MQB_Physical_Chemistry20210709181921533983_20220523115726542990

MASTER QUESTION BANK
(JEE-MAIN)
PHYSICAL CHEMISTRY
MOLE CONCEPT
1. A metal M forms the sulphate M2(SO4)3. A 0.596 gram sample of the sulphate reacts with
excess BaCl2 to give 1.220 g BaSO4. What is the atomic weight of M(in g/mol)?
(A) 26.9 (B) 69.7 (C) 55.8 (D) 23
2. The mass of CaO obtained by heating 100 kg of 95% pure limestone (CaCO3) is-
(A) 56 kg (B) 28 kg (C) 53.2 kg (D) 50 kg
3. 500 g impure sample of CaCO3 on heating gives 70 g of CaO. Percentage impurities in

sample is
(A) 25% (B) 50% (C) 75% (D) 80%
4. Percentage loss in mass, when NaHCO3(S) is heated in open vessel 2 NaHCO3(S) → Na2
CO3(S) + CO2(g) + H2O (g)
(A) 21.12% (B) 36.9% (C) 30% (D) 32.23%
5. NaCIO3 is used in spacecraft to produce O2. The daily consumption of pure O2by a person is
492 L at 1 atm, 300 K. How much amount of NaCIO3 (in grams) is required to produce O2 for
the dailyconsumption of a person at 1 atm, 300 K ?
NaCIO3 (s) + Fe (s) →O2 (g) + NaCI(s) + FeO (s) R = 0.082 L atmmol–1 K–1
(A) 21.3 (B) 1115 (C) 2130 (D) 4260
6. At constant T and P, 5.0 L of SO2 are reacted with 3.0 L of O2 according to the following
equation,
2 SO2(g) + O2(9) →2 SO3(g). The volume of the reaction mixture at the completion of the
reaction is
(A) 0.5 L (B) 8.0 L (C) 5.5 L (D) 5 L
7. 100 mL of 0.3 M acetic acid is shaken with 0.8 g wood charcoal. The final concentration of
acetic acid in the solution after adsorption is 0.125 M. The mass of acetic acid adsorbed per
gram of charcoal is
(A) 1.05 g (B) 0.0131 g (C) 1.31 g (D) 0.131 g
8. The ratio of the masses of methane and ethane in a gas mixture is 4:5. The ratio of number of
their molecules in the mixture is
(A) 4 : 5 (B) 3 : 2 (C) 2 : 3 (D) 5 : 4
: 90,Gopal square 2 & 3rd Floor, Sector - A, Shrinath Puram, Kota, Rajasthan 324010
DOWNLOAD OUR APP & GET
: www.atpstar.com
UNLIMITED PRACTICE FOR FREE PAGE NO.-1
: 08107258987
9. According to the equation : 4NH3(g) + 5 O2 (g) → 4NO (g) + 6H2O (l) when 1 mole of O2 and 1
mole of ammonia are mixed, then
(A) 0.2 mole of H2O is produced
(B) 0.1 mole of NO is produced
(C) all the oxygen will be consumed
(D) all the ammonia will be consumed in order to form 1 mole NO
10. 1.44 g of Titanium (Ti) reacted with an excess of O2 and produced x g of a non- stoichiometric
compound Ti1.44O1. The value of x in g is :
(A) 1.44 (B) 2 (C) 1.77 (D) None of these
11. The average molar mass of chlorine is 35.5 g mol–1. The ratio of 35Cl to 37
Cl in naturally
occurring chlorine is close to
(A) 4 : 1 (B) 3 : 1 (C) 2 : 1 (D)1 : 1
12. The ammonia (NH3) released on quantitative reaction of 0.6 g urea (NH2CONH2) with sodium
hydroxide (NaOH) can be neutralized by
(A) 100m L of 0.2 N HCl (B) 200 mL of 0.4 N HCl
(C) 200 mL of 0.2 N HCl (D) 100 mL of 0.1 N HCl
13. In order to oxidise a mixture of one mole of each of FeC2O4, Fe2(C2O4)3, FeSO4 and Fe2(SO4)3
in acidic medium, the number of moles of KMnO4 required is.
(A) 2 (B) 1 (C) 3 (D) 1.5
ATOMIC STURCTURE
14. The vapour of Hg absorb some electrons accelerated by a potential difference of 4.5 volts
from rest as a result of which light is emitted. If the full energy of a single incident electron is
supposed to be converted into light emitted by electron in a single Hg atom, find the wave
1
number   of the light
λ
(A) 3.63 × 106 m–1 (B) 5.93 × 106 m–1 (C) 5.93 × 106 cm–1 (D) 5.62 × 106 m–1
x
15. An electron in an atom jumps in such a way that its kinetic energy changes from x to . The
9
change in its potential energy (magnitude) will be -
x 16x 9x
(A) (B) (C) 9x (D)
9 9 16
16. What electronic transition in Li2+ produces the radiation of same wavelength as the first line in
the Balmer’s series of Hydrogen spectrum
(A) n2 = 3 to n1 = 2 (B) n2 = 6 to n1 = 3
(C) n2 = 9 to n1 = 6 (D) n2 = 9 to n1 = 8
17. An element undergoes a reaction as shown :

X + 2e– → X2– , energy released = 30.87 eV/ atom. If the energy released is used to dissociate
4 gms of H2 molecules, equally into H+ and H*, where H* is excited state of H atoms where
the electron travels in orbit whose circumference equal to four times its de Broglie's
wavelength. Determine the least moles of X that would be required.
Given I.E. of H = 13.6 eV/atom bond energy of H2 = 4.526 eV/ moleule.
(A) 1 (B) 2 (D) 3 (D) 4
: www.atpstar.com
: 08107258987
18. The de-Broglie wavelength of α-particles at a voltage V is (Given that α-particle has 2 units
positive charge and 4 units mass)
12.3 0.286 0.101 0.856
(A) λ = Å (B) λ = Å (C) λ = Å (D) λ = Å
v v v v
19. What is the wavelength of light emitted when the electron in a hydrogen atom undergoes
transition from an energy level with n = 4 to an energy level with (Given: Rydberg constant
1
]
912 Å
(A) 185.2 nm (B) 285.2 nm (C) 385.2 nm (D) 486.4 nm
20. The energy of second Bohr orbit of the hydrogen atom is –328 kJ mol–1. The energy of fourth
Bohr orbit would be:
(A) –41 kJ mol–1 (B) –82 kJ mol–1 (C) –164 kJ mol–1 (D) –1312 kJ mol–1
21. Radiation corresponding to the transition n = 4 to n = 2 in hydrogen atoms falls on a certain

metal (work function = 2.0 eV). The maximum kinetic energy of 1he photoelectrons will be:
(A) 0.55eV (B) 2.55eV (C) 4.45 eV (D) None
22. If the uncertainty in the position of a particle is equal to its de-Broglie wavelength, the
minimum uncertainty in its velocity should be
1 v v mv
(A) (B) (C) (D)
4π 4π 4πm 4π
23. The ratio of minimum to maximum wavelengths in Balmer series of H-atom is

(A) 5 : 9 (B)5 : 36 (C) 1 : 4 (D) 3 : 4
24. According to Bohr's atomic theory :-
Z2
(a) Kinetic energy of electron is μ ∝
n2
(b) The product of velocity (v) of electron and principal quantum number (n), 'vn' ∝ Z2.
Z2
(c) Frequency of revolution of electron in an orbit is ∝ .
n2
Z3
(d) Coulombic force of attraction on the electron is ∝ .
n4
Choose the most appropriate answer from the options given below :
(A) (c) Only (B) (a) Only
(C) (a), (c) and (d) only (D) (a) and (d) only
: www.atpstar.com
: 08107258987
25. The plots of radial distribution functions for various orbitals of hydrogen atom against 'r' are
given below:
8 3
4πr R n,/(r)
4πr R n,/(r)
2
2
2
(a) (b)
2
2
4
1
0 5 10 0 5 10
r(Å) → r(Å) →
2.0
3
4πr R n,/(r)
4πr R n,/(r)
1.5
2
2
2 1.0
(c) (d)
2
2
1 0.5
0 5 10 0 5 10
r(Å) → r(Å) →
The correct plot for 3s orbital is:
(A) (b) (B) (a) (C) (d) (D) (c)
26. The figure that is not a direct manifestation of the quantum nature of atoms is
Rb K Na
Kinetic energy of
Increasing wavelength photoelectrons
(A) (B)
Frequency of incident
Absorption spectrum radiation
T2 > T1
Internal Internal
(C) energy of (D) of black body
Ar radiation T1
300 400 500 600
Temperature (K) Wavelength
REDOX REACTION
27. Consider the following three halides:
(1) CH3 – CH2 – Cl (2) CH2 = CH – Cl (3) C6H5 – Cl
Arrange C –Cl bond length of these compounds in decreasing order -
(A) 1 > 2 > 3 (B) 1 > 3 > 2 (C) 3 > 2 > 1 (D) 2 > 3 > 1
28. RH2 (ion exchange resin) can replace Ca2+ ions in hard water as :
RH2 + Ca2+→RCa + 2H+
If 1 L of hard water after passing through RH2 has pH = 3, then hardness in parts per million of
Ca2+is :
(A)10 ppm (B) 40 ppm (C) 100 ppm (D) 20 ppm
: www.atpstar.com
: 08107258987
29. 2.56 x 10–3 equivalent of KOH is required to neutralise 0.12544 g H2XO4 The atomic mass of
X(in g/mol ) is:[Given: 1-12 XO 4 is a dibasic acid]
(A) 16 (B) 8 (C) 7 (D) 32
30. 1 mole of equimolar mixture of Fe2(C2O4)3 and FeC2O4 reqires X moles of KMnO4 in acid
medium for complete reaction. The value of X is :
(A) 0.9 (B) 0.6 (C) 1.2 (D) 0.8
31. A redox reaction always involves

(A) A change in oxidation number. (B) A change in phase.
(C) The transfer of protons. (D) The formation of ions.
32. 0.1 M KMnO4 is used for following titration. What volume of the solution in mL will be required
to react with 0.158 g of Na2S2O3? Not balanced: S2O 32− + MnO4– + H2O → MnO2(S) +SO 24− +OH–
(A) 26.7 mL (B) 50 mL (C) 65 mL (D) 75 mL
33. In the mixture of (Na2CO3 + NaHCO3) volume of HCl required is x mL with phenolphthalein
indicator and y mL with methyl orange indicator in the same titration. Hence volume of HCl for
complete reaction of Na2CO3 is-
x
(A) 2x (B) y (C) (D) (y – x)
2
34. What will be the value of x, y and z in the following equation?

H2C2O4 + xH-2O2→ yCO2 + zH2O
(A) 2, 1, 2 (B) 1, 2, 2 (C) 2, 2, 1 (D) 1, 2, 1
35. H2O2 acts as an oxidizing agent in

(A) neutral medium (B) acidic medium
(C) alkaline medium (D) both acidic & alkaline medium
36. 25 mL of household bleach solution was mixed with 30 mL of 0.50 M KΙand 10 mL of

4 N acetic acid. In the titration of the liberated iodine, 48 mL of 0.25 N Na2S2O3 was used to
reach the end point. The molarity of the household bleach solution is
(A) 0.24 M (B) 0.48 M (C) 0.024 M (D) 0.96 M
37. (A) HOCl + H2O2 

→ H3O+ + Cl– + O2
(B) I2 + H2O2 + 2OH– 
→ 2I– + 2H2O + O2
Choose the correct option.
(A) H2O2 acts as reducing and oxidising agent respectively in equation (A) and (B)
(B) H2O2 acts as oxidising agent in equation (A) and (B)
(C) H2O2 acts as reducing agent in equation (A) and (B)
(D) H2O2 act as oxidizing and reducing agent respectively in equation (A) and (B)
: www.atpstar.com
: 08107258987
38. Which of the following equation depicts the oxidizing nature of H2O2?
(A) KIO4 + H2O2 → KIO3 + H2O + O2
(B) 2I– + H2O2 + 2H+ → I2 + 2H2O + O2
(C) I2 + H2O2 + 2OH– → 2I– + 2H2O + O2
(D) Cl2 + H2O2 → 2HCI + O2
39. Ledt CNaCl and CBaSO be the conductances (in S) measured for saturated aqueous solution of
4
NaCl and BaSO4. Respectively, at a temperatures T. Which of the following is false ?

