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Chapter 10
Gases
Practice Problems C
10.1 (i) < (iv) < (iii) < (ii)
10.2 (i)
10.3 (i)
10.4 (ii)
10.5 (i), (ii), or (iii)
10.6 (iii)
10.7 (i) exerts greater pressure, (ii) has greater density
10.8 0.824 g
10.9 2nd decomposition would produce four times the volume of the 1st.
10.10 P after reaction will be 1/3 higher than before the reaction.
10.11 (ii) will produce a greater volume of product when equal numbers of moles are combined. Both will
produce the same volume of product when equal numbers of grams are combined.
10.12 Pred = 1.25 atm, Pgreen = 2.00 atm, Pyellow = 2.25 atm; Ptotal = 5.50 atm.
10.13 12 green spheres
10.14 (ii)
10.15 (i) and (iii) have the same χred; (ii) has the same Pred; and (iv) has the same Ptotal.
10.16 (iii)
10.17 Intermolecular attractions and nonzero volume of individual gas molecules. At high temperature,
intermolecular forces are insignificant compared to kinetic energies of gas molecules. At low pressure, the
relative distance between molecules makes their actual volume insignificant.
Visualizing Chemistry
10.1 b 10.2 a 10.3 a 10.4 b
Copyright © McGraw‐Hill Education. All rights reserved.

No reproduction or distribution without the prior written consent of McGraw‐Hill Education.
Chapter 10 – Gases 2
Applying What You Know
a) 0.39 m.
b) 245 L.
c) 0.66 g/L.
d) 4.6 × 102 L.
e) 8.7 mol N2, 2.2 mol O2.
Questions and Problems
10.1 Answers will vary.
10.2 Gases assume the volume and shape of their containers. They are compressible. They generally have low
densities and will mix in any proportions to give homogeneous solutions.
10.3 Pressure is the force per unit area. The SI units of force and pressure are the Newton and the pascal,
respectively. Other commonly used units of pressure are atmosphere, mmHg, torr, and bar.
10.4 A barometer consists of a long glass tube, closed at one end and filled with mercury. The tube is carefully
inverted in a container of mercury so that air enters the tube. When the tube is inverted, some of the
mercury in the tube will flow out into the container, creating an empty space at the top of the tube. The
weight of the mercury remaining in the tube is supported by atmospheric pressure pushing down on the
surface of the mercury in the container.
A manometer is a device used to measure pressures other than atmospheric pressure. The principle of
operation of a manometer is similar to that of a barometer. The closed-tube monomer is normally used to
measure pressures below atmospheric pressure, whereas the open-tube manometer is generally used to
measure pressures equal to or greater than atmospheric pressure. See Figure 10.6.
10.5 Mercury has a much higher density than water. The height of a column of fluid supported by a given
pressure is inversely proportional to the density of the fluid, so a more dense fluid requires a smaller height.
10.6 The height depends only on the height and the density of the fluid.
10.7 Because the height of liquid that is supported at the lower pressure on the top of the mountain is less, it
would be harder to drink through the straw.
10.8 Greater than 1 atm.

10.9 A vapor is the gaseous state of a substance that is a liquid or solid at room temperature. Cl2 is a gas. I2 is a
vapor, since it exists as a solid at room temperature.
10.10 The well must be pressurized. Increasing the pressure on the water or oil within the well will increase the
height supported.
10.12 The atmospheric pressure on the moon is much less than on earth. Since the internal pressure in the human
body is approximately equal to 1 atm (so that humans can live on earth without feeling the air pushing on
their bodies), the much lower pressure on the moon would cause the body to expand and burst.
10.13 Strategy: We use the conversion factors provided in Table 10.2 in the text to convert a pressure in
mmHg to atm, bar, torr, and Pa.
Solution: Converting to atm:
133.322 Pa 1 atm
?atm = 375 mmHg    0.493 atm
1 mmHg 101,325 Pa
We could also have solved this by remembering that 760 mmHg = 1 atm.
1 atm
?atm = 375 mmHg   0.493 atm
760 mmHg
Converting to bar:
133.322 Pa 1 bar
?bar = 375 mmHg    0.500 bar
1 mmHg 1105 Pa
Converting to torr:
133.322 Pa 1 torr
?torr = 375 mmHg    375 torr
1 mmHg 133.322 Pa
Note that because 1 mmHg and 1 torr are both equal to 133.322 Pa, this could be simplified by
recognizing that 1 torr = 1 mmHg.
1 torr
375 mmHg   375 torr
1 mmHg
Converting to Pa:
1 atm 101,325 Pa
?Pa = 375 mmHg    5.00 × 104 Pa
760 mmHg 1 atm

10.14 133.322 Pa 1 atm

?atm = 581 mmHg    0.764 atm
1 mmHg 101,325 Pa
For the second conversion, 1 atm = 101.325 kPa.
101.325 kPa
?kPa = 0.764 atm   77.5 kPa
1 atm
10.15 Strategy: This problem is similar to Sample Problem 10.1. We can use the equation derived in the sample
problem to solve for the height of the column of methanol. The equation is pressure = height ×
density × gravitational constant
The gravitational constant is 9.80665 m/s2.
Solution: Solving the equation for height of the column gives
pressure
height =
density  gravitational constant
Recall that for units to cancel properly, pressure must be expressed in Pa (1 Pa = 1 kg/m·s2) and
density must be expressed in kg/m3. Converting the information given in the problem to the
appropriate units,
101,325 Pa
?Pa = 1 atm   101,325 Pa
1 atm
Note that we consider atmospheric pressure to be exactly 1 atm.
3
0.787 g 1 kg  100 cm 
?kg/m3 =     787 kg/m
3
1 cm 3 1000 g  1 m 
Remember that when a unit is raised to a power, any conversion factor used must be raised to
the same power. Substituting into the equation to solve for height gives
101,325 Pa 101,325 kg/m  s 2

height 
787 kg/m 9.80665 m/s  787 kg/m 9.80665 m/s  

3 2 3 2
13.1 m
Think It’s easier to see how the units cancel if we express the pressure in pascals using base SI units.
About It:
10.16 Start by converting 1 atm to Pa and the density of ethylene glycol to kg/m3.
101,325 Pa
?Pa = 1 atm   101,325 Pa
1 atm

3
1 kg  100 cm 
1.12 g
?kg/m = 3

3 1000 g
   1.12 × 103 kg/m3
1 cm  1m 
Rearrange the equation derived in Sample Problem 10.1 to solve for height of the column.
101,325 Pa 101,325 kg/m  s 2
height    9.23 m
 
1.12 10 3 kg/m 3 9.80665 m/s 2   
1.12 10 3 kg/m 3 9.80665 m/s 2 
10.17 Strategy: This problem is very similar to Sample Problem 10.1. We can use the equation derived in the
sample problem to solve for the pressure exerted by the column of toluene. The equation is
pressure = height × density × gravitational constant
The gravitational constant is 9.80665 m/s2.
Solution: Recall that for units to cancel properly, density must be expressed in kg/m3.
3
0.867 g 1 kg  100 cm 
?kg/m3 =     867 kg/m
3
1 cm 3 1000 g  1 m 
Remember that when a unit is raised to a power, any conversion factor used must be raised to
the same power. Substituting into the equation to solve for pressure gives
867 kg 9.80665 m 1 atm

pressure  87 m  3
 2
 7.40 10 5 kg/m  s 2  7.40 10 5 Pa   7.3
m s 101,325 Pa
atm
Think It’s easier to see how the units cancel if we express the pressure in pascals using base SI units.
About It:
10.18 Start by converting the density of isopropanol to kg/m3.
3
0.785 g 1 kg  100 cm 
? kg/m3 =     785 kg/m3
1 cm 3 1000 g  1 m 
785 kg 9.80665 m 1 atm
pressure  264 m  3
 2
 2.03 10 6 kg/m  s 2  2.03 10 6 Pa   20.1 atm
m s 101,325 Pa
10.19 Boyle’s law states that the volume of a sample of a gas at constant temperature is inversely proportional to
pressure.
1
V  k1 1 1  P2V2
or PV (at constant temperature)
P
Charles’s law states that the volume of a sample of gas at constant pressure is directly proportional to its
absolute temperature.

