FINAL JEE–MAIN EXAMINATION – APRIL, 2024

(Held On Monday 08th April, 2024) TIME : 3 : 00 PM to 6 : 00 PM

CHEMISTRY TEST PAPER WITH SOLUTION

SECTION-A
61. In qualitative test for identification of presence of
phosphorous, the compound is heated with an
oxidising agent. Which is further treated with nitric
Sol. Antibonding molecular orbitals are formed by
destructive interference of wave functions.
(ABMO) * = A – B
64. Which one the following compounds will readily

acid and ammonium molybdate respectively. The react with dilute NaOH?

yellow coloured precipitate obtained is : (1) C6H5CH2OH (2) C2H5OH

(3) (CH3)3COH (4) C6H5OH
(1) Na 3 PO4 .12MoO3
Ans. (4)
(2)  NH 4 3 PO 4 .12  NH 4 2 MoO 4

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OH O¯Na+
(3)  NH 4 3 PO 4 .12MoO3
Sol. + NaOH + H2O
(4) MoPO4 .21NH4 NO3
Ans. (3) Stronger ACID than H2O
+
H
Sol. PO43– + (NH4)2MoO4 (NH4)3PO4.12MoO3  65. The shape of carbocation is :
Or HPO4– Ammonium Canary yellow ppt.
Molybdate (Ammonium phopho (1) trigonal planar (2) diagonal pyramidal
molybdate) (3) tetrahedral (4) diagonal
62. For a reaction A  B C
K1 K2
Ans. (1)
If the rate of formation of B is set to be zero then H
the concentration of B is given by : Sol. Carbocation C
(1) K1K2[A] (2) (K1 – K2)[A] H H
Trigonal planar
(3) (K1 + K2)[A] (4) (K1/K2)[A]
66. Given below are two statements :
Ans. (4)
Statement (I) : SN2 reactions are 'stereospecific',
Sol. Rate of formation of B is indicating that they result in the formation only one
d  B stereo-isomers as the product.
 k1  A   k 2  B
dt Statement (II) : SN1 reactions generally result in
0 = k1[A] – k2[B] formation of product as racemic mixtures. In the
light of the above statements, choose the correct
 k1 
   A    B answer from the options given below :
 k2  (1) Statement I is true but Statement II is false
63. When  and B are the wave functions of atomic (2) Statement I is false but Statement II is true
(3) Both Statement I and Statement II is true
orbitals, then * is represented by :
(4) Both Statement I and Statement II is false
(1) A – 2B (2) A – B Ans. (3)
(3) A + 2B (4) A + B Sol. SN2  Inversion
Ans. (2) SN1  Racemisation

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67. Match List-I with List-II. 68. Match List-I with List-II.
List-I List-II List-I List-II
(Reactions) (Products) (Test) (Identification)
NH2 OH (A) Bayer's test (I) Phenol
CHO
(i) NaNO2 + HCl (B) Ceric ammonium (II) Aldehyde
(A) (I)
(ii) H2O, warm nitrate test
(C) Phthalein dye test (III) Alcoholic-OH
OH OH
group
Na2Cr2O7
(B) (II) (D) Schiff's test (IV) Unsaturation
H2SO4
Choose the correct answer from the options given
OH OH below :
COOH
(i) CHCl3+aq NaOH
(1) (A)-(III), (B)-(I), (C)-(IV), (D)-(II)
(C) (ii) H+
(III) (2) (A)-(II), (B)-(III), (C)-(IV), (D)-(I)

