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Chemistry: A Molecular Approach, 1ce
Chapter 10: Chemical Bonding II: Molecular Shapes, Valence Bond Theory, and Molecular Orbital Theory
Chapter 10 Chemical Bonding II: Molecular Shapes, Valence Bond Theory, and
Molecular Orbital Theory
1) Give the approximate bond angle for a molecule with a trigonal planar shape.
A) 109.5°
B) 180°
C) 120°
D) 105°
E) 90°
Answer: C
Diff: 1 Type: MC Var: 1 Page Ref: 10.2
2) Give the approximate bond angle for a molecule with a tetrahedral shape.
A) 109.5°
B) 180°
C) 120°
D) 105°
E) 90°
Answer: A
Diff: 1 Type: MC Var: 1 Page Ref: 10.2
3) Give the approximate bond angle for a molecule with a linear shape.
A) 109.5°
B) 180°
C) 120°
D) 105°
E) 90°
Answer: B
Diff: 1 Type: MC Var: 1 Page Ref: 10.2
4) Give the approximate bond angle for a molecule with an octahedral shape.
A) 109.5°
B) 180°
C) 120°
D) 105°
E) 90°
Answer: E
Diff: 1 Type: MC Var: 1 Page Ref: 10.2
5) Give the approximate bond angle between the axial position and the equatorial position for a molecule
with a trigonal bipyramidal geometry.
A) 109.5°
B) 180°
C) 120°
D) 105°
E) 90°
Answer: E
Diff: 1 Type: MC Var: 1 Page Ref: 10.2
6) Give the approximate bond angle between two equatorial positions for a molecule with a trigonal
bipyramidal geometry.
A) 109.5°
B) 180°
C) 120°
D) 105°
E) 90°
Answer: C
Diff: 1 Type: MC Var: 1 Page Ref: 10.2
7) Determine the electron geometry (eg) and molecular geometry (mg) of BCl3.
A) eg = trigonal planar, mg = trigonal planar
B) eg = tetrahedral, mg = trigonal planar
C) eg = tetrahedral, mg = trigonal pyramidal
D) eg = trigonal planar, mg = bent
E) eg = trigonal bipyramidal, mg = trigonal bipyramidal
Answer: A
Diff: 2 Type: MC Var: 1 Page Ref: 10.2
8) Determine the electron geometry (eg) and molecular geometry (mg) of CO32⁻.
A) eg = tetrahedral, mg = tetrahedral
B) eg = tetrahedral, mg = trigonal pyramidal
C) eg = trigonal planar, mg = bent
D) eg = trigonal planar, mg = trigonal planar
E) eg = tetrahedral, mg = trigonal planar
Answer: D
Diff: 2 Type: MC Var: 1 Page Ref: 10.2
9) Determine the electron geometry (eg) and molecular geometry (mg) of CH3+1.
A) eg = tetrahedral, mg = tetrahedral
B) eg = tetrahedral, mg = trigonal pyramidal
C) eg = trigonal planar, mg = bent
D) eg = trigonal planar, mg = trigonal planar
E) eg = tetrahedral, mg = trigonal planar
Answer: D
Diff: 2 Type: MC Var: 1 Page Ref: 10.2
10) Determine the electron geometry (eg) and molecular geometry (mg) of SiF4.
A) eg = tetrahedral, mg = trigonal pyramidal
B) eg = octahedral, mg = square planar
C) eg = trigonal bipyramidal, mg = trigonal pyramidal
D) eg = tetrahedral, mg = bent
E) eg = tetrahedral, mg = tetrahedral
Answer: E
Diff: 2 Type: MC Var: 1 Page Ref: 10.2
11) Determine the electron geometry (eg) and molecular geometry (mg) of PF5.
