AL/2022/02-S-IIA/B -1-

úNd. fmryqre mÍlaIK -2022

II
II Three hours
II

Total Marks
ku - '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
úNd. wxlh - '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
mdi, - '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
m%Yak m;% mx;shg muKla iyNd.S fõ kï yßhla () fhdod olajkak' -

m%Yak wxlh 1 2 3 4 5 6 7 8 9 10 tl;=j

,enQ ,l=K

I m;%h II m;%h tl;=j W;a;r m;% mÍlaIl

id¾j;% jdhq ksh;h R = 8.314 J K-1 mol-1 wej.dâfrda ksh;h NA = 6.022 x 1023 mol-1
ma,dkalaf.a ksh;h h = 6.626 x 10-34 J s wdf,dalfha m%fõ.h C = 3 x 108 m s-1
A fldgi - jHqy.; rpkd
m%Yak y;rg u fuu m;%fhau ms<s;=re imhkak' ^tla tla m%Yakh i`oyd kshñ; ,l=Kq m%udKh 10 ls&
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1. (a) A, B, C, D, E, F, G, H hkq wdj¾;s;d j.=fõ wkqhd; uQ,øjH 8 ls' ldur WIaK;ajfha § A jdhqjls'
my; olajd we;af;a tajdfha m<uq whkSlrK Yla;s m%ia;drfha úp,khls' ta weiqßka my; (i) isg (x)
olajd m%Yak i|yd ms<s;=re imhkak' ^§ we;s ixfla; iïu; ixfla; fkdfõ'&
whkSlrK Yla;sh

uQ,øjH
A B C D E F G H

(i) A, B, C, D, E, F, G, H wh;ajk ldKav y÷kd.kak'

A = ''''''''''''''''''' B = ''''''''''''''''''' C = '''''''''''''''''''
D = ''''''''''''''''''' E = ''''''''''''''''''' F = '''''''''''''''''''
G = ''''''''''''''''''' H = '''''''''''''''''''
(ii) I. mrudKql wrh by<u uQ,øjH l=ula o@ ''''''''''''''''''''''''''''''''''''''''''''''
II. úoHq;a RK;djh by<u uQ,øjH l=ula o@ ''''''''''''''''''''''''''''''''''''''''''''''
III. m%;sl%shdYS,S;dj wju uQ,øjH l=ula o@ ''''''''''''''''''''''''''''''''''''''''''''''

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B -2-

(iii) by< ±ä njlska hq;= iumrudKql iyixhqc ±,sila idok wf,dayuh uQ,øjH
l=ula o@ '''''''''''''''''''''''''''''''''
(iv) WNh.=kS ,laIK fmkakqï lrk uQ,øjHh l=ula o@ '''''''''''''''''''''''''''''''''
(v) jvd;au mq¿,a TlaislrK wjia:d mrdihla fmkakqï lrk uQ,øjHh l=ula o@ '''''''''''''''''''''''''''''''''
(vi) whksl ,CIK jeäu whksl nkaOkh we;sjkafka l=uk mrudKq hq., w;r o@ '''''''''''''''''''''''''''''''''
(vii) m%n,u Tlaisydrlh f,i ie,flk uQ,øjHh l=ula o@ '''''''''''''''''''''''''''''''''
(viii) tla tla uQ,øjH j, fojk whkSlrK Yla;s úp,kh by; m%ia;drfhau we`o fmkajkak'
^ ,l+Kq 3'0 hs &
(b) (i) Thalimide whkfha ldfndks,a ldKav folla wvx.= fõ' tys iels,a, my; oelafõ' fuu whkh
i|yd jvd;au ms<s.; yels ¨úia jHqy w¢kak'
O3
C1
N5
C2
O4

(ii) fuu whkh i|yd iïm%hqla; jHqy 3 la w¢kak'

(iii) by; (i) ys w¢k ,o ¨úia jHqyh mokï lrf.k my; j.=j mqrjkak'

C1 C2 O3 O4 N5
I. bf,lafg%dak hq., cHdñ;sh
II. yevh
III. uqyqïlrKh
IV. TlaislrK wxlh
V. nkaOk fldaKh

(iv) by; (i) ys w¢k ,o ¨úia jHqyh i,ld my; olajd we;s nkaOk iE§u i|yd iyNd.s jk
mrudKql $ uqyqï ldlaIsl y÷kd.kak'
I. C1  N5 C 1 '''''''''''''''''''''''''''''' N5 ''''''''''''''''''''''''''''''
II. C2  O4 C 2 '''''''''''''''''''''''''''''' O4 ''''''''''''''''''''''''''''''
III. C1  O3 C 1 '''''''''''''''''''''''''''''' O3 ''''''''''''''''''''''''''''''
^ ,l+Kq 4'0 hs &

(c) my; i|yka m%ldY i;H o ke;fyd;a wi;H o hk nj i|yka lrkak'

(i) N j, bf,lafg%dak ,nd .ekSfï Yla;sh Ok w.hla fõ' ''''''''''''''''''''''''
(ii) yhsv%ckaj, mrudKql j¾Kdj,sfha" fok ,o fY%aKshl wkqhd; f¾Ld
folla w;r we;s mr;rh ;rx. wdhdu wvqjk foig l%ufhka wvq fõ' ''''''''''''''''''''''''

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B -3-

(iii) tlu m%fõ.fhka .uka lrk úg  wxY=jla yd iïnkaO ù fn%da.a,s ;rx.