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(3) (A)-(IV), (B)-(I), (C)-(II), (D)-(III)
OH O (4) (A)-(IV), (B)-(III), (C)-(I), (D)-(II)
(i) NaOH Ans. (4)
(D) (IV)
(ii) CO2 Sol. (A) Bayer's test  Unsaturation
(iii) H+
O (B) Ceric ammonium nitrate test  Alcoholic-OH group
Choose the correct answer from the options given (C) Phthalein dye test Phenol
below : (D) Schiff's test Aldehyde
(1) (A)-(III), (B)-(II), (C)-(I), (D)-(IV) 69. Identify the incorrect statements about group 15
(2) (A)-(IV), (B)-(II), (C)-(III), (D)-(I) elements :
(3) (A)-(I), (B)-(IV), (C)-(II), (D)-(III) (A) Dinitrogen is a diatomic gas which acts like an
(4) (A)-(II), (B)-(IV), (C)-(I), (D)-(III)
inert gas at room temperature.
Ans. (4)
(B) The common oxidation states of these
NH2 OH
elements are –3, +3 and +5.
(i) NaNO2 + HCl (C) Nitrogen has unique ability to form p–p
Sol.
(ii) H2O, warm
multiple bonds.
OH O (D) The stability of +5 oxidation states increases
Na2Cr2O7 down the group.
H2SO4 (E) Nitrogen shows a maximum covalency of 6.
Choose the correct answer from the options given
O
below.
OH OH
CHO (1) (A), (B), (D) only (2) (A), (C), (E) only
(i) CHCl3+aq NaOH (3) (B), (D), (E) only (4) (D) and (E) only
(ii) H+
Ans. (4)
OH OH Sol. (D) Due to inert pair effect lower oxidation state is
COOH more stable.
(i) NaOH
(E) Nitrogen belongs to 2nd period and cannot
(ii) CO2
(iii) H+ expand its octet.

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70. IUPAC name of following hydrocarbon (X) is : Sol. Buffer solution is a mixture of either weak acid /
CH3 – CH – CH2 – CH2 – CH – CH – CH2 – CH3 weak base and its respective conjugate.
CH3 (X) CH3 CH3 Blood is a buffer solution of carbonic acid H2CO3
and bicarbonate HCO3
(1) 2-Ethyl-3,6-dimethylheptane
(2) 2-Ethyl-2,6-diethylheptane Statement 1 is false but Statement II is true.
73. The correct sequence of acidic strength of the
(3) 2,5,6-Trimethyloctane
following aliphatic acids in their decreasing order
(4) 3,4,7-Trimethyloctane is :
Ans. (3) CH3CH2COOH, CH3COOH, CH3CH2CH2COOH,
1 2 3 4 5 6 7 8 HCOOH
Sol. (1) HCOOH > CH3COOH > CH3CH2COOH >
CH3 – CH – CH2 – CH2 – CH – CH – CH2 – CH3
CH3CH2CH2COOH
CH3 CH3 CH3 (2) HCOOH > CH3CH2CH2COOH >
CH3CH2COOH > CH3COOH
2,5,6-Trimethyloctane
(3) CH3CH2CH2COOH > CH3CH2COOH >

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71. The equilibrium Cr2 O27 2CrO24 is shifted to CH3COOH > HCOOH
the right in : (4) CH3COOH > CH3CH2COOH >
(1) an acidic medium CH3CH2CH2COOH > HCOOH
(2) a basic medium Ans. (1)
(3) a weakly acidic medium Sol. CH3CH2COOH, CH3COOH, CH3CH2CH2COOH,
(4) a neutral medium HCOOH
Ans. (2) The correct order is :
OH HCOOH > CH3COOH > CH3CH2COOH >
Sol. Cr2O27 2CrO24
H CH3CH2CH2COOH
72. Given below are two statements : 74. Given below are two statements :
Statement (I) : All the following compounds react
Statement (I) : A Buffer solution is the mixture of with p-toluenesulfonyl chloride.
a salt and an acid or a base mixed in any particular C6H5NH2 (C6H5)2NH (C6H5)3N
Statement (II) : Their products in the above
quantities. reaction are soluble in aqueous NaOH.
Statement (II) : Blood is naturally occurring In the light of the above statements, choose the
correct answer from the options given below.
buffer solution whose pH is maintained by
(1) Both Statement I and Statement II is false
H 2 CO3 / HCO3 concentrations. (2) Statement I is true but Statement II is false
(3) Statement I is false but Statement II is true
In the light of the above statements, choose the (4) Both Statement I and Statement II is true
Ans. (1)
correct answer from the options given below.
Sol. Hinsberg test given by 1° amine only.
(1) Statement I is false but Statement II is true 75. The emf of cell T1 T1 Cu 2  Cu is 0.83 V at
 0.001M   0.01M 
(2) Both Statement I and Statement II is true 298 K. It could be increased by :
(3) Both Statement I and Statement II is false (1) increasing concentration of T1+ ions
(2) increasing concentration of both T1+ and Cu2+ ions
(4) Statement I is true but Statement II is false
(3) decreasing concentration of both T1+ and Cu2+ ions
Ans. (1) (4) increasing concentration of Cu2+ ions

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Ans. (4) 77. Given below are two statements :
Sol. Statement (I) : Kjeldahl method is applicable to

Anodic Reaction  T s  T  aq  e   2 estimate nitrogen in pyridine.