A) eg = trigonal bipyramidal, mg = trigonal bipyramidal
B) eg = octahedral, mg = octahedral
C) eg = trigonal bipyramidal, mg = tetrahedral
D) eg = tetrahedral, mg = trigonal pyramidal
E) eg = trigonal planar, mg = octahedral
Answer: A
Diff: 2 Type: MC Var: 1 Page Ref: 10.2
12) Determine the electron geometry (eg) and molecular geometry (mg) of CO2.
A) eg = tetrahedral, mg = tetrahedral
B) eg = linear, mg = trigonal planar
C) eg = trigonal planar, mg = bent
D) eg = linear, mg = linear
E) eg = trigonal planar, mg = trigonal planar
Answer: D
Diff: 2 Type: MC Var: 1 Page Ref: 10.2
13) Determine the electron geometry (eg) and molecular geometry (mg) of NCl3.
A) eg = tetrahedral, mg = tetrahedral
B) eg = linear, mg = trigonal planar
C) eg = trigonal planar, mg = bent
D) eg = linear, mg = linear
E) eg = tetrahedral, mg = trigonal pyramidal
Answer: E
Diff: 2 Type: MC Var: 1 Page Ref: 10.2
14) Give the approximate bond angle for a molecule with trigonal planar electron geometry and bent
molecular geometry.
A) <90°
B) 90°
C) <120°
D) <109.5°
E) 120°
Answer: C
Diff: 2 Type: MC Var: 1 Page Ref: 10.3
15) Give the approximate bond angle for a molecule with tetrahedral electron geometry and trigonal
pyramidal molecular geometry.
A) 180°
B) <180°
C) <109.5°
D) 109.5°
E) <120°
Answer: C
Diff: 2 Type: MC Var: 1 Page Ref: 10.3
16) Give the approximate bond angle for a molecule with tetrahedral electron geometry and bent
molecular geometry.
A) 180°
B) <180°
C) <109.5°
D) 109.5°
E) <120°
Answer: C
Diff: 2 Type: MC Var: 1 Page Ref: 10.3
17) Give the approximate bond angle for a molecule with trigonal bipyramidal electron geometry and
seesaw molecular geometry.
A) <120° (equatorial), 90° (axial)
B) 120° (equatorial), <90° (axial)
C) <90° (equatorial), <90° (axial)
D) 120° (equatorial), 90° (axial)
E) <120° (equatorial), <90° (axial)
Answer: E
Diff: 2 Type: MC Var: 1 Page Ref: 10.3
18) Give the approximate bond angle for a molecule with T-shape molecular geometry.
A) <90°
B) 90°
C) >90°
D) <120°
E) 120°
Answer: A
Diff: 2 Type: MC Var: 1 Page Ref: 10.3
19) Give the approximate bond angle for a molecule with trigonal bipyramidal electron geometry and
linear molecular geometry.
A) 180°
B) <180°
C) >180°
D) <109.5°
E) <120°
Answer: A
Diff: 2 Type: MC Var: 1 Page Ref: 10.3
20) Give the approximate bond angle for a molecule with octahedral electron geometry and square
21) Give the approximate bond angle for a molecule with octahedral electron geometry and square planar
molecular geometry.
A) 90°
B) 180°
C) >120°
D) <90°
E) <120°
Answer: A
Diff: 2 Type: MC Var: 1 Page Ref: 10.3
22) Determine the electron geometry (eg) and molecular geometry (mg) of BrF3.
A) eg = trigonal planar, mg = trigonal planar
B) eg = trigonal bipyramidal, mg = T-shape
C) eg = trigonal planar, mg = bent
D) eg = trigonal bipyramidal, mg = seesaw
E) eg = tetrahedral, mg = trigonal pyramidal
Answer: B
Diff: 3 Type: MC Var: 1 Page Ref: 10.4
35) Determine the electron geometry (eg) and molecular geometry (mg) of ICl2⁻.
