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Chapter 09 - Behavioral Finance and Technical Analysis
CHAPTER 09
BEHAVIORAL FINANCE AND TECHNICAL ANALYSIS
1. Note the following matches

Disposition effect – d
Representativeness bias – e
Regret avoidance – b
Conservatism bias – a
Mental accounting - c
2. Representativeness bias. The sample size is not considered when making future
decisions.
3. Fundamental risk means that even if a security is mispriced, it still can be risky to
attempt to exploit the mispricing. This limits the actions of arbitrageurs who take
positions in mispriced securities. Thus, the bias may persist since no one takes
advantage of it.
4. The premise of behavioral finance is that conventional financial theory ignores how
real people make decisions and that people make a difference. Behavioral finance
may site examples of market inefficiencies, but they give no insight into how to
exploit such phenomenon. The strength of their argument relies upon observed
market inefficiencies and unexplained market behavior. There are many anomalies,
yet many can be reverse engineered or explained. Also, while anomalies exist, they
rarely meet the test of statistical significance.
5. An unfortunate consequence of behavioral finance (BF) is a tendency for investors to
assume more than actually is claimed by the field. While BF is highly critical of EMH
and claims to offer alternative theories, it does not propose to be a predictor of future
returns. Investors should be wary of people purporting to offer excess returns under
the façade of BH. Such claims are likely to be false.
6. Statement b, that a price has moved above its 52 week moving average is considered
a bullish sign.
7. After the fact, you can always find patterns and trading rules that would have
generated enormous profits. This is called data mining. For technical analysts, this is
a problem since they rarely can be reproduced to predict future profits.
8. Grinblatt and Han (2005) show that the disposition effect can lead to momentum in
stock prices even if fundamental values follow a random walk. This momentum may
not lead to abnormal profits, but may cause capital to flow to investments that appear
to benefit from the momentum, in contrast to where it would otherwise flow.
9-1
9. Arbitrage assumes the ability to initiate trades based on arbitrage information. A

severe limit of the theory is that similar assets should be priced similarly (Law of one
price). An example of a limit in which such a trade is not possible is the case of Royal
Dutch Petroleum and Shell. This is a case of “Siamese twin” companies, where the
value was not proportional to the profit distribution. Attempts to profit from the
incorrect pricing would result in substantial loss. An equity carve out is another
example. In this, the sale of a portion of the company does not necessarily generate
the exact percentage one would expect based on the percentage taken from the
original company. The last example involved closed end funds that typically sell for
less than NAV.
10. Some people may say it is consistent with both. This is consistent with efficient
markets since the price does approach intrinsic value. Behavioral would say it is
consistent since the price slowly approaches intrinsic value after the market has a
track record of time showing no other shocks are imminent. Lacking information
about another shock, EMH says the price should go directly to the new value.
Behavioral finance says that may take time.
Volume declining / Number declining 1,463,015 / 2,712
11. Trin = = = 5.1214
Volume advancing / Number advancing 52,773 / 501
This trin ratio, which is above 1.0, would be taken as a bearish signal.
12. Breadth:
Net
Advances Declines
Declines
501 2,712 2,211
Breadth is negative. This is a bearish signal (although no one would actually use a
one-day measure as in this example).
13. This exercise is left to the student.
14. The confidence index increases from (8%/9%) = 0.889 to (9%/10%) = 0.900.
This indicates slightly higher confidence. But the real reason for the increase in
the index is the expectation of higher inflation, not higher confidence about the
economy.
15. At the beginning of the period, the price of Computers, Inc. divided by the
industry index was 0.39; by the end of the period, the ratio had increased to
0.50. As the ratio increased over the period, it appears that Computers, Inc.
outperformed other firms in its industry. The overall trend, therefore, indicates
relative strength, although some fluctuation existed during the period, with the
ratio falling to a low point of 0.33 on day 19.
16. Five day moving averages:

Days 1 – 5: (19.63 + 20 + 20.5 + 22 + 21.13) / 5 = 20.65
9-2
Days 2 – 6 = 21.13
Days 3 – 7 = 21.50
Days 4 – 8 = 21.90
Days 5 – 9 = 22.13
Days 6 – 10 = 22.68
Days 7 – 11 = 23.18
Days 8 – 12 = 23.45  Sell signal (day 12 price < moving average)
Days 9 – 13 = 23.38
Days 10 – 14 = 23.15
Days 11 – 15 = 22.50
Days 12 – 16 = 21.65
Days 13 – 17 = 20.95
Days 14 – 18 = 20.28
Days 15 – 19 = 19.38
Days 16 – 20 = 19.05
Days 17 – 21 = 18.93  Buy signal (day 21 price > moving average)
Days 18 – 22 = 19.28
Days 19 – 23 = 19.93
Days 20 – 24 = 21.05
Days 21 – 25 = 22.05
Days 22 – 26 = 23.18
Days 23 – 27 = 24.13
Days 24 – 28 = 25.13
Days 25 – 29 = 26.00
Days 26 – 30 = 26.80
Days 27 – 31 = 27.45
Days 28 – 32 = 27.80
Days 29 – 33 = 27.90  Sell signal (day 33 price < moving average)
Days 30 – 34 = 28.20
Days 31 – 35 = 28.45
Days 32 – 36 = 28.65
Days 33 – 37 = 29.05
Days 34 – 38 = 29.25
Days 35 – 39 = 29.00
Days 36 – 40 = 28.75
17.
Buy
30
X
28
X 0
26
X
9-3
24
X X
22
X 0 X
20
X 0 X
18
0 X
16
Sell
A sell signal occurs at a price of approximately $19, which is similar to a sell signal
derived from the moving average rule. However, the buy signals are not the same.
18. This pattern shows a lack of breadth. Even though the index is up, more stocks
declined than advanced, which indicates a “lack of broad-based support” for the rise
in the index.
19.
Net Cumulative
Day Advances Declines
Advances Breadth
1 906 704 202 202
2 653 986 -333 -131
3 721 789 - 68 -199
4 503 968 -465 -664
5 497 1,095 -598 -1,262
6 970 702 268 -994
7 1,002 609 393 -601
8 903 722 181 -420
9 850 748 102 -318
10 766 766 0 -318
The signal is bearish as cumulative breadth is negative; however, the negative
number is declining in magnitude, indicative of improvement. Perhaps the worst of
the bear market has passed.
Volume declining/ Number declining 240 million / 704