(A) Ionic mobiliies of ions from both salts increase with T.
(B) CBaSO (T2), > CBaSO (T1) for T2 > T1
4 4
(C) CNaCl(T2) > CNaCl(T1) for T2 > T1

(D) CNaCl ≫ CBaSO at a given T
4
CHEMICAL KINETICS
40. Four thousand active nuclei of a radioactive material are present at t = 0. After 60 minutes 500
active nuclei are left in the sample. The decay constant of the sample is
ln ( 2 ) ln ( 2 )
(A) per minute (B) per minute
60 20
(C) 20 ln (2) per minute (D) 60 ln (2) per minute
41. At 500 K, the half life period of a gaseous reaction at an initial pressure of 80 kPa is 350 s.
When the pressure is 40 kPa, the half life period is 175 sec; the order of the reaction is:
(A) zero (B) one (C) two (D) three
42. Following is the graph between log and log t 1 a(a = initial concentration of reactant) for a
2
given reaction at 27ºC. Hence, order of the reaction is
θ=45º
logt1/2
O loga
(A) 0 (B) 1 (C) 2 (D) 3
43. The radioactive isotope

234
90 Th undergoes two successive β-decay followed by α-decay. The
atomic number and the mass number respectively of the resulting isotope are :
(A) 92 and 237 (B) 94 and 230 (C) 90 and 230 (D) 92 and 230
: www.atpstar.com
: 08107258987
44. The rate of decomposition for methyl nitrite and ethyl nitrite can be given in terms of rate
constant k1 and k2 respectively. The energy of activation for the two reactions are 152.30 kJ
mol–1 and mol–1 and 157.7 kJ mol–1 as well as frequency factors are 1013 and 1014 respectively
for the decomposition of methyl and ethyl nitrite. Calculate the temperature at which rate
constant will be same for the two reactions.
(A) 256 K (B) 354 K (C) 282 K (D) 674 K
45. At the point of intersection of the two curves shown, the concentration of B is given by
.............., for the first reaction A→nB.
A0
[B]
Conc.
Time
nA 0 A0 nA 0  n –1
(A) (B) (C) (D)   A0
2 n –1 n +1  n +1
46. The half-life period for catalytic decomposition of AB3 at 50 mm is found to be 4 hrs and at 100
mm it is 2 hrs. The correct of the reaction is :
(A) 3 (B) 1 (C) 2 (D) 0
47. Decomposition of H2O2 follows a first order reaction. In fifty minutes the concentration of H2O2
decreases from 0.5 to 0.125 M in one such decomposition. When the concentration of H2O2
reaches 0.05 M, the rate of formation of O2 will be :
(A) 2.66 Lmin–1 at STP (B) 1.34 × 10–2 mol min–1
(C) 6.93 × 10–2 mol min–1 (D) 6.93 × 10–4 mol min–1
   
48. =
Two substance =
A  t 1 10min  & B  t 1 20min  follows I order kinetics in such a way that
 2   2 
[A]i = 8 [B]i. Time when [B] = 2[A] in min is:
(A) 20 (B) 40 (C) 60 (D) 80
49. Consider the following gaseous reaction where initial pressure of A(g) is 200 torr
A(g) → 3B(g) + C(g)
After time t, the pressure of system increased to 650 torr. Calculate the value of t (in seconds)
(Given : rate constant of reaction, k = 4.606 × 10–3 sec–1, log 2 = 0.3)
(A) 600 (B) 300 (C) 50 (D) 5
: www.atpstar.com
: 08107258987
50. Simplified absorption spectra of three complex [(i), (ii) and (iii)] of Mn+ ion are provided below;
their λmax values are marked as A, B and C respectively. The correct match between the
complexes and their λmax values is
Absorption
B
λmax λmax λmax

Wavelength (nm)
(i) [M(NCS)6](–6 + n) (ii) [MF6](–6 + n) (iii) [M(NH3)6]n+
(A) A-(iii), B-(i), (C)-(ii) (B) A-(ii), B-(i), (C)-(iii)
(C) A-(ii), B-(iii), (C)-(i) (D) A-(i), B-(ii), (C)-(iii)
51. Amongst the following statements regarding adsorption, those that are valid are:
(a) DH becomes less negative as adsorption proceeds.
(b) On a given adsorbent, ammonia is adsorbed more than nitrogen
(c) On adsorption, the residual force acting along the surface of the adsorbent increases
(d) With increase in temperature, the equilibrium concentration of adsorbate increases.
(A) (d) and (a) (B) (b) and (c) (C) (a) and (b) (D) (c) and (d)
52. It is true that

(A) a second order reaction is always a multistep reaction
(B) a zero order reaction is a multistep reaction
(C) a first order reaction is always a single step reaction
(D) a zero order reaction is a single step reaction
LIQUID SOLUTION
∆Tb
53. Ratio of 10 g AB2 and 14 g A2 B per 100 g of solvent in their respective, solution (AB2
Kb
and A2 B both are non-electroytes) is 1 mol/kg in both cases. Hence, atomic wt. of A and B
are respectively:
(A) 100, 40 (B) 60, 20 (C) 20, 60 (D) None of these
54. The amount (in grams) of sucrose (mol wt. = 342 g) that should be dissolved in 100 g water in
order to produce a solution with a 105.0 °C difference between the freezing point and boiling
point is (given that Kf = 1.86 K kg mol–1 and kb = 0.51 k kg mol–1 for water)
(A) 34.2 g (B) 72.2 g (C) 342 g (D) 460 g
: www.atpstar.com
: 08107258987
55. Urea (NH2 – CO – NH2) needs to be dissolved in 100 g of water, in order to decrease the
vapour pressure of water by 25% ? What will be the molality of the solution ?
(A)18.52 (B) 62.45 (C) 28.52 (D)35.64
56. A 5.25% solution of a substance is isotonic with a 1.5% solution of urea (molar mass = 60 g
mol–1) in the same solvent. If the densities of both the solutions are assumed to be equal to
1.0 g cm–3, molar mass of the substance will be
(A) 210 g mol–1 (B) 90.0 g mol–1 (C) 115.0 mol–1 (D) 105.0 g mol–1
57. The solubility of N2 in water at 300 K and 500 torr partial pressure 0.01 g L–1. The solubility
(in g L–1) at 750 torr partial pressure is:
(A) 0.0075 (B) 0.005 (C) 0.02 (D) 0.015
58. 2.0 molal aqueous solution of an electrolyte X2Y3 is 75% ionised. The boiling point of the
solution a 1 atm is (Kb(H2O) = 0.52 K kg mol–1)
(A) 274.76K (B) 377K (C) 376.4K (D) 377.16K
59. The vapour pressure of pure liquid A is 10 torr and at the same temperature when 9 g of B
solid dissolved in 20 g of A, its Vapour pressure is reduced to 5 torr. If the molecular mass of
A is 200 amu, then the molecular mass of B is
(A) 100 amu (B) 90 amu (C) 75 amu (D) 120 amu
60. K2HgI4 is 55% onized in aqueous solution. The value of Van't Hoff factor is
(A) 2.1 (B) 4.3 (C) 1.9 (D) 3.7
61. The concentration in g/L of a solution of cane sugar (Molecular weight = 342) which is isotonic
with a solution containing 6 g of urea (Molecular weight = 60) per litre is
(A) 3.42 (B) 34.2 (C) 5.7 (D) 19
62. Pure water freezes at 273 K and 1 bar. The addition of 34.5 g of ethanol to 500 g of water
changes the freezing point of the solution. Use the freezing point depression constant of water as
2 K kg mol–1. The figures shown below represent plots of vapour pressure (V.P.) versus
temperature (T). [molecular weight of ethanol is 46 g mol–1.
Among the following, the option representing change in the freezing point is
Water Water
V.P./bar
V.P./bar
1 1
(A) Ice (B) Ice
Water+Ethanol Water+Ethanol
270 273 T/K 271 273 T/K
Water Water
V.P./bar
V.P./bar
Ice Ice
1 1
(C) Water+Ethanol (D) Water+Ethanol
270 273 T/K 271 273 T/K
: www.atpstar.com
: 08107258987
63. The size of raw mango shrinks to a much smaller size when kept in a concentrated salt
solution. Which one of the following processes can explain this?
(A) Osmosis (B) Dialysis (C) Diffusion (D) Reverse osmosis
64. An acidic buffer is obtained on mixing

(A) 100 mL of 0.1 CH3COOH and 100 mL of 0.1 M NaOH
(B) 100 mL of 0.1 HCl and 200 mL of 0.1 M NaCl
(C) 100 mL of 0.1 CH3COOH and 200 mL of 0.1 M NaOH
(D) 100 mL of 0.1 HCl and 200 mL of 0.1 M CH3COONa
65. A solution of two components containing n1 moles of the 1st component and n2 moles of the
2nd component is prepared. M1 and M2 are the molecular weights of component 1 and 2
respectively. If d is the density of the solution in g mL–1, C2 is the molarity and χ2 is the mole-
fraction of the 2nd component, then C2 can be expressed as
1000χ2 dχ 2
(A) C2 = (B) C2 =
M1 + χ2 (M2 − M1 ) M2 + χ2 (M2 − M1 )
1000dχ2 dχ1
(C) C2 = (D) C2 =
M2 + χ2 (M2 − M1 ) M2 + χ2 (M2 − M1 )
CHEMICAL EQUILIBRIUM
66. In a saturated solution of the sparingly soluble strong electrolyte AgIO3 (molecular mass =
283) the equilibrium which sets in is
 Ag+(aq) + IO3− (aq)
AgIO3(s) 
If the solubility product constant, Ksp of AgIO3 at a given temperature is 1.0 × 10–8, what is the
mass of AgIO3 contained in 100 mL of its saturated solution.
(A) 28.3 × 10–2 g (B) 2.83 × 10–3 g (C) 1.8 × 10–7 g (D) 1.0 × 10–4 g
67. The first and second dissociation constants of an acid H2A are 1.0 × 10–5 and 5.0 × 10–10,
respectively. The overall dissociation constant of the acid will be
(A) 5.0 × 10–5 (B) 5.0 × 1015 (C) 5.0 × 10–15 (D) 0.2 × 105
68. The equilibrium constant Kc for the reaction

1
 SO2(g) +
SO3(g)  O2(g)
2
is 4.9 × 10–2. The value of Kc for the reaction
 2SO3(g) will be
2SO2(g) + O2(g) 
(A) 416 (B) 2.40 × 10–3 (C) 9.8 × 10–2 (D) 4.9 × 10–2
69. Phosphorus pentachloride dissociates as follows, in a closed reaction vessel,

 PCl3(g) + Cl2(g)
PCl5(g) 
If total pressure, at equilibrium, of the reaction mixture is p and degree of dissociation of PCl5
is x, the partial pressure of PCl3 will be
 x   2x   x   x 
(A)  p (B)  p (C)  p (D)  p
 x + 1  1− x   x − 1  1− x 
: www.atpstar.com
: 08107258987
70. An amount of solid NH4HS is placed in a flask already containing ammonia gas at a certain
temperature and 0.50 atm pressure. Ammonium hydrogen sulphide decomposes to yield NH3
and H2S gases in the flask. When the decomposition reaction reaches equilibrium, the total
pressure in the flask rises to 0.84 atm. The equilibrium of NH4HS at this temperature is
(A) 0.11 (B) 0.17 (C) 0.18 (D) 0.30
71. For the reaction,

 2NO(g) + O2(g)
2NO2(g) 
[Kc = 1.8 × 10–6 at 184°C, R = 0.00831 kJ/(mol K)]
When Kp and Kc are compared at 184°C it is found that
(A) whether Kp is greater than, less than or equal to Kc depends upon the total gas pressure
(B) Kp = Kc
(C) Kp is less than Kc
(D) Kp is greater than Kc
72. The exothermic formation of ClF3 is represented by the equation

 ClF3(g);
Cl2(g) + 3F2(g)  ∆Hr = –329 kJ
Which of the following will increase the quantity of ClF3 in an equilibrium mixture of Cl2, F2 and
ClF3?
(A) Adding F2 (B) Increasing the volume of the container
(C) Removing Cl2 (D) Increasing the temperature
73. What is the conjugate base of HO–?

(A) O2– (B) O– (C) H2Os (D) O2
74. The solubility product of a salt having general formula MX2, in water is 4 × 10–12. The
concentration of M2+ ions in the aqueous solution of the salt is
(A) 4.0 × 10–10 M (B) 1.6 × 10–4 M (C) 1.0 × 10–4 M (D) 2.0 × 10–6 M
75. Consider the reaction equilibrium

 2SO3(g)
2SO2(g) + O2(g) 
∆H° = –198 kJ
On the basis of Le-Chatelier's principle, the condition favourable for the forward reaction is
(A) lowering of temperature as well as pressure
(B) increasing temperature as well as pressure
(C) lowering the temperature and increasing the pressure
(D) any value of temperature and pressure
: www.atpstar.com
: 08107258987
76. For the equilibrium A  , the variation of the rate of the forward (a) and reverse (b) reaction
with time is given by
Rate of reaction
Rate of reaction
a
a
(a) Equilibrium (b) Equilibrium

b b
Time Time
Rate of reaction
Rate of reaction
a a
Equilibrium Equilibrium
(c) (d) b
b
Time Time
(1) (2)
77. If the equilibrium constant for A  B + C is K eq and that of B + C  P is K eq , the
equilibrium constant for A  P is
(B) K eq + K eq (D) K eq − K eq
(1) (2) (1) (2) (1) (2) (2) (1)
(A) K eq / K eq (C) K eqK eq
78. Consider the following reaction :

N2O4(g)  2NO2(g) ; ∆Hº = + 58 kJ
For each of the following cases (A, B), the direction in which the equilibrium shifts is
(A) temperature is decreased.
(B) pressure is increased by adding N2 at constant T.
(a) (A) towards product, (B) towards reactant
(b) (A) towards reactant, (B) no change
(c) (A) towards reactant, (B) towards product
(d) (A) towards product, (B) no change
IONIC EQUILIBRIUM
79. Solid Na2SO4 is slowly added to a solution which is 0.020 M in Ba(NO3)2and 0.020 M in
Pb(NO3)2. Assume that there is no increase in volume on adding Na2SO4. There preferential
precipitation takes place. What is the concentration of Ba2+ when PbSO4. Startsto precipitate?
[Ksp (BaSO4) = 1.0 × 10–10 and Ksp(PbSO4) = 1.6 × 10–8]
(A) 5.0 × 10–9 M (B) 8.0 × 10–7 M
(C) 1.25 × 10–11 M (D) 1.95 × 10–8 M
80. For two weak acids A and B, the ratio of their percent ionization is 4:9. The ratio of their Ka
would be –
(A) 4:9 (B) 2:3
(C) 16 : 81 (D) 3:2
: www.atpstar.com
: 08107258987
81. Which one of the following mixture does not act as a buffer solution-
(A) Boric acid and borax
(B) Sodium Phosphate & disodium hydrogen phosphate
(C) Sodium propionate and propionic acid
(D) O Sodium acetate and sodium propionate
82. pH of 0.005 M calcium acetate (pKa of CH3COOH = 4.74) is

