Analytical Chemistry I (CHEM 236)

Tutorial problems: Chapter 9

Aqueous solutions and Chemical Equilibria

10. Calculate the solubility product constant, KSP for each of the following substances.
Given that the molar concentrations of their saturated solutions are as indicated:

(a) AgSeCN (2.0 X 10-8 M): (products are Ag+ and SeCN-)

(d) Ce(IO3)3 (1.9 X 10-3 M)

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14. What hydroxide concentration is required to:
(a) Initiate precipitation of Al3+ from 2.5 x10-2 M solution of Al2(SO4)3
(b) Lower the Al3+ concentrations in the foregoing solution to 2.0 x 10-7 M.

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15. The solubility-product constant for Ce(IO3)3 is 3.2 X 10-10 . what is the Ce3+ concentration in
a solution prepared by mixing 50.00 ml of 0.0450 M Ce3+ with 50 ml of

a) water
b) 0.0450 M IO3- ?
c) 0.250 M IO3- ?
d) 0.0500 M IO3- ?

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 17) The solubility products for a series of iodides are
CuI Ksp = 1 x 10-12
AgI Ksp = 8.3 x 10-17
PbI2 Ksp = 7.1 x 10-9
BiI3 Ksp = 8.2 x 10-19

List these four compounds in order of decreasing molar solubility in:

a) water
b) 0.20 M NaI
c) 0.020 M solution of the solute cation

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 20. At 25oC, what are the molar concentration H3O+ and OH- concentration in
a) 0.0300 M C6H5COOH?
b) 0.0600 M NH3?
c) 0.100 M ethylamine?
d) 0.200 M trimethylamine?
e) 0.200 M C6H5COONa (sodium benzoate)?
f) 0.0860 M CH3CH2COONa?
g) 0.250 M hydroxylamine hydrochloride?
h) 0.0250 M ethyl ammonium chloride?

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21. At 25OC, what is the hydronium ion concentration in

a) 0.200 M Chloroacetic acid?

c) 0.200 M methylamine?
f) 0.300 M HIO3 ?

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