20. Trin = = = 0.936
Volume advancing/ Number advancing 330 million / 906
This is a slightly bullish indicator, with average volume in advancing issues a bit
greater than average volume in declining issues.
9-4
Yield on top - rated corporate bonds

21. Confidence Index =
Yield on intermediate - grade corporate bonds
This year: Confidence Index = (8%/10.5%) = 0.762
Last year: Confidence Index = (8.5%/10%) = 0.850
Thus, the confidence index is decreasing.
22. [Note: In order to create the 26-week moving average for the S&P 500, we first
converted the weekly returns to weekly index values, using a base of 100 for the week
prior to the first week of the data set.]
a. The graph on the next page summarizes the data for the 26-week moving
average. The graph also shows the values of the S&P 500 index.
b. The S&P 500 crosses through its moving average from below fifteen times, as
indicated in the table below. The index increases eight times in weeks
following a cross-through and decreases seven times.
c. The S&P 500 crosses through its moving average from above sixteen times,
as indicated in the table below. The index increases ten times in weeks
following a cross-through and decreases six times.
d. It is obvious from the data presented that the rule did not work in recent years.
9-5
SP 500 index and 26-week moving average
155
Index level
145
26-week MA
135
Index and index MA
125
115
105
95
85
75
2004 2005 2006 2007 2008 2009
Week of Year
23. [Note: In order to create the relative strength measure, we convert the weekly returns
for the Fidelity Banking Fund and for the S&P 500 to base 100 weekly index values.]
a. The graphs summarize the relative strength data for the Fidelity Banking
Fund.
b. Over five-week intervals, relative strength increased by more than 5% sixteen
times, out of 255 instances. The Fidelity Banking Fund underperformed the
S&P 500 index ten times and outperformed the S&P 500 index six times in
weeks following an increase of more than 5%.
c. Over five-week intervals, relative strength decreases by more than 5% thirty
one times, out of 255 instances. The Fidelity Banking Fund underperformed
the S&P 500 index seventeen times and outperformed the S&P 500 index
fourteen times in weeks following a decrease of more than 5%.
9-6
d. An increase in relative strength, as in part (b) above, is regarded as a bullish

signal. However, in our sample, the Fidelity Banking Fund is more likely to
under perform the S&P 500 index than it is to outperform the index following
such a signal. A decrease in relative strength, as in part (c), is regarded as a
bearish signal. In our sample, the Fidelity Banking Fund underperformed the
index as expected. However, there is no statistical difference in the performance
following a substantial change in the relative strength. The subsequent
performance appears to be random.
Relative strength FSRBX vs. SP 500
1.20
1.00
0.80
FSRBX/SP 500, MA
FSRBX/SPY
0.60 26-week MA
0.40
0.20
0.00
2004.25 2004.75 2005.25 2005.75 2006.25 2006.75 2007.25 2007.75 2008.25
Year.week
24. Pontiff (1996) demonstrates that deviations of price from net asset value in closed-
end funds tend to be higher in funds that are more difficult to arbitrage, for example,
those with more idiosyncratic volatility. Since well diversified funds represent less of
an opportunity for arbitrage by removing the impact of individual stock anomalies,
they would likely have smaller deviations from NAV.
CFA 1
9-7
i. Mental accounting is best illustrated by Statement #3. Sampson’s

requirement that his income needs be met via interest income and stock
dividends is an example of mental accounting. Mental accounting holds that
investors segregate funds into mental accounts (e.g., dividends and capital
gains), maintain a set of separate mental accounts, and do not combine
outcomes; a loss in one account is treated separately from a loss in another
account. Mental accounting leads to an investor preference for dividends
over capital gains and to an inability or failure to consider total return.
ii. Overconfidence (illusion of control) is best illustrated by Statement #6.
Sampson’s desire to select investments that are inconsistent with his overall
strategy indicates overconfidence. Overconfident individuals often exhibit
risk-seeking behavior. People are also more confident in the validity of their
conclusions than is justified by their success rate. Causes of overconfidence
include the illusion of control, self-enhancement tendencies, insensitivity to
predictive accuracy, and misconceptions of chance processes.
iii. Reference dependence is best illustrated by Statement #5. Sampson’s desire
to retain poor performing investments and to take quick profits on successful
investments suggests reference dependence. Reference dependence holds that
investment decisions are critically dependent on the decision-maker’s
reference point. In this case, the reference point is the original purchase price.
Alternatives are evaluated not in terms of final outcomes but rather in terms of
gains and losses relative to this reference point. Thus, preferences are
susceptible to manipulation simply by changing the reference point.
CFA 2
a. Frost's statement is an example of reference dependence. His inclination to sell
the international investments once prices return to the original cost depends not
only on the terminal wealth value, but also on where he is now, that is, his
reference point. This reference point, which is below the original cost, has
become a critical factor in Frost’s decision.
In standard finance, alternatives are evaluated in terms of terminal wealth values or
final outcomes, not in terms of gains and losses relative to some reference point
such as original cost.
b. Frost’s statement is an example of susceptibility to cognitive error, in at least