A) eg = tetrahedral, mg = bent
B) eg = tetrahedral, mg = trigonal pyramidal
C) eg = trigonal bipyramidal, mg = linear
D) eg = trigonal bipyramidal, mg = trigonal planar
E) eg = octahedral, mg = linear
Answer: C
Diff: 3 Type: MC Var: 1 Page Ref: 10.4
36) Determine the electron geometry (eg) and molecular geometry (mg) of XeF2.
A) eg = trigonal bipyramidal, mg = bent
B) eg = linear, mg = linear
C) eg = tetrahedral, mg = linear
D) eg = trigonal bipyramidal, mg = linear
E) eg = tetrahedral, mg = bent
Answer: D
Diff: 3 Type: MC Var: 1 Page Ref: 10.4
37) Determine the electron geometry (eg) and molecular geometry (mg) of XeF4.
A) eg = tetrahedral, mg = tetrahedral
B) eg = linear, mg = linear
C) eg = tetrahedral, mg = bent
D) eg = trigonal bipyramidal, mg = tetrahedral
E) eg = octahedral, mg = square planar
Answer: E
Diff: 3 Type: MC Var: 1 Page Ref: 10.4
38) Determine the electron geometry (eg) and molecular geometry (mg) of the underlined atom
CH3OCH3.
A) eg = tetrahedral, mg = tetrahedral
B) eg = linear, mg = linear
C) eg = tetrahedral, mg = bent
D) eg = trigonal bipyramidal, mg = tetrahedral
E) eg = octahedral, mg = square planar
Answer: A
Diff: 3 Type: MC Var: 1 Page Ref: 10.4
39) Determine the electron geometry (eg) and molecular geometry (mg) of the underlined atom
CH3OCH3.
A) eg = tetrahedral, mg = tetrahedral
B) eg = linear, mg = linear
C) eg = tetrahedral, mg = bent
D) eg = trigonal bipyramidal, mg = tetrahedral
E) eg = octahedral, mg = square planar
Answer: C
Diff: 3 Type: MC Var: 1 Page Ref: 10.4
40) Consider the molecule below. Determine the molecular geometry at each of the two labelled carbons.
A) C1 = tetrahedral, C2 = linear
B) C1 = trigonal planar, C2 = bent
C) C1 = bent, C2 = trigonal planar
D) C1 = trigonal planar, C2 = tetrahedral
E) C1 = trigonal pyramidal, C2 = seesaw
Answer: D
Diff: 3 Type: MC Var: 1 Page Ref: 10.4
41) Consider the molecule below. Determine the molecular geometry at each of the three labelled atoms.
42) Place the following in order of increasing X-Se-X bond angle, where X represents the outer atoms in
each molecule.
43) Place the following in order of increasing F-A-F bond angle, where A represents the central atom in
each molecule.
44) Place the following in order of decreasing X-A-X bond angle, where A represents the central atom and
X represents the outer atoms in each molecule.
45) Place the following in order of decreasing X-A-X bond angle, where A represents the central atom and
X represents the outer atoms in each molecule.
46) Place the following in order of increasing X-A-X bond angle, where A represents the central atom and
X represents the outer atoms in each molecule.
47) A pilot checks for water in the gas before flying a small airplane. How does she do it?
A) She drains a little bit of gas from the bottom and looks for two layers.
B) She smells it.
C) She shakes the wings.
D) She pipets the liquid from the top of the tank and looks for two layers.
E) She checks the gas gauge.
Answer: A
Diff: 1 Type: MC Var: 1 Page Ref: 10.5
48) Determine the electron geometry (eg), molecular geometry (mg), and polarity of SO3.