V1 V2
V  k2T or  (at constant pressure)
T1 T2
Avogadro’s law states that the volume of a sample of gas at constant temperature and pressure is directly
proportional to the number of moles.
V
V  k3 n or  k3 (at constant temperature and pressure)
n
10.20 As the balloon rises, the air pressure decreases. This causes the volume to increase according to Boyle’s
law.
10.21 Strategy: This is a Boyle’s law problem. Temperature and the amount of gas are both constant.
Therefore, we can use Equation 10.3 to solve for the final volume.
Solution: Initial Conditions Final Conditions
P1 = 0.970 atm P2 = 0.541 atm
V1 = 25.6 mL V2 = ?
P1V1 0.970 atm 25.6 mL

V2 =   45.9 mL
P2 0.541 atm
Think Make sure that Boyle’s law is obeyed. If the pressure decreases at constant temperature, the
About It: volume must increase.
10.22 Solve for the final pressure using Equation 10.3,
P1V1 = P2V2
Initial Conditions Final Conditions
P1 = 5.3 atm P2 = ?
V1 = ? V2 = V1/4
Although neither V1 nor V2 is specified, we know from the statement of the problem that the ratio of V1 to
V2 is 4.
PV PV
P2  1 1  1 1  4P1
V2  V1 
 4 
 
P2 = 4(5.3 atm) = 21 atm

10.23 Strategy: The amount of gas and the temperature remain constant in this problem. We can use Equation
10.3 (Boyle’s Law) to solve for the unknown pressure.
P1 = 1.00 atm = 760 mmHg P2 = ?
V1 = 7.15 L V2 = 9.25 L
P1V1 = P2V2
P1V1 760 mmHg7.15 L 

P2 =   587 mmHg
V2 9.25 L
10.24 a. We use Equation 10.3 to solve for the unknown volume.

P1V1 = P2V2
P1 = 1.2 atm P2 = 6.6 atm
V1 = 3.8 L V2 = ?
The final volume is given by:
PV
1 1
V2 
P2
(1.2 atm)(3.8 L)
V2   0.69 L
(6.6 atm)
b. We use Equation 10.3 again to solve for the unknown pressure.

P1 = 1.2 atm P2 = ?
V1 = 3.8 L V2 = 0.075 L
The final pressure is given by:
PV
1 1
P2 
V2
(1.2 atm)(3.8 L)
P2   61 atm
(0.075 L)
10.25 Strategy: Pressure is held constant in this problem. Only volume and temperature change. This is a
Charles’s law problem. We use Equation 10.5 to solve for the unknown volume.

V1 V
 2
T1 T2
T1 = 35C + 273 = 308 K T2 = 72 + 273 = 345 K
V1 = 28.4 L V2 = ?
V1T2 28.4 L345 K 

V2 =   31.8 L
T1 308 K
Think Make sure you express temperatures in kelvins and that Charles’s law is obeyed. At constant
About It: pressure, when temperature increases, volume should also increase.
10.26 Pressure and the amount of gas are constant in this problem. Only temperature and volume change. This is a
Charles’s law problem. Rearranging Equation 10.5 to solve for the unknown temperature,
TV
T2  1 2
V1

T1 = 88C + 273 = 361 K T2 = ?
V1 = 9.6 L V2 = 3.4 L
(361 K)(3.4 L)
T2   1.3  102 K
(9.6 L)
10.27 The balanced equation is:
4NH3(g) + 5O2(g) 
 4NO(g) + 6H2O(g)
Recall that Avogadro’s Law states that the volume of a gas is directly proportional to the number of moles
of gas at constant temperature and pressure. The ammonia and nitric oxide coefficients in the balanced
equation are the same, so one volume of nitric oxide must be obtained from one volume of ammonia.
Could you have reached the same conclusion if you had noticed that nitric oxide is the only nitrogen-
containing product and that ammonia is the only nitrogen-containing reactant?
10.28 This is a gas stoichiometry problem that requires knowledge of Avogadro’s law to solve. Avogadro’s law
states that the volume of a gas is directly proportional to the number of moles of gas at constant temperature
and pressure.
The volume ratio, 1 vol. Cl2 : 3 vol. F2 : 2 vol. product, can be written as a mole ratio,

1 mol Cl2 : 3 mol F2 : 2 mol product.
Attempt to write a balanced chemical equation. The subscript of F in the product will be three times the Cl
subscript, because there are three times as many F atoms reacted as Cl atoms.
1Cl2(g) + 3F2(g)   2ClxF3x(g)

Balance the equation. The x must equal one so that there are two Cl atoms on each side of the equation. If
x = 1, the subscript on F is 3.
Cl2(g) + 3F2(g) 
 2ClF3(g)
The formula of the product is ClF3.
10.29 a. If the final temperature of the sample is above the boiling point, it would still be in the gas phase. The
diagram that best represents this is choice (d).
b. If the final temperature of the sample is below its boiling point, it will condense to a liquid. The liquid
will have a vapor pressure, so some of the sample will remain in the gas phase. The diagram that best
represents this is choice (b).
10.30 1
(1) Recall that V  . As the pressure is tripled, the volume will decrease to 1
3 of its original
P
volume, assuming constant n and T. The correct choice is (b).
(2) Recall that V  T. As the temperature is doubled, the volume will also double, assuming constant n
and P. The correct choice is (a). The depth of color indicates the density of the gas. As the
volume increases at constant moles of gas, the density of the gas will decrease. This decrease in
gas density is indicated by the lighter shading.
(3) Recall that V  n. Starting with n moles of gas, adding another n moles of gas (2n total) will
double the volume. The correct choice is (c). The density of the gas will remain the same as moles
are doubled and volume is doubled.
1
(4) Recall that V  T and V  . Halving the temperature would decrease the volume to 1 2 its
P
original volume. Because the number of moles of gas is constant, halving the volume will double
the density, thus increasing the intensity of color. The correct choice is (d).
10.31 An ideal gas is a hypothetical sample of gas whose pressure-volume-temperature behavior is predicted
accurately by the ideal gas equation. Although the behavior of real gases generally differs slightly from that
predicted by the ideal gas equation, in most of the cases we will encounter, the differences are usually small
enough for us to use the ideal gas equation to make reasonably good predictions about the behavior of gases.
10.32 0°C and 1 atm. At STP, 1 mole of gas has a volume of 22.41 L.
10.33 The molecules/atoms in a sample of gas are very far apart. The density of a gas is expressed in g/L, whereas
the densities of liquids and solids are expressed in g/mL.

10.34 Rearranging Equation 10.9 to solve for number of moles gives

n=
PV

4.1 atm 4.5 L   0.75 mol
RT  L  atm 
 0.0821 300 K 
 mol  K 
10.35 Strategy: This problem gives the amount, volume, and temperature of CO gas. Is the gas undergoing a
change in any of its properties?
Solution: Because no changes in gas properties occur, we can use the ideal gas equation to calculate the
nRT
pressure. Rearranging Equation 10.9 of the text, we write: P 
V
6.9 mol 0.0821 L  atm 355 K 

 mol  K 
P=  6.6 atm
30.4 L 
Think Don’t forget to convert temperatures from C to K!

About It:
10.36 We solve the ideal gas equation for V.
9.8 mol 0.0821 L  atm 378 K 

nRT  mol  K 
V=   32 L
P 9.4 atm 
10.37 In this problem, the moles of gas and the volume the gas occupies are constant. Temperature and pressure
change. We use the equation derived in Problem 10.53:
P1 P
 2
T1 T2
P1 = 1.00 atm P2 = ?
T1 = 273 K T2 = 210C + 273 = 483 K
Solving for the final pressure gives
P1T2 1.00 atm483 K 

P2 =   1.8 atm
T1 273 K
10.38 Only n and R are constant in this problem. Temperature, volume, and pressure all change. Use the
combined gas law (Equation 10.8b).