wdhduh  wxY=jl ã fn%da.a,s ;rx. wdhduhg jvd l=vd fõ' ''''''''''''''''''''''''
(iv) 3d uQ,øjHhkays >k;ajh 3s uQ,øjHhkays >K;ajhg jvd b;d by< fõ' ''''''''''''''''''''''''
(v) fojk ldKavfha my<g tajdfha ia:dhs legdhkj, ic,k tka;e,amsh jeä fõ' ''''''''''''''''''''''''
(vi) CH2Cl2 j,g jvd CHCl3 j, O%eùh;djh jeäh' ''''''''''''''''''''''''
(vii) AX4 wKqfõ oaúO%ej >Q¾Kh Y=kH kï tys yevh ksh; jYfhkau p;=ia;,Sh fõ' ''''''''''''''''''''''''
(viii) 0.1 mol dm-3 NaOH c,Sh ødjKhlg Zn l=vq tl;= l< úg pH w.h wvq fõ' ''''''''''''''''''''''''
(ix) CH3COOH j,g jvd CH3COONa j, ;dmdxlh by<h' ''''''''''''''''''''''''
(x) Na2CO3 úfhdackh fkdjQj o MgCO3 úfhdackh jkafka Na+ j,g jvd Mg2+ j,
O%ejKYS,;djh by< neúks' ''''''''''''''''''''''''
^ ,l=Kq 3'0 hs &
2. (a) X iy Y hkq mrudKql l%udxlh 18 g jvd wvq wdj¾;s;d j.=fõ wdj¾; foll uQ,øjH folls' X iy
Y foflysu nyqrEm wdldr mj;S' X ys nyqrEmS wdldr ldur WIaK;ajfha§ jdhq f,i mj;sk w;r Y ys
nyqrEmS wdldr ldur WIaK;ajfha § >k ;;a;ajfha mj;S' Y c,fha wødjH jk w;r iajNdjfha ksê
jYfhka mj;S' X, yhsv%cka iu. idok ixfhda. folla we;s w;r tajd ldur WIaK;ajfha§ øj f,i
mj;S' Y, yhsv%cka iu. idok ixfhda.h ldur WIaK;ajfha§ jdhqjls' X iu. Y m%;sl%shd ù ldur
WIaK;ajfha§ jdhquh wjia:dfõ we;s ixfhda. folla idohs'
(i) X iy Y i|yd ;sìh yels uQ,øjHh $ uQ,øjH y÷kd.kak'
X - ''''''''''''''''''''''''''''''''
Y - ''''''''''''''''''''''''''''''''
(ii) X iy Y ys nyqrEmS wdldr kï lrkak'
X - ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
Y - ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(iii) Y, yhsv%cka iu. idok ixfhda. i|yd ;sìh yels ridhksl iQ;% ,shkak'
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(iv) X, yhsv%cka iu. idok ixfhda. i|yd ;sìh yels iQ;% ,shkak'
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(v) X iu. Y m%;sl%shd ù idok ixfhda. i|yd ;sìh yels iQ;% ,shkak' tajdfha wdï,sl" NdIañl" WodiSk
fyda WNh.=KS iajNdjh o ta wi,u ,shkak'
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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(vi) Y, yhsv%cka iu. idok ixfhda.h c,fha øjKh jk w;r ,efnk ødjKh ÿn, wdï,sl .=K
fmkajhs kï Y ksjerÈj y÷kd.kak'
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(vii) ixfhda.j,§ X yd Y fmkajk TlaislrK wjia:d WodyrK iu. i|yka lrkak'
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(viii) Y ys Wmßu TlaislrK wjia:dfjka jHq;amkak jk Tlais wï,fha idkaø ødjKhla Y iu. olajk
m%;sl%shdj i|yd ;=,s; iólrKh ,shkak'
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(ix) X, yhsv%cka iu. wvq TlaislrK wjia:dfjka idok ixfhda.fha my; i|yka .=K fmkaùu i|yd
;=,s; ridhksl m%;sl%shdj ne.ska ,shkak'

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B -4-

I. wï,hla f,i
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
II. NIauhla f,i
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
III. Tlaisldrlhla f,i
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
IV. Tlaisydrlhla f,i
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(x) Y, yhsv%cka iu. idok ixfhda.fha my; i|yka .=K fmkaùu i|yd ;=,s; ridhksl m%;sl%shdj
ne.ska ,shkak'
I. Tlaisldrlhla f,i
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
II. Tlaisydrlhla f,i
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
^ ,l+Kq 4'0 hs &
(b) P isg T olajd f,an,a lr we;s mÍCId k<j, (NH4)2Cr2O7(s) , BaCl2(aq) , NaHCO3(s) , K2SO3(aq) yd
MgS2O3(aq) hk ødjK wvx.= fõ' ^ms<sfj<ska fkdfõ'& fuu tla tla ixfhda.j,ska fjkalrk ,o
fldgiaj,g isÿ lrk ,o mÍlaIK yd ksÍlaIK my; j.=fõ § we;'

ixfhda.h mÍlaIKh ksÍlaIKh

P ;kql MgSO4 c,Sh ødjKhla ødjK ñY% lsÍfï§ meyeÈ,s ødjKhla
tla lr miqj ødjKh kgjk ,§' iEfok w;r keg jQ úg iqÿ wjlafIamhla iEfoa'
Q c,Sh ødjKhg ;kql HCl tla wj¾K ødjKhla ,efnk w;r wj¾K lgql
lrk ,§' .kaOhla we;s jdhqjla msg fõ'
msgjk jdhqjg H+ / K2Cr2O7 fmryka lvodish fld< meye úh'
fmÕ jQ fmryka lvodishla
w,a,k ,§'
R >k ixfhda.h f.k ;Èka r;a fld< wjlafIamhla ,o w;r wj¾K jdhqjla
lrk ,§' msg úh'
S K2CrO4 c,Sh ødjKhla tla lrk ly wjlafIamhla ,enqKs'
,§'
T ;kql HCl ødjKhla tla lrk ødjKfha wdú,;djhla olakg ,enqKq w;r lgql
,§' .kaOhla we;s úh'

(i) P, Q, R, S, T hk ixfhda. y÷kd.kak'