A) eg = tetrahedral, mg = trigonal pyramidal, polar
B) eg = tetrahedral, mg = tetrahedral, nonpolar
C) eg = trigonal planar, mg = trigonal planar, nonpolar
D) eg = trigonal bipyramidal, mg = trigonal planar, polar
E) eg = trigonal pyramidal, mg = bent, nonpolar
Answer: C
Diff: 2 Type: MC Var: 1 Page Ref: 10.5
A) 1
B) 2
C) 3
D) 4
E) 0
Answer: A
Diff: 3 Type: MC Var: 1 Page Ref: 10.5
A) 0
B) 3
C) 1
D) 2
E) 4
Answer: B
Diff: 3 Type: MC Var: 1 Page Ref: 10.5
A) 1
B) 4
C) 2
D) 3
E) 0
Answer: C
Diff: 3 Type: MC Var: 1 Page Ref: 10.5
A) 2
B) 0
C) 1
D) 3
E) 4
Answer: D
Diff: 3 Type: MC Var: 1 Page Ref: 10.5
53) Determine the electron geometry (eg), molecular geometry (mg), and polarity of SO2.
A) eg = tetrahedral, mg = bent, polar
B) eg = trigonal planar, mg = bent, polar
C) eg = linear, mg = linear, nonpolar
D) eg = tetrahedral, mg = tetrahedral, nonpolar
E) eg = trigonal pyramidal, mg = trigonal pyramidal, polar
Answer: B
Diff: 3 Type: MC Var: 1 Page Ref: 10.5
54) Determine the electron geometry (eg), molecular geometry (mg), and polarity of SF6.
A) eg = trigonal bipyramidal, mg = trigonal bipyramidal, nonpolar
B) eg = tetrahedral, mg = tetrahedral, polar
C) eg = trigonal bipyramidal, mg = seesaw, polar
D) eg = octahedral, mg = trigonal bipyramidal, nonpolar
E) eg = octahedral, mg = octahedral, nonpolar
Answer: E
Diff: 3 Type: MC Var: 1 Page Ref: 10.5
55) Determine the electron geometry (eg), molecular geometry (mg), and polarity of TeCl6.
A) eg = octahedral, mg = octahedral, nonpolar
B) eg = trigonal bipyramidal, mg = trigonal bipyramidal, nonpolar
C) eg = octahedral, mg = square planar, polar
D) eg = trigonal bipyramidal, mg = seesaw, polar
E) eg = tetrahedral, mg = trigonal pyramidal, polar
Answer: A
Diff: 3 Type: MC Var: 1 Page Ref: 10.5
56) Determine the electron geometry (eg), molecular geometry (mg), and polarity of XeO3.
A) eg = trigonal planar, mg = trigonal planar, nonpolar
B) eg = tetrahedral, mg = trigonal pyramidal, polar
C) eg = trigonal planar, mg = trigonal pyramidal, polar
D) eg = trigonal bipyramidal, mg = trigonal planar, nonpolar
E) eg = octahedral, mg = tetrahedral, nonpolar
Answer: B
Diff: 3 Type: MC Var: 1 Page Ref: 10.5
57) Determine the electron geometry (eg), molecular geometry (mg), and polarity of HBrO2.
A) eg = trigonal bipyramidal, mg = trigonal planar, nonpolar
B) eg = octahedral, mg = square planar, nonpolar
C) eg = tetrahedral, mg = bent, polar
D) eg = tetrahedral, mg = linear, nonpolar
E) eg = linear, mg = linear, polar
Answer: C
Diff: 3 Type: MC Var: 1 Page Ref: 10.5
58) Determine the electron geometry (eg), molecular geometry (mg), and polarity of SF6.
A) eg = trigonal bipyramidal, mg = trigonal bipyramidal, nonpolar
B) eg = tetrahedral, mg = tetrahedral, polar
C) eg = trigonal bipyramidal, mg = seesaw, polar
D) eg = octahedral, mg = trigonal bipyramidal, nonpolar
E) eg = octahedral, mg = octahedral, nonpolar
Answer: E
Diff: 3 Type: MC Var: 1 Page Ref: 10.5
59) Choose the compound below that contains at least one polar covalent bond but is nonpolar.
A) HCN
B) CF4
C) SeBr4
D) ICl3
E) Both B and C are nonpolar and contain a polar covalent bond.
