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Name: Class: Date:
3. Which of these characteristics does NOT apply to the rate of heat flow?
a. depends on the material
b. proportional to the temperature gradient
c. inversely proportional to the square of the length over which heat flows
d. proportional to the cross-sectional area
ANSWER: c
4. What thickness of clothing (assume it to have the conductivity of felt) must a human wear in order to experience the
same total rate of heat loss as an animal with the same body temperature and 10% of the surface area, and having a layer
of fat under its skin 1.50 cm thick?
a. 9.00 cm
b. 2.50 cm
c. 0.40 cm
d. 0.25 cm
ANSWER: b
5. If two materials are in contact, with the first material having twice the thermal conductivity of the second, what can be
deduced about the temperature gradients in the two materials near the interface between them?
a. They are the same.
b. They depend on factors other than thermal conductivities.
c. The temperature gradient of the second is half that of the first.
d. The temperature gradient of the second is twice that of the first.
ANSWER: d
6. What is the metabolic rate (expressed in kJ/day) required by a person of surface area 1.5 m2 and wearing clothing (with
the thermal conductivity of felt) of thickness = 1 cm, to maintain a body temperature of 37°C, when the air temperature is
0°C?
a. 19180 kJ/day
b. 9590 kJ/day
c. 1918 kJ/day
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Name: Class: Date:
7. The rate of cooling of an object is proportional to the difference in temperature between the body and its surroundings.
How much faster will a cup of water at boiling point (100.0°C) cool outside where the temperature is –10.0°C compared
to in a room at temperature 20°C?
a. 0.4 times
b. 0.5 times
c. 0.7 times
d. 1.4 times
ANSWER: d
9. What is the dominant mechanism of cooling the skin when exposed to air at temperature 27°C?
a. radiation
b. convection
c. conduction
d. perspiration
ANSWER: a
10. Which of these statements best describes how thermal relaxation time depends on the geometric characteristics of a
body?
a. It is proportional to the volume.
b. It is proportional to the linear dimension.
c. It is proportional to the square of the linear dimension.
d. It is proportional to the square root of the volume.
ANSWER: c
11. The temperature of Earth’s interior is 3000°C. Taking the surface temperature as 0°C, what is the temperature at the
bottom of a mine shaft 2 km deep?
a. 10°C
b. 50°C
c. 60°C
d. 120°C
ANSWER: c
13. If the activation energy of a certain molecule is 3.0 eV, by what factor does the diffusion constant increase when the
temperature changes from 30°C to 37°C?
a. 6.7
b. 10.1
c. 13.4
d. 391.0
ANSWER: b
14. For a given time period, how does diffusion length depend on temperature?
a. decreases with temperature
b. independent of temperature
c. increases with temperature
d. can both increase and decrease with temperature
ANSWER: c
16. In Arrhenius’s formula, on which one of these factors does the factor D0 depend at the molecular scale?
a. speed of particles
b. temperature
c. the frequency with which the particle attempts to overcome the activation energy barrier
d. distance between particles
ANSWER: c
17. The parameter set for the diffusion of oxygen in silicon contains the pair of points (ln(D), 1/T) with values (–28.42,
6.0 × 10–4) and (–34.54, 8.0 × 10–4). What is the activation energy in eV?
a. 5.28 eV
b. 2.64 eV
c. 2.04 eV
d. 1.31 eV
ANSWER: b
18. The parameter set for the diffusion of carbon in silicon contains the pair of points (ln(D), 1/T) with values (–30.16, 6.0
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Name: Class: Date:
19. The diffusion constant for Cu in Si, at temperature 1394°C is larger than that of Ge in Si by a factor of 3.58 × 106. If,
after a certain time, Ge diffuses an average distance of 1 ìm, how far on average does Cu diffuse during the same time
interval?
a. 3.58 m
b. 3.78 mm
c. 1.89 mm
d. 1.89 ìm
ANSWER: c
20. How does doubling the width of a membrane affect the time it takes for a particle to pass through the membrane?
a. Time is doubled.
b. Time is four times longer.
c. Time is longer by a factor of .
d. Time remains the same.
ANSWER: b
21. In order to have life, biological systems have to exist away from equilibrium.
a. True
b. False
ANSWER: True
23. When calculating the heat loss from the human body, the metabolic rate can be higher than this heat loss.
a. True
b. False
ANSWER: True
26. Einstein’s diffusion formula may be applied to the transport of potassium ions across membranes of nerve cells.
a. True
b. False
ANSWER: False
27. The diffusion coefficient of one fluid in another medium depends on both the fluid and the medium.
a. True
b. False
ANSWER: True
28. The diffusion coefficient increases with activation energy of an atom moving through a matrix of other particles.
a. True
b. False
ANSWER: False
29. For diffusion of a molecule through a membrane, the activation energy can, in general, be estimated as accurately as
the pre-factor D0.
a. True
b. False
ANSWER: False
30. The distance that a particle diffuses is proportional to the duration of time.
a. True
b. False
ANSWER: False
31. The “R-value” is stamped onto insulating material to indicate the “thermal resistivity” of the material, and is
proportional to the inverse of the thermal conductivity coefficient k. The units of R are (foot2)(°F)(British thermal
unit/hour)–1(inch–1). Find the equation that relates R-values to thermal conductivity when the latter is expressed in SI
units (Wm–1K–1).