two ways. First, he is displaying the behavioral flaw of overconfidence. He
likely is more confident about the validity of his conclusion than is justified
by his rate of success. He is very confident that the past performance of
Country XYZ indicates future performance. Behavioral investors could, and
often do, conclude that a five-year record is ample evidence to suggest future
performance. Second, by choosing to invest in the securities of only Country
XYZ, Frost is also exemplifying the behavioral finance phenomenon of asset
segregation. That is, he is evaluating Country XYZ investment in terms of its
anticipated gains or losses viewed in isolation.
9-8
Individuals are typically more confident about the validity of their conclusions
than is justified by their success rate or by the principles of standard finance,
especially with regard to relevant time horizons. In standard finance,
investors know that five years of returns on Country XYZ securities relative to
all other markets provide little information about future performance. A
standard finance investor would not be fooled by this “law of small numbers.”
In standard finance, investors evaluate performance in portfolio terms, in this
case defined by combining the Country XYZ holding with all other securities
held. Investments in Country XYZ, like all other potential investments,
should be evaluated in terms of the anticipated contribution to the risk- reward
profile of the entire portfolio.
c. Frost’s statement is an example of mental accounting. Mental accounting

holds that investors segregate money into mental accounts (e.g., safe versus
speculative), maintain a set of separate mental accounts, and do not combine
outcomes; a loss in one account is treated separately from a loss in another
account. One manifestation of mental accounting, in which Frost is engaging,
is building a portfolio as a pyramid of assets, layer by layer, with the
retirement account representing a layer separate from the “speculative” fund.
Each layer is associated with different goals and attitudes toward risk. He is
more risk averse with respect to the retirement account than he is with respect
to the “speculative” fund account. The money in the retirement account is a
down side protection layer, designed to avoid future poverty. The money in
the “speculative” fund account is the upside potential layer, designed for a
chance at being rich.
In standard finance, decisions consider the risk and return profile of the entire
portfolio rather than anticipated gains or losses on any particular account,
investment, or class of investments. Alternatives should be considered in
terms of final outcomes in a total portfolio context rather than in terms of
contributions to a “safe” or a “speculative” account. Standard finance
investors seek to maximize the mean-variance structure of the portfolio as a
whole and consider covariances between assets as they construct their
portfolios. Standard finance investors have consistent attitudes toward risk
across their entire portfolio.
CFA 3
a. Illusion of knowledge: Maclin believes he is an expert on, and can make
accurate forecasts about, the real estate market solely because he has studied
housing market data on the Internet. He may have access to a large amount of
real estate-related information, but he may not understand how to analyze the
information nor have the ability to apply it to a proposed investment.
9-9
Overconfidence: Overconfidence causes us to misinterpret the accuracy of our

information and our skill in analyzing it. Maclin has assumed that the information
he collected on the internet is accurate without attempting to verify it or consult
other sources. He also assumes he has skill in evaluating and analyzing the real
estate-related information he has collected, although there is no information in the
question that suggests he possesses such ability.
b. Reference point: Maclin’s reference point for his bond position is the purchase
price, as evidenced by the fact that he will not sell a position for less than he
paid for it. This fixation on a reference point, and the subsequent waiting for
the price of the security to move above that reference point before selling the
security, prevents Maclin from undertaking a risk/return-based analysis of his
portfolio position.
c. Familiarity: Maclin is evaluating his holding of company stock based on his

familiarity with the company rather than on sound investment and portfolio
principles. Company employees, because of this familiarity, may have a
distorted perception of their own company, assuming a “good company” will
also be a good investment. Irrational investors believe an investment in a
company with which they are familiar will produce higher returns and have less
risk than non-familiar investments.
Representativeness: Maclin is confusing his company (which may well be a good
company) with the company’s stock (which may or may not be an appropriate
holding for his portfolio and/or a good investment) and its future performance.
This can result in employees’ overweighting their company stock, resulting in an
under-diversified portfolio
CFA 4
a. The behavioral finance principle of biased expectations/overconfidence is most
consistent with the investor’s first statement. Petrie stock provides a level of
confidence and comfort for the investor because of the circumstances in which she
acquired the stock and her recent history with the returns and income from the
stock. However, the investor exhibits overconfidence in the stock given the needs
of the Trust and the brevity of the recent performance history. Maintaining a 15
percent position in a single stock is inconsistent with the overall strategy of the
Trust, and the investor’s level of confidence should reflect the stock’s overall
record, not just the past two years.
9-10
b. The behavioral finance principle of mental accounting is most consistent with

the investor’s second statement. The investor has segregated the monies
distributed from the Trust into two “accounts”: the returns the Trust receives
from the Petrie stock, and the remaining funds that the Trust receives for her
benefit. She is maintaining a separate set of mental accounts with regard to
the total funds distributed. The investor’s “specific uses” should be viewed in
the overall context of the spending needs of the Trust and should consider the
risk and return profile of the entire Trust.
CFA 5
i. Overconfidence (Biased Expectations and Illusion of Control): Pierce is basing
her investment strategy for supporting her parents on her confidence in the
economic forecasts. This is a cognitive error reflecting overconfidence in the
form of both biased expectations and an illusion of control. Pierce is likely
more confident in the validity of those forecasts than is justified by the
accuracy of prior forecasts. Analysts’ consensus forecasts have proven
routinely and widely inaccurate. Pierce also appears to be overly confident
that the recent performance of the Pogo Island economy is a good indicator
of future performance. Behavioral investors often conclude that a short track
record is ample evidence to suggest future performance.
Standard finance investors understand that individuals typically have greater
confidence in the validity of their conclusions than is justified by their
success rate. The calibration paradigm, which compares confidence to
predictive ability, suggests that there is significantly lower probability of
success than the confidence levels reported by individuals. In addition,
standard finance investors know that recent performance provides little
information about future performance and are not deceived by this “law of
small numbers.”
ii. Loss Aversion (Risk Seeking): Pierce is exhibiting risk aversion in deciding to sell
the Core Bond Fund despite its gains and favorable prospects. She prefers a
certain gain over a possibly larger gain coupled with a smaller chance of a loss.
Pierce is exhibiting loss aversion (risk seeking) by holding the High Yield Bond
Fund despite its uncertain prospects. She prefers the modest possibility of
recovery coupled with the chance of a larger loss over a certain loss. People
tend to exhibit risk seeking, rather than risk aversion, behavior when the
probability of loss is large. There is considerable evidence indicating that risk
aversion holds for gains and risk seeking behavior holds for losses, and that
attitudes toward risk vary depending on particular goals and circumstances.
Standard finance investors are consistently risk averse, and systematically
prefer a certain outcome over a gamble with the same expected value. Such
investors also take a symmetrical view of gains and losses of the same
magnitude, and their sensitivity (aversion) to changes in value is not a function
of a specified value reference point.
9-11
9-12
iii. Reference Dependence: Pierce’s inclination to sell her Small Company

