RIT - 1

Rankers Academy JEE
FIITJEE – (JEE-Advanced)
PHYSICS, CHEMISTRY & MATHEMATICS
Pattern – 1 QP Code: 100284 RIT – 1
Time Allotted: 3 Hours Maximum Marks: 198
▪ Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
▪ You are not allowed to leave the Examin ation Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
BATCHES – XII
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & B in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Two Parts.

(i) Part-A (01-06) – Contains Six (06) multiple choice questions which have ONLY ONE CORRECT answer
Each question carries +3 marks for correct answer and -1 marks for wrong answer.
(ii) Part-A (07-12) – Contains Six (06) multiple choice questions which have One or More correct answer.
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO
incorrect option is darkened.
Zero Marks: 0 If none of the bubbles is darkened.
Negative Marks: −2 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three
will result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B)
will result in −2 marks, as a wrong option is also darkened.
(ii) Part-B (01-06) contains Six (06) Numerical based questions, the answer of which maybe positive or
negative numbers or decimals to Two decimal places (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and
each question carries +4 marks for correct answer and there will be no negative marking.
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Batch :____________________ Date of Examination :___________________
Enrolment Number :_______________________________________________
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IT−2024 (RIT-1)-(PCM) Rankers Academy JEE 2
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ONN –– 1
1:: P
PHHY
YSSIIC
CSS
PART – A
(Single Correct Choice Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.
1. A man standing on a truck which moves with a

constant horizontal acceleration a(= 10 m/s2) when
speed of the truck is 10 m/s. The man throws a ball
with velocity 5 2 m/s with respect to truck. In the
direction shown in the diagram. Find the displacement
of ball in meters in one second observed as observed
by the man. (g = 10 m/s2)
(A) 20 m (B) 10 m (C) 5 m (D) zero
2. The resultant of A + B is R1 . On reversing the vector B , the resultant becomes R2 , what

is the value of R12 + R22
(A) A2 + B2 (B) A2 - B2 (C) 2(A2 + B2) (D) 2(A2 - B2)
3. Four rods each of length l have been hinged to form a rhombus. y

B
Vertex A is fixed to rigid support, vertex C is being moved along the x
C
x-axis with a constant velocity v as shown in the figure. The rate at A v
which vertex B is approaching the x-axis at the moment the
D
rhombus is in is in the form of a square is ( figure is not to scale)
v v v v
(A) (B) (C) (D)
4 3 2 2
4. The relation between time t and distance x moved by a particle is t x2 x where 

and  are constants. The retardation is (if v represents velocity)
(A) 2 V 3 (B) 2 V 3 (C) 2 V3 (D) 2 2 V3
5. Given the A + B = C and that C is ⊥ to A. Further if | A |=| C | , then what is the angle
between A and B
  3
(A) radian (B) radian (C) radian (D)  radian
4 2 4
Space For Rough Work

6. Two particles are projected simultaneously from two points, O

and O’ such that d is the horizontal distance and h is the vertical
distance between them. They are projected at the same α
inclination α to the horizontal with the same speed v. The time O
after which their separation becomes minimum is
(A) d/(v cos α) (B) 2d/(v cos α) h
(C) d/(2v cos α) (D) d/v α

d O’
(Multi Correct Choice Type)

out of which ONE OR MORE may be correct.
7. ˆ bˆ and cˆ are unit vectors satisfying aˆ − 3 bˆ + cˆ = 0, then the angle between the
If a,
vectors aˆ and cˆ is:
   