ANSWER: Use the following conversions to SI units: 1 foot = 0.3048 m, 1°F = (9/5) K, 1 Btu = 1.054 kJ, 1 inch =
0.0254 m. From these values, an R-value of unity corresponds to thermal conductivity of 6.9404 W/(mK).
Therefore, k = 6.9404/R, where k is in SI units, and R in the units given.
RAT: SI units are used in biological situations; R-values are used to indicate, for example, the thermal
insulation efficiency of clothing.
32. Calculate the heat flux (heat flow per unit area) from the body of a person (surface area = 1.5 m2) wearing clothing of
thickness = 1 cm, when the clothing is (i) pure cloth, and (ii) cloth, with 50% air space, when the outside temperature is –
20°C and body temperature is 37°C. Use values of ë from Table 10.1. What effect does moisture caused by perspiration
have when entering the air spaces?
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33. For a given volume, how would the shape of an animal determine the rate of heat loss through its skin?
ANSWER: Answers may vary.
RAT: One way to approach this would be to consider the surface area of a long cylinder (representing the
shape of a worm or snake) and that of a sphere (representing the shape of a whale, as in Example 10.2) of the
same volume. If the cylinder has length l and diameter d, and the sphere has diameter D, then equating
volumes gives ðd2l/4 = ðD3/6, or d2l = 2/3 D3. Therefore, the ratio, r, of the area of cylinder to sphere would
be r = (2ðd2/4 + ðdl)/(ðD2) = d(½ d + l)/D2 ∝ d½d + l)/(d2l)2/3, on substituting for D from the previous
equation. If we assume that d is small in comparison to l (that is, a “long” cylinder), then r ∝ (l/d)1/3. From
this it is clear that, volume for volume, a cylinder has a much larger area than a sphere. (In fact, the sphere is
the shape that minimizes surface area for a fixed enclosed volume.)
34. Using the procedure in Example 10.1, derive a general formula for the cooling time of a planetary body of given
internal and surface temperatures and a rocky crust of thickness = l. How would this cooling time be affected if the crust
gradually formed, so that it was thinner in the past and thickened as the planet cooled down?
ANSWER: The cooling time is approximately ½ ñl2crock/ë, that is, smaller by a factor of 2 than the dimensional analysis
given below Table 10.3. If l were smaller in the past, then the cooling times would be reduced.
RAT: As in Example 10.3.
35. The history of life on Earth demonstrates that it existed long before the age of the Sun or Earth as calculated by Lord
Kelvin. Discuss how this dilemma was resolved in more recent times.
ANSWER: The internal energy sources of Earth are maintained by radioactive processes at the core. The Sun’s energy
comes predominantly from nuclear sources at its core, and contributions from cooling or gravitational
shrinking are small. In both cases, the energy supply is adequate to allow development of life over the
observed geologic timescales.
RAT: Nuclear energy sources have lifetimes that may greatly exceed the cooling timescales predicted by heat
capacity and heat conduction models.
36. Briefly discuss why passive diffusion is inadequate as a mechanism for transporting ions and molecules through a
membrane.
ANSWER: Some ions need to move against their concentration gradient, as in active ion transport: this type of transport
requires energy, such as is supplied by ATP molecules. Also, for proper functioning of nerve cells, the cell
membrane potential must be maintained by selectively allowing potassium, sodium, and other ions different
transport properties.
RAT: Structure and chemical processes of the membrane determine the transport properties, in addition to just
the concentration gradient of the diffusing species.
37. Discuss in general terms what factors affect the rate of uptake of oxygen by mammals of different sizes, considering
that the heartbeat rate determines the speed at which blood circulates from oxygen uptake by the lungs to its return to the
lungs for replenishment.
ANSWER: Answers may vary.
RAT: This may be approached as an exercise in dimensionality arguments. Some points to consider are the
following. Size (L) will determine the mass of blood in the mammal, which is proportional to L3. The rate of
oxygen uptake will scale with the area of the lungs (∝ L2) and blood circulation time (∝ L/speed). The volume
of blood pumped during each heartbeat will scale as the volume of the heart (∝ L3) and the distance travelled
along veins and arteries per heartbeat [∝ (heart volume)/(cross-sectional area of vein or artery) ∝ L3/L2 = L].
38. In Fick’s law, as stated in Eqs. [10.2] and [10.3], the assumption was made that all particles were travelling
perpendicular to the plane defining the membrane. How would you generalize this result, considering the particles move
randomly in all directions?
ANSWER: Only those particles with components of velocity perpendicular to the membrane will be candidates for
penetrating the membrane. On average, this will incur a factor one-sixth multiplying the jump frequency of
atoms when calculating the flux.
RAT: Apply reasoning similar to kinetic theory of gases.
39. When taking a deeper breath than usual, the alveoli expand to a make a larger surface area; however, each breath takes
longer. Discuss how this will affect oxygen intake by the lungs.
ANSWER: Increasing the area increases the material flux, and the longer breath cycle enables this increased flux to be
maintained for a longer time. However, the supply of oxygen becomes depleted after a while, so the benefit of
increased oxygen uptake prevails only up to some optimal time.
RAT: Apply Fick’s law (Eq. [10.3]).
40. Discuss how you might measure the diffusion coefficient of one substance in another.
ANSWER: Take measurements of diffusion length at different times, starting with a localized concentration of the first
substance in the second. Einstein’s formula, Eq. [10.6], shows that the diffusion length is proportional to the
square root of the elapsed time, with constant of proportionality (which may be estimated from the
measurements) equal to .
RAT: Apply Einstein’s formula and fit data to this.