PV
1 1 PV
 2 2
T1 T2

P1 = 1.2 atm P2 = 3.00  103 atm
V1 = 2.50 L V2 = ?
T1 = 20C + 273 = 293 K T2 = 23C + 273 = 250 K
Solving for V2 gives

P1V1T2 1.2 atm2.50 L 250 K 
V2    8.5  102 L
T1P2 
293 K  3.00  10 atm
3

10.39 Strategy: In this problem, the moles of gas and the pressure on the gas are constant. Temperature and
volume both change. This is a Charles’s law problem and we use Equation 10.5 to solve it.
Note that the way the problem is stated, it is V1 that is unknown.
V1 V2

T1 T2
V1 = ? V2 = 0.67 L
T1 = 36.5 + 273.15 = 309.7 K T2 = 22.5C + 273 = 295.7 K
Solution: Solving Equation 10.5 for the original volume of the gas gives
V2T1 0.67 L 309.7 K 

V1 =   0.70 L
T2 295.7 K
10.40 Use the combined gas law (Equation 10.8b).
PV
1 1 PV
 2 2
T1 T2
Solving for the initial volume,
P2V2T1 (0.60 atm)(94 mL)(66  273)K

V1    71 mL
PT
1 2 (0.85 atm)(45  273)K
10.41 In the problem, temperature and pressure are given. If we can determine the moles of CO2, we can calculate
the volume it occupies using the ideal gas equation.
1 mol CO 2
? mol CO2 = 124.3 g CO2   2.8244 mol CO2
44.01 g CO 2
We now substitute into the ideal gas equation to calculate volume of CO2.

2.8244 mol 0.08206 L  atm 273.15 K 

V CO 2 =   63.31 L
P 1 atm
Note that because there are four significant figures in the mass, we use more significant figures than we
usually do for R and for the temperature. We also carried an extra digit in the calculated number of moles to
avoid rounding error in the final result.
Alternatively, we could use the fact that 1 mole of an ideal gas occupies a volume of 22.41 L at STP. After
calculating the moles of CO2, we can use this fact as a conversion factor to convert to volume of CO2.
22.41 L
? L CO2  2.8244 mol   63.29 L
1 mol
The slight difference in the results of our two calculations is due to rounding the volume occupied by 1 mole
of an ideal gas to 22.41 L.
10.42 PV
1 1  P2V2
T1 T2
P1V1T2 572 mmHg6.15 L 273 K 

V2 =   4.10 L
P2T1 760 mmHg308 K 
10.43 The molar mass of CO2 = 44.01 g/mol. Since PV = nRT, we write:
nRT
P 
V
 1 mol   L  atm 
 0.050 g    0.0821 (30  273)K
44.01 g   mol  K 
P    6.1  103 atm
4.6 L
10.44 Solve for the number of moles of gas using the ideal gas equation.
PV (1.00 atm)(0.280 L)
n    0.0125 mol
 0.0821 (273 K)
 mol  K 
Solving for the molar mass:
mass (in g) 0.400 g

M    32.0 g/mol
mol 0.0125 mol
10.45 Strategy: We can calculate the molar mass of a gas if we know its density, temperature, and pressure.
What temperature and pressure units should we use?

Solution: We need to use Equation 10.11 of the text to calculate the molar mass of the gas.
dRT
M 
P
Before substituting into the above equation, we need to calculate the density and check that the
other known quantities (P and T) have the appropriate units.
7.10 g
d   1.31 g/L
5.40 L
T = 44C + 273 = 317 K
1 atm
P  741 torr   0.975 atm
760 torr
Calculate the molar mass by substituting in the known quantities.
 g  L  atm 
1.31 L  0.0821 mol  K  (317 K)
M      35.0 g/mol
0.975 atm
Alternatively, we can solve for the molar mass by writing:
mass of compound
molar mass of compound 
moles of compound
Mass of compound is given in the problem (7.10 g), so we need to solve for moles of compound
in order to calculate the molar mass.
PV
n 
RT
(0.975 atm)(5.40 L)
n   0.202 mol
 L  atm 
 0.0821 (317 K)
 mol  K 
Now, we can calculate the molar mass of the gas.
mass of compound 7.10 g

molar mass of compound    35.1 g/mol
moles of compound 0.202 mol
10.46 First calculate the moles of ozone (O3) using the ideal gas equation.
PV (1.0  103 atm)(1.0 L)

n    4.9  105 mol O3
 0.0821 mol  K  (250 K)
 

Use Avogadro’s number as a conversion factor to convert to molecules of O3.

6.022  1023 O3 molecules
molecules O3  (4.9  105 mol O3 )   3.0  1019 O3 molecules
1 mol O3
10.47 The number of particles in 1 L of gas at STP is:
1 mol 6.022  1023 particles

Number of particles  1.0 L    2.69  10 22 particles
22.41 L 1 mol
Number of N2 molecules = 0.78  2.69  1022 particles = 2.1  1022 N2 molecules
Number of O2 molecules = 0.21  2.69  1022 particles = 5.6  1021 O2 molecules
Number of Ar atoms = 0.01  2.69  1022 particles = 2.7  1020 Ar molecules
10.48 The density is given by:
mass 4.65 g
density    2.21 g/L
volume 2.10 L

2.21 g/L  0.0821 L  atm 300 K 
dRT  mol  K 
molar mass =   54.4 g/mol
P 1.00 atm 
10.49 The density can be calculated from the ideal gas equation.
PM
d 
RT
M = 1.008 g/mol + 79.90 g/mol + 80.91 g/mol
T = 46C + 273 = 319 K
1 atm
P  733 mmHg   0.964 atm
760 mmHg
 80.91 g 
(0.964 atm)  
 1 mol  mol  K
d    2.98 g/L
319 K 0.0821 L  atm
Alternatively, we can solve for the density by writing:
mass
density 
volume
Assuming that we have 1 mole of HBr, the mass is 80.91 g. The volume of the gas can be calculated using

the ideal gas equation.
nRT
V 
P
 L  atm 
(1 mol)  0.0821 (319 K)
 mol  K 
V   27.2 L
0.964 atm
Now, we can calculate the density of HBr gas.
mass 80.91 g
density    2.97 g/L
volume 27.2 L
10.50 METHOD 1:
The empirical formula can be calculated from mass percent data. The molar mass can be calculated using
the ideal gas equation. The molecular formula can then be determined.
To calculate the empirical formula, assume 100 g of substance.
1 mol C
64.9 g C   5.40 mol C
12.01 g C
1 mol H
13.5 g H   13.4 mol H
1.008 g H
1 mol O
21.6 g O   1.35 mol O
16.00 g O
This gives the formula C5.40H13.4O1.35. Dividing by 1.35 gives the empirical formula, C4H10O.
To calculate the molar mass, first calculate the number of moles of gas using the ideal gas equation.
 1 atm 
 750 mmHg   (1.00 L)
760 mmHg 
 
PV
n   0.0306 mol
 0.0821 mol  K  (120  273)K
 
mass (in g) 2.30 g

M    75.2 g/mol
mol 0.0306 mol
The empirical mass is 74.0 g/mol which is essentially the same as the molar mass. In this case, the
molecular formula is the same as the empirical formula, C4H10O.
METHOD 2:
First calculate the molar mass using the ideal gas equation.

