AL/2022/02/S-IA -1-

úfYaI úNd. fmryqre mÍlaIK

I
I
Two hours
I

Total Marks
ku - '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
úNd. wxlh - '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
mdi, - '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
m%Yak m;% mx;shg muKla iyNd.S fõ kï yßhla () fhdod olajkak' -

Wmfoia :
* m%Yak m;%fha kshñ; ia:dkfha Tfí wkkH;djh yÿkd .ekSug wjYH o;a; ,shkak'
* fuu m%Yak m;%h msgq 08 lska hqla; fõ'
* ish¨ u m%Yak j,g ms<s;=re imhkak'
* ms<s;=re W;a;r m;%fha muKla l;srhla () fhdod olajkak'

id¾j;% jdhq ksh;h R = 8.314 J K-1 mol-1 wej.dâfrda ksh;h NA = 6.022 x 1023 mol-1
ma,dkalaf.a ksh;h h = 6.626 x 10-34 Js wdf,dalfha m%fõ.h C = 3 x 108 ms-1

1. yhsârckaj, úfudapk j¾Kdj,sfha mrcïnq, fldgi uq,sku

a wOHhkh lrkq ,enqfõ ñka ljfrl= úiska o@
^1& ks,aia fnda¾ ^2& uelaia ma,dkala ^3& ,hsudka ^4& mdYka ^5& ndu¾

2. Pd uQ,øjH mrudKqjl l = 2 lafjdkagï wxl bf,lafg%dak lShla mj;shs o@

^1& 10 ^2& 12 ^3& 18 ^4& 20 ^5& 312

3. [Co(NH3)5Cl]SO4 j, Co mrudKQfõ TlaislrK wxlh yd ix.; wxlh wkqms<sfj,ska ñka l=ula u `.ska
fmkakqï lrhs o@
^1& +2 yd 6 ^2& +3 yd 5 ^3& +3 yd 6 ^4& +2 yd 1 ^5& +1 yd 2

4. m%ldY iudjhúl;dj yd cHdñ;sl iudjhúl;dj folu fmkaúh yels ir,u odu yhsfv%dldnkfha
mj;sk C mrudKq ixLHdj jkafka"
^1& 5 ^2& 6 ^3& 7 ^4& 8 ^5& 10

5. ethyl 3-bromo-5-oxopent-2-enoate hk ldnksl ixfhda.fha ksjerÈ jHqyh jkafka l=ula o@

O Br O Br
=

^1& CH3CH2O _ C _ CH2 _ CHCH2CHO ^2& CH3CH2O _ C _ CH = C _ CH2CHO

O Br O Br O
=

=
=

^3& CH3CH2O _ C _ C = CHCH2CHO ^4& CH3CH2O _ C _ CH = C _ C _ CH3

Br OO
=

^5& CH3CH2O C CH = C CH2 C _ CH3

_ _ _ _

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02/S-IA -2-

6. my; §we;s c,h ødjH;dj, ikakdhl;dj jeäjk ksjerÈ ms<sfj< jkqfha"

^1& 0.01 M NaCl < 0.1 M NaCl < 0.1 M NH4Cl < 0.1 M HCl
^2& 0.01 M NH4Cl < 0.01 M NaCl < 0.1 M NH4Cl < 0.1 M HCl
^3& 0.01 M NH4Cl < 0.01 M NaCl < 0.1 M NaCl < 0.1 M HCl
^4& 0.01 M NH4Cl < 0.1 M HCl < 0.01 M NaCl < 0.1 M NaCl
^5& 0.1 M NHCl < 0.01 M NaCl < 0.1 M NaCl < 0.1 M NH4Cl

