101st Earthborn ET, LP – Product Data Sheet (PDS) ULTRASERIES

ULTRASERIES
and Supportive Documentation (FF-01)
(FF-01)

GENERAL
DESCRIPTION

GENERAL DESCRIPTION-ULTRASERIES FF-01 is a non-toxic, biodegradable chemical formulated specifically

for use in the oil and gas industry for use in wells and radial drilling to clean downhole piping, perforations,
backside and also calcium carbonate formations to create wormholes and to substantially increase the amount of
fluid flowback, and in some cases up to 400%+ more increase of permeability has been experienced compared to
using HCL (producing more conductive pathways), dependent upon the application and other factors present at the
drilling site. It also does not harm equipment, the environment or the workers using it and also removes many
contaminants and deposits that impact the surfaces. It does not damage caulk, rubber or plastic parts. It also has
other uses in the oil and gas recovery process which can be determined by our Oil and Gas Technical representative.

PRODUCT DESCRIPTION: FF-01 is a clear to amber, non-toxic chemical, biodegradable,

nonflammable, environmentally friendly, non-regulated and worker/people safe product.
PERFORMANCE CRITERIA: Contact your representative for specifics.
LIMITATIONS: Please refer to MSDS sheet.

TECHNICAL
DATA

Physical state : ( ) GAS (x) LIQUID ( ) SOLID

Odor and appearance: Clear / light amine odor
Threshold odor : N/A
Density : l.61
Vapor pressure (mm Hg): 14mm Hg/20 deg. C
Vapor density (air = 1): N/A
Evaporation rate: Same as water
Boiling point: 350 degrees F [par]
Freezing point (degrees F) : -34 degrees F [par]
Solubility in water (70 degrees F) : Complete
PH : .5-2 initial
Volatile organic compounds
(VOC) contents: no VOC contents
SHELF LIFE: 12 months at recommended storage temperature.
FLASH POINT: None-Close Cup
HEALTH & SAFETY: Read container label and Material Safety Data Sheet health and safety information
Keep out of the reach of children.
Coverage Rates: Coverage rates vary depending upon factors such as operator application techniques, density of substrate, composite or type of substrate,
field/project circumstances, atmospheric/environmental conditions and other factors experienced relative to the application.
We customize the approach dependent upon your well.

Product Application Procedures: Please see Initial procedure sheet at end of this document
Do not use this product on any surface or application that it is not intended for. Our products are specifically formulated for use on targeted substrates within
the Series that the product(s) are/were formulated for.

Supportive Data and Technical Information: For any other information, please refer to the MSDS sheet and/or contact your representative.
For additional Technical Information: Please contact your representative to process any additional information needed.
MANUFACTURED BY: 101st Earthborn Environmental Technologies, LP
FOR ADDITIONAL INFORMATION, PLEASE CONTACT YOUR REPRESENTATIVE OR OUR SALES AND MARKETING DIVISION-
EARTHBORN CLEAN VIA OUR V.P OF SALES AND MARKETING, KYLE TAYLOR AT: info@earthbornclean.com / Toll-Free: 1-888-767-
4450 Extension 3
If in USA: Direct Line is 785-856-4500
 101ST EARTHBORNTM PRODUCT INFORMATION
MATERIAL SAFETY DATA SHEET

SECTION I – CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

COMPANY INFORMATION:

101st Earthborn Environmental

Technologies, LP
1235 South Country Club Road
Colby, Kansas 67701
1-888-767-4450

PRODUCT INFORMATION

Product Name/Number: 101st Earthborn Products- Decontamination Series-FF-01

Trade Name: Earthborn Clean – Well Extraction/Enhancement Fluid
Product Description (product use): Oil/Gas Well Cleaner and Formation Fluid
Enhancer

SECTION II – COMPOSITION / INFORMATION ON I N G R E D I E N T S

This Material Safety Data Sheet is prepared to comply with the United States Occupation
Safety and Health Administration (OSHA) Hazard Communication Standard (29 CFR
1910.1200
Unlisted ingredients are not “hazardous” per the OSHA standard.