 1 atm 
 750 mmHg   (1.00 L)
PV  760 mmHg 
n    0.0306 mol
 0.0821 (120  273)K
 mol  K 
mass (in g) 2.30 g

M    75.2 g/mol
mol 0.0306 mol
Next, multiply the mass % (converted to a decimal) of each element by the molar mass to convert to grams
of each element. Then, use the molar mass to convert to moles of each element.
1 mol C
nC  (0.649)  (75.2 g)   4.06 mol C
12.01 g C
1 mol H
nH  (0.135)  (75.2 g)   10.07 mol H
1.008 g H
1 mol O
nO  (0.216)  (75.2 g)   1.02 mol O
16.00 g O
Since we used the molar mass to calculate the moles of each element present in the compound, this method
directly gives the molecular formula. The formula is C4H10O.
10.51 This is an extension of an ideal gas law calculation involving molar mass. If you determine the molar mass
of the gas, you will be able to determine the molecular formula from the empirical formula.
dRT
M 
P
Calculate the density, then substitute its value into the equation above.
0.100 g 1000 mL
d    4.52 g/L
22.1 mL 1L
T(K) = 20C + 273 = 293 K
 g  L  atm 
 4.52 L   0.0821 mol  K  (293 K)
M      107 g/mol
1.02 atm
Compare the empirical mass to the molar mass.
empirical mass = 32.07 g/mol + 4(19.00 g/mol) = 108.07 g/mol
Remember, the molar mass will be a whole number multiple of the empirical mass. In this case, the

molar mass
 1. Therefore, the molecular formula is the same as the empirical formula, SF4.
empirical mass
10.52 T2
In this problem, the statement “...its absolute temperature is decreased by one-half” means that  0.50 .
T1
P2 1
Similarly, the statement “...pressure is decreased to one-third of its original pressure” indicates  .
P1 3
Use the combined gas law (Equation 10.8b).
PV
1 1 PV
 2 2
T1 T2
Solving for V2 gives
 P  T 
V2 = V1  1  2   6.0 L  3.0  0.50  9.0 L
 P2  T1 
10.53 Strategy: In this problem, the moles of gas are constant. Use the combined gas law (Equation 10.8b).
PV
1 1 PV
 2 2
T1 T2
Because V is constant, the above equation reduces to
P1 P
 2
T1 T2
Solution: The final temperature is given by:
T1P2
T2 
P1
T2 =
298 K 5.00 atm   1.86  103 K = 1590C
0.800 L
Think At a temperature of 1590C, the pressure in the vessel would be 5.00 atm. Any temperature
About It: higher than 1590C would result in a pressure above 5.00 atm and the vessel would burst.
10.54 In addition to a mole ratio, the coefficients from a balanced equation can represent the volume ratio in which
the gases in the equation react and are produced. Recall that Avogadro’s Law states that V µ n. See Figure
10.11 of the text. We can use this volume ratio to convert from liters of NO to liters of NO2.

2 volumes NO2
9.0 L NO   9.0 L NO2
2 volumes NO
10.55 Strategy: From the moles of CH4 that reacts, we can calculate the moles of CO2 produced. From the
balanced equation, we see that 1 mol CH4 is stoichiometrically equivalent to 1 mol CO2. Once
moles of CO2 are determined, we can use the ideal gas equation to calculate the volume of CO2.
Solution: First let’s calculate moles of CO2 produced.
1 mol CO2
? mol CO2  15.0 mol CH 4   15.0 mol CO2
1 mol CH 4
Now, we can substitute moles, temperature, and pressure into the ideal gas equation to solve for
volume of CO2.
nRT
V 
P
 L  atm 
(15.0 mol)  0.0821 (23  273) K
 mol  K 
VCO 2   3.70  102 L
0.985 atm
10.56 If we can calculate the moles of S, we can use the mole ratio from the balanced equation to calculate the
moles of SO2. Once we know the moles of SO2, we can determine the volume of SO2 using the ideal gas
equation.
3.15  10 3

gS 
1 mol S 1 mol SO 2
32.07 g S

1 mol S
 98.2 mol SO 2
98.2 mol 0.0821 L  atm 303.5 K 

V=   2.35  103 L  2.35  106 mL SO2
P 1.04 atm
10.57 From the amount of glucose that reacts (5.97 g), we can calculate the theoretical yield of CO2. We can then
compare the theoretical yield to the actual yield given in the problem (1.44 L) to determine the percent yield.
First, let’s determine the moles of CO2 that can be produced theoretically. Then, we can use the ideal gas
equation to determine the volume of CO2.
1 mol glucose 2 mol CO 2

? mol CO 2  5.97 g glucose    0.0663 mol CO2
180.2 g glucose 1 mol glucose
Now, substitute moles, pressure, and temperature into the ideal gas equation to calculate the volume of CO2.

nRT
V 
P
 L  atm 
(0.0663 mol)  0.0821 (293 K)
 mol  K 
VCO 2   1.62 L
0.984 atm
This is the theoretical yield of CO2. The actual yield, which is given in the problem, is 1.44 L. We can now
calculate the percent yield.
actual yield
percent yield   100%
theoretical yield
1.44 L
percent yield   100%  88.9%
1.62 L
10.58 If you determine the molar mass of the gas, you will be able to determine the molecular formula from the
empirical formula. First, let’s calculate the molar mass of the compound.
 1 atm 
 97.3 mmHg   (0.378 L)
PV  760 mmHg 
n    0.00168 mol
 0.0821 mol  K  (77  273)K
 
mass (in g) 0.2324 g

M    138 g/mol
mol 0.00168 mol
To calculate the empirical formula, first we need to find the mass of F in 0.2631 g of CaF2.
1 mol CaF2 2 mol F 19.00 g F

0.2631 g CaF2     0.1280 g F
78.08 g CaF2 1 mol CaF2 1 mol F
Since the compound only contains P and F, the mass of P in the 0.2324 g sample is:
0.2324 g  0.1280 g = 0.1044 g P
Now, we can convert masses of P and F to moles of each substance.
1 mol P
? mol P  0.1044 g P   0.003371 mol P
30.97 g P
1 mol F
? mol F  0.1280 g F   0.006737 mol F
19.00 g F
Thus, we arrive at the formula P0.003371F0.006737. Dividing by the smallest number of moles (0.003371 mole)
gives the empirical formula PF2.

To determine the molecular formula, divide the molar mass by the empirical mass.
molar mass 138 g

  2
empirical molar mass 68.97 g
Hence, the molecular formula is (PF2)2 or P2F4.
10.59 Strategy: We can calculate the moles of M consumed, and the moles of H2 gas produced. By comparing
the number of moles of M consumed to the number of moles H2 produced, we can determine the
mole ratio in the balanced equation.
Solution: First let’s calculate the moles of the metal (M) consumed.
1 mol M
mol M  0.225 g M   8.33  103 mol M
27.0 g M
Solve the ideal gas equation algebraically for nH2 . Then, calculate the moles of H2 by
substituting the known quantities into the equation.
1 atm
P  741 mmHg   0.975 atm
760 mmHg
T = 17C + 273 = 290 K
PVH 2
nH 2 
RT
(0.975 atm)(0.303 L)
nH 2   1.24  102 mol H 2
 L  atm 
 0.0821 mol  K  (290 K)
 
Compare the number moles of H2 produced to the number of moles of M consumed.
1.24  10 2 mol H 2
 1.5
8.33  10 3 mol M
This means that the mole ratio of H2 to M is 1.5 : 1.
We can now write the balanced equation since we know the mole ratio between H2 and M.
The unbalanced equation is:
M(s) + HCl(aq) 
 1.5H2(g) + MxCly(aq)
We have 3 atoms of H on the products side of the reaction, so a 3 must be placed in front of
HCl. The ratio of M to Cl on the reactants side is now 1 : 3. Therefore the formula of the metal