7. jeäu ;dm m%udKhla msgjkafka my; i|yka l=uk øjH ñY% l< úg o@
^1& 1 mol dm-3 HCl(aq) wï, ødjK 50 cm3 iy 1 mol dm-3 NaOH ødjK 50 cm3
^2& 1 mol dm-3 HCl(aq) wï, ødjK 50 cm3 iy 1 mol dm-3 Ba(OH)2 ødjK 50 cm3
^3& 1 mol dm-3 HNO3(aq) wï, ødjK 50 cm3 iy 1 mol dm-3 NaOH ødjK 50 cm3
^4& 1 mol dm-3 H2SO4(aq) wï, ødjK 50 cm3 iy 1 mol dm-3 Ba(OH)2 50 cm3
^5& 1 mol dm-3 HCl(aq) wï, ødjK 50 cm3 iy 1 mol dm-3 NH4OH ødjK 50 cm3

8. Pt(s) / Y2+(aq) , Y3+(aq) || XO4-(aq) , X2+(aq) , H+(aq) / Pt(s) hk fldaIh u.ska úoHq;a Odrdjla ,nd.kS'
bf,lafg%davh E(298 K) / V
Pt(s) / Y3+(aq) , Y2+(aq) +0.77
Pt(s) / XO4-(aq) , X2+(aq) +1.52
úoHq;a Odrdjla .e,Sfï § TlaisyrKh jkafka ljrla o@
^1& H+(aq) ^2& XO4-(aq) ^3& X2+(aq) ^4& Y3+(aq) ^5& Y2+(aq)

9. KCl(s) W;amdokhg wod< fndaka-fyan¾ pl%fhys wvx.= fkdjkafka my; i|yka l=uk m%;sl%shd mshjr o@
^1& K(s)  K+(s) + e ^2& K(s)  K(g) ^3& Cl2(g)  2Cl(g)
^4& Cl(g) + e  Cl (g)
-
^5& K (g) + Cl (g)  KCl(s)
+ -

10. H2O2 ødjKhlska 50 cm3 ;kql H2SO4 u`.ska wdï,sl lr jeämqr KI ødjKhla iu`. m%;sl%shd lrjk ,§'
túg ksoyia jk I2 iu. uq¿ukskau m%;sl%shd ùug 0.01 mol dm-3 Na2S2O3 ødjKhlska 20.00 cm3 la jeh
úh' H2O2 ødjKfha idkaøKh mol dm-3 j,ska fldmuK o@
^1& 0.002 mol dm-3 ^2& 0.2 mol dm-3 ^3& 0.02 mol dm-3
^4& 0.068 mol dm-3 ^5& 2.00 mol dm-3

11. ld,h;a iu. CO(g) + 2H2(g) CH3OH(g) hk moaO;sfha wvx.= ix>glj, idkaøK fjkia jk
wkaou my; m%ia;drfha ±lafõ' ld,h T1 yd T2 ys § isÿ ù we;af;a l=ula o@
idkaøKh

T1 T2 ld,h
T1 T2
^1& H2(g) tlalr we;' CH3OH(g) bj;a lr we;'
^2& CO(g) tlalr we;' CH3OH(g) bj;a lr we;'
^3& H2(g) tlalr we;' CO(g) bj;a lr we;'
^4& CO(g) tlalr we;' CO(g) yd H2(g) bj;a lr we;'
^5& H2(g) tlalr we;' moaO;sfha mSvkh wvqlr we;'

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02/S-IA -3-

12. A yd B iudk ujq,j,ska wdrïN lrñka my; mßÈ moaO;sh iu;=,s; ùug ie,eiajQ úg iu;=,s; A ys
ujq, m%udKh D ys ujq, m%udKhg iudkh'
A(g) + B(g) 2C(g) + D(g)
moaO;sfha uq¿ mSvkh 2.5 × 105 Pa kï by; WIaK;ajfha § moaO;sfha iu;=,s;;d ksh;h jkqfha"
^1& 2 × 105 Pa ^2& 2.5 × 105 Pa ^3& 4 × 105 Pa ^4& 1 × 104 Pa ^5& 2 × 104 Pa