(A) (B) (C) (D)
4 3 6 2
8. A plane is to fly due north. The speed of the plane relative to the air is 200 km/h, and the
wind is blowing from west to east at 90 km/h.
(A) The plane should head in a direction given by  = sin–1 (0.65)
(B) The plane should head in a direction given by  = sin–1 (0.45)
(C) The velocity of plane relative to the ground is 179 km/h.
(D) The velocity of plane relative to the ground is 159 km/h.
9. Let three vectors a, b and c are related as a + b = c. The angle between a and b is .
Select the correct alternative:
(A) Angle between c and b is greater than  / 2 if a  b .
(B) Angle between c and a is greater than  / 2 if a  b .
(C) Angle between c and b can be  – , for some values of a, b .
(D) Angle between c and b cannot be  – , for some value of a, b .
10. If r1 = 2iˆ + Jˆ & r2 = ˆi − 2jˆ + 3kˆ and angle between r1 & r2 is , then which of the following is
correct?
(A)  = 0° (B)  = 90°
(C) r1  r2 = 0 (D) r1  r2 = 70
11. A boat moves relative to water with a velocity which is n times the river flow velocity:
(A) If n < 1, boat cannot cross the river.
(B) If n = 1, boat cannot cross he river without drifting.
(C) If n > 1, boat can cross the river along shortest path.
(D) Boat can cross the river whatever is the value of n (excluding zero value).

12. Two vectors A and B are drawn from a common point and C = A + B
(A) If C2 = A 2 + B2 , the angle between vectors A and B is 90°
(B) If C2  A 2 + B2 , the angle between A and B is greater than 90°
(C) If C2  A 2 + B2 then angle between the vectors A and B is between 0° and 90°
(D) If C = A − B, angle between A and B is 180°
PART – B
(Numerical based)
1. Two particles move in a uniform gravitational field with an acceleration g. At the initial
moment the particles were located at one point and moved with velocities u1 = 3.0 m/s and
u2 = 4.0 m/s horizontally in opposite directions. Find the distance between the particles at
the moment when their velocity vectors become mutually perpendicular (in m).
2. Given two vectors A = 2iˆ + 3jˆ and B = ˆi + ˆj . The component of vector A along vector B is
x
. Find the value of ‘x’.
2
20 3
3. A particle is thrown horizontally with relative velocity

40 m/s from an inclined plane, which is also moving with
acceleration 10 m/s2 vertically upward. Find the time in
sec. after which it lands on the plane (take g = 10 m/s2) g = 10 m/s2
300
4. If A  B = A  B and A & B are 2 2 and 3 respectively, determine C = A  B .
V(m/s)
20
5. Referring to v–s diagram, if magnitude of acceleration

of the particle when its velocity becomes half of the
initial velocity is a, then find the value of a/5.
s(m)
O 50
6. Two ports A and B are separated by a river of width D. B
Water in the river flows with speed VW. A boat crosses the
river form port A to port B. The speed of the boat relative
 D Vw
to water is VB. Given VW = 3 VB . if at angle  = ( in
n 
0
radian) with AB in which the boat should start relative to 30
water so that it moves along A, then find the value of n A

S
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PART – A
h
1. The orbital angular momentum of an electron in an atom is given as , where ( + 1)
2
‘’ is the azimuthal quantum number of the electron. The orbital angular momentum of an
h
electron is found to be j s. What is the minimum principal quantum number of the
3

orbital in which the electron is present?
(A) 3 (B) 1
(C) 2 (D) 4
2. The compressibility factor(Z) of one mole of a gas is given below
Pb
Z = 1+
RT
b = van der Waal’s constant
According to this equation, the molecules will push each other and repulsive force will
dominate. Under which condition it happens?
(A) b = Vreal (B) Vreal > Videal
(C) b = Videal (D) b < 0
3. What is the oxidation number of carbon in the molecule given below:
O
C
F H
(A) +2 (B) +3
(C) -2 (D) -3
4. The +1 and +3 ions of which atom contain same number of unpaired electrons?
(A) Mn(Z = 25) (B) Fe(26)
(C) Cr(Z = 24) (D) V(Z = 23)
5. For easily liquefiable gases, which two terms will have the largest value?
Z = Compressibility factor
TC = Critical temperature
a, b = van der Waal’s constants
EK = Kinetic energy of the gas
(A) Z and EK (B) EK and TC
a 1
(C) and TC (D) ab and
b TC