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CHAPTER XI
THE ENLARGEMENT OF CONSCIOUSNESS
Narrowness of Consciousness in Tribal Society—Importance

of Face-to-Face Assembly—Individuality—Subconscious
Character of Wider Relations—Enlargement of
Consciousness—Irregularity in Growth—Breadth of
Modern Consciousness—Democracy.
In a life like that of the Teutonic tribes before they took on Roman
civilization, the social medium was small, limited for most purposes
to the family, clan or village group. Within this narrow circle there
was a vivid interchange of thought and feeling, a sphere of moral
unity, of sympathy, loyalty, honor and congenial intercourse. Here
precious traditions were cherished, and here also was the field for an
active public opinion, for suggestion and discussion, for leading and
following, for conformity and dissent. “In this kindly soil of the family,”
says Professor Gummere in his Germanic Origins, “flourished such
growth of sentiment as that rough life brought forth. Peace, good-will,
the sense of honor, loyalty to friend and kinsman, brotherly affection,
all were plants that found in the Germanic home that congenial
warmth they needed for their earliest stages of growth.... Originally
the family or clan made a definite sphere or system of life; outside of
it the homeless man felt indeed that chaos had come again.”[45]
When we say that public opinion is modern, we mean, of course,
the wider and more elaborate forms of it. On a smaller scale it has
always existed where people have had a chance to discuss and act
upon matters of common interest. Among our American Indians, for
example, “Opinion was a most potent factor in all tribes, and this
would be largely directed by those having popularity and power.
Officers, in fact all persons, became extremely well known in the
small community of an Amerind tribe. Every peculiarity of
temperament was understood, and the individual was respected or
despised according to his predominating characteristics. Those who
were bold and fierce and full of strategy were made war-chiefs, while
those who possessed judgment and decision were made civil chiefs
or governors.”[46] The Germanic tribes were accustomed to
assemble in those village moots to which the historian recurs with
such reverence, where “the men from whom Englishmen were to
spring learned the worth of public opinion, of public discussion, the
worth of the agreement, the ‘common-sense’ to which discussion
leads, as of the laws which derive their force from being expressions
of that general conviction.”[47]
Discussion and public opinion of this simple sort, as every one
knows, takes place also among children wherever they mingle freely.
Indeed, it springs so directly from human nature, and is so difficult to
suppress even by the most inquisitorial methods, that we may
assume it to exist locally in all forms of society and at all periods of
history. It grows by looks and gestures where speech is forbidden, so
that even in a prison there is public opinion among the inmates. But
in tribal life these local groups contained all the vivid and conscious
society there was, the lack of means of record and of quick
transmission making a wider unity impracticable.
In the absence of indirect communication people had to come into
face-to-face contact in order to feel social excitement and rise to the
higher phases of consciousness. Hence games, feasts and public
assemblies of every sort meant more to the general life than they do
in our day. They were the occasions of exaltation, the theatre for the
display of eloquence—either in discussing questions of the moment
or recounting deeds of the past—and for the practice of those
rhythmic exercises that combined dancing, acting, poetry and music
in one comprehensive and communal art. Such assemblies are
possibly more ancient than human nature itself—since human nature
implies a preceding evolution of group life—and in some primitive
form of them speech itself is supposed by some to have been born.
Just as children invent words in the eagerness of play, and slang
arises among gangs of boys on the street, so the earliest men were
perhaps incited to the invention of language by a certain ecstasy and
self-forgetting audacity, like that of the poet, sprung from the
excitement of festal meetings.[48]
Something of the spirit of these primitive assemblies is perhaps
reproduced in the social exaltation of those festal evenings around
the camp-fire which many of us can recall, with individual and group
songs, chants, “stunts” and the like; when there were not wanting
original, almost impromptu, compositions—celebrating notable
deeds or satirizing conspicuous individuals—which the common
excitement generated in the minds of one or more ingenious
persons.
It is sometimes said that the individual counted for nothing in tribal
life, that the family or the clan was the unit of society, in which all
personalities were merged. From the standpoint of organization
there is much truth in this; that is the group of kindred was for many
purposes (political, economic, religious, etc.) a corporate unit, acting
as a whole and responsible as a whole to the rest of society; so that
punishment of wrong-doing, for example, would be exacted from the
group rather than from the particular offender. But taken
psychologically, to mean that there was a lack of self-assertion, the
idea is without foundation. On the contrary, the barbaric mind exalts
an aggressive and even extravagant individuality. Achilles is a fair
sample of its heroes, mighty in valor and prowess, but vain, arrogant
and resentful—what we should be apt to call an individualist.[49] The
men of the Niebelungenlied, of Beowulf, of Norse and Irish tales and
of our Indian legends are very much like him.
Consider, also, the personal initiative displayed in the formation of
a war-party among the Omahas, as described by Dorsey, and note
how little it differs from the way in which commercial and other
enterprises are started at the present day.
“It is generally a young man who decides to undertake an
expedition against the enemy. Having formed his plan he speaks
thus to his friend: ‘My friend, as I wish to go on the war path, let us
go. Let us boil the food as for a feast.’ The friend having consented,
the two are the leaders ... if they can induce others to follow them.
So they find two young men whom they send as messengers to
invite those whom they name.... When all have assembled the
planner of the expedition addresses the company. ‘Ho! my friends,
my friend and I have invited you to a feast, because we wish to go
on the war path.’ Then each one who is willing to go replies thus:
‘Yes, my friend, I am willing.’ But he who is unwilling replies, ‘My
friend, I do not wish to go, I am unwilling.’ Sometimes the host says,
‘Let us go by such a day. Prepare yourselves.’”[50]
The whole proceeding reminds one also of the way games are
initiated among boys, the one who “gets it up” having the right to
claim the best position. No doubt the structure of some tribal
societies permitted of less initiative than others; but such differences
exist at all stages of culture.
Self-feeling, self-assertion and the general relation of the individual
to the group are much the same at all epochs, and there was never a
time since man became human when, as we sometimes read,
“personality emerged.” Change has taken place chiefly in the extent
and character of the group to which the individual appeals, and in the
ways in which he tries to distinguish himself. The Germanic
tribesman, the mediæval knight, the Renaissance artist or scholar
and the modern captain of industry are alike ambitious: it is the
object that differs. There has, indeed, been a development of
personality in history, but it has been correlative with that of the
general life, and has brought no essential change in the relation
between the two.
In tribal life, then, since the conditions did not admit of wider
unification, public consciousness could be only local in scope.
Beyond its narrow range the cords which held life together were of a
subconscious character—heredity, of course, with its freight of
mental and social tendency; oral tradition, often vague and devious,
and a mass of custom that was revered without being understood.
These wider relations, not being surveyed and discussed, could not
be the objects of deliberate thought and will, but were accepted as
part of the necessary order of things, and usually ascribed to some
divine source. In this way language, laws, religion, forms of
government, social classes, traditional relations to other clans or
tribes—all of which we know to have been built up by the cumulative
workings of the human mind—were thought of as beyond the sphere
of man’s control.
The wider unity existed, then as now; human development was
continuous in time and, after a blind fashion, coöperative among
contemporaries. The tools of life were progressively invented and
spread by imitation from tribe to tribe, the fittest always tending to
survive; but only the immediate details of such changes were
matters of consciousness: as processes they were beyond human
cognizance. A man might adapt an ancient custom to a fresh
emergency, but he would be unaware that he was shaping the
growth of institutions.
There was even a tribal or national opinion, of a slow,
subconscious sort; a growth and consensus of ideas upon matters of
general and enduring interest, such as religion, marriage and
government. And, under unusual pressure, some more conscious
unity of spirit might be aroused, as among the Germans or Gauls
confederated against Rome; but this was likely to be transient.
The central fact of history, from a psychological point of view, may
be said to be the gradual enlargement of social consciousness and
rational coöperation. The mind constantly, though perhaps not
regularly, extends the sphere within which it makes its higher powers
valid. Human nature, possessed of ideals moulded in the family and
the commune, is ever striving, somewhat blindly for the most part,
with those difficulties of communication and organization which
obstruct their realization on a larger scale. Whether progress is
general or not we need not now inquire; it is certain that great gains
have been made by the more vigorous or fortunate races, and that
these are regarded with emulation and hope by many of the others.
Throughout modern European history, at least, there has been an
evident extension of the local areas within which communication and
coöperation prevail, and, on the whole, an advance in the quality of
coöperation as judged by an ideal moral unity. It has tended to
become more free and human, more adequately expressive of
communal feeling.
Perhaps all apparent departures from this tendency may plausibly
be explained as cases of irregular growth. If we find that vast
systems of discipline, like the Roman Empire, have broken down, we
find also that these systems were of a low type, psychologically, that
the best features of them were after all preserved, and that the new
systems that arose, though perhaps less in extent, were on the