(A) 7.04 (B) 9.37 (C) 9.26 (D) 8.37
83. If pKb for CN– at 25°C is 4.7, the pH of 0.5 M aqueous NaCN solution is
(A) 10 (B) 11.5 (C) 11 (D) 12
84. An acid base indicator has Ka = 3 × 10–5. The acid form of the indicator is red and the basic
form is blue. By how much must the pH change in order to change the indicator from 75% red
to 75% blue (log 3 = 0.4770)
(A) 0 0.95 (B) 2.3 (C) 0.75 (D) 5
85. An alkali is titrated against an acid with methyl orange as indicator, which of the following is a
correct combination?
Base Acid End point Base Acid End point
(A) (B)
Strong Strong Pink to colorless Weak Strong Colorless to pink
Base Acid End point Base Acid End point
(C) (D)
Strong Strong Pinkish red to yellow Weak Strong Yellow to pinkish red
86. The pH of 0.1 M solution of the following salts increases in the order
(A)NaCl< NH4CI <NaCN<HCl (B)HCl< NH4CI <NaCl<NaCN
(C)NaCN< NH4CI <NaCl<HCl (D)HCl<NaCl<NaCN< NH4Cl
87. 20 ml of 0.1 M NaOh is added to 30 ml 0.1 M NaOH 30 ml 0.2 M CH3COOH, (pKa = 4.74)
calculate the pH of the resulting solution ?
[given : log 2 = 0.3]
(A) 3.44 (B) 4.01 (C) 4.44 (D) 4.71
88. The table below gives the results of three titrations carried out with 0.200 M HCI to determine
the molarity of a given NaOH solution using phenolphthalein as indicator. NaOH was taken in
the burette and HCI was taken in a conical flask for the titrations
Titration No. VHCl(mL) VNaOH(mL) MNaOH mol/dm3
I 21.4 19.3 0.222
II 18.6 16.8 0.221
III 22.2 21.1 0.210
The actual molarity of the prepared NaOH solution was 0.220 mol dm–3. Which among the
following could be the reason for the wrong value obtained in titration III?
(A) Number of drops of phenolphthalein added to the titration flask was more in this titration
(B) The concentration of HCl was wrongly used as 0.250 M for the calculation of M NaOH
(C) A few drops of NaOH solution were spilled outside the titration flask during titration
(D) A few drops of the neutralized solution from titration II were left behind in the flask
: www.atpstar.com
: 08107258987
89. The solubility of AgCN in a buffer solution of pH = 3 is x. The value of x is:
[Assume : No cyano complex is formed; Ksp(AgCN) = 2.2 × 10–16 and Ka(HCN) = 6.2 × 10–10]
(A) 0.625 × 10–6 (B) 1.9 × 10–5 (C) 2.2 × 10–16 (D) 1.6 × 10–6
90. The solubility of Ca(OH)2 in water is :

[Given: The solubility product of Ca(OH)2 in water = 5.5 × 10–6]
(A) 1.77 × 10–6 (B) 1.11 × 10–6 (C) 1.11 × 10–2 (D) 1.77 × 10–2
91. Amongst the following, the form of water with the lowest ionic conductance at 298 K is
(A) saline water used for intravenous injection (B) distilled water
(C) water from a well (D) sea water
GASEOUS STATE
92. N 2 + 3H 2 
→ 2NH 3 1 mole N2 and 4 moles H2 are taken in 15L flask at 27º C. After complete
conversion of N2 into NH3, 5L of H2O is added. Pressure set up in the flast is (assume water
dissolves NH3)
3 × 0.0821 × 300 2 × 0.0821 × 300
(A) atm (B) atm
15 10
1 × 0.0821 × 300 1 × 0.0821 × 300
(C) atm (D) atm
15 10
T
93. The reduced temperature = θ =
TC
P
The reduced pressure = π =
PC
V
The reduced volume = φ =
VC
Hence, it can be said that the reduced equation of state may be given as
π 1  8 n 1 8
(A)  + 2  (3φ – 1) = θ (B)  +  (φ – 1) = θ
3 φ  3  3 φ 3
π 1 8 π 1 8
(C)  +  (3θ – 1) = φ (D)  +  (3φ – 1) = θ
 4 φ 3  3 φ 3
94. For one mole of a van der Waals when b = 0 and T = 300 K, the PV vs. 1/V plot is shown
below. The value of the van der Waals constant a (atmlitre2 mole–2) is:
24.6
PV(litre-atm mol–1)
[Graph not to scale]

23.1
21.6
20.1
0 2.0 3.0
1
(mol littre–1)
V
(A) 1.0 (B) 4.5 (C) 1.5 (D) 3.0
: www.atpstar.com
: 08107258987
95. An open manometer attached to a flask containing ammonia gas have no difference in
mercury level initially as shown in diagram. After sparking into the flask, ammonia is partially
dissociated as 2NH3(g) → N2(g) + 3H2(g). Now it have difference of 18 cm in mercury level
in two columns, what is partial pressure of H2(g) at equilibrium?
p (atm)
(A) 9 cm of Hg (B)18 cm of Hg (C) 27 cm of Hg (D)None of these
96. The Van der Waal's constant 'b' of a gas is 4π × 10–4 L/mol. How near can the centres of the to
molecules approach each other ? [ Use NA = 6 × 1023]
(A) 10–7 m (B) 10–10m (C) 5 × 10–11m (D) 5 × 10–9m
97. 

At 800º C, the following equilibrium is established as F2 (g) 
 2F(g)
The composition of equilibrium may be determined by measuring the rate of effusion of the
mixture through a pin hole. It is found that 800°C and 1 atm mixture effuses 1.6 times as fast as
SO2 effuses under the similar conditions. (At. wt. of F =19). What is the value of Kp (in atm) ?
(A) 0.315 (B) 0.685 (C) 0.46 (D) 1.49
98. For a given one mole of ideal gas ket at 6.5 atmin a container of capacity 2.463 L, the
Avogadro proportionality constant for the hypothesis is (see figure)
V
(A) 0.406 (B)2.46 (C) 22.4 (D) none of these
99. An open vessel at 27ºC is heated until 3/8th of the air in it has been expelled. Assuming that
the volume remains constant, calculate the temperature at which the vessel was heated
(A) 307ºC (B) 107ºC (C) 480ºC (D) 207ºC
: www.atpstar.com
: 08107258987
100. Which of the following graph represent Boyles law?
P
P
(A) (B) V
V 1
V2
(C) (D) All of these

log P
log V
101. An air column closed in a tube sealed at one end by a Hg column having height h. When the
tube is placed with open end down, the height of the air column is l1. If the tube is turned so
that its open end is at the top, the height of the air column is I2. What is the atmospheric
pressure (P0)
(I) (II)
h
1
1
h
h(11 + 12 ) h(11 − 12 )
(A) P0 = cm ofHg (B) P0 = cm ofHg
(12 − 11 ) (11 + 12 )
h(11 + 12 )
(C) 76cm of Hg (D) P0 = cm ofHg
(11 − 12 )
102. Which one of the following graphs is not correct for ideal gas ?
d d
(I) T (II) T
d d
1/T
(IV) p
(III)
d = density, p = pressure, T = Temperature
(A) III (B) I (C) IV (D) II
: www.atpstar.com
: 08107258987
103. A mixture of one mole each of H2, He and O2 each are enclosed in a cylinder of volume, V at
temperature T. If the partial pressure of H2 is 2 atm, the total pressure of the gases in the
cylinder is
(A) 14 atm (B) 38 atm (C) 22 atm (D) 6 atm
104. An element crystallises in a face-centred cubic (fcc) unit cell with cell edge a. The distance
between the centres of two nearest octahedral voids in the crystal lattice is
a a
(A) (B) a (C) 2a (D)
2 2
THERMODYNAMICS
105. The enthalpy of neutralisation of NH4OH and CH3COOH is –10.5 kcal mol–1 andenthalpy of
neutralisation of CH3COOH with strong base is –12.5 kcal mol–1.The enthalpy of ionisation of
NH4OH will be
(A) 4.0 kcal mol–1 (B) 3.0 kcal mol–1 (C) 2.0 kcal mol–1 (D) 3.2 kcal mol–1
106. Hydrogen peroxide (H2O2) decomposes according to the equation

2H2O2  2H2O (I) + O2 ( g)
From the following data at 250 C Calculate the value of Kp at 400 K for the above reaction,
∆H0 = −196.0KJ ∆s0 =
125.65 J/K
0.15
[Given : 10 = 1.41]
(A) 0.14 × 032 (B) 0.14 × 10-32 (C) 0.14 × 103 (D) 1.3 × 1015
107. What is the true regarding complete combustion of gaseous isobutane-

(A) ∆H = ∆E (B) ∆H > ∆E (C) ∆H = ∆E = 0 (D) ∆H < ∆E
108. Two moles of an ideal gas is expanded isothermally and reversibly from 1 litre to 10 litre at
300 K. The enthalpy change (in kJ) for the process is
(A) 11.4 kJ (B) – 11.4 kJ (C) 0 kJ (D) 4.8 kJ
109. The reversible expansion of an ideal gas under adiabatic and isothermal conditions is
shown in the figure. Which of the following statement is incorrect?
(P1, V1, T1)
P
(P2, V2, T2)
adiabatic
(P3, V3, T3)
(A) T3> T1 (B) T2 = T2

(C) ∆Uisothermal>∆Uadiabatic (D) W isothermal>W adiabatic
110. A sample of gas is compressed by an average pressure of 0.50 atmosphere so as to

decrease its volume from 400 cm3 to 200cn3. During the process 8.00 J of heat flows out to
surroundings. The change in internal energy of the system is
(A) +2.13 J (B) +10.13 J (C) –2.13 J (D) –10.13 J
: www.atpstar.com
: 08107258987
111. When the following reaction was carried out in a bomb calorimeter, ∆U is found to be
–740.0 kJ/mol of NH2 CN(s) (s) at 300k.
3
NH2CN(s) + CO2(g)→ N2(g)+ CO2(g) + H2O(A) Calculate AH300K for the reaction.
2
(A) –738.75 kJ (B) +738.75 kJ (C) –824.75 kJ (D) –919.57 kJ
112. The entropy change when an ideal gas under atmospheric condition at room temperature is
allowed to expand from 0.5 L to 1.0 L and also is simultaneously heated to 373 K will be
(Given: Cv, m = 12.50 J K–1mol–1 and log 1.25 = 0.1)
(A) 0.18 J K–1 (B) 0.36 JK–1 (C) 0.90 JK–1 (D) 0.72 JK–1
113. A fixed mass m of a gas is subjected to transformation of states from K to L to M to N and

back to K as shown in the Figure.
K L
N M
The succeeding operation that enable this tansformation of state are
(A) heating, cooling, heating, cooling (B) cooling, heating, cooling, heating
(C) heating, cooling, cooling, heating (D)cooling, cooling, heating eating,
114. Three samples of 100 g of water (samples I, Il and Ill), initially kept at 1 atm pressure and
298 K were given 1he following treatments.
Sample I was heated to 320 K and cooled to 298 K
Sample lI was heated to 300 K, cooled to 273 K and heated to 298 K
Sample Ill was heated to 373 K and cooled to 298 K
At the end of these processes, the internal energy of
(A) III is the highest
(B) II is the highest
(C) I and III are the same, II is lower than that of I and II
(D) I, II and III are the same
: www.atpstar.com
: 08107258987
115. For silver, Cp(J K–1 mol–1) = 23 + 0.01 T. If the temperature (T) of 3 moles of silver is raised
from 300 K to 1000 K at 1 atm pressure, the value of ∆H will be close to
(A) 62 kJ (B) 16 kJ (C) 21 kJ (D) 13 kJ
116. A process will be spontaneous at all temperature if

(A) ∆H > 0 and ∆S < 0 (B) ∆H < 0 and ∆S > 0
(C) ∆H < 0 and ∆S < 0 (D) ∆H > 0 and ∆S > 0
117. Consider the reversible isothermal expansion of an ideal gas in a closed system at two
different temperatures T1 and T2 (T1 < T2). The correct graphical depiction of the dependence
of work done (W) on the final volume (V) is
|W| T2 |W| T2 |W| T2 |W| T2
T1 T1
T1 T1
(A) (B) (C) (D)
O ln V O ln V O ln V O ln V
ELECTROCHEMISTRY
118. Consider the following cell reaction
2Fe ( s ) + O 2 ( g ) + 4H + ( aq ) → 2Fe 2 + ( aq ) + 2H 2 O ( l )
If Ecell = E ºcell at 25º C and  Fe 2 +  = 10−3 M, = 0.01 atm and pH = x
value of x is
(A) 1 (B) 2 (C) 3 (D) 4
119. The standard reduction potential for Cu2+/Cu is +0.34 V. Calculate the reduction potential at
pH = 14 for the above couple. (ksp of Cu(OH)2 = 1 × 10–19)
(A) –0.22 V (B) +0.22 V (C) –0.44 V (D) +0.44 V
120. The equivalent conductivity of 0.1 M weak acid is 100 times lesser than that at infinite dilution.
The degree of dissociation of weak electrolyte at 0.1 M is-
(A) 100 (B) 10 (C) 0.01 (D) 0.001
121. For sparingly soluble salt [M(NH3)4Br2]H2PO2, what will be the solubility product constant in
2
 mol 
 litre  ?
 