13. CH3CH = CH CONH2  CH3CH(Br)CH(Br)CH2Br njg m;a lsÍu i|yd Ndú;d l< yels m%;sl%shd
wkqms<sfj<la my; ±la fõ'
mshjr 1 mshjr 2 mshjr 3 mshjr 4
CH3CH = CH CONH2     CH3CHBrCHBrCH2Br

tla tla mshjr i|yd Ndú;d l< yels m%;sldrl yd ;;aj ksjerÈ wkqms<sfj,g olajd we;af;a"
mshjr 1 mshjr 2 mshjr 3 mshjr 4
^1& H2 / Ni Br 2 NaNO2 / HCl PBr 3
^2& Zn / Hg / HCl HBr 2 NaNO2 / HCl Br2 Èhr
^3& H2 / Ni NaNO2 / HCl Br 2 PBr 3
^4& LiAlH4 NaNO2 / HCl PBr 3 Br 2
^5& LiAlH4 Br2 Èhr NaNO2 / HCl PBr 3

14. 25 0C § tal NdIañl ÿn, wï,hl Ka w.h 1.0 × 10-6 mol dm-3 fõ' fuu wï,fha 1.0 mol dm-3 c,Sh
ødjKhl pOH w.h 25 0C § fldmuK fõo@ ^ie'hq' 25 0C § Kw = 10-14 mol2 dm-6)
^1& 3 ^2& 6 ^3& 8 ^4& 10 ^5& 11

15. 2 NO2(g) N2O4(g) hk m%;sl%shdfõ iïu; tka;e,ams úm¾hdih - 58 kJ mol-1 fõ' K1 yd K -1

hkq bÈß yd miq m%;sls%hd i|yd iS>%;d ksh; fõ' KC hkq iu;=,s;;d ksh;hhs' WIaK;ajh by< kexjQ úg
K1 , K -1 yd KC flf¾ we;sjk n,mEu ljf¾ o@
^1& K1 jeä fõ' K -1 wvq fõ' KC jeä fõ' ^2& K1 jeä fõ' K -1 jeä fõ' KC jeä fõ'
^3& K1 jeä fõ' K -1 jeä fõ' KC wvq fõ' ^4& K1 jeä fõ' K -1 wvq fõ' KC wvq fõ'
^5& K1 wvq fõ' K -1 wvq fõ' KC wvq fõ'

16. 25 0C WIaK;ajfha § ødjKhla AgSCN iy AgBr j,ska ix;Dma;j mj;S' ødjKfha Ag+ whk idkaøKh
mol dm-3 j,ska jkqfha"
Ksp(AgBr) = 5 × 10-13 mol2 dm-6
Ksp(AgSCN) = 1.2 × 10-12 mol2 dm-6
^1& 1.3 × 10-5 ^2& 1.3 × 10-12 ^3& 1.3 × 10-6 ^4& 1.3 × 10-8 ^5& 1.3 × 10-10

17. my; olajd we;s m%;sl%shdfõ m%Odk M,h l=ula o@

CO2Cl
jeämqr c,Sh NaOH

HO CH 2 OH

CO2-Na + CO2-Na + CO2-Na +

^1& ^2& ^3&

Na+O- CH2O Na
- +
Na+O- CH 2 OH HO CH2O-Na +

CO2-Na + CO 2 H
^4& ^5&

HO CH 2 OH Na+O- CH 2 OH

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02/S-IA -4-

18. A iy B hk ñY%K ødjK mßmQ¾K ødjK idohs' tla;rd WIaK;ajhl § ixY=oaO ødjk foflys jdIam mSvk
ms<sfj,ska 6 atm iy 12 atm fõ' A : B ujq, wkqmd;h 1 : 3 jk ødjKhl iuia; jdIam mSvkh fï
WIaK;ajfha§u fldmuK o@
^1& 7.5 atm ^2& 9.0 atm ^3& 10.0 atm ^4& 10.5 atm ^5& 11.0 atm

19. X keu;s ldnksl ixfhda.hla my; m%;sl%shd olajhs'

(a) 0 0C § NaNO2 / HCl iuÕ m%;sls%hd ù khsg%cka uqod yÍ'
(b) c,Sh KHCO3 iuÕ m%;sls%hdlr CO2 uqod yÍ'
(c) c,Sh CsOH iuÕ r;al< úg NH3 uqod yÍ'
X úh yelafla "
NH3+ Cl- CONH 2 COOH COONH4 CONH 2