P - '''''''''''''''''''''''''''''''''''''''''''''' S - ''''''''''''''''''''''''''''''''''''''''''''''
Q - '''''''''''''''''''''''''''''''''''''''''''''' T - ''''''''''''''''''''''''''''''''''''''''''''''
R - ''''''''''''''''''''''''''''''''''''''''''''''
(ii) by; i|yka wjlafIam idok ish¨u m%;sl%shd i|yd ;=,s; ridhksl iólrK ,shkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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(iii) Q iy T olajk m%;sl%shd i|yd ;=,s; ridhksl iólrK ,shkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
^ ,l=Kq 3'0 hs &

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B -5-

(c) A, B, C, D yd E hkq fidaähï ,jKj, >k ixfhda. myls' ridhkslj fjkalr y÷kd.ekSu i|yd isÿ
lrk ,o mÍCIK yd ksÍCIK my; j.=fõ olajd we;'

mÍCIK ksÍCIK
A ;kql HCl tl;= lsÍu ^ÿUqre jdhqjla (F) msgúh'
B c,Sh ødjKhg AgNO3(aq) tla lsÍu iqÿ wjlafIamhla (G) iE§ miqj th l¿ mdg (H) úh'
C c,Sh ødjKhg BaCl2(aq) tl;= lsÍu ,d ly mdg wjlafIamla (I) iEÿKs'
D c,Sh ødjKhgCuSO4(aq) tl;= lsÍu l¿ mdg wjlafIamhla (J) iEÿKs'
E c,Sh ødjKhg Cl2 / CCl4 tl;= lsÍu CCl4 ia:rh ;eô,smdg (K) úh'

(i) A, B, C, D yd E y÷kd.kak'
A = ''''''''''''''''''''''''''''''''' B = ''''''''''''''''''''''''''''''''' C = '''''''''''''''''''''''''''''''''
D = ''''''''''''''''''''''''''''''''' E = '''''''''''''''''''''''''''''''''
(ii) ksÍCIKj,g fya;=jk F, G, H, I, J yd K ixfhda. y÷kd.kak'
F = ''''''''''''''''''''''''''''''''' G = ''''''''''''''''''''''''''''''''' H = '''''''''''''''''''''''''''''''''
I = ''''''''''''''''''''''''''''''''' J = ''''''''''''''''''''''''''''''''' K = '''''''''''''''''''''''''''''''''
(iii) by; mÍCIK j, ksÍlaIKj,g wod, ;=,s; ridhksl iólrKh ,shkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
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(ii) tuÕska 27 0C § by; moaO;sh i|yd Kp .Kkh lrkak'

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(iii) I' WIaK;ajh 100 0C olajd by< kexjqjfyd;a m%;sls%hdj iajxisoaO fõ oehs .Kkh lsÍfuka
fmkajkak'
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B -8-

''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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II' by; I ys .Kkfha § Tn Ndú;d l< Wml,amk i|yka lrkak'
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(iv) I' fu;fkdhsla wï,fha ú,hkfha tka;e,ams úm¾hdih 12 kJ mol-1 fõ' tys øjdxlh 7 0C kï
my; m%;sls%hdj i|yd S0 .Kkh lrkak'
HCOOH(l)  HCOOH(s)
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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II' S0 ys ,l=K" isÿjk m%;sls%hdj yd tlÕ fõ oehs fya;= iys;j i|yka lrkak'
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^ ,l=Kq 5'0 hs &
4. (a) A yd B hkq wKql iQ;%h C5H8 jk ixfhda.hl iudjhúl folls' A, Na f,dayh iy NH3 iu. m%;sl%shd
fkdlrhs' A yd B hk folu ;' H2SO4 / HgSO4 iu. m%;sl%shdfjka C keue;s tlu ldnksl M,hla
iEÈh yel' C ixfhda.h we,afldfyd,Sh NaBH4 yuqfõ§ D keue;s tlu ixfhda.h idohs' D ;%sudK
iudjhúl fmkajhs' Na / NH3 iu. B m%;sl%shdfjka idok E M,h C iu. m%;sl%shd lrjd H+ / H2O fh¥
úg F idohs' F ixfhda.h Na f,dayh iu. wj¾K jdhqjla msg lrhs'
(i) A yd B ys jHqy w¢kak'

A B
(ii) C, D, E yd F ys jHqy w¢kak'

C D

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B -9-

E F
(iii) D i|yd ;sìh yels ;%sudK iudjhúl jHqy ,shkak'

(iv) C yd D fjkalr y÷kd .ekSug ridhksl mÍCIdjla ,shkak'

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^ ,l+Kq 4'0 hs &

(b) my; § we;s m%;sl%shdj, G, H I, J, K M, N, O iy P hk m%;sldrl $ W;afm%Arl iqÿiq ;;a;aj wef;d;a tajd
iu`. bÈßfhka we;s fldgqj ;=< ,shd olajkak'

G
(i) CH3 - CH = CH2 CH3 - CH2 - CH2 Br

H
(ii) C6H5N2+Cl C6H 5I
O
I
(iii) CH3 - C  C - H CH3 - C - CH3
O
J
(iv) CH3 - C - CH2 - COOH CH3 - CH(OH)-CH2-(OH)
CH 3 CH 3 O
K
(v) CH - CH - CH2(OH) CH3 - CH - C - H

L
(vi) CH3 - C  C - H CH3 - CH = CH2

M
(vii) C 6H 5COOH C 6H5COBr
O
N
(viii) CH3 - CH2 - C - CH3 CH3 - CH2 - CH2 - CH3
O
O
(ix) CH3 - CH2 - C - NH2 CH3 - CH2 - CH2 - NH2

P
(x) CH3 - CH2 - CH2 - NH2 CH3 - CH2 - CH2 - OH

^ ,l+Kq 3'0 hs &

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B - 10 -

(c) CH3CH2CH2Cl iy uOHidÍh KOH w;r m%;sl%shdj i,lkak'

(i) by; m%;sl%shdfõ§ ,efnk m%Odk M,h ,shd olajkak'

(ii) by; m%;sl%shdj i|yd hdka;%Kh ,shd olajkak'