[Given λ 0M( NH + = 100 Sm2mol–1, λ 0H2 PO2 = 50 Sm2mol–1]
3 ) 4 Br2
Take specific resistance as 200 Ωcm

(A) 1.11 × 10–11 (B)1.11 × 10–3 (C) 3.33 × 10–6 (D) None of these
122. Calculate ∆G° for the following cell reaction Zn(s) + Ag2O(s) + H2O(l) → Zn2 (aq) + 2Ag(s) +
2OH–(aq) E0Ag = 0.80 V and E0Zn+2 / Zn = −0.76 V ,F = 96500. (Given :Ksp of AgOH = 2 × 10 )
–8
+
/ Ag
(A)– 305 kJ/mol (B) 212 kJ/mol (C) 305 kJ/mol (D) 301 kJ/mol
: www.atpstar.com
: 08107258987
123. The resistance of 0.01 N solution of an electrolyte was found to be 220 ohm at 298 K using a
conductivity cell with a cell constant of 0.88 cm–1. The value of equivalent conductivity of
solution is .
(A) 400 mho cm2 eq–1 (B) 295 mho cm2 eq–1
(C) 419 mho cm2 eq–1 (D) 425 mho cm2 eq–1
124. In a Cu-voltmeter, mass deposited in 30 s in ‘m’ g. If the time-current graph is shown in the
following figure :
200 mA
current
100 mA
10s 20s 30s

time
What is the electrochemical equivalent of Cu?
m m m m
(A) (B) (C) (D)
2 3 4 63.5
125. A current of 1.93 ampere is passed through 200 mL of 0.5 M Zinc sulphate (aq.) solution for
50 min. with a current efficiency of 80%. If volume of solution remain constant, then  Zn2+ 
after deposition of Zn2+.
(A) 0.38 M (B) 0.26 M (C) 0.35 M (D) 0.076 M
126. Ksp of Al(OH)3 = 10–35 and EoAl3 + / Al = – 1.66 V

Reduction potential of Al3+/Al couple at pH = 12 and 298 K is
(A) 1.07 V (B) 2.25 V (C) –1.07 V (D) –2.25 V
[Sn2 + ]
127. For a electrochemical cell, SN(s)|SN2+ (aq, 1M). the ratio || Pb2 (a q, 1M | Pb(s) when the
[Pb2 + ]
2.303
cell attains equilibrium is (Given E0Sn 2+
|Sn
=
−0.14V, EPb
0
2+
|Pb
=
−0.13V, =
0.06 ).
F
(A) 4.3 (B)1 (C) –2.15 (D)2.14
128. Which one of the following graphs between molar conductivity ( Λm ) versus C is correct?
NaCl
KCl
(A) Λm
NaCl
(B) Λm KCl
C C
KCl
(C) Λm (D) Λm
KCl
NaCl
NaCl
C C
: www.atpstar.com
: 08107258987
129. An example of a disproportionation reaction is
(A) 2MnO−4 + 10 I– + 16H+ → 2Mn2+ + 5I2 + 8H2O
(B) 2NaBr + Cl2 → 2NaCl + Br2
(C) 2KMnO4 → K2MnO4 + MnO2 + O2
(D) 2CuBr → CuBr2 + Cu
130. The anodic half-cell of lead-acid battery is recharged using electricity of 0.05 Faraday. The
amount of PbSO4 electrolysed in g during the process is (Molar mass of PbSO4 = 303 g mol–1)
(A) 11.4 (B) 7.6 (C) 15.2 (D) 22.8
SOLID STATE
131. One mole crystal of a metal halide of the type MX with molecular weight 119 g having face
centered cubic structure with unit cell length 6.58 Å was recrystallized. The density of the
recrystallized crystal was found to be 2.44 gcm–3. The type of defect introduced during the
recrystalization may be
(A) Additional M+ and X– ions at interstitial sites
(B) Schottky defect
(C) F-centre
(D) Frenkel defect
132. The arrangement of X- ions around A+ ion in solid AX is given in the figure (not drawn to
scale). If the radius of X- is 250 pm, the radius of A+ is
x–
+ +
OHA A
(A) 104 PM (B) 125 (C)183 PM (D) 57PM
133. The shortest distance between two Na+ ions in rock-salt arrangement having edge length
equal to a 2 picometers is-
a
(A) 2a (B) 2a 2 (C) (D) a
2
134. The crystal system of a compound with unit cell dimensions a = 0.387, b = 0.387 and
c = 0.504 nm and α = β= 90° and γ = 120° is
(A) Hexagonal (B) Cubic
(C) Rhombohedral (D)Orthorhombic
135. A solid is formed and it has three types of atoms X, Y and Z. X forms a fcc lattice with Y
atoms occupying all tetrahedral voids and Z atoms occupying half of octahedral voids.
The formula of solid is
(A) X4YZ2 (B) X4Y2Z (C)XY2Z4 (D) X2Y4Z
: www.atpstar.com
: 08107258987
136. CsBr has bcc structure with edge length 4.3 Å. The shortest inter ionic distance in between
Cs+ and Br– is -
(A) 4.3 Å (B) 7.44 Å (C) 1.86 Å (D) 3.72 Å
137. If the unit cell of a mineral has cubic close packed (ccp) array of oxygen atoms with m fraction
of octahedral holes occupied by aluminium ions and n fraction of tetrahedral holes occupied
bymagnesium ions, m and n, respectively, are
1 1 1 1 1 1 1
(A) , (B) 1, (C) , (D) ,
2 8 4 2 2 4 8
138. The density of KBr is 2.75 g cm–3, length of the unit cell is 654 pm. K = 39, Br = 80, then what
can be true about the predicted nature of the solid ? (Given: NA = 6.023 × 1023)
(A)Solid has face centred cubic system with co-ordination number = 6
(B)Solid has simple cubic system with co-ordination number = 8
(C)Solid has face centred cubic system with co-ordination number =12
(D)None of the above
139. A crystalline solid of a pure substance has a face-centred cubic structure with a cell edge of
400 pm. If the density of the substance in the crystal is 8 g cm–3 then the number of atoms
present in 256 g of the crystal is N x 1024. The value of N is
140. CsCl crystallises in body centred cubic lattice. If ‘a’ is its edge length then which of the
following expressions is correct?
3a
(A) rCs− + rCl− = 3a (B) rCs− + rCl− =
2
3
(C) rCs− + rCl− = a (D) rCs− + rCl− = − 3a
2
141. In a binary compound, atoms of element A form a hcp structure and those of element M
occupy 2/3 of the tetrahedral voids of the hcp structure. The formula of the binary compound
is :
(A) M2A3 (B) M4A3 (C) M4A (D) MA3
142. A hard substance melts at high temperature and is an insulator in both solid and in molten
state. This solid is most likely to be a / an :
(A) Ionic acid (B) Molecular solid (C) Metallic solid (D) Covalent solid
SURFACE CHEMISTRY
143. 10 mL of 1 mM surfactant solution forms a monolayer covering 0. 24 cm2 on a polar substrate.

If the polar head is approximated as cube, what is its edge length?
(A) 2.0 pm (B) 2.0 nm (C) 1.0 pm (D) 0.1 nm
144. The coagulation values in millimoles per litre of the electrolytes used for coagulation of As2S2
are given below.
I. NaCl = 52 II. BaCl2 = 0.69 III. MgSO4 = 0.22]
The correct order of their coagulation is:
(A) III > I > II (B) I > II > III (C) II > I > III (D) III > II > I
: www.atpstar.com
: 08107258987
145. Which of the following statements about physical adsorption is not correct?
(A) It is usually monolayer
(B) It is reversible in nature
(C) It involves van der Waals interactions between adsorbent and adsorbate
(D) It involves small value of adsorption
146. The plots of the extent of adsorption (x/m) Vs pressure at different temperature are as follows;
T1
IV T2
X/m
T3
T4
PA(cm of hg)
The correct order of increasing temp for curves I, II, III, IV are :
(A) T1> T2> T3> T4 (B) T4> T3> T2> T1
(C) T3> T2> T1> T4 (D) can't be predicted
147. Among the following, the surface that will form micelles in aqueous solution at the lowest
molar concentration at ambient condition is:
(A) CH3(CH2)15 N+(CH3)3 Br– (B) CH3(CH3)11 OSO3– Na+
(C) CH3 (CH2)= COO– Na+ (D)CH3(CH2) 11N+(CH3)3Br–
148. Which of the following statements is correct for a lyophilic sol?

(A) It is not easily solvated
(B) The coagulation of this sol is irreversidble in nature
(C) It is unstable
(D) It is quite stable in a solvent
149. For coagulation of Arsenioussulphide sol, which one of the following salt solution will be most
effective
(A) AICI3 (B) NaCI (C) BaCI2 (D) Na3P04
150. As2S3 and TiO2sol example of

(A) Negativity charge sols
(B) Positively charged sols
(C) Positively and negatively charged sols respectively
(D) Negatively and positively charged sols respectively.
: www.atpstar.com
: 08107258987
151. In Freundlich adsorption isotherm, slope of AB line is :
A
x
log
m
log P
(A) log n with (n > 1) (B) n with (n, 0.1 to 0.5)

1 1 1 
(C) log with (n < 1) (D) with  = 0 to 1
n n n 
152. Most suitable salt which can be used for efficient clotting of blood will be :-
(A) NaHCO3 (B) FeSO4 (C) Mg(HCO3)2 (D) FeCl3
x
153. In Freundlich adsorption isotherm at moderate pressure, the extent of adsorption   directly
m
proportional to Px. The value of x is
1
(A) zero (B) (C) 1 (D) ∞
n
154. Which one of the following statements is FALSE for hydrophilic sols ?
(A) Their viscosity is of the order of that of H2O.
(B) The sols cannot be easily coagulated.
(C) They do not require electrolytes for stability.
(D) These sols are reversible in nature.
155. The nature of charge on resulting colloidal particles when FeCl3 is added to excess of hot
water is :
(A) Positive (B) Sometimes positive and sometimes negative
(C) Neutral (D) Negative
: www.atpstar.com
: 08107258987
SOLUTION & ANSWER KEY
1. (A)
1.22
Sol. Mole of BaSO4 =
233.3
1.22 1
Moles of M2 ( SO
= 4 )3 =
× 1.743 × 10 −3
233.3 3
Wt. of M2 ( SO4 )3 = 0.596
∴1.743 × 10−3 (2M + 96 × 3) = 0.596 = M = 26.9
2. (C)
Sol. CaCO3(s) → CaO(s) + CO2(g)
105 × 95
mass = × 56 gm = 53.2 kg
100 × 100
3. (C)
Sol. CaCO3 → CaO + CO2
Let the % purity is x
500 × x
Mol : mol
100 × 100
500 × x
× 56 =
70
100 × 100
X = 25
% Impurities = 100 – 25 = 75%
4. [B]
Sol. Let the number of moles of NaHCO3 is x.
x x
Wt. loss = × 44 + × 18
2 2
x
× 62
% Weight loss = 2 × 100 =
36.9%
x × 84
5. [C]
PV 1× 492
Sol. Moles of NaClO3 = moles of O2, moles of =
O2 = = 20 moles
RT 0.082 × 300
As molecular of NaClO3 = 106.5
NaClO3 = 20 × 106.5 = 2130 g
6. (C)
Sol. 2SO2 (g) + O2 (g) → 2SO3 (g)
initial volume: 5 3 0
volumeafterrxn: 0 (3 – 2.5) 5
= 0.5
Total volume of reaction mixture
= 0.5 + 5 = 5.5 L
: www.atpstar.com
: 08107258987
7. (C)
100(0.3 − 0.125)60
Sol. Mass adsorbed = = 1.05g
1000
(0.3 − 0.125)6
Mass adsorbed per gram of charcoal = = 1.3125
0.8
8. (B)
nCH mCH4 (MC2H6 )
=
Sol. 4
= 3:2
nC2H6 (mCH4 )(MCH4 )
9. [C]
Sol. 4NH3 (g)+ 5O2 (g) → 4NO(g)+ 6H2 O(g) (l)
4 moles 5 moles 4 moles 46moles
 4 moles of NH3 ≅ 5 moles of O2

5
1 moles of NH3 ≅ moles of O2 ≅ 1.25 moles of O2
4
Thus, all volume of oxygen will be consumed.
10. [C]
Sol. Ti + O2 
→ Ti1.44O
(1.44 g) ( x )g
Apply POAC to Ti
 1.44g   xg 
 48  × 1 =
× +
1.44
   (1.44 48) 16 
48 × 1.44 + 16 16
x= = 1.44 + = 1.44 + 0.33 = 1.77 g
48 48
11. (B)
Sol. Given,
Average molar mass of chlorine is 35.5 g mol–1.
Naturally occurring chorine are
35 37
Cl Cl
Mass ratio x 1–x
Total molar ratio = x + 1 – x = 1
Mass average = 35 × x + 37 × (1 – x)
35.5 = 35x + 37 – 37x
1.5 3
2x = 37 – 35.5; x = = 0.75 =
2 4
35 3
For Cl , x =
4
37 3
For Cl , 1 –
4
35 37
Cl ; Cl
3  3 3 1
;  1–  ⇒ :
4  4 4 4
On simplify this ratio, we get 3 : 1
: www.atpstar.com
: 08107258987
12. (A)
Sol. NH 2CONH2 + 2 NaOH → 2 NH3 + Na2CO3
(M=60)
No. of moles of urea = Given mass / molar mass