NH 2
OH OH CONH 2 COOH
^1& ^2& ^3& ^4& ^5&

20. 2NO(g) + 3H2(g) N2(g) + 2H2O(l) hk m%;sl%shdfjys YS>%;d iólrKh mÍlaIKd;aulj fiúu i|yd
isÿ lrk mÍlaIKhl È ,;a mdGdxl my; j.=fõ ±lafõ'
NO(g) wdxYsl mSvkh H2(g) wdxYsl mSvkh wdrïNl YS>%;djh
Hg mm Hg mm Hg mm s-1
200 400 0.46
400 200 0.92
400 400 1.84
by; m%;sl%shdfjys YS>%;d iólrKh jkqfha"
^1& R = K PNO ^2& R = K PH2 ^3& R = K PNO × PH2
^4& R = K PNO × PH2 2
^5& R = K PNO2 × PH2

O
=

21. CH2 - C- NH2 hk ixfhda.hg ;kql HCl iy ;kql NaOH fhdod c,úÉfþokh l<úg
Cl ,efnk m%Odk M,hka ms<sfj<ska A iy B fõ' A iy B jkqfha"
CH 2 NH 2

O O O O
=

C - OH C - ONa CH2 - C - OH CH2 - C - ONa

+ +
^1& Cl CH2NH3Cl - Cl CH 2 NH 2 ^2& Cl CH2NH3Cl - Cl CH 2 NH 2
(A) (B) (A) (B)
O O O O
=

=
=

CH2 - C - Cl CH2 - C - ONa CH2 - C - OH CH2 - C - OH

+
^3& Cl CH 2 NH 2 HO CH 2 NH 2 ^4& Cl CH2NH3Cl - Cl CH 2 NH 2
(A) (B) (A) (B)

O O
=
=

CH2 - C - OH CH2 - C - ONa

^5& Cl Cl CH 2 NH 2
CH 2 NH 2
(A) (B)

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02/S-IA -5-

22. WIaK;ajh 25 0C § c,Sh ix;Dma; M(OH)2 ødjKhl pH w.h 10 fõ' 25 0C § c,fha Kw = 1.0 × 10-14
mol2 dm-6 kï" fï WIaK;ajfha§ M(OH)2 ys Ksp w.h l=ula o@
^1& 1 × 10-8 mol2 dm-6 ^2& 1 × 10-10 mol dm-3 ^3& 5 × 10-12 mol2 dm-6
^4& 5 × 10-13 mol3 dm-9 ^5& 1 × 10-30 mol3 dm-9

23. jdhq ms<sn| pd,l wKql jdohg wkqj mßmQ¾K jdhq ksheÈhla i|yd my; § we;s l=uk j.ka;sh i;H
fkdfõ o@
^1& ksh; WIaK;ajhl § wKq .eàfï § wKqj, uq¿ pd,l Yla;sh fjkia fkdfõ'
^2& j¾. uOHkh uQ, m%fõ.h jdhq j¾.h u; r|d mj;S'
^3& jdhq wKqjl uOHhk pd,l Yla;sh ksrfmaCI WIaK;ajhg wkqf,dauj iudkqmd;sl fõ'
^4& jdhq wKqjl mßudj wka;¾.; Ndckfha mßudj iu. ii|k úg fkd.sksh yels ;rï l=vdh'
^5& ksh; WIaK;ajfha § jdhq wKqjl uOHhk pd,l Yla;sh mSvkh jeäjk úg jeä fõ'

24. N2O4(g) 2NO2(g) iu;=,s;h i,lkak' wdrïNfha § N2O4 muKla we;s moaO;shla iu;=,s; jQ miq
uq ¨ mSvkh P o iu;=,s;;d ksh;h Kp o kï ú>gk m%udKh i|yd ksjerÈ m%ldYkh l=ula o@
1/2
Kp / P Kp Kp / P
^1&  ^2&  ^3&  4 + Kp / P
4 + kp / P 4 + Kp
2 1/2
Kp Kp / P
^4&  ^5& 
4 + kp 4p + Kp / P

25. my; ±lafjk ixfhda. i,lkak'