^ ,l+Kq 3'0 hs &

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B fldgi - rpkd
m%Yak follg ms<s;=re imhkak' ^tla tla m%Yakh i`oyd kshñ; ,l=Kq m%udKh 15 ls&
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5. (a) (i) c,fha § Mn+(aq) iy Nm-(aq) whk ,ndfok b;d iq¿ jYfhka ødjh MmNn(s) hk ixfhda.fha
ødjH;d .=Ks;h i|yd m%ldYkhla ,shkak'
(ii) 25 0C § Bi2S3(s) ixfhda.fha ødjH;djh 1.60 × 10-20 nj fidhd.kakd ,§' tu WIaK;ajfha§ Bi2S3(s)
ixfhda.fha ødjH;d .=Ks;h .Kkh lrkak'
(iii) tu WIaK;ajfha§u 0.01 mol dm-3 Na2S ødjKhla ;=< Bi2S3(s) ys ødjH;djh .Kkh lrkak' fuu
.Kkh lsÍfï§ Tn úiska Ndú; l< Wml,amkhla wef;d;a meyeÈ,sj ,shd olajkak'
(iv) tla;rd c,Sh ødjKhl Bi3+ whk idkaøKh 0.01 mol dm-3 jk w;r Cu2+ whk idkaøKh 0.04 mol
dm-3 fõ' fuu ødjKfhka 1 dm3 lg Na2S >kh 0.01 mol lska iaj,amh ne.ska osh lrkq ,efí' l=ula
m%:ufhka wjlafIam fõ±hs .Kkh lrkak'
wod< WIaK;ajfha§" Bi2S3(s) ys Ksp = 1 × 10-97 mol5 dm-15
CuS ys Ksp = 4 × 10-36 mol2 dm-6
(v) by; Bi2S3(s) yd CuS(s) hk ixfhda.j,ska fojk ixfhda.h wjlafIam ùug wdrïN jk fudfydf;a§
ødjKfha we;s Bi3+ yd Cu2+ whk idkaøK wkqmd;h .Kkh lrkak'
^ ,l+Kq 5'0 hs &

(b) 25 0C § I-(aq) + I2(aq) I3-(aq) hk iu;=,s;h ms<sn|j l< wOHhkhl§ whãka ldnkafgg%dlaf,darhsâ
iy 0.1 mol dm-3 c,Sh fmdgEishï whvhsâ ødjKhla ;=< jHdma; ù iu;=,s; ùug bv yßk ,§' 25 0C
§ CCl4 iy H2O w;r whãkays jHdma;s ix.=Klh 80 fõ' ldnksl ia:rfhka 5.00 cm3 la fjkalr f.k
th 0.1 mol dm-3 Na2S2O3 ødjKhla u.ska wkqudmkh l< úg wka; ,CIHfha§ ìhqfrÜgq mdGdxlh
10.0 cm3 la úh' c,Sh ia:rfhka 25.00 cm3 la fjka lr f.k th o by; Na2S2O3 ødjKfhka wkqudmkh
l< úg wka; ,CIHfha§ ìhqfrÜgq mdGdxlh 10.0 cm3 la úh'
(i) c, ia:rfha we;s ksoyia I2 idkaøKh fidhkak'
(ii) c, ia:rfha we;s I2 idkaøKh fidhkak'
(iii) I-(aq) + I2(aq) I3-(aq) iu;=,s;h i|yd iu;=,s;;d ksh;h .Kkh lrkak'
^ ,l+Kq 5'0 hs &

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B - 11 -

(c) (i) my; ±lafjk tla tla m%ldYhg wod< l%shdj,s i|yd ;=,s; ridhksl iólrK ,shkak
Tlaiscka ys iïu; ;=lrK tka;e,amsh 299 kJ mol-1 fõ'
Tlaiscka ys iïu; m<uqjk bf,lafg%dak ,nd .ekSfï Yla;sh -149 kJ mol-1 fõ'
Tlaiscka ys iïu; fojk bf,lafg%dak ,nd .ekSfï Yla;sh 798 kJ mol-1 fõ'
Mg(s) ys iïu; ;=lrK tka;e,amsh 148 kJ mol-1 fõ'
Mg(s) ys iïu; m<uqjk whkSlrK Yla;sh 738 kJ mol-1 fõ'
Mg(s) ys iïu; fojk whkSlrK Yla;sh 1451 kJ mol-1 fõ'
MgO(s) ys iïu; ±,si Yla;sh -3791 kJ mol-1 fõ'
(ii) by; oS we;s ;dmridhksl o;a; Ndú; lrñka" 25 0C §
2 Mg(s) + O2(g)  2MgO(s)
m%;sl%shdj i|yd tka;e,ams fjki .Kkh lrkak'
^ ,l+Kq 5'0 hs &
6. (a) H u.ska wdï,sl udOHfha § BrO3 whk c,Sh Br whk iu. m%;sl%shdlr Br2 ksmojhs' fuu
+ - -

m%;sl%shdfõ pd,lh wOHhkh i|yd YsIHfhla mÍlaIK fufyhjhs'

(i) by; m%;sl%shdj i|yd ;=,s; iólrKh ,shd olajkak'
(ii) BrO3-(aq) whk idkaøKhg tfrys m%;sl%shdfõ wdrïNl YS>%;dj m%ia;dr.; l< úg my; mßÈ fõ'

wdrïNl iS>%;dj
(mol dm-3 s-1)

[BrO3-] (mol dm-3)

tfiau [BrO3-(aq)] ksh;j ;ndf.k [Br-(aq)] yd [H+(aq)] fjkia lrñka isÿ lrk ,o ;j;a
mÍlaIK lsysmhl f;dr;=re my; j.=fõ ±lafõ'
[BrO3-(aq)] [Br-(aq)] [H+(aq)] wdrïNl YS>%;dj
mol dm-3 mol dm-3 mol dm-3 mol dm-3 s-1
^1& 5.0 × 10-2 1.5 × 10-1 3.0 × 10-1 1.20 × 10-5
^2& 5.0 × 10-2 1.5 × 10-1 6.0 × 10-1 1.20 × 10-5
^3& 5.0 × 10-2 4.5 × 10-1 3.0 × 10-1 3.60 × 10-5