0.6
= = 0.1 mol NH2CONH2
60
∴ It gives 0.02 mol NH3 as per the equation.
To neutralize it, 0.02 equivalents of HCl needed.
As we know, no. of equivalents of HCl = Normally × Volume
13. (A)
The oxidation of a mixture of one mole of each of
FeC2O4, Fe2(C2O4)3FeSO4 and
Fe2(SO4)3 in acidic medium with KMnO4 is as follows
FeC2O4 + KMnO4 → Fe3++CO2 + Mn2+ …… (i)
Fe2(C2O4)3 + KMnO4 → Fe3++CO2 + Mn2+ …… (ii)
FeSO4+ KMnO4 → Fe3++ SO2-4 + Mn2+ …… (iii)
Change in oxidation number of Mn is 5. Change in oxidation number of Fe in (i), (ii) and (iii)
are +3,+6,+1, respectively
neqKMnO4 = neq[FeC2O4 + Fe2(C2O4)3 + FeSO4]
n×5 = 1×3+1×6+1×1
n=2
14. (A) 15. (B) 16. (C) 17. (B) 18. (C)
19. (D) 20. (B) 21. (A) 22. (B) 23. [A]
24. (C)
Sol. According to Bohr’s theory :
z 2 eV z2
(A) KE = 13.6 ⇒ KE α
n2 atom n2
z
(B) speed of e– α
n
∴ v ×nα z
v
(C) Frequency of revolution of e − =
2πr
z2
∴ frequency α
n3
kq1q2 kze2  n2 z z3
=
(D) F = rα ⇒ Fα ⇒ Fα
r2 r2  z  n2 
2
n4
 
 z 
: www.atpstar.com
: 08107258987
25. (C)
Sol. Number of radial nodes = n – – 1
=3–0–1=2
Therefore corresponding graph is (D)
Hence answer is (C)
26. (C)
Sol. Quantum nature of atoms are associated with following phenomena or process :
(i) Absorption spectrum
(ii) Emission spectrum
(iii) Black body radiation
(iv) Photo-electricity
Internal energy (U) of particles like atoms depends upon the thermodynamics variables (p, V,
T) of the system. Thus, U = f(p, T)
or U = f1(TV)
or U = f2(p, V)
So, quantum nature of atom is not associated with its internal energy.
Graph (C) is not a direct manifestation of the quantum nature of atoms.
27. (A)
Sol. (A) CH3 – CH2 – Cl
R.S. = 0
(B) CH2 = CH – Cl
R.S = 2
(C) C6 H5 – Cl
R.S. = 4
1
R.S . ∝
Bond length of sin gle bond
28. (D)
Sol. [H+] = 10–3 M [pH = 3 = –log[H+] = 10–3 moles per litre
[Ca2+] = 5 × 10–4 moles of per litre = 5 × 10–1 moles of Ca2+ per 103 L = 5 × 10–1 × 40 g Ca2+
per 106 g of H2O
Ca2+ = 20 ppm = (H).
29. (D)
Sol. Let the atomic weight of X = y
No. of equivalents of KOH = No. of equivalents of H2XO4
0.12544
i.e.= = 0.12544
66 + y
2
∴ y = 32
: www.atpstar.com
: 08107258987
30. (A)
Sol. Fe2(C2O4)3 → 2Fe3+ + 6CO2 + 6e– (n Factor = 6)
Fe(C2O4) → Fe3+ + 2CO2 + 3e– (n Factor = 3)
Meqs of [Fe2(C2O4)3 + Fe(C2O4)] = 0.5 × 6 + 0.5 × 3
= 4.5 Eqs.
= 4.5 Eqs. of KMnO4
4 .5
= = 0.9 moles of KMnO4
5
31. (A)
Sol. It is a fact that a redox reaction always involves change in oxidation number.
32. (A)
+2 +6
−
Sol. S2 O32− + MnO4 + H2O → MnO2(s) + S O24− + OH–
'n' factor of Na2S2O3 = 8
'n' factor of KMnO4 = 3
0.158
m.eq of Na2S2O3 = m.eq of KMnO4 × 8 × 1000 = 0.1 ×V × 3
158
V = 26.7 mL
33. (A)
Sol. If x mL is with phenolphthalein the rxn occurring is
Na2CO3 + HCl → NaHCO3 + NaCl
Sol the volume of HCI for complete reaction of Na2CO3 would be double of 'x' because the
reaction will be
Na2CO3 + 2HCl → Na2CO3 + 2NaCl
So, 2x
34. (B)
Sol. (i) The half reaction for oxidation is, H2C2O4→ 2CO2
Balancing carbon atoms on both sides, H2C2O4→ 2CO2
Balancing hydrogen atoms on both sides, H2C2O4→ 2CO2 + 2H+
Balancing the charge on both sides, H2C2O4→ 2CO2 + 2H+ + 2e– ....(i)
(ii) The half reaction for reduction is H2O2→ H2O
Balancing oxygen atoms on both sides, H2O2→ 2H2O
Balancing hydrogen atoms, H2O2 + 2H+→ 2H2O
Balancing eh charge, H2O2 + 2H+ + e–→ 2H2O .......(ii)
Now, adding both equation,
H2C2O4 + H2O2→ 2CO2 + 2H2O
This is balanced equation so x, y, z are 1, 2, 2 respectively.
35. (D)
Sol. H2O2 acts as an oxidizing agent in both acidic and alkaline medium.
: www.atpstar.com
: 08107258987
36. (A)
Sol. H2O2 + 2l− + 2H+ → Ι2 ……(i)
Bleach 0.5M (from CH3 COOH)
30 ml 4N(10 ml)
25 ml
+ 2H2O
Ι 2 + 2Na2S2O3 → Na2S 4O6 + 2Nal …….(ii)
0.25 N( 48 ml)
1
m. mol of Ι 2 = (m. mole of Na2S2O3)
2
1
= × (0.25 × 48) =
6 m.mol
2
Using equation (i)
1m. mol of Ι2≡ 1m.Mol of H2O2
m. mol of H2O2 = 6 m. mol
6
Molarity of H2O2 = = 0.24M
25
37. (C)
Sol. (A) HOCl + H2O2  → H3O+ + Cl– + O2
In this equation, H2O2 is reducing chlorine from +1 to –1.
(B) I2 + H2O2 + 2OH–  → 2I– + 2H2O + O2
In this equation, H2O2 is reducing iodine from 0 to –1.
In (A) reduction of HOCl occurs so it will be a oxidising agent hence H2O2 will be a reducing
agent.
In(B) reduction of I2 occurs so it will be a oxidising agent and H2O2 will be a reducing agent.
38. (B)
Sol. I– is oxidised to I2 by H2O2. Hence answer is (B)
39. (C)
Sol. NaCl is a strong electrolyte, whereas BaSO4 is a sparingly soluble (weaker) electrolyte. So,
even in saturated solution, NaCl will almost remain in dissociated form to give free Na+ and
Cl–. But availability of Ba2+ and SO24− in water will be very poor. But degree of dissociation of
BaSO4 will increase with a temperature to give more ions.
BaSO4(s)  Ba2+(aq) + SO24+ (aq)
Again, with increase in temperature ionic mobility alos increases. So options (A), (B) and (D)
are true but (C) is false.
Solubility of NaCl in water remains almost constant with increase in temperature. So, option ©
is false.
Solubility
NaCl
Temperature (ºC)
(Solubility curve)
: www.atpstar.com
: 08107258987
40. (B)
Sol. 60 minutes = 3 half lives
∴ T1 = 20 min
2
ln 2 ln 2
λ
∴= = per min
t1/ 2 20
41. (A)
1− n
 T1 / 2   C1 
Sol.  = 
 T1 / 2   C2 
1− n
 350   80 
⇒ = 
 175   40 
= 2 = (b)1 – n ⇒ 1 – n = 1 ⇒ n = 0
42. (A)
n –1
1
Sol. t1 ∝   for nth order reaction
2 a
t 1 = k(a)1– n
2
log t 1 = (1 – n) loga + logk

2
Thus, graph between log t 1 and log a is linear slope

2
(1 – n) = tan45º
n–0
43. (C)
−2β −α
Sol. 90 Th 234  → 92 X 234 → 90 Th
230
Elimination of 1α and 2β particles give isotope.
44. (C)
–Ea
Sol. k = Ae RT
For methyl nitrite k1 = 1013e[–152300/(8.314 × T)]

For ethyl nitrite k2 = 1014e[–157700/(8.314 × T)]
If k1 = k2 then
1013e[–152300/(8.314 × T)] =1014 e[–157700/(8.314 × T)]
157700 – 152300
Or 2.303 log 10 =
8.314 × T
T = 282 K
: www.atpstar.com
: 08107258987
45. (C)
Sol.
A0
[B]
Conc.
Time
A →nB
At t = 0 A0 –
At t = t A0–x nx
According to question, at presentation point
⇒ A0 – x = nx
⇒ A0 = (n + 1)x
A0
⇒x =
n +1
 n × A0 
[B] = nx =  
 n +1 
46. (C)
Sol. t 1 ∝ a1−n
2
1−n
t1  α1 
= 
t2  α2 
1−n
4  50 
=
2  100 
n=2
Therefore, the order of reaction is 2.
47. (D)
1
Sol. H2O2 → H2O + O2
2
d [H2O2 ] d [H2O] d [O2 ]
− = =2
dt dt dt
t1/2
0.5 0.25 0.125
t3/4 = 50 minute
t 1 = 25
2
0.69314
t1 =
2
k
0.69314
k=
25
: www.atpstar.com
: 08107258987
rate of reaction = k [H2O2 ]
d [O2 ]
1
∴ = × k H 2O2 
dt 2
1 0.69314
= × = 6.93 × 10 –4 molmin–1
× 0.05
2 25
48. (D)
Sol. For A:
a
8a →
10
→
10
→
10
→
10
→
10
→
10
→
10
→
10
32
For B:
a
a →
20
→
20
→
20
→
20
16
49. (B)
Sol. A(g) → 3B(g) + C(g)
at t = 0 200 torr – –
at t = t 200 – p 3p p
p = 150 torr
1 200 1× 2.303 × log 4
t= × 2.303 × log = = 300 sec
k 200 – p 4.606 × 10 –3
50. (A)
Sol. Here, same metal ion, Mn+ from three homoleptic octahedral complexes (i), (ii) and (iii) on
Θ Θ
separate combination with three mono-dentate ligands- NCS,F and NH3 respectively.
So we have to compare their CFSE(∆0) as well as wavelength (λ) values, where
hc 1
∆E(CFSE) = or, ∆0 ∝
λ λ
Again, ∆0 value will depend on power of lignad as placed in spectrochemical series.
1
Power of ligand ∝ ∆0 ∝ , F– < NCS– < NH3, F > NCS > NH3
λ
→ Power of Ligand ←λ
→ ∆0
So, for the given complexes, it is evidented from the plot (Absorption vs λ)
(ii) (i) (iii)
λmax > λmax > λmax
(C) (B) (A)
[F− ] [NCS− ] [NH3 ]
51. (C)
Sol. On adsorption (both physical and chemical), the residual force acting along the surface of
absorbent decreases. So, ∆H of the adsorption becomes less negative as adsorption
proceeds. So, statement (A) is correct but statement (C) is incorrect. Ammonia molecules
(NH3) is larger in size and dipolar in nature. Nitrogen is smaller in size and it is a non-polar
molecule. So, degree of adsorption : NH3 > N2. So, Statement (B) is correct. With increase in
temperature, kinetic energy of adsorbate molecules will increase and hence, its equilibrium
concentration will decreases. So, statement (D) is not correct.
: www.atpstar.com
: 08107258987
52. (B)
Sol. Only statement (B) is true whereas all other statements are incorrect. A zero order reaction is
a multistep reaction because in most of the zero order reactions, free radical is the
intermediate which follow chain-initiation, chain-propagation and chain-termination like steps,
e.g., free radical substitution reaction.
(A) A second order reaction is always a single step reaction, e.g., SN2 and E2 reactions.
(C) A first order reaction may be a multi-step reaction when intermediate of the reaction, like
carbocation (l1) gets rearranged into its most stable form (l2).
Same is the case with (D).
So, options (A), (C) and (D) are not true .
53. (B)
 w 1 
Exp.=
∆Tb K b  solute ×  × 1000
 Wsolvent M solute 
1000 × 10
1= ⇒ M AB2 =
100
100 × M AB2
Similarly
100 + MA + 2 ⋅ MB
and 140 = 2 ⋅ MA + MB;
MA = 60 and MB = 20
Alternative solution
∆Tb 10
= 1=
Kb M A + 2M B
0.1
MA + 2MB = 100 ...(1)
∆Tb 14
= 1=
Kb 2M A + MB
0.1
2MA + MB = 140 ...(2)
MA = 60, MB = 20
54.(B)
Boiling point (Tb) = 100 + ∆Tb = 100 + Kbm
Exp.
Freezing point (Tf) = 0 – ∆Tf = kfm
Tb – Tf = (100 + kbm) – (– kfm)
105 = 100 + 0.51 m + 1.86 m
5
2.37 m = 5 or= m = 2.11
2.37
∴ Weight of sucrose to be dissolved in 100 g water
2.11× 342
= ×=
100 72.2g
1000
: www.atpstar.com
: 08107258987
55. [A]
Wsolutes
p0 − pS Msolutes
Sol. = x solutes =
p0 Wsolutes Wsolvent
+
Msolutes Msolvent
p0 − pS w A mB
= × (A stands for solute and B for solvent)
p0 mA WB
75
x − x×
100 w 18
= ×
75 60 100
x×
100
[Let the vapour pressure of pure water P0 = x]
0.25x w 18
= ×
0.75x 60 100
∴ w = 111.118
111.11 1000
Molality = × =
18.52
60 100
56. (A)
Sol. Isotonic solution have same osmotic pressure
=
π1 C1RT,=
π2 C2RT
For isotonic solution, π1 = π2
 5.25 / M   1.5 / 60 
=π  ×=
10  RT  × 10  RT
 100   100 
5.25 1.5
=
M 60
60 × 5.25
=M = 210 g / mole
1.5
57. (D)
Sol. P2 = KHX2 where P2→ partial presence of gas
X2→mole fraction of gas in solution
KH = Henry's law constant
So, P ∝ solubility
p1 s1 500 750
= ⇒ =
p2 s2 0.01 x
∴ x = 0.01 5 g/L
58. (D)
Sol. X2 Y2 ( aq) → 2X3+ ( aq) + 3Y 2− ( aq)
n=5
∆Tb = i Kb .m = 11 (1+4α) Kbm
= (1 + 4 × 0.75) × 0.52 × 2
= 4.16; Tb = 373 + 4.16 = 374.76
: www.atpstar.com
: 08107258987
59. (B)
P0 − Ps n
Sol. =
Ps N
10 − 5 9 × 200
=
5 M × 20
M = 90 amu
60. (A)
Sol. K2Hgl4→ 2K+ +HgI42+
⇒ i = 1 + (n – 1) a
⇒ i = 1 + (0.55) (3.1) ( n = 3)
∴ I = 21
61. (B)
Sol. The two solution should have same molar concentration for being isotonic.
Molar concentration of cabe sugar = Molar
6
Concentration of urea = = 0.1 mol/L
60
Concentration of cane sugar in g/L
= molar concentration × molecular weight
= 0.1 × 342 = 34.2
62. (A)
Sol. As when temperature increase, vapour pressure increases so C and D options get rejected.
∆Tf = Kf × m
34.5
273 – Tf = 2 × 46
'
0.5
So, Tf' = 270 K
63. (A)
Sol. When a raw mango is kept in a concentrated salt solution, the mango will shrink because of
exo-osmosis. Mango cell membrane acts as semi-permeable membrane and its cell
cytoplasm is considered as a solution of concentration, C1M (say). Let the concentration of
salt solution is C2M, where C1 < C2 (mentioned).
So, osmotic pressure developed at salt solution, π2 will be greater than that at cell cytoplasm,
π1 at a given temperature.
π1 = C1RT and π2 = C2RT
So, solvent molecules (water) will flow out from mango cells to salt solution resulting shrinking
of mango. This state is also known as plasmolysis.
: www.atpstar.com
: 08107258987
64. (D)
Sol. An acidic buffer is a mixture of weak and its salt with strong base. Now, let us study the
composition of each mixture obtained by mixing of two solutions.
+
(A) CH3COOH + NaOH → CH3COONa + H2O
t =0 100 × 0.1 100 × 0.1 0 0
milimol
t=a 0 0 10 10
So, it is not a buffer.
NaCl, a salt of strong acid (HCl) and strong base (NaOH) is not hydrolysable by HCl also. So,
it is not a buffer.
+
CH3COOH + NaOH → CH3COONa + H2O
t=0 100 × 0.1 200 × 0.1 0 0
(Limiting)
milimol
= t a 0= 20 − 10 10 10 10
After mixing, the solution contains equimolar amounts by NaOH(a strong base) and
+
CH3COONa (salt). So, it is also not a buffer.
+
CH3COONa + HCl → + CH3COOH + NaO
t =0 200 × 0.1 100 × 0.1 0 0
(Limiting)
milimol
= t a 20 − 10
= 10 0 10 10
Now, the resultant solution contains equimolar amount of CH3COOH (an week acid) and
CH3COONa (a salt of CH3COOH with strong base, NaOH).
So, it is an acid buffer.
65. (C)
Sol. In first component,
Mass = number of mole × molecular weight = n1M1
In second component, Mass = n2M2
Mass of solution = n1M1 + n2M2 ……….(i)
n2
Mole-fraction (χ2) =
n1 + n2
n (1 + χ2 )
∴ n1 = 2 ……….(ii)
χ2
Place the value of n1 in eq. (i)
n2 (1 + χ2 )M1
∴ = n1 + n2M2
χ2
n2
⇒ (M2χ2 – M1χ2 + M1)
χ2
Volume of solution,
n (M χ − M1χ2 + M1 )
= 2 2 2 L
1000 × d × χ2
1000 × n2 × dχ2
C2 =
n2 (M2 χ2 − M1χ2 + M1 )
1000dχ2
∴ C2 =
M1 + χ2 (M2 − M1 )
Hence, the correct option is (3).
: www.atpstar.com
: 08107258987
66. (B)
Sol. AgIO3(s)  + −
 Ag (aq) + IO3 (aq)
Let the solubility of AgIO3 be S
Ksp = [Ag+] IO3− 
1.0 × 10–8 = S2 or S = 1 × 10–4 mol/L
In 1000 mL moles of AgIO3 dissolved
= 1 × 10–4 moles
In 100 mL moles of AgIO3 dissolved
= 1 × 10–5 moles
Mass of AgIO3 in 100 mL
= 1 × 10–5 mol × 283 g mol–1 = 2.83 × 10–3 g
67. (C)
Sol. The overall dissociation constant of the acid is
K = K1 × K2 = 1.0 × 10–5 × 5.0 × 10–10 = 5 × 10–15
68. (A)
Sol. Equilibrium constant for the reaction,
1
SO2(g) + 
O2(g)  SO3(g)
2
1
Kc =
4.9 × 10 −2