(a) NH4Cl (b) NaNO3 (c) NaNO2 (d) CO(NH2)2
NaOH yd Al l=vq ñY% lr keg jQ úg NH3 fokafka ñka l=uk ixfhda.h o@ $ ixfhda. o@
^1& (a) muKs' ^2& (b) muKs' ^3& (a) yd (b) muKs'
^4& (a) , (b) , (c) muKs' ^5& (a) , (b) , (c) , (d) ish,a,u

26. A(g) B(g) + C(g) hk m<uq fm< uQ,sl m%;sl%shdfõ" § we;s WIaK;ajhl § fõ. ksh;h K fõ' wdrïNl
wjia:dfõ (t = 0) § wdrïNl mSvkh P1 jk w;r t ld,hlg miqj moaO;sfha mSvkh P2 kï tu
fudfydf;a § by; m%;sl%shdfõ fõ.h ,ndfok m%ldYh jkafka"
^1& K (P2 - P1) ^2& K (P1 - P2) ^3& K (2P1 - P2) ^4& K (P1 - 2P2) ^5& 2K (P1 - P2)

27. s f.dkqfõ f,day ms<sn| j my; l=uk m%ldYh i;H fõ o@

^1& s f.dkqfõ ish¨ f,day isis,a c,h iuÕ m%;sls%hd lr yhsv%cka msg lrñka yhsfv%dlaihsv ,nd foa'
^2& ldKAvfha my<g hdfï § fojk ldKAvfha f,day j, yhsfv%dlaihsvhkaf.a whksl ,CIK wvq fõ'
^3& fojk ldKAvfha ish¿ f,day khsg%cka iuÕ m%;sl%shd lsÍfï § khsg%hsv ,nd foa'
^4& m<uq ldKAvfha Li yer ish¨ f,day jeämqr Tlaiscka iuÕ m%;sl%shd lsÍfï § iqm¾ Tlaihsv ,nd foa'
^5& fojk ldKAvfha lsisu f,dayhla jeämqr Tlaiscka iuÕ m%;sl%shd lr fmfrdlaihsv fkdidohs'

28. ld¾ñlj ethanoic wï,h ksIamdokh lr .kq ,nkafka ethanol iu. Tlaiscka TlaislrKfhks' ethanoic
wï,h" c,h iy ethanol j, iïu; W;amdok tka;e,amsh ms<sfj,ska -487 kJ mol-1, -286 kJ mol-1 iy
- 278 kJ mol-1 fõ' ethanoic wï,h ksIamdokhg wod, iïu; tka;e,ams fjki kJ mol-1 fldmuK o@
^1& -209 ^2& -495 ^3& +495 ^4& -990 ^5& -1051

29. ;dmhg jvd;au Tfrd;a;= fokafka ñka l=ula o@

^1& khsf,daka ^2& fíla,hsÜ ^3& fmd,s;Ska
^4& jeä >k;aj fmd,s;Ska ^5& hQßhdfmdue,aäyhsâ

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02/S-IA -6-

30. HA kï talNdIañl ÿn, wï,h c,hg jvd fyd¢ka CHCl3 ;=< ødjH fõ' HA Èhù we;s CHCl3 50 cm3 la
c,h 50 cm3 iu. fid,jd iu;=,s;ùug bv yßk ,§' iu;=,s; moaO;sfha CHCl3 10.0 cm3 iu. m%;sl%shd
lsÍu i|yd 0.02 mol dm-3 jQ NaOH 20.0 cm3 jeh úh' fuu WIaK;ajfha § CHCl3 yd c,h ;=< HA ys
jHdma;s ix.=Klh 4 fõ' HA c,Sh ia;rfha § muKla wdxYslj ú>gkh jk w;r Ka w.h 1 × 10-5 mol dm-3
fõ' iu;=,s; wjia:dfõ § c,Sh ia;rfha pH w.h jkafka"
^1& 3 ^2& 3.5 ^3& 4 ^4& 4.5 ^5& 5

 wxl 31 isg 40 olajd jq m%Yak j,g my; Wmfoia mßÈ ms<s;=re imhkak'