    
Cathodic Reaction 2 
Cu  aq   2e  Cu s Statement (II) : The nitrogen present in pyridine

Overall Redox Reaction 2T  Cu 2 aq   2T 

 Cu s can easily be converted into ammonium sulphate in
s  aq 
Kjeldahl method.

 T  
2
In the light of the above statements, choose the
0.0591
E cell  E o
cell  log correct answer from the options given below.
2  Cu 2 
(1) Both Statement I and Statement II is false
+2
Ecell increases by increasing concentration of [Cu ] (2) Statement I is false but Statement II is true
ions. (3) Both Statement I and Statement II is true
76. Identify the correct statements about p-block (4) Statement I is true but Statement II is false

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elements and their compounds. Ans. (1)
(A) Non metals have higher electronegativity than Sol. Nitrogen present in pyridine can not be estimated
metals. by Kjeldahl method as the nitrogen present in
(B) Non metals have lower ionisation enthalpy pyridine can not be easily converted into
than metals. ammonium sulphate.
(C) Compounds formed between highly reactive 78. The reaction ;
nonmetals and highly reactive metals are
1  
generally ionic. H2(g)  AgCl(s)  H(aq)  Cl(aq)  Ag(s)
2
(D) The non-metal oxides are generally basic in nature.
(E) The metal oxides are generally acidic or occurs in which of the following galvanic cell :

neutral in nature. (1) Pt H2(g) HCl(soln.) AgCl(s) Ag

(1) (D) and (E) only (2) (A) and (C) only
(2) Pt H2(g) HCl(soln.) AgNO3(aq) Ag
(3) (B) and (E) only (4) (B) and (D) only

Ans. (2) (3) Pt H2(g) KCl(soln.) AgCl(s) Ag

Sol. As electronegativity increases non-metallic nature
(4) Ag AgCl(s) KCl(soln.) AgNO3(aq.) Ag
increases.

Along the period ionisation energy increases. Ans. (3)

High electronegativity difference results in ionic Sol. Anodic half cell

bond formation. Gas – gas ion electrode

Oxides of metals are generally basic and that of 1

H 2  H   aq   e 
2  g
non-metals are acidic in nature.

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 Cathodic Reaction 80. Match List-I with List-II.

Metal-metal insoluble salt anion electrode List-I List-II

Agaq   e  Ags (Complex ion) (Spin only magnetic

moment in B.M.)
AgCls Agaq   Claq 
(A) [Cr(NH3)6]3+ (I) 4.90
AgCls  e  Ags  Claq  (B) [NiCl4]2– (II) 3.87

Overall redox reaction (C) [CoF6]3– (III) 0.0

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H 2  g   AgCls  H   aq   Cl  aq   Ags  (D) [Ni(CN)4]2– (IV) 2.83
2
Cell Representation Choose the correct answer from the options given

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below :
Pt | H2(g) | kCl(sol) | AgCl(s) | Ag
(1) (A)-(I), (B)-(IV), (C)-(II), (D)-(III)
79. Given below are two statements : (2) (A)-(IV), (B)-(III), (C)-(I), (D)-(II)
Statement (I) : Fusion of MnO2 with KOH and an
(3) (A)-(II), (B)-(IV), (C)-(I), (D)-(III)
oxidising agent gives dark green K2MnO4.
Statement (II) : Manganate ion on electrolytic (4) (A)-(II), (B)-(III), (C)-(I), (D)-(IV)
oxidation in alkaline medium gives permanganate Ans. (3)
ion. Sol. (A) [Cr(NH3)6]3+
In the light of the above statements, choose the Cr3+ : 3d3
correct answer from the options given below. n = 3 (unpaired electrons)
 3.87 B.M. (II)
(1) Both Statement I and Statement II is true
(B) [NiCl4]2–
(2) Both Statement I and Statement II is false
Ni2+ : 3d8
(3) Statement I is true but Statement II is false
n=2
(4) Statement I is false but Statement II is true
 2.83 B.M. (IV)
Ans. (1)
(C) [CoF6]3–
fused
Sol. MnO2 + 4KOH + O2   2K2MnO4 + 2H2O Co3+ : 3d6