and for 2SO2(g) + O2(g)  2SO3(g)
2
 1  10 4
Kc =  −2 
=
 4.9 × 10  (4.9)2
= 416.490 ≈ 416
69. (A)
Sol. 
PCl5(g)   PCl3(g) + Cl2(g)
Initially 1 0 0
At equilibrium (1 – x) x x
Total number of moles at equilibrium
= (1 – x) + x + x = 1 + x
 x 
pPCl3 =  p
1 + x 
70. (A)
Sol. 
NH4HS(s)   NH3(g) + H2S(g)
Initially 1 0.5 0
At equilibrium (1 – x) (0.5 + x) x
Total pressure at equilibrium
= pNH3 + pH2S
= 0.5 + x + x = 0.84
∴ x = 0.17 atm
∴ pNH3 = 0.50 + 0.17 = 0.67 atm
pH2S = 0.17 atm
∴ Kp = pNH3 ⋅ pH2S
= 0.67 × 0.17 = 0.114 atm
: www.atpstar.com
: 08107258987
71. (D)
Sol. 2NO2(g)  2NO(g) + O2(g)
Kc = 1.8 × 10–6 at 184°C (= 457 K)
R = 0.00831 kJ mol–1 K–1
Kp = Kc (RT )
∆ng
where,
∆ng = (gaseous products – gaseous reactants)
=3–2=1
∴ Kp = 1.8 × 10–6 × 0.00831 × 457
= 6.836 × 10–6 > 1.8 × 10–6
Thus, Kp > Kc.
72. (A)
Sol. Reaction is exothermic. By Le–Chatelier principle, a reaction is spontaneous in forward side
(in the direction of formation of more ClF3). If F2 is added, temperature is lowered and ClF3 is
removed.
73. (A)
Sol. conjugate base is formed by loss of H+
OH– → O2 + H+
Conjugate
base
O2– is the conjugate base of OH–.
74. (C)
Sol. MX2  2+
 M + 2X
–
S 2S
Ksp = [M ] [X–]2
2+
If solubility be S, then
Ksp = (S) (2S)2 = 4S3
4S3 = 4 × 10–12
∴ S = 1 × 10–4 M
∴ [M2+] = S = 1 × 10–4 M
75. (C)
Sol.
Dng = – ve ∆H° = – ve
Takes place with decrease Takes place with evolution of
in number of moles heat of increase in
of pressure, hence temperature, hence
increase in pressure decrease in temperature
shifts equilibrium in shifts this equilibrium in
forward side. forward side.
: www.atpstar.com
: 08107258987
76. (A)
Sol. Fro the equilibrium, A  B
At equilibrium, ra rb
Equilibrium is the condition when a forward chemical reaction and its reverse reaction proceed
at equal rates. It can be illustrated by following graph.
Rate of reaction
a
Equilibrium
b
Time
77. (C)
 

 [B][C]
 B + C;K eq =
(1)
Sol. A  

[A]
 

 [P]
B + C   P;K eq =


(2)
[B][C]
Equilibrium equation (i) and (ii)
[P]
(eq) × K (eq) =
K (1) =K eq
(2)
[A]
78. (B)
Sol. N2O4(s)  2NO2(s) ; DHº = + 58 kJ
Because in case of an endothermic reaction (∆H = + ve), the equilibrium constant increases
with rise in temperature and hence, the reaction moves in forward direction. On adding N2,
pressure is increases at constant T, and volume would also be constant, so no change is
observed.
79. [C]
Sol. When BaSO4 begins to precipitate
K sp [BaSO4 ] 1.0 × 10 −10
[SO24− ]
= = = 5.0 × 10–9M
[Ba2+ ] 0.020
When PbSO4 begins to precipitate
K sp [PbSO4 ] 1.6 × 10 −8
[SO24− ]
= = 2+
= 8.0 × 10–7 M
[Pb ] 0.020
[SO42–] is less for BaSO4 precipitation
So BaSO4precipitates first when PbSO4 begins to precipitate
[SO42–] = 8.0 × 10–7M at that point concentration of
2+
K sp [BaSO4 ] 1.0 × 10 −10
=
Ba 2−
= = −7
1.25 × 10 −4 M
[SO4 ] 8.0 × 10
80. (C)
Sol. K a ∝ ca2
K a1 a12 42 16
∴ = = =
K a2 a22 g2 81
: www.atpstar.com
: 08107258987
81. [D]
Sol. Sodium acetate and sodium propionate are not conjugate acid base pairs
82. (A)
Sol. Calcium acetate is a salt of weak acid and weak base.
0.005 M calcium acetate, (CH3COO)2Ca
(CH3COO)2Ca → Ca2+ + 2CH3COO–
0.005 M (2 × 0.005 = 0.01)
∴ [CH3COO ] = 0.01M
–
−
CH3COO– + H2O    CH3COOH + OH Alkaline
pK a logC
pH = 7 + +
2 2
log0.01
= 7 + 2.37 +
2
= 7 + 2.37 – 2.30 = 7.06
83. (B)
Sol. pkb of CN– = 4.7
pka of HCN = 4.7
NaCN is salt of weak acid (HCN) and strong base (NaOH) so
1 1
pH = 7 + pka + logC
2 2
1 1
=7+ x 9.3 + log(0.5)
2 2
∴ pH = 11.5
84. (A)
Sol. pH change = pH of 75 % blue 75% red
75
= [pKa + loglog ]
25
25
= [pKa + loglog ]
75
= log3 + log3
pH = 0.954
85. (D)
Sol. Methyl orange is weak organic base. It is used in the titration of weak base vs strong acid.
MeOH  


 Me+ + OH-
Unionized form Ionized form
(Yellow) (Red)
In basic medium, equilibrium lies in backward direction and therefore it shows yellow colour.
In acidic medlum, equilibrium shifts in forward direction and therefore, colour changes from
yellow to red.
: www.atpstar.com
: 08107258987
86. [B]
Sol. HCI: Strong acid (low pH)
NH4CI : Salt of weak base + strong acid→ it gives acidic solution. (pH less than 7)
NaCl: Salt of strong base + strong base → it gives neutral solution with pH = 7.
NaCl: Salt of strong base + weak acid → it gives basic solution with pH > 7.
Thus the increasing order of pH is HCI < NH4CI <NaCl<NaCN
87. [C]
Sol. NaOH + CH3COOH → CH3COONa + H2O
2 6
m mol LR
– 4 2
The resulting solution is an acidic buffer.
[Salt]
so pH = pKa + log
[Acid]
2
= 4.71 + log
4
= 4.44
88. (C)
Sol.
NaOH
HCl
nOH− nacid [HCl] VHCl

OH
=−
 = = = 0.21 M < 0.220
  V – V V
OH NaOH NaOH
89. (B)
K sp s2 K sp +
Sol. = +
; s= (H )
Ka (H ) Ka
2.2 × 10 −16
=s −10
× 10−3
6.2 × 10
s = 1.9 × 10–5
Hence answer is (B)
90. (C)
Sol. Ca(OH)2 Ca2+(aq) + 2OH–(aq)
s 2s
ksp = s(2s) ⇒ 5.5 × 10 = 4S
2 –6 3
1
 5.5  3 −2
=
⇒ s   × 10 = 1.11 × 10
–2
 4 
: www.atpstar.com
: 08107258987
91. (B)
Sol. Among the given options, distilled water has the lowest ionic conductance at 298 K.
Water from well or sea contains mineral ions,
∴ they have ionic conductance.
Saline water is an electrolyte and contain ions
∴ It also has ionic conductance.
92. (D)
N 2 + 3H 2  → 2NH 3
Initial mole 1 4 0
Exp.
Re acted mole 1 3
Left mod e 0 4−3= 1 2
H2 Left = 1 mole
NH3 formed = 2 mol
But NH3 (g) dissolves in water forming NH4 OH. Residual gas only H2 which exerts pressure.
Volume = 15 – 5 = 10 L (5L occupied by H2O added)
n 1 × 0.821 × 300
∴ p = RT atm
V 10
93. (A)
 a 
Sol. P = Pcπ =  2 
π
 27b 
V – Vcφ = (3b)φ
 8a 
T = T cθ =  θ
 27Rb 
Hence substituting in the van der Waal’s equation
 a 
 P + 2  (V – b) = RT
 v 
 3
⇒  π + 2  (3φ – 1) = 8θ
 φ 
This is reduced state equation
 3   3φ 1  π 1  8
 π + 2  –  = 1 ⇒  + 2  (3φ – 1) = θ
 φ   8θ 8θ  3 φ  3
94. (C)
Exp.
24.6
PV(litre-atm mol–1)
[Graph not to scale]