Answer: B
Diff: 3 Type: MC Var: 1 Page Ref: 10.5
60) Choose the compound below that contains at least one polar covalent bond but is nonpolar.
A) GeH2Br2
B) SCl2
C) AsCl5
D) CF2Cl2
E) All of the above are nonpolar and contain a polar covalent bond.
Answer: C
Diff: 3 Type: MC Var: 1 Page Ref: 10.5
A) I < II = III
B) II < III < I
C) I < II < III
D) II < I < III
E) I < III < II
Answer: E
Diff: 3 Type: MC Var: 1 Page Ref: 10.5
63) Determine the electron geometry (eg), molecular geometry (mg), and polarity of N2O (N central).
A) eg = linear, mg = linear, nonpolar
B) eg = tetrahedral, mg = linear, nonpolar
C) eg = tetrahedral, mg = bent, polar
D) eg = linear, mg = linear, polar
E) eg = trigonal planar, mg = bent, polar
Answer: D
Diff: 3 Type: MC Var: 1 Page Ref: 10.5
66) A molecule containing a central atom with sp hybridization has a ________ electron geometry.
A) linear
B) trigonal bipyramidal
C) trigonal planar
D) tetrahedral
E) bent
Answer: A
Diff: 1 Type: MC Var: 1 Page Ref: 10.7
67) Identify the number of electron groups around a molecule with sp hybridization.
A) 1
B) 2
C) 3
D) 4
E) 5
Answer: B
Diff: 1 Type: MC Var: 1 Page Ref: 10.7
68) A molecule containing a central atom with sp2 hybridization has a ________ electron geometry.
A) linear
B) trigonal bipyramidal
C) trigonal planar
D) tetrahedral
E) bent
Answer: C
Diff: 1 Type: MC Var: 1 Page Ref: 10.7
69) Identify the number of electron groups around a molecule with sp2 hybridization.
A) 1
B) 2
C) 3
D) 4
E) 5
Answer: C
Diff: 1 Type: MC Var: 1 Page Ref: 10.7
70) A molecule containing a central atom with sp3 hybridization has a(n) ________ electron geometry.
A) linear
B) trigonal bipyramidal
C) octahedral
D) tetrahedral
E) bent
Answer: D
Diff: 1 Type: MC Var: 1 Page Ref: 10.7
71) Identify the number of electron groups around a molecule with a tetrahedral shape.
A) 1
B) 2
C) 3
D) 4
E) 5
Answer: D
Diff: 1 Type: MC Var: 1 Page Ref: 10.7
72) A molecule containing a central atom with sp3d hybridization has a(n) ________ electron geometry.
A) tetrahedral
B) linear
C) octahedral
D) trigonal planar
E) trigonal bipyramidal
Answer: E
Diff: 1 Type: MC Var: 1 Page Ref: 10.7
73) Identify the number of electron groups around a molecule with a trigonal bipyramidal shape.
A) 1
B) 2
C) 3
D) 4
E) 5
Answer: E
Diff: 1 Type: MC Var: 1 Page Ref: 10.7
74) A molecule containing a central atom with eight electron groups has a(n) ________ electron geometry.
A) octahedral
B) trigonal bipyramidal
C) tetrahedral
D) trigonal planar
E) trigonal pyramidal
Answer: A
Diff: 1 Type: MC Var: 1 Page Ref: 10.7
75) Determine the electron geometry (eg) and molecular geometry (mg) of the underlined carbon in
CH3CN.
A) eg = tetrahedral, mg = tetrahedral
B) eg = linear, mg = trigonal planar
C) eg = trigonal planar, mg = bent
D) eg = linear, mg = linear
E) eg = trigonal planar, mg = trigonal planar
Answer: D
Diff: 2 Type: MC Var: 1 Page Ref: 10.7
76) Determine the electron geometry (eg) and molecular geometry (mg) of the underlined carbon in
CH3CN.