Fund once it returns to her original cost is an example of reference
dependence. Her sell decision is predicated on the current value as related
to original cost, her reference point. Her decision does not consider any
analysis of expected terminal value or the impact of this sale on her total
portfolio. This reference point of original cost has become a critical but
inappropriate factor in Pierce’s decision.
In standard finance, alternatives are evaluated in terms of terminal wealth
values or final outcomes, not in terms of gains and losses relative to a
reference point such as original cost. Standard finance investors also
consider the risk and return profile of the entire portfolio rather than
anticipated gains or losses on any particular investment or asset class.
9-13
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-particle comes out exactly twice the charge which I measure in my
oil-drop experiments.
While then it would not be in keeping with the spirit or with the
method of modern science to make any dogmatic assertion about
the existence or non-existence of a sub-electron, it can be asserted
with entire confidence that there has not appeared up to the present
a scrap of evidence for the existence of charges smaller than the
electron. If all of Dr. Ehrenhaft’s assumptions as to the nature of his
particles were correct, then his experiments would mean simply that
Einstein’s Brownian-movement equation is not of universal validity
and that the law of motion of minute charged particles is quite
different from that which he has assumed. It is exceedingly unlikely
that either of these results can be drawn from his experiments, for
Nordlund[132] and Westgren[133] have apparently verified the
Einstein equation in liquids with very much smaller particles than Dr.
Ehrenhaft uses; and, on the other hand, while I have worked with
particles as small as cm. and with values of as large as
135, which is very much larger than any which appear in the work of
Dr. Ehrenhaft and his pupils, I have thus far found no evidence of a
law of motion essentially different from that which I published in
1913, and further elaborated and refined in 1923.
There has then appeared up to the present time no evidence
whatever for the existence of a sub-electron. The chapter having to
do with its discussion is now considered for the present at least to
have been closed,[134] but it constitutes an interesting historical
document worthy of study as an illustration on the one hand of the
solidity of the foundations upon which the atomic theory of electricity
now rests, and on the other hand of the severity of the gauntlet of
criticism which new results must run before they gain admission to
the body of established truth in physics.
CHAPTER IX
THE STRUCTURE OF THE ATOM
We have shown in the preceding chapters how within the last two decades there has been
discovered beneath the nineteenth-century world of molecules and atoms a wholly new world of
electrons, the very existence of which was undreamed of twenty years ago. We have seen that
these electrons, since they can be detached by X-rays from all kinds of neutral atoms, must be
constituents of all atoms. Whether or not they are the sole constituents we have thus far made no
attempt to determine. We have concerned ourselves with studying the properties of these electrons
themselves and have found that they are of two kinds, negative and positive, which are, however,
exactly alike in strength of charge but wholly different in inertia or mass, the negative being
commonly associated with a mass which is but ¹⁄₁₈₄₅ of that of the lightest known atom, that of
hydrogen, while the positive appears never to be associated with a mass smaller than that of the
hydrogen atom. We have found how to isolate and measure accurately the electronic charge and
have found that this was the key which unlocked the door to many another otherwise inaccessible
physical magnitude. It is the purpose of this chapter to consider certain other fields of exact
knowledge which have been opened up through the measurement of the electron, and in particular
to discuss what the physicist, as he has peered with his newly discovered agencies, X-rays,
radioactivity, ultra-violet light, etc., into the insides of atoms, has been able to discover regarding
the numbers and sizes and relative positions and motions of these electronic constituents, and to
show how far he has gone in answering the question as to whether the electrons are the sole
building-stones of the atoms.
1. THE SIZES OF ATOMS