Dark green n=4

 4.90 B.M. (I)
Electrolytic oxidation in alkaline medium :
(D) [Ni(CN)4]2–
At anode : Ni2+ : 3d8
n=0
MnO24  MnO4  e 
 = 0 B.M. (III)

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 SECTION-B 42
B.O. = 1
81. vap H for water is +40.49 kJ mol–1 at 1 bar and 2

100°C. Change in internal energy for this Ne2

vapourisation under same condition is ______ kJ (20e–) : 1s2,*1s2,2s2,*2s2,2pz2

mol–1. (Integer answer)

 2p2x  2p2y    * 2p2x   * 2p2y   * 2pz2
–1 –1    
(Given R = 8.3 JK mol )
Ans. (38) 10  10
B.O. = 0
2
Sol. H2 O( ) H2O(g) H 0vap  40.79 kJ / mole
N2
H 0vap  U vap
0
 n g RT

 8.3  373.15 (14e–) : 1s2,*1s2,2s2,*2s2  2p2x  2p2y  2p 2z

40.79  U 0vap 
1000
10  4
B.O. = 6

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U 0vap  40.79  3.0971 2
 37.6929 He2
U 0
vap 38
(4e–) : 1s2,*1s2
82. Number of molecules having bond order 2 from
22
B.O. = 0
the following molecule is _______. 2
C2, O2, Be2, Li2, Ne2, N2, He2 83. Total number of optically active compounds from
Ans. (2) the following is _______.
Sol. C2 CH3 OH OH CH3 – CH2 – CH2 – CH2 – OH,
CH3 – CH2 – CH – CH3
(12e–) : 1s2,*1s2,2s2,*2s2  2p2x  2p2y  H C OH ,
, Cl
OH
H C OH
84 CH3 – CH2 – CH2 – CH2 – Cl,
B.O. = 2 (CH3)2CH – CH2 – CH2 – Cl
2 CH3

O2 Ans. (1)
– 2 2 2 2 2
(16e ) : 1s ,*1s ,2s ,*2s ,2pz
Sol. CH3 – CH2 – CH – CH3
 2p2x  2p2y    * 2p1x   * 2p1y  Cl
   
84. The total number of carbon atoms present in
10  6
B.O. = 2 tyrosine, an amino acid, is _______.
2
Ans. (9)
Be2
(8e–) : 1s2,*1s2,2s2,*2s2 Sol. Tyrosine

44 O
B.O. = 0
2
OH
Li2 HO NH 2
Number of carbon atoms = 9
(6e–) : 1s2,*1s2,2s2

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85. Two moles of benzaldehyde and one mole of 88. Total number of unpaired electrons in the complex
acetone under alkaline conditions using aqueous
ion [Co(NH3)6]3+ and [NiCl4]2– is
NaOH after heating gives x as the major product.
Ans. (2)
The number of  bonds in the product x is
Ans. (9) Sol. Co+3 : 3d6 t 2,2,2
2g e 0,0
g

O Unpaired e– = 0
Ph Ph
Sol. C = O + CH3–C–CH3 + O = C
H H Ni+2 : 3d8 e 2,2 t 2,1,1
2
NaOH/
O Aldol Unpaired e– = 2
Ph Ph condensation
C = CH–C–CH = C 89. Wavenumber for a radiation having 5800 Å
H H reaction
wavelength is x × 10 cm–1. The value of x is

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86. Total number of aromatic compounds among the _____.
following compounds is _______.
 Ans. (1724)
, , , , ,
1 1
N Sol.  (wave no.) =  = 17241
 5800  10 8 cm
Ans. (1)
OR
Sol.
1724  10 cm 1 x = 1724
N
90. A solution is prepared by adding 1 mole ethyl
87. Molality of an aqueous solution of urea is 4.44 m.
Mole fraction of urea in solution is x × 10–3. alcohol in 9 mole water. The mass percent of
Value of x is _______. (integer answer) solute in the solution is _______ (Integer Answer)
Ans. (74)
(Given : Molar mass in g mol–1 Ethyl alcohol : 46,
Sol. Molality of urea is 4.44 m, that means 4.44 moles
water : 18)
of urea present in 1000 gm of water.
Ans. (22)
4.44
 X urea  Sol. Mass percent of Alcohol
1000
4.44 
18
Mass of ethyl alcohol
= 0.0740 =  100
Total mass of solution
OR
1  46 4600
=  100 =
74 10 3
1  46  9  18 208

X = 74 = 22.11 Or 22