!”—the very words spoke of England
and of home, and brought to his weary heart probably, more strongly
than anything else could do, the thought of what he had lost.
“Rosemary for remembrance!”—we, in England, thousands of
miles away, speak of the little plant as meaning remembrance;
before me, in one moment, with those words, the gorgeousness of
mystic Kamt had disappeared, and I saw its loveliest daughter filling
the old Chestnuts with the radiance of her beauty, the melody of her
voice. She became the incarnation of womanhood, of her who alone
knows how to combine the tender friend, the wife, the mistress.
There was dead silence in the temple. Neit-akrit had taken the bunch
of rosemary and was fastening it to her posy, while Hugh watched
her silently.
Then, suddenly, from the farther end of the sacred edifice, there
where the great gateway faced directly towards the east, it seemed
to me that a dull yet rosy light began to creep gently through.
“Neit-akrit,” said Hugh, after a long while, “if thou didst wish to give
me that posy as an emblem of happiness, it was wrong to add
remembrance to it.”
“Why?”
“Because since I have smelt that sprig of rosemary my memory
has come back to me. Remembrance, like duty, is at times cold and
cruel, and her figure now stands beside that gate and points towards
the east.”
“Nay, not yet!” she pleaded; “ ’tis but the lights of the city of Tanis
gone crazy with joy.”
“Remembrance whispers, Neit-akrit, that I have plighted my troth,
and that if I stay beside thee and chase remembrance away, I break
the pledge which I gave to another.”
“Nay! the heralds of dawn have not yet sounded the trumpets.
Osiris is still well hidden behind the hills, and my nosegay is not
ready. I have no tuberose, which means passion, and no white
pansy, which means forgetfulness.”
“It is not in thy power, Neit-akrit, to put white pansy into thy bunch,
and I…”
“And thou?”
“I would not put them there if I could.”
“Then, thou hast no wish to forget?”
“Rosemary, which is for remembrance, will be my most cherished
flower. Give me that one, Neit-akrit, out of the bunch… touch it once
with thy lips and then let the poor fool go his way.”
Ill, paralysed, numbed as I was, all my hopes tended towards the
beautiful girl who alone could keep Hugh away from the terrible
danger. I longed to give her courage to tell Hugh all, yet feared every
moment that she would, and that he would not believe, that his
loyalty to his bride should not allow him to listen to terrible
accusations framed against her by another woman. The moments
were precious; already through the distant gate the light of dawn
grew stronger and more clear.
“Nay! what is the use?” she said, as she drew a step back from
him; “thou dost seem to remember all that thou dost wish—thy duty,
thy word; the white rosemary should not come from me.”
“Sweet Neit-akrit, thou art a child,” he said with almost rough
earnestness. “Thou dost not understand—how couldst thou? I am a
senseless fool.… Give me thy hands to kiss… place them both upon
my mouth… for I dare not take them in mine… lest their touch should
indeed make me forget…”
Quietly she pulled from out the canopy of flowers a bunch of white
pansies, and stretching out both her hands up to him she murmured:
“White pansies for forgetfulness!”
He had fallen on his knees, and his arms encircled her dainty
figure. She turned towards the statue of the goddess as if to beg of
the cold, immovable image inspiration and perhaps strength. Ay! she
needed all her woman’s wits; there were a hundred unseen enemies
to fight, and one whom she feared more than any—the other woman
to whom he had plighted his troth. I suppose she found it hard to say
to him, “Beware, that woman has murdered her son; she even now
has planned thy ruin.” Supposing his loyalty forbade him to listen!
Her accusations to him might sound like the words of a woman mad
with jealousy… and she thought that she could not prove them; she
did not know I, too, had seen and heard, that I was here, close by, a
caged and useless log, a dumb beast, while twenty priests—a
hundred, if need be—were ready to swear that she lied.
And I was helpless—a caged, helpless, dumb creature—and the
minutes were speeding so fast.
Suddenly from afar the sacred heralds of Osiris rang out upon
their golden trumpets the announcement of the sun-god’s approach.
In a moment Hugh had sprung to his feet, but Neit-akrit now would
not let him go; she clung to his garments, dragged at his cloak.
“Thou must not go,” she entreated. “The temple is dark and lonely
—I am frightened; for pity’s sake do not leave me!”
“Nay, sweet! thou art safe enough here… for the love of heaven
take thy dear hands from off my cloak!”
“Thou wilt not leave me?”
“I must go, sweet. Remember I have sworn! wouldst make a
coward of me?… Nay! thou hast all but succeeded… be satisfied
and let me go!”
She took her hands from off his cloak, but came up close to him
and whispered:
“See! I do not hold thee, and yet thou wilt not go… thou art free!
and yet thou wilt stay… thou hast smelt the perfume of the white
pansy, and thou wilt forget all… save that thou dost love me.…”
“Neit-akrit!”
“Nay! thou dost entreat in vain.… Sweet, I would not have thee go!
What is duty? what is the meaning of oath or pledge? Wouldst know
why I came to-night?… I came because I knew that danger doth
await thee outside this sacred temple.… I came because I knew that
thou dost love me… and I trusted that that love would make thee
forget the dawn, thy duty, thy pledged word, forget all, in order to
remain beside Neit-akrit.”
“Forget? Ay! I have forgotten but too long already. Neit-akrit, thou
speakest of danger; to me there is but one, and that is that I might
forget all—my manhood, my honour, my pledge, my word, might
forget thy innocence, and remember only that thou art fair.”
“But that is all I would have thee remember,” she whispered so
softly that her voice hardly sounded above the murmur of the flower,
which some stray current of air began gently to fan. “If I am fair it is
because Isis hath made me so in order that thou shouldst love me! I
am young, and I have waited for thee all these years because,
although I knew it not, I wished that my beauty should gladden thine
eyes. Nay! at first I longed for thy love out of sheer pride and
revenge. Dost remember the iridescent scarabæus, which should
have guarded thee from the peril of giving thy love to Neit-akrit?
Sweet! ’twas I stole the scarabæus. I would not have thee turn coldly
from me; thou hadst taken from me my crown and my throne; I
wished to steal thy heart from thee, and then to break it in wanton
cruelty, and I threw the charmed scarabæus into the lake.… Then
thou didst speak to me… I looked into thine eyes… I knew thy soul
was mine… but… I guessed even then, my sweet, that Isis had
made me doubly fair, had placed radiance over my body and my
soul, for that day I learnt… that I loved thee!”
“Neit-akrit, for pity’s sake,” he pleaded.
But her arms were round his neck, her sweet face quite close to
his, her eyes looked ardently into his own.
“I love thee!” she whispered.
“Wouldst make me mad, Neit-akrit?”
“I love thee!”
And far, very far away, the sacred heralds of Osiris rang out upon
their golden trumpets the announcement that the sun-god was
emerging behind the hills of Kamt, which hid the valley of death.
“I love thee, oh thou who art beloved of all the gods!”
Hugh had clasped her in his arms, and as I closed my burning
eyes and fell back fainting in my prison, I knew that he was safe, that
Neit-akrit had succeeded in making him forget.
CHAPTER XXVIII.
THE THREAT