whole a higher and fuller expression of human nature.
In the later Empire, for example, it seems plain that social
mechanism (in its proper kind and measure one of the conditions of
freedom) had grown in such a way as to shackle the human mind. In
order to achieve and maintain an imperial reach of control, the state
had gradually been forced to take on a centralized bureaucratic
structure, which left the individual and the local group no sphere of
self-reliant development. Public spirit and political leadership were
suppressed, and the habit of organized self-expression died out,
leaving the people without group vitality and as helpless as children.
They were not, in general, cowards or voluptuaries—it seems that
the decline of courage and domestic morals has been exaggerated
—but they had no trained and effective public capacity. Society, as
Professor Dill says, had been elaborately and deliberately
stereotyped.
The decline of vitality and initiative pervaded all spheres of life.
There were no inventions and little industrial or agricultural progress
of any kind. Literature degenerated into rhetoric: “In the same
manner,” says Longinus, “as some children always remain pigmies,
whose infant limbs have been too closely confined, thus our tender
minds, fettered by the prejudices and habits of a just servitude, are
unable to expand themselves, or to attain that well-proportioned
greatness which we admire in the ancients, who, living under a
popular government, wrote with the same freedom as they acted.”[51]
The growing states of the earlier world were confronted, whether
they knew it or not, with an irreconcilable opposition between
freedom and expansion. They might retain in small areas those
simple and popular institutions which nearly all the great peoples
started with, and to which they owed their vigor; or they could
organize on a larger scale a more mechanical unity. In the first case
their careers were brief, because they lacked the military force to
ensure permanence in a hostile world. In the latter they incurred, by
the suppression of human nature, that degeneracy which sooner or
later overtook every great state of antiquity.
In some such way as this we may, perhaps, dispose of the
innumerable instances which history shows of the failure of free
organization—as in the decay of ancient and mediæval city
republics. Not only was their freedom of an imperfect nature at the
best, but they were too small to hold their own in a world that was
necessarily, for the most part, autocratic or customary. Freedom,
though in itself a principle of strength, was on too little a scale to
defend itself. “If a republic be small,” said Montesquieu, “it is
destroyed by a foreign force; if it be large it is ruined by internal
imperfection.”[52]
But how splendid, in literature, in art, and even in arms, were
many of these failures. How well did Athens, Florence and a hundred
other cities illustrate the intrinsic strength and fecundity of that free
principle to which modern conditions permit an indefinite expansion.
The present epoch, then, brings with it a larger and, potentially at
least, a higher and freer consciousness. In the individual aspect of
life this means that each one of us has, as a rule, a wider grasp of
situations, and is thus in a position to give a wider application to his
intelligence, sympathy and conscience. In proportion as he does this
he ceases to be a blind agent and becomes a rational member of the
whole.
Because of this more conscious relation to the larger wholes—
nations, institutions, tendencies—he takes a more vital and personal
part in them. His self-feeling attaches itself, as its nature is, to the
object of his free activity, and he tends to feel that “love of the maker
for his work,” that spiritual identification of the member with the
whole, which is the ideal of organization.
De Tocqueville found that in the United States there was no
proletariat. “That numerous and turbulent multitude does not exist,
who regarding the law as their natural enemy look upon it with fear
and distrust. It is impossible, on the contrary, not to perceive that all
classes ... are attached to it by a kind of parental affection.”[53] And,
notwithstanding a deep and well-grounded “social unrest,” this
remains essentially true at the present day, and should be true of all
real democracy. Where the state is directly and obviously founded
upon the thought of the people it is impossible to get up much
fundamental antagonism to it; the energies of discontent are
absorbed by moderate agitation.
The extension of reach and choice favors, in the long run, not only
political but every kind of opportunity and freedom. It opens to the
individual a more vital, self-determined and energetic part in all
phases of the whole.
At the same time, the limits of human faculty make it impossible
that any one of us should actually occupy all the field of thought thus
open to him. Although stimulated to greater activity than before, one
must constantly select and renounce; and most of his life will still be
on the plane of custom and mechanism. He is freer chiefly in that he
can survey the larger whole and choose in what relations he will
express himself.
Indeed, an ever-present danger of the new order is that one will
not select and renounce enough, that he will swallow more than he
can properly digest, and fail of the benefits of a thorough
subconscious assimilation. The more one studies current life, the
more he is inclined to look upon superficiality as its least tractable
defect.
The new conditions demand also a thorough, yet diversified and
adaptable, system of training for the individual who is to share in this
freer and more exigent society. While democracy as a spirit is
spontaneous, only the fullest development of personal faculty can
make this spirit effectual on a great scale. Our confidence in our
instincts need not be shaken, but our application of them must be
enlarged and enlightened. We must be taught to do some one thing
well, and yet never allowed to lose our sense of the relation of that
one thing to the general endeavor.
The general or public phase of larger consciousness is what we
call Democracy. I mean by this primarily the organized sway of public
opinion. It works out also in a tendency to humanize the collective
life, to make institutions express the higher impulses of human
nature, instead of brutal or mechanical conditions. That which most
inwardly distinguishes modern life from ancient or mediæval is the
conscious power of the common people trying to effectuate their
instincts. All systems rest, in a sense, upon public opinion; but the
peculiarity of our time is that this opinion is more and more rational
and self-determining. It is not, as in the past, a mere reflection of
conditions believed to be inevitable, but seeks principles, finds these
principles in human nature, and is determined to conform life to them
or know why not. In this all earnest people, in their diverse ways, are
taking part.
We find, of course, that but little can be carried out on the highest
moral plane; the mind cannot attend to many things with that
concentration which achieves adequate expression, and the principle
of compensation is ever at work. If one thing is well done, others are
overlooked, so that we are constantly being caught and ground in
our own neglected mechanism.
On the whole, however, the larger mind involves a democratic and
humanistic trend in every phase of life. A right democracy is simply
the application on a large scale of principles which are universally
felt to be right as applied to a small group—principles of free
coöperation motived by a common spirit which each serves
according to his capacity. Most of what is characteristic of the time is
evidently of this nature; as, for instance, our sentiment of fair play,
our growing kindliness, our cult of womanhood, our respect for hand
labor, and our endeavor to organize society economically or on
“business principles.” And it is perhaps equally evident that the ideas
which these replace—of caste, of domination, of military glory, of
“conspicuous leisure”[54] and the like—sprang from a secondary and
artificial system, based on conditions which forbade a large
realization of primary ideals.
May we not say, speaking largely, that there has always been a
democratic tendency, whose advance has been conditioned by the
possibility, under actual conditions, of organizing popular thought
and will on a wide scale? Free coöperation is natural and human; it
takes place spontaneously among children on the playground,
among settlers in new countries, and among the most primitive sorts
of men—everywhere, in short, where the secondary and artificial
discipline has not supplanted it. The latter, including every sort of
coercive or mechanical control is, of course, natural in the larger
sense, and functional in human development; but there must ever be
some resistance to it, which will tend to become effective when the
control ceases to be maintained by the pressure of expediency.
Accordingly we see that throughout modern history, and especially
during the past century, there has been a progressive humanism, a
striving to clear away lower forms of coöperation no longer essential,
and to substitute something congenial to natural impulse.
Discussion regarding the comparative merits of monarchy,
aristocracy and democracy has come to be looked upon as
scholastic. The world is clearly democratizing; it is only a question of
how fast the movement can take place, and what, under various
conditions, it really involves. Democracy, instead of being a single
and definite political type, proves to be merely a principle of breadth
in organization, naturally prevalent wherever men have learned how
to work it, under which life will be at least as various in its forms as it
was before.
It involves a change in the character of social discipline not
confined to politics, but as much at home in one sphere as another.
With facility of communication as its mechanical basis, it proceeds
inevitably to discuss and experiment with freer modes of action in
religion, industry, education, philanthropy and the family. The law of
the survival of the fittest will prevail in regard to social institutions, as
it has in the past, but the conditions of fitness have undergone a
change the implications of which we can but dimly foresee.
FOOTNOTES:
[45] Pages 169, 171.
[46] F. S. Dellenbaugh, The North Americans of Yesterday, 416.
[47] J. R. Green, History of the English People, i, 13.
[48] J. Donovan, The Festal Origin of Human Speech. Mind,
October, 1891.
[49] “Jura neget sibi nata, nihil non arroget armis.”—Horace,
Ars Poet., 122.
[50] J. O. Dorsey, Omaha Sociology, 315, 316. A publication of
the U. S. Bureau of Ethnology.
[51] Quoted by Gibbon, Decline and Fall, Milman-Smith edition,
i, 194, 195.
[52] The Spirit of Laws, book ix, chap. 1.
[53] Democracy in America, vol. i, chap. 24.
[54] One of many illuminating phrases introduced by T. V.
Veblen in his work on The Theory of the Leisure Class.
CHAPTER XII
THE THEORY OF PUBLIC OPINION
Public Opinion as Organization—Agreement not Essential—