23.1
21.6
θ
20.1
0 2.0 3.0
1
(mol littre–1)
V
van der Waals equation for 1 mol of real gas is

: www.atpstar.com
: 08107258987
 a 
P + v2  [ V − b] =
RT
 
Given that b = 0
 a 
∴P +  [V – b] =
RT
 V2 
a
∴ PV = RT – .....(i)
V
1
Following y = mx + c for the curve PV vs
v
Slope = –a
21.6 – 20.1
=
Slope = 1.5
2–3
∴ a = 1.5
95. (C)
Sol. 2NH3(g)→ N2(g) + 3H2
76–2x
76 + 2x = 76 + 18
2x = 18
∴ x=9
∴ p H2 = 3 × 9
= 27 cm of Hg
96. (B)
4
Sol. b= 4 × × πr 3 × N A ;
3
we know that,1L = 1000cm3
4
4 × π × 10 −4 × 1000= 4 × × π × r 3 × 6 × 1023
3
r = 5 × 10–9 cm
97. (D)
Sol. According to Graham's law of effusion.
1
r∝
M
rmix MSO2
=
rso2 Mmix
64
⇒ 2.56 =
Mmix
⇒ Mmixture =25
Let mole fraction of F2 is x. Therefore, mole fraction of F will be (1– x)
38 × x + (1 − x ) × 19
25 =
1
P2 (0.685P)2
x = 0.315 ; ⇒ Kp = F =  1.49 atm
PF2 (0.315P)
: www.atpstar.com
: 08107258987
98. (B)
Sol. According to Avogadro hypothesis
V∝n
(RT)
V =n
P
RT
Proportionality constant =
P
Using PV = nRT
RT V 2.463
∴ = =
P n 1
99. (D)
3th 5
Sol. If of the air is expelled out then remaining air =
8 8
In the open vessel volume and pressure are both constant but moles are decreasing
∴ n1T1 = n2T2
5 
∴ n1 × 300 =  n1  T2
8 
8 8
∴ T2 = × T1 = × 300 = 480 K
5 5
= 480 – 273 = 207ºC
100. (D)
Sol. As per Boyles law
PV = constant
P  1 
= cons tan t  2 
V V 
logP = – log V + log(constant)
101. (D)
Sol. Let P0 be the value at atmospheric pressure
(I) (II)
h
1
1
h
In case I:
Pgas + hcm of Hg = P0cm of Hg
In case ii Pgas = P0cm of Hg + hcm of Hg
: www.atpstar.com
: 08107258987
By applying Boyle's law between (I) & (II)
(P0 – h)× l1 = (P0 + h) × I2
orP011 – h11 = P012 + h12
orP0(11 – 12) = h(11 + 12)
h(11 + 12 )
or P0 =
(11 − 12 )
102. (D)
Sol. Graph (II) is not correct for ideal gas.
For n mole of an ideal gas,
W
pV = nRT = RT
M
W RT RT  W 
⇒ p= × =×
d  M =d
V M M  
p·M
⇒ d=
RT
Where, p = pressure, V = volume,
T = temperature in K, R = molar gas constant,
w = mass of the gas in g,
M = gram molar mass of the gas and
W
d= = density of the gas.
V
1
(i) When, p = constant ⇒ d ∝
T
So, nature of the plot, d vs T is rectangular hyperbolic (I) but not linear (II). Again,
1
nature of the plot, d vs will be linear in (III).
T
(ii) When, T = constant ⇒ d ∝ p
Here, nature of the plot, d vs p will be linear as (IV).
103. (D)
Sol. Volume of cylinder = V, Temperature = T,
Partial pressure of H2 = 2 atm
According to law of partial pressure
pi = χi × pT
pi = partial pressure of the ith component,
χi = mole fraction, pr = total pressure
 nH2 
⇒ 2atm 
=  × pr
 nH2 + nHe + nO2 
3
Then, pr = 2 × = 6 atm
1
: www.atpstar.com
: 08107258987
104. (A)
Sol.
OV
OV
a/2
OV a/2
In fcc octahedral voids are present at the edge centrers at body center.
Minimum distance between centres of two octahedral at voids.
2 2
a a a2 a2 a
x= 2 +2 = + =
    4 4 2
105. [C]
Sol. ∆Hneutr.for strong acid with strong base = –13.7 kcal equiv–1
Enthalpy of ionisation of acetic acid &NH4OH together
=–10.5 – (–13.7) = +3.2 kcal mol–1
Enthalpy of ionisation of only acetic acid
= –12.5 – (–13.7) = +1.2 kcal mol–1
Enthalpy of ionisation of only NH4OH
= 3.2 – 1.2 = 2 kcal mol–1
106. (A)
Sol. ∆Gº = +∆Hº −T∆Sº
= –196000 –400 (125.65)
=– 196000 –50260
= – 246260= –2.303 x 8.314 x 400 log Kp
−246260
logKp = = 32.15
−7658
Kp = Antilog (32.15)
= 0.4 x 1032
107. (D)
Sol. C4H10(g) + 6.5O2(g) → 4CO2(g) + 5H2O(l)
∆n = [4 – 7.5] = –3.5
∆H = ∆E + ∆ngRT
∴ ∆H < ∆E
108. (C)
Sol. ∆H = ∆( E + PV) = ∆E + ∆(RT) = ∆E + R∆T
For isothermal expansion of ideal gas, E = 0
(∆E = Cv ∆T)
So ∆H = 0 + 0 = 0 ( T = 0)
putting
∆E = Cv∆T, ∆H = Cv∆T + R∆T for = (Cv + R) ∆T = Cp ∆T
1 mole
for n moles, ∆H = nCp∆T = 0
: www.atpstar.com
: 08107258987
109. [A]
Sol. In an isothermal process, temperature is constant T2 = T1
Area under P - V graph is more is isothermal
Wisothermal>W adiabatic
Now ∆Ulsothermal = 0
In adiabatic T1V1γ–1 = T3V3γ–1
γ−1
T3  V1 
= 
T1  V3 
T3< T1 Hence internal energy decreases
∆Uisothermal>∆Uadiabatic
110. (A)
Sol. Here, ∆V = 200 – 400 = –200 cm3
A we know 1 litre = 1000 cm3⇒ ∆V = –0.2 litre
External Pressure(P) = 0.50 then work done = –P∆V = +0.50(0.2) = +0.1b atmlitre and 1 litre
atmosphere = 101.3 joule
∴ W = + 10.13 joule
According to first law of thermodynamics
q = ∆E – W
then∆E = q + W
Given q = –8.00 J
⇒ ∆E = –8 + 10.13 = 2.13 Joule
111. (A)
Sol. ∆H = ∆U + ∆ng RT
∆H = –740000 + 0.5 × 8.3 × 300 = – 738755 J
112. (A)
PV
Sol. n= = 0.02moles
RT
v T
∆S = nRln 2 + nC v,m ln 2
v1 T1
∆S = 0.12 +0.06
∆S =0.18 JK–1
113. (C)
 TL   PL 
Sol. K →L : Isochoric process with increasing in pressure so by  = 
 TK   PK 
PL> PK so TL> TK so it is a case of heating.
 TM   VM 
L → M : Isochoric process with increasing in pressure so by  = 
 L   VL 
T
: www.atpstar.com
: 08107258987
VM< VL so TM< TL so it is a case of cooling
Similarly for
 TN   PN 
M →N : Isochoric process with increasing in pressure so by  = 
 TM   PM 
PN< PM so TN< TM so it is a case of cooling.
114. (D)
Sol. As Internal energy change is a state function so it depends only on the initial and final
temperature and does not depends on the path taken.
115. (A)
Sol. According to Kirchoff’s relation,
T2
∆H =n ∫ CpdT …(i)
T1
Where ∆H = Change in enthalpy

Cp = Heat capacity at constant pressure.
Give, n = 3 moles, T1 = 300 K, T2 = 1000 K,
Cp = 23 + 0.01 T
On substituting the given values in Eq. (i), we get
1000 1000
=
∆H 3 ∫
300
(23 + 0.01T)dT
= 3 ∫
300
23dT + 0.01T dT
1000
 0.01T 2 
= 3  23T +
 2 300
 0.01 
= 3  23(1000 − 300) + (10002 − 3002 )
 2 
= 3[16100 + 4550] = 61950 J ≈ 62 kJ
116. (B)
Sol. A process will be spontaneous when its free energy (Gibb’s energy) change will be negative,
i.e. ∆G < 0. Spontaneity of a process is decided by the value of ∆G, which can be predicted
from the Gibb’s equation, ∆G = ∆H – T∆S for positive/negative signs of ∆H and ∆S at
any/higher/lower temperature as :
∆H ∆S Comment on temperature (T) ∆G Comment on the process

<0 >0 at any temp. <0 Spontaneous
>0 <0 At any temp. >0 Non-spontaneous
<0 <0 At lower temp. <0 Spontaneous
>0 >0 at higher temp. <0 spontaneous
: www.atpstar.com
: 08107258987
117. (C)
Sol. For isothermal reversible expansion.
V V
= =
| W | nRT ln f nRT ln
Vi Vi
Where, V = final volume, Vi = initial final.
Or |W| = nRt ln V – nRT ln Vi
On comparing with equation of straight line,
Y = mx + c, we get
slope = m = + nRT
intercept = – nRT ln Vi
Thus, plot of |W| with ln V will give straight line in which slope of 2(T2) is greater than slope of
1(T1) which is given in all options.
Now, it Vi < 1 then y intercept (–nRT Vi) becomes positive and if it is positive for one case then
it is positive for other case also. Thus, it is not possible that one y-intercept goes above and
other y-intercept goes below. Thus, option (B) and 9d) are incorrect.
If we extent plot given in option (A) it seems to be merging which is not possible because if
they are merging they give same +ve y-intercept. But they cannot give same y-intercept
because value of T is different.
Now, if we extent the line of T1 and T2 given in option (C) it seems to be touching the origin. If
they touch the origin then y-intercept becomes zero which is not possible. Thus, it is not the
exactly correct answer but among the given options it is the most appropriate one.
118. (A)
Exp. For Ecell = E ºcell
log Q must be zero
Q =1
2
 Fe 2 +  10−6
Q=  4  ⇒ =
1
 H +  [ Po 2 ] (10 ) ( 0.01)
−4x
10–4 = 10–4x
x=1
119. (A)
Sol. When pH = 14, [H+] = 10–14 and [OH–] = 1 M
Ksp = [Cu2+] [OH–]2= 10–19
10 –19
∴ [Cu2+] = = 10–19
[OH – ]2
The half cell reaction
Cu2+ + 2e–→ Cu
0.059 1
E = E0 – log
2 [Cu 2 + ]
0.059 1
= 0.34 – log –19 = –0.22 V
2 10
: www.atpstar.com
: 08107258987
120. (C)
Exp. The equivalent conductivity of 0.1 M weak acid is 100 time lesser thn that at infinite dilution.
∧0
∧v =
100
∴ Degree of dissociation
∧ ∧0
(α) = ∧ v= 0v= = 0.01
∧ 100 ∧ 0
121. (A)
Sol. Saturated solution corresponding to infinite dilution
∧ 0m for salt
= ∧ 0M( NH + + λ 0H – = 100 S m2 mole–1 + 50 Sm2mol–1 = 150 Sm2mol–1
3 ) 4 Br2 2 PO 2
1 1 1
K= = Ω–1 cm–1 = Ω–1m–1
ρ 200 2
1 –1 –1
Ω m
k
∧ 0m (salt) = = 2
s s moles m –3
1 1
S (moles m–3) = = = 3⋅33 × 10–3
2 × 150 300
S (moles L–1) = 3⋅33 × 10–6
Ksp = (3⋅33 × 10–6)2
= 1.11 × 10–11 M2
122. [B]
−
Sol. Calculation for EOH |Ag O|Ag −
2
Reduction 2Ag+ + 2e− → 2Ag( s), ∆G°1= –2 × F × E°Ag 

 +
/ Ag 
Lonisation  Ag2O + H2O(l) → 2Ag+ + 2OH− ∆G°2 =−2.303RT logk sp 
  2
Net  Ag2O + H2O(l) + 2e− → 2Ag(s) + 2OH− , ∆G°3 =−2 × F × E°OH |Ag O|Ag 
 −
2 
2.303RT logk sp2
∆G3° =∆G1° + ∆G°2 + 2 × F × EOH
°
−
|Ag O|Ag
=+2 × F × E° Ag+ /Ag +
2
2F
0.06
E°OH− |Ag O|Ag =
E°Ag+ /Ag + × 2logk sp
2
2
= 0.8 + 0.06 log [2 × 10–8]
= 0.8 + 0.06 [–8 + 0.3]
= 0.8 + 0.06 × (–7.7)
= 0.8 – 0.462
= 0.338 Volt ≅ 0.34 V
∆G° = –nFE°ceu
–nF(E°c – EA)Red
= −2 × (E°OH |Ag O|Ag − E°Zn /Zn )
− +2
2
= –2 × 96500 × (0.34 + 0.76)