(1) (2) (3) (4) (5)

(a) iy (b) (b) iy (c) (c) iy (d) (d) iy (a) m%;spdr tlla muKla fyda fjk;a
muKla muKla muKla muKla m%;spdr ixLHdjla fyda ksjerÈh'
ksjerÈh ksjerÈh ksjerÈh ksjerÈh

31. ridhksl l¾udka; iïnkaOfhka my; l=uk m%ldYh $ m%ldY wi;H fõo@
(a) N2(g) + 3H2(g) 2NH3(g) ; H = - hk m%;sl%shdj u`.ska wefudakshd ksIamdokfha fyan¾ l%ufha§
250 - 300 atm hk m%Yia; mSvkfha§ Wmßu NH3 M,odjla ,efí'
(b) N2(g) + 3H2(g) 2NH3(g) ; H = - hk m%;sl%shdj u`.ska wefudakshd ksIamdokfha fyan¾ l%ufha§
450 - 500 C hk m%Yia; WIaK;ajfha§ Wmßu NH3 M,odjla ,efí'
0

(c) hlv ksiaidrKfha§ m%Odk Tlaisydrlh jk CO(g) u`.ska 3Fe2O3(s) + CO(g)  2Fe2O4(s) + CO2(g)
njg o FeO(s) + CO(g)  Fe(s) + CO2(g) njg o" TlaisyrKh flf¾'
(d) 2NO(g) + O2(g) 2NO2(g) hk m%;sl%shdj ;dmodhl ksid Tiaj,aâ l%ufhka HNO3 ksmoùfï tu
mshjf¾§ 150 C g jvd wvq WIaK;ajhla mj;ajd .kS'
0

32. X ixfhda.h iïnkaOfhka my; ±lafjk l=uk m%ldYh $ m%ldY ksjerÈ fõ o@

CH2COCH 3
[X] CH3CH = C
CH2CHOHCH3
(a) X cHdñ;sl iudjhúl;djh iy m%ldY iudjhúl;djh fmkajhs'
(b) X f¾ks ksl,a W;a`fm%arl f,i we;súg H2 iu. m%;sl%shd lsÍfuka ,efnk M,h m%ldY iudjhúl;djh
fkdfmkajhs'
(c) X msßãkshï laf,dafrdfl%dafïÜ (PCC) iu. m%;sl%shd lsÍfuka ,efnk M,h m%ldY iudjhúl;djh
fkdfmkajhs'
(d) X msßãkshï laf,dafrdfl%dafïÜ iu. m%;sl%shd lsÍfuka ,efnk M,h cHdñ;sl iudjhúl;djh fmkajhs'

33. my; i|yka j.ka;s w;ßka wi;H jkafka"

(a) ;dmodhl m%;sl%shdjl iu;=,s;;d ksh;h" WIaK;ajh by< kexùu;a iu. wvq fõ'
(b) iu;=,s; wjia:dfõ § m%;sl%shdj kej;Su ksid" M, yd m%;sl%shlj, idkaøKh ksh; fõ'
(c) W;afm%Arlhla tl;= l< úg bÈß m%;sl%shdfõ fõ.h" miq m%;sl%shdfõ fõ.hg jvd jeä fõ'
(d) Kp ys w.h ieu úgu Kc ys w.hg iudk fkdfõ'

34. 2A + B  C hk m%;sl%shdj iïnkaOj pd,l úoHd;aul f;dr;=re lsysmhla my; § we;'

* B ys idkaøKh ksh;j ;nd ksh; WIaK;ajfha § A ys idkaøKh fo.=K l< úg m%;sl%shd iS>%;djh
y;r .=Khla fõ'
* 25 0C § m%;sl%shdjg wod< iS>%;d ksh;h 48 dm6 mol-2 fõ'
wod< m%;sl%shdj iïnkaOj by; f;dr;=re j,ska ,nd.; yels wksjd¾Hh ks.ukhla $ ks.uk jkafka"
(a) uQ,sl m%;sl%shdjls'
(b) fojk fm< m%;sl%shdjls'
(c) B g idfmalaIj m<uq fm< m%;sl%shdjls'
(d) 25 0C § A yd B idkaøK 0.1 mol dm-3 jk úg m%;sl%shdfõ iS>%;djh 4.8 × 10-4 mol dm-3 s-1 fõ'