Hazardous ingredients: No Hazardous Ingredients

FLAMMABILITY : <0>
Approx. concentration (%) : Proprietary
REACTIVITY : <0>
#CAS – NA or UN : N/A
HEALTH :<1>
DL 50 (specific type and way): N/A
Limit of exposition: none

101st EarthbornTM Descalers/Decontaminators do not contain any of

the following ingredients: Halogen, Fluoride, Chloride, Sulfate or
Heavy Metals.
 MATERIAL SAFETY DATA SHEET

SECTION III – FIRE AND EXPLOSION HAZARD DATES

Inflammability : ( ) yes (x) no

Extinguishing media : water – foam – powder, dry chemical
Special method : none
Flash point / method : none close cup
Flammability limits in air (% per volume) : N/D
Temperature auto ignition (degrees F) : N/A
Class of flammability THD : N/D
Unusual fire and explosion hazard : none
Explosion data : none
Sensibility of chemical impact : none
Combustion rate : N/A
Sensibility of electrostatic discharge : N/A

SECTION IV – PHYSICAL CHARACTERISTICS

Physical state : ( ) GAS (x) LIQUID ( ) SOLID

Odor and appearance : Clear toAmber / light amine odor
Threshold odor : N/A
Density : l.61
Vapor pressure (mm Hg) : 14mm Hg/20 deg. C
Vapor density (air = 1) : N/A
Evaporation rate : Same as water
Boiling point : 350 degrees F [par]
Freezing point (degrees F) : -34 degrees F [par]
Solubility in water (70 degrees F) : Complete
PH : .5-2 initial
Volatile organic compounds
(VOC) contents : no VOC contents

SECTION V – REACTIVITY DATA

Chemical stability : (x) yes ( ) no

If yes, in which conditions? : if stored at the recommended temperature
Incompatibility (Materials to avoid): *(Pertains to storage only-do not store in close proximity)Avoid
contact with materials such as sulfides and sulfites while storing which could release toxic gases, and be
cautious in mixing with strong Alkali bases because high heat of reaction can generate steam.
Hazardous Decomposition Materials: None
Hazardous Polymerization: None
Condition to Avoid for Polymerization: None described
Stability Considerations: Stable
Conditions to Avoid for Stability: None Known

SECTION VI – POTENTIAL HEALTH EFFECTS

Eyes: Eye contact with liquid product may cause irritation.

Skin: Prolonged or repeated contact with liquid product may cause light irritation.
Inhalation: Exposure to vapors in poorly ventilated areas may cause light irritation of
the nose.
Ingestion: Small amounts are not harmful.

SECTION VII – TOXICITY DATA

Chronic effects of exposure to the product : none

Irritations : none
Exposition limit : see Section II
CL50 of product : N/A
Sensibility : N/N
Synergic Material
• Carcinogenicity effects : none
• Harmful effects of reproduction : none
• Teratogenes effects : none
• Mutageny effects : none

SECTION VIII – FIRST AID MEASURES

Skin: wash with water for a few minutes

Eyes: rinse with water for a few minutes, if irritation
persists consult a physician
Ingestion: drink one or two glasses of water or milk. Do not
induce vomiting, consult a physician if stomach ache persists.
General recommendation: none

SECTION IX – SPILL OR LEAK PROCEDURES

Small Spills: Spill and absorbent disposal procedure. Layer dirt, absorbent shop material
(known under one name as Oil absorb) any other absorbent material(S) [rags, old
newspaper, etc.] Rinse copiously with water. *Follow any other local jurisdictional
requirements for nontoxic-nonflammable materials if necessary
Large Spills: Most Tanker and Tank Haulers keep a emergency spill kit readily
available. Check (before loading and leaving-See picture #1 below). FIND THE
SOURCE OF THE LEAK AND STOP IT. Analyze the situation immediately to
determine if a slip hazard is present. Stop traffic flow or reroute (based on BMP) if
necessary.
Boom affected area off to contain spill to a smaller localized area (air pillows,
containment berms, etc.) Follow the same general procedures as small spills, only
increase the amount of material needed to cover the spill. After moving the material
used to absorb (shoveling, vacuuming, etc.) the dirt, sand or other absorbents to the
clean-up containers, these vessels can then be disposed of in most landfills, dependent
upon if any other contaminant impacted the area while the clean-up was being
performed. All work and procedures must conform to Federal, State and Municipal
regulations.