One of the results of the measurement of the electronic charge was to make it possible to find
the quantity which is called the diameter of an atom with a definiteness and precision theretofore
altogether unattained.
It was shown in chap. V that the determination of gave us at once a knowledge of the exact
number of molecules in a cubic centimeter of a gas. Before this was known we had fairly
satisfactory information as to the relative diameters of different molecules, for we have known for a
hundred years that different gases when at the same temperature and pressure possess the same
number of molecules per cubic centimeter (Avogadro’s rule). From this it is at once evident that, as
the molecules of gases eternally dart hither and thither and ricochet against one another and the
walls of the containing vessel, the average distance through which one of them will go between
collisions with its neighbors will depend upon how big it is. The larger the diameter the less will be
the mean distance between collisions—a quantity which is technically called “the mean free path.”
Indeed, it is not difficult to see that in different gases the mean free path is an inverse measure of
the molecular cross-section. The exact relation is easily deduced (see Appendix E). It is
in which is the molecular diameter and is the number of molecules per cubic centimeter of the
gas. Now, we have long had methods of measuring , for it is upon this that the coefficient of
viscosity of the gas largely depends. When, therefore, we have measured the viscosities of
different gases we can compute the corresponding ’s, and then from equation (31) the relative
diameters , since is the same for all gases at the same temperature and pressure. But the
absolute value of can be found only after the absolute value of is known. If we insert in
equation (31) the value of found from by the method presented in chap. V, it is found that the
average diameter of the atom of the monatomic gas helium is , that of the diatomic
hydrogen molecule is a trifle more, while the diameters of the molecules of the diatomic gases,
oxygen and nitrogen, are 50 per cent larger.[135] This would make the diameter of a single atom of
hydrogen a trifle smaller, and that of a single atom of oxygen or nitrogen a trifle larger than that of
helium. By the average molecular diameter we mean the average distance to which the centers of
two molecules approach one another in such impacts as are continually occurring in connection
with the motions of thermal agitation of gas molecules—this and nothing more.
As will presently appear, the reason that two molecules thus rebound from one another when in
their motion of thermal agitation their centers of gravity approach to a distance of about
is presumably that the atom is a system with negative electrons in its outer regions.
When these negative electrons in two different systems which are coming into collision approach to
about this distance, the repulsions between these similarly charged bodies begin to be felt,
although at a distance the atoms are forceless. With decreasing distance this repulsion increases
very rapidly until it becomes so great as to overcome the inertias of the systems and drive them
asunder.
II. THE RADIUS OF THE ELECTRON FROM THE ELECTROMAGNETIC THEORY OF THE
ORIGIN OF MASS
The first estimates of the volume occupied by a single one of the electronic constituents of an
atom were obtained from the electromagnetic theory of the origin of mass, and were therefore to a
pretty large degree speculative, but since these estimates are strikingly in accord with results
which follow from direct experiments and are independent of any theory, and since, further, they
are of extraordinary philosophic as well as historic interest, they will briefly be presented here.
Since Rowland proved that an electrically charged body in motion is an electrical current the
magnitude of which is proportional to the speed of motion of the charge, and since an electric
current, by virtue of the property called its self-induction, opposes any attempt to increase or
diminish its magnitude, it is clear that an electrical charge, as such, possesses the property of
inertia. But inertia is the only invariable property of matter. It is the quantitative measure of matter,
and matter quantitatively considered is called mass. It is clear, then, theoretically, that an
electrically charged pith ball must possess more mass than the same pith ball when uncharged.
But when we compute how much the mass of a pith ball is increased by any charge which we can
actually get it to hold, we find that the increase is so extraordinarily minute as to be hopelessly
beyond the possibility of experimental detection. However, the method of making this computation,
which was first pointed out by Sir J. J. Thomson in 1881,[136] is of unquestioned validity, so that we
may feel quite sure of the correctness of the result. Further, when we combine the discovery that
an electric charge possesses the distinguishing property of matter, namely, inertia, with the
discovery that all electric charges are built up out of electrical specks all alike in charge, we have
made it entirely legitimate to consider an electric current as the passage of a definite, material,
granular substance along the conductor. In other words, the two entities, electricity and matter,
which the nineteenth century tried to keep distinct, begin to look like different aspects of one and
the same thing.
But, though we have thus justified the statement that electricity is material, have we any
evidence as yet that all matter is electrical—that is, that all inertia is of the same origin as that of an
electrical charge? The answer is that we have evidence, but as yet no proof. The theory that this is
the case is still a speculation, but one which rests upon certain very significant facts. These facts
are as follows:
If a pith ball is spherical and of radius , then the mass due to a charge spread uniformly
over its surface is given, as is shown in Appendix D) by,
The point of especial interest in this result is that the mass is inversely proportional to the radius,
so that the smaller the sphere upon which we can condense a given charge the larger the mass
of that charge. If, then, we had any means of measuring the minute increase in mass of a pith ball
when we charge it electrically with a known quantity of electricity , we could compute from
equation (32) the size of this pith ball, even if we could not see it or measure it in any other way.
This is much the sort of a position in which we find ourselves with respect to the negative electron.
We can measure its mass, and it is found to be accurately ¹⁄₁₈₄₅ of that of the hydrogen atom. We
have measured accurately its charge and hence can compute the radius of the equivalent
sphere, that is, the sphere over which would have to be uniformly distributed to have the
observed mass, provided we assume that the observed mass of the electron is all due to its
charge.
The justification for such an assumption is of two kinds. First, since we have found that
electrons are constituents of all atoms and that mass is a property of an electrical charge, it is of
course in the interests of simplicity to assume that all the mass of an atom is due to its contained
electrical charges, rather than that there are two wholly different kinds of mass, one of electrical
origin and the other of some other sort of an origin. Secondly, if the mass of a negative electron is
all of electrical origin, then we can show from electromagnetic theory that this mass ought to be
independent of the speed with which the electron may chance to be moving unless that speed
approaches close to the speed of light. But from one-tenth the speed of light up to that speed the
mass ought to vary with speed in a definitely predictable way.
Now, it is a piece of rare good fortune for the testing of this theory that radium actually does
eject negative electrons with speeds which can be accurately measured and which do vary from
three-tenths up to ninety-eight hundredths of that of light. It is further one of the capital discoveries
of the twentieth century[137] that within these limits the observed rate of variation of the mass of the
negative electron with speed agrees accurately with the rate of variation computed on the
assumption that this mass is all of electrical origin. Such is the experimental argument for the
electrical origin of mass.[138]
Solving then equation (32) for , we find that the radius of the sphere over which the charge
of the negative electron would have to be distributed to have the observed mass is but
, or but one fifty-thousandth of the radius of the atom ( ). From this point of
view, then, the negative electron represents a charge of electricity which is condensed into an
exceedingly minute volume. In fact, its radius cannot be larger in comparison with the radius of the
atom than is the radius of the earth in comparison with the radius of her orbit about the sun.
In the case of the positive electron there is no direct experimental justification for the
assumption that the mass is also wholly of electrical origin, for we cannot impart to the positive
electrons speeds which approach the speed of light, nor have we as yet found in nature any of
them which are endowed with speeds greater than about one-tenth that of light. But in view of the
experimental results obtained with the negative electron, the carrying over of the same assumption
to the positive electron is at least natural. Further, if this step be taken, it is clear from equation
(32), since for the positive is nearly two thousand times larger than for the negative, that for
the positive can be only ¹⁄₂₀₀₀ of what it is for the negative. In other words, the size of the positive
electron would be to the size of the negative as a sphere having a two-mile radius would be to the
size of the earth. From the standpoint, then, of the electromagnetic theory of the origin of mass, the
dimensions of the negative and positive constituents of atoms in comparison with the dimensions
of the atoms themselves are like the dimensions of the planets and asteroids in comparison with
the size of the solar system. All of these computations, whatever their value, are rendered possible
by the fact that is now known.
Now we know from methods which have nothing to do with the electromagnetic theory of the
origin of mass, that the excessive minuteness predicted by that theory for both the positive and the
negative constituents of atoms is in fact correct, though we have no evidence as to whether the
foregoing ratio is right.
III. DIRECT EXPERIMENTAL PROOF OF THE EXCESSIVE MINUTENESS OF THE