6. How much gram of solid oxalic acid (H2C2O4.2H2O) should be added to 400 mL of 0.2 M
acidified KMnO4 solution so that the solution will just decolourize from pink colour?
MnO−4 + C2O24− + H+ ⎯⎯→ Mn2+ + CO2 + H2O
(A) 4.032 (B) 25.2
(C) 15.62 (D) 5.865

7.
200 K
 Curve-1
dnc
Ndc 200 K
(s m -1)
Curve-2
Velocity (m s –1)→
The distribution of velocity of two gases CO2 and CH4 at constant temperature is given
above. Choose the correct statement(s).
(A) Curve-1 is for CO2 gas and Curve-2 is for CH4 gas.
(B) Most probable velocity of CH4 is higher than that of CO2
(C) At 0K, the distribution curves become so narrowest that all molecules of a particular
gas will have constant velocity
(D) The molecules of both gases move with the same velocity at absolute zero
8. The outermost electronic configuration of three atoms are given below

ns2np4(X), (n + 1)s2p3(Y), (n -1)s2p1(Z)
Choose correct statements
(A) if n = 3, X, Y and Z can make available more number of unpaired electrons by
excitation of electrons.
(B) Y has the most stable electronic configuration as compared to X and Z for any possible
allowed values of n.
(C) For all atoms, the azimuthal quantum number of the highest energetic electron is one.
(D) Minimum value of ‘n’ is 3
9. Nine gram of water contains

(A) 8 g of oxygen atoms
(B) one mole of hydrogen atoms
(C) five moles of electrons
8
(D) four mole of neutrons if the oxygen atom is 16 O and hydrogen atoms are 11H

10. Which of the following characteristic(s) of ideal gases do(es) not vary with temperature and
pressure?
(A) Compressibility factor(Z) (B) Root mean square velocity(Crms)
(C) Kinetic energy (D) Vapour density
11. The complete normalized wave function(containing the radial and the angular part) of the
2pz orbital is given below
5/2
 Z 
1 − Zr/2a0
 2pz =   re cos 
4 2  0 
a
Choose the correct statement(s)
(A) the orbital has no radial node as r = 0 at the node
(B) the orbital has one angular node or nodal plane at which 22p = 0
z
(C) 2p will be zero when  = 90o

z
(D) XY-plane is the nodal plane for 2pz orbital as z-axis is at 90o with XY-plane
12. A solid mixture contains 0.1 mole of each of NaOH, NaHCO3, Na2CO3 and NaCl. The
mixture is dissolved in water forming one litre solution. Choose correct statement(s).
(A) 400 mL of 0.5 M HCl solution can neutralize the above solution in presence of
phenolphthalein indicator.
(B) 500 mL of 0.8 M HCl solution is used to neutralize above solution in presence of methyl
orange indicator.
(C) the molarity of Na+ ions in the solution is 0.5 M assuming all the chemical species are
completely soluble in water
(D) the mole fraction of NaOH in the solid mixture is 0.25
PART – B
(Numerical based)
1.
X2 Cl2 + He
1 mole 4 mole
V = 0.2 L V = 0.2 L
The ratio of rate of effusion of X2 and the mixture of gases(Cl2 and He) is 1: 2. If molar
mass of X2 is 18.75 g mol–1 and the molar mass of mixture of Cl2 and He is M, what is the
M
value of ?
10

2. 19.6 g of the hydrated salt Na2CO3.xH2O in one litre solution requires 200 mL of 0.5 M HCl
solution for neutralization in presence of phenolphthalein indicator. How many hydrated
H2O molecules are present in the salt?
3. What is the maximum sum of principal(n), azimuthal () and magnetic(m) quantum
numbers of the lower energetic electron of sodium, which is removed from the atom by
supplying energy that is equal to the sum of I.E1 and I.E2 of sodium atom?
4. The ratio of wavelengths of the photons that constitutes the first line of Lyman series to the
x+y
second line of Balmer series is expressed as x : y, what is the value of ?
10
5. The electronic configuration of an atom(X) is 1s22s22p63s23p64s2

If x = Number of orbitals of the atom having one radial node and
y = Number of orbtials having one angular node or nodal plane, what is the value of (x +
y)?
6. S + O2 ⎯⎯→ SO2
How much gram of sulphur will completely react with 0.4 g equivalent of oxygen according
to above reaction?