To assist with visuals of the various methods referenced above, please see the pictorials
below
SECTION XI – PERSONAL PROTECTION

Protection equipment:
• Gloves: rubber gloves
• Respiration protection: none
• Eye protection: goggles
• Shoes: normal
• Clothing: normal
• Control mechanic device: none

SECTION XI – SPECIAL PRECAUTIONS

Precautions to be taken in handling and storing: Store drums away from excessive heat.

SECTION XII – TRANSPORTATION INFORMATION

Transportation: DOT
Class 55 - Not regulated

SECTION XIII – REGULATORY INFORMATION

SARA TITLE III

Section 313: This product does not contain regulated levels of any toxic chemical subject
to the reporting requirements of section 313 of Title III of the Superfund
Amendments and Reauthorization Act of 1986 (SARA) and 40 CFR 372.

STATE REGULATION
FEDERAL
Toxic Substance Control Act (TSCA)
Section 8 (b) – Inventory Status
This product is in compliance with the Toxic Substances Control Act’s Inventory
requirements.
California Proposition 65: The Safe Drinking Water and Toxic Enforcement Act of 1986.
This product contains no chemical(s) known to the state of California to cause cancer (c)
reproductive (r) damage.
HMIS= 0
WHMIS/TDG: Not classified- not hazardous/non-toxic, refer to Section VII
GHS+ N/A, not regulated-non hazmat, refer to Section VII
NFPA= 0 – Non Flammable, refer to Sections II,III,IX
Rev Date: 5/21/15
The information contained in this MSDS was compiled using the latest and most reliable information available to. The information is provided without any warranty, express or implied regarding its
correctness or accuracy nor will we assume any liability for any loss or damage arising out of the use of this information including without limitation direct or indirect losses or expenses. To the
extent permitted by law, no warranty express or implied regarding the product described herein shall be created by or inferred from any statement or omission from this MSDS. It is solely the
responsibility of the user to determine safe conditions for use of this product and to assume liability for any loss, damage or expense whatsoever arising out of the product's improper use.
 SUPPORTIVE TECHNICAL/TESTING INFORMATION
If the reaction order is zero, then the reaction constant is the slope of the plot of Ca concentration vs. Time.
The equation that was used in COMSOL to get the reaction order and the reaction constant is:
∗ , 10
Where k is the reaction constant and β is the reaction order.

Ca concentration in 15 % HCl:

Time (min) Time (s) Ca in HCl Sample (ppm) Ca (mol/ m3)

0 0 0 0
1 60 800 19.9021
2 120 1845 45.8993
3 180 2550 63.4381
4 240 3350 83.3402
5 300 4325 107.5959
10 600 7900 196.5337
15 900 8100 201.5093
20 1200 10075 250.6427
25 1500 10825 269.3010

Results From Excel

Reaction order Reaction Constant
[The Linear Part] (10 minutes)
0 0.3280114

Results From COMSOL

Reaction order Reaction Constant
[The Linear Part] (10 minutes)
-0.0791 0.46336

Results From COMSOL

Reaction order Reaction Constant
(25 minutes)
-0.57368 3.07987

Ca Concentration in UltraSeries (FF-01):

Time (min) Time (s) Ca in Ultra Frac Sample (ppm) Ca (mol/ m3)
0 0 0 0
1 60 242.5 6.03284
2 120 307.5 7.64989
3 180 405 10.07546
4 240 510 12.68762
5 300 685 17.04122
10 600 1080 26.86790
15 900 1405 34.95315
 20 1200 2137.5 53.17605
25 1500 2445 60.82594

Results From Excel Reaction order Reaction Constant

0 0.0394510

Results From COMSOL

Reaction order Reaction Constant
[Using The Equation From Excel]
2.054890E-16 0.039640

Results From COMSOL

Reaction order Reaction Constant
[Using Data]
-0.17234 0.070010

Excel Plots:
Ca Concentration in 15% HCl
250

y = 0.3280114x + 3.5274937
200 R² = 0.9968310
Ca Concentration (mol/m^3)

150

100

50

0
0 100 200 300 400 500 600 700
Time (s)
 Ca Concentration in UltraSeries (F-01)
70