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02/S-IA -7-

35. .;sl iu;=,s;;djfha mj;sk my; moaO;sh i,lkak'

2A(g) + B(g) 2C(g) ; H > 0
my; tajdhska i;H m%ldYh $ m%ldY l=ula o@
(a) WIaK;ajh jeäl< úg miq m%;sl%shd YS>%;djh wvq fõ'
(b) ksh; WIaK;ajfha § A ys idkaøKh fo.=Khla lr B ys idkaøKh wvla l< úg iu;=,s;;d ,laIHh
fjkia fkdfõ'
(c) ksh; WIaK;ajfha § moaO;sfha iuia; mßudj jeä l< úg C ys wdxYsl mSvkh jeä fõ'
(d) ksh; WIaK;ajfha § A ys idkaøKh jeä l< úg C ys idkaøKh jeäjk w;r B ys idkaøKh wvq fõ'

36. m%;sl%shdjl w;rueÈ m%fNaofha wdxYsl jHqyhla f,i C  HC+  C jHqyh ,eîug yelshdj we;af;a"
(a) kshqla,sfhda*s,sl wdl,k m%;sl%shd j, (b) kshqla,sfhda*s,sl wdfoaY m%;sl%shd j,
(c) bf,lafg%d*s,sl wdl,k m%;sl%shd j, (d) wefrdaueál bf,lafg%d*s,sl wdfoAY m%;sl%shd j,

37. C6H5N+NCl- ms<sn|j jerÈ m%ldY ^h& l=ula o@

(a) C6H5N+NCl- " CuI iu. m%;sl%shd lr whfvdfnkaiSka ,nd fohs'
(b) C6H5N+N whkhg bf,lafg%da*hs,hla f,i l%shd l< yelsh'
(c) C6H5N+NCl- ys c,Sh H3PO2 ødjKhla r;a l< úg th úfhdackh ù fnkaiSka ,ndfohs'
(d) C6H5N+NCl- NdIañl udOHfha § *Sfkda, iu. m%;sl%shd lr r;= meye;s ixfhda. idohs'

38. hï WIaK;ajhl § Zn(s) / Zn2+(aq) Cu2+(aq) / Cu(s) hk fldaIfha úoHq;a.dul n,h 1.0 V fõ' my;
tajdhska l=ula $ l=uk tajd i;H fõ o@
(a) Zn2+(aq) ødjKfha idkaøKh jeä lsÍfuka fldaIfha úoHq;a .dul n,h wvq fõ'
(b) Cu2+(aq) ødjKfha idkaøKh jeä lsÍfuka fldaIfha úoHq;a .dul n,h wvq fõ'
(c) ,jK fia;=fõ È. jeä lsÍfuka fldaIfha úoHq;a .dul n,h wvq fõ'
(d) fldaIfha w.% fol n,anhlska tlsfklg iïnkaO l<fyd;a w.% 2 w;r úNj wka;rh 1 V j,g jvd wvq fõ'

39. my; ljr j.ka;sh$ j.ka;s i;H fõ o@

(a) ldfndlais,sla wï, LiAlH4 u`.ska muKla TlaisyrKh fõ'
(b) bromobenzene myiqfjka kshqla,sfhda*s,sl wdfoaY m%;sl%shd fmkajhs'
(c) ish¨u we,alhs,a fya,hsv laIdÍh KOH u`.ska we,alSk idohs'
(d) C6H5CH=CH2(Styrene) bf,lafg%d*s,sl wdl,k m%;sl%shd fukau bf,lafg%d*s,sl wdfoaY m%;sl%shd fmkajhs'

