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1335_1979_Reff2021_alumina in bricks
1335_1979_Reff2021_alumina in bricks
1335_1979_Reff2021_alumina in bricks
(Reaffirmed 2001)
(Reaffirmed!2016)!
(Reaffirmed 2021)
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IS I 1335 • 1979
( ReafT'anned 1991 )
Indian Standard
METHOD FOR
DIRECT DETERMINATION OF
ALUMINA IN REFRACTORY MATERIALS
(First Revision)
Methods of Chemical Analysis'Sectional Committee, SMDC 2
Chairman Representin,
DR R. K. OUTTA Steel Authority of India Ltd (Durgapur Steel
Plant), Durgapur
Members
SHRI G. M. ApPARAO Steel Authority of India Ltd (Bhilai Steel Plant).
Bhilai
SIRI R. K. GUl'TA ( Alternate )
SHRI P. K. BANERJEE Directorate General of Ordnance Factories ( Minis-
try of Defence), Calcutta
SHRI II. C. BHARGAVA India Government Mint (Ministry of Finance ),
Bombay
SHRI J. BlIATTACBARJEE Ministry of Defence ( DGI )
Snu M. Y. BaRKER ( AlUrnate )
DR V. M. BHUCBAR National Physical Laboratory ( CSIR ), New Delhi
DR S . K. BISWAS. Hindustan Copper Ltd, Calcutta
SHR} S. N. BOHIDAR Steel Authority of India Ltd ( Rourkela Steel Plant),
Rourkela
SUR} p. CBAKRA Indian Metals & Ferro Alloys Ltd, Koraput
DR M . M. CHAKRABORTY Indian Iron &. Steel Co Ltd, Burnpur
5HRI A. C. MUKHERJEE ( Alllmal, )
CH1UU8T & METALLURGIST, Ministry of Railways
SOfTU CENTRAL RAILWAY,
SECUNDERABAD
ASSISTANT DIRECTOR ( MET),
ROSO, CUITTARANJAN (Alternate)
CUIIlI' CHEMIST The Tata Iron & Steel Company Ltd, Jamshedpur
ASSISTANT CUIE), CHEMIST ( Allertlot, )
DR A. N. CHOWDHURY Geological Survey of India, Calcutta
SHRI B. N. BHATTAOHARYA ( Alternate)
( Contin.ud on pa,. 2 )
•
© Copyright 1980
BUREAU OF INDIAN STANDARDS
This publication is protected under tiie Indian Copyright Act ( XIV of 1957) and
reproduction in whole or in part by any means except with written permission of the
publisher shall be deemed to be an infringement of copyright under the laid Act.
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IS : 1335 • 1979
( Continu,d from pac. I )
Members ReprlS.ntinf:
SHRJ H. P. DUBEY National Test House, Calcutta
DR B. C. DUTTA Bharat Aluminium Company Ltd, New Delhi
SHRI K. P. MUKHERJEE ( Alternat.)
SHRI S. N. HONAVAR Italab Private Ltd, Bombay
SHm J. C. DEY ( Alternate I )
SHRI J. P. PATEL (Alternate II )
SHRI D. P. JAIN Saru Smelt in! Pvt Ltd, Meerut
SHRI D. N. CHAKRABORTY ( Alternate)
SHRI G. L. JETHWANI Hindustan Zinc Ltd, Udaipur
SHRI V. B. KHANNA Directorate General of Supplies & Disposals,
New Delhi
SHRI M. P. CHOWDHURY (AII.rnat,)
DR L. P. PANDEY National Metallurgical Laboratory ( CSIR ),
Jamshedpur
SHRI B. N. PRASAD Steel Authority of India Ltd (Bokaro Steel Plaat ),
Bokaro
DR J. RAJARAM Essen & Co, Bangalore
SHRI K. RAMAKRISHNAN ( AltlTnat. )
SHRID.RAMAMOORTHY Bharat Heavy Electricals Ltd, Tiruchirapalli
SHRI M. B. UNNI ( AltlTnate )
SHRI M. K. RAO Binani Metal Works Ltd, Calcutta
SHRl A. SANGAMESWARA RAO Ferro Alloys Corporation Ltd, Shreeramnagar
SHRI G. RAJARAO ( Alternate)
DR B. C. SINHA Central Glass & Ceramic Research IDltitute
( CSIR ), Calcutta
SHRI R. SEN ( Alternate)
DR P. SUBRAMANIAM Ministry of Defence ( R&D)
DR B. V. RAO ( Alternate)
DR CH. VENKATESWARLU Bhabha Atomic Research Centre, Bombay
DR C. S. P. hER ( Alternate I )
SHRI P. MURUGAIYAN ( Alternat. II )
SIIBI C. R. R>'.MA RAO, Director General, lSI ( Ex-officio M,mb,,)
Director ( Struc & Met)
Se&retary
SHRIS. L. BALI
Deputy Director ( Met), IHS
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IS : 1335 • 1979
Indian Standard
METHOD FOR
DIRECT DETERMINATION OF
ALUMINA IN REFRACTORY MATERIALS
(First Revision)
o. FOR E W 0 R D
0.1 This Indian Standard ( First Revision) was adopted by the Indian
Standards Institution on 27 June 1979, after the draft finalized by the
Methods of Chemical Analysis Sectional Committee had been approved
by the Structural and Metals Division Council.