60 y = 0.039451x + 2.810905
R² = 0.990538
Ca Concentration (mol/m^3)

50

40

30

20

10

0
0 200 400 600 800 1000 1200 1400 1600
Time (s)

COMSOL Plots for 15% HCl:

COMSOL Plots for UltraSeries-FF-01:
 LC50 TESTING–SAFE FOR
DISCHARGE

832 N.W. 67Th Street, Oklahoma City, Oklahoma 73116 - Ph: 405.286.0468 -Fax: 405.286.0297

Report Date: 07/28/13 Lab Contact: D'Ann Wilkins Lab Certification: OK-AR
Report ldent: 101EA0713 Client Contact: Daniel Ackwith EPA LabID: OK01010
Client ldent: 126 ODEQ Lab lD: 9961
Test Type: Product Test
Client: 101st Earthborn Environmental Technologies, LP
1235 S. Country Club Drive
Colby, KS 67701

Sample Data
'
Sample # Description

2013-106 FF-01

Test Method/Description: Methods for Measuring the Acute Toxicity of Effluents to Freshwater and Marine Organisms
(EPA-821-R-02-012) 48-hour Acute Toxicity Test (Static-renewal) with D. pulex (Method 2021.0), and P. promelas
(Method 2000.0)

Deviations from Test Method: None.

Statistical Software Utilized: Tox Cale 5.0
Source of Organism Cultures: WILKINS ENVIRONMENTAL
Dilution Concentrations : 1000ppm, 875ppm, 750ppm, 625ppm, 500ppm, Oppm

PRODUCT TESTING RESULTS

FF-01
Effluent
Concentration Daphnia pulex Pimephales promelas
O DDffl 100 100
500 oom 100 100
Percen 625 DDm 0 0
t 750 oom 0 0
Surviva 875 oom 0 0
l 1000 DDffl 0 0

LC50 559 PDm 559 DDffl

NOEC 500 DDffl 500 DDffl
LOEC 625 DDffl 625 oom
Test Validity: No exceptions to or deviations from the prescribed test method.

Reviewed and Approved By:

Laboratory Report - Supporting Documentation Reportl
dent: 101EA0713

Table A
Summary of Effluent Toxicit Test Conditions for the Oaphnid(Daohn/a oulexJ
1. Test type: Static renewal (acute)
2. Temperature: 25•c ± 1 c
3. Light quallty: Ambient laboratory illumination
4. Lightintensity: 50 • 100 ft-c (ambient laboratory levels)
5. Photoperiod: 16 hours tight, 8 hours darkness
6. Size of test vessels: 30 mL
7. Test solution volume: 25 mL
8. Age of test organisms: Less than 24 hours old
9. No. of organisms per test vessel: 5
10. No. of replicate test vessels per concentration: 4
11. Total no. of organisms per concentration: 20
12. Test vessel randomization: Randomized
Fed 0.2 ml of YCT and Selenastrum capricomucum algal suspension prior to
13. Feeding regimen:
setup or renewal
14. Aeration: None
15. Diiution water: Moderately Hard Syntheic.
16. Effluent concentrations: 1000ppm, 875ppm, 750ppm, 625ppm, 500ppm, Oppm
17. Test acceptability: 90% or greater survival inthe controls
18. Test duration: 48 hours
19. Endpoints: Mortality

Table B
Summary of Effluent Toxicity Test Conditions for the Fathead Minnow (Plmepha/es promelas)
1. Test type: Static renewal (acute)
2. Temperature: 25•c ± 1 c
3. Light quality: Ambient laboratory illumination
4. Light intensity: 50 • 100ft-c (ambient laboratory levels)
5. Photoperiod: 16 hours light, 8 hours darkness
6. Test chamber size: 500 mL
7. Test solution volume: 200 mL
8. Renewal of test solutions: Daily @ 24-hours
9. Age of test organisms Less than 48 hour old
10. No.of organisms per chamber: 5
11. No.of replicate test chambers per concentration: 4
12. No.of organisms per concentration: 20
13. Feeding regimen: None
14. Aeration: None
15. Dilution water: Moderately Hard Syntheic.
16. Effluent concentrations: 1000ppm, 875ppm, 750ppm, 625ppm, 500ppm, Oppm
17. Test acceptability: 90% or greater survivalin controls
18. Test duration: 48 hours
19. Endpoints: Mortality
Laboratory Report - Supporting Documentation Reportl
dent: 101EA0713