ELECTRONIC CONSTITUENTS OF ATOMS
For at least twenty years we have had direct experimental proof[139] that the fastest of the -
particles, or helium atoms, which are ejected by radium, shoot in practically straight lines through
as much as 7 cm. of air at atmospheric pressure before being brought to rest. This distance is then
called the “range” of these -rays. Figs. 14 and 15 show actual photographs of the tracks of such
particles. We know too, for the reasons given on p. 139, that these -particles do not penetrate the
air after the manner of a bullet, namely, by pushing the molecules of air aside, but rather that they
actually shoot through all the molecules of air which they encounter. The number of such passages
through molecules which an -particle would have to make in traversing seven centimeters of air
would be about a hundred and thirty thousand.
Further, the very rapid -particles, or negative electrons, which are shot out by radium have
been known for a still longer time to shoot in straight lines through much greater distances in air
than 7 cm., and even to pass practically undeflected through appreciable thicknesses of glass or
metal.
We saw in chap. VI that the tracks of both the - and the -particles through air could be
photographed because they ionize some of the molecules through which they pass. These ions
then have the property of condensing water vapor about themselves, so that water droplets are
formed which can be photographed by virtue of the light which they reflect. Fig. 17 shows the track
of a very high-speed -ray. A little to the right of the middle of the photograph a straight line can be
drawn from bottom to top which will pass through a dozen or so of pairs of specks. These specks
are the water droplets formed about the ions which were produced at these points.
Fig. 14—Photographs of the Tracks of -Particles Shooting through Air
Since we know the size of a molecule and the number of molecules per cubic centimeter, we can
compute, as in the case of the -particle, the number of molecules through which a -particle must
pass in going a given distance. The extraordinary situation revealed by this photograph is that this
particular particle shot through on an average as many as 10,000 atoms before it came near
enough to an electronic constituent of any one of these atoms to detach it from its system and form
an ion. This shows conclusively that the electronic or other constituents of atoms can occupy but
an exceedingly small fraction of the space inclosed within the atomic system. Practically the whole
of this space must be empty to an electron going with this speed.
The left panel in the lower half of the plate (Fig. 16) shows the track of a negative electron of
much slower speed, and it will be seen, first, that it ionizes much more frequently, and, secondly,
that instead of continuing in a straight line it is deflected at certain points from its original direction.
The reason for both of these facts can readily be seen from the considerations on p. 139, which it
may be worth while to extend to the case in hand as follows.
If a new planet or other relatively small body were to shoot with stupendous speed through our
solar system, the tune which it spent within our system might be so small that the force between it
and the earth or any other member of the solar system would not have time either to deflect the
stranger from its path or to pull the earth out of its orbit. If the speed of the strange body were
smaller, however, the effect would be more disastrous both to the constituents of our solar system
and to the path of the strange body, for the latter would then have a much better chance of pulling
one of the planets out of our solar system and also a much better chance of being deflected from a
straight path itself. The slower a negative electron moves, then, the more is it liable to deflection
and the more frequently does it ionize the molecules through which it passes.
This conclusion finds beautiful experimental confirmation in the three panels of the plate
opposite this page, for the speed with which X-rays hurl out negative electrons from atoms has
long been known to be much less than the speed of -rays from radium, and the zigzag tracks in
these photographs are the paths of these corpuscles. It will be seen that they bend much more
often and ionize much more frequently than do the rays shown in Figs. 16 and 17.
But the study of the tracks of the -particles (Figs. 14 and 15, opposite p. 190) is even more
illuminating as to the structure of the atom. For the -particle, being an atom of helium eight
thousand times more massive than a negative electron, could no more be deflected by one of the
latter in an atom through which it passes than a cannon ball could be deflected by a pea. Yet Figs.
14 and 15 show that toward the end of its path the -particle does in general suffer several sudden
deflections. Such deflections could be produced only by a very powerful center of force within the
atom whose mass is at least comparable with the mass of the helium atom.
Fig. 18—Photographs of the tracks of -particles ejected by x-rays from molecules of air
These sharp deflections, which occasionally amount to as much as 150° to 180°, lend the
strongest of support to the view that the atom consists of a heavy positively charged nucleus about
which are grouped enough electrons to render the whole atom neutral. But the fact that in these
experiments the -particle goes through 130,000 atoms without approaching near enough to this
central nucleus to suffer appreciable deflection more than two or three times constitutes the most
convincing evidence that this central nucleus which holds the negative electrons within the atomic
system occupies an excessively minute volume, just as we computed from the electromagnetic
theory of the origin of mass that the positive electron ought to do. Indeed, knowing as he did by
direct measurement the speed of the -particle, Rutherford, who is largely responsible for the
nucleus-atom theory, first computed,[140] with the aid of the inverse square law, which we know to
hold between charged bodies of dimensions which are small compared with their distances apart,
how close the -particle would approach to the nucleus of a given atom like that of gold before it
would be turned back upon its course (see Appendix F). The result was in the case of gold, one of
the heaviest atoms, about , and in the case of hydrogen, the lightest atom, about
. These are merely upper limits for the dimensions of the nuclei.
However uncertain, then, we may feel about the sizes of positive and negative electrons
computed from the electromagnetic theory of the origin of the mass, we may regard it as fairly well
established by such direct experiments as these that the electronic constituents of atoms are as
small, in comparison with the dimensions of the atomic systems, as are the sun and planets in
comparison with the dimensions of the solar system. Indeed, when we reflect that we can shoot
helium atoms by the billion through a thin-walled highly evacuated glass tube without leaving any
holes behind, i.e., without impairing in the slightest degree the vacuum or perceptibly weakening
the glass, we see from this alone that the atom itself must consist mostly of “hole”; in other words,
that an atom, like a solar system, must be an exceedingly loose structure whose impenetrable
portions must be extraordinarily minute in comparison with the penetrable portions. The notion that
an atom can appropriate to itself all the space within its boundaries to the exclusion of all others is
then altogether exploded by these experiments. A particular atom can certainly occupy the same
space at the same time as any other atom if it is only endowed with sufficient kinetic energy. Such
energies as correspond to the motions of thermal agitation of molecules are not, however,
sufficient to enable one atom to penetrate the boundaries of another, hence the seeming
impenetrability of atoms in ordinary experiments in mechanics. That there is, however, a portion of
the atom which is wholly impenetrable to the alpha particles is definitely proved by experiments of
the sort we have been considering; for it occasionally happens that an alpha particle hits this
nucleus “head on,” and, when it does so, it is turned straight back upon its course. As indicated
above, the size of this impenetrable portion, which may be defined as the size of the nucleus, is in
no case larger than ¹⁄₁₀₀₀₀ the diameter of the atom, and yet there may be contained within it, as
will presently be shown, several hundred positive and negative electrons, so that the excessive
minuteness of these bodies is established, altogether without reference to any theory as to what
they are.
IV. THE NUMBER OF ELECTRONS IN AN ATOM