I. H+ , Br- yd BrO3- g idfmalaIj m%;sl%shdfõ fm< ks¾Kh lrkak'

II. m%;sl%shdfõ uq¿ fm< l=ula o@
III. by; ,enQ m%;sM, weiqfrka fõ. iólrKh f.dvk.kak'
IV. m%;sl%shdfõ fõ. ksh;h .Kkh lrkak'
^ ,l+Kq 4'0 hs'&
(b) ² WIaK;ajh 400 K iy mSvkh 3.0 × 10 Nm ys§
5 -2
A jdhqj" mßudj 2.0 m jk oDV jdhq n,anhl we;'
3

² WIaK;ajh 400 K iy mSvkh 4.0 × 105 Nm-2 ys§ B jdhqj" mßudj 3.0 m3 jk oDV jdhq n,anhl we;'
² WIaK;ajh 500 K iy mSvkh 6.0 × 105 Nm-2 ys§ C jdhqj" mßudj 5.0 m3 jk oDV jdhq n,anhl we;'
A, B iy C hk jdhq tlsfkl ñY% ùfï§ lsisÿ m%;sl%shdjla isÿ fkdfõ'

A b B
a c

(i) a iy b lrdu fol újD; lrñka A iy B jdhq folu iïmQ¾Kfhkau ñY% ùug bv fokq ,efí'
iïnkaê; lrduj, mßudj fkdi,ld yßñka A yd B jdhqj, wdxYsl mSvk .Kkh lrkak'
(ii) C lrduh o újD; lrñka A, B iy C hk jdhq ;=kgu iïmQ¾Kfhka u ñY% ùug bvfokq ,efí'
bkamiq uq¿ moaO;sfha WIaK;ajh 500 K j,g f.k wd miq tla tla jdhqfõ wdxYsl mSvk .Kkh lrkak'

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
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(iii) lrdu ;=ku újD; lsÍfuka miq moaO;sfha WIaK;ajh 300 K olajd wvq l< miq moaO;sfha uq¿ mSvkh
.Kkh lrkak'
(iv) A, B yd C jdhq tlsfkl ñY% ùfï§ lsisÿ m%;sl%shdjla isÿ fkdjk nj uQ,slj Wml,amkh lr we;'
fï yer by; .Kkh lsÍïj,§ Tn isÿ lrk ;j;a Wml,amk folla meyeÈ,sj ,shd olajkak'
^ ,l+Kq 5'0 hs &
(c) weks,Ska my; ±lafjk wkaoug c,h iu. m%;sl%shd fõ'
C6H5NH2(aq) + H2O(l) C6H5N+H3(aq) + OH-(aq)
25 0C § 0.180 mol dm-3 weks,Ska ødjKhl wvx.= OH-(aq) idkaøKh 8.8 × 10-6 mol dm-3 fõ'
(i) by; m%;sl%shdfõ iu;,s;;d ksh;h" Kb i|yd m%ldYkhla ,shkak'
(ii) 25 0C § C6H5NH2 ys ú>gk ksh;h" Kb .Kkh lrkak'
(iii) 25 0C § C6H5NH2 ys ú>gk m%;sY;h .Kkh lrkak'
(iv) C6H5NH2(aq) + H3O+(aq) C6H5N+H3(aq) + H2O(l) hk m%;sl%shdj i|yd iu;=,s;;d ksh;h
fidhkak'
(v) pH w.h 7.75 jk ødjKhla ,nd .ekSu i|yd ;sìh hq;="
I. [C6H5N+H3(aq)] / [C6H5NH2(aq)] hk wkqmd;h fidhkak'
II. fï wkqmd;h mj;ajd .ekSu i|yd 0.180 mol dm-3 C6H5NH2 ødjKhl 250 cm3 lg tla l<
hq;= 0.050 mol dm-3 HCl mßudj ljf¾ o@
^ ,l+Kq 6'0 hs &
7. (a) iïu; wjia:dfõ we;s my; úoHq;a ridhksl fldaIh i,lkak'

Zn Pt

1.0 mol dm-3 1.0 mol dm-3

ZnCl2(aq) ne.ska jQ
,jK fia;=j Fe2+(aq) , Fe3+(aq)
by; fldaIfha we;s bf,lafg%dav fol lïìhlska iïnkaO l< úg úoHq;a Odrdjla .,d hhs'
EZn(s) / Zn3+(aq) = -0.76 V | EFe3+(s) / Fe2+(aq) = +0.77 V | 1 F = 96500 C mol-1
tu fldaIfha"
(i) wefkdav yd lef;dav m%;sl%shd ,shkak'
(ii) fldaI m%;sl%shdj ,shkak'
(iii) iïuq;sl fldaI wxlkh ,shd olajkak'
(iv) Odrdj fkd.,k úg fldaIfha úoHq;a .dul n,h fidhkak'
(v) by; fldaIfha
I. Zn2+(aq) idkaøKh jeä lsÍu
II. Fe3+(aq) idkaøKh jeä lsÍu
III. wefkdav ødjKhg wdi%e; c,h tla lsßu
fldaIfha úoHq;a .dul n,h flfrys n,mdk wkaou myokak'
(vi) by; fldaIfhka 2A Odrdjla úkdä 40 l ld,hla ;=< ,nd.kakd ,§' bka miq Pt / Fe2+ , Fe3+ w¾O
fldaIfha wvx.= ødjKfhka 100 cm3 la f.k th idkaøKh 0.8 mol dm-3 jk KMnO4 ødjKhla
u.ska wkqudmkh lrk ,§' w¾O fldaI foflysu wdrïNl mßudj 200.0 cm3 ne.ska fõ' wdrïNfha
§ Fe2+ yd Fe3+ whkj, idkaøKh 1.0 mol dm-3 ne.ska jk nj i,lñka jehjk KMnO4 mßudj
fidhkak'
^ ,l+Kq 5'0 hs &
(b) A iy B jdIamYS,S øj 2 ñY% l< úg mßmQ¾K ødjKhla idohs' fuu ñY%Kh tys jdIamh iu. iu;=,s;;djhla
we;slr .kS' A yd B f.a ix;Dma; jdIam mSvk P0A iy P0B o jdIam l,dmfha A iy B j, ujq, Nd.
ms<sfj<ska X1A iy X1B o jdIamfha uq¿ mSvkh P o fõ'
1 1 - X 1A X 1A
(i) = + nj fmkajkak'
P P 0B P0
A