Tabl
eC
Detailed Test Results
Daphnia pulex Percent Survival
Date/Time TestI
nitiated: 07/17/13. 1500 hrs Dilution water used: Moderately hard Synthetic
Time Concentration
Rep
Ooom 500oom 625oom 750oom 875oom 1000oom
A 100 100 0 0 0 0
24-hr B 100 100 0 0 0 0
Survival c 100 100 0 0 0 0
D 100 100 0 0 0 0
A 100 100 0 0 0 0
48-hr B 100 100 0 0 0 0
Survival c 100 100 0 0 0 0
D 100 100 0 0 0 0
Mean % Survival 100 100 0 0 0 0
Da11,hnia e,ulex reorting:
Report the Daphnia pulex 48-hour LC50 value for survival: [ 559ppm ]

Pimephales prome/as Percent Survival

Date/Time Test Initiated: 07/17/13, 1515 hrs Dilution water used: Moderately hard Synthetic
Concentration
Time Rep
100ppm 500ppm 625ppm 750ppm 875ppm 1000ppm
A 100 100 0 0 0 0
24-hr B 100 100 0 0 0 0
Survival c 100 100 0 0 0 0
D 100 100 0 0 0 0
A 100 100 0 0 0 0
48-hr B 100 100 0 0 0 0
Survival c 100 100 0 0 0 0
D 100 100 0 0 0 0
Mean % Survival 100 100 0 0 0 0
Fathead minnow reporting:
Report the Fathead minnow 48-hour LC50 value for survival: [ 559ppm J

The upper pages contain raw test data and statistical analysis data, including the
following:
• Acute Toxicity Test Raw Data Sheet(s)
• Statistical Analysis Data Sheet(s)
 ADDITIONALINFORMATION AND
UltraSeries FF-01 INITIAL PROCEDURALFORM FOR
BEGINNINGTHE PROCESS
Rheological Testi
Viscosity vs. Shear
10
Viscosity
cP

10 100 1000
10000
Shear Rate, s-1

UltraSeries FF-01 is pressure independent and is a non-Newtonian Fluid. FF-01’s thinning ability
during pumping allows for decreased horsepower usage during the pumping stage. However, once
the UltraSeries FF-01 reaches the formation matrix it becomes more viscous which allows for better
formation coverage and less fluid-loss, increasing the effectiveness of the product.

ADDITIONAL NOTE: 300 ml of FF-01 reaches equilibrium with a calcium carbonate addition of 27 grams.
This equates to 751 lbs of carbonate dissolved per 1,000 gallons of FF-01.
 Procedural FORM for Retrieving Produced Oil/Water Samples
Kerui, WellJet Energy Services, Earthborn Clean

Note: All produced oil/water samples need to be taken directly from the wellhead and must contain
between 50%-60% Oil cut. The sample container must be clean before retrieving samples. Please label
the sample container with Well Name and/or Well Number, Production Company Name, Country, and
Date of retrieval.

Please fill out complete report and include copy with the samples being shipped out:

Production Company Name:

Country of Origin:

Well Name and/or Well Number:

Depth of Oil Production: Meters or Feet (please circle one) Date of

Sample Taken:

Person Taking Sample:

Please initial the following box as showing completed: Initial Box

Retrieved from wellhead a minimum of 1 gallon produced oil/water with

50%-60% being produced oil. Made sure cap is secure for shipment.

Labeled sample with well name/#, company, country, and date.

All Samples will need to be shipped to the following address in the United States:

Baten Consulting Clay Baten

2712 SCR 1257
Midland TX 79706 U.S.A.
Phone 432-563-1768

Please scan and send copy of completed form to Kyle Taylor at

kyle.taylor@earthbornclean.com and Vicky Stone at keruigroupamerica@outlook.com

If you have any questions about these procedures, please contact Kyle Taylor via email at
kyle.taylor@earthbornclean.com or Skype Name kyle.taylor.ksjayhawk