= 212300 J
= 212.3 kJ
: www.atpstar.com
: 08107258987
123. (A)
100 1 1 1000
Sol. Λ eq = k × = × ×
N R a N
1 1000
× cell cons tan t ×
R N
1 1000
= × 0.88 ×
220 0.01
= 400 mho cm2 eq–1
124. (B)
Sol. Total current passed in 30 sec = Area of current–time curve
1  1 
= × 100 × 10  + (100 × 10 ) + (100 × 10 ) +  × 100 × 10 
2  2 
= 3 × 100 × 10 mA × s
= 3000 × 10–3 amp s = 3C
EQ W E m
W= or = = Z=
F Q F 3
125. (A)
1.93 × 50 × 60
Sol. No. faraday = = 0.06
96500
80 0.06
∴ Moles of Zn2+ deposited = × = 0.024
100 2
0.5 × 2 – 0.024
 Zn  =
2+
=
∴ 0.38M
0.2
126. (D)
Sol. Al3+ + 3e– → Al
0.059 1
E = E° – log
3 [ Al3+ ]
at pH = 12 ⇒ pOH = 14 – 12 = 2 ⇒ [OH–] = 0.01 M
10 −36 10 −36
[Al+3] = − 3
= 3
= 10–30
[OH ] (0.01)
0.059  1 
∴ E = –1.55 – log  −30 
3  10 
0.059
= – 1.66 – × 30 = – 1.66 – 0.59 = – 2.25 V
3
127. [D]
Sol. At equilibrium
Ecell = 0
E0cell = 0.01 V
: www.atpstar.com
: 08107258987
Sn + Pb2+→ Sn2+ + Pb
0.06
E=
cell
0
Ecell − logQ
n
0.06 [Sn2 + ]
=0 0.01 − log
2 [Pb2 + ]
0.06 [Sn2 + ]
0.01 − log
2 [Pb2 + ]
1 [Sn2 + ]
= log
3 [Pb2 + ]
[Sn2 + ] 1
= =
10 3
2.14
[Pb2 + ]
128. (C)
Sol. NaCl and KCl are strong electrolytes. So, the study of their molar conductances (λm) can be
experimentally verified by Debye-Huckel
Λm
c
=Λm
0
−B C
Λm
c
= molar conductance at concentration.
Λm
0
= molar conductance at infinite diution.
i.e. C → 0
B = Debye-Hukel Onsgar constant.
For (both NaCl and KCl) a strong binary electrolyte like AB, the nature of the plot of Λm vs
C will be
Λm
C
Na⊕ will remain in more hydrated state, i.e. larger sized in aqueous solution. As a result, ionic
mobility as well as ionic conductance of Na⊕.
(or NaCl as ClΘ is common to NaCl and KCl) will be lower than K⊕ (or KCl). Thus, the plot of
Λm vs C for NaCl and KCl is as follows :
KCl
NaCl
Λm
C
: www.atpstar.com
: 08107258987
129. (D)
Sol. In disproportionation reactions, same element undergoes oxidation as well as reduction.
e.g.
Reduction
+1 +2 0
2CuBr CuBr2 + Cu
Oxidation
Here, CuBr get oxidised to CuBr2 and also it get reduced to Cu. other given reactions and
their types are given below.
Reduction
+7
2 MnO−4 + 10I– + 16H+ 2Mn
+2
+ 5I2 + 8H2O
Oxidation
In the given reaction, MnO−4 get oxidised to Mn2+ and I– get reduced to I2. It is an example of
redox reaction. The reaction takes place in acidic medium.
2KMnO4 → K2MnO4 + MnO2 + O2
The given reaction is an example of decomposition reaction, Here, one compound split into
two or more simpler compounds, atleast one of which must be in elemental form.
2NaBr + Cl2 → 2NaCl + Br2
The given reaction is an example of displacement reaction. In this reaction, an atom (or ion)
replaces the ion (or atom) of another element from a compound.
130. (B)
Sol. Key Idea This question is based upon Faraday’s first law which states that “Mass of any
substance deposited of liberated at any electrode is directly proportional to the quantity of
electricity passed.”
During charging :
Pb + SO24− → PbSO4 + 2e–
⇒ 1 F ≡1 g-equiv. of PbSO4
1 303
= mol of PbSO4 ⇒ g PbSO4
2 2
303
∴ 0.05 F ≡ × 0.05 g PbSO4
2
= 7.575 g of PbSO4
131. (B)
molar mass 4 × 119

Sol. Calculated density d = z × = −8 3
= 2.78 g cm–3
NA × volume 6.023 × 10 × (6.58 × 10 )
23
Is greater then actual density 2.44 gcm–3 therefore density decreases and defect is Schottky
defect.
: www.atpstar.com
: 08107258987
132. (A)
r+ rA+
Sol. =A
−
=
0.414
rx 250
rA+ =0.414 × 250 pm =104 pm
133. [D]
1
Sol. Distance between two Na+ is times of edge length
2
134. [A]
Sol. For the given crystal, a = b ≠ c, α = β = 90°, γ = 120°
These are the characteristic of hexagonal system.
135. [D]
Sol. X is in f.c.c. lattice
1 1
Number of atoms= atom at corner × + atoms at faces ×
8 2
1 1
X = 8× + 6× = 4
8 2
Total tetrahedral voids = 8
As y are at T.V.
So Y = 8
Number of Octahedra voids = 4
1
Z= ×4 = 2
2
So X = 4, Y = 8, Z = 2
Hence the formula of solid is X4Y8Z2
or X2Y4Z.
136. [D]
Sol. In BCC structure the cations and anions touch along the body diagonal
( )
2 rcs+ + rBr − = 3 × 4.3 (Body diagonal = 3a )
1.72 × 4.3
rcs+ =
+ rBr − = 3.72Å
2
2rc + rBr −
s
rBr −
: www.atpstar.com
: 08107258987
137. [A]
Sol. No. of oxygen atoms per unit cell in ccp = 4(O2–)
No. of octahedral voids per unit cell = 4 (Al3+)
No. of Tetrahedral voids per unit cell = 8 (Mg2+)
Total negative charge due to oxygen atoms = 8
Net charge must be zero.
m4 (C) + 2n (8) + 4 (–2) = 0
3m + 4n = 2
3 4
(A) + =2 is correct
2 8
4
(B) 3 × 1 + 4 × = 4≠2
4
1 1
(C) 3 × + 4× = 4 ≠ 2
2 4
1 1 3 2 5
(D) 3 × + 4× = + = ≠2
4 8 4 4 4
138. [A]
Sol. Given that ρ = 2.75 g cm–3
We need to find type of unit cell
Z×M
∴ρ =
NA a3
ρ × NA × a3
Z=
M
2.75 × 6.023 × 1023 × (654 × 10 −10 )3
=
119
∴ Z = 4 so FCC unit cell
In FCC 1 atm surrounded by 6 atoms so coordination number is 6.
139. (B)
M0
z×
NA
Sol. d= (d = density)
a3
M0
4×
8= 6 × 1023
( 4 × 10 )
3
−10
1
M0 =
8 × 6 × 1.6
256 10
Number of moles =
in 256 g =
8 × 6 × 1.6 3
10
Number of atoms = × 6 × 1023 = 2 × 1024
3
: www.atpstar.com
: 08107258987
140. (C)
Sol. 8chloride ions at 8 corners Cs+ cation at body centre along body diagonal there will be one
Cs+ cation and 2Cl– ions at ends of body diagonal.
2rCs − + 2rCl− = 3a
a is edge length
Cl–
+
Cs
–
Cl
141. (B)
Sol. M 2 A6
12×
3
M8A6
M4A3
142. (D)
Sol. Covalent or network sold have very high melting point and they are insulators in their slid and
molten form.
143. (A)
Sol. Millimoles = 10 × 10–3 = 10–2
moles = 10–5
No. of molecules = 6 × 1023 × 10–5 = 6 × 1018
0.24
Suface area ocupied by one molecule = = 0.04 × 10–18 cm2
6 × 1018
4 × 10–20 = x2 [ x = edge length]

x = 2 × 10–10 cm = 2 pm
144. [D]
1
Sol. Coagulation value ∝
coagulating power
∴ Coagulating power As2S3 is
MgSO4 > BaCl2 > NaCl
III > II > I
145. (A)
Sol. Physical adsorption is a multilayer phenomenon. Rest all are correct features of physical
adsorption.
: www.atpstar.com
: 08107258987
146. [B]
Sol. Physisorption is exothermic in nature. Therefore, in accordance with Le-Chatliers principle, it
decreases with increase in temperature. This means physisorption occurs at low temperature
more readily. So, The correct order of temperature for curves I, II, III, IV are :
T4> T3> T2> T1
147. [A]
Sol. Larger the hydrophobic fragment of surfactant molecule easier will be micellization, smaller
the CMC value i.e., CH3(CH2)15 N+(CH3)3 Br– will have lowest CMC due to longest hydrophobic
chain.
148. (D)
Sol. In lyophilic sols, the dispersed phase particles have great affinity for the dispersion medium.
These sols are reversible. These are quite stable. Examples include gum, gelatin, starch,
proteins and rubber etc.
149. (A)
Sol. Arsenioussulphide is –ve charged colloid. Hence cation having maximum positive charge will
be nost effective for coagulation, (Hardy Schulz rule)
Al3+> Ba2+> Na+ (coagulating power)
150. (D)
Sol. As2S3 and TiO2solare examples of negatively and positively charged sols respectively.
151. (D)
x
Sol. = K(P)1/n
m
x 1
log =  logK + logP
m n
y = c + mx
m = 1/n so slope will be equal to 1/n.
x/m
1<n<∞ n=∞
n<1
1
Hence 0 ≤ ≤1
n
: www.atpstar.com
: 08107258987
152. (D)
Sol. Blood : negatively charged sol
According to Hardly-schulz rule, for the negatively charged sol, most (+) ve ion is needed for
its efficient coagulation.
153. (B)
1
x 1
Sol. As per Freundlich adsorption isotherm   = KP n → x =
 
m n
Hence answer is (B)
154. (A)
Sol. → Viscosity of hydrophilic sol > viscosity of H2O
→ Hydrophilic sol is more stable so can't be easily coagulated.
→ Hydrophilic sols are reversible sols.
→ No electrolytes are required to stabilize hydrophilic sol.
155. (A)
Sol. If FeCl3 is added to hot water, a positively charged sol, hydrated ferric oxide is formed due to
adsorption of Fe3+ ions.
Fe2O3. xH2O/Fe3+ Positively charged.
: www.atpstar.com
: 08107258987

MQB_Physical_Chemistry20210709181921533983_20220523115726542990

Uploaded by

Document Information

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

MQB_Physical_Chemistry20210709181921533983_20220523115726542990

Uploaded by

Copyright:

Available Formats

MASTER QUESTION BANK

3. 500 g impure sample of CaCO3 on heating gives 70 g of CaO. Percentage impurities in

17. An element undergoes a reaction as shown :

21. Radiation corresponding to the transition n = 4 to n = 2 in hydrogen atoms falls on a certain

23. The ratio of minimum to maximum wavelengths in Balmer series of H-atom is

24. According to Bohr's atomic theory :-

Temperature (K) Wavelength

31. A redox reaction always involves

34. What will be the value of x, y and z in the following equation?

35. H2O2 acts as an oxidizing agent in

36. 25 mL of household bleach solution was mixed with 30 mL of 0.50 M KΙand 10 mL of

37. (A) HOCl + H2O2 

NaCl and BaSO4. Respectively, at a temperatures T. Which of the following is false ?

(C) CNaCl(T2) > CNaCl(T1) for T2 > T1

given reaction at 27ºC. Hence, order of the reaction is

(A) 0 (B) 1 (C) 2 (D) 3

43. The radioactive isotope

λmax λmax λmax

52. It is true that

270 273 T/K 271 273 T/K

270 273 T/K 271 273 T/K

64. An acidic buffer is obtained on mixing

68. The equilibrium constant Kc for the reaction

69. Phosphorus pentachloride dissociates as follows, in a closed reaction vessel,

71. For the reaction,

72. The exothermic formation of ClF3 is represented by the equation

73. What is the conjugate base of HO–?

75. Consider the reaction equilibrium

(a) Equilibrium (b) Equilibrium

equilibrium constant for A  P is

78. Consider the following reaction :

82. pH of 0.005 M calcium acetate (pKa of CH3COOH = 4.74) is

90. The solubility of Ca(OH)2 in water is :

[Graph not to scale]

(A) 1.0 (B) 4.5 (C) 1.5 (D) 3.0

(A) 9 cm of Hg (B)18 cm of Hg (C) 27 cm of Hg (D)None of these

(C) (D) All of these

106. Hydrogen peroxide (H2O2) decomposes according to the equation

107. What is the true regarding complete combustion of gaseous isobutane-

(A) T3> T1 (B) T2 = T2

110. A sample of gas is compressed by an average pressure of 0.50 atmosphere so as to

113. A fixed mass m of a gas is subjected to transformation of states from K to L to M to N and

The succeeding operation that enable this tansformation of state are

Sample I was heated to 320 K and cooled to 298 K

Sample lI was heated to 300 K, cooled to 273 K and heated to 298 K

Sample Ill was heated to 373 K and cooled to 298 K

At the end of these processes, the internal energy of

(A) III is the highest

(B) II is the highest

(D) I, II and III are the same

116. A process will be spontaneous at all temperature if

(A) (B) (C) (D)

Take specific resistance as 200 Ωcm

10s 20s 30s

126. Ksp of Al(OH)3 = 10–35 and EoAl3 + / Al = – 1.66 V

(A) 104 PM (B) 125 (C)183 PM (D) 57PM

143. 10 mL of 1 mM surfactant solution forms a monolayer covering 0. 24 cm2 on a polar substrate.

148. Which of the following statements is correct for a lyophilic sol?

150. As2S3 and TiO2sol example of

(A) log n with (n > 1) (B) n with (n, 0.1 to 0.5)

∴1.743 × 10−3 (2M + 96 × 3) = 0.596 = M = 26.9

 4 moles of NH3 ≅ 5 moles of O2

No. of moles of urea = Given mass / molar mass

log t 1 = (1 – n) loga + logk