Public Opinion versus Popular Impression—Public
Thought not an Average—A Group is Capable of
Expression through its most competent members—
General and Special Public Opinion—The Sphere of the
Former—Of the Latter—The Two are United in
Personality—How Public Opinion Rules—Effective Rule
Based on Moral Unity.
Public opinion is no mere aggregate of separate individual
judgments, but an organization, a coöperative product of
communication and reciprocal influence. It may be as different from
the sum of what the individuals could have thought out in separation
as a ship built by a hundred men is from a hundred boats each built
by one man.
A group “makes up its mind” in very much the same manner that
the individual makes up his. The latter must give time and attention
to the question, search his consciousness for pertinent ideas and
sentiments, and work them together into a whole, before he knows
what his real thought about it is. In the case of a nation the same
thing must take place, only on a larger scale. Each individual must
make up his mind as before, but in doing so he has to deal not only
with what was already in his thought or memory, but with fresh ideas
that flow in from others whose minds are also aroused. Every one
who has any fact, or thought, or feeling, which he thinks is unknown,
or insufficiently regarded, tries to impart it; and thus not only one
mind but all minds are searched for pertinent material, which is
poured into the general stream of thought for each one to use as he
can. In this manner the minds in a communicating group become a
single organic whole. Their unity is not one of identity, but of life and
action, a crystallization of diverse but related ideas.
It is not at all necessary that there should be agreement; the
essential thing is a certain ripeness and stability of thought resulting
from attention and discussion. There may be quite as much
difference of opinion as there was before, but the differences now
existing are comparatively intelligent and lasting. People know what
they really think about the matter, and what other people think.
Measures, platforms, candidates, creeds and other symbols have
been produced which serve to express and assist coöperation and to
define opposition. There has come to be a relatively complete
organization of thought, to which each individual or group contributes
in its own peculiar way.
Take, for instance, the state of opinion in the United States
regarding slavery at the outbreak of the civil war. No general
agreement had been reached; but the popular mind had become
organized with reference to the matter, which had been turned over
and regarded from all points of view, by all parts of the community,
until a certain ripeness regarding it had been reached; revealing in
this case a radical conflict of thought between the North and the
South, and much local diversity in both sections.
One who would understand public opinion should distinguish
clearly between a true or mature opinion and a popular impression.
The former requires earnest attention and discussion for a
considerable time, and when reached is significant, even if mistaken.
It rarely exists regarding matters of temporary interest, and current
talk or print is a most uncertain index of it. A popular impression, on
the other hand, is facile, shallow, transient, with that fickleness and
fatuity that used to be ascribed to the popular mind in general. It is
analogous to the unconsidered views and utterances of an
individual, and the more one studies it the less seriously he will take
it. It may happen that ninety-nine men in a hundred hold opinions to-
day contrary to those they will hold a month hence—partly because
they have not yet searched their own minds, partly because the few
who have really significant and well-grounded ideas have not had
time to impress them upon the rest.
It is not unreasonable, then, to combine a very slight regard for
most of what passes as public opinion with much confidence in the
soundness of an aroused, mature, organic social judgment.
There is a widespread, but as I believe a fallacious, idea that the
public thought or action must in some way express the working of an
average or commonplace mind, must be some kind of a mean
between the higher and lower intelligences making up the group. It
would be more correct to say that it is representative, meaning by
this that the preponderant feeling of the group seeks definite and
effectual expression through individuals specially competent to give
it such expression. Take for instance the activities of one of our
colleges in intercollegiate athletics or debates. What belongs to the
group at large is a vague desire to participate and excel in such
competitions; but in realizing itself this desire seeks as its agents the
best athletes or debaters that are to be found. A little common-sense
and observation will show that the expression of a group is nearly
always superior, for the purpose in hand, to the average capacity of
its members.
I do not mean morally superior, but simply more effective, in a
direction determined by the prevalent feeling. If a mob is in question,
the brutal nature, for the time-being ascendant, may act through the
most brutal men in the group; and in like manner a money-making
enterprise is apt to put forward the shrewdest agents it can find,
without regard for any moral qualities except fidelity to itself.
But if the life of the group is deliberate and sympathetic, its
expression may be morally high, on a level not merely of the average
member, but of the most competent, of the best. The average theory
as applied to public consciousness is wholly out of place. The public
mind may be on a lower plane than that of the individual thinking in
separation, or it may be on a higher, but is almost sure to be on a
different plane; and no inkling of its probable character can be had
by taking a mean. One mind in the right, whether on statesmanship,
science, morals, or what not, may raise all other minds to its own
point of view—because of the general capacity for recognition and
deference—just as through our aptitude for sudden rage or fear one
mind in the wrong may debase all the rest.
This is the way in which right social judgments are reached in
matters so beyond commonplace capacity as science, philosophy,
and much of literature and art. All good critics tell us that the
judgment of mankind, in the long run, is sure and sound. The world
makes no mistake as to Plato, though, as Emerson said, there are
never enough understanding readers alive to pay for an edition of his
works. This, to be sure, is a judgment of the few; and so, in a sense,
are all finer judgments. The point is that the many have the sense to
adopt them.
And let us note that those collective judgments in literature, art and
science which have exalted Plato and Dante and Leonardo and
Michelangelo and Beethoven and Newton and Darwin, are
democratic judgments, in the sense that every man has been free to
take a part in proportion to his capacity, precisely as the citizen of a
democracy is free to take a part in politics. Wealth and station have
occasionally tried to dictate in these matters, but have failed.
It is natural for an organism to use its appropriate organ, and it
would be as reasonable to say that the capacity of the body for
seeing is found by taking an average of the visual power of the hand,
nose, liver, etc., along with that of the eye, as that the capacity of a
group for a special purpose is that of its average member. If a group
does not function through its most competent instruments, it is
simply because of imperfect organization.
It is strange that people who apply the average theory to
democracy do not see that if it were sound it must apply to all the
social phenomena of history, which is a record of the works of the
collective mind. Since the main difference between democracy and
ancient or mediæval systems is merely that the former is less
restricted by time, space and caste, is essentially an appeal to free
human power as against what is merely mechanical or conventional;
by what magic is this appeal to deprive us of our ancient privilege of
acting through our efficient individuals?
One who ponders these things will see that the principles of
collective expression are the same now as ever, and that the special
difficulties of our time arise partly from confusion, due to the pace of
change, and partly from the greater demands which a free system
makes upon human capacity. The question is, whether, in practice,
democracy is capable of the effective expression to which no very
serious theoretical obstacle can be discerned. It is a matter of doing
a rather simple thing on a vaster and more complicated scale than in
the past.
Public opinion is no uniform thing, as we are apt to assume, but
has its multifarious differentiations. We may roughly distinguish a
general opinion, in which almost everybody in the community has a
part, and an infinite diversity of special or class opinions—of the
family, the club, the school-room, the party, the union, and so on.
And there is an equal diversity in the kind of thought with which the
public mind may be concerned: the content may be of almost any
sort. Thus there are group ideals, like the American ideal of
indissoluble unity among the states, the French ideal of national
glory, or the ideals of honor and good-breeding cherished in many
families; and there are group beliefs, regarding religion, trade,
agriculture, marriage, education and the like. Upon all matters in
which the mind has, in the past, taken a lively interest there are
latent inclinations and prepossessions, and when these are aroused
and organized by discussion they combine with other elements to
form public opinion. Mr. Higginson, recounting his experience in the
Massachusetts legislature, speaks of “certain vast and inscrutable
undercurrents of prejudice ... which could never be comprehended
by academic minds, or even city-bred minds,” but which were usually
irresistible. They related to the rights of towns, the public school
system, the law of settlement, roads, navigable streams, breadth of
wheels, close time of fishing, etc. “Every good debater in the House,
and every one of its recognized legal authorities, might be on one
side, and yet the smallest contest with one of these latent prejudices
would land them in a minority.”[55]
This diversity merely reflects the complexity of organization,
current opinion and discussion being a pervasive activity, essential to
growth, that takes place throughout the system at large and in each
particular member. General opinion existing alone, without special
types of thought as in the various departments of science and art,
would indicate a low type of structure, more like a mob than a
rational society. It is upon these special types, and the individuals
that speak for them, that we rely for the guidance of general opinion
(as, for instance, we rely upon economists to teach us what to think
about the currency), and the absence of mature speciality involves
weakness and flatness of general achievement. This fault is often
charged to democracy, but it should rather be said that democracy is
substituting a free type of speciality, based upon choice, for the old
type based upon caste, and that whatever deficiency exists in this
regard is due chiefly to the confused conditions that accompany
transition.
General public opinion has less scope than is commonly imagined.
It is true that with the new communication, the whole people, if they
are enough interested, may form public judgments even upon
transient questions. But it is not possible, nor indeed desirable, that
they should be enough interested in many questions to form such
judgments. A likeness of spirit and principle is essential to moral
unity, but as regards details differentiation is and should be the rule.
The work of the world is mostly of a special character, and it is quite
as important that a man should mind his own business—that is, his
own particular kind of general service—as that he should have public
spirit. Perhaps we may say that the main thing is to mind his private
business in a public spirit—always remembering that men who are in
a position to do so should make it their private business to attend to
public affairs. It is not indolence and routine, altogether, but also an
inevitable conflict of claims, that makes men slow to exert their
minds upon general questions, and underlies, the political maxim
that you cannot arouse public opinion upon more than one matter at
a time. It is better that the public, like the general-in-chief of an army,
should be relieved of details and free to concentrate its thought on
essential choices.
I have only a limited belief in the efficacy of the referendum and
similar devices for increased participation of the people at large in
the details of legislation. In so far as these facilitate the formation
and expression of public will upon matters to which the public is
prepared to give earnest and continuous attention, they are
serviceable; but if many questions are submitted, or those of a
technical character, the people become confused or indifferent, and
the real power falls into the hands of the few who manage the
machinery.
The questions which can profitably be decided by this direct and
general judgment of the public are chiefly those of organic change or
readjustment, such, for instance, as the contemporary question of
what part the government is to take in relation to the consolidation of
industries. These the people must decide, since no lesser power will
be submitted to, but routine activities, in society as in individuals, are
carried on without arousing a general consciousness. The people
are also, as I shall shortly point out, peculiarly fit to make choice
among conspicuous personalities.
Specialists of all sorts—masons, soldiers, chemists, lawyers,
bankers, even statesmen and public officials—are ruled for the most
part by the opinion of their special group, and have little immediate
dependence upon the general public, which will not concern itself
with them so long as their work is not palpably inefficient or in some
way distasteful.
Yet special phases of thought are not really independent, but are
to be looked upon as the work of the public mind acting with a less
general consciousness—partly automatic like the action of the legs
in walking. They are still responsible to the general state of opinion;
and it is usually a general need of the special product, as shoes,
banks, education, medical aid and so on, that gives the special
group its pecuniary support and social standing. Moreover, the
general interest in a particular group is likely to become awakened
and critical when the function is disturbed, as with the building trades
or the coal-mine operators in case of a strike; or when it becomes
peculiarly important, as with the army in time of war. Then is the day
of reckoning when the specialist has to render an account of the
talents entrusted to him.
The separateness of the special group is also limited by
personality, by the fact that the men who perform the specialty do not
in other matters think apart from the rest of the society, but, in so far
as it is a moral whole, share its general spirit and are the same men
who, all taken together, are the seat of public opinion. How far the
different departments of a man’s mind, corresponding to general and
special opinion, may be ruled by different principles, is a matter of
interest from the fact that every one of us is the theatre of a conflict
of moral standards arising in this way. It is evident by general
observation and confession that we usually accept without much
criticism the principles we become accustomed to in each sphere of
activity, whether consistent with one another or not. Yet this is not
rational, and there is and must ever be a striving of conscience to
redress such conflicts, which are really divisions in society itself, and
tend toward anarchy. It is an easy but weak defence of low principles
of conduct, in business, in politics, in war, in paying taxes, to say that
a special standard prevails in this sphere, and that our behavior is
justified by custom. We cannot wholly escape from the customary,
but conscience should require of ourselves and others an honest
effort to raise its standard, even at much sacrifice of lower aims.
Such efforts are the only source of betterment, and without them
society must deteriorate.
In other words, it is the chief and perhaps the only method of
moral and intellectual progress that the thought and sentiment
pertaining to the various activities should mingle in the mind, and
that whatever is higher or more rational in each should raise the
standard of the others. If one finds that as a business man he tends
to be greedy and narrow, he should call into that sphere his
sentiments as a patriot, a member of a family and a student, and he
may enrich these latter provinces by the system and shrewdness he
learns in business. The keeping of closed compartments is a
principle of stagnation and decay.
The rule of public opinion, then, means for the most part a latent
authority which the public will exercise when sufficiently dissatisfied
with the specialist who is in immediate charge of a particular
function. It cannot extend to the immediate participation of the group
as a whole in the details of public business.
This principle holds good in the conduct of government as well as
elsewhere, experience showing that the politics of an intricate state