A) eg = tetrahedral, mg = tetrahedral
B) eg = linear, mg = trigonal planar
C) eg = trigonal planar, mg = bent
D) eg = linear, mg = linear
E) eg = trigonal planar, mg = trigonal planar
Answer: A
Diff: 2 Type: MC Var: 1 Page Ref: 10.7
77) Determine the electron geometry (eg) and molecular geometry (mg) of H2CO.
A) eg = tetrahedral, mg = tetrahedral
B) eg = linear, mg = trigonal planar
C) eg = trigonal planar, mg = bent
D) eg = linear, mg = linear
E) eg = trigonal planar, mg = trigonal planar
Answer: E
Diff: 2 Type: MC Var: 1 Page Ref: 10.7
78) Draw the Lewis structure for OF2. What is the hybridization on the O atom?
A) sp
B) sp3
C) sp2
D) sp3d
E) sp3d2
Answer: B
Diff: 3 Type: MC Var: 1 Page Ref: 10.7
79) Draw the Lewis structure for H3O+. What is the hybridization on the O atom?
A) sp
B) sp3
C) sp2
D) sp3d
E) sp3d2
Answer: B
Diff: 3 Type: MC Var: 1 Page Ref: 10.7
80) Draw the Lewis structure for SO3. What is the hybridization on the S atom?
A) sp
B) sp3
C) sp2
D) sp3d
E) sp3d2
Answer: C
Diff: 3 Type: MC Var: 1 Page Ref: 10.7
81) Draw the Lewis structure for BrO4⁻. What is the hybridization on the Br atom?
A) sp
B) sp3d2
C) sp3d
D) sp3
E) sp2
Answer: D
Diff: 3 Type: MC Var: 1 Page Ref: 10.7
82) Draw the Lewis structure for CCl4. What is the hybridization on the C atom?
A) sp
B) sp3d2
C) sp3d
D) sp3
E) sp2
Answer: D
Diff: 3 Type: MC Var: 1 Page Ref: 10.7
83) Draw the Lewis structure for CO2. What is the hybridization on the C atom?
A) sp
B) sp3d2
C) sp3d
D) sp3
E) sp2
Answer: A
Diff: 3 Type: MC Var: 1 Page Ref: 10.7
84) Draw the Lewis structure for BF3. What is the hybridization on the B atom?
A) sp
B) sp3d2
C) sp3d
D) sp3
E) sp2
Answer: E
Diff: 3 Type: MC Var: 1 Page Ref: 10.7
85) Draw the Lewis structure for COCl2. What is the hybridization on the C atom?
A) sp
B) sp3d2
C) sp3d
D) sp3
E) sp2
Answer: E
Diff: 3 Type: MC Var: 1 Page Ref: 10.7
86) Draw the Lewis structure for SO2-3. What is the hybridization on the S atom?
A) sp
B) sp3d2
C) sp3d
D) sp3
E) sp2
Answer: D
Diff: 3 Type: MC Var: 1 Page Ref: 10.7
87) Draw the Lewis structure for N2H2. What is the hybridization on the N atoms?
A) sp
B) sp3d2
C) sp3d
D) sp3
E) sp2
Answer: E
Diff: 3 Type: MC Var: 1 Page Ref: 10.7
88) Draw the Lewis structure for C2H2. What is the hybridization on the C atoms?
A) sp
B) sp3d2
C) sp3d
D) sp3
E) sp2
Answer: A
Diff: 3 Type: MC Var: 1 Page Ref: 10.7
89) Consider the molecule below. Determine the hybridization at each of the two labelled carbons.
A) C1 = sp3, C2 = sp3d
B) C1 = sp, C2 = sp2
C) C1 = sp2, C2 = sp3d
D) C1 = sp3d, C2 = sp3d2
E) C1 = sp2, C2 = sp3
Answer: E
Diff: 3 Type: MC Var: 1 Page Ref: 10.7
90) Consider the molecule below. Determine the hybridization at each of the three labelled atoms.
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