0.2 This standard was first published in 1959 as a tentative standard. In
this revision, the earlier methods have been replaced by an EDT A
method for direct determination of alumina in refractory materials.
0.3 In reporting the result of a test or analysis made in accordance with
this standard, if the final value, observed or calculated, is to be rounded
off, it shall bedone in accordance with IS : 2-1960·.
I. SCOPE
1.1 This standard covers the method for direct determination of a1umina
in high alumino refractories and alumino-silicates containing low (less
than 2 percent) lime and magnesia.
2. SAMPLING AND PREPARATION OF SAMPLE
2.1 The material shall be sampled in accordance with the procedure
laid down in IS : 1528 ( Part VII )-1974t.
2.2 Laboratory Sample - The samples shall be crushed in any type of
crusher with hardened tool steel faces with due precautions to prevent
contamination of the sample with steel particles from the sampling equip-
ment during crushing and grinding. After quartering, 20 g of the sample
3
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IS : 1335 • 1979
3. QUALITY OF REAGENTS
3.1 Unless specified otherwise, pure chemicals and distilled water
( see IS : 1070-1977t ) shall be used.
NOTE - • Pure chemicals· shall mean chemicals that do not contain impurities
which affect the results of analysis.
IS I 1335 • 1979
IS : 1335 - 1979
potassium pyrosulphate or potassium bisulphate, dissolve the melt in
dilute hydrochloric acid ( 1 : 4 ) ( see Note ).
NOTE - After dissolving the melt in dilute hydrochloric acid, if the solution is not
clear, filter and wash the residue 2 to 3 times with a little dilute hydrochloric acid
( I : 10). Ignite the residue in a platinum crucible and then fuse with about I g of
sodium carbonate and borax ( 2 : I ) mixture. Extract the melt with dilute hydro-
chloric acid ( I : 4: ) and add to the filtrate.
6.2 Make the volume to about 75 ml and nearly neutralize with sodium
hydroxide solution. Slowly and while swirling constantly pour the
solution into a 250-ml volumetric flask containing 100 ml of sodium
hydroxide solution to which has been added 1 g of sodium carbonate
(see Note). Warm on a water bath for one hour and cool to room
temperature. Dilute with water to the mark, mix well and let stand for
a few minutes. Filter off the precipitate on a filter paper that has been
previously washed with sodium hydroxide solution, catching the filtrate
in a beaker (rinse the beaker first with a few ml of the same filtrate ).
Transfer a suitable aliquot from the filtrate to a 250-ml conical flask.
Add one drop of methyl orange and then dilute hydrochloric acid
( 1 : 1 ) dropwise until the colour changes from yellow to red.
NOTE - The sodium carbonate is used to precipitate calcium and magnesium
along with iron and titanium.
7. CALCULATION
A X B X 100
Alumina, percent - C
where
A = volume in ml of standard zinc solution required for
titration of liberated EDT A,
B = equivalent AlzOa in g/ml of standard zinc solution, and
C = mass in g of the sample represented by the aliquot taken.
6
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