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Introduction to Chemistry 4th Edition Bauer Solutions

10.1 (i) < (iv) < (iii) < (ii)

10.5 (i), (ii), or (iii)

10.7 (i) exerts greater pressure, (ii) has greater density

10.13 12 green spheres

10.1 b 10.2 a 10.3 a 10.4 b

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Applying What You Know

e) 8.7 mol N2, 2.2 mol O2.

Questions and Problems

10.1 Answers will vary.

10.8 Greater than 1 atm.

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Solution: Converting to atm:

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10.14 133.322 Pa 1 atm

For the second conversion, 1 atm = 101.325 kPa.

The gravitational constant is 9.80665 m/s2.

Solution: Solving the equation for height of the column gives

Note that we consider atmospheric pressure to be exactly 1 atm.

101,325 Pa 101,325 kg/m  s 2

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pressure = height × density × gravitational constant

The gravitational constant is 9.80665 m/s2.

867 kg 9.80665 m 1 atm

10.18 Start by converting the density of isopropanol to kg/m3.

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Solution: Initial Conditions Final Conditions

P1 = 0.970 atm P2 = 0.541 atm

P1V1 0.970 atm 25.6 mL

10.22 Solve for the final pressure using Equation 10.3,

P2 = 4(5.3 atm) = 21 atm

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Solution: Initial Conditions Final Conditions

P1 = 1.00 atm = 760 mmHg P2 = ?

P1V1 760 mmHg7.15 L 

10.24 a. We use Equation 10.3 to solve for the unknown volume.

The final volume is given by:

b. We use Equation 10.3 again to solve for the unknown pressure.

The final pressure is given by:

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Solution: Initial Conditions Final Conditions

T1 = 35C + 273 = 308 K T2 = 72 + 273 = 345 K

V1T2 28.4 L345 K 

Initial Conditions Final Conditions

10.27 The balanced equation is:

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1 mol Cl2 : 3 mol F2 : 2 mol product.

1Cl2(g) + 3F2(g)   2ClxF3x(g)

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10.34 Rearranging Equation 10.9 to solve for number of moles gives

6.9 mol 0.0821 L  atm 355 K 

Think Don’t forget to convert temperatures from C to K!

10.36 We solve the ideal gas equation for V.

9.8 mol 0.0821 L  atm 378 K 

Initial Conditions Final Conditions