S
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3:: M
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ATTIIC
CSS
PART – A
1. The minimum value of cos x cos 60o − x cos 60o + x is ( ) ( )

1 1
(A) − (B) −
2 3
1 1
(C) − (D) −
4 5
sin x sec x tan x  

2. If   = 9 where x   0,  then x = _______
cos x cos ec x cot x  2
 
(A) (B)
4 3

(C) (D) 
2
sin2 x
3. lim equals
x →0
2 − 1 + cos x
(A) 2 (B) 4 2
(C) 4 (D) 2 2
dy
4. Let y = x + x + x..... then at x = 2 is equal to
dx
(A) 1 (B) 3
1 1
(C) (D)
2 3
−27
5. If ,  be such that    −   3 and cos  + cos  = ,
65
−21  −
sin  + sin  = then cos   is
65  2 
6 3
(A) (B)
65 130
(C) less than 0 (D) greater than 0

6. Let x = sin1o , then the value of the expression

1 1 1 1
o o
+ o o
+ o o
+ ... + is equal to
cos0 cos1 cos1 cos 2 cos 2 cos3 cos 44 cos 45o
o
1
(A) x (B)
x
2 x
(C) (D)
x 2

1 
7. If sin  + cos  = − then a value of tan satisfies, which of the following equations?
5 2
(A) 2x2 − x − 1 = 0 (B) x2 − 2x − 3 = 0
(C) 2x2 − 5x − 3 = 0 (D) 2x3 − 7x2 + 2x + 3 = 0
8. If 24a−b = log7 ( 2401) and log4 ( 98a + 138b) = 5, then find the value of the product
(ab).
(A) a = 2 (B) a = 6
(C) ab = 12 (D) ab = 36
1  
9. The value(s) of x  0,  which satisfy the equation sin x + cos x = sin2  x +  is:
2  4
(A) (B)
(C) (D)
sin  sin3 sin9

10. If k1 = tan 27 − tan  and k 2 = + + , then
cos3 cos9 cos 27
(A) k1 = 2k 2 (B) 2 k1 = k 2
k + k2 k + k2
(C) 1 =1 (D) 1 =2
2k1 − k 2 2k1 − k 2
11. If 24a−b = log7 ( 2401) and log4 ( 98a + 138b) = 5, then find the value of the product (ab).
(A) a = 2 (B) a = 6
(C) ab = 12 (D) ab = 36

12. If A, B, C are the three angles in the triangle such that 2sinBsin ( A + B) − cos A = 1 and
2sinCsin (B + C) − cosB = 0, then:
(A) A = 120o (B) B = 120o
(C) C = 30o (D) B = C
PART – B
(Numerical based)
3
1. The solution set of the system of equaitons log2 x + log2 y = log2 9 + 1, logx + y ( 27 ) = is
2
(p, q) then pq =
3 x + 33− x − 12
2. lim is equal to _________
x →2 3 − x/2 − 31− x
1 cos ec 2 − sec 2 
3. If  is an acute angle and tan  = then, =
7 cos ec 2 + sec 2 
 2 
4. Let f() = cos  cos 2 cos 3 cos 4 cos 5 cos 6 and f   = P . Find value of 28 |P|
 13 
( ) − 2x
3
log 1/ 4 x log27 x2 +1
2 2
−3 dy
5. Let y = and = ax + b , then the value of a + b is
7 4log49 x
− x −1 dx
 /4
2 
 (tan x + cot 2 x )dx = −
2
6. If then k =
/6 3 k