If it be considered as fairly conclusively established by the experiments just described that an
atom consists of a heavy but very minute positively charged nucleus which holds light negative
electrons in some sort of a configuration about it, then the number of negative electrons outside
the nucleus must be such as to have a total charge equal to the free positive charge of the
nucleus, since otherwise the atom could not be neutral.
But the positive charge on the nucleus has been approximately determined as follows: With the
aid of the knowledge, already obtained through the determination of , of the exact number of
atoms in a given weight of a given substance, Sir Ernest Rutherford[141] first computed the chance
that a single helium atom in being shot with a known speed through a sheet of gold foil containing
a known number of atoms per unit of area of the sheet would suffer a deflection through a given
angle. This computation can easily be made in terms of the known kinetic energy and charge of
the -particle, the known number of atoms in the gold foil, and the unknown charge on the nucleus
of the gold atom (see Appendix F). Geiger and Marsden[142] then actually counted in Rutherford’s
laboratory, by means of the scintillations produced on a zinc-sulphide screen, what fraction of, say,
a thousand -particles, which were shot normally into the gold foil, were deflected through a given
angle, and from this observed number and Rutherford’s theory they obtained the number of free
positive charges on the nucleus of the gold atom.
Repeating the experiment and the computations with foils made from a considerable number of
other metals, they found that in every case the number of free positive charges on the atoms of
different substances was approximately equal to half its atomic weight. This means that the
aluminum atom, for example, has a nucleus containing about thirteen free positive charges and
that the nucleus of the atom of gold contains in the neighborhood of a hundred. This result was in
excellent agreement with the conclusion reached independently by Barkla[143] from experiments of
a wholly different kind, namely, experiments on the scattering of X-rays. These indicated that the
number of scattering centers in an atom—that is, its number of free negative electrons—was equal
to about half the atomic weight. But this number must, of course, equal the number of free positive
electrons in the nucleus.
V. MOSELEY’S REMARKABLE DISCOVERY