40. jdhqf.da,Sh ¥IKh iïnkaOj my; l=uk m%ldY^h& i;H fõ o@

(a) f.da,Sh WKqiqu i|yd CO2 m%Odk f,i odhl jk w;r CFC o ta i|yd odhl fõ'
(b) wï, jeis i|yd CO2 fukau i,a*¾j, Tlaihsv o odhl fõ'
(c) CO, CFC yd SO2 hk jdhQka ´fidaka ia:rh laIh ùug fya;= fõ'
(d) r:jdykj,ska ksl=;ajk fkd±jqKq yhsfv%dldnk yd khsg%ckaj, Tlaihsv m%ldY ridhksl OQñldj i|yd
m%Odk fya;=jhs'

 wxl 41 isg 50 olajd m%Yak j,g my; Wmfoia mßÈ ms<s;=re imhkak'

. m%;spdrh m<uq m%ldYh fojk m%ldYh

^1& i;Hh i;H jk w;r" bka m<uqjekak ksjerÈj myod fohs'
^2& i;Hh i;H jk w;r" bka m<uqjekak ksjerÈj myod fkdfohs'
^3& i;Hh wi;Hh'
^4& wi;Hh i;Hh'
^5& wi;Hh wi;Hh'

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02/S-IA -8-

m<uq m%ldYh fojk m%ldYh

41. ixY=oaO c,fha pH w.h 6 ùug mq¿jk' WIaK;ajh jeäjk úg" c,fha ú>gk m%udKh jeä fõ'

42. iam¾Y l%ufhka H2SO4 ksmoùfï § by< mSvk by< mSvkj,g Tfrd;a;= fok WmlrK ksmoùu
Ndú; fkdflf¾' wd¾Ólj wjdisodhlh'

43. WIaK;ajh iu`. øjhl jdIam mSvkh f¾Çhj jeä wjê WIaK;ajhg jvd wvq WIaK;ajhl§ mSvkh
fkdfõ' fh§fuka jdhqjla øj l< fkdyel'

44. W;afm%Arl j,ska m%;sl%shdjl m%;sl%shd ;dmh fjkia W;afm%arl j,ska m%;sl%shdjl il%Shk Yla;sh wvq
fkdlf¾' flf¾'

45. WIaK;ajh by< hk úg ;dmodhl m%;sl%shdjl WIaK;ajh by< hk úg il%shk Yla;sh blaujd
iS>%;djh wvq jk w;r ;dm wjfYdaIl m%;sl%shdjl hk wkqNd.h jeä fõ'
iS>%;djh jeä fõ'

46. m%;sl%shdjl fm< m%;sl%shlj, idkaøKh u; r|d m%;sl%shdjl ta ta m%;sl%shlhg wod< fm< u`.ska
mj;S' m%;sl%shdfõ iS>%;djh flfrys m%;sl%shlj, idkaøKfha
n,mEu meyeos,s lrhs'

47. m%;slh
s% djl .síia Yla;s úm¾hdih úYd, RK w.hla .síia Yla;s úm¾hdi úYd, RK w.hla jk
jk m%;sl%shdjla iajhx isoaOjk w;r b;d m%;sl%shdjl il%shk Yla;sh b;d wvqh'
fõ.fhka isÿ fõ'

48. 0.1 mol dm-3 CH3COOH ødjKhlg jvd 0.1 mol dm-3 ;kql c,Sh ødjKj, § fu;fkdhsla wï,hg jvd
HCOOH ødjKhl pH w.h wvq h' t;fkdhsla wï,h m%n, wdï,sl ,laIK fmkajhs'

49. Fe(OH)3 >kh c,fha Èh lsÍfuka idod.kakd fmdÿ whkhla mj;sk c,Sh ødjKhla ;=< whksl
,o ødjKhla ;=< Mg(OH)2 ys ødjH;dj" tu ixfhda.hl ødjH;dj" tu WIaK;ajfha§ tu whksl
WIaK;ajfha § Mg(OH)2 ys c, ødjH;djg jvd ixfhda.fha c, ødjH;djg jvd iEu úgu l=vd fõ'
ie,lsh hq;= f,i l=vd fõ'

-
50. O2- whk c,h iu`. iïmQ¾K fhka m%;sl%shd lr c,Sh ødjKhl mej;sh yels m%n,;u NIauh OH
-
OH whk idohs' whkh fõ'

*****

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]