QP Code: 100284
ANSWERS
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1 :: P
PHHY
YSSIIC
CSS
PART – A
1. B 2. C 3. C 4. A
5. C 6. C 7. B 8. ABC
9. ABC 10. BCD 11. BCD 12. ABCD
PART – B
1. 2.42 2. 5 3. 2 4. 6
5. 0.80 6. 3
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PART – A
1. D 2. B 3. A 4. B
5. C 6. B 7. ABCD 8. ABCD
9. ABCD 10. AD 11. ABCD 12. ABCD
PART – B
1. 7.5 2. 5 3. 4 4. 0.5
5. 10 6. 3.2
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3 :: M
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CSS
PART – A
1. C 2. B 3. B 4. D
5. C 6. B 7. ABCD 8. AC
9. ABD 10. AC 11. AC 12. ACD
PART – B
1. 18 2. 36 3. 1 4. 4
5. 3 6. 6

Hints & Solutions

Mathematics
PART – A
1. C
cos3x
Sol. f (x) =
4
2. B
sin x sec x tan x
Sol. Given, ,  =9
cos x cos ec x cot x
 tan x  tan x  tan2 x = 9
( 3)
4
 tan4 x =
 tan x = 3

x=
3
3. B
 sin2 x 
 2 
 x 
( 2 + 1 + cos x )
Sol. lim
x →0  1 − cos x 
 x2 
 
=
(1)
2
(
. 2 2 )=4 2
1
2
4. D
dx
Sol. y = x + y  x = y2 − y  = 2 y −1
dy
Now at x = 2, y is also equal to 2
dy 1 1
Hence at (2, 2) is =
dx 2 ( 2) −1 3
5. C
27
Sol. cos  + cos  = −
65
21
sin  + sin  = −
65
Squaring and adding
234 −728
2 + 2cos (  −  ) =  cos (  −  ) =
845 845
 − 728 117
 2cos2   = 1 − 845 = 845
 2 
 − 3
 cos  =−
 2  130

   −  3 
 Since 2  2  2 
 
6. B
1  sin (1 − 0 ) sin ( 2 − 1) sin ( 45 − 44 ) 
Sol.  + + ... + 
sin1  cos0 cos1 cos 2cos 2 cos 44 cos 45 
1
=
sin1
 tan1 − tan0 + tan2 − tan2 + tan3 − tan2 + ... + tan 45 − tan 44
1
= .1 − 0
sin 1
1
=
sin1
1
= .
x
7. ABCD
1 2 tan  2 1 − tan 2  2 1
Sol. sin  + cos  = −  + =−
5 1 + tan 2  2 1 + tan 2  2 5
−1
Put x = tan  2  2x 2 − 5x − 3 = 0  x = 3,
2
Hence all options correct.
8. AC
Sol. 24a−b = log7 ( 2401)  4a − b = 2 ……..(1)
log8 ( 98a + 138b ) = 5  98a + 138b = 4 = 1024 5
………(2)
On solving equation (1) and (2), we get
a = 2 and b = 6  product (ab) = 12
9. ABD
1  
Sol. sin x + cos x = sin2  x + 
2  4
 
2sin x + cos x = 2sin2  x + 
 4
2 sin x + cos x = 1 + sin 2x
2 sin x + cos x − 1 − 2 sin x cos x = 0
2sin x (1 − cos x ) − 1(1 − cos x ) = 0
( 2sin x − 1)(1 − cos x ) = 0
1
sin x = , cos x = 1
2
x = 30 , 150o , x = 0
o
10. AC
Sol. k1 = tan 27 − tan  = ( tan27 − tan9) + ( tan9 − tan3) + ( tan3 − tan  )
sin2 2sin 
Now, tan3 − tan  = =
cos3 cos  cos3
2sin3
Similarly, tan9 − tan3 =
cos 9