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(ii) P0A iy P0B ms<sfj<ska 3 × 104 Pa yd 2 × 104 Pa o jdIamfha B j, ujq, Nd.h 0'6 la o kï jdIamfha
uq¿ mSvkh .Kkh lrkak'
(iii) jdIamfha A iy B j, wdxYsl mSvk .Kkh lrkak'
(iv) ixhq;sh iu. jdIam mSvk úp,kh iy ;dmdxl úp,kh fjk fjku o< m%ia;dr .; lr kï
lrkak'
^ ,l+Kq 5'0 hs &
(c) A iy B hkq wIaG;,Sh cHdñ;shla we;s ixlS¾K whk wvx.= ix.; ixfhda. folls' tajdfhys wvx.=
ixlS¾K whkfha fmdÿ mrudKql ixhq;sh FeC4N3O5 fõ' tla tla ixlS¾K whkfha ,shk j¾. 3 ne.ska
we;' A iy B c,Sh ødjK fjk fjku AgNO3 ødjKhla iu. msßhï l< úg ;kql NH3 ys Èhjk iqÿ
meye;s E wjlafIamhla ,nd foa' tys§ A ixfhda.fha 1 mol u.ka E 2 mol ,ndfoa' B ixfhda.fha 1 mol u.ska
E, 1 mol ,nd foa' A ys wvx.= ixlS¾K whkh C o" B ys wvx.= ixlS¾K whkh D o fõ' C yd D folgu
wIaG;,Sh cHdñ;shla we;'
(i) A, B ix.; ixfhda. y÷kd.kak'
(ii) C, D ixlS¾K whk y÷kd.kak'
(iii) E wjlafIamh ;kql NH3 ;=< Èhùug wod< ;=,s; ridhksl iñlrKh ,ndfokak'
(iv) C yd D ys Fe j, bf,lafg%dak úkHdihka ,shkak'
(v) A yd B IUPAC kï ,shkak'
^ ,l+Kq 5'0 hs &
----------------------------------------------------------------------------------------------------------------------------------------
C fldgi - rpkd
m%Yak follg ms<s;=re imhkak' ^tla tla m%Yakh i`oyd kshñ; ,l=Kq m%udKh 15 ls&
----------------------------------------------------------------------------------------------------------------------------------------
8. (a) A, B, C yd D hkq wKql iQ;%h C4H11N jk we,s*eál weók 4 ls' fï w;=ßka"
* A muKla m%ldY iudjhúl;dj olajhs'
* NaNO2 / ;kql HCl iu. m%;sl%shd lr A yd B u.ska N2 msglrk w;r" C u.ska ly meye;s
f;,la iEfoa' D by; ksÍCIK foflka tllaj;a ,nd fkdfoa'
* by; m%;sl%shdfõ§ B j,ska ,efnk ldnksl M,h ks¾c,Sh ZnCl2 / id' HCl iu. CIKsl
wdú,;djhla foa'
(i) A, B , C yd D ixfhda.j, jHqy olajkak'
-
(ii) CH3CH2Cl iuÕ by; C ixfhda.h m%;sl%shd lsÍfuka (CH3CH2)4N+Cl idohs kï" fuu m%;sl%shdjg
m<uq mshjr i|yd iqÿiq hdka;%Kh meyeÈ,sj olajkak'
^ ,l+Kq 4'0 hs' &
(b) ,ehsia;=fõ § we;s ridhksl øjH muKla Ndú;lr Tn my; i|yka mßj¾;kh isÿ lrkafka flfia±hs
fmkajkak'
O CH 3
CH2=CHCH2Br CH3COCHCH2CH3

ridhksl øjH ,ehsia;=j

HBr , C2H5OH / KOH , NaNH2 , CH3Br , H2 / BaSO4 / Pd laúfkda,Ska" CH3COOH , idkaø H2SO4 , H2O
^ ,l+Kq 5'0 hs' &

(c) my; olajd we;s m%;sl%shd wkqms<sfj< fol [i iy ii] i,ld P, Q, R, S iy T hk M,j, jHqy w¢kak'
COOH H3O+ / KMnO4
NaBH 4 Q
P
(i)
COCH 3

NaNH 2 1. CH3COH HgSO4 / ;' H2SO4

(ii) CH3CCH R S T
2. HCl
^ ,l=Kq 3'0 hs &

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
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(d) my; § we;s m%;sl%shdfõ i,lkak'

C6H5 CH2I + CH3CH2NH2 
(i) iefok m%Odk m%;sM,h l=ula o@
(ii) m%;sl%shdj i|yd hdka;%Khla fhdackd lrkak'
(iii) fuu m%;sls%hdj l=uk j¾.fha m%;sl%shdjla o@
^ ,l+Kq 3'0 hs &