The foregoing result was only approximate. Indeed, there was internal evidence in Geiger and
Marsden’s work itself that a half was somewhat too high. The answer was made very definite and
very precise in 1913 through the extraordinary work of a brilliant young Englishman, Moseley, who,
at the age of twenty-seven, had accomplished as notable a piece of research in physics as has
appeared during the last fifty years. Such a mind was one of the early victims of the world-war. He
was shot and killed instantly in the trenches in Gallipoli in the summer of 1915.
Laue in Munich had suggested in 1912 the use of the regular spacing of the molecules of a
crystal for the analysis, according to the principle of the grating, of ether waves of very short wave-
length, such as X-rays were supposed to be, and the Braggs[144] had not only perfected an X-ray
spectrometer which utilized this principle, but had determined accurately the wave-lengths of the
X-rays which are characteristic of certain metals. The accuracy with which this can be done is
limited simply by the accuracy in the determination of , so that the whole new field of exact X-ray
spectrometry is made available through our exact knowledge of . Moseley’s discovery,[145] made
as a result of an elaborate and difficult study of the wave-lengths of the characteristic X-rays which
were excited when cathode rays were made to impinge in succession upon anticathodes
embracing most of the known elements, was that these characteristic wave-lengths of the different
elements, or, better, their characteristic frequencies, are related in a very simple but a very
significant way. These frequencies were found to constitute the same sort of an arithmetical
progression as do the charges which we found to exist on our oil drops. It was the square root of
the frequencies rather than the frequencies themselves which showed this beautifully simple
relationship, but this is an unimportant detail. The significant fact is that, arranged in the order of
increasing frequency of their characteristic X-ray spectra, all the known elements which have been
examined constitute a simple arithmetical series each member of which is obtained from its
predecessor by adding always the same quantity.
The plate opposite this page shows photographs of the X-ray spectra of a number of elements
whose atomic numbers—that is, the numbers assigned them in Moseley’s arrangement of the
elements on the basis of increasing X-ray frequency—are given on the left. These photographs
were taken by Siegbahn.[146] The distance from the “central image”—in this case the black line on
the left—to a given line of the line spectrum on the right is approximately proportional to the wave-
length of the rays producing this line. The photographs show beautifully, first, how the atoms of all
the elements produce spectra of just the same type, and, secondly, how the wave-lengths of
corresponding lines decrease, or the frequencies increase, with increasing atomic number. The
photograph on the left shows this progression for the highest frequency rays which the atoms
produce, the so-called series, while the one on the right shows the same sort of a progression
for the rays of next lower frequency, namely, those of the so-called series, which have uniformly
from seven to eight times the wave-length of the series. The plate opposite p. 200 shows some
very beautiful photographs taken by De Broglie in Paris[147] in October, 1916.
The upper one is the X-ray emission spectrum of tungsten. It consists of general radiations,
corresponding to white light, scattered throughout the whole length of the spectrum as a
background and superposed upon these two groups of lines.
Fig. 21a—PHOTOGRAPHS OF THE SPECTRA OF THE CHARACTERISTIC X-RAYS FROM CERTAIN
SUBSTANCES
The remarkable element in these photographs is the exact similarity of the spectra produced by
the different elements and the step-by-step shortening of the wave-length (which is proportional to
the distance from the line on the left to the spectral lines) as the atomic number increases. This
is shown both in the series, which is produced by stimulating the inmost pair of electrons in
each atom, and the series, which is produced by stimulating the group of eight electrons in the
second ring or shell from the center.
Fig. 21b—PHOTOGRAPHS OF THE SPECTRA OF THE CHARACTERISTIC X-RAYS FROM CERTAIN
SUBSTANCES
The two lines are here close to the central image, for the wave-lengths are here very short,
since tungsten has a high atomic number (74). Farther to the right is the series of tungsten lines
which will be recognized because of its similarity to the series in the plate opposite p. 198.
Between the and the lines are two absorption edges marked and . The former
represents the frequency above which the silver absorbs all the general radiation of tungsten but
below which it lets it all through. The latter is the corresponding line for bromine. In a print from a
photograph absorption in the plate itself obviously appears as a darkening, transmission as a
lightening. Just below is the spectrum obtained by inserting a sheet of molybdenum in the path of
the beam, i.e., before the slit of the spectrometer. Absorption in the molybdenum will obviously
appear as a lightening, transmission as a darkening. It will be seen that the molybdenum absorbs
all the frequencies in the X-ray emission of tungsten higher than a particular frequency and lets
through all frequencies lower than this value. This remarkable characteristic of the absorption of X-
rays was discovered by Barkla in 1909.[148] The absorption edge at which, with increasing
frequency, absorption suddenly begins is very sharply marked.
This edge coincides with the highest emission frequency of which molybdenum is theoretically
capable, and is a trifle higher than the highest observed emission frequency. De Broglie has
measured accurately these critical absorption frequencies for all the heavy elements up to thorium,
thus extending the series from atomic number where he found it, to , a notable
advance. The two absorption edges characteristic of the silver and the bromine in the photographic
plate appear in the same place on all the photographs in which they could appear. The other
absorption edges vary from element to element and are characteristic each of its particular
element. The way in which this critical absorption edge moves toward the central image as the
atomic number increases in the steps Br 35, Mo 42, Ag 47, Cd 48, Sb 51, Ba 56, W 74, Hg 80, is
very beautifully shown in De Broglie’s photographs all the way up to mercury, where the absorption
edge is somewhat inside the shortest of the characteristic radiations of tungsten. There must be
twelve more of these edges between mercury (N = 80) and uranium ( ) and De Broglie has
measured them up to thorium ( ). They become, however, very difficult to locate in this
region of frequencies on account of their extreme closeness to the central image. But the
radiations, which are of seven times longer wave-length, may then be used, and Fig. 23 of the
plate opposite this page shows the -ray absorption edges, of which there are three, as obtained
by De Broglie in both uranium and thorium, so that the position in the Moseley table of each
element all the way to the heaviest one, uranium, is fixed in this way by direct experiment. Fig. 25
shows the progression of square-root frequencies as it appears from measurements made on the
successive absorption edges of De Broglie’s photographs and on a particular one of Siegbahn’s
emission lines. It will be noticed that, in going from bromine (35) to uranium (92), the length of the
step does change by a few per cent. The probable cause of this will be considered later.
Fig. 22—X-ray absorption spectra. series

Fig. 23—X-ray absorption spectra, series
Fig. 24—Hydrogen spectrum from the star Vega

Fig. 25
According to modern theory an absorption edge appears where the incident energy—which is
proportional to the incident frequency—has become just large enough to lift the particular electron
which absorbs it entirely out of the atom. If this removed electron should then fall back to its old
place in the atom, it would emit in so doing precisely the frequency which was absorbed in the
process of removal.
Since these enormously high X-ray frequencies must arise from electrons which fall into
extraordinarily powerful fields of force, such as might be expected to exist in the inner regions of
the atom close to the nucleus, Moseley’s discovery strongly suggests that the charge on this
nucleus is produced in the case of each atom by adding some particular invariable charge to the
nucleus of the atom next below it in Moseley’s table. This suggestion gains added weight when it is
found that with one or two trifling exceptions, to be considered later, Moseley’s series of increasing
X-ray frequencies is exactly the series of increasing atomic weights. It also receives powerful
support from the following discovery.
Mendeleéff’s periodic table shows that the progression of chemical properties among the
elements coincides in general with the progression of atomic weights. Now it was pointed out ten
years ago that whenever a radioactive substance loses a doubly charged -particle it moves two
places to the left in the periodic table, while whenever it loses a singly charged -particle it moves
one place to the right,[149] thus showing that the chemical character of a substance depends upon
the number of free positive charges in its nucleus.
One of the most interesting and striking characteristics of Moseley’s table is that all the known
elements between sodium (atomic number 11, atomic weight 23) and lead (atomic number 82,
atomic weight, 207.2) have been fitted into it and there are left but three vacancies within this
range. Below sodium there are just 10 known elements, and very recent study[150] of their spectra
in the extreme ultra-violet has fixed the place of each in the Moseley progression, though in this
region the progression of atomic weights and of chemical properties is also altogether definite and
unambiguous. It seems highly probable, then, from Moseley’s work that we have already found all

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13. This exercise is left to the student.

16. Five day moving averages:

Volume declining/ Number declining 240 million / 704

Yield on top - rated corporate bonds

SP 500 index and 26-week moving average

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1. THE SIZES OF ATOMS

III. DIRECT EXPERIMENTAL PROOF OF THE EXCESSIVE MINUTENESS OF THE

IV. THE NUMBER OF ELECTRONS IN AN ATOM

V. MOSELEY’S REMARKABLE DISCOVERY

Fig. 22—X-ray absorption spectra. series

Fig. 24—Hydrogen spectrum from the star Vega

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