2 sin9
and tan 27 − tan9 =
cos 27
 sin9 sin3 sin  
 k1 = 2  + +  = 2k 2
 cos 27 cos 9 cos 3 
11. AC
Sol. 24a−b = log7 ( 2401)  4a − b = 2 ……..(1)
log8 ( 98a + 138b ) = 5  98a + 138b = 4 = 1024 5
………(2)
On solving equation (1) and (2), we get
a = 2 and b = 6  product (ab) = 12
12. ACD
Sol. 2sinBsin ( A + B) = 2sinBsinC = cos (C − B ) − cos (C + B )
= cos ( C − B) + cos A
 cos ( C − B) = 1  B = C
PART – B
1. 18
Sol. log2 ( xy ) = log2 18  xy = 18 and x + y = 9
x and y are roots of t 2 − 9t + 18 = 0
t = 3, 6
2. 36
Sol. Let 3x/2 = t
27
t2 + − 12
t2 t 4 + 27 − 12t 2
lim = lim
t →3 1 3
− 2
t →3 t −3
t t
lim
(t 2
)
− 3 ( t + 3 )( t − 3 )
= 6  6 = 36
t →3 ( t − 3)
3. 1
1
Sol. tan  = = cot  = 7
7
(
 sec 2  = 1 + tan2  = 1 + ) 1 8
(
= and cos ec 2 = 1 + cot 2  = 1 + 7 = 8
7 7
)
8
8−
cos ec  − sec 
2 2
7 = 48 = 3 .
 =
cos ec  + sec  8 + 8 64 4
2 2
4. 4
Sol. cos5 = cos8
cos3 = cos16
 cos  cos 2 cos 4 cos 8 cos 16 cos 32
sin64 sin  −1
= =− 6 = =P
26 sin  2 sin  26
1
28|P| = 28 × 6 = 4
2

5. 3
Sol. y simplifies to (using log properties)
x 4 − (x 2 + 1) − 2x
y=
x2 − x − 1
6. 6
 /4
 (sec x + cos ec 2 x − 2)dx

2
Sol.
 /6
= [tan x − cot x − 2x] /4

   1 2 
= 1 − 1 −  −  − 3− 
 2  3 6 
 2  2 
= − + + = −
2 3 3 3 6
k =6

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Rankers Academy JEE

Pattern – 1 QP Code: 100284 RIT – 1

Time Allotted: 3 Hours Maximum Marks: 198

B. Filling of OMR Sheet

C. Marking Scheme For All Two Parts.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

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1. A man standing on a truck which moves with a

2. The resultant of A + B is R1 . On reversing the vector B , the resultant becomes R2 , what

3. Four rods each of length l have been hinged to form a rhombus. y

4. The relation between time t and distance x moved by a particle is t x2 x where 

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6. Two particles are projected simultaneously from two points, O

(C) d/(2v cos α) (D) d/v α

(Multi Correct Choice Type)

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3. A particle is thrown horizontally with relative velocity

4. If A  B = A  B and A & B are 2 2 and 3 respectively, determine C = A  B .

5. Referring to v–s diagram, if magnitude of acceleration

6. Two ports A and B are separated by a river of width D. B

water so that it moves along A, then find the value of n A

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(Multi Correct Choice Type)

8. The outermost electronic configuration of three atoms are given below

9. Nine gram of water contains

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(C) 2p will be zero when  = 90o

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5. The electronic configuration of an atom(X) is 1s22s22p63s23p64s2

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1. The minimum value of cos x cos 60o − x cos 60o + x is ( ) ( )

sin x sec x tan x  

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6. Let x = sin1o , then the value of the expression

(Multi Correct Choice Type)

sin  sin3 sin9

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Hints & Solutions

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 (sec x + cos ec 2 x − 2)dx

= [tan x − cot x − 2x] /4

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Batch :__ Date of Examination :_