9. (a) I. S hk c,Sh ødjKh 3d f,day ;=kl legdhk ;=klska iy wekdhk follska iukaú; fõ' tu
ødjKfha wvx.= whk y÷kd .ekSu i|yd isÿ l< mÍCIK yd tajdfha ksÍlaIK my; ±lafõ'

mÍCIKh ksÍCIKh
^1& S ødjKhg jeämqr ;kql NaOH tl;= j¾Kj;a wjlafIamhla (A) yd j¾Kj;a ødjKhla
lrk ,§' (B) ,efí'
^2& A wjlafIamhg jeämqr NH3 tl;= wjlafIamh iïmQ¾Kfhka Èh ù ;o ks,a mdg
lrk ,§' meyeÈ,s ødjKhla (C) ,efí'
^3& B fmrKhg ;kql HCl ìxÿ jYfhka wjlafIam ñY%Khla (D) ,efí'
tl;= lrk ,§'
^4& D wjlafIam ñY%Khg jeämqr c,Sh NH3 j¾Kj;a wjlafIamhla o (E) wj¾K ødjKhla
tl;= lrk ,§' (F) ,efí'
^5& E wjlafIamhg H2O2 yd NaOH tl;= ly mdg ødjKhla (G) ,efí'
lrk ,§'

(i) S ødjKfha wvx.= leghdk ;=k y÷kd.kak'

(ii) A yd E wjlafIamj, ridhksl iQ;% iy j¾Kh ,shkak'
(iii) B ødjKh ;=< wvx.=fj;ehs Tn wfmaCId lrk d f.dkqfõ uQ,øjH wvx.= ridhksl m%fNao
fudkjd o@ ta w;ßka j¾Kj;a m%fNaofha IUPAC kï ,shkak'
(iv) D hk wjlafIam ñY%Kfha wvx.= ridhksl m%fNaohka fudkjd±hs ridhksl iQ;% ,shd olajkak'
(v) D yd F ødjKj, wvx.= jk ixlS¾K whkj, iQ;% yd IUPAC kï ,shkak'
(vi) 5 mÍCIKfha§ isÿjk m%;sl%shd i|yd ;=,s; whksl iólrK ,shkak'

II. by; S hk c,Sh ødjKfha wvx.= wekdhk y÷kd .ekSug isÿ l< mÍCId iy tys § ,enqKq ksÍCIK
my; ±lafõ'

mÍCIKh
^1& S ødjKfhka fldgilg ;kql HNO3 yd
AgNO3 ødjKhla ouk ,§'
^2& S ødjKfhka fldgilg ;kql NaOH yd
Al l=vq oud kgjk ,§'
ksÍCIKh
wjlafIamhla ,enqKs' fuu wjlafIamh ;kql
NH3 ys wødjH jk w;r idkaø NH3 ys Èh fõ'
lgql .|la we;s jdhqjla msg úh' tu jdhqj
u.ska r;= ,sÜuia ks,a meye fõ'

(i) S ødjKfha wvx.= wekdhk fol y÷kd.kak'

(ii) by; fojk mÍCIKfha§ isÿjk m%;sl%shdj i|yd ;=,s; whksl iólrKh ,nd.kak'
^ ,l+Kq 4'0 hs &
(b) A hkq wdj¾;s;d j.=fõ 3 jk wdj¾;fha uQ,øjHhls' A c,Sh NaOH iu. m%;sl%shdfjka X jdhqj ,nd foa'
X tu wdj¾;fha uQ,øjHhla jk B iu`. m%;sl%shd lr Y jdhqj ,nd foa' Y wdï,sl KMnO4 iu. lsß meye
ødjKhla ,nd foa'
(i) A, B, X, Y y÷kd.kak'
(ii) A yd NaOH(aq) w;r m%;sl%shdj i|yd ;=,s; ridhksl iólrKh ,shd olajkak'
(iii) A c,Sh ødjK ;=< § idok ia:dhs whkfha wKql iQ;%h IUPAC kduh yd bf,lafgdak úkHdih
,shd olajkak'

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(iv) A ys ia:dhs whkfha c,Sh ødjKhla i,ld my; wjiaa:d i|yd ;=,s; whksl iólrK ,shkak'
I. NaOH iSñ; m%udKhla tla lsÍu
II. by; ødjKhg jeämqr NaOH tla lsÍu
(v) by; (iv) ys ksÍlaIK i|yka lrkak'
(vi) I. A idok Tlaihsvh l=ula o@
II. by; ^1& ys Tlaihsvh Ndú; lrñka mÍCIKd.drfha § ksmojkq ,nk ldnksl øjHfhys
idudkH ku ,shd olajkak'
(vii) A yd laf,darSka jdhqj m%;sl%shd lr idok ixfhda.fha jdhquh wjia:dfõ§ wKql iq;%h ,shd tys ¨úia
jHqyh w`Èkak'
(viii) B uQ,øjH Tlafid wï, lsysmhla idohs' bka tla Tlafid wï,hl B ys TlaislrK wjia:d 2 la
fmkajhs' Tlafid wï,fha iQ;%h iy ku i|yka lrkak'
(ix) by; (viii) ys olajk ,o Tlafid wï,fha Tlaisydrl .=Kh fmkaùug iqÿiq ;=,s; whksl iólrKhla
,shd olajkak'
(x) I. B ys idok Tlaihsv fol l=ula o@
II. by; ^1& ys olajk ,o Tlaihsv NaOH iu. olajk m%;sl%shd i|yd ;=,s; iólrK ,shkak'
^ ,l+Kq 7'0 hs &
(c) P kï mdIdK idïm,hla fldm¾" is,aj¾ iy wl%Sh øjHhlska iukaú;h' P ys wka;¾.; is,aj¾ iy
fldm¾ m%udK ks¾Kh lsÍu i|yd my; i|yka l%shdms<sfj< wkq.ukh lrk ,§'
P ys 0.525 g la idkaø HNO3 ;=< Èh lrk ,§' tys§ ,enqkq meyeÈ,s ødjKhg c,Sh NaCl tlal< úg iqÿ
meye;s wjlafIamhla (Q) iEÿKs' wjlafIamh fmrd fjka lrf.k" wjlafIamh (Q) iy fmrKh (R) by;
f,dayj, m%udK úYaf,aIKh lsÍu i|yd Ndú; lrk ,§'
wjlafIamh (Q) - wjlafIamh (Q) ksh; nrla ,efnk ;=re úh,d .;a úg ialkaOh 0.287 g fõ'
fmrKh (R) - fmrkh WodiSk lr jeämqr KI tl;= lrk ,§' ksoyia jk I2 , 0.200 mol dm-3
Na2S2O3 iu. msIaGh o¾Ylh f,i fhdod.ksñka wkqudmkh lrk ,§' tys§ wka;
,laIHfha§ ìhqfrÜgq mdGdxlh 24.00 cm3 la úh' ^wl%Sh øjH idkaø HNO3 ;=, Èhjk
njo" bka mÍCIkh i|yd lsisÿ n,mEula isÿ fkdjk nj o i,lkak'&
(Ag = 108 , Cu = 63.5 , Cl = 35.5)
(i) isÿjk ish¨u m%;sl%shd i`oyd ;=,s; ridhksl iólrK ,shkak'
(ii) P j, wka;¾.; is,aj¾ iy fldm¾ ialkaO m%;sY; .Kkh lrkak'
^ ,l+Kq 4'0 hs &

10. (a) my; i|yka m%Yak" Odrd W!Iaulh (Blast Furnace) Ndú; lr hlv ksiaidrKh u; mokï ù we;'
(i) hlv ksiaidrKfha§ Ndú; lrk hlv f,damia iy wksl=;a wuqøjHhkays idudkH kï yd ridhksl
iQ;% fokak'
(ii) hlv f,damia yer" wksl=;a tla tla wuqøjHfhys ld¾hh (Function) fláfhka idlÉPd lrkak'
wod< wjia:djkays ;=,s; ridhksl iólrK Ndú; lrkak'
(iii) Odrd W!Ia ulh ;=< hlv f,damia" hlv njg fida mdKS h f,i is ÿjk mßj¾;kh (stepwise
conversion) ±laùu i|yd ;=,s; ridhksl iólrK ,shkak'
(iv) Odrd W!Iaulh m;=f,a iEfok øj hlvfha ku ,shd tys wdikak ixhq;sh fokak'
(v) Odrd W!Iaulfhka ,nd.kakd hlv" u< fkdnef|k jdfka (stainless steel) njg mßj¾;kh lsÍu
i|yd tys ixhq;sfha isÿúh hq;= fjkialï olajkak' fuh flfia isÿlrkafka±hs fláfhka i|yka
lrkak'
(vi) hlv f,damia" fidamdKSh f,i mßj¾;kfhka hlv 2000 kg ksIamdokh lsÍfï§ Ndú; jk jdhqfõ
[(iii) fldgfiys y÷kd.;a] ialkaOh kg j,ska .Kkh lrkak'
(vii) Odrd W!Iaulfha by<g .uka lr thska msgjk wmf;a hk jdhq ñY%kh (waste gas mixture) Odrd
W!Iaulfha jdhqj fyda *aÆ jdhqj f,i ye¢kafõ' fuu ñY%Kfha we;s m%Odk jdhq i|yka lr" m%uqL
jdhqj y÷kd.kak'
^idfmaCI mrudKql ialkaOh Fe = 56 , O = 16 , c = 12)
^ ,l+Kq 5'0 hs &

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(b) my; .e,Sï igykska olajd we;af;a ifudaOdksl ld¾ñl l%shdj,shls' fuys A2 hkq Lksc je,s j¾.hls'
P3 fmdfydr ksIamdokh i|yd Ndú; jk wuqøjHhls'

A M P

wuqøjH ksIamdok l%shdj,sh wjidk M,h

B1, B2, B3 iy B4 wod, jdhq j¾. fõ'

A1 A2 A3

B1
øjhls'
M1 M2

B4
P1 B3
Nd.sl
P2
wdijkh
A4 B2 M3

P3

(i) M1, M2 yd M3 hk ld¾ñl l%shdj,s y÷kd.kak'

(ii) A1, A2, A3 yd A4 hk wuqøjH kï lrkak'
(iii)P1, P2 yd P3 M, kï lrkak'
(iv) B1, B2, B3 yd B4 jdhq j¾. kï lrkak'
(v) M3 ld¾ñl l%shdj,sh ;=<§ M,odj by< kexùu i|yd fN!; ridhksl uQ,O¾u fhdod .ekSu
;dm.;sl f;dr;=re iy ridhksl pd,kh Ndú;fhka myokak'
(vi) M2 ld¾ñl l%shdj,sfhka P2 M, ,nd .ekSug wod< jk m%;sl%shd i|yd ;=,s; ridhksl iólrK
,shd olajkak'
^ ,l+Kq 5'0 hs &

(c) khsÜrcka jdhqj jdhqf.da,fha mßudj wkqj 78 ] l muK m%;sY;hlska wvx.= jk w;r fndfyda ÿrg
WÉp jdhqjlg wdikak .=K fmkajhs' tfy;a khsÜrckays iuyr ixfhda. mßirh flfrys wys;r
wdjrK ±laùug fnfyúka odhl fõ'
(i) khsÜrcka jdhqj WÉp jdhqjlg iudkj yeisÍug fya;=j meyeÈ,s lrkak'
(ii) mßir ¥IKhg odhl jk khsÜrckays jdhquh ixfhda. folla i|yka lrkak'
(iii) by; Tn i|yka l< ix>gl mßirhg uqod yefrk l%shdj,s ;=kla i|yka lrkak'
(iv) by; (ii) ys i|yka l< ixfhda. u`.ska we;s lrk mdßißl wdprK y;rla i`oyka lrkak'
(v) by; Tn i|yka l< wdjrK w;ßka folla flfrys jdhqf.da,Sh khsÜrcka odhl jk wdldrh
m%;sl%shd weiqfrka meyeÈ,s lrkak'
(vi) by; (ii) ys § Tn i|yka l< ¥Il mßirhg tl;=ùu md,kh l< yels l%u folla i|yka lrkak'
^ ,l+Kq 5'0 hs &

olaIhka w;r w;s olaIhl= ùug